WO2022075673A1 - 수지, 수지 조성물 및 이를 이용한 표시장치 - Google Patents
수지, 수지 조성물 및 이를 이용한 표시장치 Download PDFInfo
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- WO2022075673A1 WO2022075673A1 PCT/KR2021/013547 KR2021013547W WO2022075673A1 WO 2022075673 A1 WO2022075673 A1 WO 2022075673A1 KR 2021013547 W KR2021013547 W KR 2021013547W WO 2022075673 A1 WO2022075673 A1 WO 2022075673A1
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- ring
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- resin composition
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- 239000011342 resin composition Substances 0.000 title claims description 45
- 239000011347 resin Substances 0.000 title claims description 39
- 229920005989 resin Polymers 0.000 title claims description 39
- 150000001875 compounds Chemical class 0.000 claims description 144
- 229920000642 polymer Polymers 0.000 claims description 133
- 125000003118 aryl group Chemical group 0.000 claims description 124
- 125000000623 heterocyclic group Chemical group 0.000 claims description 64
- 125000000217 alkyl group Chemical group 0.000 claims description 58
- 229910052760 oxygen Inorganic materials 0.000 claims description 57
- 125000005842 heteroatom Chemical group 0.000 claims description 54
- 229910052717 sulfur Inorganic materials 0.000 claims description 51
- 125000001931 aliphatic group Chemical group 0.000 claims description 50
- 125000003545 alkoxy group Chemical group 0.000 claims description 50
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 claims description 49
- 125000003342 alkenyl group Chemical group 0.000 claims description 47
- 229910052757 nitrogen Inorganic materials 0.000 claims description 45
- 229910052698 phosphorus Inorganic materials 0.000 claims description 45
- 229910052710 silicon Inorganic materials 0.000 claims description 45
- 125000000304 alkynyl group Chemical group 0.000 claims description 44
- YZCKVEUIGOORGS-OUBTZVSYSA-N Deuterium Chemical compound [2H] YZCKVEUIGOORGS-OUBTZVSYSA-N 0.000 claims description 41
- -1 methyl hydroxy group Chemical group 0.000 claims description 40
- 125000004104 aryloxy group Chemical group 0.000 claims description 36
- 229910052736 halogen Inorganic materials 0.000 claims description 36
- 150000002367 halogens Chemical class 0.000 claims description 36
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- 125000001424 substituent group Chemical group 0.000 claims description 14
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- 239000003999 initiator Substances 0.000 claims description 8
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- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 7
- 238000010521 absorption reaction Methods 0.000 claims description 6
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- 125000000524 functional group Chemical group 0.000 abstract description 10
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- ISAOCJYIOMOJEB-UHFFFAOYSA-N benzoin Chemical compound C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1 ISAOCJYIOMOJEB-UHFFFAOYSA-N 0.000 description 6
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/30—Devices specially adapted for multicolour light emission
- H10K59/38—Devices specially adapted for multicolour light emission comprising colour filters or colour changing media [CCM]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
Definitions
- the present invention relates to a photosensitive resin composition and a display device capable of realizing a clearer image using the same.
- a liquid crystal display device LCD
- an organic light emitting display device OLED
- the organic light emitting display device in particular has advantages such as low power consumption, fast response speed, high color reproducibility, high luminance, and wide viewing angle.
- a polarizing film is used to block the light reflected from the panel due to incident external light.
- the coloring pattern is used as red, green, and blue color filters in a liquid crystal display device, not only in a liquid crystal display but also in an organic light emitting display.
- carbon black and inorganic pigments as well as various kinds of organic pigments are used as colorants, and the pigment dispersion in which these are dispersed is mixed with other compositions to form a pattern.
- the organic light emitting display made in the pixel formed in this way can realize more vivid colors.
- the coloring pattern has a large amount of outgas, and this outgas reduces the lifespan of the display.
- one embodiment of the present invention is to provide a pixel with high reliability as well as vivid color by implementing a colored pattern with a low amount of outgas on an electrode substrate.
- the present invention is an alkali-soluble resin; reactive unsaturated compounds; a photoinitiator having a maximum molar absorption coefficient of 10,000 (L/mol ⁇ cm) or more in the region of 320 nm to 380 nm and a loss of 5% by weight at 200° C. or less; Colorant; And it provides a photosensitive resin composition comprising a solvent.
- the alkali-soluble resin includes a repeating unit represented by the following formula (1).
- R 1 and R 2 are each independently hydrogen; heavy hydrogen; halogen; C 6 ⁇ C 30 Aryl group; O, N, S, Si and P containing at least one heteroatom C 2 ⁇ C 30 A heterocyclic group; C 6 ⁇ C 30 A fused ring group of an aliphatic ring and an aromatic ring; C 1 ⁇ C 20 Alkyl group; C 2 ⁇ C 20 Alkenyl group; C 2 ⁇ C 20 Alkynyl group; C 1 ⁇ C 20 Alkoxy group; C 6 ⁇ C 30 Aryloxy group; fluorenyl group; carbonyl group; ether group; Or C 1 ⁇ C 20 An alkoxycarbonyl group,
- R 1 and R 2 are each capable of forming a ring with an adjacent group
- a and b are each independently an integer from 0 to 4,
- X 1 is a single bond, O, CO, SO 2 , CR'R", SiR'R", Formula (A) or Formula (B),
- X 2 is a C 6 ⁇ C 30 aryl group; O, N, S, Si and P containing at least one heteroatom C 2 ⁇ C 30 A heterocyclic group; C 6 ⁇ C 30 A fused ring group of an aliphatic ring and an aromatic ring; C 1 ⁇ C 20 Alkyl group; C 2 ⁇ C 20 Alkenyl group; C 2 ⁇ C 20 Alkynyl group; C 1 ⁇ C 20 Alkoxy group; C 6 ⁇ C 30 Aryloxy group; or a combination thereof,
- R' and R" are each independently hydrogen; deuterium; halogen; C 6 -C 30 Aryl group; O, N, S, Si and P containing at least one heteroatom of C 2 -C 30 Heterocyclic group; C 6 ⁇ C 30 A fused ring group of an aliphatic ring and an aromatic ring; C 1 ⁇ C 20 Alkyl group; C 2 ⁇ C 20 Alkenyl group; C 2 ⁇ C 20 Alkynyl group; C 1 ⁇ C 20 Alkoxy group; C 6 ⁇ C 30 Aryloxy group; Fluorenyl group; Carbonyl group; Ether group; Or C 1 ⁇ C 20 Alkoxycarbonyl group,
- R' and R" may each form a ring with an adjacent group
- a 1 and A 2 are each independently Formula (C) or Formula (D),
- X 3 is O, S, SO 2 or NR',
- R' is hydrogen; heavy hydrogen; halogen; C 6 ⁇ C 30 Aryl group; O, N, S, Si and P containing at least one heteroatom C 2 ⁇ C 30 A heterocyclic group; C 6 ⁇ C 30 A fused ring group of an aliphatic ring and an aromatic ring; C 1 ⁇ C 20 Alkyl group; C 2 ⁇ C 20 Alkenyl group; C 2 ⁇ C 20 Alkynyl group; C 1 ⁇ C 20 Alkoxy group; C 6 ⁇ C 30 Aryloxy group; fluorenyl group; carbonyl group; ether group; Or C 1 ⁇ C 20 An alkoxycarbonyl group,
- R 3 to R 6 are each independently hydrogen; heavy hydrogen; halogen; C 6 ⁇ C 30 Aryl group; O, N, S, Si and P containing at least one heteroatom C 2 ⁇ C 30 A heterocyclic group; C 6 ⁇ C 30 A fused ring group of an aliphatic ring and an aromatic ring; C 1 ⁇ C 20 Alkyl group; C 2 ⁇ C 20 Alkenyl group; C 2 ⁇ C 20 Alkynyl group; C 1 ⁇ C 20 Alkoxy group; C 6 ⁇ C 30 Aryloxy group; fluorenyl group; carbonyl group; ether group; Or C 1 ⁇ C 20 An alkoxycarbonyl group,
- R 3 to R 6 are each capable of forming a ring with an adjacent group
- c ⁇ f are independently integers from 0 to 4,
- R 7 to R 10 are each independently hydrogen; heavy hydrogen; halogen; C 6 ⁇ C 30 Aryl group; O, N, S, Si and P containing at least one heteroatom C 2 ⁇ C 30 A heterocyclic group; C 6 ⁇ C 30 A fused ring group of an aliphatic ring and an aromatic ring; C 1 ⁇ C 20 Alkyl group; C 2 ⁇ C 20 Alkenyl group; C 2 ⁇ C 20 Alkynyl group; C 1 ⁇ C 20 Alkoxy group; C 6 ⁇ C 30 Aryloxy group; fluorenyl group; carbonyl group; ether group; Or C 1 ⁇ C 20 An alkoxycarbonyl group,
- Y 1 and Y 2 are each independently Formula (E) or Formula (F),
- R 11 to R 15 are each independently hydrogen; heavy hydrogen; halogen; C 6 ⁇ C 30 Aryl group; O, N, S, Si and P containing at least one heteroatom C 2 ⁇ C 30 A heterocyclic group; C 6 ⁇ C 30 A fused ring group of an aliphatic ring and an aromatic ring; C 1 ⁇ C 20 Alkyl group; C 2 ⁇ C 20 Alkenyl group; C 2 ⁇ C 20 Alkynyl group; C 1 ⁇ C 20 Alkoxy group; C 6 ⁇ C 30 Aryloxy group; fluorenyl group; carbonyl group; ether group; Or C 1 ⁇ C 20 An alkoxycarbonyl group,
- L 1 ⁇ L 3 are each independently a single bond, C 1 ⁇ C 30 alkylene, C 6 ⁇ C 30 arylene or C 2 ⁇ C 30 heterocycle,
- R 1 to R 15 , R′, R′′, X 1 to X 2 and L 1 to L 3 and the rings formed by bonding adjacent groups to each other are deuterium; halogen; C 1 to C 30 alkyl group Or C 6 ⁇ C 30 A silane group unsubstituted or substituted with an aryl group; siloxane group; boron group; germanium group; cyano group; amino group; nitro group; C 1 ⁇ C 30 alkylthio group; C 1 ⁇ C 30 Alkoxy group; C 6 ⁇ C 30 Arylalkoxy group; C 1 ⁇ C 30 Alkyl group; C 2 ⁇ C 30 Alkenyl group; C 2 ⁇ C 30 Alkynyl group; C 6 ⁇ C 30 Aryl group; Deuterium Substituted C 6 ⁇ C 30 Aryl group; Fluorenyl group; C 2 ⁇ C 30 Heterocyclic group comprising at least one heteroatom selected from the group consisting of O, N, S, Si and
- the alkali-soluble resin according to the present invention preferably has a weight average molecular weight of 1,000 to 100,000 g/mol.
