WO2022265011A1 - Welded structure - Google Patents
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- WO2022265011A1 WO2022265011A1 PCT/JP2022/023799 JP2022023799W WO2022265011A1 WO 2022265011 A1 WO2022265011 A1 WO 2022265011A1 JP 2022023799 W JP2022023799 W JP 2022023799W WO 2022265011 A1 WO2022265011 A1 WO 2022265011A1
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- welded
- joined
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- butt
- joint
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Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/24—Selection of soldering or welding materials proper
- B23K35/30—Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
- B23K35/3053—Fe as the principal constituent
- B23K35/3073—Fe as the principal constituent with Mn as next major constituent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/24—Selection of soldering or welding materials proper
- B23K35/30—Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K9/00—Arc welding or cutting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K9/00—Arc welding or cutting
- B23K9/02—Seam welding; Backing means; Inserts
Definitions
- the present invention relates to welded steel structures (hereinafter also referred to as welded structures) that are welded using thick steel plates, such as large container ships and bulk carriers.
- the present invention is a welded structure having excellent brittle crack arrestability, which can stop the propagation of brittle cracks generated from the base metal of a thick steel plate or the welded joint before it reaches a large-scale fracture of the structure.
- container ships and bulk carriers have a structure with a large opening at the top of the ship in order to improve loading capacity and cargo handling efficiency. Therefore, in container ships and bulk carriers, it is necessary to increase the strength or increase the thickness of the hull panels.
- TEU wenty Feet Equivalent Unit
- the steel plates that form the hull shell are often butt welded by high heat input welding, such as electrogas arc welding, from the viewpoint of shortening the construction period.
- high heat input welding is likely to lead to a significant decrease in toughness in the weld heat-affected zone, and has been one of the causes of brittle cracking from the welded joint.
- Non-Patent Document 1 reports the results of an experimental study on the brittle crack propagation behavior of welds in shipbuilding steel plates with a thickness of less than 50 mm.
- Non-Patent Document 1 the propagation path and propagation behavior of brittle cracks forcibly generated in welds are experimentally investigated.
- This document states that if the fracture toughness of the weld zone is secured to some extent, brittle cracks often deviate from the weld zone toward the base metal due to the influence of welding residual stress.
- multiple cases of brittle crack propagation along the weld have been confirmed. This suggests that the possibility of brittle fracture propagating straight along the weld cannot be ruled out.
- Non-Patent Document 1 there are many achievements that ships built by applying welding equivalent to the welding applied in Non-Patent Document 1 to steel plates with a thickness of less than 50 mm are in service without any problems.
- steel plate base material e.g. shipbuilding class E steel
- the brittle crack arrestability of welded parts of shipbuilding steel is specifically required by ship classification rules. It hasn't been done.
- Non-Patent Document 2 also points out that a thick steel plate having a special brittle crack arresting property is required in order to arrest the propagation of brittle cracks that have occurred.
- Patent Document 1 discloses that, in a welded structure, which is preferably a hull plate having a thickness of 50 mm or more, an aggregate is arranged so as to intersect the butt weld portion, and fillet welding is performed. Welded structures are described that are joined by In the technique described in Patent Document 1, a steel plate having a predetermined microstructure is used as a reinforcing material and fillet-welded, so that even if a brittle crack occurs in the butt welded joint, the aggregate, which is the reinforcing material, is used. It is said that brittle fracture can be stopped at this time, and fatal damage such as destruction of the welded structure can be prevented.
- Patent Literature 1 requires a complicated process to form the reinforcing material into a steel sheet having a desired structure. As a result, there is a problem that productivity is lowered and it is difficult to stably obtain a steel sheet having a desired structure.
- Patent Document 2 describes a welded structure provided with a fillet-welded joint formed by fillet-welding a joining member to a member to be joined.
- a fillet-welded joint formed by fillet-welding a joining member to a member to be joined.
- an unwelded portion remains on the butting surface of the member to be joined in the cross section of the fillet welded joint with the member to be joined, and the width of the unwelded portion is determined by the brittleness of the member to be joined. It is said to be adjusted so as to satisfy the crack arrestability Kca and a special relational expression.
- the member to be joined is a thick material with a plate thickness of 50 mm or more
- the propagation of brittle cracks generated in the member to be joined is stopped at the butt surface of the fillet weld, and the brittleness of the member to be joined is prevented. Propagation of cracks can be prevented.
- the technique described in Patent Document 2 since the brittle crack propagation arresting properties of the joining members are insufficient, the technique is sufficient to stop the propagation of brittle cracks occurring in the joined members at the joining members. It can not be said.
- Patent Documents 3 to 5 describe welded structures formed by abutting the end face of a joining member against the surface of a member to be joined and joining the member to be joined and the member to be joined by fillet welding.
- an unwelded portion is provided on the surface where the end surface of the member to be joined and the surface of the member to be joined are butted, and at least one of the weld leg length and weld width is 16 mm or less.
- a fillet welded joint in which the toughness of the fillet weld metal has a special relationship with the plate thickness of the member to be joined, or a steel plate with excellent brittle crack arrestability as the joint member.
- the weld metal of the butt weld joint a welded structure with high toughness, brittle cracks generated from the welded part of the joined member , can be prevented from propagating at the welded portion of the member to be joined.
- Patent Document 6 discloses a fillet welded joint in which the end surface of a member to be joined is butted against the surface of a member to be joined having a plate thickness of 50 mm or more, and the member to be joined and the member to be joined are joined.
- a welded structure comprising: In the welded structure described in Patent Document 6, the weld leg length and welding width of the fillet welded joint exceed 16 mm, and the end surface of the member to be joined and the surface of the member to be joined in the fillet welded joint are butted against each other.
- the cross section of the fillet welded joint has an unwelded portion of 95% or more of the plate thickness tw of the member to be joined, and the smaller value L of the weld leg length and the weld width and the plate thickness tf of the member to be joined Therefore, by using a fillet weld metal that has a toughness that satisfies the specified relationship, even if the plate thickness of the joint member is 65 to 120 mm, the fillet weld metal prevents the propagation of brittle cracks that occur in the member to be joined. It is said that it can be done.
- Patent Document 7 describes a welded structure provided with a doubler member at the butted portion of the web and flange.
- the web is butt fillet welded to the doubler member, an unwelded portion remains on the butt surface, and the tabler member is overlap fillet welded to the flange, and the overlap is welded.
- the welded structure has unwelded portions remaining on the mating surfaces. According to the technique described in Patent Document 7, if an austenitic steel plate is used for the doubler member, propagation of long brittle cracks can be prevented by the doubler member.
- Patent Document 6 requires strict construction control during welding in order to limit the weld leg length and weld width, and there are problems such as a decrease in productivity of welding construction and an increase in construction costs. .
- Patent Document 7 has a problem that the construction cost increases due to processing and welding of the doubler member, and a problem that the material cost rises when an expensive austenitic steel plate is used for the doubler member. .
- the present invention solves the problems of the prior art as described above, and solves the problem of brittle cracks occurring in members to be joined (flanges) with a plate thickness of 50 mm or more without requiring strict construction control during welding.
- An object of the present invention is to provide a welded structure excellent in brittle crack arrestability, capable of stopping propagation to (web) before reaching large-scale fracture.
- the welded structure targeted by the present invention is a welded structure having a T joint formed by butting the end face of the joining member against the surface of the member to be joined and joining them by fillet welding or partial penetration welding. is.
- the present inventors diligently studied various factors affecting the brittle crack arrest toughness of T-joints.
- the weld metal structure of the T-joint is made mainly of an austenite phase, the weld metal can be made to have high toughness.
- propagation of brittle cracks generated in the joined member (flange) to the joined member (web) without special consideration of the brittle crack propagation arresting performance of the thick steel plate used for the joined member (web). can be prevented by the weld metal of the T-joint.
- a welded structure comprising a T joint for joining the joint member and the joint member, wherein the end face of the joint member is butted against the surface of the joint member having a plate thickness of 50 mm or more, L, which is the longer value of the weld leg length and weld width of the T joint, is 16 mm or more,
- the weld metal of the T joint is % by mass, C: 0.10-0.70%, Si: 0.10-1.00%, Mn: 15.00-28.00%, P: 0.030% or less, S: 0.015% or less, Ni: 1.00-5.00%, Cr: 0.50-4.00% , Mo: 2.00% or less, N: 0.150% or less and O: 0.050% or less, the balance being Fe and unavoidable impurities;
- a welded structure having a weld metallographic structure in which the austenitic phase is 80% or more by area.
