WO2022107753A1 - 金属部材の処理方法及び処理装置 - Google Patents
金属部材の処理方法及び処理装置 Download PDFInfo
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- WO2022107753A1 WO2022107753A1 PCT/JP2021/042043 JP2021042043W WO2022107753A1 WO 2022107753 A1 WO2022107753 A1 WO 2022107753A1 JP 2021042043 W JP2021042043 W JP 2021042043W WO 2022107753 A1 WO2022107753 A1 WO 2022107753A1
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- gas
- atmosphere gas
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/40—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using liquids, e.g. salt baths, liquid suspensions
- C23C8/42—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using liquids, e.g. salt baths, liquid suspensions only one element being applied
- C23C8/48—Nitriding
- C23C8/50—Nitriding of ferrous surfaces
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B5/00—Muffle furnaces; Retort furnaces; Other furnaces in which the charge is held completely isolated
- F27B5/06—Details, accessories, or equipment peculiar to furnaces of these types
- F27B5/16—Arrangements of air or gas supply devices
- F27B2005/161—Gas inflow or outflow
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D7/00—Forming, maintaining, or circulating atmospheres in heating chambers
- F27D7/02—Supplying steam, vapour, gases, or liquids
- F27D2007/023—Conduits
Definitions
- the present invention relates to a method and a treatment apparatus for a metal member that activates the surface of the metal member prior to subjecting the metal member to a gas nitriding treatment or a gas soft nitriding treatment.
- gas nitriding treatment or gas soft nitriding treatment is widely applied in order to improve fatigue resistance, wear resistance, and corrosion resistance.
- the immobilization film (oxide, etc.) present on the surface of the member causes the surface of metal members such as nitrogen and carbon to be present.
- metal members such as nitrogen and carbon
- a method using a chloride-based compound (activator) typified by a marcomizing treatment for example, a method using a chloride-based compound (activator) typified by a marcomizing treatment is known.
- the chloride vinyl chloride resin, ammonium chloride, methylene chloride and the like are used.
- the chloride is put into a processing furnace together with a metal member and heated. By this heating, the chloride is decomposed to form HCl.
- the generated HCl destroys (denatures) the passivation film on the surface of the metal member and activates the surface. This makes the diffusion infiltration treatment such as nitriding and carburizing in the next step more reliable.
- the generated HCl reacts with ammonia contained in the atmospheric gas during the gas nitriding treatment or the gas soft nitriding treatment to generate ammonium chloride.
- This ammonium chloride can not only be deposited in the processing furnace or in the exhaust system and cause trouble, but also remain on the surface of the metal member (work) and cause deterioration of corrosion resistance and fatigue strength.
- NF 3 fluorine compound belonging to the same halogen group instead of chloride
- Patent Document 1 JP-A-3-44457
- the surface activation of the metal member by the fluorine compound (NF 3 ) as described above requires advanced treatment for detoxifying NF 3 and HF that may be contained in the exhaust gas, which hinders the spread of the method. ing.
- Patent Document 2 Japanese Patent No. 4861703
- Patent Document 3 Japanese Patent Application No. 9-38341
- Patent Document 4 Japanese Patent Application Laid-Open No. 10-219418
- acetylene is introduced into the furnace, and HCN generated in the process of the reaction process starting from its thermal decomposition reduces the immobilized film on the surface of the metal member and activates the surface (patented).
- No. 4861703 Patent Document 2
- acetone vapor is introduced into the furnace, and HCN generated in the process of the reaction process starting from its thermal decomposition reduces the passivation film on the surface of the metal member and activates the surface (Japanese Patent Application No. flat). 9-38341A (Patent Document 3), JP-A-10-219418 (Patent Document 4)).
- Patent Document 5 a method for activating a metal surface using a carbon dioxide compound is described in Patent No. 5826748 (Patent Document 5).
- Patent Document 5 also refers to a method using formamide, which is a liquid at room temperature, in addition to a method using urea or acetamide, which is solid at room temperature.
- Non-Patent Document 1 It has been known since the 1970s that CO gas forms HCN in a furnace ("Heat Treatment", Vol. 18, No. 5, pp. 255-262 (Kiyomitsu Otomo) (Non-Patent Document 1)). Based on this finding, it seems that carbon compounds and carbon dioxide compounds have been selected and studied as CO gas generated in the furnace in the process of the reaction process.
- HCN carbon compound, carbon dioxide compound
- HCl chloride
- Carbon compounds and carbon dioxide compounds which are gases at room temperature, have the advantage of being able to be introduced into the furnace while controlling the appropriate amount using a mass flow controller.
- it is not easy to handle the gas cylinder there is a problem that the gas cylinder takes up a lot of space, and it is necessary to take measures against the risk of gas leakage from the piping.
- some types of carbon compounds and carbon dioxide compounds are incompatible with the mass flow controller (control of the introduction amount cannot be preferably carried out).
- Carbon compounds and carbon dioxide compounds that are liquid at room temperature are generally gasified before being introduced into the furnace in order to be introduced into the furnace while controlling the appropriate amount (Patent No. 4861703 (Patent No. 4861703).
- Patent No. 4861703 Patent No. 4861703
- paragraph 0010 of Document 2 "Since liquid acetone is used at normal temperature and pressure, a device for introducing acetone vapor is required").
- Patent Document 5 describes that liquid formamide is directly introduced into the hot zone of a tube furnace (small experimental furnace) by a probe (Patent No. 5826748 (Patent Document 5). See paragraph 1981).
- this method is difficult to apply to a general production furnace. This is because, in a configuration in which the probe is directly communicated to a general production furnace, the formamide in the probe is vaporized to cause backflow due to the large degree of heat dissipation in the production furnace, and the desired amount can be introduced into the furnace. Because it cannot be fulfilled. Further, there is a concern that the backflow formamide precipitates in an undesired pipe, causing clogging of the pipe.
- the present inventor has placed an organic solvent (carbon compound, carbon dioxide compound, plus chloride) that is liquid at room temperature in the activated atmosphere gas introduction pipe in a state where the activated atmosphere gas is continuously introduced into the processing furnace. It was found that the occurrence of the situation where the organic solvent vaporizes and flows back can be effectively suppressed even if the processing furnace is at a high temperature by adding a compound).
- organic solvent carbon compound, carbon dioxide compound, plus chloride
- the inventor of the present invention can realize the addition of an appropriate amount of the organic solvent at a timing suitable for the state in the processing furnace by intermittently adding the organic solvent which is liquid at room temperature in a plurality of times. I found out.
- An object of the present invention is to provide a method and a treatment apparatus for treating a metal member, which can practically activate the surface of the metal member by using an organic solvent in a liquid state.
- the present invention It is a method of processing metal parts using a processing furnace.
- the process of charging metal parts into the processing furnace and the process of charging metal parts The activation atmosphere gas introduction step of introducing the activation atmosphere gas into the processing furnace, and the activation atmosphere gas introduction step.
- the first heating step of heating the activated atmosphere gas in the processing furnace to the first temperature and After the first heating step, a main atmosphere gas introduction step of introducing a nitriding atmosphere gas or a soft nitriding atmosphere gas into the processing furnace, and a step of introducing the nitriding atmosphere gas.
- the treatment method is characterized in that, during the above period, the organic solvent in a liquid state is intermittently charged into the activated atmosphere gas introduction pipe a plurality of times.
- a liquid organic solvent (a chloride in addition to a carbon compound and a carbon dioxide compound) is placed in the activated atmosphere gas introduction pipe in a state where the activated atmosphere gas is continuously introduced into the processing furnace.
- a liquid organic solvent a chloride in addition to a carbon compound and a carbon dioxide compound
- the first heating temperature is 400 ° C to 500 ° C.
- the occurrence of the situation where the organic solvent vaporizes and flows back is effectively suppressed.
- the activated atmosphere gas contains ammonia gas
- the organic solvent is a compound containing at least one kind of hydrocarbon.
- HCN generated in the process of the reaction process starting from the thermal decomposition of the organic solvent can reduce the passivation film on the surface of the metal member and effectively activate the surface.
- the organic solvent is one of formamide, xylene and toluene.
- the organic solvent is added at a substantially uniform rate over 1 second to 2 minutes (preferably 10 seconds to 2 minutes) in a single dose of 10 to 80 ml, with an interval of 10 minutes or more. It was confirmed by the present inventor in an actual production furnace that it is effective to put it in 2 to 6 times.
- the activated atmosphere gas contains ammonia gas
- the organic solvent is a compound containing at least one kind of chlorine.
- HCl generated in the process of the reaction process starting from the thermal decomposition of the organic solvent can reduce the passivation film on the surface of the metal member and effectively activate the surface.
- the organic solvent is any one of trichlorethylene, tetrachlorethylene and tetrachloroethane.
- the organic solvent is added at a substantially uniform rate over 1 second to 2 minutes (preferably 10 seconds to 2 minutes) in a single dose of 10 to 80 ml, with an interval of 10 minutes or more. It was confirmed by the present inventor in an actual production furnace that it is effective to put it in 2 to 6 times.
- inventions excluding the condition of introducing a liquid organic solvent into the activated atmosphere gas introduction pipe are also subject to protection under the present patent.
- the present invention It is a method of processing metal parts using a processing furnace.