- the ratio of the formula (E) to the formula (F) in the polymer chain of the resin including the repeating unit represented by the formula (1) is 2:0 to 1:1.
- the reactive unsaturated compound is included in an amount of 1 to 40 wt% based on the total amount of the photosensitive resin composition.
- the said reactive unsaturated compound contains the compound represented by following formula (2).
- Z 1 to Z 4 each independently have a structure of Formula (G);
- the remaining Z 1 to Z 4 are each independently hydrogen, deuterium, halogen, a methyl group, an ethyl group; methyl hydroxy group; C 6 ⁇ C 30 Aryl group; O, N, S, Si and P containing at least one heteroatom C 2 ⁇ C 30 A heterocyclic group; C 6 ⁇ C 30 A fused ring group of an aliphatic ring and an aromatic ring; C 1 ⁇ C 20 Alkyl group; C 2 ⁇ C 20 Alkenyl group; C 2 ⁇ C 20 Alkynyl group; C 1 ⁇ C 20 Alkoxy group; C 6 ⁇ C 30 Aryloxy group; fluorenyl group; carbonyl group; ether group; Or C 1 ⁇ C 20 An alkoxycarbonyl group,
- t is an integer from 1 to 20,
- L 4 is a single bond, C 1 ⁇ C 30 alkylene, C 6 ⁇ C 30 arylene or C 2 ⁇ C 30 heterocycle,
- Y 3 is the following formula (H) or formula (I),
- R 21 is hydrogen, deuterium, halogen, a methyl group, or an ethyl group; methyl hydroxy group; C 6 ⁇ C 30 Aryl group; O, N, S, Si and P containing at least one heteroatom C 2 ⁇ C 30 A heterocyclic group; C 6 ⁇ C 30 A fused ring group of an aliphatic ring and an aromatic ring; C 1 ⁇ C 20 Alkyl group; C 2 ⁇ C 20 Alkenyl group; C 2 ⁇ C 20 Alkynyl group; C 1 ⁇ C 20 Alkoxy group; C 6 ⁇ C 30 Aryloxy group; fluorenyl group; carbonyl group; ether group; Or a C 1 ⁇ C 20 alkoxycarbonyl group.
- the colorant is included in an amount of 5 to 40% by weight based on the total amount of the photosensitive resin composition.
- the colorant preferably includes at least one of black, red, blue, green, yellow, purple, orange, white, silver or gold inorganic dyes, organic dyes, inorganic pigments and organic pigments.
- the photoinitiator is included in an amount of 0.01 to 10% by weight based on the total amount of the photosensitive resin composition.
- the said photoinitiator contains the compound represented by following formula (3).
- u 1 ⁇ u 3 are each independently 0 or an integer of 1,
- L 5 and L 8 are the following formula (J),
- L 6 , L 7 and L 9 are each independently a C 6 ⁇ C 30 aryl group; O, N, S, Si and P containing at least one heteroatom C 2 ⁇ C 30 A heterocyclic group; C 6 ⁇ C 30 A fused ring group of an aliphatic ring and an aromatic ring; C 3 ⁇ C 30 An aliphatic group C 1 ⁇ C 20 Alkyl group; C 2 ⁇ C 20 Alkenyl group; C 2 ⁇ C 20 Alkynyl group; C 1 ⁇ C 20 Alkoxy group; C 6 ⁇ C 30 Aryloxy group; fluorenyl group; carbonyl group; ether group; C 1 ⁇ C 20 Alkoxycarbonyl; C 1 ⁇ C 30 Alkylene or C 6 ⁇ C 30 Arylene,
- R 31 is hydrogen, deuterium, halogen, a methyl group, or an ethyl group; methyl hydroxy group; C 6 ⁇ C 30 Aryl group; O, N, S, Si and P containing at least one heteroatom C 2 ⁇ C 30 A heterocyclic group; C 6 ⁇ C 30 A fused ring group of an aliphatic ring and an aromatic ring; C 1 ⁇ C 20 Alkyl group; C 2 ⁇ C 20 Alkenyl group; C 2 ⁇ C 20 Alkynyl group; C 1 ⁇ C 20 Alkoxy group; C 6 ⁇ C 30 Aryloxy group; fluorenyl group; carbonyl group; ether group; Or a C 1 ⁇ C 20 alkoxycarbonyl group.
- L 6 , L 7 and L 9 in Formula (3) are each independently one of the following Formulas (K) to (N).
- A is hydrogen; O; S; silane group; siloxane group; boron group; germanium group; cyano group; nitro group; nitrile group; C 1 ⁇ C 30 Alkyl group, C 6 ⁇ C 30 Aryl group or C 2 ⁇ C 30 A substituted or unsubstituted amino group with a heterocyclic group; C 1 ⁇ C 30 Alkylthio group; C 1 ⁇ C 30 Alkyl group; C 1 ⁇ C 30 Alkoxy group; C 6 ⁇ C 30 Arylalkoxy group; C 2 ⁇ C 30 Alkenyl group; C 2 ⁇ C 30 Alkynyl group; C 6 ⁇ C 30 Aryl group; C 6 ⁇ C 30 Aryl group substituted with deuterium; fluorenyl group; O, N, S, Si and P containing at least one heteroatom selected from the group consisting of C 2 ⁇ C 30 A heterocyclic group; C 3 ⁇ C 30 of an aliphatic ring; C 7 ⁇ C 30 Arylal
- R 32 to R 34 are each independently hydrogen; heavy hydrogen; halogen; C 6 ⁇ C 30 Aryl group; O, N, S, Si and P containing at least one heteroatom C 2 ⁇ C 30 A heterocyclic group; C 6 ⁇ C 30 A fused ring group of an aliphatic ring and an aromatic ring; C 1 ⁇ C 20 Alkyl group; C 2 ⁇ C 20 Alkenyl group; C 2 ⁇ C 20 Alkynyl group; C 1 ⁇ C 20 Alkoxy group; C 6 ⁇ C 30 Aryloxy group; fluorenyl group; carbonyl group; ether group; Or C 1 ⁇ C 20 An alkoxycarbonyl group,
- T is S, O or Se.
- the display device preferably includes a first electrode formed on a substrate, a second electrode provided to face the first electrode, and a pattern or film formed of the photosensitive resin composition according to claim 1 . .
- the pattern is a color part or a color separation part.
- the electronic device according to the present invention preferably includes the display device according to the present invention and a control unit for driving the display device.
- the resin composition according to an embodiment of the present invention is decomposed at a lower temperature by using a photoinitiator having a radical-forming functional group having a weak bond strength, and the pattern thus formed not only emits a smaller amount of outgas, but also has high sensitivity It is possible to provide a more reliable display panel by forming a pattern.
- FIG. 3 schematically illustrates a display device according to an exemplary embodiment of the present invention.
- the present invention is an alkali-soluble resin; reactive unsaturated compounds; a photoinitiator having a maximum molar absorption coefficient of 10,000 (L/mol ⁇ cm) or more in the region of 320 nm to 380 nm and a loss of 5% by weight at 200° C. or less; Colorant; And it provides a photosensitive resin composition comprising a solvent.
- the alkali-soluble resin includes a repeating unit represented by the following formula (1).
- a component such as a layer, membrane, region, plate, etc.
- temporal precedence relationship such as “after”, “after”, “after”, “before”, etc.
- a flow precedence relationship when a flow precedence relationship is described, it may include a case where it is not continuous unless “immediately” or "directly” is used.
- the numerical values or corresponding information may be caused by various factors (eg process factors, internal or external shock, noise, etc.) It may be interpreted as including a possible error range.
- halo or halogen includes fluorine (F), chlorine (Cl), bromine (Br), and iodine (I), unless otherwise specified.
- alkyl or "alkyl group” as used in this application, unless otherwise specified, has 1 to 60 carbons linked by a single bond, straight chain alkyl group, branched chain alkyl group, cycloalkyl (alicyclic) group, alkyl-substituted means a radical of saturated aliphatic functional groups including cycloalkyl groups and cycloalkyl-substituted alkyl groups.
- haloalkyl group or “halogenalkyl group” refers to an alkyl group substituted with halogen unless otherwise specified.
- alkenyl or “alkynyl” as used in this application, unless otherwise specified, has a double bond or a triple bond, respectively, includes a straight or branched chain group, and has 2 to 60 carbon atoms, but is limited thereto it is not going to be
- cycloalkyl refers to an alkyl forming a ring having 3 to 60 carbon atoms, unless otherwise specified, and is not limited thereto.
- alkoxy group or “alkyloxy group” refers to an alkyl group to which an oxygen radical is bonded, and has 1 to 60 carbon atoms unless otherwise specified, but is not limited thereto.
- alkenoxyl group refers to an alkenyl group to which an oxygen radical is attached, and unless otherwise specified, 2 to 60 has a carbon number of, but is not limited thereto.
- aryl group and arylene group used in the present application have 6 to 60 carbon atoms, respectively, unless otherwise specified, but are not limited thereto.
- the aryl group or the arylene group includes a single ring type, a ring aggregate, a fused multiple ring-based compound, and the like.
