AR006290A1 - Sistema catalitico y metodo de oxidacion de materiales - Google Patents
Sistema catalitico y metodo de oxidacion de materialesInfo
- Publication number
- AR006290A1 AR006290A1 ARP980101023A ARP980101023A AR006290A1 AR 006290 A1 AR006290 A1 AR 006290A1 AR P980101023 A ARP980101023 A AR P980101023A AR P980101023 A ARP980101023 A AR P980101023A AR 006290 A1 AR006290 A1 AR 006290A1
- Authority
- AR
- Argentina
- Prior art keywords
- oxidation
- fabrics
- metal catalysts
- oxidizable compounds
- materials
- Prior art date
Links
- 238000007254 oxidation reaction Methods 0.000 title abstract 5
- 230000003647 oxidation Effects 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 3
- 230000003197 catalytic effect Effects 0.000 title abstract 2
- 239000000463 material Substances 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 2
- 239000004744 fabric Substances 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 238000004061 bleaching Methods 0.000 abstract 1
- 239000000975 dye Substances 0.000 abstract 1
- -1 enines Chemical class 0.000 abstract 1
- 238000006735 epoxidation reaction Methods 0.000 abstract 1
- 125000000524 functional group Chemical group 0.000 abstract 1
- 125000005842 heteroatom Chemical group 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 230000005764 inhibitory process Effects 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 239000011572 manganese Substances 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 150000003457 sulfones Chemical class 0.000 abstract 1
- 150000003568 thioethers Chemical class 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
- B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
- B01J31/182—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine comprising aliphatic or saturated rings
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F13/00—Compounds containing elements of Groups 7 or 17 of the Periodic Table
- C07F13/005—Compounds without a metal-carbon linkage
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
- B01J2231/72—Epoxidation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
- B01J2531/0258—Flexible ligands, e.g. mainly sp3-carbon framework as exemplified by the "tedicyp" ligand, i.e. cis-cis-cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
- B01J2531/16—Copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/50—Complexes comprising metals of Group V (VA or VB) as the central metal
- B01J2531/56—Vanadium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
- B01J2531/62—Chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
- B01J2531/64—Molybdenum
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
- B01J2531/66—Tungsten
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
- B01J2531/72—Manganese
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/821—Ruthenium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/824—Palladium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/842—Iron
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/845—Cobalt
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/847—Nickel
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Epoxy Compounds (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Detergent Compositions (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Sistemas catalíticos y métodos para oxidar materiales en presencia de catalizadores de metal (preferiblemente catalizadores que contienenmanganeso) compuestos con ligandos rígidos macropolicíclicos seleccionados, preferiblemente de puentescruzados. Se incluye la utilización de estoscatalizadores de metal en tales procesos como: las reacciones de oxidación sintética orgánica como la oxidación de grupos funcionales orgánicos,hidrocarburos y heteroátomos, incluyendo la epoxidacióne nanciómera de alquenos, eninas, sulfuros a sulfonas, etc. La oxidación de compuestosoxidables (por ejemplo las manchas) en superficies tales como los tejidos, la vajilla, la dentadura, etc.; la oxidación de compuestos oxidables ensolución ,la inhibición de la transferencia de tinturas durante el lavado de los tejidos y, además, en el blanqueo de productos de pulpa y papel.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US4062997P | 1997-03-07 | 1997-03-07 |