- the process of charging metal parts into the processing furnace and the process of charging metal parts The activation atmosphere gas introduction step of introducing the activation atmosphere gas into the processing furnace, and the activation atmosphere gas introduction step.
- the first heating step of heating the activated atmosphere gas in the processing furnace to the first temperature and After the first heating step, a main atmosphere gas introduction step of introducing a nitriding atmosphere gas or a soft nitriding atmosphere gas into the processing furnace, and a step of introducing the nitriding atmosphere gas.
- a second heating step of heating the nitrided atmosphere gas or the soft nitrided atmosphere gas in the processing furnace to a second temperature in order to nitride or softly nitrid the metal member. Equipped with The treatment method is characterized in that, during the first heating step, the organic solvent in a liquid state is intermittently charged into the treatment furnace a plurality of times.
- the present invention by intermittently charging the organic solvent in a liquid state in a plurality of times, it is possible to realize the charging of an appropriate amount of the organic solvent at a timing suitable for the state in the processing furnace.
- a metal member charging mechanism for charging metal members into the processing furnace Atmospheric gas introduction piping that is arranged so as to communicate with the processing furnace and introduces atmospheric gas into the processing furnace.
- An organic solvent injection device that intermittently injects a liquid organic solvent into the atmosphere gas introduction pipe multiple times.
- a heating device that heats the atmospheric gas in the processing furnace to a predetermined temperature, It is a processing device for a metal member, which is characterized by being provided with.
- a liquid organic solvent (a chloride can be used in addition to a carbon compound or a carbon dioxide compound) in the atmosphere gas introduction pipe in a state where the activation atmosphere gas is continuously introduced into the processing furnace. ) Is added, it is possible to effectively suppress the occurrence of a situation in which the organic solvent vaporizes and flows back even if the temperature of the processing furnace is high.
- the organic solvent charging device has a check valve on the upstream side of the atmospheric gas introduction pipe.
- a dehumidifying device is provided in the middle of the atmosphere gas introduction pipe.
- the metal member charging mechanism is configured to move the metal member in and out of the processing furnace in the horizontal direction.
- the atmospheric gas is an activated atmospheric gas, and it is preferable that a second processing furnace for nitriding or soft nitriding is provided separately from the processing furnace.
- the activation treatment and the nitriding treatment or the soft nitriding treatment can be carried out by separate processing furnaces, there is no risk of precipitation of the organic solvent in the nitriding treatment or the soft nitriding treatment. Further, since the nitriding treatment or the soft nitriding treatment and the activation treatment for the next metal member can be performed at the same time, the productivity is also high (compared to simply preparing two processing devices). Since it is not necessary to add an organic solvent to the processing furnace for nitriding or soft nitriding, the cost will be reduced accordingly).
- inventions excluding the condition of introducing a liquid organic solvent into the activated atmosphere gas introduction pipe are also subject to protection under the present patent.
- a metal member charging mechanism for charging metal members into the processing furnace Atmospheric gas input piping that is arranged so as to communicate with the processing furnace and introduces atmospheric gas into the processing furnace.
- An organic solvent charging device that intermittently charges a liquid organic solvent into the processing furnace multiple times.
- a heating device that heats the atmospheric gas in the processing furnace to a predetermined temperature, It is a processing device for a metal member, which is characterized by being provided with.
- the present invention by intermittently charging the organic solvent in a liquid state in a plurality of times, it is possible to realize the charging of an appropriate amount of the organic solvent at a timing suitable for the state in the processing furnace.
- the present invention it is possible to add an appropriate amount of the organic solvent at a timing suitable for the state in the processing furnace by intermittently adding the organic solvent in a liquid state in a plurality of times.
- a liquid organic solvent (carbon compound or carbon nitrogen compound) is contained in the activated atmosphere gas introduction pipe in a state where the activated atmosphere gas is continuously introduced into the processing furnace.
- chloride is also acceptable), which can effectively suppress the occurrence of a situation in which the organic solvent vaporizes and flows back even if the temperature of the processing furnace is high.
- FIG. 1 is a schematic view of a metal member processing apparatus 1 (nitriding processing apparatus) according to the first embodiment of the present invention.
- the processing apparatus 1 of the present embodiment includes a circulation type processing furnace 2, and uses only two types of gases, ammonia and ammonia decomposition gas, as the gas to be introduced into the circulation type processing furnace 2. ing.
- the ammonia decomposition gas is a gas also called AX gas, which is a mixed gas composed of nitrogen and hydrogen in a ratio of 1: 3.
- FIG. 2 An example of the cross-sectional structure of the circulation type processing furnace 2 is shown in FIG.
- a cylinder 202 called a retort is arranged in a furnace wall (also called a bell) 201 in which a heater (heating device) 201h is built, and a cylinder 204 ( ⁇ 700 mm ⁇ 1000 mm) called an internal retort is further inside.
- the heater 201h is conceptually exemplified, and the actual arrangement mode varies).
- the introduced gas supplied from the gas introduction pipe 205 passes around the metal member as the object to be treated, and then is between the two cylinders 202 and 204 by the action of the stirring fan 203. It circulates through space.
- 206 is a gas exhaust device with flare
- 207 is a thermocouple
- 208 is a lid for cooling work
- 209 is a fan for cooling work.
- the circulation type processing furnace 2 is also called a horizontal gas nitriding furnace, and its structure itself is known.
- the metal member S is, for example, stainless steel or heat-resistant steel, for example, a unison ring or an internal crank which is a turbocharger component for an automobile, an engine valve for an automobile, or the like.
- the SUS304 plate material (50 mm ⁇ 50 mm ⁇ 1 mm) and the SUS301S plate material (50 mm ⁇ 50 mm ⁇ 1 mm) are used.
- the processing furnace 2 of the processing device 1 of the present embodiment includes a furnace opening / closing lid 7 (metal member charging mechanism), a stirring fan 8, a stirring fan drive motor 9, and an atmosphere gas concentration detecting device. 3, a nitride potential adjuster 4, a programmable logic controller 31, and an in-core gas introduction unit 20 are provided.
- the stirring fan 8 is arranged in the processing furnace 2 and rotates in the processing furnace 2 to stir the atmosphere in the processing furnace 2.
- the stirring fan drive motor 9 is connected to the stirring fan 8 so as to rotate the stirring fan 8 at an arbitrary rotation speed.
- the atmosphere gas concentration detecting device 3 is composed of a sensor that can detect the hydrogen concentration or the ammonia concentration in the processing furnace 2 as the atmosphere gas concentration in the furnace.
- the detection main body of the sensor communicates with the inside of the processing furnace 2 via the atmosphere gas detection pipe 12.
- the atmosphere gas detection pipe 12 is formed by a path that directly connects the sensor main body of the atmosphere gas concentration detection device 3 and the processing furnace 2, and disposes of the gas in the furnace connected to the exhaust gas combustion decomposition device 41 on the way.
- the pipe 40 is connected. As a result, the atmospheric gas is distributed into the discarded gas and the gas supplied to the atmospheric gas concentration detecting device 3.
- the atmosphere gas concentration detection device 3 detects the atmosphere gas concentration in the furnace, and then outputs an information signal including the detected concentration to the nitride potential regulator 4.
- the nitriding potential regulator 4 has an in-core nitriding potential arithmetic unit 13 and a gas flow rate output adjusting device 30. Further, the programmable logic controller 31 has a gas introduction amount control device 14 and a parameter setting device 15.
- the in-core nitriding potential calculation device 13 calculates the nitriding potential in the processing furnace 2 based on the hydrogen concentration or the ammonia concentration detected by the atmospheric gas concentration detection device 3. Specifically, a formula for calculating the nitriding potential programmed according to the actual gas introduced into the furnace is incorporated, and the nitriding potential is calculated from the value of the atmospheric gas concentration in the furnace.
- the parameter setting device 15 is composed of, for example, a touch panel, and can set and input the total flow rate of the gas introduced into the furnace, the gas type, the processing temperature, the target nitriding potential, and the like. Each setting parameter value input for setting is transmitted to the gas flow rate output adjusting device 30.
- the gas flow rate output adjusting device 30 sets the nitriding potential calculated by the in-core nitriding potential calculation device 13 as the output value, sets the target nitriding potential (set nitriding potential) as the target value, and sets the ammonia gas and the ammonia decomposition gas. Control is carried out with each introduction amount as an input value. More specifically, for example, it is possible to carry out control for changing the introduction ratio of each other while keeping the total flow rate of the introduction amount of ammonia gas and the introduction amount of ammonia decomposition gas constant.
- the output value of the gas flow rate output adjusting device 30 is transmitted to the gas introduction amount control device 14.
- the gas introduction amount control device 14 has a first supply amount control device 22 (specifically, a mass flow controller) for ammonia gas and a second supply amount control device 26 for ammonia decomposition gas in order to realize the introduction amount of each gas. (Specifically, a control signal is sent to each of the mass flow controller).
- a first supply amount control device 22 specifically, a mass flow controller
- a second supply amount control device 26 for ammonia decomposition gas in order to realize the introduction amount of each gas.
- the in-firer introduction gas supply unit 20 of the present embodiment includes a first in-firet introduction gas supply unit 21 for ammonia gas, a first supply amount control device 22, and a first supply valve 23. Further, the in-firer introduction gas supply unit 20 of the present embodiment includes a second in-core introduction gas supply unit 25 for ammonia decomposition gas (AX gas), a second supply amount control device 26, and a second supply valve 27. ,have.