- the aryl group may include a phenyl group, a monovalent functional group of biphenyl, a monovalent functional group of naphthalene, a fluorenyl group, and a substituted fluorenyl group
- the arylene group may include a fluorenylene group, a substituted fluorenylene group. may include a group.
- ring assemblies means that two or more ring systems (monocyclic or fused ring systems) are directly connected to each other through a single bond or a double bond, and between such rings It means that the number of direct links is one less than the total number of ring systems in the compound. In a ring aggregate, the same or different ring systems may be directly linked to each other through single or double bonds.
- the aryl group in the present application includes a ring aggregate, the aryl group includes biphenyl and terphenyl in which a single aromatic benzene ring is connected by a single bond.
- the aryl group includes compounds in which an aromatic single ring and a fused aromatic ring system are connected by a single bond, for example, a compound in which a benzene ring, which is an aromatic single ring, and a fluorene, a fused aromatic ring system, are connected by a single bond are also included. do.
- fused multiple ring system refers to a fused ring type that shares at least two atoms, and includes a fused ring system of two or more hydrocarbons and at least one heteroatom. and a form in which at least one heterocyclic system is fused.
- the fused multiple ring system may be an aromatic ring, a heteroaromatic ring, an aliphatic ring, or a combination of these rings.
- an aryl group it may be a naphthalenyl group, a phenanthrenyl group, a fluorenyl group, etc., but is not limited thereto.
- spiro compound as used in the present application has a 'spiro union', and the spiro linkage means a connection formed by sharing only one atom in two rings. At this time, the atoms shared by the two rings are called 'spiro atoms', and they are respectively 'monospiro-', 'dispiro-', 'trispiro-', depending on the number of spiro atoms in a compound. ' It's called a compound.
- fluorenyl group As used herein, the terms “fluorenyl group”, “fluorenylene group”, and “fluorentriyl group” are, unless otherwise specified, in the following structures, R, R', R” and R'” are all hydrogen. It refers to a monovalent, divalent or trivalent functional group, and “substituted fluorenyl group”, “substituted fluorenylene group” or “substituted fluorentriyl group” is a substituent R, R', R", R' "means that at least one of " is a substituent other than hydrogen, and includes cases in which R and R' are bonded to each other to form a spiro compound together with the carbon to which they are bonded.
- the fluorenyl group, the fluorenylene group, and the fluorentriyl group may all be referred to as fluorene groups regardless of valences such as monovalent, divalent, trivalent, and the like.
- R, R', R" and R'" are each independently an alkyl group having 1 to 20 carbon atoms, an alkenyl group having 1 to 20 carbon atoms, an aryl group having 6 to 30 carbon atoms, 2 to It may be a heterocyclic group having 30 carbon atoms, for example, the aryl group may be phenyl, biphenyl, naphthalene, anthracene or phenanthrene, and the heterocyclic group may be pyrrole, furan, thiophene, pyrazole, imidazole, triazole, pyridine, pyrimidine, pyridazine, pyrazine, triazine, indole, benzofuran, quinazoline or quinoxaline.
- the aryl group may be phenyl, biphenyl, naphthalene, anthracene or phenanthrene
- the heterocyclic group may be pyrrole, furan, thi
- the substituted fluorenyl group and the fluorenylene group are monovalent to 9,9-dimethylfluorene, 9,9-diphenylfluorene and 9,9'-spirobi[9H-fluorene], respectively. It may be a functional group or a divalent functional group.
- heterocyclic group used in this application includes not only aromatic rings such as “heteroaryl group” or “heteroarylene group” but also non-aromatic rings, and unless otherwise specified, each carbon number including at least one heteroatom It means a ring of 2 to 60, but is not limited thereto.
- heteroatom refers to N, O, S, P or Si unless otherwise specified, and the heterocyclic group is a monocyclic group including a heteroatom, a ring aggregate, a fused multiple ring system, a spy means a compound or the like.
- ring includes monocyclic and polycyclic rings, and includes hydrocarbon rings as well as heterocycles including at least one heteroatom, and includes aromatic and non-aromatic rings.
- polycyclic includes ring assemblies such as biphenyl, terphenyl, etc., fused multiple ring systems and spiro compounds, and includes aromatic as well as non-aromatic, hydrocarbon Rings include, of course, heterocycles containing at least one heteroatom.
- aliphatic ring group used in this application means a cyclic hydrocarbon other than an aromatic hydrocarbon, and includes a monocyclic type, a ring aggregate, a fused multiple ring system, a spiro compound, etc., and unless otherwise specified, the number of carbon atoms It means a ring of 3 to 60, but is not limited thereto. For example, even when benzene, which is an aromatic ring, and cyclohexane, which is a non-aromatic ring, are fused, it corresponds to an aliphatic ring.
- an arylalkoxy group means an alkoxy group substituted with an aryl group
- an alkoxycarbonyl group means a carbonyl group substituted with an alkoxy group
- an arylcarbonylalkenyl group means an alkenyl group substituted with an arylcarbonyl group, where The arylcarbonyl group is a carbonyl group substituted with an aryl group.
- substitution means deuterium, halogen, amino group, nitrile group, nitro group, C 1 ⁇ C 20 alkyl group, C 1 ⁇ C 20 Alkoxy group, C 1 ⁇ C 20 Alkylamine group, C 1 ⁇ C 20 Alkylthiophene group, C 6 ⁇ C 20 Arylthiophene group, C 2 ⁇ C 20 Alkenyl group, C 2 ⁇ C 20 alkynyl group, C 3 ⁇ C 20 cycloalkyl group, C 6 ⁇ C 20 aryl group, C 6 ⁇ C 20 aryl group substituted with deuterium, C 8 ⁇ C 20 arylalkenyl group, silane group, boron A group, a germanium group, and O, N, S, Si and P containing at least one heteroatom selected from the group consisting of C 2 ⁇ C 20 It means substituted with one or
- the 'functional group name' corresponding to the aryl group, arylene group, heterocyclic group, etc. exemplified as examples of each symbol and its substituents may be described as 'the name of the functional group reflecting the valence', but it is described as 'the name of the parent compound' You may.
- 'phenanthrene' which is a type of aryl group
- the monovalent 'group' is 'phenanthryl (group)'
- the divalent group is 'phenanthrylene (group)', etc. It can be described, but it can also be described as 'phenanthrene', which is the name of the parent compound, regardless of the valence.
- pyrimidine regardless of the valence, it is described as 'pyrimidine', or if it is monovalent, it is pyrimidinyl (group), and if it is divalent, the 'group of the valence, such as pyrimidinylene (group), etc. It can also be written in the name of '. Therefore, in the present application, when the type of the substituent is described as the name of the parent compound, it may mean an n-valent 'group' formed by the detachment of a hydrogen atom bonding to a carbon atom and/or a hetero atom of the parent compound.
- the substituent R 1 means that it does not exist, that is, when a is 0, it means that all hydrogens are bonded to the carbons forming the benzene ring, and in this case, the display of hydrogen bonded to carbon It can be omitted and the chemical formula or compound can be described.
- R 1 when a is an integer of 1, one substituent R 1 is bonded to any one carbon of the carbons forming the benzene ring, and when a is an integer of 2 or 3, it may be bonded as follows, for example, a is 4 to 6 Even if it is an integer of , it is bonded to the carbon of the benzene ring in a similar manner, and when a is an integer of 2 or more, R 1 may be the same as or different from each other.
- forming a ring means that adjacent groups combine with each other to form a single ring or fused multiple rings, and the single ring and the formed fused multiple rings are at least one hydrocarbon ring as well as a hydrocarbon ring. It includes heterocycles containing heteroatoms, and may include aromatic and non-aromatic rings.
- the number in 'number-condensed ring' indicates the number of rings to be condensed.
- a form in which three rings are condensed with each other, such as anthracene, phenanthrene, benzoquinazoline, etc. may be expressed as a 3-condensed ring.
- bridged bicyclic compound refers to a compound in which two rings share three or more atoms to form a ring, unless otherwise specified.
- the shared atom may include carbon or a hetero atom.
- the organic electric device may mean a component(s) between the anode and the cathode, or may refer to an organic light emitting diode including the anode and the cathode, and the component(s) positioned therebetween.
- a display device in the present application may mean an organic electric device, an organic light emitting diode, and a panel including the same, or an electronic device including a panel and a circuit.
- the electronic device includes a lighting device, a solar cell, a portable or mobile terminal (eg, a smart phone, tablet, PDA, electronic dictionary, PMP, etc.), a navigation terminal, a game machine, various TVs, various computer monitors, etc. All may be included, but not limited thereto, and may be any type of device as long as the component(s) are included.
- the photosensitive resin composition according to an embodiment of the present invention includes an alkali-soluble resin; reactive unsaturated compounds; a photoinitiator having a maximum molar absorption coefficient of 10,000 (L/mol ⁇ cm) or more in the region of 320 nm to 380 nm and a loss of 5% by weight at 200° C. or less; Colorant; and solvents.
- the alkali-soluble resin includes a repeating unit represented by the following formula (1).
- the binder resin according to an embodiment of the present invention includes a repeating unit having a structure as shown in Formula (1) below.
