GB1038215A - Production of ethylene polymers and copolymers - Google Patents

Production of ethylene polymers and copolymers

Info

Publication number
GB1038215A
GB1038215A GB1997963A GB1997963A GB1038215A GB 1038215 A GB1038215 A GB 1038215A GB 1997963 A GB1997963 A GB 1997963A GB 1997963 A GB1997963 A GB 1997963A GB 1038215 A GB1038215 A GB 1038215A
Authority
GB
United Kingdom
Prior art keywords
specified
polymerization
temperature
comonomers
heat transfer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1997963A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of GB1038215A publication Critical patent/GB1038215A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

In a process for the polymerization of ethylene, with or without comonomers, in a tubular reactor at elevated pressures and temperatures in the presence of a polymerization initiator, cooling is effected by circulating a heat transfer fluid through a jacket surrounding the reactor, the temperature of the fluid being maintained below the reaction temperature and at a temperature in the range of 30 DEG to 140 DEG C. The polymerization may be carried out at 40-400 DEG C. and at pressures of 5000-60,000 p.s.i. Comonomers specified are vinyl acetate, ethyl acrylate, vinyl propionate, propylene, butene-1, acrylonitrile and vinyl chloride. Chain transfer agents (many specified) may also be present. In examples, oxygen is used as the polymerization initiator (many others are specified elsewhere) and water is used as the heat transfer medium.
GB1997963A 1962-05-21 1963-05-20 Production of ethylene polymers and copolymers Expired GB1038215A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US19642962A 1962-05-21 1962-05-21

Publications (1)

Publication Number Publication Date
GB1038215A true GB1038215A (en) 1966-08-10

Family

ID=22725389

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1997963A Expired GB1038215A (en) 1962-05-21 1963-05-20 Production of ethylene polymers and copolymers

Country Status (1)

Country Link
GB (1) GB1038215A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100113692A1 (en) * 2008-11-04 2010-05-06 Mcguire Jr James E Apparatus for Continuous Production of Partially Polymerized Compositions
WO2017106940A1 (en) * 2015-12-22 2017-06-29 Braskem S.A. Device for injecting a polymerization initiator in a tubular reactor, tubular reactor for continuous polymerization of olefins, and process for producing ethylene copolymers and polymers

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100113692A1 (en) * 2008-11-04 2010-05-06 Mcguire Jr James E Apparatus for Continuous Production of Partially Polymerized Compositions
WO2017106940A1 (en) * 2015-12-22 2017-06-29 Braskem S.A. Device for injecting a polymerization initiator in a tubular reactor, tubular reactor for continuous polymerization of olefins, and process for producing ethylene copolymers and polymers
US10829568B2 (en) 2015-12-22 2020-11-10 Braskem S.A. Tubular reactor polymerization initiator injector device, tubular reactor for continuous polymerization of olefins, and a process for production of polymers and copolymers of ethylene

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