- AX gas ammonia decomposition gas
- the ammonia gas and the ammonia decomposition gas are mixed in the furnace introduction gas introduction pipe 29 before entering the processing furnace 2.
- the first furnace introduction gas supply unit 21 is formed of, for example, a tank filled with the first furnace introduction gas (ammonia gas in this example).
- the first supply amount control device 22 is formed by a mass flow controller, and is interposed between the first furnace introduction gas supply unit 21 and the first supply valve 23.
- the opening degree of the first supply amount control device 22 changes according to the control signal output from the gas introduction amount control device 14. Further, the first supply amount control device 22 detects the supply amount from the first furnace introduction gas supply unit 21 to the first supply valve 23, and sends an information signal including the detected supply amount to the gas introduction amount control device 14. It is designed to output to.
- the control signal can be used for correction of control by the gas introduction amount control device 14.
- the first supply valve 23 is formed by a solenoid valve that switches an open / closed state according to a control signal output by the gas introduction amount control device 14, and is provided on the downstream side of the first supply amount control device 22.
- the second furnace introduction gas supply unit 25 is formed of, for example, a tank filled with the second furnace introduction gas (ammonia decomposition gas in this example).
- the second furnace introduction gas supply unit 25 may be a pipe arranged from a pyrolysis furnace that thermally decomposes ammonia gas to generate ammonia decomposition gas.
- the second supply amount control device 26 is formed by a mass flow controller, and is interposed between the second furnace introduction gas supply unit 25 and the second supply valve 27.
- the opening degree of the second supply amount control device 26 changes according to the control signal output from the gas introduction amount control device 14. Further, the second supply amount control device 26 detects the supply amount from the second furnace introduction gas supply unit 25 to the second supply valve 27, and sends an information signal including the detected supply amount to the gas introduction amount control device 14. It is designed to output to.
- the control signal can be used for correction of control by the gas introduction amount control device 14.
- the second supply valve 27 is formed by a solenoid valve that switches the open / closed state according to the control signal output by the gas introduction amount control device 14, and is provided on the downstream side of the second supply amount control device 26.
- the processing apparatus 1 of the present embodiment uses the gas introduced into the first furnace (ammonia gas) and the gas introduced into the second furnace (ammonia decomposition gas) in order to activate the surface of the metal member S as a pretreatment for the nitriding treatment. It can be introduced into the processing furnace 2 as an activating atmosphere gas. Further, during the pretreatment, the heater 201h can heat the activated atmosphere gas in the processing furnace 2 to a first temperature (specific examples will be described later, for example, 350 ° C to 550 ° C).
- the surface of the metal member S is nitrided and hardened, so that the gas introduced into the first furnace (ammonia gas) and the gas introduced into the second furnace (AX gas) are used. ) Can be introduced into the processing furnace 2 while being feedback-controlled as a nitrided atmosphere gas. Further, during the pretreatment, the heater 201h can heat the nitriding atmosphere gas in the processing furnace 2 to a second temperature (specific examples will be described later, for example, 520 ° C to 650 ° C).
- the processing apparatus 1 of the present embodiment includes an organic solvent charging device 300 for intermittently charging a liquid organic solvent into the furnace introduction gas introduction pipe 29 (atmospheric gas introduction pipe) a plurality of times. ing.
- the organic solvent charging device 300 includes a tank 301 filled with an organic solvent (specific examples will be described later), an organic solvent charging pipe 302 extending from the container 301 to the inside of the furnace introduction gas introduction pipe 29, and the organic solvent. It has a pump 303 provided in the middle of the charging pipe 302 and sending out the organic solvent in the container 301 toward the in-core introduction gas introduction pipe 29, and a check valve 304 provided on the downstream side of the pump 303. ing.
- the pump 303 intermittently dispenses a predetermined amount of organic solvent (for example, 0 to 100 ml) at a predetermined delivery rate (for example, 0 to 5000 ml / min) at predetermined intervals (for example, 0 to 120 minutes). It can be sent out to the furnace introduction gas introduction pipe 29 multiple times.
- the operating conditions of such a pump 303 are controlled by the organic solvent input control device 305.
- the organic solvent is charged at a substantially uniform rate over 1 second to 2 minutes (preferably 10 to 2 minutes) in a single dose of 10 to 80 ml for 10 minutes or more. It is designed to be thrown 2 to 6 times at intervals.
- the tip of the organic solvent input pipe 302 penetrates the pipe wall of the gas introduction pipe 29 (for example, a cylindrical pipe having a diameter of 27 mm) in the furnace at a substantially right angle, and the gas introduction pipe 29 in the furnace has a pipe wall. It extends into the pipe (for example, it protrudes about 300 mm toward the central axis (the illustrated dimensions may vary depending on the size of the processing furnace 2).
- the in-core gas introduction pipe 29 extends into the processing furnace 2.
- the tip of the cylinder is an inclined surface (inclined surface of approximately 45 °) (the shorter one is the lower side and the tip is the upper side), but the tip of the organic solvent input pipe 302 is perpendicular to the axis of the organic solvent input pipe 302. It is in the form of being cut in various planes.
- the check valve 304 is a general-purpose check valve for a medium in a liquid state.
- the possibility that the organic solvent in the liquid state is undesirably vaporized is extremely small, no special specification is required.
- ammonia gas and ammonia decomposition gas are introduced into the processing furnace 2 at a set flow rate from the furnace introduction gas supply unit 20 via the furnace introduction gas introduction pipe 29 (atmosphere gas introduction pipe) as the activation atmosphere gas.
- This set flow rate can be set and input in the parameter setting device 15, and is controlled by the first supply amount control device 22 (mass flow controller) and the second supply amount control device 26 (mass flow controller).
- the stirring fan drive motor 9 is driven to rotate the stirring fan 8 to stir the atmosphere in the processing furnace 2.
- the furnace introduction gas introduction pipe 29 (atmosphere gas introduction pipe) in a state where the organic solvent charging device 300 continues to introduce the activated atmosphere gas (ammonia gas and ammonia decomposition gas) into the processing furnace 2.
- the organic solvent in a liquid state is intermittently added to the water a plurality of times.
- the conditions for charging the organic solvent by the organic solvent charging device 300 can be set and input in the parameter setting device 15, and are controlled by the pump 303.
- the liquid organic solvent introduced into the furnace introduction gas introduction pipe 29 is extruded into the activated atmosphere gas (ammonia gas and ammonia decomposition gas) in the liquid state in the processing furnace. Reach within 2. Then, it is vaporized in the processing furnace 2 and thermally decomposed.
- the surface of the metal member S can be activated by the above pretreatment.
- the organic solvent is a compound containing at least one kind of hydrocarbon
- HCN generated in the process of the reaction process starting from the thermal decomposition of the organic solvent demobilizes the surface of the metal member S.
- the film is reduced to effectively activate the surface.
- the organic solvent is a compound containing at least one kind of chlorine
- HCl generated in the process of the reaction process starting from the thermal decomposition of the organic solvent reduces the passivation film on the surface of the metal member S. The surface is effectively activated.
- the organic solvent when the organic solvent is added intermittently a plurality of times, the organic solvent is additionally added during the progress of the pretreatment, so that the effect of adding the organic solvent is remarkably enhanced, and the metal member.
- the effect of activating the surface of S is remarkably enhanced.
- the circulation type processing furnace 2 is heated to a desired nitriding processing temperature by the heater 201h.
- the introduction of the activated atmosphere gas (ammonia gas and ammonia decomposition gas) into the processing furnace 2 is continued as the introduction of the nitrided atmosphere gas (as a gas type, the introduction amount is continued. Can be changed).
- a mixed gas of ammonia gas and ammonia decomposition gas is introduced into the processing furnace 2 from the furnace introduction gas supply unit 20 at a set initial flow rate for nitriding treatment.
- This set initial flow rate can also be set and input in the parameter setting device 15, and is controlled by the first supply amount control device 22 and the second supply amount control device 26 (both are mass flow controllers). Further, the stirring fan drive motor 9 is driven to rotate the stirring fan 8 to stir the atmosphere in the processing furnace 2.
- the in-core nitriding potential calculation device 13 of the nitriding potential regulator 4 calculates the nitriding potential in the furnace (at first, the value is extremely high (because there is no hydrogen in the furnace), but the decomposition of ammonia gas (hydrogen generation)). Decreases as it progresses), and it is determined whether or not the sum of the target nitriding potential and the reference deviation value has been exceeded. This reference deviation value can also be set and input in the parameter setting device 15.
- the nitriding potential regulator 4 When it is determined that the calculated value of the nitriding potential in the furnace is less than the sum of the target nitriding potential and the reference deviation value, the nitriding potential regulator 4 introduces the gas introduced into the furnace via the gas introduction amount control device 14. Starts control of.
- the in-core nitriding potential calculation device 13 of the nitriding potential regulator 4 calculates the in-core nitriding potential based on the input hydrogen concentration signal or ammonia concentration signal. Then, the gas flow rate output adjusting device 30 sets the nitriding potential calculated by the in-core nitriding potential calculation device 13 as the output value, sets the target nitriding potential (set nitriding potential) as the target value, and introduces the gas into the furnace.
