WO2022259925A1 - 連続鋳造用のストッパー - Google Patents
連続鋳造用のストッパー Download PDFInfo
- Publication number
- WO2022259925A1 WO2022259925A1 PCT/JP2022/022210 JP2022022210W WO2022259925A1 WO 2022259925 A1 WO2022259925 A1 WO 2022259925A1 JP 2022022210 W JP2022022210 W JP 2022022210W WO 2022259925 A1 WO2022259925 A1 WO 2022259925A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- stopper
- porous refractory
- refractory
- porous
- peripheral surface
- Prior art date
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- 238000009749 continuous casting Methods 0.000 title claims abstract description 22
- 230000002093 peripheral effect Effects 0.000 claims abstract description 35
- 239000011819 refractory material Substances 0.000 claims abstract description 15
- 238000005452 bending Methods 0.000 claims description 13
- 230000035699 permeability Effects 0.000 claims description 11
- 238000005336 cracking Methods 0.000 abstract description 7
- 229910000831 Steel Inorganic materials 0.000 description 18
- 239000010959 steel Substances 0.000 description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 238000005266 casting Methods 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 238000007667 floating Methods 0.000 description 5
- 229910002804 graphite Inorganic materials 0.000 description 5
- 239000010439 graphite Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 239000004927 clay Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000007664 blowing Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000010953 base metal Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D41/00—Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
- B22D41/14—Closures
- B22D41/16—Closures stopper-rod type, i.e. a stopper-rod being positioned downwardly through the vessel and the metal therein, for selective registry with the pouring opening
- B22D41/18—Stopper-rods therefor
- B22D41/186—Stopper-rods therefor with means for injecting a fluid into the melt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D41/00—Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
- B22D41/14—Closures
- B22D41/16—Closures stopper-rod type, i.e. a stopper-rod being positioned downwardly through the vessel and the metal therein, for selective registry with the pouring opening
- B22D41/18—Stopper-rods therefor
Definitions
- the present invention is a gas blowing method that controls the flow rate of molten steel by fitting it from above into a nozzle installed at the bottom of the tundish when the molten steel is discharged from the tundish into the mold.
- the present invention relates to a functional stopper for continuous casting.
- Patent Document 1 As a technique for suppressing the adhesion of inclusions near the fitting portion of the stopper, a technique is known in which a part of the tip region of the stopper is made of a porous refractory material (see Patent Document 1, for example). Also, there is known a configuration in which a through hole is provided in the tip region of the stopper (see, for example, Patent Document 2).
- FIG. 4 of Patent Document 1 when the tip of the stopper is composed of a porous tip portion 76, gas is blown only from the porous tip portion 76, so the vicinity of the fitting portion of the stopper Adhesion of inclusions in can not be suppressed.
- FIG. 3 of Patent Document 1 there is also known a configuration in which a porous tip portion 66 is sandwiched between low-permeability refractory materials in the vertical direction of the tip region of the stopper. When viewed in cross section in the lateral direction, the entire surface is composed of a porous material (porous tip portion 66), so the structural strength is not sufficient. For this reason, there is a possibility that the porous tip portion 66 may crack or peel off due to impact, vibration, or the like during control during casting.
- Patent Document 2 in a configuration in which through holes are provided in the tip region of the stopper, a large number of through holes (for example, a large number of through holes as shown in FIG. 5) are provided to suppress adhesion of alumina inclusions. ) must be provided. Then, there is a problem that manufacturing is complicated and manufacturing cost is high. In addition, there is also a problem in that the air bubbles coming out of the through-holes are not fine air bubbles like the air bubbles coming out of the porous refractory material, and adhesion of inclusions cannot be suppressed. Further, in general, in a configuration in which a through hole is provided, the hole diameter of the through hole is as large as 2 to 5 mm. In this case, the bubble diameter becomes large, and the effect of suppressing adhesion of inclusions cannot be exhibited. In addition, boiling in the mold is likely to occur, and powder entrainment is likely to occur.
- an object of the present invention is to suppress adhesion of inclusions in the vicinity of the fitting portion of the stopper, and to prevent cracking or peeling of the tip region of the stopper due to insufficient strength.
- a stopper for the following continuous casting comprising a cavity for gas circulation in the center in the vertical direction, In at least part of the vertical cross section of the tip side region, a porous refractory having gas permeability is arranged on the outer peripheral surface side, and a refractory material having a higher strength than the porous refractory is arranged on the inner peripheral surface side. , stopper for continuous casting.