- the composition of the weld metal further contains, in mass %, (a) one or more selected from V: 0.10% or less, Ti: 0.10% or less, and Nb: 0.10% or less; and (b) at least one selected from Cu: 1.00% or less, Al: 0.10% or less, Ca: 0.010% or less, and REM: 0.020% or less, [1] Welded structure according to. [3] In the T-joint, there is an unwelded portion on the surface where the end surface of the joining member and the surface of the member to be joined meet, and the ratio of the width of the unwelded portion to the plate thickness of the joining member The welded structure according to [1], wherein the unwelded ratio Y is 30% or more.
- the joining member has a butt-welded joint portion, and the joining member is arranged so that the butt-welded joint portion of the joining member and the butt-welded joint portion of the member to be welded intersect.
- the joining member has a butt-welded joint, and the joining member is arranged so that the butt-welded joint of the joining member and the butt-welded joint of the member to be welded intersect.
- brittle crack propagation arrestability can be improved simply by selecting welding materials and adjusting welding conditions during welding without using special steel materials and without compromising safety. There is also an effect that an excellent welded structure can be manufactured.
- FIG. 4 is an explanatory diagram schematically showing an example of a joint cross section of a T joint;
- FIG. 4 is an explanatory diagram schematically showing another example of a T-joint;
- (a) is an external view, and
- (b) is a sectional view.
- FIG. 4 is an explanatory diagram schematically showing another example of a T-joint;
- (a) is an external view, and
- (b) is a sectional view.
- FIG. 4 is an explanatory diagram schematically showing the shape of a super-large structural model specimen;
- FIG. 4 is an explanatory diagram showing an example of a groove shape of a T-joint;
- a welded structure according to one embodiment of the present invention is a welded structure provided with a T-joint that joins the joining member 1 and the to-be-welded member 2 by abutting the end face of the joining member 1 against the surface of the to-be-joined member 2.
- a welded structure according to an embodiment of the present invention is, for example, a hull structure in which a hull skin of a ship is a member to be joined and a bulkhead is a member to be joined, or a hull structure in which a deck is a member to be joined and a hatch is a member to be joined.
- the T-joint described above has a joining member 1 , a member to be joined 2 , and a weld metal 5 .
- the member to be joined 2 to be used is made of a thick steel plate having a plate thickness of 50 mm or more, preferably 60 mm or more and 120 mm or less.
- the joining member 1 is preferably made of a thick steel plate having a thickness of 50 mm or more, more preferably 60 mm or more and 120 mm or less.
- the steel type of the thick steel plate used for the joining member 1 and the joined member 2 is not particularly limited, and for example, a thick steel plate having a yield strength of 350 to 490 N/mm 2 (MPa) can be suitably used.
- the T-joint provided in the welded structure according to one embodiment of the present invention has weld metal 5, and L, which is the longer one of weld leg length 3 and weld width 13, is set to 16 mm or more.
- the non-welded portion 4 (the width 16 of the unwelded portion), which is a structural discontinuity, is present on the butting surfaces of the joining member 1 and the member to be joined 2. good too.
- the presence of the unwelded portion 4 makes it easier for the brittle crack that has propagated through the members to be joined 2 to stop at the butt surfaces.
- the upper limit of the unwelded ratio Y is not particularly limited, the unwelded ratio Y is preferably 98% or less from the viewpoint of ensuring a predetermined strength.
- the welded leg length 3, the welded width 13, and the width 16 of the unwelded portion are the joint cross section of the T joint (the joint cross section shown in FIG. 1, which will be described later). , which is a plane parallel to the xy plane when the plate thickness direction of the member 2 to be joined is taken as the y axis.
- FIG. 1(a) shows a case where the member to be joined 1 is joined upright to the member to be joined 2, the present invention is not limited to this.
- the joining member 1 may be joined at an angle ⁇ with respect to the member 2 to be joined.
- a gap 14 may be provided between the member to be joined 1 and the member to be joined 2, and a spacer 15 may be inserted into the gap 14 as shown in FIG. 1(d).
- the gap 14 is preferably 10 mm or less from the viewpoint of reducing man-hours during welding.
- brittle cracks are generated from the butt-welded joint portion 11 .
- a structural discontinuity As a discontinuous portion of the structure, for example, as described above, it is preferable to have an unwelded portion 4 on the butting surfaces of the joined member 2 and the joining member 1 of the T-joint.
- the welded structure shown in FIG. 2 is a welded structure in which the member to be joined 2 is a steel plate joined by a butt weld joint 11, and the joint member 1 is welded so as to intersect the welded portion 11 of the butt weld joint. .
- the joint member 1 is a steel plate joined by a butt weld joint 12
- the member to be joined 2 is a steel plate joined by a butt weld joint 11
- the butt weld joint 12 of the joint member 1 is used.
- the butt welded joint 11 of the member to be joined 2 are welded so as to intersect each other.
- the joint member 1 and the butt-welded joint 11 are arranged so as to be perpendicular to each other, but the present invention is not limited to this. Needless to say, they may cross each other obliquely.
- the method for manufacturing the welded joint is not particularly limited, and any commonly used manufacturing method can be applied. For example, steel plates for members to be joined and steel plates for members to be joined are butt-welded to obtain joining members and members to be joined having butt-welded joints. Then, the obtained joining member and the member to be joined may be welded to produce a T-joint.
- a set of steel plates for joining members before butt welding is tack-welded to a member to be joined, and then the steel plates for joining members are butt-welded to each other to obtain a joining member having a butt-welded joint. Then, the obtained joining member may be permanently welded to the member to be joined to manufacture a T-joint.
- L which is the longer value of the weld leg length 3 and the weld width 13 of the T-joint, shall be 16 mm or more. If L is less than 16 mm, that is, both the weld leg length 3 and the weld width 13 are less than 16 mm, it is advantageous to ensure brittle crack arrestability. However, when the member plate thickness exceeds 80 mm, it becomes difficult to ensure the strength of the welded portion. In addition, even if the plate thickness of the member is 80 mm or less, there is a high risk that it will be difficult to secure the strength of the welded portion due to rework during construction. Although the upper limit of L is not particularly limited, L is preferably 30 mm or less from the viewpoint of construction efficiency and the like.
- the structure of the weld metal of the T-joint is a structure in which the austenite phase is 80% or more in terms of area% (area ratio). .
- the upper limit of the austenite phase is not particularly limited, and may be 100% in terms of area %.
- a phase other than the austenite phase (hereinafter also referred to as the residual phase) is 0 to 20% in terms of area %, and examples of the residual phase include ferrite phase and the like.
- the weld metal structure By setting the weld metal structure to a structure in which the austenite phase is 80% or more in area%, the toughness of the weld metal is improved. As a result, even when L is 16 mm or more, the propagation of brittle cracks generated in the members to be joined can be stopped by the weld metal of the T-joint, and the propagation of brittle cracks to the members to be joined can be prevented.
- the weld metal having the above structure has a Vickers hardness of 170 to 260 HV (yield strength of 390 MPa or more, tensile strength of 490 MPa or more). It is preferred to have
- the mass % of the weld metal of the T joint is C: 0.10 to 0.70%, Si: 0.10 to 1.00%, Mn: 15.00 to 28.00%, P: 0.030% or less, S: 0.015% or less, Ni: 1.00% or more.
- the balance consists of Fe and unavoidable impurities.
- the toughness of the weld metal is improved by setting the weld metal structure to a structure in which the austenite phase is 80% or more in terms of area %.
- L is 16 mm or more
- the propagation of brittle cracks generated in the members to be joined can be stopped by the weld metal of the T-joint, and the propagation of brittle cracks to the members to be joined can be prevented.
- mass % in the weld metal composition is simply expressed as %.
- C 0.10-0.70%
- C is an element that stabilizes austenite.
- C is an element that has the effect of increasing the strength of the weld metal through solid-solution strengthening.
