BR0213665A - Componente cocatalìtico sólido para polimerização de olefinas e sistema catalìtico obtido a partir dele - Google Patents

Componente cocatalìtico sólido para polimerização de olefinas e sistema catalìtico obtido a partir dele

Info

Publication number
BR0213665A
BR0213665A BR0213665-1A BR0213665A BR0213665A BR 0213665 A BR0213665 A BR 0213665A BR 0213665 A BR0213665 A BR 0213665A BR 0213665 A BR0213665 A BR 0213665A
Authority
BR
Brazil
Prior art keywords
olefin polymerization
group
solid
catalytic system
system obtained
Prior art date
Application number
BR0213665-1A
Other languages
English (en)
Inventor
Satoru Ishigaki
Shinji Hinokuma
Original Assignee
Sunallomer Ltd
Basell Polyolefine Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sunallomer Ltd, Basell Polyolefine Gmbh filed Critical Sunallomer Ltd
Publication of BR0213665A publication Critical patent/BR0213665A/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/645Component covered by group C08F4/64 with a metal or compound covered by group C08F4/44, not provided for in a single group of groups C08F4/642 - C08F4/643
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

"COMPONENTE COCATALìTICO SóLIDO PARA POLIMERIZAçãO DE OLEFINAS E SISTEMA CATALìTICO OBTIDO A PARTIR DELE". Refere-se o presente invento a um cocatalisador sólido para a polimerização de olefinas em que um composto contendo íons compreendendo um cátion expresso por [R~ 4~M]^ +^, em que os grupos R são cada qual individualmente escolhidos dentre o grupo que consiste de um átomo de hidrogênio e um grupo hidrocarboneto substituído ou não tendo de 1 a 30 átomos de carbono com a exceção de um grupo arila; dois ou mais grupos R podem formar um anel unindo-se uns aos outros; pelo menos um dos grupos R é um grupo hidrocarboneto tendo de 1 a 30 átomos de carbono com a exceção de um grupo arila; e M representa nitrogênio ou enxofre; e um ânion não coordenante expresso por [A]^ -^; dito composto contendo íons sendo quimicamente ligado a um suporte particulado fino.
BR0213665-1A 2001-10-19 2002-10-17 Componente cocatalìtico sólido para polimerização de olefinas e sistema catalìtico obtido a partir dele BR0213665A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2001322615A JP2003128720A (ja) 2001-10-19 2001-10-19 オレフィン重合用固体助触媒成分、オレフィン重合用触媒およびイオン含有化合物
PCT/EP2002/011729 WO2003035708A1 (en) 2001-10-19 2002-10-17 Solid cocatalyst component for olefin polymerization and catalyst system thereof

Publications (1)

Publication Number Publication Date
BR0213665A true BR0213665A (pt) 2004-10-26

Family

ID=19139635

Family Applications (1)

Application Number Title Priority Date Filing Date
BR0213665-1A BR0213665A (pt) 2001-10-19 2002-10-17 Componente cocatalìtico sólido para polimerização de olefinas e sistema catalìtico obtido a partir dele

Country Status (9)