Publications (1)
Publication Number | Publication Date |
---|---|
AR006290A1 true AR006290A1 (es) | 1999-08-25 |
Family
ID=21912044
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP980101023A AR006290A1 (es) | 1997-03-07 | 1998-03-06 | Sistema catalitico y metodo de oxidacion de materiales |
ARP030100652A AR038614A2 (es) | 1997-03-07 | 2003-02-27 | Complejo de metal de transicion coordinado con un ligando macropoliciclico |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP030100652A AR038614A2 (es) | 1997-03-07 | 2003-02-27 | Complejo de metal de transicion coordinado con un ligando macropoliciclico |
Country Status (19)
Country | Link |
---|---|
US (7) | US20070093379A1 (es) |
EP (2) | EP0966323B1 (es) |
JP (1) | JP4476364B2 (es) |
CN (1) | CN1261823B (es) |
AR (2) | AR006290A1 (es) |
AT (2) | ATE248650T1 (es) |
AU (1) | AU731371B2 (es) |
BR (1) | BR9812424B1 (es) |
CA (1) | CA2282406C (es) |
CZ (1) | CZ302258B6 (es) |
DE (2) | DE69838111T2 (es) |
ES (2) | ES2289202T3 (es) |
HU (1) | HU225021B1 (es) |
ID (1) | ID23801A (es) |
MA (1) | MA24593A1 (es) |
MX (1) | MXPA99008248A (es) |
TR (1) | TR199902475T2 (es) |
WO (1) | WO1998039098A1 (es) |
ZA (1) | ZA981883B (es) |
Families Citing this family (82)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20080125344A1 (en) * | 2006-11-28 | 2008-05-29 | Daryle Hadley Busch | Bleach compositions |
ZA981883B (en) * | 1997-03-07 | 1998-09-01 | Univ Kansas | Catalysts and methods for catalytic oxidation |
US6667288B2 (en) * | 1998-11-13 | 2003-12-23 | Procter & Gamble Company | Bleach compositions |
EP1129095B1 (en) | 1998-11-13 | 2004-09-15 | The Procter & Gamble Company | Process for preparing cross-bridged tetraaza macrocycles |
JP2002531457A (ja) * | 1998-11-30 | 2002-09-24 | ザ、プロクター、エンド、ギャンブル、カンパニー | 架橋テトラアザマクロサイクル類の製造方法 |
US6653270B2 (en) | 1999-03-02 | 2003-11-25 | Procter & Gamble Company | Stabilized bleach compositions |
AU772358B2 (en) * | 1999-03-02 | 2004-04-22 | Procter & Gamble Company, The | Stabilized bleach compositions |
WO2000060045A1 (en) * | 1999-04-01 | 2000-10-12 | The Procter & Gamble Company | Transition metal bleaching agents |
GB0004990D0 (en) | 2000-03-01 | 2000-04-19 | Unilever Plc | Composition and method for bleaching a substrate |
GB9930695D0 (en) * | 1999-12-24 | 2000-02-16 | Unilever Plc | Composition and method for bleaching a substrate |
GB9930697D0 (en) * | 1999-12-24 | 2000-02-16 | Unilever Plc | Method of treating a textile |
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AU2001292792A1 (en) * | 2000-09-25 | 2002-04-08 | The Procter And Gamble Company | Manganes complexes for magnetic resonance imaging |
GB0030877D0 (en) | 2000-12-18 | 2001-01-31 | Unilever Plc | Enhancement of air bleaching catalysts |
GB0103871D0 (en) | 2001-02-16 | 2001-04-04 | Unilever Plc | Bleaching composition of enhanced stability and a process for making such a composition |
AU2002237306B2 (en) | 2001-03-14 | 2005-03-24 | Unilever Plc | Bleaching catalysts with unsaturated surfactant and antioxidants |
GB0106285D0 (en) | 2001-03-14 | 2001-05-02 | Unilever Plc | Air bleaching catalysts with moderating agent |
JP2006504809A (ja) | 2002-05-02 | 2006-02-09 | ザ プロクター アンド ギャンブル カンパニー | 洗剤組成物及びその成分 |
JP4945755B2 (ja) * | 2004-03-30 | 2012-06-06 | 国立大学法人 名古屋工業大学 | ケージ状配位子を有する多核金属錯体 |
GB0412893D0 (en) * | 2004-06-10 | 2004-07-14 | Univ Hull | Novel antiviral macrocycle derivatives and metal complexes, incorporating bridged macrocycles |
EP1700907A1 (en) | 2005-03-11 | 2006-09-13 | Unilever N.V. | Liquid bleaching composition |
US7514577B2 (en) * | 2006-05-31 | 2009-04-07 | Exxonmobil Chemical Patents Inc. | Pd- and Pt-substituted polyoxometalates and process for their preparation |
ES2349082T3 (es) | 2006-07-07 | 2010-12-27 | Unilever Plc | Endurecimiento de un líquido. |
US7820868B2 (en) | 2007-01-19 | 2010-10-26 | Exxonmobil Chemical Patents Inc. | Transition metal substituted polyoxometalates and process for their preparation |