- the C content must be 0.10% or more.
- the C content should be 0.10-0.70%.
- the C content is preferably 0.20-0.60%.
- Si 0.10-1.00% Si suppresses the precipitation of carbides, causes C to dissolve in austenite, and stabilizes austenite.
- the content of Si must be 0.10% or more.
- Si content exceeds 1.00%, Si segregates during solidification to form a liquid phase at solidification cell interfaces. This reduces hot cracking resistance. Furthermore, the toughness is lowered. Therefore, the Si content should be 0.10 to 1.00%.
- the Si content is preferably 0.20 to 0.90%.
- Mn 15.00-28.00%
- Mn is an element that stabilizes the austenite phase at low cost.
- the content of Mn is required to be 15.00% or more. If the Mn content is less than 15.00%, the stability of austenite is insufficient. As a result, a hard martensite phase is generated in the weld metal and the toughness is lowered. On the other hand, if the Mn content exceeds 28.00%, excessive Mn segregation occurs during solidification, which induces hot cracking. Therefore, the Mn content should be 15.00-28.00%.
- the Mn content is preferably 17.00-26.00%.
- P 0.030% or less
- P is an element that segregates at grain boundaries and induces hot cracking. Therefore, it is preferable to reduce P as much as possible, but 0.030% or less is permissible. Therefore, the P content should be 0.030% or less. Excessive reduction of P invites an increase in refining cost. Therefore, it is preferable to adjust the P content to 0.002% or more.
- S 0.015% or less S is an element that segregates at grain boundaries and induces hot cracking. Therefore, it is preferable to reduce S as much as possible, but 0.015% or less is permissible. Therefore, the S content should be 0.015% or less. Note that an excessive reduction in S causes an increase in refining costs. Therefore, it is preferable to adjust the S content to 0.001% or more.
- Ni 1.00-5.00%
- Ni is an element that strengthens austenite grain boundaries, and by suppressing embrittlement of grain boundaries, suppresses the occurrence of hot cracks. In order to obtain such effects, the content of Ni must be 1.00% or more. Ni also has the effect of stabilizing the austenite phase. However, Ni is an expensive element, and a Ni content exceeding 5.00% is economically disadvantageous. Therefore, the Ni content should be 1.00 to 5.00%.
- Cr 0.50-4.00% Cr has the effect of improving the strength of the weld metal. If the Cr content is less than 0.50%, the above effects cannot be secured. On the other hand, when the Cr content exceeds 4.00%, the toughness and hot cracking resistance of the weld metal deteriorate. Therefore, the Cr content should be 0.50 to 4.00%. The Cr content is preferably 0.70-3.00%.
- Mo is an element that strengthens austenite grain boundaries, and by suppressing embrittlement of grain boundaries, suppresses the occurrence of hot cracks. Mo also has the effect of improving wear resistance by hardening the weld metal. In order to obtain such effects, the Mo content is preferably 0.10% or more. On the other hand, if the Mo content exceeds 2.00%, the grain interiors are too hardened, the grain boundaries become relatively weak, and hot cracking occurs. Therefore, the Mo content should be 2.00% or less. Incidentally, the Mo content is more preferably 0.20 to 1.90%.
- N 0.150% or less
- N is an element that is unavoidably mixed.
- N like C, effectively contributes to improving the strength of the weld metal.
- N is also an element that stabilizes the austenite phase and stably improves the cryogenic toughness. Since such an effect becomes remarkable when the N content is 0.003% or more, the N content is preferably 0.003% or more.
- the N content exceeds 0.150%, nitrides are formed and the low temperature toughness is lowered. Therefore, the N content should be 0.150% or less.
- the N content is preferably 0.003-0.120%.
- O 0.050% or less
- O (oxygen) is an unavoidable element. However, O forms Al-based oxides and Si-based oxides in the weld metal and contributes to suppression of coarsening of the solidified structure. Since such an effect becomes significant when the O content is 0.003% or more, the O content is preferably 0.003% or more. However, when the O content exceeds 0.050%, coarsening of the oxide becomes significant. Therefore, the O (oxygen) content should be 0.050% or less. The O content is preferably 0.003-0.040%.
- components described above are the basic components of the weld metal composition, but in addition to the basic components described above, optional components include: (a) one or more selected from V: 0.10% or less, Ti: 0.10% or less, and Nb: 0.10% or less; and (b) at least one selected from Cu: 1.00% or less, Al: 0.10% or less, Ca: 0.010% or less, and REM: 0.020% or less.
- V 0.10% or less
- Ti 0.10% or less
- Nb 0.10% or less It is an element that precipitates carbides and contributes to an increase in the strength of the weld metal, and one or more of these elements can be optionally contained.
- V 0.10% or less
- V is a carbide-forming element that precipitates fine carbides in grains and contributes to improving the strength of the weld metal.
- the V content is preferably 0.10% or less.
- the V content is more preferably 0.002-0.050%.
- Ti 0.10% or less
- Ti is a carbide-forming element, which precipitates fine carbides and contributes to improving the strength of the weld metal.
- the Ti content is preferably 0.10% or less.
- the Ti content is more preferably 0.002 to 0.050%.
- Nb 0.10% or less Like V and Ti, Nb is also a carbide-forming element that precipitates fine carbides and contributes to improving the strength of the weld metal. In order to obtain such effects, it is preferable to contain 0.001% or more of Nb. However, if the Nb content exceeds 0.10%, excessive carbides act as starting points for fractures, resulting in a decrease in low-temperature toughness. Therefore, when Nb is contained, the Nb content is preferably 0.10% or less. The Nb content is more preferably 0.002-0.090%.
- Cu is an element that contributes to austenite stabilization.
- Al is an element that acts as a deoxidizing agent.
- Ca and REM are elements that contribute to the suppression of hot cracking.
- Cu, Al, Ca and REM can optionally contain one or more.
- Cu 1.00% or less
- Cu is an element that stabilizes the austenite phase. In order to obtain such effects, it is preferable to contain 0.01% or more of Cu. However, when the Cu content exceeds 1.00%, a liquid phase with a low melting point is generated at the grain boundary, resulting in hot cracking. Therefore, when Cu is contained, the Cu content is preferably 1.00% or less. The Cu content is more preferably 0.02-0.80%.
- Al acts as a deoxidizing agent. Also, Al has an important effect of increasing the viscosity of the molten metal, stably maintaining the bead shape, and reducing the occurrence of spatter. Furthermore, Al reduces the solid-liquid coexistence temperature range and contributes to suppressing the occurrence of hot cracks in the weld metal. Since such an effect becomes remarkable when the Al content is 0.001% or more, the Al content is preferably 0.001% or more. However, if the Al content exceeds 0.10%, the viscosity of the molten metal becomes too high, and conversely, spatter increases and defects such as poor fusion increase without bead spreading. Therefore, when Al is contained, the Al content is preferably 0.10% or less. The Al content is more preferably 0.002-0.090%.
- Ca 0.010% or less Ca is an element that contributes to the suppression of hot cracking.
- Ca combines with S in the molten metal to form sulfide CaS with a high melting point, thereby suppressing hot cracking.
- the Ca content is preferably 0.010% or less.
- the Ca content is more preferably 0.002 to 0.008%.
- REM 0.020% or less REM, like Ca, is an element that contributes to the suppression of hot cracking.
- REM is also a strong deoxidizing agent and exists in the form of REM oxides in the weld metal. REM oxides act as nucleation sites during solidification, thereby changing the solidification morphology of the weld metal and contributing to the suppression of hot cracking. Such an effect becomes remarkable when the content of REM is 0.001% or more.
- the REM content exceeds 0.020%, arc stability decreases. Therefore, when REM is contained, the REM content is preferably 0.020% or less.
- the REM content is more preferably 0.002-0.016%.
- the balance other than the above components is Fe and unavoidable impurities.
- unavoidable impurities include Bi, Sn, Sb, etc., and a total content of 0.2% or less is permissible.
- weld metal of the T-joint having the above weld metal composition and the above weld metal structure can be formed, for example, by adjusting the welding material and welding conditions and performing multi-layer welding.
- gas metal arc welding which is commonly used, is suitable.
- the solid wire to be used has the above-described weld metal composition and the above-described weld metal structure so that the weld metal of the T-joint can be formed.
