AR027616A1 - Un procedimiento para la produccion de monoxido de carbono por retroconversion inversa con un catalizador adaptado - Google Patents
Un procedimiento para la produccion de monoxido de carbono por retroconversion inversa con un catalizador adaptadoInfo
- Publication number
- AR027616A1 AR027616A1 ARP010101059A ARP010101059A AR027616A1 AR 027616 A1 AR027616 A1 AR 027616A1 AR P010101059 A ARP010101059 A AR P010101059A AR P010101059 A ARP010101059 A AR P010101059A AR 027616 A1 AR027616 A1 AR 027616A1
- Authority
- AR
- Argentina
- Prior art keywords
- gaseous
- carbon monoxide
- production
- carried out
- temperature
- Prior art date
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/26—Chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/86—Chromium
- B01J23/866—Nickel and chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0242—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
- B01J8/025—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical in a cylindrical shaped bed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0285—Heating or cooling the reactor
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/40—Carbon monoxide
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00115—Controlling the temperature by indirect heat exchange with heat exchange elements inside the bed of solid particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00176—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles outside the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00212—Plates; Jackets; Cylinders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00477—Controlling the temperature by thermal insulation means
- B01J2208/00495—Controlling the temperature by thermal insulation means using insulating materials or refractories
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/18—Details relating to the spatial orientation of the reactor
- B01J2219/182—Details relating to the spatial orientation of the reactor horizontal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/19—Details relating to the geometry of the reactor
- B01J2219/194—Details relating to the geometry of the reactor round
- B01J2219/1941—Details relating to the geometry of the reactor round circular or disk-shaped
- B01J2219/1943—Details relating to the geometry of the reactor round circular or disk-shaped cylindrical
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
Abstract
Un procedimiento para la produccion de monoxido de carbono por retroconversion inversa en fase gaseosa, de anhídrido carbonico gaseoso y de hidrogenogaseoso con minimizacion de la produccion de metano, en donde la reaccion se realiza a una temperatur a de 300 a 520*C y bajo una presion de 10 a 40 bars enpresencia de un catalizador a base de oxido de zinc y oxido de cromo, que no contiene hierro. Este procedimiento es preferentemente continuo y comprendepreferentemente las etapas que consisten en: a) preparar una mezcla gaseosa rica en dioxido de carbono y en hidrogeno que presenta una temperatura comprendidaentre 300 y 520*C; b) hacer reaccionar dicha mezcla gaseosa, con formacion de monoxido de carbono y de vapor de agua, mediante el pasaje de dicha mezclagaseosa a través de un lecho catalítico provisto de un catalizador a base de oxido de zinc y de oxido de cromo y mantenido bajo una presion de 10 a 40 bars; c)enfriar el flujo gaseoso que sale de dicho lecho catalítico de manera tal d e provocar la condensacion de todo o parte del vapor de agua formado; d) separar elagua condensada de dicho flujo gaseoso; y e) llegado el caso, volver a procesar por lo menos una vez el flujo gaseoso resultante, previamente llevado a unatemperatura de 300 a 520*C, efectuando las etapas b) a d) precedentes, de manera tal de aumentar la proporcion de monoxido de carbono en el flujo gaseoso,realizandose preferentemente cada etapa b) en un lecho catalítico distinto.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0002927A FR2806073B1 (fr) | 2000-03-07 | 2000-03-07 | Procede de production de monoxyde de carbone par retroconversion inverse avec un catalyseur adapte |
Publications (1)
Publication Number | Publication Date |
---|---|
AR027616A1 true AR027616A1 (es) | 2003-04-02 |
Family
ID=8847823
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP010101059A AR027616A1 (es) | 2000-03-07 | 2001-03-07 | Un procedimiento para la produccion de monoxido de carbono por retroconversion inversa con un catalizador adaptado |
Country Status (18)
Country | Link |
---|---|
US (1) | US20030113244A1 (es) |
EP (1) | EP1263681B1 (es) |
JP (1) | JP4903339B2 (es) |
KR (1) | KR100760502B1 (es) |
CN (1) | CN1198758C (es) |
AR (1) | AR027616A1 (es) |
AT (1) | ATE303342T1 (es) |
AU (1) | AU3935801A (es) |
BR (1) | BR0109037B1 (es) |
CA (1) | CA2399956A1 (es) |
DE (1) | DE60113070T2 (es) |
ES (1) | ES2247077T3 (es) |
FR (1) | FR2806073B1 (es) |
HU (1) | HUP0300106A2 (es) |
PL (1) | PL201232B1 (es) |
TW (1) | TWI221463B (es) |
WO (1) | WO2001066463A1 (es) |
ZA (1) | ZA200206409B (es) |
Families Citing this family (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100555294B1 (ko) * | 2003-09-17 | 2006-03-03 | 한국과학기술연구원 | 역수성가스 반응을 이용한 디메틸에테르의 제조방법 |
US7351275B2 (en) * | 2004-12-21 | 2008-04-01 | The Boc Group, Inc. | Carbon monoxide production process |
US20080110801A1 (en) * | 2006-11-09 | 2008-05-15 | Leon Yuan | Process For Heating A Hydrocarbon Stream Entering A Reaction Zone With A Heater Convection Section |
US7740751B2 (en) | 2006-11-09 | 2010-06-22 | Uop Llc | Process for heating a stream for a hydrocarbon conversion process |
EP2152409B1 (en) * | 2007-04-27 | 2016-06-29 | Saudi Basic Industries Corporation | Catalytic hydrogenation of carbon dioxide into syngas mixture |
WO2009000494A2 (en) * | 2007-06-25 | 2008-12-31 | Saudi Basic Industries Corporation | Catalytic hydrogenation of carbon dioxide into syngas mixture |
CN102256687A (zh) | 2008-12-17 | 2011-11-23 | 沙特基础工业公司 | 增加合成气混合物中一氧化碳含量的方法 |
US8282814B2 (en) * | 2009-03-31 | 2012-10-09 | Uop Llc | Fired heater for a hydrocarbon conversion process |
CN101624186B (zh) * | 2009-07-31 | 2011-09-14 | 崔卫东 | 二氧化碳选择性加氢合成一氧化碳的方法 |
US8658554B2 (en) * | 2009-11-04 | 2014-02-25 | The United States Of America, As Represented By The Secretary Of The Navy | Catalytic support for use in carbon dioxide hydrogenation reactions |
WO2012153762A1 (ja) * | 2011-05-11 | 2012-11-15 | 株式会社村田製作所 | 逆シフト反応用触媒、およびそれを用いた合成ガスの製造方法 |
US8962702B2 (en) | 2011-12-08 | 2015-02-24 | Saudi Basic Industries Corporation | Mixed oxide based catalyst for the conversion of carbon dioxide to syngas and method of preparation and use |
MX354529B (es) * | 2012-04-16 | 2018-03-07 | Seerstone Llc | Métodos para producir carbono sólido mediante la reducción de dióxido de carbono. |
CN104395232A (zh) * | 2012-06-21 | 2015-03-04 | 沙特基础工业公司 | 用于生产合成气混合物的方法 |
US8551434B1 (en) | 2012-06-29 | 2013-10-08 | Saudi Basic Industries Corporation | Method of forming a syngas mixture |
US8647493B2 (en) * | 2012-07-26 | 2014-02-11 | Liquid Light, Inc. | Electrochemical co-production of chemicals employing the recycling of a hydrogen halide |
WO2014180888A1 (en) * | 2013-05-08 | 2014-11-13 | Shell Internationale Research Maatschappij B.V. | Process for the preparation of syngas |
CA2919752C (en) | 2013-07-31 | 2023-10-03 | Research Triangle Institute | Mixed metal iron oxides and uses thereof |
WO2015066117A1 (en) | 2013-10-29 | 2015-05-07 | Saudi Basic Industries Corporation | Method for carbon dioxide hydrogenation of syngas and the integration of the process with syngas conversion processes |
EP3092287A1 (en) | 2014-01-06 | 2016-11-16 | Saudi Basic Industries Corporation | Method for carbon dioxide hydrogenation of syngas |
CN106133118B (zh) | 2014-04-03 | 2018-03-23 | 沙特基础工业公司 | 使用co2转化甲烷蒸汽重整合成气的方法 |
US20180029884A1 (en) * | 2015-02-23 | 2018-02-01 | Sabic Global Technologies B.V. | Methods for hydrogenation of carbon dioxide to syngas |
RU2660139C1 (ru) * | 2017-11-28 | 2018-07-05 | Федеральное государственное автономное образовательное учреждение высшего образования "Национальный исследовательский технологический университет "МИСиС" | Способ получения синтез-газа из CO2 |
WO2021062384A1 (en) | 2019-09-27 | 2021-04-01 | Oxy Low Carbon Ventures, Llc | Process for the conversion of carbon dioxide |
US11498886B2 (en) | 2020-05-04 | 2022-11-15 | Infinium Technology, Llc | Catalysts and processes for the direct production of liquid fuels from carbon dioxide and hydrogen |
EP4146387A1 (en) | 2020-05-04 | 2023-03-15 | Infinium Technology, LLC | Reverse water gas shift catalytic reactor systems |
EP4146372A1 (en) | 2020-05-04 | 2023-03-15 | Infinium Technology, LLC | Process for capture of carbon dioxide from air and the direct conversion of carbon dioxide into fuels and chemicals |
JP2023527651A (ja) | 2020-05-04 | 2023-06-30 | インフィニウム テクノロジー,エルエルシー | 二酸化炭素及び電気を燃料及び化学物質へと変換するための方法 |
US11819815B2 (en) | 2021-11-19 | 2023-11-21 | Infinium Technology, Llc | Catalytic reactor for the conversion of carbon dioxide and hydrogen to syngas |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3718418A (en) * | 1970-09-01 | 1973-02-27 | Inst Gas Technology | Co shift process |
JPS53119798A (en) * | 1977-03-30 | 1978-10-19 | Mitsui Toatsu Chem Inc | Production of carbon monoxide |
US4265868A (en) * | 1978-02-08 | 1981-05-05 | Koppers Company, Inc. | Production of carbon monoxide by the gasification of carbonaceous materials |
FR2593164B1 (fr) * | 1986-01-17 | 1989-08-18 | Charbonnages Ste Chimique | Procede de fabrication d'oxyde de carbone a partir d'un melange de gaz carbonique et d'hydrogene et catalyseur pour la mise en oeuvre de ce procede. |
JP2535752B2 (ja) * | 1991-09-25 | 1996-09-18 | 工業技術院長 | 炭酸ガスの気相還元方法 |
DK169615B1 (da) * | 1992-12-10 | 1994-12-27 | Topsoe Haldor As | Fremgangsmåde til fremstilling af carbonmonoxidrig gas |
JPH06279012A (ja) * | 1993-03-24 | 1994-10-04 | Tosoh Corp | 一酸化炭素の製造方法 |
JP2847018B2 (ja) * | 1993-06-25 | 1999-01-13 | 株式会社コスモ総合研究所 | 二酸化炭素還元反応触媒 |
US5911964A (en) * | 1993-06-25 | 1999-06-15 | Cosmo Research Institute | Method for reducing carbon dioxide using a catalyst for reduction of carbon dioxide |
JPH07136462A (ja) * | 1993-11-12 | 1995-05-30 | Toshiba Corp | 排ガス中の二酸化炭素固定方法及びこの方法を用いた環境調和型発電プラント |
JPH07299330A (ja) * | 1994-05-11 | 1995-11-14 | Toshiba Corp | 排ガス処理装置 |
JPH08245211A (ja) * | 1995-03-09 | 1996-09-24 | Tosoh Corp | 一酸化炭素の製造方法 |
-
2000
- 2000-03-07 FR FR0002927A patent/FR2806073B1/fr not_active Expired - Fee Related
-
2001
- 2001-03-05 TW TW090105221A patent/TWI221463B/zh not_active IP Right Cessation
- 2001-03-07 AR ARP010101059A patent/AR027616A1/es unknown
- 2001-03-07 AT AT01913958T patent/ATE303342T1/de not_active IP Right Cessation
- 2001-03-07 EP EP01913958A patent/EP1263681B1/fr not_active Expired - Lifetime
- 2001-03-07 PL PL365425A patent/PL201232B1/pl not_active IP Right Cessation
- 2001-03-07 ES ES01913958T patent/ES2247077T3/es not_active Expired - Lifetime
- 2001-03-07 DE DE60113070T patent/DE60113070T2/de not_active Expired - Lifetime
- 2001-03-07 US US10/220,873 patent/US20030113244A1/en not_active Abandoned
- 2001-03-07 JP JP2001565286A patent/JP4903339B2/ja not_active Expired - Fee Related
- 2001-03-07 BR BRPI0109037-2A patent/BR0109037B1/pt not_active IP Right Cessation
- 2001-03-07 AU AU39358/01A patent/AU3935801A/en not_active Abandoned
- 2001-03-07 CA CA002399956A patent/CA2399956A1/fr not_active Abandoned
- 2001-03-07 WO PCT/FR2001/000689 patent/WO2001066463A1/fr active IP Right Grant
- 2001-03-07 KR KR1020027011687A patent/KR100760502B1/ko not_active IP Right Cessation
- 2001-03-07 CN CNB018062067A patent/CN1198758C/zh not_active Expired - Fee Related
- 2001-03-07 HU HU0300106A patent/HUP0300106A2/hu unknown
-
2002
- 2002-08-12 ZA ZA200206409A patent/ZA200206409B/xx unknown
Also Published As
Publication number | Publication date |
---|---|
ZA200206409B (en) | 2004-01-30 |
PL201232B1 (pl) | 2009-03-31 |
DE60113070D1 (de) | 2005-10-06 |
FR2806073A1 (fr) | 2001-09-14 |
PL365425A1 (en) | 2005-01-10 |
ATE303342T1 (de) | 2005-09-15 |
US20030113244A1 (en) | 2003-06-19 |
JP4903339B2 (ja) | 2012-03-28 |
HUP0300106A2 (en) | 2003-05-28 |
EP1263681A1 (fr) | 2002-12-11 |
CN1416404A (zh) | 2003-05-07 |
EP1263681B1 (fr) | 2005-08-31 |
DE60113070T2 (de) | 2006-09-21 |
CN1198758C (zh) | 2005-04-27 |
KR100760502B1 (ko) | 2007-10-04 |
WO2001066463A1 (fr) | 2001-09-13 |
BR0109037B1 (pt) | 2010-02-23 |
AU3935801A (en) | 2001-09-17 |
KR20020092378A (ko) | 2002-12-11 |
JP2003525832A (ja) | 2003-09-02 |
TWI221463B (en) | 2004-10-01 |
FR2806073B1 (fr) | 2002-06-07 |
ES2247077T3 (es) | 2006-03-01 |
CA2399956A1 (fr) | 2001-09-13 |
BR0109037A (pt) | 2003-06-03 |
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