- PID control is performed with the input value of. Specifically, in the PID control, for example, a control is carried out in which the total flow rate of the introduced amount of ammonia gas and the introduced amount of ammonia decomposition gas is kept constant and the introduction ratio of each is changed. In the PID control, each setting parameter value set and input by the parameter setting device 15 is used. As the setting parameter value, for example, different values are prepared depending on the value of the target nitriding potential.
- the gas flow rate output adjusting device 30 controls the amount of each introduced gas in the furnace as a result of the PID control. Specifically, the gas flow rate output adjusting device 30 determines the flow rate of each gas, and the output value is transmitted to the gas introduction amount control device 14.
- the gas introduction amount control device 14 sends a control signal to the first supply amount control device 22 for ammonia gas and the second supply amount control device 26 for ammonia decomposition gas, respectively, in order to realize the introduction amount of each gas.
- the nitriding potential in the furnace can be stably controlled in the vicinity of the target nitriding potential.
- the surface of the metal member S can be subjected to nitriding treatment with extremely high quality.
- the pretreatment temperature was 420 ° C.
- the set flow rates of the ammonia gas and the ammonia decomposition gas introduced as the activating atmosphere gas were 35 L / min (constant) and 5 L / min (constant), respectively.
- the duration of the pretreatment was set to 1 hour, and the organic solvent was added at a substantially uniform rate over 1 minute in a single dose of 20 ml, and was added 4 times at intervals of 14 minutes.
- the first charging start of the organic solvent is considered to be the timing when the temperature in the processing furnace 2 reaches 420 ° C., and the pretreatment is completed 14 minutes after the completion of the fourth charging of the organic solvent. (See Fig. 3).
- the nitriding temperature is 580 ° C.
- the set initial flow rate of the ammonia gas introduced as the nitriding atmosphere gas is 17 L / min
- the set initial flow rate of the ammonia decomposition gas introduced as the nitriding atmosphere gas is 23 L / min. It was set to min.
- the duration of the nitriding process was set to 5 hours
- the target nitriding potential was set to 1.5
- the introduction flow rate of the nitriding atmosphere gas was feedback-controlled.
- the processing furnace 2 (and the metal member S) was cooled by using the lid 208 for the cooling work and the fan 209 for the cooling work (see FIG. 2).
- the thickness of the nitrided layer formed on the surface of the metal member S was measured by observing the vicinity of the surface of the cut metal member S with an optical microscope. The average value of the measured values is shown in the table below.
- the addition of the organic solvent 80 ml was changed to be added only once at a substantially uniform rate over 1 minute, and the timing of the start of the addition was set so that the temperature inside the processing furnace 2 was 420 ° C. It was the timing when it reached. Other conditions were the same as those in the above embodiment. Then, the thickness of the nitrided layer formed on the surface of the metal member S was measured by observing the vicinity of the surface of the cut metal member S with an optical microscope. The average value of the measured values is shown in the table below.
- the ease of nitriding (easiness of invasion of nitrogen atoms) in the subsequent nitriding treatment may differ depending on the level of the pretreatment temperature.
- the pretreatment temperature (first temperature) of 300 ° C. to 550 ° C. the plate material (50 mm ⁇ 50 mm ⁇ 1 mm) of SUS316 is used as the metal member S, and the other conditions are the same as in the above embodiment, and the surface of the metal member S is used.
- the thickness of the formed nitride layer was measured by observing the vicinity of the surface of the cut metal member S with an optical microscope. The average value of the measured values is shown in the table below. As you can see from the table.
- a pretreatment temperature in the range of 400 ° C to 500 ° C was suitable.
- the introduction gas introduction pipe 29 (introduction gas introduction pipe 29) in a state where the introduction of the activated atmosphere gas (ammonia gas and the ammonia decomposition gas) into the processing furnace 2 is continued.
- the organic solvent charging device 300 charges a liquid organic solvent (chloride may be used in addition to carbon compounds and carbon dioxide compounds) into the atmosphere gas introduction pipe), so that the temperature of the processing furnace 2 is high. However, it is possible to effectively suppress the occurrence of a situation in which the organic solvent vaporizes and flows back.
- the organic solvent charging device 300 intermittently charges the organic solvent in a liquid state in a plurality of times, so that the timing matches the state in the processing furnace 2. It is possible to realize the addition of an appropriate amount of organic solvent. As a result, since the organic solvent can be additionally added during the progress of the pretreatment, the effect of adding the organic solvent is remarkably enhanced, and the effect of activating the surface of the metal member S is remarkably enhanced. Specifically, by controlling the pump 303, the organic solvent is charged at a substantially uniform rate over 1 second to 2 minutes in a single dose of 10 to 80 ml, with an interval of 10 minutes or more. It can be thrown up to 6 times.
- the organic solvent charging device 300 has a check valve 304 on the upstream side of the in-core introduction gas introduction pipe 29 (atmosphere gas introduction pipe). As a result, the backflow of the organic solvent is prevented, and an appropriate amount of the organic solvent can be added with higher accuracy.
- the metal member S is taken in and out of the processing furnace 2 in the horizontal direction via the furnace opening / closing lid 7. As a result, even when the organic solvent precipitates, the possibility that the precipitate and the metal member S come into contact with each other is relatively small.
- the pretreatment temperature (first heating temperature) is set within the range of 400 ° C. to 500 ° C. According to the temperature range, while the activation treatment of the metal member S proceeds suitably, the occurrence of a situation in which the organic solvent vaporizes and flows back is effectively suppressed.
- the activated atmosphere gas may contain ammonia gas
- the organic solvent may be a compound containing at least one kind of hydrocarbon.
- HCN generated in the process of the reaction process starting from the thermal decomposition of the organic solvent can reduce the passivation film on the surface of the metal member S and effectively activate the surface.
- the organic solvent is any of formamide, xylene and toluene. In these cases, it is effective that the organic solvent is added at a substantially uniform rate over 1 second to 2 minutes in a single dose of 10 to 80 ml, and is added 2 to 6 times at intervals of 10 minutes or more. It was confirmed by the inventor of the present invention in an actual production furnace.
- the activated atmosphere gas may contain ammonia gas
- the organic solvent may be a compound containing at least one kind of chlorine.
- HCl generated in the process of the reaction process starting from the thermal decomposition of the organic solvent can reduce the passivation film on the surface of the metal member S and effectively activate the surface.
- the organic solvent is any one of trichlorethylene, tetrachlorethylene and tetrachloroethane. In these cases, it is effective that the organic solvent is added at a substantially uniform rate over 1 second to 2 minutes in a single dose of 10 to 80 ml, and is added 2 to 6 times at intervals of 10 minutes or more. It was confirmed by the inventor of the present invention in an actual production furnace.
- FIG. 4 is a schematic view of a modified example of the processing device 1.
- the dehumidifying device 331 is provided on the upstream side of the first supply amount control device 22 for ammonia gas (an example in the middle of the atmosphere gas introduction pipe), and is used for ammonia decomposition gas.
- a dehumidifying device 335 is provided on the upstream side of the second supply amount control device 26 (an example in the middle of the atmosphere gas introduction pipe).
- the introduction gas supply unit 25 in the second furnace is a pipe arranged from a pyrolysis furnace that thermally decomposes ammonia gas to generate ammonia decomposition gas
- a dehumidifying device is located upstream of the thermal decomposition furnace.
- Ammonia gas which is a raw material for ammonia decomposition gas, is dehumidified
- the ammonia gas after being dehumidified by the dehumidifying device on the upstream side of the first supply amount control device 22 is the heat.
- the dehumidifying device is distributed and supplied to the decomposition furnace, the one dehumidifying device is sufficient.
- FIG. 6 is a schematic diagram of a further modification of the processing device 1.
- the two processing devices 1'and 1 are linked.
- the first processing device 1' is used for the activation processing, and the atmospheric gas detection pipe 12, the atmospheric gas concentration detection device 3, the in-core nitriding potential calculation device 13, and the in-core nitriding potential calculation device 13 are used for the above-mentioned processing device 1. Can be omitted.
- the second processing device 1 is used for the nitriding treatment, and the organic solvent charging device 300 may be omitted from the above-mentioned processing device 1.
- the mobile furnace 400 (vacuum furnace or atmosphere furnace) for transporting the metal member S whose pretreatment has been completed by the first treatment device 1'to the second treatment device 1" is the first treatment device. It is movably provided from the vicinity region of the furnace opening / closing lid 7 of 1'to the vicinity region of the furnace opening / closing lid 7 of the second processing device 1".
- the first in-firer introduction gas supply unit 21 for ammonia gas
- the second in-core introduction gas supply unit for ammonia gas decomposition gas are used.
- 25 is common.
- the activation treatment can be performed by the processing furnace 2 of the first processing device 1'and the nitriding treatment can be performed by the processing furnace 2 of another second processing device 1 ", the second There is no possibility that the organic solvent will precipitate during the nitriding treatment in the processing furnace 2 of the processing apparatus 1 ”.
- the nitriding treatment in the processing furnace 2 of the second processing device 1 "and the activation treatment of the next metal member S in the processing furnace 2 of the first processing device 1' are simultaneously performed. Because it can be done, productivity is also high.
