AR111814A1 - Compuestos de formimidamida útiles contra microorganismos fitopatógenos - Google Patents
Compuestos de formimidamida útiles contra microorganismos fitopatógenosInfo
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- AR111814A1 AR111814A1 ARP180101326A ARP180101326A AR111814A1 AR 111814 A1 AR111814 A1 AR 111814A1 AR P180101326 A ARP180101326 A AR P180101326A AR P180101326 A ARP180101326 A AR P180101326A AR 111814 A1 AR111814 A1 AR 111814A1
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- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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Abstract
Reivindicación 1: Un compuesto de la fórmula general (1) en donde, R¹ es seleccionado entre el grupo que consiste en hidrógeno, CN, SR, OR, alquenilo C₁₋₁₂, alquenilo C₂₋₁₂, alquinilo C₂₋₁₂, haloalquilo C₁₋₁₂, haloalquenilo C₂₋₁₂, haloalquinilo C₂₋₁₂, alcoxi C₁₋₁₂, alqueniltio C₁₋₁₂, alquilo C₃₋₈ cíclico, alquenilo C₄₋₈ cíclico, alquinilo C₄₋₈ cíclico; en donde uno o más átomos de carbono en sistema de anillos cíclicos pueden ser reemplazados por heteroátomos seleccionados entre el grupo formado por N, O, S y que opcionalmente incluyen 1 a 3 miembros de anillos seleccionados entre el grupo formado por C(=O), C(=S), S(O)ₘ o Si(R₂); R² y R³ son independientemente seleccionados entre el grupo formado por hidrógeno, CN, S(O)ₙR, OR, (C=O)-R, alquenilo C₁₋₁₂, alquenilo C₂₋₁₂, alquinilo C₂₋₁₂, haloalquilo C₁₋₁₂, haloalquenilo C₂₋₁₂, haloalquinilo C₂₋₁₂, alquilo C₃₋₈ cíclico, alquenilo C₄₋₈, cíclico, alquinilo C₄₋₈ cíclico, arilo C₅₋₁₈, aralquilo C₇₋₁₉; en donde uno o más átomos de carbono en sistema de anillos cíclicos pueden ser reemplazados por heteroátomos seleccionados entre el grupo formado por N, O, S y que opcionalmente incluyen 1 a 3 miembros de anillos seleccionados entre el grupo formado por C(=O), C(=S), S(O)ₘ o Si(R₂); R¹ y R², R² y R³ o R¹ y R³ junto con los átomos a los que se encuentran fijados o junto con otros átomos seleccionados entre el grupo formado por C, N, O, S y que opcionalmente incluyen 1 a 3 miembros de anillos seleccionados entre el grupo formado por C(=O), C(=S), S(O)ₘ o Si(R₂) pueden formar un anillo no aromático de tres a siete miembros, que por su parte pueden ser sustituidos por uno o más X, R, OR, SR, N(R)₂, Si(R)₃, COOR, CN, o CON(R)₂; en donde, cada uno entre R¹, R² y R³ puede ser opcionalmente sustituido por uno o más grupos seleccionados entre el grupo formado por X, R, OR, SR, N(R)₂, Si(R)₃, COOR, CN, o CON(R)₂; A¹, A², A³ y A⁴ representan CR⁴ o nitrógeno; siempre que no más de dos entre A¹, A², A³ y A⁴ sean nitrógeno simultáneamente; R⁴ es independientemente seleccionado entre el grupo formado por hidrógeno, X, CN, N(R)₂, SCN, SF₅, S(O)ₙR, Si(R)₃, OR, (C=O)-R, CR=NR, alquenilo C₁₋₁₂, alquenilo C₂₋₁₂, alquinilo C₂₋₁₂, haloalquilo C₂₋₁₂, haloalquenilo C₂₋₁₂, haloalquinilo C₂₋₁₂, alquilo C₃₋₈ cíclico, alquenilo C₄₋₈ cíclico, alquinilo C₄₋₈ cíclico, arilo C₅₋₁₈, aralquilo C₇₋₁₉; en donde uno o más átomos de carbono en sistema de anillos cíclicos pueden ser