- R 1 and R 2 are each independently hydrogen; heavy hydrogen; halogen; C 6 ⁇ C 30 Aryl group; O, N, S, Si and P containing at least one heteroatom C 2 ⁇ C 30 A heterocyclic group; C 6 ⁇ C 30 A fused ring group of an aliphatic ring and an aromatic ring; C 1 ⁇ C 20 Alkyl group; C 2 ⁇ C 20 Alkenyl group; C 2 ⁇ C 20 Alkynyl group; C 1 ⁇ C 20 Alkoxy group; C 6 ⁇ C 30 Aryloxy group; fluorenyl group; carbonyl group; ether group; Or C 1 ⁇ C 20 An alkoxycarbonyl group,
- R 1 and R 2 are each capable of forming a ring with an adjacent group
- a and b are each independently an integer from 0 to 4,
- X 1 is a single bond, O, CO, SO 2 , CR′R′′, SiR′R′′, Formula (A) or Formula (B); preferably formula (A) or formula (B); More preferably, it is the formula (A),
- X 2 is a C 6 ⁇ C 30 aryl group; O, N, S, Si and P containing at least one heteroatom C 2 ⁇ C 30 A heterocyclic group; C 6 ⁇ C 30 A fused ring group of an aliphatic ring and an aromatic ring; C 1 ⁇ C 20 Alkyl group; C 2 ⁇ C 20 Alkenyl group; C 2 ⁇ C 20 Alkynyl group; C 1 ⁇ C 20 Alkoxy group; C 6 ⁇ C 30 Aryloxy group; or a combination thereof,
- R' and R" are each independently hydrogen; deuterium; halogen; C 6 -C 30 Aryl group; O, N, S, Si and P containing at least one heteroatom of C 2 -C 30 Heterocyclic group; C 6 ⁇ C 30 A fused ring group of an aliphatic ring and an aromatic ring; C 1 ⁇ C 20 Alkyl group; C 2 ⁇ C 20 Alkenyl group; C 2 ⁇ C 20 Alkynyl group; C 1 ⁇ C 20 Alkoxy group; C 6 ⁇ C 30 Aryloxy group; Fluorenyl group; Carbonyl group; Ether group; Or C 1 ⁇ C 20 Alkoxycarbonyl group,
- R' and R" are each capable of forming a ring with an adjacent group
- a 1 and A 2 are each independently Formula (C) or Formula (D),
- X 3 is O, S, SO 2 or NR',
- R' is hydrogen; heavy hydrogen; halogen; C 6 ⁇ C 30 Aryl group; O, N, S, Si and P containing at least one heteroatom C 2 ⁇ C 30 A heterocyclic group; C 6 ⁇ C 30 A fused ring group of an aliphatic ring and an aromatic ring; C 1 ⁇ C 20 Alkyl group; C 2 ⁇ C 20 Alkenyl group; C 2 ⁇ C 20 Alkynyl group; C 1 ⁇ C 20 Alkoxy group; C 6 ⁇ C 30 Aryloxy group; fluorenyl group; carbonyl group; ether group; Or C 1 ⁇ C 20 An alkoxycarbonyl group,
- R 3 to R 6 are each independently hydrogen; heavy hydrogen; halogen; C 6 ⁇ C 30 Aryl group; O, N, S, Si and P containing at least one heteroatom C 2 ⁇ C 30 A heterocyclic group; C 6 ⁇ C 30 A fused ring group of an aliphatic ring and an aromatic ring; C 1 ⁇ C 20 Alkyl group; C 2 ⁇ C 20 Alkenyl group; C 2 ⁇ C 20 Alkynyl group; C 1 ⁇ C 20 Alkoxy group; C 6 ⁇ C 30 Aryloxy group; fluorenyl group; carbonyl group; ether group; Or C 1 ⁇ C 20 An alkoxycarbonyl group,
- R 3 to R 6 are each capable of forming a ring with an adjacent group
- c ⁇ f are integers from 0 to 4 independently of each other.
- R 7 to R 10 are each independently hydrogen; heavy hydrogen; halogen; C 6 ⁇ C 30 Aryl group; O, N, S, Si and P containing at least one heteroatom C 2 ⁇ C 30 A heterocyclic group; C 6 ⁇ C 30 A fused ring group of an aliphatic ring and an aromatic ring; C 1 ⁇ C 20 Alkyl group; C 2 ⁇ C 20 Alkenyl group; C 2 ⁇ C 20 Alkynyl group; C 1 ⁇ C 20 Alkoxy group; C 6 ⁇ C 30 Aryloxy group; fluorenyl group; carbonyl group; ether group; Or C 1 ⁇ C 20 An alkoxycarbonyl group,
- Y 1 and Y 2 are each independently Formula (E) or Formula (F).
- R 11 to R 15 are each independently hydrogen; heavy hydrogen; halogen; C 6 ⁇ C 30 Aryl group; O, N, S, Si and P containing at least one heteroatom C 2 ⁇ C 30 A heterocyclic group; C 6 ⁇ C 30 A fused ring group of an aliphatic ring and an aromatic ring; C 1 ⁇ C 20 Alkyl group; C 2 ⁇ C 20 Alkenyl group; C 2 ⁇ C 20 Alkynyl group; C 1 ⁇ C 20 Alkoxy group; C 6 ⁇ C 30 Aryloxy group; fluorenyl group; carbonyl group; ether group; Or C 1 ⁇ C 20 An alkoxycarbonyl group,
- L 1 ⁇ L 3 are each independently a single bond, C 1 ⁇ C 30 alkylene, C 6 ⁇ C 30 arylene, or C 2 ⁇ C 30 heterocycle,
- R 1 to R 15 , R′, R′′, X 1 to X 2 and L 1 to L 3 and the rings formed by bonding adjacent groups to each other are deuterium; halogen; C 1 to C 30 alkyl group Or C 6 ⁇ C 30 A silane group unsubstituted or substituted with an aryl group; siloxane group; boron group; germanium group; cyano group; amino group; nitro group; C 1 ⁇ C 30 alkylthio group; C 1 ⁇ C 30 Alkoxy group; C 6 ⁇ C 30 Arylalkoxy group; C 1 ⁇ C 30 Alkyl group; C 2 ⁇ C 30 Alkenyl group; C 2 ⁇ C 30 Alkynyl group; C 6 ⁇ C 30 Aryl group; Deuterium Substituted C 6 ⁇ C 30 Aryl group; Fluorenyl group; C 2 ⁇ C 30 Heterocyclic group comprising at least one heteroatom selected from the group consisting of O, N, S, Si and
- R 1 to R 15 , R′, R′′ and X 1 to X 2 are an aryl group, preferably a C 6 to C 30 aryl group, more preferably a C 6 to C 18 aryl group, such as phenyl , biphenyl, naphthyl, terphenyl, and the like.
- a heterocyclic group Preferably a C 2 ⁇ C 30 heterocyclic group, more preferably a C 2 ⁇ C 18 heterocyclic group, such as dibenzofuran, dibenzothiophene, naphthobenzothiophene, naphthobenzofuran, etc. .
- R 1 to R 15 , R′, R′′ and X 1 to X 2 are fluorenyl groups, preferably 9,9-dimethyl-9H-fluorene, 9,9-diphenyl-9H-flu orenyl group, 9,9'-spirobifluorene, and the like.
- L 1 ⁇ L 3 is an arylene group, preferably a C 6 ⁇ C 30 arylene group, more preferably a C 6 ⁇ C 18 arylene group, such as phenyl, biphenyl, naphthyl, terphenyl, etc. there is.
- R 1 to R 15 , R′ and R′′ are an alkyl group, it may be preferably a C 1 to C 10 alkyl group, for example, methyl, t-butyl, or the like.
- R 1 to R 15 , R′ and R′′ are an alkoxyl group, preferably a C 1 to C 20 alkoxyl group, more preferably a C 1 to C 10 alkoxyl group, such as methoxy, t-part Toxic, etc. may be used.
- the R 1 to R 15 , R′, R′′, X 1 to X 2 and L 1 A ring formed by bonding to each other is a C 6 to C 60 aromatic ring group; fluorenyl group; O, N, A C 2 ⁇ C 60 heterocyclic group comprising at least one heteroatom of S, Si and P; or a C 3 ⁇ C 60 aliphatic ring group, for example, adjacent groups are bonded to each other to form an aromatic ring
- a C 6 ⁇ C 20 aromatic ring more preferably a C 6 ⁇ C 14 aromatic ring, such as benzene, naphthalene, phenanthrene, etc. may be formed.
- the ratio of Formula (E) to Formula (F) in the polymer chain of the resin including the repeating unit represented by Formula (1) is preferably 2:0 to 1:1, most preferably 1.5:0.5 am.
- the ratio of the formula (F) is higher than the ratio of the formula (E)
- a residue may be generated due to the too high adhesion, the amount of outgas generated may also be significantly increased, and the ratio of the formula (E) to the formula (F) is 1.5
- it is :0.5 the resolution of the pattern is the best and the amount of outgas can be satisfied.
- the weight average molecular weight of the resin of the present invention may be 1,000 to 100,000 g/mol, preferably 1,000 to 50,000 g/mol, and more preferably 1,000 to 30,000 g/mol.
- the pattern can be well formed without a residue when the pattern layer is manufactured, there is no loss of film thickness during development, and a good pattern can be obtained.
- the resin may be included in an amount of 1 to 30% by weight, more preferably 3 to 20% by weight, based on the total amount of the photosensitive resin composition.
- excellent sensitivity, developability, and adhesion (adhesion) can be obtained.
- the photosensitive resin composition may further include an acrylic resin in addition to the resin.
- the acrylic resin is a copolymer of a first ethylenically unsaturated monomer and a second ethylenically unsaturated monomer copolymerizable therewith, and may be a resin including one or more acrylic repeating units.
- the photosensitive resin composition according to an embodiment of the present invention includes a reactive unsaturated compound having a structure as shown in Formula (2) below.
- Z 1 to Z 4 each independently have a structure of Formula (G);
- the remaining Z 1 to Z 4 are each independently hydrogen, deuterium, halogen, a methyl group, an ethyl group; methyl hydroxy group; C 6 ⁇ C 30 Aryl group; O, N, S, Si and P containing at least one heteroatom C 2 ⁇ C 30 A heterocyclic group; C 6 ⁇ C 30 A fused ring group of an aliphatic ring and an aromatic ring; C 1 ⁇ C 20 Alkyl group; C 2 ⁇ C 20 Alkenyl group; C 2 ⁇ C 20 Alkynyl group; C 1 ⁇ C 20 Alkoxy group; C 6 ⁇ C 30 Aryloxy group; fluorenyl group; carbonyl group; ether group; Or a C 1 ⁇ C 20 alkoxycarbonyl group.
- t is an integer from 1 to 20,
- L 4 is a single bond, C 1 ⁇ C 30 alkylene, C 6 ⁇ C 30 arylene or C 2 ⁇ C 30 heterocycle,
- Y 3 is the following formula (H) or formula (I).