Country Link
US (1) US7247686B2 (pt)
EP (1) EP1442067B1 (pt)
JP (1) JP2003128720A (pt)
KR (1) KR20040045872A (pt)
CN (1) CN1612900A (pt)
AT (1) ATE360039T1 (pt)
BR (1) BR0213665A (pt)
DE (1) DE60219660T2 (pt)
WO (1) WO2003035708A1 (pt)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005008719A (ja) * 2003-06-18 2005-01-13 Mitsui Chemicals Inc 保存安定性に優れたオレフィン重合用の触媒成分
ATE504349T1 (de) * 2004-06-16 2011-04-15 Dow Global Technologies Inc Verfahren zur auswahl von polymerisationsmodifikatoren
US7829147B2 (en) 2005-08-18 2010-11-09 Corning Incorporated Hermetically sealing a device without a heat treating step and the resulting hermetically sealed device
US20070040501A1 (en) 2005-08-18 2007-02-22 Aitken Bruce G Method for inhibiting oxygen and moisture degradation of a device and the resulting device
US7722929B2 (en) 2005-08-18 2010-05-25 Corning Incorporated Sealing technique for decreasing the time it takes to hermetically seal a device and the resulting hermetically sealed device
EP2050755A1 (en) 2007-10-19 2009-04-22 Total Petrochemicals Research Feluy Supported ionic liquids or activating supports
EP2070953A1 (en) 2007-12-11 2009-06-17 Total Petrochemicals Research Feluy Activating supports based on phosphonium complexes
US20090240640A1 (en) * 2008-03-21 2009-09-24 David Alan Blain Apparatus and method for predicting engine test performance from bench test data
US7799879B2 (en) 2008-08-01 2010-09-21 Exxonmobil Chemical Patents Inc. Catalyst system and process for olefin polymerization
WO2010014344A2 (en) 2008-08-01 2010-02-04 Exxonmobil Chemical Patents Inc. Catalyst system and process for olefin polymerization
US8580902B2 (en) 2008-08-01 2013-11-12 Exxonmobil Chemical Patents Inc. Catalyst system, process for olefin polymerization, and polymer compositions produced therefrom
EP2760895A4 (en) 2011-09-30 2015-07-22 Exxonmobil Chem Patents Inc DYNAMIC MODULATION OF METALLOCENE CATALYSTS
US9266910B2 (en) 2013-10-29 2016-02-23 Exxonmobil Chemical Patents Inc. Asymmetric polypropylene catalysts
WO2023150480A1 (en) 2022-02-07 2023-08-10 Exxonmobil Chemical Patents Inc. C1 symmetric 5-ome-6-alkyl substituted metallocenes

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5621126A (en) 1987-01-30 1997-04-15 Exxon Chemical Patents Inc. Monocyclopentadienyl metal compounds for ethylene-α-olefin-copolymer production catalysts
JP2939354B2 (ja) 1991-03-26 1999-08-25 出光興産株式会社 スチレン系重合体の製造方法及びその触媒
DE69222317T2 (de) 1991-11-25 1998-02-12 Exxon Chemical Patents, Inc., Baytown, Tex. Polyionische, uebergangsmetall enthaltende katalysatorzusammensetzung
ES2093166T3 (es) 1991-11-30 1996-12-16 Hoechst Ag Metalocenos con derivados de indenilo condensados con benzo como ligandos, procedimiento para su preparacion y su utilizacion como catalizadores.
TW294669B (pt) 1992-06-27 1997-01-01 Hoechst Ag
JPH06345809A (ja) 1993-06-07 1994-12-20 Mitsui Petrochem Ind Ltd 新規な遷移金属化合物および該遷移金属化合物からなるオレフィン重合用触媒成分、該オレフィン重合用触媒成分を含むオレフィン重合用触媒ならびにオレフィンの重合方法
US5939347A (en) * 1995-01-25 1999-08-17 W.R. Grace & Co. -Conn. Supported catalytic activator
JPH11503113A (ja) * 1995-03-10 1999-03-23 ザ ダウ ケミカル カンパニー 支持された触媒成分、支持された触媒、製造法、重合法、錯体化合物、及びその製造法
DE69617371T2 (de) * 1995-06-08 2002-08-08 Showa Denko K.K., Tokio/Tokyo Ionische Verbindungen und Katalysator für die Olefinpolymerisation, der die Verbindungen verwendet
DE19544828A1 (de) 1995-12-01 1997-06-05 Hoechst Ag Hochmolekulare Copolymere
US6340652B1 (en) 1996-12-09 2002-01-22 Mitsubishi Chemical Corporation Catalysts for polymerization of α-olefins, process for producing α-olefin polymers, novel transition metal compounds and catalyst components for polymerization of α-olefin
JP3815876B2 (ja) 1996-12-09 2006-08-30 三菱化学株式会社 α−オレフィン重合用触媒およびα−オレフィン重合体の製造方法
JPH10279588A (ja) 1997-04-01 1998-10-20 Mitsubishi Chem Corp 新規な遷移金属化合物、α−オレフィン重合用触媒成分およびα−オレフィン重合体の製造方法
KR20030019447A (ko) 2000-06-23 2003-03-06 엑손모빌 케미칼 패턴츠 인코포레이티드 올레핀 중합용 실록시 치환된 조촉매 활성화제