- gas bubbles blown into the molten steel from the porous refractory disposed on the outer peripheral surface side of the tip side region of the stopper are drawn into the vicinity of the fitting portion of the stopper by the molten steel.
- air bubbles are supplied to the vicinity of the fitting portion of the stopper, and adhesion of inclusions such as alumina to the vicinity of the fitting portion of the stopper can be suppressed.
- the gas bubbles blown into the molten steel from the porous refractory are finer than the gas bubbles blown into the molten steel through the through-holes.
- the refractory having a higher strength than the porous refractory is arranged on the inner peripheral surface side of the tip side region of the stopper, the tip region of the stopper, especially the tip side region, cracks or peels due to lack of strength. can be prevented.
- FIG. 2 is a cross-sectional view taken along the line AA in FIG. 1, showing one aspect of the arrangement of the porous refractory.
- FIG. 2 is a cross-sectional view taken along the line AA in FIG. 1, showing another aspect of the arrangement of the porous refractories.
- Graph showing the results of a water model test.
- FIG. 1 shows a continuous casting stopper (hereinafter simply referred to as "stopper") 1, which is an embodiment of the present invention, in a vertical cross section.
- FIG. 2 shows a cross section along the line AA of FIG.
- the vertical cross section of the stopper 1 means a vertical cross section passing through the vertical central axis B of the stopper 1 .
- FIG. 1 also shows a virtual nozzle 2 into which the stopper 1 is fitted from above. This nozzle 2 is specifically a nozzle (upper nozzle) installed at the bottom of the tundish.
- the stopper 1 has a cavity 11 for gas circulation in the center in the vertical direction. Then, in at least a part of the vertical cross section of the tip side region C of the stopper 1, a porous refractory 12 having gas permeability on the outer peripheral surface side and a higher strength than the porous refractory 12 on the inner peripheral surface side A refractory (hereinafter referred to as “high-strength refractory”) 13 is arranged.
- the tip side region C of the stopper 1 refers to the tip region above the fitting portion 14 of the stopper 1 with the nozzle 2.
- the tip side region C and the stopper 1 The area below the fitting portion 14 is collectively referred to as a tip area D of the stopper.
- the porous refractory 12 is arranged on the outer peripheral surface side in at least part of the vertical cross section of the tip side region C. Specifically, the porous refractory 12 is the fitting portion 14 of the stopper 1. It is preferable to arrange it in an upper region of 10 mm or more and 250 mm or less. This is based on the water model test results and the like described below.
- FIG 4 shows the results of the water model test.
- the arrangement position of the porous refractory 12, that is, from the fitting portion 14 to the porous was changed, and the floating rate of the air bubbles coming out of the porous refractory 12 into the tundish (TD) was measured.
- the water model test was conducted by adjusting the gap between the fitting portion 14 of the stopper 1 and the fitting portion 21 of the nozzle 2 so that the water flow rate was 0.42 m 3 /min. This water flow rate of 0.42 m 3 /min corresponds to a casting rate of 3 t/min.
- the flow rate of the gas blown into the water from the porous refractory 12 was set to 5 L/min, and the diameter of the bubbles coming out of the porous refractory 12 was set to approximately 0.3 to 1 mm.
- the distance from the fitting portion 14 to the porous refractory 12 means the distance from the fitting portion 14 to the lower end of the porous refractory 12 .
- the floating rate of air bubbles coming out of the porous refractory 12 into the tundish increases.
- a high rate of floating into the tundish means that fewer air bubbles are supplied to the vicinity of the fitting portion 14 . Therefore, from the viewpoint of suppressing adhesion of inclusions in the vicinity of the fitting portion 14, the smaller the distance from the fitting portion 14 to the porous refractory 12, the better.
- the floating rate into the tundish can be suppressed to less than about 80%.
- the distance from the portion 14 to the porous refractory 12 is preferably 250 mm or less.
- the tip side region C in which the porous refractory 12 is arranged in the present embodiment refers to a region up to approximately 250 mm above the fitting portion 14 .
- the distance to the object 12 is more preferably 150 mm or less, and even more preferably 100 mm or less.
- the lower limit of the distance from the fitting portion 14 to the porous refractory 12 is not particularly limited. is preferably 10 mm or more.
- the porous refractory 12 is arranged on the entire periphery of the outer peripheral surface side in at least a part of the vertical cross section of the tip side region C. As shown in FIG.
- the porous refractory 12 By arranging the porous refractory 12 on the entire circumference of the outer peripheral surface side in this way, the gas bubbles blown from the porous refractory 12 can be uniformly supplied to the vicinity of the fitting portion 14 of the stopper 1. .
