BR0213665A - Componente cocatalìtico sólido para polimerização de olefinas e sistema catalìtico obtido a partir dele - Google Patents
Componente cocatalìtico sólido para polimerização de olefinas e sistema catalìtico obtido a partir deleInfo
- Publication number
- BR0213665A BR0213665A BR0213665-1A BR0213665A BR0213665A BR 0213665 A BR0213665 A BR 0213665A BR 0213665 A BR0213665 A BR 0213665A BR 0213665 A BR0213665 A BR 0213665A
- Authority
- BR
- Brazil
- Prior art keywords
- olefin polymerization
- group
- solid
- catalytic system
- system obtained
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/645—Component covered by group C08F4/64 with a metal or compound covered by group C08F4/44, not provided for in a single group of groups C08F4/642 - C08F4/643
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
"COMPONENTE COCATALìTICO SóLIDO PARA POLIMERIZAçãO DE OLEFINAS E SISTEMA CATALìTICO OBTIDO A PARTIR DELE". Refere-se o presente invento a um cocatalisador sólido para a polimerização de olefinas em que um composto contendo íons compreendendo um cátion expresso por [R~ 4~M]^ +^, em que os grupos R são cada qual individualmente escolhidos dentre o grupo que consiste de um átomo de hidrogênio e um grupo hidrocarboneto substituído ou não tendo de 1 a 30 átomos de carbono com a exceção de um grupo arila; dois ou mais grupos R podem formar um anel unindo-se uns aos outros; pelo menos um dos grupos R é um grupo hidrocarboneto tendo de 1 a 30 átomos de carbono com a exceção de um grupo arila; e M representa nitrogênio ou enxofre; e um ânion não coordenante expresso por [A]^ -^; dito composto contendo íons sendo quimicamente ligado a um suporte particulado fino.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2001322615A JP2003128720A (ja) | 2001-10-19 | 2001-10-19 | オレフィン重合用固体助触媒成分、オレフィン重合用触媒およびイオン含有化合物 |
PCT/EP2002/011729 WO2003035708A1 (en) | 2001-10-19 | 2002-10-17 | Solid cocatalyst component for olefin polymerization and catalyst system thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
BR0213665A true BR0213665A (pt) | 2004-10-26 |
Family
ID=19139635
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR0213665-1A BR0213665A (pt) | 2001-10-19 | 2002-10-17 | Componente cocatalìtico sólido para polimerização de olefinas e sistema catalìtico obtido a partir dele |
Country Status (9)
Country | Link |
---|---|
US (1) | US7247686B2 (pt) |
EP (1) | EP1442067B1 (pt) |
JP (1) | JP2003128720A (pt) |
KR (1) | KR20040045872A (pt) |
CN (1) | CN1612900A (pt) |
AT (1) | ATE360039T1 (pt) |
BR (1) | BR0213665A (pt) |
DE (1) | DE60219660T2 (pt) |
WO (1) | WO2003035708A1 (pt) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005008719A (ja) * | 2003-06-18 | 2005-01-13 | Mitsui Chemicals Inc | 保存安定性に優れたオレフィン重合用の触媒成分 |
ATE504349T1 (de) * | 2004-06-16 | 2011-04-15 | Dow Global Technologies Inc | Verfahren zur auswahl von polymerisationsmodifikatoren |
US7829147B2 (en) | 2005-08-18 | 2010-11-09 | Corning Incorporated | Hermetically sealing a device without a heat treating step and the resulting hermetically sealed device |
US20070040501A1 (en) | 2005-08-18 | 2007-02-22 | Aitken Bruce G | Method for inhibiting oxygen and moisture degradation of a device and the resulting device |
US7722929B2 (en) | 2005-08-18 | 2010-05-25 | Corning Incorporated | Sealing technique for decreasing the time it takes to hermetically seal a device and the resulting hermetically sealed device |
EP2050755A1 (en) | 2007-10-19 | 2009-04-22 | Total Petrochemicals Research Feluy | Supported ionic liquids or activating supports |
EP2070953A1 (en) | 2007-12-11 | 2009-06-17 | Total Petrochemicals Research Feluy | Activating supports based on phosphonium complexes |
US20090240640A1 (en) * | 2008-03-21 | 2009-09-24 | David Alan Blain | Apparatus and method for predicting engine test performance from bench test data |
US7799879B2 (en) | 2008-08-01 | 2010-09-21 | Exxonmobil Chemical Patents Inc. | Catalyst system and process for olefin polymerization |
WO2010014344A2 (en) | 2008-08-01 | 2010-02-04 | Exxonmobil Chemical Patents Inc. | Catalyst system and process for olefin polymerization |