- FIG. 7 is a schematic view of a metal member processing device 501 (soft nitriding processing device) according to the second embodiment of the present invention.
- the processing apparatus 501 of the present embodiment also has the same circulation type processing furnace 2 as the processing apparatus 1 of the first embodiment, but as a gas to be introduced into the circulation type processing furnace 2. , Ammonia, ammonia decomposition gas, and carbon dioxide gas are used.
- the third furnace introduction gas supply unit 561 for carbon dioxide gas, the third supply amount control device 562, and the third A supply valve 563 is added.
- the third furnace introduction gas supply unit 561 is formed of, for example, a tank filled with the third furnace introduction gas (carbon dioxide gas in this example).
- the third supply amount control device 562 is also formed by a mass flow controller, and is interposed between the third furnace introduction gas supply unit 561 and the third supply valve 563.
- the opening degree of the third supply amount control device 562 changes according to the control signal output from the gas introduction amount control device 14. Further, the third supply amount control device 562 detects the supply amount from the third furnace introduction gas supply unit 561 to the third supply valve 563, and sends an information signal including the detected supply amount to the gas introduction amount control device 14. It is designed to output to.
- the control signal can be used for correction of control by the gas introduction amount control device 14.
- the third supply valve 563 is formed by a solenoid valve that switches the open / closed state according to the control signal output by the gas introduction amount control device 14, and is provided on the downstream side of the third supply amount control device 562.
- the ammonia gas, the ammonia decomposition gas, and the carbon dioxide gas are mixed in the furnace introduction gas introduction pipe 29 before entering the processing furnace 2.
- the gas flow rate output adjusting device 30 sets the nitriding potential calculated by the in-core nitriding potential calculation device 13 of the nitriding potential regulator 4 as the output value, sets the target nitriding potential (set nitriding potential) as the target value, and uses ammonia gas. Control is performed by using each introduction amount of ammonia decomposition gas as an input value (the introduction amount of carbon dioxide gas is constant). More specifically, for example, it is possible to carry out control for changing the introduction ratio of each other while keeping the total flow rate of the introduction amount of ammonia gas and the introduction amount of ammonia decomposition gas constant. The output value of the gas flow rate output adjusting device 30 is transmitted to the gas introduction amount control device 14.
- the gas introduction amount control device 14 has a first supply amount control device 22 (specifically, a mass flow controller) for ammonia gas and a second supply amount control device 26 for ammonia decomposition gas in order to realize the introduction amount of each gas.
- a control signal is sent to (specifically, a mass flow controller) and a third supply amount control device 562 (specifically, a mass flow controller) for carbon dioxide gas, respectively.
- the gas introduced into the first furnace (ammonia gas) and the gas introduced into the second furnace (ammonia) are used to activate the surface of the metal member S.
- (Decomposition gas) can be introduced into the processing furnace 2 as an activating atmosphere gas.
- the heater 201h can heat the activated atmosphere gas in the processing furnace 2 to a first temperature (specific examples will be described later, for example, 350 ° C to 550 ° C).
- a certain amount of gas (carbon dioxide gas) introduced into the third furnace is used as the soft nitride atmosphere gas in order to softly nitride and harden the surface of the metal member S.
- the gas introduced into the first furnace (ammonia gas) and the gas introduced into the second furnace (AX gas) can be introduced into the processing furnace 2 while being controlled by feedback (variation control).
- the heater 201h can heat the nitriding atmosphere gas in the processing furnace 2 to a second temperature (specific examples will be described later, for example, 520 ° C to 650 ° C).
- FIG. 7 Other configurations of the processing device 501 of the present embodiment are substantially the same as those of the processing device 1 of the first embodiment.
- FIG. 7 the same parts as those in the first embodiment are designated by the same reference numerals. Further, detailed description of the same parts as those of the first embodiment of the present embodiment will be omitted.
- the metal member S to be soft-nitrided in the present embodiment is also, for example, stainless steel or heat-resistant steel, for example, a unison ring or an internal crank which is a turbocharger component for an automobile, an engine valve for an automobile, or the like.
- a SUS304 plate material 50 mm ⁇ 50 mm ⁇ 1 mm
- a SUS301S plate material 50 mm ⁇ 50 mm ⁇ 1 mm
- ammonia gas and ammonia decomposition gas as activated atmosphere gas are introduced into the processing furnace 2 at a set flow rate from the furnace introduction gas supply unit 520 via the furnace introduction gas introduction pipe 29 (atmosphere gas introduction pipe).
- This set flow rate can be set and input in the parameter setting device 15, and is controlled by the first supply amount control device 22 (mass flow controller) and the second supply amount control device 26 (mass flow controller).
- the stirring fan drive motor 9 is driven to rotate the stirring fan 8 to stir the atmosphere in the processing furnace 2.
- the furnace introduction gas introduction pipe 29 (atmosphere gas introduction pipe) in a state where the organic solvent charging device 300 continues to introduce the activated atmosphere gas (ammonia gas and ammonia decomposition gas) into the processing furnace 2.
- the organic solvent in a liquid state is intermittently added to the water a plurality of times.
- the conditions for charging the organic solvent by the organic solvent charging device 300 can be set and input in the parameter setting device 15, and are controlled by the pump 303.
- the liquid organic solvent introduced into the furnace introduction gas introduction pipe 29 is extruded into the activated atmosphere gas (ammonia gas and ammonia decomposition gas) in the liquid state in the processing furnace. Reach within 2. Then, it is vaporized in the processing furnace 2 and thermally decomposed.
- the surface of the metal member S can be activated by the above pretreatment.
- the organic solvent is a compound containing at least one kind of hydrocarbon
- HCN generated in the process of the reaction process starting from the thermal decomposition of the organic solvent demobilizes the surface of the metal member S.
- the film is reduced to effectively activate the surface.
- the organic solvent is a compound containing at least one kind of chlorine
- HCl generated in the process of the reaction process starting from the thermal decomposition of the organic solvent reduces the passivation film on the surface of the metal member S. The surface is effectively activated.
- the organic solvent when the organic solvent is added intermittently a plurality of times, the organic solvent is additionally added during the progress of the pretreatment, so that the effect of adding the organic solvent is remarkably enhanced, and the metal member.
- the effect of activating the surface of S is remarkably enhanced.
- the circulation type processing furnace 2 is heated to a desired soft nitriding processing temperature by the heater 201h.
- the introduction of the activated atmosphere gas into the processing furnace 2 is started. That is, the introduction of the ammonia gas and the ammonia decomposition gas is continued as the introduction of the nitrided atmosphere gas, while the introduction of the carbon dioxide gas is started.
- a mixed gas of ammonia gas, ammonia decomposition gas, and carbon dioxide gas is introduced into the processing furnace 2 from the furnace introduction gas supply unit 20 at a set initial flow rate for soft nitriding treatment.
- This set initial flow rate can also be set and input in the parameter setting device 15, and is controlled by the first supply amount control device 22, the second supply amount control device 26, and the third supply amount control device 562 (all are mass flow controllers). .. Further, the stirring fan drive motor 9 is driven to rotate the stirring fan 8 to stir the atmosphere in the processing furnace 2.
- the in-core nitriding potential calculation device 13 of the nitriding potential regulator 4 calculates the nitriding potential in the furnace (at first, the value is extremely high (because there is no hydrogen in the furnace), but the decomposition of ammonia gas (hydrogen generation)). Decreases as it progresses), and it is determined whether or not the sum of the target nitriding potential and the reference deviation value has been exceeded. This reference deviation value can also be set and input in the parameter setting device 15.
- the nitriding potential regulator 4 When it is determined that the calculated value of the nitriding potential in the furnace is less than the sum of the target nitriding potential and the reference deviation value, the nitriding potential regulator 4 introduces the gas introduced into the furnace via the gas introduction amount control device 14. Starts control of.
- the in-core nitriding potential calculation device 13 of the nitriding potential regulator 4 calculates the in-core nitriding potential based on the input hydrogen concentration signal or ammonia concentration signal. Then, the gas flow rate output adjusting device 30 sets the nitriding potential calculated by the in-core nitriding potential calculation device 13 as the output value, sets the target nitriding potential (set nitriding potential) as the target value, and introduces the gas into the furnace.
- PID control is performed with the input value of. Specifically, in the PID control, for example, a control is carried out in which the introduction ratio of each other is changed while the total amount of the introduction amount of the ammonia gas and the introduction amount of the ammonia decomposition gas is kept constant. In the PID control, each setting parameter value set and input by the parameter setting device 15 is used. As the setting parameter value, for example, different values are prepared depending on the value of the target nitriding potential.
- the gas flow rate output adjusting device 30 controls the amount of each introduced gas in the furnace as a result of the PID control. Specifically, the gas flow rate output adjusting device 30 determines the flow rate of each gas, and the output value is transmitted to the gas introduction amount control device 14.
- the gas introduction amount control device 14 has a first supply amount control device 22 for ammonia gas, a second supply amount control device 26 for ammonia decomposition gas, and a third supply for carbon dioxide gas in order to realize the introduction amount of each gas.
- a control signal is sent to and from the quantity control device 562, respectively.
- the nitriding potential in the furnace can be stably controlled in the vicinity of the target nitriding potential.
- the surface of the metal member S can be subjected to nitriding treatment with extremely high quality.