- % by mass C: 0.10-0.70%, Si: 0.10-1.00%, Mn: 15.00-28.00%, P: 0.030% or less, S: 0.015% or less, Ni: 1.00-5.00%, Cr: 0.50-4.00% , Mo: 2.00% or less, N: 0.150% or less, and O: 0.050% or less, optionally, (a) one or more selected from V: 0.10% or less, Ti: 0.10% or less, and Nb: 0.10% or less; and (b) Cu: 1.00% or less, Al: 0.10% or less, Ca: 0.010% or less, and REM: 0.020% or less.
- the wire preferably has a wire composition in which the balance is Fe and unavoidable impurities.
- gas metal arc welding is preferably performed in a shielding gas to form a multi-layer weld metal.
- the welding conditions are downward position, current: 150 to 450 A (DCEP), voltage: 20 to 40 V, welding speed: 15 to 60 cm/min, interpass temperature: 100 to 200°C, and shield gas: 80 volumes. It is preferable to satisfy the conditions of %Ar-20% by volume CO 2 at the same time.
- the welding heat input for one pass within the range of 1.0 to 3.0 kJ/mm.
- the joining member 1 may be provided with a groove having a predetermined angle (40°).
- the end surface of the member to be joined 1 is butted against the surface of the member to be joined 2, and these are welded to produce a large welded joint 9 of the actual size having the shape shown in FIGS. did.
- the member to be joined is a thick steel plate (only the base material, the type in Table 2 is indicated as "base material”) (Fig.
- Welding of the joining member 1 and the member to be joined 2 was performed by gas metal arc welding (GMAW) so that the weld metal composition shown in Table 1 and the weld metal structure, hardness and L shown in Table 2 were obtained.
- welding materials, and welding conditions such as welding heat input and shielding gas were varied to fabricate T-joints.
- the welding consumable was a solid wire with a diameter of 1.2 mm adjusted to the desired weld metal composition.
- the welding conditions are downward position, current: 150 to 450A (DCEP), voltage: 20 to 40V, welding speed: 15 to 60cm/min, interpass temperature: 100 to 200°C, shield gas: 80% by volume Ar.
- the condition was -20 vol% CO 2 .
- the heat input for one-pass welding was adjusted within the range of 1.0 to 3.0 kJ/mm.
- a gap 14 was provided between the joining member 1 and the joined member 2.
- the joining member 1 was welded with a groove as shown in FIG.
- a test piece was taken from the weld metal of the obtained T joint. Using the sampled test piece, a chemical analysis method according to a conventional method was performed to measure the composition of the weld metal. Table 2 shows the results.
- the austenite phase and ferrite phase were identified by phase analysis by the EBSD method according to the usual method, and the area ratio of each phase in the weld metal structure was calculated. Table 2 shows the results.
- weld metal hardness was measured according to JIS Z 2244-1 (2020) using the sampled test pieces. Table 2 shows the results.
- a super-large structural model specimen shown in Fig. 4 was produced, and a brittle crack arrest test was performed.
- a steel plate having the same thickness as the member to be joined 2 was welded below the member to be joined 2 of the large welded joint 9 by tack welding 8 .
- a mechanical notch 7 is provided in the member 2 to be joined.
- brittle crack arrest test the machine notch 7 was hit to generate a brittle crack, and it was investigated whether the propagated brittle crack would stop at the weld metal (WM). All tests were conducted under conditions of stress of 243 to 283 N/mm 2 and temperature of -10°C.
- the stress of 243 N/mm 2 is equivalent to the maximum allowable stress of 355 N/mm class 2 steel plate applied to the hull, and the stress of 257 N/mm 2 is the yield strength of 390 N/mm 2 applied to the hull.
- the stress of 283N/ mm2 is the value equivalent to the maximum allowable stress of class steel plates with a yield strength applied to ship hulls. It was set to correspond to the maximum allowable stress depending on the The temperature of -10°C is the design temperature for ships.
- the brittle crack propagated through the joined member 2 and then entered the weld metal 5 and stopped.
- the brittle crack propagated to the joint member 1 without stopping at the weld metal 5 .
- weld metal 5 could not prevent the propagation of brittle cracks.
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Abstract
Description
[1]接合部材の端面が板厚50mm以上の被接合部材の表面に突き合され、前記接合部材と前記被接合部材とを接合するT継手を備える、溶接構造体であって、
前記T継手の溶接脚長および溶着幅のうちの長い方の値であるLが16mm以上であり、
前記T継手の溶接金属が、
質量%で、C:0.10~0.70%、Si:0.10~1.00%、Mn:15.00~28.00%、P:0.030%以下、S:0.015%以下、Ni:1.00~5.00%、Cr:0.50~4.00%、Mo:2.00%以下、N:0.150%以下およびO:0.050%以下であり、残部がFe及び不可避的不純物である、溶接金属組成と、
オーステナイト相が面積%で80%以上である、溶接金属組織と、を有する、溶接構造体。
[2]前記溶接金属組成が、さらに、質量%で、
(a)V:0.10%以下、Ti:0.10%以下およびNb:0.10%以下のうちから選んだ1種または2種以上、
ならびに
(b)Cu:1.00%以下、Al:0.10%以下、Ca:0.010%以下およびREM:0.020%以下のうちから選んだ1種または2種以上
のうちの少なくとも一方を含有する、[1]に記載の溶接構造体。
[3]前記T継手における前記接合部材の端面と前記被接合部材の表面とを突き合わせた面に未溶着部が存在し、かつ、前記接合部材の板厚に対する前記未溶着部の幅の比率である未溶着比率Yが30%以上である、[1]に記載の溶接構造体。
[4]前記T継手における前記接合部材の端面と前記被接合部材の表面とを突き合わせた面に未溶着部が存在し、かつ、前記接合部材の板厚に対する前記未溶着部の幅の比率である未溶着比率Yが30%以上である、[2]に記載の溶接構造体。
[5]前記被接合部材が、前記接合部材と交差するように突合せ溶接継手部を有する、[1]に記載の溶接構造体。
[6]前記被接合部材が、前記接合部材と交差するように突合せ溶接継手部を有する、[2]に記載の溶接構造体。
[7]前記被接合部材が、前記接合部材と交差するように突合せ溶接継手部を有する、[3]に記載の溶接構造体。
[8]前記被接合部材が、前記接合部材と交差するように突合せ溶接継手部を有する、[4]に記載の溶接構造体。
[9]前記接合部材が、突合せ溶接継手部を有し、該接合部材の突合せ溶接継手部と前記被溶接部材の突合せ溶接継手部とが交差するように、前記接合部材を、配設してなる、[5]に記載の溶接構造体。
[10]前記接合部材が、突合せ溶接継手部を有し、該接合部材の突合せ溶接継手部と前記被溶接部材の突合せ溶接継手部とが交差するように、前記接合部材を、配設してなる、[6]に記載の溶接構造体。
[11]前記接合部材が、突合せ溶接継手部を有し、該接合部材の突合せ溶接継手部と前記被溶接部材の突合せ溶接継手部とが交差するように、前記接合部材を、配設してなる、[7]に記載の溶接構造体。
[12]前記接合部材が、突合せ溶接継手部を有し、該接合部材の突合せ溶接継手部と前記被溶接部材の突合せ溶接継手部とが交差するように、前記接合部材を、配設してなる、[8]に記載の溶接構造体。
[13]前記接合部材の板厚が50mm以上である、請求項[1]ないし[12]のいずれかに記載の溶接構造体。
[14]前記接合部材と前記被接合部材との間の隙間が10mm以下である、請求項[1]ないし[12]のいずれかに記載の溶接構造体。
[15]前記接合部材と前記被接合部材との間の隙間が10mm以下である、[13]に記載の溶接構造体。 The present invention has been completed by further studies on the above findings. That is, the gist of the present invention is as follows.