- the porous refractory 12 instead of arranging the porous refractory 12 on the entire circumference of the outer peripheral surface side, as shown in FIG.
- the porous refractories 12 may be arranged in a dispersed state adjacent to the refractory 13 . Even when the porous refractories 12 are arranged in a dispersed state in this way, the bubbles generated by the gas blown from the porous refractories 12 can be almost uniformly supplied to the vicinity of the fitting portion 14 of the stopper 1 .
- the high-strength refractory 13 is arranged on the outer peripheral surface side, so compared to the case where the porous refractory 12 is arranged on the entire outer peripheral surface side, the tip The effect of preventing the side regions C from cracking or peeling due to insufficient strength can be remarkably exhibited.
- the porous refractory 12 is divided into eight and arranged in a dispersed state, but the number of divisions of the porous refractory 12 is not limited to this. That is, from the viewpoint of uniformly supplying the bubbles generated by the gas blown from the porous refractory 12 to the vicinity of the fitting portion 14 of the stopper 1, it is preferable that the number of divisions of the porous refractory 12 is large. If this is the case, the manufacturing process becomes complicated and the manufacturing cost increases.
- the porous refractory 12 is arranged in one stage in a part of the vertical cross section of the tip side region C, but for example, the stage of the porous refractory 12 in FIG. It is also possible to arrange another stage of the porous refractory 12 as shown in FIG. 2 or FIG. It can also be placed on all sides.
- the materials, physical properties, etc. of the porous refractory 12 and the high-strength refractory 13 will be described.
- alumina-graphite graphite
- the gas permeability (air permeability), pore size, and the like are adjusted.
- the range of air permeability of the porous refractory 12 can be about 2 ⁇ 10 ⁇ 15 M 2 to 5 ⁇ 10 ⁇ 14 M 2 .
- the thickness of the porous refractory 12 (horizontal dimension in the vertical cross section (FIG. 1) of the tip side region C) is 5 mm or more.
- the thickness of the porous refractory 12 is 10 mm or more.
- the height of the porous refractory 12 (the vertical dimension in the vertical cross section of the tip side region C (FIG. 1)) is preferably 15 mm or more.
- the high-strength refractory 13 is used for parts other than the porous refractory 12, and as described above, alumina/graphite (graphite), which is typical as a stopper material, can be used as the material.
- the room-temperature bending strength of the high-strength refractory 13 is preferably 105 or more as an index, where 100 is the room-temperature bending strength of the porous refractory 12 .
- the room temperature bending strength of the refractory disposed on the inner peripheral surface side of the porous refractory 12 is set to 105 or more by setting the room temperature bending strength of the porous refractory 12 to 100, so that the tip side region The effect of preventing C from cracking or peeling due to lack of strength can be remarkably exhibited. It is more preferable that the bending strength at room temperature of the high-strength refractory 13 is 110 or more as an index, where the bending strength at room temperature of the porous refractory 12 is 100.
- the upper limit of the room temperature bending strength of the high-strength refractory 13 is not particularly limited, the upper limit is about 300 in terms of the room temperature bending strength of the porous refractory 12 as 100 in reality.
- the porous refractory 12 has a higher permeability than the high-strength refractory 13 .
- the air permeability of the porous refractory 12 can be 300 or more as an index based on the air permeability of the high-strength refractory 13 as 100 in the measurement based on JIS-R2115.
- the upper limit of the permeability of the high-strength refractory 13 is not particularly limited, but in reality, the upper limit is about 9000 as an index where the permeability of the high-strength refractory 13 is 100.
- the stopper 1 has a cavity 11 for gas circulation in the center in the vertical direction, and the gas supplied to this cavity 11 is blown from the porous refractory 12 into the molten steel. Therefore, the stopper 1 has a gas passageway 15 for allowing gas to flow from the cavity 11 to the porous refractory 12 .
- the gas passage 15 includes a slit-shaped gas pool 15a provided between the inner peripheral surface of the porous refractory 12 and the outer peripheral surface of the high-strength refractory 13, and the gas pool 15a from the cavity 11. It consists of the through-hole 15b which connects. In this embodiment, as shown in FIG.
- the through holes 15b are provided in two stages, and as shown in FIG. 2 and FIG. That is, the gas supplied to the cavity 11 is supplied to the porous refractory 12 via the 16 through-holes 15b and the gas pool 15a, and is blown into the molten steel from the porous refractory 12.