reemplazados por heteroátomos seleccionados entre el grupo formado por N, O, S y que opcionalmente incluyen 1 a 3 miembros de anillos seleccionados entre el grupo formado por C(=O), C(=S), S(O)ₘ o Si(R₂); o dos R⁴ vecinos junto con el átomo al cual se encuentran fijados o junto con otros átomos seleccionados entre el grupo formado por C, N, O, S y que opcionalmente incluyen 1 a 3 miembros de anillos seleccionados entre el grupo formado por C(=O), C(=S), S(O)ₘ o Si(R₂) pueden formar un anillo de cuatro a siete miembros, que por su parte pueden ser sustituidos por uno o más X, R, OR, SR, N(R)₂, Si(R)₃, COOR, CN, o CON(R)₂; L representa O, S, NR, CR⁵R⁶ o T; en donde cuando L representa O, S, NR, CR⁵R⁶ entonces w ¹ 0, en donde T representa un radical seleccionado entre T1 a T12 del grupo de fórmulas (2); en donde el lado izquierdo del fragmento T se fija a Q; en donde la línea ondulada representan fijaciones del átomo o grupo; R⁵ y R⁶ son independientemente seleccionados entre el grupo formado por hidrógeno, X, CN, NR₂, SCN, S(O)ₙR, Si(R)₃, OR, (C=O)-R, CR=NR, alquenilo C₁₋₁₂, alquenilo C₂₋₁₂, alquinilo C₂₋₁₂, haloalquilo C₁₋₁₂, haloalquenilo C₂₋₁₂, haloalquinilo C₂₋₁₂, alquilo C₃₋₈ cíclico, alquenilo C₄₋₈ cíclico, alquinilo C₄₋₈ cíclico, arilo C₅₋₁₈, aralquilo C₇₋₁₉; en donde uno o más átomos de carbono en sistema de anillos cíclicos pueden ser reemplazados por heteroátomos seleccionados entre el grupo formado por N, O, S y que opcionalmente incluyen 1 a 3 miembros de anillos seleccionados entre el grupo formado por C(=O), C(=S), S(O)ₘ o Si(R₂); o R⁵ y R⁶ junto con el átomo al cual se encuentran fijados o junto con otros átomos seleccionados entre el grupo formado por C, N, O, S y que opcionalmente incluyen 1 a 3 miembros de anillos seleccionados entre el grupo formado por C(=O), C(=S), S(O)ₘ o Si(R₂) pueden formar un anillo de tres a siete miembros, que por su parte pueden ser sustituidos por uno o más X, R, OR, SR, N(R)₂, Si(R)₃, COOR, CN, o CON(R)₂; o R⁵ y R⁶ juntos representan el grupo seleccionado entre =C(RR), =S, =O, =NR; el Anillo Q representa carbociclo opcionalmente sustituido, en donde uno o más átomos de carbono pueden ser reemplazados por heteroátomos seleccionados entre N, O, S y que opcionalmente incluyen 1 a 3 miembros de anillos seleccionados entre el grupo formado por C(=O), C(=S), S(O)ₘ o Si(R₂); en donde R⁷ es seleccionado entre el grupo que consiste en hidrógeno, X, CN, SCN, SF₅, OR, NO₂, N(R)₂, Si(R)₃, (C=O)-R, S(O)ₙR, alquilo C₁₋₈-S(O)ₙR, alquilo C₁₋₈-(C=O)-R, CR=NR, S(O)ₙ-arilo C₅₋₁₈, S(O)ₙ-aralquilo C₇₋₁₉, S(O)ₙ-alcarilo C₇₋₁₉, alquenilo C₁₋₁₂, alquenilo C₂₋₁₂, alquinilo C₂₋₁₂, haloalquilo C₁₋₁₂, haloalquenilo C₂₋₁₂, haloalquinilo C₂₋₁₂, alquilo C₃₋₈ cíclico, alquenilo C₄₋₈ cíclico, alquinilo C₄₋₈ cíclico, aralquilo C₇₋₁₉, alquilo C₅₋₁₂ bicíclico, alquenilo C₇₋₁₂ bicíclico, o un resto del grupo de fórmulas (3); en donde uno o más átomos de carbono en sistema de anillos cíclicos pueden ser reemplazados por heteroátomos seleccionados entre el grupo formado por N, O, S y que opcionalmente incluyen 