- R 21 is hydrogen, deuterium, halogen, a methyl group, or an ethyl group; methyl hydroxy group; C 6 ⁇ C 30 Aryl group; O, N, S, Si and P containing at least one heteroatom C 2 ⁇ C 30 A heterocyclic group; C 6 ⁇ C 30 A fused ring group of an aliphatic ring and an aromatic ring; C 1 ⁇ C 20 Alkyl group; C 2 ⁇ C 20 Alkenyl group; C 2 ⁇ C 20 Alkynyl group; C 1 ⁇ C 20 Alkoxy group; C 6 ⁇ C 30 Aryloxy group; fluorenyl group; carbonyl group; ether group; Or a C 1 ⁇ C 20 alkoxycarbonyl group.
- the multi-acrylic compound having the structure as in Formula (2) may be used alone or in combination of two or more.
- Examples thereof include polyfunctional esters of (meth)acrylic acid having at least two ethylenically unsaturated double bonds.
- (meth)acrylic acid may refer to methacrylic acid, acrylic acid, or a mixture of methacrylic acid and acrylic acid.
- the reactive unsaturated compound has the ethylenically unsaturated double bond, it is possible to form a pattern excellent in heat resistance, light resistance and chemical resistance by causing sufficient polymerization during exposure to light in the pattern forming process.
- the reactive unsaturated compound examples include ethylene glycol diacrylate, ethylene glycol dimethacrylate, diethylene glycol diacrylate, triethylene glycol diacrylate, triethylene glycol dimethacrylate, and 1,6-hexanediol.
- bifunctional ester of (meth)acrylic acid examples include Aronix M-210, M-240, M-6200 of Toagosei Chemical Co., Ltd., and KAYARAD HDDA, HX- of Nihon Kayaku Co., Ltd. 220, R-604, etc., and V-260, V-312, V-335 HP of Osaka Yuki Chemical High School Co., Ltd. are mentioned.
- the reactive unsaturated compound may be used after treatment with an acid anhydride in order to provide better developability than .
- the reactive unsaturated compound may be included in an amount of 1 to 40% by weight, for example, 1 to 20% by weight, based on the total amount of the photosensitive resin composition.
- the photoinitiator is a photoinitiator having a maximum molar absorption coefficient in the region of 320 to 380 nm of 10,000 (L/mol ⁇ cm) or more and a loss of 5% by weight occurs at 200° C. or less.
- the maximum molar extinction coefficient in the region of 320 to 380 nm may be calculated by the beer-Lambert Law.
- weight loss was measured by raising the temperature to 300 °C at a rate of 5 °C per minute in a nitrogen atmosphere using TGA.
- the photosensitive resin composition according to an embodiment of the present invention includes a photoinitiator having a structure as shown in Formula (3) below.
- u 1 ⁇ u 3 are each independently 0 or an integer of 1,
- L 5 and L 8 are the following formula (J),
- L 6 , L 7 and L 9 are each independently a C 6 ⁇ C 30 aryl group; O, N, S, Si and P containing at least one heteroatom C 2 ⁇ C 30 A heterocyclic group; C 6 ⁇ C 30 A fused ring group of an aliphatic ring and an aromatic ring; C 3 ⁇ C 30 An aliphatic group C 1 ⁇ C 20 Alkyl group; C 2 ⁇ C 20 Alkenyl group; C 2 ⁇ C 20 Alkynyl group; C 1 ⁇ C 20 Alkoxy group; C 6 ⁇ C 30 Aryloxy group; fluorenyl group; carbonyl group; ether group; C 1 ⁇ C 20 Alkoxycarbonyl; C 1 ⁇ C 30 Alkylene or C 6 ⁇ C 30 Arylene.
- R 31 is hydrogen, deuterium, halogen, a methyl group, or an ethyl group; methyl hydroxy group; C 6 ⁇ C 30 Aryl group; O, N, S, Si and P containing at least one heteroatom C 2 ⁇ C 30 A heterocyclic group; C 6 ⁇ C 30 A fused ring group of an aliphatic ring and an aromatic ring; C 1 ⁇ C 20 Alkyl group; C 2 ⁇ C 20 Alkenyl group; C 2 ⁇ C 20 Alkynyl group; C 1 ⁇ C 20 Alkoxy group; C 6 ⁇ C 30 Aryloxy group; fluorenyl group; carbonyl group; ether group; Or a C 1 ⁇ C 20 alkoxycarbonyl group.
- L 6 , L 7 and L 9 of Formula (3) are each independently one of the following Formulas (K) to (N).
- A is hydrogen; O; S; silane group; siloxane group; boron group; germanium group; cyano group; nitro group; nitrile group; C 1 ⁇ C 30 Alkyl group, C 6 ⁇ C 30 Aryl group or C 2 ⁇ C 30 A substituted or unsubstituted amino group with a heterocyclic group; C 1 ⁇ C 30 Alkylthio group; C 1 ⁇ C 30 Alkyl group; C 1 ⁇ C 30 Alkoxy group; C 6 ⁇ C 30 Arylalkoxy group; C 2 ⁇ C 30 Alkenyl group; C 2 ⁇ C 30 Alkynyl group; C 6 ⁇ C 30 Aryl group; C 6 ⁇ C 30 Aryl group substituted with deuterium; fluorenyl group; O, N, S, Si and P containing at least one heteroatom selected from the group consisting of C 2 ⁇ C 30 A heterocyclic group; C 3 ⁇ C 30 aliphatic ring; C 7 ⁇ C 30 Arylalkyl
- R 32 to R 34 are each independently hydrogen; heavy hydrogen; halogen; C 6 ⁇ C 30 Aryl group; O, N, S, Si and P containing at least one heteroatom C 2 ⁇ C 30 A heterocyclic group; C 6 ⁇ C 30 A fused ring group of an aliphatic ring and an aromatic ring; C 1 ⁇ C 20 Alkyl group; C 2 ⁇ C 20 Alkenyl group; C 2 ⁇ C 20 Alkynyl group; C 1 ⁇ C 20 Alkoxy group; C 6 ⁇ C 30 Aryloxy group; fluorenyl group; carbonyl group; ether group; Or C 1 ⁇ C 20 An alkoxycarbonyl group,
- T is S, O or Se.
- the oxime ester-based compound of Formula (3) may be used alone or in combination of two or more.
- the initiator that can be mixed with the oxime ester-based compound is an initiator used in the photosensitive resin composition, for example, an acetophenone-based compound, a benzophenone-based compound, a thioxanthone-based compound, a benzoin-based compound, a triazine-based compound, etc. can be used
- acetophenone-based compound examples include 2,2'-diethoxy acetophenone, 2,2'-dibutoxy acetophenone, 2-hydroxy-2-methylpropiophenone, p-t-butyltrichloroacetophenone, p-t-Butyldichloro acetophenone, 4-chloro acetophenone, 2,2'-dichloro-4-phenoxy acetophenone, 2-methyl-1- (4- (methylthio) phenyl) -2-morpholinopropane- 1-one, 2-benzyl-2-dimethylamino-1-(4-morpholinophenyl)-butan-1-one, and the like.
- benzophenone-based compound examples include benzophenone, benzoyl benzoic acid, methyl benzoyl benzoate, 4-phenyl benzophenone, hydroxy benzophenone, acrylated benzophenone, 4,4'-bis(dimethyl amino)benzophenone, 4,4 '-bis(diethylamino)benzophenone, 4,4'-dimethylaminobenzophenone, 4,4'-dichlorobenzophenone, 3,3'-dimethyl-2-methoxybenzophenone, etc. are mentioned.
- thioxanthone-based compound examples include thioxanthone, 2-chlorothioxanthone, 2-methylthioxanthone, isopropyl thioxanthone, 2,4-diethyl thioxanthone, 2,4-diiso and propyl thioxanthone and 2-chlorothioxanthone.
- benzoin-based compound examples include benzoin, benzoin methyl ether, benzoin ethyl ether, benzoin isopropyl ether, benzoin isobutyl ether, and benzyldimethyl ketal.
- triazine-based compound examples include 2,4,6-trichloro-s-triazine, 2-phenyl 4,6-bis(trichloromethyl)-s-triazine, 2-(3', 4'- Dimethoxystyryl)-4,6-bis(trichloromethyl)-s-triazine, 2-(4'-methoxynaphthyl)-4,6-bis(trichloromethyl)-s-triazine, 2-(p-methoxyphenyl)-4,6-bis(trichloromethyl)-s-triazine, 2-(p-tolyl)-4,6-bis(trichloromethyl)-s-triazine; 2-biphenyl 4,6-bis(trichloromethyl)-s-triazine, bis(trichloromethyl)-6-styryl-s-triazine, 2-(naphtho1-yl)-4,6 -bis(trichloromethyl)
- a carbazole-based compound As the initiator, a carbazole-based compound, a diketone-based compound, a sulfonium borate-based compound, a diazo-based compound, an imidazole-based compound, or a biimidazole-based compound may be used in addition to the above compound.
- a peroxide-based compound, an azobis-based compound, or the like may be used as a radical polymerization initiator.
- peroxide-based compound examples include ketone peroxides such as methyl ethyl ketone peroxide, methyl isobutyl ketone peroxide, cyclohexanone peroxide, methylcyclohexanone peroxide, and acetylacetone peroxide; diacyl peroxides such as isobutyryl peroxide, 2,4-dichlorobenzoyl peroxide, o-methylbenzoyl peroxide, and bis-3,5,5-trimethylhexanoyl peroxide; hydroperoxides such as 2,4,4,-trimethylpentyl-2-hydroperoxide, diisopropylbenzenehydroperoxide, cumene hydroperoxide, and t-butylhydroperoxide; Dicumyl peroxide, 2,5-dimethyl-2,5-di(t-butylperoxy)hexane, 1,3-bis(t-butyloxyisopropyl
- azobis-based compound examples include 1,1'-azobiscyclohexane-1-carbonitrile, 2,2'-azobis(2,4-dimethylvaleronitrile), 2,2,-azobis( methylisobutyrate), 2,2′-azobis(4-methoxy-2,4-dimethylvaleronitrile), ⁇ , ⁇ ′-azobis(isobutylnitrile) and 4,4′-azobis(4 -Cyanovaleic acid) and the like.
