AR009034A1 - Complejos de metales que contienen ciclopentadienilo sustituido por heteroatomos en la posicion 2, sistemas catalizadores que incluyen dichoscomplejos; proceso para polimerizar olefinas aplicando dichos sistemas; productos de polimerizacion de olefinas obtenidas con dicho proceso; los - Google Patents
Complejos de metales que contienen ciclopentadienilo sustituido por heteroatomos en la posicion 2, sistemas catalizadores que incluyen dichoscomplejos; proceso para polimerizar olefinas aplicando dichos sistemas; productos de polimerizacion de olefinas obtenidas con dicho proceso; losInfo
- Publication number
- AR009034A1 AR009034A1 ARP970103616A ARP970103616A AR009034A1 AR 009034 A1 AR009034 A1 AR 009034A1 AR P970103616 A ARP970103616 A AR P970103616A AR P970103616 A ARP970103616 A AR P970103616A AR 009034 A1 AR009034 A1 AR 009034A1
- Authority
- AR
- Argentina
- Prior art keywords
- olefins
- complexes
- systems
- heteroatomes
- applying
- Prior art date
Links
- 150000001336 alkenes Chemical class 0.000 title abstract 4
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 title abstract 3
- 238000006116 polymerization reaction Methods 0.000 title abstract 3
- 239000002184 metal Substances 0.000 title abstract 2
- 238000000034 method Methods 0.000 title 2
- HPYIUKIBUJFXII-UHFFFAOYSA-N Cyclopentadienyl radical Chemical group [CH]1C=CC=C1 HPYIUKIBUJFXII-UHFFFAOYSA-N 0.000 title 1
- 239000003054 catalyst Substances 0.000 title 1
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 abstract 2
- 239000003446 ligand Substances 0.000 abstract 2
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 125000005842 heteroatom Chemical group 0.000 abstract 1
- 229920006158 high molecular weight polymer Polymers 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 229920000098 polyolefin Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/10—Compounds having one or more C—Si linkages containing nitrogen having a Si-N linkage
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US2376896P | 1996-08-08 | 1996-08-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR009034A1 true AR009034A1 (es) | 2000-03-08 |
Family
ID=21817090
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP970103616A AR009034A1 (es) | 1996-08-08 | 1997-08-08 | Complejos de metales que contienen ciclopentadienilo sustituido por heteroatomos en la posicion 2, sistemas catalizadores que incluyen dichoscomplejos; proceso para polimerizar olefinas aplicando dichos sistemas; productos de polimerizacion de olefinas obtenidas con dicho proceso; los |
Country Status (21)
| Country | Link |
|---|---|
| EP (1) | EP1021454A1 (hu) |
| JP (1) | JP2000516608A (hu) |
| KR (1) | KR20000029853A (hu) |
| CN (1) | CN1231668A (hu) |
| AR (1) | AR009034A1 (hu) |
| AU (1) | AU716659B2 (hu) |
| BR (1) | BR9711115A (hu) |
| CA (1) | CA2262377A1 (hu) |
| CO (1) | CO4870709A1 (hu) |
| CZ (1) | CZ42499A3 (hu) |
| HU (1) | HUP9904148A3 (hu) |
| ID (1) | ID18005A (hu) |
| NO (1) | NO990546L (hu) |
| NZ (1) | NZ333877A (hu) |
| PL (1) | PL331526A1 (hu) |
| RU (1) | RU2196776C2 (hu) |
| SA (1) | SA97180735B1 (hu) |
| SK (1) | SK15299A3 (hu) |
| TR (1) | TR199900589T2 (hu) |
| WO (1) | WO1998006728A1 (hu) |
| ZA (2) | ZA976999B (hu) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FI971565A (fi) * | 1997-04-14 | 1998-10-15 | Borealis As | Olefiinien polymerointiin tarkoitettujen katalysaattorisysteemien substituoituja metalloseeniyhdisteitä, niiden välituotteet ja valmistusmenetelmä |