US8580902B2 (en) | 2008-08-01 | 2013-11-12 | Exxonmobil Chemical Patents Inc. | Catalyst system, process for olefin polymerization, and polymer compositions produced therefrom |
EP2760895A4 (en) | 2011-09-30 | 2015-07-22 | Exxonmobil Chem Patents Inc | DYNAMIC MODULATION OF METALLOCENE CATALYSTS |
US9266910B2 (en) | 2013-10-29 | 2016-02-23 | Exxonmobil Chemical Patents Inc. | Asymmetric polypropylene catalysts |
WO2023150480A1 (en) | 2022-02-07 | 2023-08-10 | Exxonmobil Chemical Patents Inc. | C1 symmetric 5-ome-6-alkyl substituted metallocenes |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5621126A (en) | 1987-01-30 | 1997-04-15 | Exxon Chemical Patents Inc. | Monocyclopentadienyl metal compounds for ethylene-α-olefin-copolymer production catalysts |
JP2939354B2 (ja) | 1991-03-26 | 1999-08-25 | 出光興産株式会社 | スチレン系重合体の製造方法及びその触媒 |
DE69222317T2 (de) | 1991-11-25 | 1998-02-12 | Exxon Chemical Patents, Inc., Baytown, Tex. | Polyionische, uebergangsmetall enthaltende katalysatorzusammensetzung |
ES2093166T3 (es) | 1991-11-30 | 1996-12-16 | Hoechst Ag | Metalocenos con derivados de indenilo condensados con benzo como ligandos, procedimiento para su preparacion y su utilizacion como catalizadores. |
TW294669B (pt) | 1992-06-27 | 1997-01-01 | Hoechst Ag | |
JPH06345809A (ja) | 1993-06-07 | 1994-12-20 | Mitsui Petrochem Ind Ltd | 新規な遷移金属化合物および該遷移金属化合物からなるオレフィン重合用触媒成分、該オレフィン重合用触媒成分を含むオレフィン重合用触媒ならびにオレフィンの重合方法 |
US5939347A (en) * | 1995-01-25 | 1999-08-17 | W.R. Grace & Co. -Conn. | Supported catalytic activator |
JPH11503113A (ja) * | 1995-03-10 | 1999-03-23 | ザ ダウ ケミカル カンパニー | 支持された触媒成分、支持された触媒、製造法、重合法、錯体化合物、及びその製造法 |
DE69617371T2 (de) * | 1995-06-08 | 2002-08-08 | Showa Denko K.K., Tokio/Tokyo | Ionische Verbindungen und Katalysator für die Olefinpolymerisation, der die Verbindungen verwendet |
DE19544828A1 (de) | 1995-12-01 | 1997-06-05 | Hoechst Ag | Hochmolekulare Copolymere |
US6340652B1 (en) | 1996-12-09 | 2002-01-22 | Mitsubishi Chemical Corporation | Catalysts for polymerization of α-olefins, process for producing α-olefin polymers, novel transition metal compounds and catalyst components for polymerization of α-olefin |
JP3815876B2 (ja) | 1996-12-09 | 2006-08-30 | 三菱化学株式会社 | α−オレフィン重合用触媒およびα−オレフィン重合体の製造方法 |
JPH10279588A (ja) | 1997-04-01 | 1998-10-20 | Mitsubishi Chem Corp | 新規な遷移金属化合物、α−オレフィン重合用触媒成分およびα−オレフィン重合体の製造方法 |
KR20030019447A (ko) | 2000-06-23 | 2003-03-06 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 올레핀 중합용 실록시 치환된 조촉매 활성화제 |
-
2001
- 2001-10-19 JP JP2001322615A patent/JP2003128720A/ja active Pending
-
2002
- 2002-10-17 EP EP02782961A patent/EP1442067B1/en not_active Expired - Lifetime
- 2002-10-17 WO PCT/EP2002/011729 patent/WO2003035708A1/en active IP Right Grant
- 2002-10-17 CN CNA028206975A patent/CN1612900A/zh active Pending
- 2002-10-17 KR KR10-2004-7005762A patent/KR20040045872A/ko not_active Application Discontinuation
- 2002-10-17 US US10/493,089 patent/US7247686B2/en not_active Expired - Fee Related
- 2002-10-17 DE DE60219660T patent/DE60219660T2/de not_active Expired - Fee Related
- 2002-10-17 BR BR0213665-1A patent/BR0213665A/pt not_active Application Discontinuation
- 2002-10-17 AT AT02782961T patent/ATE360039T1/de not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
US20050009689A1 (en) | 2005-01-13 |
EP1442067B1 (en) | 2007-04-18 |
JP2003128720A (ja) | 2003-05-08 |
CN1612900A (zh) | 2005-05-04 |
KR20040045872A (ko) | 2004-06-02 |
EP1442067A1 (en) | 2004-08-04 |
DE60219660T2 (de) | 2008-01-10 |
WO2003035708A1 (en) | 2003-05-01 |
US7247686B2 (en) | 2007-07-24 |
DE60219660D1 (de) | 2007-05-31 |
ATE360039T1 (de) | 2007-05-15 |
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Legal Events
Date | Code | Title | Description |
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B11A | Dismissal acc. art.33 of ipl - examination not requested within 36 months of filing | ||
B11Y | Definitive dismissal - extension of time limit for request of examination expired [chapter 11.1.1 patent gazette] |