[1] A welded structure comprising a T joint for joining the joint member and the joint member, wherein the end face of the joint member is butted against the surface of the joint member having a plate thickness of 50 mm or more,
L, which is the longer value of the weld leg length and weld width of the T joint, is 16 mm or more,
The weld metal of the T joint is
% by mass, C: 0.10-0.70%, Si: 0.10-1.00%, Mn: 15.00-28.00%, P: 0.030% or less, S: 0.015% or less, Ni: 1.00-5.00%, Cr: 0.50-4.00% , Mo: 2.00% or less, N: 0.150% or less and O: 0.050% or less, the balance being Fe and unavoidable impurities;
A welded structure having a weld metallographic structure in which the austenitic phase is 80% or more by area.
[2] The composition of the weld metal further contains, in mass %,
(a) one or more selected from V: 0.10% or less, Ti: 0.10% or less, and Nb: 0.10% or less;
and (b) at least one selected from Cu: 1.00% or less, Al: 0.10% or less, Ca: 0.010% or less, and REM: 0.020% or less, [1] Welded structure according to.
[3] In the T-joint, there is an unwelded portion on the surface where the end surface of the joining member and the surface of the member to be joined meet, and the ratio of the width of the unwelded portion to the plate thickness of the joining member The welded structure according to [1], wherein the unwelded ratio Y is 30% or more.
[4] In the T-joint, there is an unwelded portion on the surface where the end surface of the joining member and the surface of the member to be joined are butted against each other, and the ratio of the width of the unwelded portion to the plate thickness of the joining member The welded structure according to [2], wherein the unwelded ratio Y is 30% or more.
[5] The welded structure according to [1], wherein the member to be joined has a butt weld joint so as to intersect the member to be joined.
[6] The welded structure according to [2], wherein the member to be joined has a butt weld joint so as to intersect the member to be joined.
[7] The welded structure according to [3], wherein the member to be joined has a butt weld joint that intersects the member to be joined.
[8] The welded structure according to [4], wherein the member to be joined has a butt weld joint so as to intersect the member to be joined.
[9] The joining member has a butt-welded joint portion, and the joining member is arranged so that the butt-welded joint portion of the joining member and the butt-welded joint portion of the member to be welded intersect. The welded structure according to [5].
[10] The joining member has a butt-welded joint portion, and the joining member is arranged so that the butt-welded joint portion of the joining member and the butt-welded joint portion of the member to be welded intersect. The welded structure according to [6].
[11] The joining member has a butt-welded joint portion, and the joining member is arranged so that the butt-welded joint portion of the joining member and the butt-welded joint portion of the member to be welded intersect. The welded structure according to [7].
[12] The joining member has a butt-welded joint, and the joining member is arranged so that the butt-welded joint of the joining member and the butt-welded joint of the member to be welded intersect. The welded structure according to [8].
[13] The welded structure according to any one of [1] to [12], wherein the joining member has a plate thickness of 50 mm or more.
[14] The welded structure according to any one of [1] to [12], wherein the gap between the joining member and the member to be joined is 10 mm or less.
[15] The welded structure according to [13], wherein the gap between the member to be joined and the member to be joined is 10 mm or less.
Cは、オーステナイトを安定化させる元素である。また、Cは、固溶強化により、溶接金属の強度を上昇させる作用を有する元素である。このような効果を得るためには、Cの0.10%以上の含有を必要とする。しかし、C含有量が0.70%を超えると、溶接時の高温割れが生じやすくなる。そのため、C含有量は0.10~0.70%とする。なお、C含有量は、好ましくは0.20~0.60%である。 C: 0.10-0.70%
C is an element that stabilizes austenite. Also, C is an element that has the effect of increasing the strength of the weld metal through solid-solution strengthening. In order to obtain such effects, the C content must be 0.10% or more. However, when the C content exceeds 0.70%, hot cracks tend to occur during welding. Therefore, the C content should be 0.10-0.70%. The C content is preferably 0.20-0.60%.
Siは、炭化物の析出を抑制することで、Cをオーステナイトに固溶させ、オーステナイトを安定化させる。そのような効果を得るためには、Siの0.10%以上の含有を必要とする。しかし、Si含有量が1.00%を超えると、Siが、凝固時に偏析して、凝固セル界面に液相を生成する。これにより、耐高温割れ性を低下させる。さらには靭性が低下する。そのため、Si含有量は0.10~1.00%とする。なお、Si含有量は、好ましくは0.20~0.90%である。 Si: 0.10-1.00%
Si suppresses the precipitation of carbides, causes C to dissolve in austenite, and stabilizes austenite. In order to obtain such an effect, the content of Si must be 0.10% or more. However, when the Si content exceeds 1.00%, Si segregates during solidification to form a liquid phase at solidification cell interfaces. This reduces hot cracking resistance. Furthermore, the toughness is lowered. Therefore, the Si content should be 0.10 to 1.00%. Incidentally, the Si content is preferably 0.20 to 0.90%.
Mnは、安価に、オーステナイト相を安定化する元素である。そのためには、Mnの15.00%以上の含有を必要とする。Mn含有量が15.00%未満では、オーステナイトの安定度が不足する。これにより、溶接金属中に硬質のマルテンサイト相が生成し、靭性が低下する。一方、Mn含有量が28.00%を超えると、凝固時に過度のMn偏析が発生し、高温割れを誘発する。そのため、Mn含有量は15.00~28.00%とする。なお、Mn含有量は、好ましくは17.00~26.00%である。 Mn: 15.00-28.00%
Mn is an element that stabilizes the austenite phase at low cost. For that purpose, the content of Mn is required to be 15.00% or more. If the Mn content is less than 15.00%, the stability of austenite is insufficient. As a result, a hard martensite phase is generated in the weld metal and the toughness is lowered. On the other hand, if the Mn content exceeds 28.00%, excessive Mn segregation occurs during solidification, which induces hot cracking. Therefore, the Mn content should be 15.00-28.00%. The Mn content is preferably 17.00-26.00%.
Pは、結晶粒界に偏析し、高温割れを誘発する元素である。そのため、Pはできるだけ低減することが好ましいが、0.030%以下であれば許容できる。そのため、P含有量は0.030%以下とする。なお、Pの過度の低減は、精練コストの高騰を招く。そのため、P含有量は0.002%以上に調整することが好ましい。 P: 0.030% or less P is an element that segregates at grain boundaries and induces hot cracking. Therefore, it is preferable to reduce P as much as possible, but 0.030% or less is permissible. Therefore, the P content should be 0.030% or less. Excessive reduction of P invites an increase in refining cost. Therefore, it is preferable to adjust the P content to 0.002% or more.
Sは、結晶粒界に偏析し、高温割れを誘発する元素である。そのため、Sはできるだけ低減することが好ましいが、0.015%以下であれば許容できる。そのため、S含有量は0.015%以下とする。なお、Sの過度の低減は、精練コストの高騰を招く。そのため、S含有量は0.001%以上に調整することが好ましい。 S: 0.015% or less S is an element that segregates at grain boundaries and induces hot cracking. Therefore, it is preferable to reduce S as much as possible, but 0.015% or less is permissible. Therefore, the S content should be 0.015% or less. Note that an excessive reduction in S causes an increase in refining costs. Therefore, it is preferable to adjust the S content to 0.001% or more.
Niは、オーステナイト粒界を強化する元素であり、粒界の脆化を抑制することで、高温割れの発生を抑制する。このような効果を得るためには、Niの1.00%以上の含有を必要とする。また、Niは、オーステナイト相を安定化させる効果もある。しかし、Niは高価な元素であり、5.00%を超える含有は、経済的に不利となる。そのため、Ni含有量は1.00~5.00%とする。 Ni: 1.00-5.00%
Ni is an element that strengthens austenite grain boundaries, and by suppressing embrittlement of grain boundaries, suppresses the occurrence of hot cracks. In order to obtain such effects, the content of Ni must be 1.00% or more. Ni also has the effect of stabilizing the austenite phase. However, Ni is an expensive element, and a Ni content exceeding 5.00% is economically disadvantageous. Therefore, the Ni content should be 1.00 to 5.00%.
Crは、溶接金属の強度を向上させる効果がある。Cr含有量が0.50%未満では、上記した効果を確保できない。一方、Cr含有量が4.00%を超えると、溶接金属の靱性および耐高温割れ性が低下する。そのため、Cr含有量は0.50~4.00%とする。なお、Cr含有量は、好ましくは0.70~3.00%である。 Cr: 0.50-4.00%
Cr has the effect of improving the strength of the weld metal. If the Cr content is less than 0.50%, the above effects cannot be secured. On the other hand, when the Cr content exceeds 4.00%, the toughness and hot cracking resistance of the weld metal deteriorate. Therefore, the Cr content should be 0.50 to 4.00%. The Cr content is preferably 0.70-3.00%.