| DE19809159A1 (de) * | 1998-03-04 | 1999-09-09 | Bayer Ag | Metallorganische Verbindungen |
| US6326493B1 (en) * | 1999-01-25 | 2001-12-04 | Chisso Corporation | Metallocene compounds, processes for the preparation thereof, catalyst components for olefin polymerization, and processes for the production of olefin polymers |
| AU3902300A (en) | 1999-04-29 | 2000-11-17 | Dow Chemical Company, The | Bis(n,n-dihydrocarbylamino)- substituted cyclopentadienes and metal complexes thereof |
| WO2000069870A1 (en) | 1999-05-13 | 2000-11-23 | The Dow Chemical Company | Metal complexes containing bridging heteroatom for olefin-polymerization-process |
| US6555634B1 (en) | 1999-05-13 | 2003-04-29 | The Dow Chemical Company | Di- and tri-heteroatom substituted indenyl metal complexes |
| WO2000075146A1 (en) | 1999-06-04 | 2000-12-14 | The Dow Chemical Company | Boron-substituted cyclopentadienes and metal complexes thereof |
| KR100714508B1 (ko) * | 1999-12-10 | 2007-05-07 | 다우 글로벌 테크놀로지스 인크. | 치환된 4족 금속 착체, 촉매 및 올레핀 중합 방법 |
| US6825295B2 (en) | 1999-12-10 | 2004-11-30 | Dow Global Technologies Inc. | Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process |
| EP1253158A1 (en) * | 1999-12-10 | 2002-10-30 | Dow Global Technologies Inc. | Substituted group 4 metal complexes, catalysts and olefin polymerization process |
| KR100675053B1 (ko) | 2000-01-18 | 2007-01-26 | 바셀 테크놀로지 캄파니 비이브이 | 실질적으로 무정형인 프로필렌 기재 중합체의 제조 방법 |
| AU2001226937A1 (en) * | 2000-01-19 | 2001-07-31 | Borealis Technology Oy | Metallocene catalysts comprising monocyclic siloxy substituted cyclopentadienyl group(s) for the polymerisation of olefins |
| GB0001232D0 (en) * | 2000-01-19 | 2000-03-08 | Borealis Polymers Oy | Polymerisation catalysts |
| JP4062929B2 (ja) | 2002-02-08 | 2008-03-19 | 住友化学株式会社 | 遷移金属錯体、配位子、オレフィン重合用触媒およびオレフィン重合体の製造方法 |
| KR20100101024A (ko) * | 2002-03-14 | 2010-09-15 | 다우 글로벌 테크놀로지스 인크. | 치환된 인데닐 금속 착물 |
| US6927264B2 (en) | 2003-05-28 | 2005-08-09 | Dow Global Technologies Inc. | Metal complexes and polymerization process using same |
| MY158186A (en) | 2009-07-28 | 2016-09-15 | Univation Tech Llc | Polymerization process using a supported constrained geometry catalyst |
| CN103249755A (zh) * | 2010-09-15 | 2013-08-14 | 株式会社日本触媒 | 可作为热潜在性聚合引发剂使用的组合物 |
| CN102101897B (zh) * | 2010-12-24 | 2013-02-06 | 上海化工研究院 | 侧链含杂环的茂金属催化剂及其在烯烃聚合中的应用 |
| US9382361B2 (en) | 2014-03-21 | 2016-07-05 | Exxonmobil Chemical Patents Inc. | Process to produce ethylene propylene copolymers |
| PL3245258T3 (pl) | 2015-01-06 | 2020-01-31 | Scg Chemicals Co., Ltd. | MIKROSFERY SiO₂ Z WARSTWOWYM PODWÓJNYM WODOROTLENKIEM I SPOSOBY ICH OTRZYMYWANIA |
| KR102010630B1 (ko) * | 2016-01-20 | 2019-08-13 | 한화토탈 주식회사 | 올레핀 중합촉매 및 이를 이용한 올레핀 중합방법 |
| GB201608384D0 (en) | 2016-05-12 | 2016-06-29 | Scg Chemicals Co Ltd | Unsymmetrical metallocene catalysts and uses thereof |
| CN110612313A (zh) * | 2017-03-23 | 2019-12-24 | 埃克森美孚化学专利公司 | 催化剂体系及其制备和使用方法 |
| KR102643986B1 (ko) | 2017-09-29 | 2024-03-07 | 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 | 신규한 인덴계 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법 |
| KR20200105409A (ko) | 2019-02-28 | 2020-09-07 | 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 | 신규한 테트라아릴보레이트 화합물, 이를 포함하는 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법 |