- the gas pool 15a has a bridging portion that partially bridges the inner peripheral surface of the porous refractory 12 and the outer peripheral surface of the high-strength refractory 13.
- the configuration of the gas passage 15 is not limited to the configurations shown in FIGS. 1 to 3.
- the gas may be supplied directly from the through holes 15b to the porous refractory 12 without providing the gas pool 15a.
- the amount of gas blown from the stopper can be in the range of 1 L/min or more and 15 L/min or less.
- Such a stopper 1 arranges the clay for forming the porous refractory 12 and the clay for forming the high-strength refractory 13 at predetermined positions in the forming mold, and pressurizes the gas. It can be obtained by arranging a material that disappears by heat treatment to form the passageway 15 so as to form the shape of the gas passageway 15, molding it, and then heat-treating it.
- the porous refractory 12 is formed as shown in FIG. and the high-strength refractory 13 have a continuous structure without joints.
- the gas bubbles blown into the molten steel from the porous refractory 12 arranged on the outer peripheral surface side of the tip side region C of the stopper 1 are generated by the molten steel. Pulled in around 14.
- air bubbles are supplied to the vicinity of the fitting portion 14 of the stopper, and adhesion of inclusions such as alumina to the vicinity of the fitting portion 14 of the stopper can be suppressed.
- the gas bubbles blown into the molten steel from the porous refractory 12 are finer than the gas bubbles blown into the molten steel through the through-holes.
- the high-strength refractory 13 is arranged on the inner peripheral surface side of the tip side region C of the stopper, the tip region D of the stopper, particularly the tip side region C, is prevented from cracking or peeling due to insufficient strength. can be prevented.
- a continuous casting test for controlling the flow rate of molten steel was performed using the stoppers of the examples and comparative examples shown in Table 1, and the state of the tip region of the stopper and the adhesion of inclusions near the fitting portion of the stopper were evaluated. .
- the continuous casting test was performed under the condition that the number of casting charges (ch) was 6 ch.
- Other casting conditions (casting speed, casting size, etc.) were general conditions.
- Alumina/graphite was used as the material for the porous refractories and high-strength refractories used for the stoppers of the examples and comparative examples.
- the porous refractory material on the outer peripheral surface side was arranged in a region of 20 to 50 mm above the fitting portion of the stopper. That is, in the stoppers of Examples 1 to 3, the height of the porous refractory material on the outer peripheral surface side was set to 30 mm.
- the thickness of the porous refractory on the outer peripheral side is as shown in Table 1.
- the thickness of the porous refractory on the outer peripheral surface side differs in the height direction, but Table 1 shows the minimum thickness.
- the room temperature bending strength of the porous refractory on the outer peripheral surface side and the high-strength refractory on the inner peripheral surface side was measured based on JIS-R2213 using a test piece of 20 ⁇ 20 ⁇ 70 mm. measured by In Table 1, the room-temperature bending strength of the high-strength refractory on the inner peripheral surface side is shown as an index with 100 as the room-temperature bending strength of the porous refractory.
- the state of the tip region of the stopper was evaluated by visually confirming the state of the tip region of the stopper after the continuous casting test.
- the state of adhesion of inclusions near the fitting portion of the stopper was evaluated by measuring the adhesion thickness near the fitting portion of the stopper of each example after the continuous casting test. It was expressed as an index with 100 as the adhesion thickness near the joint.
- the stopper of Comparative Example 1 has a porous refractory disposed only at the tip of the stopper as shown in FIG. 4 of Patent Document 1 above.
- the effect of suppressing the adhesion of inclusions in the vicinity of the fitting portion of the stopper was not obtained, and the adhesion of inclusions in the vicinity of the fitting portion of the stopper increased.
- the stopper of Comparative Example 2 did not have the high-strength refractory placed on the inner peripheral side of the porous refractory as shown in FIG. 3 of Patent Document 1 above. Since the structural strength was not sufficient, the porous refractory part cracked during continuous casting of 6ch, and the tip of the stopper fell off. Therefore, the continuous casting had to be stopped, and the adhesion of inclusions in the vicinity of the fitting portion of the stopper could not be evaluated.