Moは、オーステナイト粒界を強化する元素であり、粒界の脆化を抑制することで、高温割れの発生を抑制する。また、Moは、溶接金属を硬化させることにより、耐摩耗性を向上させる作用も有する。このような効果を得るためには、Mo含有量を0.10%以上とすることが好ましい。一方、Mo含有量が2.00%を超えると、粒内が硬化しすぎて、相対的に粒界が弱くなり、高温割れが発生する。そのため、Mo含有量は2.00%以下とする。なお、Mo含有量は、より好ましくは0.20~1.90%である。 Mo: 2.00% or less Mo is an element that strengthens austenite grain boundaries, and by suppressing embrittlement of grain boundaries, suppresses the occurrence of hot cracks. Mo also has the effect of improving wear resistance by hardening the weld metal. In order to obtain such effects, the Mo content is preferably 0.10% or more. On the other hand, if the Mo content exceeds 2.00%, the grain interiors are too hardened, the grain boundaries become relatively weak, and hot cracking occurs. Therefore, the Mo content should be 2.00% or less. Incidentally, the Mo content is more preferably 0.20 to 1.90%.
Nは、不可避的に混入する元素である。ただし、Nは、Cと同様に、溶接金属の強度向上に有効に寄与する。また、Nは、オーステナイト相を安定化し、極低温靱性を安定的に向上させる元素でもある。このような効果は、Nの0.003%以上の含有で顕著となるため、N含有量は0.003%以上が好ましい。しかし、N含有量が0.150%を超えると、窒化物を形成し、低温靱性が低下する。そのため、N含有量は0.150%以下とする。なお、N含有量は、好ましくは0.003~0.120%である。 N: 0.150% or less N is an element that is unavoidably mixed. However, N, like C, effectively contributes to improving the strength of the weld metal. N is also an element that stabilizes the austenite phase and stably improves the cryogenic toughness. Since such an effect becomes remarkable when the N content is 0.003% or more, the N content is preferably 0.003% or more. However, when the N content exceeds 0.150%, nitrides are formed and the low temperature toughness is lowered. Therefore, the N content should be 0.150% or less. The N content is preferably 0.003-0.120%.
O(酸素)は、不可避的に混入する元素である。ただし、Oは、溶接金属中で、Al系酸化物やSi系酸化物を形成し、凝固組織の粗大化抑制に寄与する。このような効果は、Oの0.003%以上の含有で著しくなるため、O含有量は0.003%以上が好ましい。しかしながら、O含有量が0.050%を超えると、酸化物の粗大化が著しくなる。そのため、O(酸素)含有量は0.050%以下とする。なお、O含有量は、好ましくは0.003~0.040%である。 O: 0.050% or less O (oxygen) is an unavoidable element. However, O forms Al-based oxides and Si-based oxides in the weld metal and contributes to suppression of coarsening of the solidified structure. Since such an effect becomes significant when the O content is 0.003% or more, the O content is preferably 0.003% or more. However, when the O content exceeds 0.050%, coarsening of the oxide becomes significant. Therefore, the O (oxygen) content should be 0.050% or less. The O content is preferably 0.003-0.040%.
(a)V:0.10%以下、Ti:0.10%以下およびNb:0.10%以下のうちから選んだ1種または2種以上、
ならびに
(b)Cu:1.00%以下、Al:0.10%以下、Ca:0.010%以下およびREM:0.020%以下のうちから選んだ1種または2種以上
のうちの少なくとも一方を含有させることができる。 The components described above are the basic components of the weld metal composition, but in addition to the basic components described above, optional components include:
(a) one or more selected from V: 0.10% or less, Ti: 0.10% or less, and Nb: 0.10% or less;
and (b) at least one selected from Cu: 1.00% or less, Al: 0.10% or less, Ca: 0.010% or less, and REM: 0.020% or less.
V、TiおよびNbはいずれも、炭化物形成元素で、粒内に微細な炭化物を析出させて溶接金属の強度増加に寄与する元素であり、任意に1種または2種以上を含有させることができる。 (a) One or more selected from V: 0.10% or less, Ti: 0.10% or less, and Nb: 0.10% or less It is an element that precipitates carbides and contributes to an increase in the strength of the weld metal, and one or more of these elements can be optionally contained.
Vは、炭化物形成元素で、粒内に微細な炭化物を析出させて、溶接金属の強度向上に寄与する。このような効果を得るためには、Vを0.001%以上含有させることが好ましい。しかし、V含有量が0.10%を超えると、過剰な炭化物が破壊の発生起点となるため、低温靭性が低下する。そのため、Vを含有させる場合、V含有量は0.10%以下が好ましい。なお、V含有量は、より好ましくは0.002~0.050%である。 V: 0.10% or less V is a carbide-forming element that precipitates fine carbides in grains and contributes to improving the strength of the weld metal. In order to obtain such effects, it is preferable to contain 0.001% or more of V. However, if the V content exceeds 0.10%, the excessive carbides act as starting points for fracture, resulting in a decrease in low-temperature toughness. Therefore, when V is contained, the V content is preferably 0.10% or less. The V content is more preferably 0.002-0.050%.
また、TiもVと同様に、炭化物形成元素で、微細な炭化物を析出させて、溶接金属の強度向上に寄与する。このような効果を得るためには、Tiを0.001%以上含有させることが好ましい。しかし、Ti含有量が0.10%を超えると、過剰な炭化物が破壊の発生起点となるため、低温靭性が低下する。そのため、Tiを含有させる場合、Ti含有量は0.10%以下が好ましい。なお、Ti含有量は、より好ましくは0.002~0.050%である。 Ti: 0.10% or less Ti, like V, is a carbide-forming element, which precipitates fine carbides and contributes to improving the strength of the weld metal. In order to obtain such effects, it is preferable to contain 0.001% or more of Ti. However, when the Ti content exceeds 0.10%, the excessive carbides act as starting points for fractures, resulting in a decrease in low-temperature toughness. Therefore, when Ti is contained, the Ti content is preferably 0.10% or less. Incidentally, the Ti content is more preferably 0.002 to 0.050%.
また、NbもVおよびTiと同様に、炭化物形成元素で、微細な炭化物を析出させて、溶接金属の強度向上に寄与する。このような効果を得るためには、Nbを0.001%以上含有させることが好ましい。しかし、Nb含有量が0.10%を超えると、過剰な炭化物が破壊の発生起点となるため、低温靭性が低下する。そのため、Nbを含有させる場合、Nb含有量は0.10%以下が好ましい。なお、Nb含有量は、より好ましくは0.002~0.090%である。 Nb: 0.10% or less Like V and Ti, Nb is also a carbide-forming element that precipitates fine carbides and contributes to improving the strength of the weld metal. In order to obtain such effects, it is preferable to contain 0.001% or more of Nb. However, if the Nb content exceeds 0.10%, excessive carbides act as starting points for fractures, resulting in a decrease in low-temperature toughness. Therefore, when Nb is contained, the Nb content is preferably 0.10% or less. The Nb content is more preferably 0.002-0.090%.
Cuは、オーステナイト安定化に寄与する元素である。Alは、脱酸剤として作用する元素である。また、CaおよびREMは高温割れの抑制に寄与する元素である。Cu、Al、CaおよびREMは、任意に1種または2種以上を含有できる。 (b) One or more selected from Cu: 1.00% or less, Al: 0.10% or less, Ca: 0.010% or less, and REM: 0.020% or less Cu is an element that contributes to austenite stabilization. Al is an element that acts as a deoxidizing agent. Also, Ca and REM are elements that contribute to the suppression of hot cracking. Cu, Al, Ca and REM can optionally contain one or more.