Also Published As

Publication number Publication date
US20050009689A1 (en) 2005-01-13
EP1442067B1 (en) 2007-04-18
JP2003128720A (ja) 2003-05-08
CN1612900A (zh) 2005-05-04
KR20040045872A (ko) 2004-06-02
EP1442067A1 (en) 2004-08-04
DE60219660T2 (de) 2008-01-10
WO2003035708A1 (en) 2003-05-01
US7247686B2 (en) 2007-07-24
DE60219660D1 (de) 2007-05-31
ATE360039T1 (de) 2007-05-15

Similar Documents

Publication Publication Date Title
BR0213665A (pt) Componente cocatalìtico sólido para polimerização de olefinas e sistema catalìtico obtido a partir dele
PT955304E (pt) Complexo de metaloceno com pontes para a (co) polimerizacao de olefinas
BR0016197A (pt) Sistema catalisador múltiplo
BR9912124A (pt) Co-catalisadores de ácido de lewis à base de alumìnio para a polimerização de olefina
NO942369L (no) Organo-aluminoksy-produkt og anvendelse derav
EP1538167A4 (en) A CATALYST FOR THE POLYMERIZATION OR COPOLYMERIZATION OF α-OLEFINES, CATALYST COMPONENTS THEREOF AND METHOD FOR POLYMERIZING α-OLEFINS WITH THE CATALYSTS
ES2139094T3 (es) Componentes cataliticos puenteados de amido-siladiilo, metodo de fabricacion y uso.
AU2003293320A1 (en) Catalyst systems for ethylene oligomerisation to linear alpha olefins
ATE454214T1 (de) Katalytische oligomerisierung von olefinischen monomeren
ATE516079T1 (de) Katalytische trimerisierung von olefinischen monomeren
BR9912690A (pt) Processo de polimerização de uma ou mais olefinas
WO2001083571A3 (en) Catalysts containing n-pyrrolyl substituted nitrogen donors
AR009034A1 (es) Complejos de metales que contienen ciclopentadienilo sustituido por heteroatomos en la posicion 2, sistemas catalizadores que incluyen dichoscomplejos; proceso para polimerizar olefinas aplicando dichos sistemas; productos de polimerizacion de olefinas obtenidas con dicho proceso; los
TR200003273A2 (tr) Olefinler'den katalitik olarak aldehit imalatına yönelik usul
BR0007150A (pt) Catalisadores de metal de transição e produção de alfa-olefinas e polìmeros de compostos de vinila
WO2003014166A1 (en) Process for producing polymer
ATE480547T1 (de) Übergangsmetallkomplexe, liganden, katalysatoren für die polymerisation von olefinen und verfahren zur herstellung von olefinpolymeren
BR0009363A (pt) Processo para a polimerização de olefinas, sistemacatalisador, e, polìmero de olefina
EA200101024A1 (ru) Каталитические композиции на подложках для полимеризации олефинов с задержкой активности, способ их приготовления и их применение
MXPA02007950A (es) Catalizadores para la polimerizacion de olefina.
ATE428499T1 (de) Oligomerisierung von ethylen mit aluminiumphosphat-geträgerten gruppe 6 metallamidkatalysatoren
ATE364047T1 (de) Monocyclopentadienylkomplexe
AU2001282297A1 (en) Catalysts
ATE256692T1 (de) Verfahren zur polymerisation von olefinen in anwesenheit von indenylverbindungen.
DE60317903D1 (de) Katalysatorsystem für die polymerisation von olefinen

Legal Events

Date Code Title Description
B11A Dismissal acc. art.33 of ipl - examination not requested within 36 months of filing
B11Y Definitive dismissal - extension of time limit for request of examination expired [chapter 11.1.1 patent gazette]