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- Engineering & Computer Science (AREA)
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Abstract
Description
上下方向中心部にガス流通のための空洞を備える連続鋳造用のストッパーであって、
先端側部領域の上下方向断面の少なくとも一部において、外周面側にガス透過性を有する多孔質耐火物、内周面側に前記多孔質耐火物よりも高強度の耐火物が配置されている、連続鋳造用のストッパー。
ここで図3では、多孔質耐火物12を8分割して分散状態で配置しているが、多孔質耐火物12の分割数はこれに限定されるものではない。すなわち、多孔質耐火物12から吹き込まれるガスによる気泡をストッパー1の嵌合部14付近に均一に供給する観点からは、多孔質耐火物12の分割数は多い方がよいが、分割数が多くなると製造が複雑になり製造コストが高くなるので、これらのバランスを考慮して多孔質耐火物12の分割数を適宜決定すればよい。
なお、本実施形態では図1に示すように、多孔質耐火物12を先端側部領域Cの上下方向断面の一部に1段で配置したが、例えば図1の多孔質耐火物12の段の上にもう1段、図2又は図3に示したような多孔質耐火物12の段を配置することもできるし、多孔質耐火物12を先端側部領域Cの上下方向断面の外周面側全部に配置することもできる。
ここで、多孔質耐火物12の厚み(先端側部領域Cの上下方向断面(図1)において横方向の寸法)は5mm以上であることが好ましい。多孔質耐火物12の厚みを5mm以上とすることで、多孔質耐火物12が剥離しにくくなる。また、多孔質耐火物12の厚みを十分に確保できるので、製造しやすいという効果も得られる。多孔質耐火物12の厚みは10mm以上であることがより好ましい。
また、多孔質耐火物12の高さ(先端側部領域Cの上下方向断面(図1)において上下方向の寸法)は15mm以上であることが好ましい。多孔質耐火物12の高さを15mm以上とすることにより、多孔質耐火物12から十分な量のガスを溶鋼中に吹き込むことができる。
また、本実施形態において多孔質耐火物12の通気率は高強度耐火物13の通気率より高い。具体的に多孔質耐火物12の通気率は、JIS‐R2115に基づく測定において高強度耐火物13の通気率を100とする指数で300以上とすることができる。高強度耐火物13の通気率の上限は特に限定されないが、現実的には高強度耐火物13の通気率を100とする指数で9000程度が上限である。
なお、ガス通過経路15の構成は図1から図3に示した構成には限定されず、例えば、ガスプール15aを設けずに貫通孔15bから直接多孔質耐火物12へガスを供給することもできる。ただし、多孔質耐火物12へガスを均一に供給する観点からは、多孔質耐火物12の内周面側にスリット状のガスプールを設けることが好ましい。なお、ストッパーからのガス吹き込み量については、1L/min以上15L/min以下の範囲とすることができる。
比較例2のストッパーは、上記特許文献1の第3図のように多孔質耐火物の内周側に高強度耐火物を配置しなかったものである。構造上強度が十分ではないため、6chの連続鋳造の途中で、多孔質耐火物部分が割れてストッパーの先端部分が脱落した。そのため、連続鋳造を中止せざるを得なくなり、ストッパーの嵌合部付近における介在物の付着は評価できなかった。
11 空洞
12 多孔質耐火物
13 高強度耐火物
14 嵌合部
15 ガス通過経路
15a ガスプール(ガス通過経路)
15b 貫通孔(ガス通過経路)
2 ノズル(上ノズル)
21 嵌合部
B ストッパーの上下方向中心軸
C ストッパーの先端側部領域
D ストッパーの先端領域
Claims (4)
- 上下方向中心部にガス流通のための空洞を備える連続鋳造用のストッパーであって、
先端側部領域の上下方向断面の少なくとも一部において、外周面側にガス透過性を有する多孔質耐火物、内周面側に前記多孔質耐火物よりも高強度の耐火物が配置されている、連続鋳造用のストッパー。 - 前記内周面側に配置される耐火物の常温曲げ強度は、前記多孔質耐火物の常温曲げ強度を100とする指数で105以上である、請求項1に記載の連続鋳造用のストッパー。
- 前記先端側部領域の上下方向断面の少なくとも一部において、前記多孔質耐火物は、前記外周面側の全周に配置、又は前記外周面側において前記多孔質耐火物よりも高強度の耐火物と隣接する分散状態で配置されている、請求項1又は請求項2に記載の連続鋳造用のストッパー。
- 前記先端側部領域の上下方向断面の少なくとも一部において、前記多孔質耐火物の厚みが5mm以上である、請求項1から請求項3のいずれか一項に記載の連続鋳造用のストッパー。
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
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CN202280037307.1A CN117377541A (zh) | 2021-06-10 | 2022-05-31 | 连续铸造用的塞棒 |
BR112023022704A BR112023022704A2 (pt) | 2021-06-10 | 2022-05-31 | Rolha para lingotamento contínuo |
EP22820107.5A EP4354064A1 (en) | 2021-06-10 | 2022-05-31 | Stopper for continuous casting |
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JP2021097589A JP2022189169A (ja) | 2021-06-10 | 2021-06-10 | 連続鋳造用のストッパー |
JP2021-097589 | 2021-06-10 |
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WO2022259925A1 true WO2022259925A1 (ja) | 2022-12-15 |
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PCT/JP2022/022210 WO2022259925A1 (ja) | 2021-06-10 | 2022-05-31 | 連続鋳造用のストッパー |