1 a 3 miembros de anillos seleccionados entre el grupo formado por C(=O), C(=S), S(O)ₘ o Si(R₂); R⁷ es independientemente seleccionado entre el grupo fórmado por los restos del grupo de fórmulas (3); opcionalmente sustituidos, en donde R⁸ es independientemente seleccionado entre el grupo formado por R, N(RR), Si(R)₃, (C=O)-R, alquilo C₁₋₈-S(O)ₙR, alquilo C₁₋₈-(C=O)-R, CR=NR, alquenilo C₁₋₁₂, alquenilo C₂₋₁₂, alquinilo C₂₋₁₂, haloalquilo C₁₋₁₂, haloalquenilo C₂₋₁₂, haloalquinilo C₂₋₁₂, alquilo C₃₋₈ cíclico, alquenilo C₄₋₈ cíclico, alquinilo C₄₋₈ cíclico, aralquilo C₇₋₁₉, alquilo C₅₋₁₂ bicíclico, alquenilo C₇₋₁₂ bicíclico, carbociclo C₃₋₁₈ fusionado o no fusionado o bicíclico sustituido con uno o más R¹⁰; en donde uno o más átomos de carbono en sistema de anillos cíclicos pueden ser reemplazados por heteroátomos seleccionados entre el grupo formado por N, O, S y que opcionalmente incluyen 1 a 3 miembros de anillos seleccionados entre el grupo formado por C(=O), C(=S), S(O)ₘ o Si(R₂); R⁹ es seleccionado entre el grupo que consiste en hidrógeno, CN, OR, N(RR), Si(R)₃, (C=O)-R, S(O)ₙR, alquilo C₁₋₈-S(O)ₙR, alquilo C₁₋₈-(C=O)-R, CR=NR, S(O)ₙ-arilo C₅₋₁₈, S(O)ₙ-aralquilo C₇₋₁₉, S(O)ₙ-alcarilo C₇₋₁₉, alquilo C₁₋₁₂, alquenilo C₂₋₁₂, alquinilo C₂₋₁₂, alquinilo C₂₋₁₂-alquilo C₁₋₆, haloalquilo C₁₋₁₂, haloalquenilo C₂₋₁₂, haloalquinilo C₂₋₁₂, alquilo C₃₋₈ cíclico, alquenilo C₄₋₈ cíclico, alquinilo C₄₋₈ cíclico, aralquilo C₇₋₁₉, alquilo C₅₋₁₂ bicíclico, alquenilo C₇₋₁₂ bicíclico, C₃₋₁₈ fusionado o no fusionado o bicíclico sustituido con uno o más R¹⁰; en donde uno o más átomos de carbono en sistema de anillos cíclicos pueden ser reemplazados por heteroátomos seleccionados entre el grupo formado por N, O, S y que opcionalmente incluyen 1 a 3 miembros de anillos seleccionados entre el grupo formado por C(=O), C(=S), S(O)ₘ o Si(R₂); o R⁷ y R⁸, R⁷ y R⁹, R⁸ y R⁹, R⁸ y R⁴, dos R⁸ o dos R⁷ junto con el átomo al cual se encuentran fijados o junto con otros átomos seleccionados entre el grupo formado por C, N, O, S y que opcionalmente incluyen 1 a 3 miembros de anillos seleccionados entre el grupo formado por C(=O), C(=S), S(O)ₘ o Si(R₂) pueden formar un anillo de tres a siete miembros, que por su parte pueden ser sustituidos por uno o más X, R, OR, SR, N(R)₂, Si(R)₃, COOR, CN, o CON(R)₂; R¹⁰ es seleccionado entre el grupo que consiste en hidrógeno, X, CN, N(R)₂, SCN, S(O)ₙR, Si(R)₃, OR, (C=O)-R, CR=NR, alquilo C₁₋₁₂, alquenilo C₂₋₁₂, alquinilo C₂₋₁₂, haloalquilo C₁₋₁₂, haloalquenilo C₂₋₁₂, haloalquinilo C₂₋₁₂, alquilo C₃₋₈ cíclico, alquenilo C₄₋₈ cíclico, en donde uno o más átomos de carbono en sistema de anillos cíclicos pueden ser reemplazados por heteroátomos seleccionados entre el grupo formado por N, O, S y que opcionalmente incluyen 1 a 3 miembros de anillos seleccionados entre el grupo formado por C(=O), C(=S), S(O)ₘ o Si(R₂), en donde cada uno entre R⁴, R⁵, R⁶, R⁷, R⁸, R⁹ y R¹⁰ puede ser opcionalmente sustituido por uno o más grupos seleccionados entre el grupo formado por X, R, OR, SR, N(RR), Si(R)₃, COOR, CN, y