| WO2020174346A1 (ko) | 2019-02-28 | 2020-09-03 | 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 | 신규한 테트라아릴보레이트 화합물, 이를 포함하는 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법 |
| EP3865522A4 (en) | 2019-09-27 | 2022-05-18 | LG Chem, Ltd. | POLYETHYLENE AND RELATED CHLORINATED POLYETHYLENE |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5096867A (en) * | 1990-06-04 | 1992-03-17 | Exxon Chemical Patents Inc. | Monocyclopentadienyl transition metal olefin polymerization catalysts |
| NZ235032A (en) * | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
| DE59310131D1 (de) * | 1992-08-03 | 2001-01-25 | Targor Gmbh | Verfahren zur Herstellung eines Olefinpolymers unter Verwendung spezieller Metallocene |
| DE4406963A1 (de) * | 1994-03-03 | 1995-09-07 | Basf Ag | Metallocenkomplexe mit heterofunktionellen Gruppen am Cyclopentadienylsystem |
| DE4406964A1 (de) * | 1994-03-03 | 1995-09-07 | Basf Ag | Geträgerte Metalloxenkomplexe mit heterofunktionellen Gruppen am Cyclopentadienylsystem als Katalysatorsysteme |
-
1997
- 1997-07-28 CZ CZ99424A patent/CZ42499A3/cs unknown
- 1997-07-28 NZ NZ333877A patent/NZ333877A/xx unknown
- 1997-07-28 AU AU39647/97A patent/AU716659B2/en not_active Ceased
- 1997-07-28 EP EP97937033A patent/EP1021454A1/en not_active Withdrawn
- 1997-07-28 HU HU9904148A patent/HUP9904148A3/hu unknown
- 1997-07-28 BR BR9711115A patent/BR9711115A/pt not_active IP Right Cessation
- 1997-07-28 CN CN97198208A patent/CN1231668A/zh active Pending
- 1997-07-28 WO PCT/US1997/013171 patent/WO1998006728A1/en not_active Application Discontinuation
- 1997-07-28 RU RU99104650/04A patent/RU2196776C2/ru not_active IP Right Cessation
- 1997-07-28 KR KR1019997001015A patent/KR20000029853A/ko not_active Application Discontinuation
- 1997-07-28 PL PL97331526A patent/PL331526A1/xx unknown
- 1997-07-28 TR TR1999/00589T patent/TR199900589T2/xx unknown
- 1997-07-28 SK SK152-99A patent/SK15299A3/sk not_active Application Discontinuation
- 1997-07-28 CA CA002262377A patent/CA2262377A1/en not_active Abandoned
- 1997-07-28 JP JP10509760A patent/JP2000516608A/ja active Pending
- 1997-08-06 ZA ZA976999A patent/ZA976999B/xx unknown
- 1997-08-06 ZA ZA976998A patent/ZA976998B/xx unknown
- 1997-08-07 ID IDP972749A patent/ID18005A/id unknown
- 1997-08-08 AR ARP970103616A patent/AR009034A1/es not_active Application Discontinuation
- 1997-08-08 CO CO97045592A patent/CO4870709A1/es unknown
- 1997-12-24 SA SA97180735A patent/SA97180735B1/ar unknown
-
1999
- 1999-02-05 NO NO990546A patent/NO990546L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| ZA976998B (en) | 1999-02-08 |
| HUP9904148A2 (hu) | 2000-03-28 |
| ZA976999B (en) | 1999-02-08 |
| TR199900589T2 (xx) | 1999-07-21 |
| BR9711115A (pt) | 1999-08-17 |
| EP1021454A1 (en) | 2000-07-26 |
| SK15299A3 (en) | 2000-03-13 |
| NO990546L (no) | 1999-03-29 |
| AU3964797A (en) | 1998-03-06 |
| AU716659B2 (en) | 2000-03-02 |
| PL331526A1 (en) | 1999-07-19 |
| SA97180735B1 (ar) | 2006-10-08 |
| RU2196776C2 (ru) | 2003-01-20 |
| NZ333877A (en) | 2000-08-25 |
| NO990546D0 (no) | 1999-02-05 |
| WO1998006728A1 (en) | 1998-02-19 |
| CZ42499A3 (cs) | 1999-07-14 |
| HUP9904148A3 (en) | 2003-03-28 |
| CN1231668A (zh) | 1999-10-13 |
| CO4870709A1 (es) | 1999-12-27 |
| JP2000516608A (ja) | 2000-12-12 |
| KR20000029853A (ko) | 2000-05-25 |
| ID18005A (id) | 1998-02-19 |
| CA2262377A1 (en) | 1998-02-19 |
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