- the photoinitiator may be used together with a photosensitizer that causes a chemical reaction by absorbing light to enter an excited state and then transferring the energy.
- a photosensitizer that causes a chemical reaction by absorbing light to enter an excited state and then transferring the energy.
- the photosensitizer include tetraethylene glycol bis-3-mercaptopropionate, pentaerythritol tetrakis-3-mercaptopropionate, dipentaerythritol tetrakis-3-mercaptopropionate, and the like. can be heard
- the maximum molar absorption coefficient in the 320 to 380 nm region of the photoinitiator is preferably 10,000 (L/mol ⁇ cm) or more, more preferably 5,000 to 40,000 (L/mol ⁇ cm).
- the maximum molar extinction coefficient in the region of 320 to 380 nm of the photoinitiator is 5,000 to 40,000 (L/mol ⁇ cm)
- the temperature of the photoinitiator to lose 5% by weight is preferably 200° C. or less, and more preferably 150 to 200° C.
- the 5 wt% reduction temperature of the photoinitiator is 150 to 200 ° C, there is an advantage of showing a low outgas in the finally formed pattern, when it is less than 150 ° C, there is a problem in storage stability, and when it is 200 ° C or more, low reliability due to high outgas There is a visible problem.
- the photoinitiator may be included in an amount of 0.01 to 10% by weight, for example 0.1 to 5% by weight, based on the total amount of the photosensitive resin composition.
- the photoinitiator is included within the above range, curing occurs sufficiently upon exposure in the pattern forming process to obtain excellent reliability, and the pattern has excellent heat resistance, light resistance and chemical resistance, resolution and adhesion are also excellent, and due to unreacted initiator A decrease in transmittance can be prevented.
- pigments such as pigments and dyes may be used independently or together, and both organic pigments and inorganic pigments may be used as the pigments.
- the pigment includes a red pigment, a green pigment, a blue pigment, a yellow pigment, and a black pigment.
- the pigments may be used alone or in combination of two or more, and the examples are not limited thereto.
- red pigment examples include C.I. Red pigment 254, C.I. Red pigment 255, C.I. Red pigment 264, C.I. Red pigment 270, C.I. Red pigment 272, C.I. Red pigment 177, C.I. Red pigment 89 etc. are mentioned.
- green pigment examples include C.I. Green pigment 36, C.I. and halogen-substituted copper phthalocyanine pigments such as green pigment 7 and the like.
- blue pigment examples include C.I. Blue pigment 15:6, C.I. Blue pigment 15, C.I. Blue pigment 15:1, C.I. Blue pigment 15:2, C.I. Blue pigment 15:3, C.I. Blue pigment 15:4, C.I. Blue pigment 15:5, C.I. and copper phthalocyanine pigments such as blue pigment 16.
- yellow pigment examples include C.I. isoindoline pigments such as yellow pigment 139, C.I. quinophthalone-based pigments such as yellow pigment 138, C.I. Nickel complex pigments, such as yellow pigment 150, etc. are mentioned.
- black pigment examples include benzofuranone black, lactam black, aniline black, perylene black, titanium black, carbon black, and the like.
- a dispersant may be used together to disperse the pigment in the photosensitive resin composition.
- the pigment may be surface-treated in advance with a dispersant, or may be used by adding a dispersing agent together with the pigment when preparing the photosensitive resin composition.
- a dispersant a nonionic dispersant, an anionic dispersant, a cationic dispersant, etc. may be used.
- dispersant examples include polyalkylene glycol and its esters, polyoxyalkylene, polyalcohol ester alkylene oxide adduct, alcohol alkylene oxide adduct, sulfonic acid ester, sulfonic acid salt, carboxylic acid ester, carboxylic acid salts, alkylamide alkylene oxide adducts, alkyl amines, and the like, and these may be used alone or in combination of two or more.
- Examples of commercially available products of the dispersant include BYK's DISPERBYK-101, DISPERBYK-130, DISPERBYK-140, DISPERBYK-160, DISPERBYK-161, DISPERBYK-162, DISPERBYK-163, DISPERBYK-164, DISPERBYK-165, DISPERBYK -166, DISPERBYK-170, DISPERBYK-171, DISPERBYK-182, DISPERBYK-2000, DISPERBYK-2001 and BASF's EFKA-47, EFKA-47EA, EFKA-48, EFKA-49, EFKA-100, EFKA-400, EFKA-450 and Zeneka's Solsperse 5000, Solsperse 12000, Solsperse 13240, Solsperse 13940, Solsperse 17000, Solsperse 20000, Solsperse 24000GR, Solsper
- the dispersant may be included in an amount of 0.1 to 15 wt% based on the total amount of the photosensitive resin composition.
- the dispersing agent is included within the above range, the dispersibility of the photosensitive resin composition is excellent, and thus, stability, developability and patternability are excellent in manufacturing the light blocking layer.
- the pigment may be used after pre-treatment using a water-soluble inorganic salt and a wetting agent.
- the primary particle size of the pigment can be refined.
- the pretreatment may be performed by kneading the pigment with a water-soluble inorganic salt and a wetting agent, and filtering and washing the pigment obtained in the kneading step.
- the kneading may be performed at a temperature of 40° C. to 100° C., and the filtration and washing may be performed by filtration after washing the inorganic salt with water or the like.
- water-soluble inorganic salt examples include, but are not limited to, sodium chloride and potassium chloride.
- the wetting agent serves as a medium through which the pigment and the water-soluble inorganic salt are uniformly mixed and the pigment can be easily pulverized, for example, ethylene glycol monoethyl ether, propylene glycol monomethyl ether, diethylene glycol monomethyl ether, etc. alkylene glycol monoalkyl ethers; and alcohols such as ethanol, isopropanol, butanol, hexanol, cyclohexanol, ethylene glycol, diethylene glycol, polyethylene glycol, glycerin polyethylene glycol, and the like, and these may be used alone or in combination of two or more.
- the pigment that has undergone the kneading step may have an average particle diameter of 20 nm to 110 nm.
- the average particle diameter of the pigment is within the above range, it is possible to effectively form a fine pattern while having excellent heat resistance and light resistance.
- C.I. As a solvent dye, C.I. yellow dyes such as solvent yellow 4, 14, 15, 16, 21, 23, 24, 38, 56, 62, 63, 68, 79, 82, 93, 94, 98, 99, 151, 162, 163; C.I. red dyes such as solvent red 8, 45, 49, 89, 111, 122, 125, 130, 132, 146, 179; C.I. orange dyes such as solvent orange 2, 7, 11, 15, 26, 41, 45, 56, 62; C.I. blue dyes such as solvent blue 5, 35, 36, 37, 44, 59, 67, and 70; C.I. violet dyes such as solvent violet 8, 9, 13, 14, 36, 37, 47, 49; C.I. Green dyes, such as solvent green 1, 3, 4, 5, 7, 28, 29, 32, 33, 34, 35, etc. are mentioned.
- C.I. yellow dyes such as solvent yellow 4, 14, 15, 16, 21, 23, 24, 38, 56, 62, 63, 68, 79, 82,
- C.I. Among solvent dyes, C.I. Solvent Yellow 14, 16, 21, 56, 151, 79, 93; C.I. Solvent Red 8, 49, 89, 111, 122, 132, 146, 179; C.I. Solvent Orange 41, 45, 62; C.I. Solvent Blue 35, 36, 44, 45, 70; C.I. Solvent Violet 13 is preferred.
- C.I. Solvent Yellow 21, 79; C.I. Solvent Red 8, 122, 132; C.I. Solvent orange 45 and 62 are more preferable.
- C.I. As an acid dye, C.I. Acid Yellow 1, 3, 7, 9, 11, 17, 23, 25, 29, 34, 36, 38, 40, 42, 54, 65, 72, 73, 76, 79, 98, 99, 111, 112, 113, 114, 116, 119, 123, 128, 134, 135, 138, 139, 140, 144, 150, 155, 157, 160, 161, 163, 168, 169, 172, 177, 178, 179, 184, 190, 193, 196, 197, 199, 202, 203, 204, 205, 207, 212, 214, 220, 221, 228, 230, 232, 235, 238, 240, 242, 243, 251, etc.
- C.I. Acid Yellow 42 which has excellent solubility in organic solvents among the acid dyes; C.I. Acid Red 92; C.I. Acid Blue 80, 90; C.I. Acid Violet 66; C.I. Acid Green 27 is preferred.
- C.I. Direct Yellow 2 33, 34, 35, 38, 39, 43, 47, 50, 54, 58, 68, 69, 70, 71, 86, 93, 94, 95, 98, yellow dyes such as 102, 108, 109, 129, 136, 138 and 141; C.I.
- Green dyes such as C.I. direct green 25, 27, 31, 32, 34, 37, 63, 65, 66, 67, 68, 69, 72, 77, 79, 82, etc. are mentioned.
- C.I. As the modant dye, yellow dyes such as C.I. modant yellow 5, 8, 10, 16, 20, 26, 30, 31, 33, 42, 43, 45, 56, 61, 62, 65; C.I. modant red 1, 2, 3, 4, 9, 11, 12, 14, 17, 18, 19, 22, 23, 24, 25, 26, 30, 32, 33, 36, 37, 38, 39, red dyes such as 41, 43, 45, 46, 48, 53, 56, 63, 71, 74, 85, 86, 88, 90, 94, 95; C.I. Modant Orange 3, 4, 5, 8, 12, 13, 14, 20, 21, 23, 24, 28, 29, 32, 34, 35, 36, 37, 42, 43, 47, 48, etc. orange dyes; C.I.
