ATE337386T1 - OXYDATION PROCESS FOR ORGANIC SULFUR COMPOUNDS. - Google Patents

OXYDATION PROCESS FOR ORGANIC SULFUR COMPOUNDS.

Info

Publication number
ATE337386T1
ATE337386T1 AT03816406T AT03816406T ATE337386T1 AT E337386 T1 ATE337386 T1 AT E337386T1 AT 03816406 T AT03816406 T AT 03816406T AT 03816406 T AT03816406 T AT 03816406T AT E337386 T1 ATE337386 T1 AT E337386T1
Authority
AT
Austria
Prior art keywords
titanium
sulfur compounds
organic sulfur
organosulfur
containing catalyst
Prior art date
Application number
AT03816406T
Other languages
German (de)
Inventor
David W Leyshon
Lawrence J Karas
Yuan-Zhang Han
Kevin M Carroll
Original Assignee
Lyondell Chemical Tech Lp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lyondell Chemical Tech Lp filed Critical Lyondell Chemical Tech Lp
Application granted granted Critical
Publication of ATE337386T1 publication Critical patent/ATE337386T1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C10G27/12—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen with oxygen-generating compounds, e.g. per-compounds, chromic acid, chromates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

This invention is a method of oxidizing organosulfur impurites found in fuel streams. The method comprises reacting the organosulfur impurities with an organic hydroperoxide in the presence of a titanium-containing catalyst. The titanium-containing catalyst is obtained by impregnating a siliceous solid with a titanium halide in a hydrocarbon solvent, or a vapor stream of titanium tetrachloride, followed by calcination. The resulting sulfones are more readily removed from the fuel stream than the non-oxidized organosulfur impurities.
AT03816406T 2003-03-13 2003-12-19 OXYDATION PROCESS FOR ORGANIC SULFUR COMPOUNDS. ATE337386T1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US10/387,849 US20040178121A1 (en) 2003-03-13 2003-03-13 Organosulfur oxidation process

Publications (1)

Publication Number Publication Date
ATE337386T1 true ATE337386T1 (en) 2006-09-15

Family

ID=32961991

Family Applications (1)

Application Number Title Priority Date Filing Date
AT03816406T ATE337386T1 (en) 2003-03-13 2003-12-19 OXYDATION PROCESS FOR ORGANIC SULFUR COMPOUNDS.

Country Status (12)

Country Link
US (1) US20040178121A1 (en)
EP (1) EP1601749B1 (en)
JP (1) JP4209394B2 (en)
KR (1) KR20050115911A (en)
CN (1) CN100339462C (en)
AT (1) ATE337386T1 (en)
AU (1) AU2003300427A1 (en)
BR (1) BR0318282A (en)
CA (1) CA2513863A1 (en)
DE (1) DE60307902T2 (en)
ES (1) ES2266923T3 (en)
WO (1) WO2004083345A1 (en)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8715489B2 (en) 2005-09-08 2014-05-06 Saudi Arabian Oil Company Process for oxidative conversion of organosulfur compounds in liquid hydrocarbon mixtures
US7744749B2 (en) 2005-09-08 2010-06-29 Saudi Arabian Oil Company Diesel oil desulfurization by oxidation and extraction
KR101642695B1 (en) 2007-05-03 2016-07-27 오테라, 인코포레이티드 Product containing monomer and polymers of titanyls and methods for making same
US8764973B2 (en) 2008-03-26 2014-07-01 Auterra, Inc. Methods for upgrading of contaminated hydrocarbon streams
US8197671B2 (en) * 2008-03-26 2012-06-12 Auterra, Inc. Methods for upgrading of contaminated hydrocarbon streams
US9206359B2 (en) 2008-03-26 2015-12-08 Auterra, Inc. Methods for upgrading of contaminated hydrocarbon streams
US8241490B2 (en) * 2008-03-26 2012-08-14 Auterra, Inc. Methods for upgrading of contaminated hydrocarbon streams
US8894843B2 (en) 2008-03-26 2014-11-25 Auterra, Inc. Methods for upgrading of contaminated hydrocarbon streams
US8298404B2 (en) 2010-09-22 2012-10-30 Auterra, Inc. Reaction system and products therefrom
US9061273B2 (en) 2008-03-26 2015-06-23 Auterra, Inc. Sulfoxidation catalysts and methods and systems of using same
EP2265694B1 (en) * 2008-03-26 2017-05-17 Auterra, Inc. Sulfoxidation method
WO2012036445A2 (en) * 2010-09-13 2012-03-22 한국화학연구원 Catalyst for selective oxidative desulfurization and preparation method thereof
US9828557B2 (en) 2010-09-22 2017-11-28 Auterra, Inc. Reaction system, methods and products therefrom
CN102059131A (en) * 2010-12-14 2011-05-18 华东理工大学 Novel titanium salt catalyst and catalytic esterification reaction thereof
WO2013049177A1 (en) 2011-09-27 2013-04-04 Saudi Arabian Oil Company Selective liquid-liquid extraction of oxidative desulfurization reaction products
KR101918775B1 (en) * 2012-08-23 2018-11-15 에스케이이노베이션 주식회사 Oxidative desulfurization process for hydrocarbon
WO2016154529A1 (en) 2015-03-26 2016-09-29 Auterra, Inc. Adsorbents and methods of use
US10450516B2 (en) 2016-03-08 2019-10-22 Auterra, Inc. Catalytic caustic desulfonylation