- the pretreatment temperature was 420 ° C.
- the set flow rates of the ammonia gas and the ammonia decomposition gas introduced as the activating atmosphere gas were 35 L / min (constant) and 5 L / min (constant), respectively.
- the duration of the pretreatment was set to 1 hour, and the organic solvent was added at a substantially uniform rate over 1 minute in a single dose of 20 ml, and was added 4 times at intervals of 14 minutes.
- the first charging start of the organic solvent is considered to be the timing when the temperature in the processing furnace 2 reaches 420 ° C., and the pretreatment is completed 14 minutes after the completion of the fourth charging of the organic solvent. (See Fig. 3).
- the soft nitride temperature is 580 ° C.
- the set initial flow rate of the ammonia gas introduced as the soft nitride atmosphere gas is 17 L / min
- the set initial flow rate of the ammonia decomposition gas introduced as the soft nitride atmosphere gas is. , 23 L / min
- the set flow rate (constant) of the carbon dioxide gas introduced as the soft nitride atmosphere gas was set to 2 L / min.
- the duration of the soft nitriding treatment was set to 5 hours
- the target nitriding potential was set to 1.5
- the introduction flow rate of the soft nitriding atmosphere gas was feedback-controlled.
- the processing furnace 2 (and the metal member S) was cooled by using the lid 208 for the cooling work and the fan 209 for the cooling work (see FIG. 2).
- the thickness of the soft nitride layer formed on the surface of the metal member S was measured by observing the vicinity of the surface of the cut metal member S with an optical microscope. The average value of the measured values is shown in the table below.
- the addition of the organic solvent 80 ml was changed to be added only once at a substantially uniform rate over 1 minute, and the timing of the start of the addition was set so that the temperature inside the processing furnace 2 was 420 ° C. It was the timing when it reached. Other conditions were the same as those in the above embodiment. Then, the thickness of the soft nitride layer formed on the surface of the metal member S was measured by observing the vicinity of the surface of the cut metal member S with an optical microscope. The average value of the measured values is shown in the table below.
- the introduction gas introduction pipe 29 in the furnace in a state where the activation atmosphere gas (ammonia gas and ammonia decomposition gas) is continuously introduced into the processing furnace 2.
- the organic solvent charging device 300 can be used even if the temperature of the processing furnace 2 is high. It is possible to effectively suppress the occurrence of a situation in which the organic solvent vaporizes and flows back.
- the organic solvent charging device 300 intermittently charges the organic solvent in a liquid state in a plurality of times, so that the organic solvent is added at a timing commensurate with the state in the processing furnace 2. It is possible to realize the addition of an appropriate amount of solvent. As a result, since the organic solvent can be additionally added during the progress of the pretreatment, the effect of adding the organic solvent is remarkably enhanced, and the effect of activating the surface of the metal member S is remarkably enhanced. Specifically, by controlling the pump 303, the organic solvent is charged at a substantially uniform rate over 1 second to 2 minutes in a single dose of 10 to 80 ml, with an interval of 10 minutes or more. It can be thrown up to 6 times.
- the organic solvent charging device 300 has a check valve 304 on the upstream side of the in-core introduction gas introduction pipe 29 (atmosphere gas introduction pipe). As a result, the backflow of the organic solvent is prevented, and an appropriate amount of the organic solvent can be added with higher accuracy.
- the metal member S is taken in and out of the processing furnace 2 in the horizontal direction via the furnace opening / closing lid 7. As a result, even when the organic solvent precipitates, the possibility that the precipitate and the metal member S come into contact with each other is relatively small.
- the pretreatment temperature (first heating temperature) is set within the range of 400 ° C. to 500 ° C. According to the temperature range, while the activation treatment of the metal member S proceeds suitably, the occurrence of a situation in which the organic solvent vaporizes and flows back is effectively suppressed.
- the activated atmosphere gas may contain ammonia gas
- the organic solvent may be a compound containing at least one kind of hydrocarbon.
- HCN generated in the process of the reaction process starting from the thermal decomposition of the organic solvent can reduce the passivation film on the surface of the metal member S and effectively activate the surface.
- the organic solvent is any of formamide, xylene and toluene. In these cases, it is effective that the organic solvent is added at a substantially uniform rate over 1 second to 2 minutes in a single dose of 10 to 80 ml, and is added 2 to 6 times at intervals of 10 minutes or more. It was confirmed by the inventor of the present invention in an actual production furnace.
- the activated atmosphere gas may contain ammonia gas
- the organic solvent may be a compound containing at least one kind of chlorine.
- HCl generated in the process of the reaction process starting from the thermal decomposition of the organic solvent can reduce the passivation film on the surface of the metal member S and effectively activate the surface.
- the organic solvent is any one of trichlorethylene, tetrachlorethylene and tetrachloroethane. In these cases, it is effective that the organic solvent is added at a substantially uniform rate over 1 second to 2 minutes in a single dose of 10 to 80 ml, and is added 2 to 6 times at intervals of 10 minutes or more. It was confirmed by the inventor of the present invention in an actual production furnace.
- FIG. 8 is a schematic view of a modified example of the processing device 501.
- the dehumidifying device 331 is provided on the upstream side of the first supply amount control device 22 for ammonia gas (an example in the middle of the atmosphere gas introduction pipe), and is used for ammonia decomposition gas.
- a dehumidifying device 335 is provided on the upstream side of the second supply amount control device 26 (an example in the middle of the atmosphere gas introduction pipe).
- the introduction gas supply unit 25 in the second furnace is a pipe arranged from a pyrolysis furnace that thermally decomposes ammonia gas to generate ammonia decomposition gas
- a dehumidifying device is located upstream of the thermal decomposition furnace.
- Ammonia gas which is a raw material for ammonia decomposition gas, is dehumidified
- the ammonia gas after being dehumidified by the dehumidifying device on the upstream side of the first supply amount control device 22 is the heat.
- the dehumidifying device is distributed and supplied to the decomposition furnace, the one dehumidifying device is sufficient.
- FIG. 9 is a schematic diagram of a further modification of the processing device 501.
- the two processing devices 501'and 501 "are linked.
- the first processing device 501' is used for the activation treatment, and the atmospheric gas detection pipe 12, the atmospheric gas concentration detection device 3, the in-core nitride potential calculation device 13, and the in-core nitriding potential calculation device 13 are used for the above-mentioned processing device 501.
- the third supply amount control device 562 and the third supply valve 563 may be omitted.
- the mobile furnace 400 (vacuum furnace or atmosphere furnace) for transporting the metal member S whose pretreatment has been completed by the first treatment device 501'to the second treatment device 501' is the first treatment device. It is movably provided from the vicinity region of the furnace opening / closing lid 7 of 501'to the vicinity region of the furnace opening / closing lid 7 of the second processing apparatus 501 ".
- the first furnace introduction gas supply unit 21 (tank) for ammonia gas and the second furnace introduction gas supply unit for ammonia gas decomposition gas 25 (tank or piping) is common.
- the soft nitriding treatment can be performed by the processing furnace 2 of another second processing device 501'. There is no possibility that an organic solvent will precipitate during the soft nitriding treatment in the processing furnace 2 of the 2 processing apparatus 501.
- the soft nitriding treatment in the processing furnace 2 of the second processing device 501 "and the activation treatment of the next metal member S in the processing furnace 2 of the first processing device 501' are performed at the same time. Since it can be carried out, productivity is also high.