- modant blue 1, 2, 3, 7, 8, 9, 12, 13, 15, 16, 19, 20, 21, 22, 23, 24, 26, 30, 31, 32, 39, 40, 41, blue dyes such as 43, 44, 48, 49, 53, 61, 74, 77, 83, 84; purple dyes such as C.I. modant violet 1, 2, 4, 5, 7, 14, 22, 24, 30, 31, 32, 37, 40, 41, 44, 45, 47, 48, 53, 58; Green dyes, such as C.I. modant green 1, 3, 4, 5, 10, 15, 19, 26, 29, 33, 34, 35, 41, 43, 53, etc. are mentioned.
- each of the dyes may be used alone or in combination of two or more.
- the pigment and dye may be included in an amount of 5 to 40 wt%, more specifically 8 to 30 wt%, based on the total amount of the photosensitive resin composition.
- the pigment When the pigment is included within the above range, it has an absorbance of 0.5/ ⁇ m or more at a wavelength of 550 nm, and has excellent curability and adhesion of the pattern.
- the solvent materials having compatibility with the binder resin, the reactive unsaturated compound, the pigment, and the initiator but not reacting may be used.
- the solvent examples include alcohols such as methanol and ethanol; ethers such as dichloroethyl ether, n-butyl ether, diisoamyl ether, methylphenyl ether, and tetrahydrofuran; glycol ethers such as ethylene glycol monomethyl ether and ethylene glycol monoethyl ether; cellosolve acetates such as methyl cellosolve acetate, ethyl cellosolve acetate, and diethyl cellosolve acetate; carbitols such as methylethyl carbitol, diethyl carbitol, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol dimethyl ether, diethylene glycol methyl ethyl ether, and diethylene glycol diethyl ether; propylene glycol alkyl ether acetates such as propylene glycol methyl ether acetate and propy
- glycol ethers such as ethylene glycol monoethyl ether; ethylene glycol alkyl ether acetates such as ethyl cellosolve acetate; esters such as ethyl 2-hydroxypropionate; carbitols such as diethylene glycol monomethyl ether; Propylene glycol alkyl ether acetates such as propylene glycol methyl ether acetate and propylene glycol propyl ether acetate can be used.
- the solvent may be included as a balance based on the total amount of the photosensitive resin composition, and specifically may be included in an amount of 50 to 90% by weight. When the solvent is included within the above range, since the photosensitive resin composition has an appropriate viscosity, processability is excellent in manufacturing the pattern layer.
- another embodiment of the present invention may provide a display device.
- a display device includes a first electrode 4 formed on a substrate 1 and a second electrode installed opposite to the first electrode ( 7) and a display device comprising a pattern or film formed of the photosensitive resin composition according to the present invention, wherein the pattern or film is a photosensitive resin comprising a polymer as an essential component of the structural unit represented by the formula (1) formed into a composition.
- the photosensitive resin composition is the same as the photosensitive resin composition according to the above-described embodiments of the present invention, it will be omitted.
- the display device may include an organic light emitting device and a color filter, and a color filter may be formed on the organic light emitting device by using the photosensitive composition of the present invention.
- the organic light emitting device may be divided into a red organic light emitting device, a green organic light emitting device, a blue organic light emitting device, an orange organic light emitting device, and a white organic light emitting device by the pixel separation unit 5 .
- a first electrode, an organic layer 6 and a second electrode may be sequentially stacked, and a sealing layer 8 including organic and inorganic materials is formed on the second electrode to protect from moisture and oxygen. can be blocked
- the color filter may be positioned on the sealing layer and include a color part 10 aligned in a vertical direction with the organic light emitting device and a color separation part 11 separating the color part.
- the photosensitive composition of the present invention is included in the color part or the color separation part to narrow the wavelength range of light emitted from the organic light emitting device to improve color purity, and to block light incident from the outside of the organic light emitting device to improve outdoor visibility can be improved
- the photosensitive composition of the present invention may include a red pigment or a red dye to form a red color part vertically aligned with the red organic light emitting diode.
- the photosensitive composition of the present invention may include a green pigment or a green dye to form a green color part vertically aligned with the green organic light emitting diode.
- the photosensitive composition of the present invention may include a blue pigment or a blue dye to form a blue color part vertically aligned with the blue organic light emitting diode.
- the photosensitive composition of the present invention may include a black pigment or a black dye to form a color separation unit vertically aligned with the pixel separation unit.
- the color part or the color separation part of the color filter When the color part or the color separation part of the color filter is formed using the photosensitive composition of the present invention, it has a low outgassing amount and can form a pattern of a fine size, so that a high resolution color filter can be manufactured.
- the display device may include a TFT layer 3 including a TFT (Thin Film Transistor: 2) between the substrate 1 and the first electrode 4, and includes a flattening layer 12 on the TFT layer. can do.
- the sealing layer 8 and the color filter may include several functional layers such as a TSP (Touch Screen Panel: 9) layer that allows the user to touch and manipulate the display device.
- the photosensitive composition of the present invention may be patterned on the TSP layer to form a color filter.
- the composition of the present invention may be patterned on the TSP layer to form a color part or a color separation part, and may be included in both the color part and the curlie separation part at the same time.
- Synthesis Example 16 (Polymer 2-1) Synthesis Example 17 (Polymer 2-2) Synthesis Example 18 (Polymer 2-3) Synthesis Example 19 (Polymer 2-4) Synthesis Example 20 (Polymer 2-5) Synthesis Example 21 (Polymer 2-6) Synthesis Example 22 (Polymer 2-7) polymer backbone Polymer 1-1 Polymer 1-2 Polymer 1-3 Polymer 1-4 Polymer 1-5 Polymer 1-6 Polymer 1-7 silane group compound 3-7 compound 3-7 compound 3-7 compound 3-7 compound 3-7 compound 3-7 compound 3-7 compound 3-7 weight average Molecular Weight 4,880 g/mol 4,250 g/mol 4,680 g/mol 4,430 g/mol 4,140 g/mol 5,270 g/mol 3,320 g/mol
- Synthesis Example 23 (Polymer 3-1) Synthesis Example 24 (Polymer 3-2) Synthesis Example 25 (Polymer 3-3) Synthesis Example 26 (Polymer 3-4) Synthesis Example 27 (Polymer 3-5) Synthesis Example 28 (Polymer 3-6) Synthesis Example 29 (Polymer 3-7) polymer backbone Polymer 1-1 Polymer 1-2 Polymer 1-3 Polymer 1-4 Polymer 1-5 Polymer 1-6 Polymer 1-7 silane group compound 3-1 compound 3-1 compound 3-1 compound 3-1 compound 3-1 compound 3-1 compound 3-1 weight average Molecular Weight 4,900 g/mol 4,280 g/mol 4,690 g/mol 4,470 g/mol 4,160 g/mol 5,290 g/mol 3,360 g/mol
- Synthesis Example 30 (Polymer 4-1) Synthesis Example 31 (Polymer 4-2) Synthesis Example 32 (Polymer 4-3) Synthesis Example 33 (Polymer 4-4) Synthesis Example 34 (Polymer 4-5) Synthesis Example 35 (Polymer 4-6) Synthesis Example 36 (Polymer 4-7) polymer backbone Polymer 1-1 Polymer 1-2 Polymer 1-3 Polymer 1-4 Polymer 1-5 Polymer 1-6 Polymer 1-7 silane group compound 3-4 compound 3-4 compound 3-4 compound 3-4 compound 3-4 compound 3-4 compound 3-4 compound 3-4 weight average Molecular Weight 4,900 g/mol 4,290 g/mol 4,690 g/mol 4,480 g/mol 4,180 g/mol 5,290 g/mol 3,380 g/mol
- Irgaphor Red BT-CF red pigment/BASF 15g
- Disperbyk 163 8.5g
- BYK Disperbyk 163 8.5g
- the maximum molar extinction coefficient of compound 5-3 prepared in Synthesis Example 40, OXE-02 (BASF), and 1-Hydroxycyclohexyl phenyl ketone in the 320 nm to 380 nm region was measured using a UV-Vis spectrometer UV-2600 (Shimadzu). was measured, and the 5% weight loss temperature of the three types of compounds was measured using TGA Q50 (TA), and the measured values are shown in Table 5.
- the temperature at which 5% weight loss occurs was 250° C. or higher, indicating a relatively high value compared to Compound 5-3, and 320 nm to 380
- the maximum molar extinction coefficient in the nm region was measured to be 21,000 (L/mol ⁇ cm) in the 338 nm wavelength region.
- Photosensitive composition solutions were prepared with the composition shown in Table 6 below.
- Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 Example 8 Example 9 Example 10 Red pigment dispersion of Preparation Example 1 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 compound 4-1 7 7 7 7 7 7 7 7 7 compound 5-3 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Polymer 1-1 7 - - - - - - - - Polymer 1-2 - 7 - - - - - - - - Polymer 1-3 - - 7 - - - - - - - Polymer 1-4 - - - 7 - - - - - - Polymer 1-5 - - - - 7 - - - - - Polymer 2-1 - - - - - - - - Polymer 2-2 - -
- Photosensitive composition solutions were prepared with the composition shown in Table 7 below.
- Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 Comparative Example 6 Comparative Example 7 Comparative Example 8 Comparative Example 9 Red pigment dispersion of Preparation Example 1 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30
- the manufacturing method of the light blocking layer using the composition solution according to Tables 6 and 7 is as follows (photolithography step).
- the above-described black photosensitive resin composition was applied to a washed 10 cm * 10 cm ITO/Ag substrate to a thickness of 1.5 ⁇ m using a spin coater, and then heated at a temperature of 100° C. for 1 minute to remove the solvent, thereby forming a coating film.
- a mask of a predetermined shape was interposed, and then actinic rays of 190 nm to 500 nm were irradiated.
- the exposure machine was MA-6, and the exposure amount was 100 mJ/cm 2 .