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3556725A (en) * 1969-02-26 1971-01-19 Sylvania Electric Prod Process for producing low-bulk density silica
US3829392A (en) * 1970-10-01 1974-08-13 Shell Oil Co Heterogeneous catalysts for olefin epoxidation
US3923843A (en) * 1972-03-13 1975-12-02 Shell Oil Co Epoxidation process with improved heterogeneous catalyst
US3816301A (en) * 1972-06-30 1974-06-11 Atlantic Richfield Co Process for the desulfurization of hydrocarbons
US5985136A (en) * 1998-06-18 1999-11-16 Exxon Research And Engineering Co. Two stage hydrodesulfurization process
US6368495B1 (en) * 1999-06-07 2002-04-09 Uop Llc Removal of sulfur-containing compounds from liquid hydrocarbon streams
US6114552A (en) * 1999-09-28 2000-09-05 Arco Chemical Technology, L.P. Heterogeneous epoxidation catalyst
CN1148436C (en) * 1999-10-28 2004-05-05 中国石油化工集团公司 Process for refining gasoline or diesel oil by oxidation method
GB9925971D0 (en) * 1999-11-03 1999-12-29 Exxon Chemical Patents Inc Reduced particulate froming distillate fuels
FR2802939B1 (en) * 1999-12-28 2005-01-21 Elf Antar France PROCESS FOR THE DESULFURATION OF THIOPHENE DERIVATIVES CONTAINED IN FUELS
US6402939B1 (en) * 2000-09-28 2002-06-11 Sulphco, Inc. Oxidative desulfurization of fossil fuels with ultrasound

Also Published As

Publication number Publication date
KR20050115911A (en) 2005-12-08
BR0318282A (en) 2006-05-30
DE60307902T2 (en) 2007-02-22
AU2003300427A1 (en) 2004-10-11
CN100339462C (en) 2007-09-26
US20040178121A1 (en) 2004-09-16
EP1601749B1 (en) 2006-08-23
DE60307902D1 (en) 2006-10-05
CA2513863A1 (en) 2004-09-30
CN1753975A (en) 2006-03-29
JP4209394B2 (en) 2009-01-14
EP1601749A1 (en) 2005-12-07
ES2266923T3 (en) 2007-03-01
JP2006514146A (en) 2006-04-27
WO2004083345A1 (en) 2004-09-30

Similar Documents

Publication Publication Date Title
ATE337386T1 (en) OXYDATION PROCESS FOR ORGANIC SULFUR COMPOUNDS.
Ravikumar et al. A selective conversion of sulfide to sulfoxide in hexafluoro-2-propanol
ES2183710A1 (en) Method and catalysts for the elimination of sulfur compounds from the diesel fraction
BR0314772A (en) Process for preparing at least one partial propylene oxidation and / or amoxidation product
WO2003000737A3 (en) MOUSE μ LIGHT CHAIN LOCUS
DE602004011222D1 (en) PROCESS FOR EPOXIDING PROPES
WO2007085514A3 (en) Method for producing methionine from homoserine
BR0208815A (en) Process for the separation and recovery of carbon dioxide from tail gas or oxidative combustion fumes
EP1916237A4 (en) Compound containing fluorosulfonyl group, process for producing the same, and polymer thereof
PT1280593E (en) PROCESS FOR THE PURIFICATION OF COMBUSTION GASES
AR035259A1 (en) HYDRODESULFURATION OF OXIDIZED SULFUR COMPOUNDS IN LIQUID HYDROCARBONS
ATE530535T1 (en) METHOD FOR PRODUCING PROPYLENE OXIDE
BRPI0503815A (en) process for production of mercaptoorganyl (alkoxysilane)
BR112018076933A2 (en) oxidation process
ATE346899T1 (en) ORGANOSULFUR OXIDATION PROCESS
WO2001066671A8 (en) Process for removing sulfur compounds from gas and liquid hydrocarbon streams
WO2003064384A3 (en) Environment friendly reagents and process for trifluoromethylsulfinylation of organic compounds
DE59911664D1 (en) METHOD FOR THE PRODUCTION OF ORGANIC DISULPHIDES
BR0212585A (en) Processes for the preparation of organic hydroperoxides, oxiran compounds and alkenylaryl
NO20074319L (en) Process for removing, by oxidation, mercaptans contained in hydrocarbons
Feng et al. Facile Approach for C (sp3)–H Bond Thioetherification of Isochroman
CY1112734T1 (en) PROTEIN PRODUCTIVITY INCREASE FACTOR, ORIGINAL CELL SERIES AND USES
ATE387424T1 (en) METHOD FOR PRODUCING CHLOROSULFONYLISOCYANATE
DE602007001451D1 (en) METHOD OF DISPOSING DISULFIDE COMPOUNDS
Dadashi Hadigavabar et al. Efficient molybdenum catalyzed chemoselective, solvent-free oxidation of sulfides to sulfones at room temperature

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties