AR012324A1 - Proceso para la polimerizacion de monomeros de olefinas para producir polimeros y sistemas de catalizadores de aplicacion en dicho proceso - Google Patents
Proceso para la polimerizacion de monomeros de olefinas para producir polimeros y sistemas de catalizadores de aplicacion en dicho procesoInfo
- Publication number
- AR012324A1 AR012324A1 ARP980101529A ARP980101529A AR012324A1 AR 012324 A1 AR012324 A1 AR 012324A1 AR P980101529 A ARP980101529 A AR P980101529A AR P980101529 A ARP980101529 A AR P980101529A AR 012324 A1 AR012324 A1 AR 012324A1
- Authority
- AR
- Argentina
- Prior art keywords
- catalyst
- polymerization
- metallocene complex
- component
- monomers
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/905—Polymerization in presence of transition metal containing catalyst in presence of hydrogen
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Se trata un proceso para polimerizar monomeros de olefinas utilizando sistemas catalizadores de alto rendimiento en poliolefinas; dicho proceso esde aplicacion para la polimerizacion de un monomero de olefina, o de un monomero de olefina y uno o más comonomeros, para producir polímeros enreactores de polimerizacion en presencia de un sistema catalizador de polimerizacion de olefinas soportado producido a partir de componentes decatalizacion que comprenden: 1) un componente de material de soporte que comprende uno o más materiales de soporte deshidratados; 2) un componentede complejo de metaloceno que comprende uno o más complejos de metaloceno usados en un rango de carga total de desde aproximadamente 0.1 hastaaproximadamente 25 micrones mol de complejo de metaloceno/gramo de componente de material de soporte; 3) un componente activador que comprende unoo más activadores usados en un rango de proporciones molares de moles totales de activador contra moles totales de complejo de metaloceno de desdeaproximadamente 0.5 hasta aproximadamente 2.5; en donde el sistema catalizador se usa a una concentracion de catalizador en el rango de desde aproximadamente0.01 hasta aproximadamente 6moles de catalizador activo/mol de monomero, y una eficiencia de catalizador resulta que es de cuando menos 2.4 x 10 (7) gramosde polímero/gramos mol catalizador/hora.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US4263897P | 1997-04-04 | 1997-04-04 |
Publications (1)
Publication Number | Publication Date |
---|---|
AR012324A1 true AR012324A1 (es) | 2000-10-18 |
Family
ID=21922978
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP980101529A AR012324A1 (es) | 1997-04-04 | 1998-04-03 | Proceso para la polimerizacion de monomeros de olefinas para producir polimeros y sistemas de catalizadores de aplicacion en dicho proceso |
Country Status (22)
Country | Link |
---|---|
US (1) | US6479599B1 (es) |
EP (1) | EP0971962B1 (es) |
JP (1) | JP2001524144A (es) |
KR (1) | KR100538590B1 (es) |
CN (1) | CN1255928A (es) |
AR (1) | AR012324A1 (es) |
AT (1) | ATE259384T1 (es) |
AU (1) | AU738227B2 (es) |
BR (1) | BR9807921A (es) |
CA (1) | CA2284789A1 (es) |
DE (1) | DE69821605T2 (es) |
EG (1) | EG22079A (es) |
HU (1) | HUP0001378A3 (es) |
ID (1) | ID22626A (es) |
MY (1) | MY118708A (es) |
NZ (1) | NZ337968A (es) |
PL (1) | PL336078A1 (es) |
SK (1) | SK135199A3 (es) |
TR (1) | TR199902755T2 (es) |
TW (1) | TW572915B (es) |
WO (1) | WO1998045337A1 (es) |
ZA (1) | ZA982860B (es) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU1842300A (en) * | 1998-12-30 | 2000-07-24 | Bp Chemicals Limited | Process for preparing a supported polymerization catalyst using reduced amounts of solvent and polymerization process |
US6852811B1 (en) | 1998-12-30 | 2005-02-08 | The Dow Chemical Company | Process for preparing a supported polymerization catalyst using reduced amounts of solvent and polymerization process |
US6211311B1 (en) * | 1999-05-25 | 2001-04-03 | Equistar Chemicals, L.P. | Supported olefin polymerization catalysts |
US6291386B1 (en) * | 1999-05-25 | 2001-09-18 | Equistar Chemicals, Lp | Process for the in-situ preparation of single-site transition metal catalysts and polymerization process |
GB9918668D0 (en) * | 1999-08-06 | 1999-10-13 | Bp Chem Int Ltd | Polymerisation catalysts |
KR100371909B1 (ko) * | 1999-12-20 | 2003-02-11 | 삼성종합화학주식회사 | 다핵으로 구속된 배열을 갖는 메탈로센 촉매 및 이를이용한 에틸렌/방향족 비닐화합물의 공중합체 |
DE19962910A1 (de) * | 1999-12-23 | 2001-07-05 | Targor Gmbh | Chemische Verbindung, Verfahren zu deren Herstellung und deren Verwendung in Katalysatorsystemen zur Herstellung von Polyolefinen |
GB0319738D0 (en) | 2003-08-22 | 2003-09-24 | Bp Chem Int Ltd | Supported polymerisation catalysts |
EP1930348A1 (en) * | 2006-12-05 | 2008-06-11 | Ineos Manufacturing France SAS | Supported catalyst system |
JP6457716B2 (ja) | 2011-01-14 | 2019-01-23 | ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット | 修飾メタロセン触媒の作成法、生成された触媒およびそれらの使用 |
CN104926963A (zh) * | 2015-06-26 | 2015-09-23 | 哈尔滨工业大学 | 1-丁烯齐聚反应合成聚α-烯烃基础油的方法 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DZ520A1 (fr) | 1982-03-24 | 2004-09-13 | Union Carbide Corp | Procédé perfectionné pour accroitre le rendement espace temps d'une réaction de polymérisation exothermique en lit fluidisé. |
US4543399A (en) | 1982-03-24 | 1985-09-24 | Union Carbide Corporation | Fluidized bed reaction systems |
US4912075A (en) * | 1987-12-17 | 1990-03-27 | Exxon Chemical Patents Inc. | Method for preparing a supported metallocene-alumoxane catalyst for gas phase polymerization |
US5352749A (en) | 1992-03-19 | 1994-10-04 | Exxon Chemical Patents, Inc. | Process for polymerizing monomers in fluidized beds |
EP0699212A1 (en) | 1993-04-26 | 1996-03-06 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
ZA943399B (en) | 1993-05-20 | 1995-11-17 | Bp Chem Int Ltd | Polymerisation process |
NZ268270A (en) * | 1993-06-24 | 1997-10-24 | Dow Chemical Co | Titanium (ii)- or zirconium (ii)- containing complexes and addition polymerisation catalysts therefrom (m is ti or zr) |
US5466649A (en) * | 1993-10-15 | 1995-11-14 | Exxon Chemical Patents Inc. | Polymerization catalyst systems, their production and use |
WO1995014044A1 (en) * | 1993-11-19 | 1995-05-26 | Exxon Chemical Patents Inc. | Polymerization catalyst systems, their production and use |
JPH11503113A (ja) * | 1995-03-10 | 1999-03-23 | ザ ダウ ケミカル カンパニー | 支持された触媒成分、支持された触媒、製造法、重合法、錯体化合物、及びその製造法 |
-
1998
- 1998-03-30 SK SK1351-99A patent/SK135199A3/sk unknown
- 1998-03-30 HU HU0001378A patent/HUP0001378A3/hu unknown
- 1998-03-30 WO PCT/US1998/006271 patent/WO1998045337A1/en active IP Right Grant
- 1998-03-30 NZ NZ337968A patent/NZ337968A/en unknown
- 1998-03-30 PL PL98336078A patent/PL336078A1/xx unknown
- 1998-03-30 US US09/381,664 patent/US6479599B1/en not_active Expired - Fee Related
- 1998-03-30 JP JP54284798A patent/JP2001524144A/ja not_active Ceased
- 1998-03-30 ID IDW991150A patent/ID22626A/id unknown
- 1998-03-30 KR KR10-1999-7009019A patent/KR100538590B1/ko not_active IP Right Cessation
- 1998-03-30 EP EP98913310A patent/EP0971962B1/en not_active Revoked
- 1998-03-30 AT AT98913310T patent/ATE259384T1/de not_active IP Right Cessation
- 1998-03-30 DE DE69821605T patent/DE69821605T2/de not_active Revoked
- 1998-03-30 CN CN98805035A patent/CN1255928A/zh active Pending
- 1998-03-30 AU AU67893/98A patent/AU738227B2/en not_active Ceased
- 1998-03-30 CA CA002284789A patent/CA2284789A1/en not_active Abandoned
- 1998-03-30 BR BR9807921-2A patent/BR9807921A/pt unknown
- 1998-03-30 TR TR1999/02755T patent/TR199902755T2/xx unknown
- 1998-04-03 AR ARP980101529A patent/AR012324A1/es not_active Application Discontinuation
- 1998-04-03 MY MYPI98001503A patent/MY118708A/en unknown
- 1998-04-03 TW TW87105083A patent/TW572915B/zh not_active IP Right Cessation
- 1998-04-03 ZA ZA9802860A patent/ZA982860B/xx unknown
- 1998-04-04 EG EG37998A patent/EG22079A/xx active
Also Published As
Publication number | Publication date |
---|---|
EP0971962A1 (en) | 2000-01-19 |
DE69821605D1 (de) | 2004-03-18 |
BR9807921A (pt) | 2000-02-22 |
MY118708A (en) | 2005-01-31 |
WO1998045337A1 (en) | 1998-10-15 |
JP2001524144A (ja) | 2001-11-27 |
HUP0001378A3 (en) | 2003-01-28 |
ID22626A (id) | 1999-12-02 |
CA2284789A1 (en) | 1998-10-15 |
EG22079A (en) | 2002-07-31 |
TR199902755T2 (xx) | 2000-04-21 |
EP0971962B1 (en) | 2004-02-11 |
CN1255928A (zh) | 2000-06-07 |
KR100538590B1 (ko) | 2005-12-22 |
AU738227B2 (en) | 2001-09-13 |
SK135199A3 (en) | 2000-05-16 |
AU6789398A (en) | 1998-10-30 |
KR20010005942A (ko) | 2001-01-15 |
ATE259384T1 (de) | 2004-02-15 |
DE69821605T2 (de) | 2004-12-16 |
ZA982860B (en) | 1999-10-04 |
NZ337968A (en) | 2001-10-26 |
PL336078A1 (en) | 2000-06-05 |
HUP0001378A1 (en) | 2000-07-28 |
US6479599B1 (en) | 2002-11-12 |
TW572915B (en) | 2004-01-21 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FA | Abandonment or withdrawal |