CON(RR); en donde X representa halógeno; R representa hidrógeno, alquenilo C₁₋₁₂ o alquilo C₃₋₁₀ cíclico en donde los grupos alquilo y cicloalquilo pueden ser opcionalmente sustituidos por uno o más X; R representa hidrógeno; N(R)₂, OR, alquenilo C₁₋₁₂, haloalquilo C₁₋₁₂, alquilo C₃₋₈ cíclico que pueden ser opcionalmente sustituidos por uno o más grupos seleccionados entre el grupo formado por X, R, OR, SR, N(R)₂, Si(R)₃, COOR, CN, o CON(R)₂, arilo C₅₋₁₈ que pueden ser opcionalmente sustituidos por uno o más X, R, OR, SR, N(R)₂, Si(R)₃, COOR, CN, o CON(R)₂; en donde uno o más átomos de carbono en sistema de anillos cíclicos pueden ser reemplazados por heteroátomos seleccionados entre el grupo formado por N, O, S y que opcionalmente incluyen 1 a 3 miembros de anillos seleccionados entre el grupo formado por C(=O), C(=S), S(O)ₘ o Si(R₂); R es seleccionado entre los grupos formados por hidrógeno, R, CN, OR, (C=O)-R, COOR, CON(R)₂, alquenilo C₁₋₁₂, haloalquilo C₂₋₁₂, alquenilo C₂₋₁₂, alquinilo C₂₋₁₂, alquilo C₃₋₈ cíclico, alquenilo C₄₋₈ cíclico, alquinilo C₄₋₈ cíclico, arilo C₆₋₁₈, aralquilo C₇₋₁₉, alcarilo C₇₋₁₉, en donde uno o más átomos de carbono en sistema de anillos cíclicos pueden ser reemplazados por heteroátomos seleccionados entre el grupo formado por N, O, S y que opcionalmente incluyen 1 a 3 miembros de anillos seleccionados entre el grupo formado por C(=O), C(=S), S(O)ₘ o Si(R₂); y cada uno de los grupos anteriores pueden ser sustituidos por uno o más grupos seleccionados entre el grupo formado por X, R, OR, SR, N(R)₂, Si(R)₃, COOR, CN, o CON(R)₂; en donde n representa un entero 0, 1 ó 2; v representa un entero 0, 1, 2, 3, 4 ó 5; y w representa un entero 0 ó 1; y sales agronómicamente aceptables, isómeros / isómeros estructurales, estéreo-isómeros, diastereoisómeros, enantiómeros, tautómeros, o N-óxidos de los mismos.
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TW202237561A (zh) * | 2020-11-23 | 2022-10-01 | 美商科迪華農業科技有限責任公司 | 殺真菌芳基脒 |
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-
2018
- 2018-05-17 EP EP18739630.4A patent/EP3625215B1/en active Active
- 2018-05-17 US US16/613,815 patent/US20200148635A1/en not_active Abandoned
- 2018-05-17 WO PCT/IB2018/053456 patent/WO2018211442A1/en unknown
- 2018-05-17 JP JP2019563737A patent/JP2020520373A/ja active Pending
- 2018-05-17 BR BR112019023453-5A patent/BR112019023453A2/pt active Search and Examination
- 2018-05-17 CN CN201880032808.4A patent/CN110770210A/zh active Pending
- 2018-05-17 TW TW107116747A patent/TW201900604A/zh unknown
- 2018-05-18 AR ARP180101326A patent/AR111814A1/es unknown
- 2018-05-18 UY UY0001037739A patent/UY37739A/es not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
UY37739A (es) | 2018-11-30 |
WO2018211442A1 (en) | 2018-11-22 |
JP2020520373A (ja) | 2020-07-09 |
EP3625215A1 (en) | 2020-03-25 |
CN110770210A (zh) | 2020-02-07 |
EP3625215B1 (en) | 2023-09-13 |
US20200148635A1 (en) | 2020-05-14 |
TW201900604A (zh) | 2019-01-01 |
BR112019023453A2 (pt) | 2020-06-16 |
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