- Processing device 1'1st processing device 1 "2nd processing device 3 Atmospheric gas concentration detection device 4 Nitride potential adjuster 7 Furnace opening / closing lid 8 Stirring fan 9 Stirring fan drive motor 12 Atmosphere gas detection piping 13 In-furnace nitriding potential calculation device 14 Gas introduction amount control device 15 Parameter setting device 20 In-combustion introduction gas supply unit 21 1st in-combustion introduction gas supply unit 22 1st supply amount control device 23 1st supply valve 25 2nd in-core introduction gas supply unit 26 2nd Supply amount control device 27 2nd supply valve 29 In-core gas introduction pipe 30 Gas flow output adjustment device 31 Programmable logic controller 40 In-core gas waste pipe 41 Exhaust gas combustion decomposition device 201h Heater 202 Cylindrical 203 Stirring fan 204 Cylindrical 205 Gas introduction pipe 206 Gas exhaust device 208 Lid 209 Fan 300 Organic solvent input device 301 Tank 302 Organic solvent input pipe 303 Pump 304 Check valve 305 Organic solvent input control device 331 Dehumidifying device
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Abstract
Description
処理炉を用いた金属部材の処理方法であって、
処理炉内に金属部材を投入する金属部材投入工程と、
前記処理炉内に活性化雰囲気ガスを導入する活性化雰囲気ガス導入工程と、
前記処理炉内の活性化雰囲気ガスを第1温度に加熱する第1加熱工程と、
前記第1加熱工程の後、前記処理炉内に窒化雰囲気ガスまたは軟窒化雰囲気ガスを導入する主雰囲気ガス導入工程と、
前記金属部材を窒化または軟窒化するために、前記処理炉内の窒化雰囲気ガスまたは軟窒化雰囲気ガスを第2温度に加熱する第2加熱工程と、
を備え、
前記活性化雰囲気ガス導入工程において、前記活性化雰囲気ガスは、活性化雰囲気ガス配管を介して前記処理炉内に導入されるようになっており、
前記第1加熱工程の少なくとも一部の期間中、前記活性化雰囲気ガス導入工程が同時に実施されるようになっており、
前記期間中、液体状態の有機溶剤が、前記活性化雰囲気ガス導入配管内に断続的に複数回投入される
ことを特徴とする処理方法
である。
処理炉を用いた金属部材の処理方法であって、
処理炉内に金属部材を投入する金属部材投入工程と、
前記処理炉内に活性化雰囲気ガスを導入する活性化雰囲気ガス導入工程と、
前記処理炉内の活性化雰囲気ガスを第1温度に加熱する第1加熱工程と、
前記第1加熱工程の後、前記処理炉内に窒化雰囲気ガスまたは軟窒化雰囲気ガスを導入する主雰囲気ガス導入工程と、
前記金属部材を窒化または軟窒化するために、前記処理炉内の窒化雰囲気ガスまたは軟窒化雰囲気ガスを第2温度に加熱する第2加熱工程と、
を備え、
前記第1加熱工程中に、液体状態の有機溶剤が、前記処理炉内に断続的に複数回投入される
ことを特徴とする処理方法
である。
処理炉と、
前記処理炉内に金属部材を投入するための金属部材投入機構と、
前記処理炉内に連通するように配設され雰囲気ガスを前記処理炉内に導入する雰囲気ガス導入配管と、
前記雰囲気ガス導入配管内に液体状態の有機溶剤を断続的に複数回投入する有機溶剤投入装置と、
前記処理炉内の雰囲気ガスを所定の温度に加熱する加熱装置と、
を備えたことを特徴とする金属部材の処理装置
である。
処理炉と、
前記処理炉内に金属部材を投入するための金属部材投入機構と、
前記処理炉内に連通するように配設され雰囲気ガスを前記処理炉内に導入する雰囲気ガス投入配管と、
前記処理炉内に液体状態の有機溶剤を断続的に複数回投入する有機溶剤投入装置と、
前記処理炉内の雰囲気ガスを所定の温度に加熱する加熱装置と、
を備えたことを特徴とする金属部材の処理装置
である。
図1は、本発明の第1実施形態による金属部材の処理装置1(窒化処理装置)の概略図である。図1に示すように、本実施形態の処理装置1は、循環型処理炉2を備えており、当該循環型処理炉2内へ導入するガスとして、アンモニアとアンモニア分解ガスの2種類のみを用いている。アンモニア分解ガスとは、AXガスとも呼ばれるガスで、1:3の比率の窒素と水素とからなる混合ガスである。
循環型処理炉2の断面構造例を、図2に示す。図2において、ヒータ(加熱装置)201hが内蔵された炉壁(ベルとも呼ばれる)201の中に、レトルトと呼ばれる円筒202が配置され、更にその内側に内部レトルトと呼ばれる円筒204(φ700mm×1000mm)が配置されている(図2において、ヒータ201hは概念的に例示されており、実際の配置態様は様々である)。ガス導入管205から供給される導入ガスは、図中の矢印に示されるように、被処理品としての金属部材の周囲を通過した後、攪拌扇203の作用によって2つの円筒202、204間の空間を通過して循環する。206は、フレア付きのガス排気装置であり、207は、熱電対であり、208は冷却作業用の蓋であり、209は、冷却作業用のファンである。当該循環型処理炉2は、横型ガス窒化炉とも呼ばれており、その構造自体は公知のものである。
金属部材Sは、例えばステンレス鋼または耐熱鋼であって、例えば自動車用のターボチャージャー部品であるユニゾンリングやインターナルクランクまたは自動車用のエンジンバルブ等である。もっとも、以下の実施例では、SUS304の板材(50mm×50mm×1mm)とSUS301Sの板材(50mm×50mm×1mm)とが用いられている。
図1に示すように、本実施形態の処理装置1の処理炉2には、炉開閉蓋7(金属部材投入機構)と、攪拌ファン8と、攪拌ファン駆動モータ9と、雰囲気ガス濃度検出装置3と、窒化ポテンシャル調節計4と、プログラマブルロジックコントローラ31と、炉内導入ガス供給部20と、が設けられている。
本実施形態の処理装置1は、その新規な特徴として、炉内導入ガス導入配管29(雰囲気ガス導入配管)内に液体状態の有機溶剤を断続的に複数回投入する有機溶剤投入装置300を備えている。
次に、本実施形態の処理装置1の作用について説明する。まず、炉開閉蓋7(金属部材投入機構)を介して、被処理品としての金属部材Sが循環型処理炉2内に水平方向に投入される。そして、ヒータ201hによって、循環型処理炉2が加熱される。
その後、ヒータ201hによって、循環型処理炉2が所望の窒化処理温度に加熱される。一方、本実施形態では、処理炉2内への活性化雰囲気ガス(アンモニアガス及びアンモニア分解ガス)の導入が、窒化雰囲気ガスの導入として継続される(ガス種としては継続されるが導入量は変更され得る)。具体的には、炉内導入ガス供給部20からアンモニアガスとアンモニア分解ガスとの混合ガスが、窒化処理用の設定初期流量で処理炉2内へ導入される。この設定初期流量も、パラメータ設定装置15において設定入力可能であり、第1供給量制御装置22及び第2供給量制御装置26(共にマスフローコントローラ)によって制御される。また、攪拌ファン駆動モータ9が駆動されて攪拌ファン8が回転し、処理炉2内の雰囲気を攪拌する。
本実施形態の処理装置1を用いて、以下の6種類の有機溶剤の投入について、実用上の効果が検証された。ホルムアミド、キシレン及びトルエンは、炭化水素を含有する液体状態の化合物の例である。トリクロロエチレン、テトラクロロエチレン及びテトラクロロエタンは、塩素を含有する液体状態の化合物の例である。
前処理温度の高低によって、その後の窒化処理における窒化のし易さ(窒素原子の侵入のし易さ)が異なり得る。300℃~550℃の前処理温度(第1温度)について、SUS316の板材(50mm×50mm×1mm)を金属部材Sとし、その他の条件については前記実施例と同一として、金属部材Sの表面に形成された窒化層厚さが、切断された金属部材Sの表面近傍を光学顕微鏡観察することより測定された。当該測定値の平均値が、以下の表に記載されている。当該表から分かるように。400℃~500℃の範囲の前処理温度が好適であった。
以上のような本実施形態の処理装置1によれば、処理炉2内への活性化雰囲気ガス(アンモニアガス及びアンモニア分解ガス)の導入を継続している状態の炉内導入ガス導入配管29(雰囲気ガス導入配管)内に、有機溶剤投入装置300が液体状態の有機溶剤(炭素化合物や炭窒素化合物に加えて塩化物でも可)を投入することで、処理炉2の温度が高温であっても当該有機溶剤が気化して逆流するという事態の発生を効果的に抑制できる。
図4は、処理装置1の変形例の概略図である。図4に示すように、当該変形例では、アンモニアガス用の第1供給量制御装置22の上流側(雰囲気ガス導入配管の途中の一例)に脱湿装置331が設けられ、アンモニア分解ガス用の第2供給量制御装置26の上流側(雰囲気ガス導入配管の途中の一例)に脱湿装置335が設けられている。第2炉内導入ガス供給部25が、アンモニアガスを熱分解してアンモニア分解ガスを生成する熱分解炉から配設される配管である場合には、当該熱分解炉の上流側に脱湿装置を設けてもよい(アンモニア分解ガスの原料であるアンモニアガスが脱湿される)、更に、第1供給量制御装置22の上流側の脱湿装置で脱湿された後のアンモニアガスが当該熱分解炉に分配供給される場合には、脱湿装置は当該1つの脱湿装置で足りる。