US7645907B2 (en) * | 2007-03-23 | 2010-01-12 | Exxonmobil Chemical Patents Inc. | Transition metal substituted polyoxometalates and process for their preparation |
US20090151601A1 (en) * | 2007-12-17 | 2009-06-18 | Elementis Specialties, Inc. | Low voc waterbased coatings with efflorescence resistance |
EP2103735A1 (en) | 2008-03-18 | 2009-09-23 | Unilever PLC | Catalytic bleaching of substrates |
JP5513486B2 (ja) * | 2008-04-28 | 2014-06-04 | ブリッジポイント、メディカル、インコーポレイテッド | 血管の閉塞部を横断するための方法および装置 |
GB0810881D0 (en) | 2008-06-16 | 2008-07-23 | Unilever Plc | Improvements relating to fabric cleaning |
EP2228429A1 (en) | 2009-03-13 | 2010-09-15 | Unilever PLC | Shading dye and catalyst combination |
JP5538760B2 (ja) * | 2009-07-03 | 2014-07-02 | 清蔵 宮田 | 酸化触媒、還元触媒及び排気ガス浄化触媒 |
US10392395B2 (en) | 2009-10-30 | 2019-08-27 | Sumitomo Chemical Company, Limited | Nitrogen-containing aromatic compounds and metal complexes |
KR20120114287A (ko) * | 2009-12-02 | 2012-10-16 | 바스프 에스이 | 포장 용도를 위한 산소 흡수제/제거제 부재로서 금속 착물의 용도 |
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AU2011267128B2 (en) | 2010-06-16 | 2015-05-07 | Akzo Nobel Chemicals International B.V. | Accelerator solution and process for curing curable resins |
EP2441820A1 (en) | 2010-10-14 | 2012-04-18 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Laundry detergent particles |
US10077353B2 (en) | 2010-12-15 | 2018-09-18 | Ppg Europe Bv | Drier composition and use thereof |
EP2474578A1 (en) | 2011-01-06 | 2012-07-11 | Rahu Catalytics Limited | Antiskinning compositions |
CN103347928B (zh) | 2011-01-31 | 2016-10-12 | 荷兰联合利华有限公司 | 碱性液体洗涤剂组合物 |
DE102011010818A1 (de) | 2011-02-10 | 2012-08-16 | Clariant International Ltd. | Verwendung von Übergangsmetallkomplexen als Bleichkatalysatoren in Wasch- und Reinigungsmitteln |
EP2675880B1 (en) | 2011-02-16 | 2016-12-14 | The Procter and Gamble Company | Liquid cleaning compositions |
WO2012112741A1 (en) | 2011-02-16 | 2012-08-23 | The Procter & Gamble Company | Compositions and methods of bleaching |
EP2476743B1 (en) | 2011-04-04 | 2013-04-24 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Method of laundering fabric |
EP2522715A1 (en) | 2011-05-13 | 2012-11-14 | Unilever Plc, A Company Registered In England And Wales under company no. 41424 of Unilever House | Aqueous concentrated laundry detergent compositions |
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- 1998-03-06 CZ CZ0313899A patent/CZ302258B6/cs not_active IP Right Cessation
- 1998-03-06 EP EP98904334A patent/EP0966323B1/en not_active Expired - Lifetime
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- 1998-03-06 DE DE69838111T patent/DE69838111T2/de not_active Expired - Lifetime
- 1998-03-06 DE DE69817780T patent/DE69817780T2/de not_active Expired - Lifetime
- 1998-03-06 MA MA24994A patent/MA24593A1/fr unknown
- 1998-03-06 EP EP03008790A patent/EP1338337B1/en not_active Expired - Lifetime
- 1998-03-06 BR BRPI9812424-2A patent/BR9812424B1/pt not_active IP Right Cessation
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- 1998-03-06 HU HU0001906A patent/HU225021B1/hu not_active IP Right Cessation
- 1998-03-06 ES ES98904334T patent/ES2203928T3/es not_active Expired - Lifetime
- 1998-03-06 WO PCT/IB1998/000302 patent/WO1998039098A1/en active IP Right Grant
- 1998-03-06 AT AT98904334T patent/ATE248650T1/de not_active IP Right Cessation
- 1998-03-06 AU AU62264/98A patent/AU731371B2/en not_active Ceased
- 1998-03-06 MX MXPA99008248A patent/MXPA99008248A/es active IP Right Grant
- 1998-03-06 TR TR1999/02475T patent/TR199902475T2/xx unknown
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2006
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2007
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2009
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2010
- 2010-04-20 US US12/763,248 patent/US20100210451A1/en not_active Abandoned
- 2010-10-13 US US12/903,449 patent/US20110028310A1/en not_active Abandoned
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