Cuは、オーステナイト相を安定化する元素である。このような効果を得るためには、Cuを0.01%以上含有させることが好ましい。しかし、Cu含有量が1.00%を超えると、粒界で低融点の液相が生成するため、高温割れが発生する。そのため、Cuを含有させる場合、Cu含有量は1.00%以下が好ましい。なお、Cu含有量は、より好ましくは0.02~0.80%である。 Cu: 1.00% or less Cu is an element that stabilizes the austenite phase. In order to obtain such effects, it is preferable to contain 0.01% or more of Cu. However, when the Cu content exceeds 1.00%, a liquid phase with a low melting point is generated at the grain boundary, resulting in hot cracking. Therefore, when Cu is contained, the Cu content is preferably 1.00% or less. The Cu content is more preferably 0.02-0.80%.
Alは、脱酸剤として作用する。また、Alは、溶融金属の粘性を高め、ビード形状を安定的に保持し、スパッタの発生を低減する重要な作用を有する。さらに、Alは、固液共存温度範囲を小さくして、溶接金属の高温割れ発生の抑制に寄与する。このような効果は、Alの0.001%以上の含有で顕著となるため、Al含有量は0.001%以上が好ましい。しかし、Al含有量が0.10%を超えると、溶融金属の粘性が高くなりすぎて、逆に、スパッタの増加や、ビードが広がらずに融合不良などの欠陥が増加する。そのため、Alを含有させる場合、Al含有量は0.10%以下が好ましい。なお、Al含有量は、より好ましくは0.002~0.090%である。 Al: 0.10% or less Al acts as a deoxidizing agent. Also, Al has an important effect of increasing the viscosity of the molten metal, stably maintaining the bead shape, and reducing the occurrence of spatter. Furthermore, Al reduces the solid-liquid coexistence temperature range and contributes to suppressing the occurrence of hot cracks in the weld metal. Since such an effect becomes remarkable when the Al content is 0.001% or more, the Al content is preferably 0.001% or more. However, if the Al content exceeds 0.10%, the viscosity of the molten metal becomes too high, and conversely, spatter increases and defects such as poor fusion increase without bead spreading. Therefore, when Al is contained, the Al content is preferably 0.10% or less. The Al content is more preferably 0.002-0.090%.
Caは、高温割れの抑制に寄与する元素である。また、Caは、溶融金属中でSと結合し、高融点の硫化物CaSを形成することで、高温割れを抑制する。このような効果は、Caの0.001%以上の含有で顕著となる。一方、Ca含有量が0.010%を超えると、溶接時にアークに乱れが生じ、安定な溶接が困難となる。そのため、Caを含有させる場合、Ca含有量は0.010%以下が好ましい。なお、Ca含有量は、より好ましくは0.002~0.008%である。 Ca: 0.010% or less Ca is an element that contributes to the suppression of hot cracking. In addition, Ca combines with S in the molten metal to form sulfide CaS with a high melting point, thereby suppressing hot cracking. Such an effect becomes remarkable when the content of Ca is 0.001% or more. On the other hand, when the Ca content exceeds 0.010%, arc disturbance occurs during welding, making stable welding difficult. Therefore, when Ca is contained, the Ca content is preferably 0.010% or less. Incidentally, the Ca content is more preferably 0.002 to 0.008%.
REMも、Caと同様、高温割れの抑制に寄与する元素である。また、REMは、強力な脱酸剤であり、溶接金属中でREM酸化物の形態で存在する。REM酸化物は凝固時の核生成サイトとなることで、溶接金属の凝固形態を変化させ、高温割れの抑制に寄与する。このような効果は、REMの0.001%以上の含有で顕著となる。しかし、REM含有量が0.020%を超えると、アークの安定性が低下する。そのため、REMを含有させる場合、REM含有量は0.020%以下が好ましい。なお、REM含有量は、より好ましくは0.002~0.016%である。 REM: 0.020% or less REM, like Ca, is an element that contributes to the suppression of hot cracking. REM is also a strong deoxidizing agent and exists in the form of REM oxides in the weld metal. REM oxides act as nucleation sites during solidification, thereby changing the solidification morphology of the weld metal and contributing to the suppression of hot cracking. Such an effect becomes remarkable when the content of REM is 0.001% or more. However, when the REM content exceeds 0.020%, arc stability decreases. Therefore, when REM is contained, the REM content is preferably 0.020% or less. The REM content is more preferably 0.002-0.016%.
質量%で、C:0.10~0.70%、Si:0.10~1.00%、Mn:15.00~28.00%、P:0.030%以下、S:0.015%以下、Ni:1.00~5.00%、Cr:0.50~4.00%、Mo:2.00%以下、N:0.150%以下およびO:0.050%以下であり、
任意に、
(a)V:0.10%以下、Ti:0.10%以下およびNb:0.10%以下のうちから選んだ1種または2種以上、
ならびに
(b)Cu:1.00%以下、Al:0.10%以下、Ca:0.010%以下およびREM:0.020%以下のうちから選んだ1種または2種以上
のうちの少なくとも一方を含有し、
残部がFe及び不可避的不純物からなる、ワイヤ組成を有するワイヤとすることが好ましい。 The solid wire to be used has the above-described weld metal composition and the above-described weld metal structure so that the weld metal of the T-joint can be formed.
% by mass, C: 0.10-0.70%, Si: 0.10-1.00%, Mn: 15.00-28.00%, P: 0.030% or less, S: 0.015% or less, Ni: 1.00-5.00%, Cr: 0.50-4.00% , Mo: 2.00% or less, N: 0.150% or less, and O: 0.050% or less,
optionally,
(a) one or more selected from V: 0.10% or less, Ti: 0.10% or less, and Nb: 0.10% or less;
and (b) Cu: 1.00% or less, Al: 0.10% or less, Ca: 0.010% or less, and REM: 0.020% or less.
The wire preferably has a wire composition in which the balance is Fe and unavoidable impurities.
また、溶接では、図5に示すような、接合部材1に、所定の角度(40°)を有する開先を付与してもよい。 Then, using a wire having the wire composition described above, gas metal arc welding is preferably performed in a shielding gas to form a multi-layer weld metal. The welding conditions are downward position, current: 150 to 450 A (DCEP), voltage: 20 to 40 V, welding speed: 15 to 60 cm/min, interpass temperature: 100 to 200°C, and shield gas: 80 volumes. It is preferable to satisfy the conditions of %Ar-20% by volume CO 2 at the same time. In order to adjust the strength of the weld metal, it is preferable to adjust the welding heat input for one pass within the range of 1.0 to 3.0 kJ/mm.
Moreover, in welding, as shown in FIG. 5, the joining
2 被接合部材
3 溶接脚長
4 未溶着部
5 溶接金属
7 機械ノッチ
8 仮付け溶接
9 大型溶接継手
11 被接合部材の突合せ溶接継手
12 接合部材の突合せ溶接継手
13 溶着幅
14 隙間
15 スペーサー
16 未溶着部の幅 1 Joined
Claims (15)
- 接合部材の端面が板厚50mm以上の被接合部材の表面に突き合され、前記接合部材と前記被接合部材とを接合するT継手を備える、溶接構造体であって、
前記T継手の溶接脚長および溶着幅のうちの長い方の値であるLが16mm以上であり、
前記T継手の溶接金属が、
質量%で、C:0.10~0.70%、Si:0.10~1.00%、Mn:15.00~28.00%、P:0.030%以下、S:0.015%以下、Ni:1.00~5.00%、Cr:0.50~4.00%、Mo:2.00%以下、N:0.150%以下およびO:0.050%以下であり、残部がFe及び不可避的不純物である、溶接金属組成と、
オーステナイト相が面積%で80%以上である、溶接金属組織と、を有する、溶接構造体。 A welded structure comprising a T-joint in which an end surface of a joining member is butted against a surface of a member to be joined having a plate thickness of 50 mm or more, and which joins the member to be joined and the member to be joined,
L, which is the longer value of the weld leg length and weld width of the T joint, is 16 mm or more,
The weld metal of the T joint is
% by mass, C: 0.10-0.70%, Si: 0.10-1.00%, Mn: 15.00-28.00%, P: 0.030% or less, S: 0.015% or less, Ni: 1.00-5.00%, Cr: 0.50-4.00% , Mo: 2.00% or less, N: 0.150% or less and O: 0.050% or less, the balance being Fe and unavoidable impurities;
A welded structure having a weld metallographic structure in which the austenitic phase is 80% or more by area. - 前記溶接金属組成が、さらに、質量%で、
(a)V:0.10%以下、Ti:0.10%以下およびNb:0.10%以下のうちから選んだ1種または2種以上、
ならびに
(b)Cu:1.00%以下、Al:0.10%以下、Ca:0.010%以下およびREM:0.020%以下のうちから選んだ1種または2種以上
のうちの少なくとも一方を含有する、請求項1に記載の溶接構造体。 The weld metal composition is further, in mass %,
(a) one or more selected from V: 0.10% or less, Ti: 0.10% or less, and Nb: 0.10% or less;
and (b) Cu: 1.00% or less, Al: 0.10% or less, Ca: 0.010% or less, and REM: 0.020% or less. Welded structure according to. - 前記T継手における前記接合部材の端面と前記被接合部材の表面とを突き合わせた面に未溶着部が存在し、かつ、前記接合部材の板厚に対する前記未溶着部の幅の比率である未溶着比率Yが30%以上である、請求項1に記載の溶接構造体。 An unwelded portion exists on the surface of the T joint where the end surface of the joining member and the surface of the member to be joined are butted against each other, and the unwelded portion is a ratio of the width of the unwelded portion to the plate thickness of the joining member. Welded structure according to claim 1, wherein the ratio Y is 30% or more.