図7は、本発明の第2実施形態による金属部材の処理装置501(軟窒化処理装置)の概略図である。図7に示すように、本実施形態の処理装置501も、第1実施形態の処理装置1と同様の循環型処理炉2を備えているが、当該循環型処理炉2内へ導入するガスとして、アンモニアとアンモニア分解ガスと炭酸ガスとの3種類を用いている。
本実施形態で軟窒化処理される金属部材Sも、例えばステンレス鋼または耐熱鋼であって、例えば自動車用のターボチャージャー部品であるユニゾンリングやインターナルクランクまたは自動車用のエンジンバルブ等である。以下の実施例では、SUS304の板材(50mm×50mm×1mm)とSUS301Sの板材(50mm×50mm×1mm)とが用いられている。
次に、本実施形態の処理装置501の作用について説明する。まず、炉開閉蓋7(金属部材投入機構)を介して、被処理品としての金属部材Sが循環型処理炉2内に水平方向に投入される。そして、ヒータ201hによって、循環型処理炉2が加熱される。
その後、ヒータ201hによって、循環型処理炉2が所望の軟窒化処理温度に加熱される。一方、本実施形態では、処理炉2内への活性化雰囲気ガスの導入が開始される。すなわち、アンモニアガス及びアンモニア分解ガスの導入が、窒化雰囲気ガスの導入として継続される一方、炭酸ガスの導入が開始される。具体的には、炉内導入ガス供給部20からアンモニアガスとアンモニア分解ガスと炭酸ガスとの混合ガスが、軟窒化処理用の設定初期流量で処理炉2内へ導入される。この設定初期流量も、パラメータ設定装置15において設定入力可能であり、第1供給量制御装置22、第2供給量制御装置26及び第3供給量制御装置562(いずれもマスフローコントローラ)によって制御される。また、攪拌ファン駆動モータ9が駆動されて攪拌ファン8が回転し、処理炉2内の雰囲気を攪拌する。
本実施形態の処理装置501を用いて、前記した表1の6種類の有機溶剤の投入について、実用上の効果が検証された。
以上のような本実施形態の処理装置501によっても、処理炉2内への活性化雰囲気ガス(アンモニアガス及びアンモニア分解ガス)の導入を継続している状態の炉内導入ガス導入配管29(雰囲気ガス導入配管)内に、有機溶剤投入装置300が液体状態の有機溶剤(炭素化合物や炭窒素化合物に加えて塩化物でも可)を投入することで、処理炉2の温度が高温であっても当該有機溶剤が気化して逆流するという事態の発生を効果的に抑制できる。
図8は、処理装置501の変形例の概略図である。図8に示すように、当該変形例では、アンモニアガス用の第1供給量制御装置22の上流側(雰囲気ガス導入配管の途中の一例)に脱湿装置331が設けられ、アンモニア分解ガス用の第2供給量制御装置26の上流側(雰囲気ガス導入配管の途中の一例)に脱湿装置335が設けられている。第2炉内導入ガス供給部25が、アンモニアガスを熱分解してアンモニア分解ガスを生成する熱分解炉から配設される配管である場合には、当該熱分解炉の上流側に脱湿装置を設けてもよい(アンモニア分解ガスの原料であるアンモニアガスが脱湿される)、更に、第1供給量制御装置22の上流側の脱湿装置で脱湿された後のアンモニアガスが当該熱分解炉に分配供給される場合には、脱湿装置は当該1つの脱湿装置で足りる。
1’ 第1処理装置
1” 第2処理装置
3 雰囲気ガス濃度検出装置
4 窒化ポテンシャル調節計
7 炉開閉蓋
8 攪拌ファン
9 攪拌ファン駆動モータ
12 雰囲気ガス検出配管
13 炉内窒化ポテンシャル演算装置
14 ガス導入量制御装置
15 パラメータ設定装置
20 炉内導入ガス供給部
21 第1炉内導入ガス供給部
22 第1供給量制御装置
23 第1供給弁
25 第2炉内導入ガス供給部
26 第2供給量制御装置
27 第2供給弁
29 炉内導入ガス導入配管
30 ガス流量出力調整装置
31 プログラマブルロジックコントローラ
40 炉内ガス廃棄配管
41 排ガス燃焼分解装置
201h ヒータ
202 円筒
203 攪拌扇
204 円筒
205 ガス導入管
206 ガス排気装置
208 蓋
209 ファン
300 有機溶剤投入装置
301 タンク
302 有機溶剤投入管
303 ポンプ
304 逆止弁
305 有機溶剤投入制御装置
331 脱湿装置
335 脱湿装置
400 移動炉
S 金属部材
501 処理装置
501’ 第1処理装置
501” 第2処理装置
561 第3炉内導入ガス供給部
562 第3供給量制御装置
563 第3供給弁
Claims (15)
- 処理炉を用いた金属部材の処理方法であって、
処理炉内に金属部材を投入する金属部材投入工程と、
前記処理炉内に活性化雰囲気ガスを導入する活性化雰囲気ガス導入工程と、
前記処理炉内の活性化雰囲気ガスを第1温度に加熱する第1加熱工程と、
前記第1加熱工程の後、前記処理炉内に窒化雰囲気ガスまたは軟窒化雰囲気ガスを導入する主雰囲気ガス導入工程と、
前記金属部材を窒化または軟窒化するために、前記処理炉内の窒化雰囲気ガスまたは軟窒化雰囲気ガスを第2温度に加熱する第2加熱工程と、
を備え、
前記活性化雰囲気ガス導入工程において、前記活性化雰囲気ガスは、活性化雰囲気ガス導入配管を介して前記処理炉内に導入されるようになっており、
前記第1加熱工程の少なくとも一部の期間中、前記活性化雰囲気ガス導入工程が同時に実施されるようになっており、
前記期間中、液体状態の有機溶剤が、前記活性化雰囲気ガス導入配管内に断続的に複数回投入される
ことを特徴とする処理方法。 - 前記第1加熱温度は、400℃~500℃である
ことを特徴とする請求項1に記載の処理方法。 - 前記活性化雰囲気ガスは、アンモニアガスを含んでおり、
前記有機溶剤は、少なくとも一種類の炭化水素を含有する化合物である
ことを特徴とする請求項1または2に記載の処理方法。 - 前記有機溶剤は、ホルムアミド、キシレン及びトルエンの内のいずれかである
ことを特徴とする請求項3に記載の処理方法。 - 前記有機溶剤は、1回の量が10~80mlで1秒~2分間をかけて略均一速度で投入され、10分以上の間隔を空けて2~6回投入される
ことを特徴とする請求項3または4に記載の処理方法。 - 前記活性化雰囲気ガスは、アンモニアガスを含んでおり、
前記有機溶剤は、少なくとも一種類の塩素を含有する化合物である
ことを特徴とする請求項1または2のいずれかに記載の処理方法。 - 前記有機溶剤は、トリクロロエチレン、テトラクロロエチレン及びテトラクロロエタンの内のいずれかである
ことを特徴とする請求項6に記載の処理方法。 - 前記有機溶剤は、1回の量が10~80mlで1秒~2分間をかけて略均一速度で投入され、10分以上の間隔を空けて2~6回投入される
ことを特徴とする請求項7に記載の処理方法。 - 処理炉を用いた金属部材の処理方法であって、
処理炉内に金属部材を投入する金属部材投入工程と、
前記処理炉内に活性化雰囲気ガスを導入する活性化雰囲気ガス導入工程と、
前記処理炉内の活性化雰囲気ガスを第1温度に加熱する第1加熱工程と、
前記第1加熱工程の後、前記処理炉内に窒化雰囲気ガスまたは軟窒化雰囲気ガスを導入する主雰囲気ガス導入工程と、
前記金属部材を窒化または軟窒化するために、前記処理炉内の窒化雰囲気ガスまたは軟窒化雰囲気ガスを第2温度に加熱する第2加熱工程と、
を備え、
前記第1加熱工程中に、液体状態の有機溶剤が、前記処理炉内に断続的に複数回投入される
ことを特徴とする処理方法。 - 処理炉と、
前記処理炉内に金属部材を投入するための金属部材投入機構と、
前記処理炉内に連通するように配設され雰囲気ガスを前記処理炉内に導入する雰囲気ガス導入配管と、
前記雰囲気ガス導入配管内に液体状態の有機溶剤を断続的に複数回投入する有機溶剤投入装置と、
前記処理炉内の雰囲気ガスを所定の温度に加熱する加熱装置と、
を備えたことを特徴とする金属部材の処理装置。 - 前記有機溶剤投入装置は、前記雰囲気ガス導入配管の上流側において、逆止弁を有している
ことを特徴とする請求項10に記載の処理装置。 - 前記雰囲気ガス導入配管の途中に、脱湿装置が設けられている
ことを特徴とする請求項10または11に記載の処理装置。 - 前記金属部材投入機構は、前記金属部材を前記処理炉内に対して水平方向に出し入れするようになっている
ことを特徴とする請求項10乃至12のいずれかに記載の処理装置。 - 前記雰囲気ガスは、活性化雰囲気ガスであり、
前記処理炉とは別に窒化用または軟窒化用の第2処理炉が設けられている
ことを特徴とする請求項10乃至13のいずれかに記載の処理装置。 - 処理炉と、
前記処理炉内に金属部材を投入するための金属部材投入機構と、
前記処理炉内に連通するように配設され雰囲気ガスを前記処理炉内に導入する雰囲気ガス投入配管と、
前記処理炉内に液体状態の有機溶剤を断続的に複数回投入する有機溶剤投入装置と、
前記処理炉内の雰囲気ガスを所定の温度に加熱する加熱装置と、
を備えたことを特徴とする金属部材の処理装置。
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JP2021042398A (ja) * | 2017-12-27 | 2021-03-18 | パーカー熱処理工業株式会社 | 窒化鋼部材並びに窒化鋼部材の製造方法及び製造装置 |
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- 2021-11-16 EP EP21894627.5A patent/EP4249625A4/en active Pending
- 2021-11-16 CN CN202180077040.4A patent/CN116457493A/zh active Pending
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JP7471206B2 (ja) | 2020-11-27 | 2024-04-19 | エア・ウォーターNv株式会社 | 鋼材の表面処理方法 |
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JPWO2022107753A1 (ja) | 2022-05-27 |
TW202235641A (zh) | 2022-09-16 |
CN116457493A (zh) | 2023-07-18 |
EP4249625A1 (en) | 2023-09-27 |
EP4249625A4 (en) | 2023-12-27 |
TWI798885B (zh) | 2023-04-11 |
MX2023005818A (es) | 2023-06-01 |
KR20230088445A (ko) | 2023-06-19 |
US20240011142A1 (en) | 2024-01-11 |
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