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EP (1) | EP4354064A1 (ja) |
JP (1) | JP2022189169A (ja) |
CN (1) | CN117377541A (ja) |
BR (1) | BR112023022704A2 (ja) |
TW (1) | TWI837692B (ja) |
WO (1) | WO2022259925A1 (ja) |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
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JPS50155314U (ja) * | 1974-06-11 | 1975-12-23 | ||
JPH026040A (ja) | 1987-11-25 | 1990-01-10 | Vesuvius Internatl Corp | ガス透過性ストッパロッド |
JPH0381061A (ja) * | 1989-08-03 | 1991-04-05 | Vesuvius Fr Sa | 液体流量調節用ストッパロッド |
JPH03110048A (ja) | 1989-09-25 | 1991-05-10 | Akechi Ceramics Kk | タンディッシュストッパー |
JPH0631410A (ja) * | 1992-07-15 | 1994-02-08 | Nippon Steel Corp | 連続鋳造用ロングストッパー |
JPH10510474A (ja) * | 1994-11-28 | 1998-10-13 | ベシュビウス フランス ソシエテ アノニム | 気体不透過性の層を形成することのできる外層を有する停止ロッド |
KR20160051354A (ko) * | 2014-11-03 | 2016-05-11 | 주식회사 포스코 | 스토퍼 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
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ATE278493T1 (de) * | 2001-06-12 | 2004-10-15 | Vesuvius Crucible Co | Stopfenstange für zuverlässiges gaseinblasen |
DE602007005493D1 (de) * | 2007-11-24 | 2010-05-06 | Refractory Intellectual Prop | Stopfenstange |
US12023730B2 (en) * | 2018-12-25 | 2024-07-02 | Krosakiharima Corporation | Stopper for continuous casting and continuous casting method |
JP7182496B2 (ja) * | 2019-03-12 | 2022-12-02 | 黒崎播磨株式会社 | ノズル及びノズルとストッパーの構造体 |
-
2021
- 2021-06-10 JP JP2021097589A patent/JP2022189169A/ja active Pending
-
2022
- 2022-05-31 WO PCT/JP2022/022210 patent/WO2022259925A1/ja active Application Filing
- 2022-05-31 BR BR112023022704A patent/BR112023022704A2/pt unknown
- 2022-05-31 CN CN202280037307.1A patent/CN117377541A/zh active Pending
- 2022-05-31 EP EP22820107.5A patent/EP4354064A1/en active Pending
- 2022-06-07 TW TW111121031A patent/TWI837692B/zh active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
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JPS50155314U (ja) * | 1974-06-11 | 1975-12-23 | ||
JPH026040A (ja) | 1987-11-25 | 1990-01-10 | Vesuvius Internatl Corp | ガス透過性ストッパロッド |
JPH0381061A (ja) * | 1989-08-03 | 1991-04-05 | Vesuvius Fr Sa | 液体流量調節用ストッパロッド |
JPH03110048A (ja) | 1989-09-25 | 1991-05-10 | Akechi Ceramics Kk | タンディッシュストッパー |
JPH0631410A (ja) * | 1992-07-15 | 1994-02-08 | Nippon Steel Corp | 連続鋳造用ロングストッパー |
JPH10510474A (ja) * | 1994-11-28 | 1998-10-13 | ベシュビウス フランス ソシエテ アノニム | 気体不透過性の層を形成することのできる外層を有する停止ロッド |
KR20160051354A (ko) * | 2014-11-03 | 2016-05-11 | 주식회사 포스코 | 스토퍼 |
Also Published As
Publication number | Publication date |
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CN117377541A (zh) | 2024-01-09 |
JP2022189169A (ja) | 2022-12-22 |
TW202306667A (zh) | 2023-02-16 |
TWI837692B (zh) | 2024-04-01 |
EP4354064A1 (en) | 2024-04-17 |
BR112023022704A2 (pt) | 2024-01-16 |
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