- 前記T継手における前記接合部材の端面と前記被接合部材の表面とを突き合わせた面に未溶着部が存在し、かつ、前記接合部材の板厚に対する前記未溶着部の幅の比率である未溶着比率Yが30%以上である、請求項2に記載の溶接構造体。 An unwelded portion exists on the surface of the T joint where the end surface of the joining member and the surface of the member to be joined are butted against each other, and the unwelded portion is a ratio of the width of the unwelded portion to the plate thickness of the joining member. Welded structure according to claim 2, wherein the ratio Y is 30% or more.
- 前記被接合部材が、前記接合部材と交差するように突合せ溶接継手部を有する、請求項1に記載の溶接構造体。 The welded structure according to claim 1, wherein said members to be joined have a butt weld joint portion so as to intersect said members to be joined.
- 前記被接合部材が、前記接合部材と交差するように突合せ溶接継手部を有する、請求項2に記載の溶接構造体。 The welded structure according to claim 2, wherein the members to be joined have a butt weld joint portion so as to intersect the members to be joined.
- 前記被接合部材が、前記接合部材と交差するように突合せ溶接継手部を有する、請求項3に記載の溶接構造体。 The welded structure according to claim 3, wherein the members to be joined have a butt weld joint portion so as to intersect the members to be joined.
- 前記被接合部材が、前記接合部材と交差するように突合せ溶接継手部を有する、請求項4に記載の溶接構造体。 The welded structure according to claim 4, wherein the members to be joined have a butt weld joint portion so as to intersect the members to be joined.
- 前記接合部材が、突合せ溶接継手部を有し、該接合部材の突合せ溶接継手部と前記被溶接部材の突合せ溶接継手部とが交差するように、前記接合部材を、配設してなる、請求項5に記載の溶接構造体。 The joining member has a butt-welded joint portion, and the joining member is arranged so that the butt-welded joint portion of the joining member and the butt-welded joint portion of the member to be welded intersect. Item 6. The welded structure according to item 5.
- 前記接合部材が、突合せ溶接継手部を有し、該接合部材の突合せ溶接継手部と前記被溶接部材の突合せ溶接継手部とが交差するように、前記接合部材を、配設してなる、請求項6に記載の溶接構造体。 The joining member has a butt-welded joint portion, and the joining member is arranged so that the butt-welded joint portion of the joining member and the butt-welded joint portion of the member to be welded intersect. The welded structure according to Item 6.
- 前記接合部材が、突合せ溶接継手部を有し、該接合部材の突合せ溶接継手部と前記被溶接部材の突合せ溶接継手部とが交差するように、前記接合部材を、配設してなる、請求項7に記載の溶接構造体。 The joining member has a butt-welded joint portion, and the joining member is arranged so that the butt-welded joint portion of the joining member and the butt-welded joint portion of the member to be welded intersect. The welded structure according to Item 7.
- 前記接合部材が、突合せ溶接継手部を有し、該接合部材の突合せ溶接継手部と前記被溶接部材の突合せ溶接継手部とが交差するように、前記接合部材を、配設してなる、請求項8に記載の溶接構造体。 The joining member has a butt-welded joint portion, and the joining member is arranged so that the butt-welded joint portion of the joining member and the butt-welded joint portion of the member to be welded intersect. Item 9. The welded structure according to Item 8.
- 前記接合部材の板厚が50mm以上である、請求項1ないし12のいずれかに記載の溶接構造体。 The welded structure according to any one of claims 1 to 12, wherein the plate thickness of the joining member is 50 mm or more.
- 前記接合部材と前記被接合部材との間の隙間が10mm以下である、請求項1ないし12のいずれかに記載の溶接構造体。 The welded structure according to any one of claims 1 to 12, wherein the gap between the joining member and the member to be joined is 10 mm or less.
- 前記接合部材と前記被接合部材との間の隙間が10mm以下である、請求項13に記載の溶接構造体。
14. The welded structure according to claim 13, wherein the gap between the joining member and the member to be joined is 10 mm or less.
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KR (1) | KR20230158578A (en) |
CN (1) | CN117241907A (en) |
TW (1) | TWI823427B (en) |
WO (1) | WO2022265011A1 (en) |
Citations (4)
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WO2013038685A1 (en) * | 2011-09-13 | 2013-03-21 | Jfeスチール株式会社 | Welded structure |
JP2017502842A (en) * | 2013-12-06 | 2017-01-26 | ポスコPosco | High strength weld joint with excellent cryogenic impact toughness and flux cored arc welding wire for this purpose |
JP2018059190A (en) * | 2016-09-30 | 2018-04-12 | 株式会社神戸製鋼所 | Steel component, manufacturing method thereof, and steel sheet for steel component |
WO2020138490A1 (en) * | 2018-12-28 | 2020-07-02 | 日鉄ステンレス株式会社 | Weld structure and method for producing same |
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JP4074524B2 (en) | 2003-01-31 | 2008-04-09 | 新日本製鐵株式会社 | Welded structure with excellent brittle fracture resistance |
JP5144053B2 (en) | 2006-05-12 | 2013-02-13 | Jfeスチール株式会社 | Welded structure with excellent brittle crack propagation stop properties |
CN103796786B (en) | 2011-09-13 | 2015-04-22 | 杰富意钢铁株式会社 | Welded structure |
JP5408396B1 (en) | 2012-05-10 | 2014-02-05 | Jfeスチール株式会社 | Welded structure |
WO2016143354A1 (en) | 2015-03-12 | 2016-09-15 | Jfeスチール株式会社 | Welded structure |
KR102258423B1 (en) | 2016-06-16 | 2021-06-03 | 제이에프이 스틸 가부시키가이샤 | Welded structure having excellent brittle crack arrestability |
TW202022137A (en) * | 2018-12-11 | 2020-06-16 | 日商日本製鐵股份有限公司 | High-strength steel plate with excellent formability, toughness and weldability, and production method thereof having a microstructure including more than 20% of acicular ferrite and more than 10% of martensite |
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Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2013038685A1 (en) * | 2011-09-13 | 2013-03-21 | Jfeスチール株式会社 | Welded structure |
JP2017502842A (en) * | 2013-12-06 | 2017-01-26 | ポスコPosco | High strength weld joint with excellent cryogenic impact toughness and flux cored arc welding wire for this purpose |
JP2018059190A (en) * | 2016-09-30 | 2018-04-12 | 株式会社神戸製鋼所 | Steel component, manufacturing method thereof, and steel sheet for steel component |
WO2020138490A1 (en) * | 2018-12-28 | 2020-07-02 | 日鉄ステンレス株式会社 | Weld structure and method for producing same |
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KR20230158578A (en) | 2023-11-20 |
JPWO2022265011A1 (en) | 2022-12-22 |
TW202300264A (en) | 2023-01-01 |
TWI823427B (en) | 2023-11-21 |
JP7195503B1 (en) | 2022-12-26 |
CN117241907A (en) | 2023-12-15 |
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