- the image pattern obtained by the above process was post-baking in an oven at 230°C for 30 minutes. did
- Example 1 Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 Example 8 Example 9 Example 10 Minimum pattern size on substrate ( ⁇ m) 5.2 5.4 5.5 5.6 5.6 3.6 3.8 4.0 4.2 4.3 Outgassing (ppm) 3.1 3.0 3.3 3.2 3.1 3.7 3.8 3.6 3.5 3.7
- Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 Comparative Example 6 Comparative Example 7 Comparative Example 8 Comparative Example 9 Minimum pattern size on substrate ( ⁇ m) 7.4 7.8 6.2 6.3 12.6 5.4 14.9 4.5 13.1 Outgassing (ppm) 3.4 3.1 4.1 3.9 4.8 8.9 3.2 9.2 3.7
- the minimum size (size) pattern on the substrate showed a small tendency. It is determined that, when a binder resin substituted with a silane group is used, the adhesion to the substrate is improved, so that the resolution of the final pattern after the PR process is improved, but the amount of outgas generated is also increased.
- Comparative Examples 1 to 4 of Table 9 also showed a similar tendency to Examples 1 to 10.
- Comparative Examples 3 and 4 using Polymers 2-6 and 2-7 substituted with a silane substituent compared with Comparative Examples 1 and 2 using Polymers 1-6 and 1-7 in which a silane substituent is not substituted, on the substrate As the size of the minimum size pattern became smaller, the resolution was improved, and it was confirmed that the amount of outgas generated was increased.
- a polymer backbone is formed by polymerizing one type of monomer, and has a relatively linear shape compared to Polymers 1-1 to 1-5 and Polymers 2-1 to 2-5 depending on the structure of the monomer.
- the polymer main chain is polymerized with three types of monomers having different structures to form Polymers 1-6, 1 It has a relatively reticulated structure compared to -7, 2-6 and 2-7.
- Polymers 1-1 to 1-5 and Polymers 2-1 to 2-5 are more suitable for a photolithography process by effectively intermolecular bonding with surrounding compounds due to their structural characteristics, and thus Examples 1 to 10 are comparative examples It is judged that the resolution of the developing process is higher than that of 1 to 4 in comparison, and the amount of outgas generation is low.
- Comparative Example 5 of Table 9 it can be seen that when an acrylic binder (SR-6100) is used as the binder resin, the resolution and outgas characteristics are significantly lowered compared to Examples 1 to 10 and Comparative Examples 1 to 4 there is.
- SR-6100 acrylic binder
- Example 1 of Table 6 and Comparative Examples 6 and 7 of Table 7 all contain the same alkali-soluble resin (Polymer 1-1), and contain different photoinitiators, respectively.
- compound 5-3 was used as a photoinitiator
- Comparative Examples 6 and 7 OXE-02 (BASF Corporation) and 1-Hydroxycyclohexyl phenyl ketone were used as photoinitiators, respectively.
- Compound 5-3 of the present invention is included in the condition that the maximum molar extinction coefficient in the region of 320 nm to 380 nm is 10,000 (L/mol ⁇ cm) or more, and the 5% by weight loss is 200° C. or less, and is not included in the above conditions It can be seen that the minimum pattern size on the substrate is small and outgas is generated less than the photoinitiators that do not, thereby greatly improving the resolution.
- Example 6 of Table 6 and Comparative Examples 8 and 9 of Table 7 all contain the same alkali-soluble resin (Polymer 2-1), and contain different photoinitiators, respectively.
- compound 5-3 was used as a photoinitiator
- Comparative Examples 8 and 9 OXE-02 (BASF) and 1-Hydroxycyclohexyl phenyl ketone were used as photoinitiators, respectively.
- TFT layer 4 1st electrode
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Abstract
Description
합성예 3 (Polymer 1-1) |
합성예 4 (Polymer 1-2) |
합성예 5 (Polymer 1-3) |
합성예 6 (Polymer 1-4) |
합성예 7 (Polymer 1-5) |
합성예 8 (Polymer 1-6) |
합성예 9 (Polymer 1-7) |
|
화합물 2-1 | 3 g | 1 g | 1 g | 4.25 g | 0.25 g | 5 g | 0 g |
화합물 2-2 | 1 g | 3 g | 1 g | 0.25 g | 4.25 g | 0 g | 5 g |
화합물 2-3 | 1 g | 1 g | 3 g | 0.5 g | 0.5 g | 0 g | 0 g |
무게 평균 분자량 |
4,800 g/mol | 4,200 g/mol | 4,600 g/mol | 4,400 g/mol | 4,100 g/mol | 5,200 g/mol | 3,300 g/mol |
합성예 16 (Polymer 2-1) |
합성예 17 (Polymer 2-2) |
합성예 18 (Polymer 2-3) |
합성예 19 (Polymer 2-4) |
합성예 20 (Polymer 2-5) |
합성예 21 (Polymer 2-6) |
합성예 22 (Polymer 2-7) |
|
Polymer backbone | Polymer 1-1 | Polymer 1-2 | Polymer 1-3 | Polymer 1-4 | Polymer 1-5 | Polymer 1-6 | Polymer 1-7 |
실란 그룹 | 화합물 3-7 | 화합물 3-7 | 화합물 3-7 | 화합물 3-7 | 화합물 3-7 | 화합물 3-7 | 화합물 3-7 |
무게 평균 분자량 |
4,880 g/mol | 4,250 g/mol | 4,680 g/mol | 4,430 g/mol | 4,140 g/mol | 5,270 g/mol | 3,320 g/mol |
합성예 23 (Polymer 3-1) |
합성예 24 (Polymer 3-2) |
합성예 25 (Polymer 3-3) |
합성예 26 (Polymer 3-4) |
합성예 27 (Polymer 3-5) |
합성예 28 (Polymer 3-6) |
합성예 29 (Polymer 3-7) |
|
Polymer backbone | Polymer 1-1 | Polymer 1-2 | Polymer 1-3 | Polymer 1-4 | Polymer 1-5 | Polymer 1-6 | Polymer 1-7 |
실란 그룹 | 화합물 3-1 | 화합물 3-1 | 화합물 3-1 | 화합물 3-1 | 화합물 3-1 | 화합물 3-1 | 화합물 3-1 |
무게 평균 분자량 |
4,900 g/mol | 4,280 g/mol | 4,690 g/mol | 4,470 g/mol | 4,160 g/mol | 5,290 g/mol | 3,360 g/mol |
합성예 30 (Polymer 4-1) |
합성예 31 (Polymer 4-2) |
합성예 32 (Polymer 4-3) |
합성예 33 (Polymer 4-4) |
합성예 34 (Polymer 4-5) |
합성예 35 (Polymer 4-6) |
합성예 36 (Polymer 4-7) |
|
Polymer backbone | Polymer 1-1 | Polymer 1-2 | Polymer 1-3 | Polymer 1-4 | Polymer 1-5 | Polymer 1-6 | Polymer 1-7 |
실란 그룹 | 화합물 3-4 | 화합물 3-4 | 화합물 3-4 | 화합물 3-4 | 화합물 3-4 | 화합물 3-4 | 화합물 3-4 |
무게 평균 분자량 |
4,900 g/mol | 4,290 g/mol | 4,690 g/mol | 4,480 g/mol | 4,180 g/mol | 5,290 g/mol | 3,380 g/mol |
5% 무게 감량 온도 (℃) | 320 nm 내지 380 nm 영역 최대 몰 흡광 계수 (L/㏖㎝) | |
화합물 5-3 | 188.53 | 16,000 (@332nm) |
OXE-02 (BASF社) | 250.13 | 21,000 (@338nm) |
1-Hydroxycyclohexyl phenyl ketone | 143.12 | 2,400 (@330nm)14,000 (@245nm) |
실시예 1 | 실시예 2 | 실시예 3 | 실시예 4 | 실시예 5 | 실시예 6 | 실시예 7 | 실시예 8 | 실시예 9 | 실시예 10 | |
제조예1의 적색 안료 분산액 | 30 | 30 | 30 | 30 | 30 | 30 | 30 | 30 | 30 | 30 |
화합물 4-1 | 7 | 7 | 7 | 7 | 7 | 7 | 7 | 7 | 7 | 7 |
화합물 5-3 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 |
Polymer 1-1 | 7 | - | - | - | - | - | - | - | - | - |
Polymer 1-2 | - | 7 | - | - | - | - | - | - | - | - |
Polymer 1-3 | - | - | 7 | - | - | - | - | - | - | - |
Polymer 1-4 | - | - | - | 7 | - | - | - | - | - | - |
Polymer 1-5 | - | - | - | - | 7 | - | - | - | - | - |
Polymer 2-1 | - | - | - | - | - | 7 | - | - | - | - |
Polymer 2-2 | - | - | - | - | - | - | 7 | - | - | - |
Polymer 2-3 | - | - | - | - | - | - | - | 7 | - | - |
Polymer 2-4 | - | - | - | - | - | - | - | - | 7 | - |
Polymer 2-5 | - | - | - | - | - | - | - | - | - | 7 |
프로필렌글리콜메틸에테르아세테이트 (다이셀社) | 55.5 | 55.5 | 55.5 | 55.5 | 55.5 | 55.5 | 55.5 | 55.5 | 55.5 | 55.5 |
비교예 1 | 비교예 2 | 비교예 3 | 비교예 4 | 비교예 5 | 비교예 6 | 비교예 7 | 비교예 8 | 비교예 9 | |
제조예1의 적색 안료 분산액 | 30 | 30 | 30 | 30 | 30 | 30 | 30 | 30 | 30 |
화합물 4-1 | 7 | 7 | 7 | 7 | 7 | 7 | 7 | 7 | 7 |
화합물 5-3 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | - | - | - | - |
OXE-02 (BASF社) | - | - | - | - | - | 0.5 | - | 0.5 | - |
1-Hydroxycyclohexyl phenyl ketone | - | - | - | - | - | - | 0.5 | - | 0.5 |
Polymer 1-1 | - | - | - | - | - | 7 | 7 | - | - |
Polymer 2-1 | - | - | - | - | - | - | - | 7 | 7 |
Polymer 1-6 | 7 | - | - | - | - | - | - | - | - |
Polymer 1-7 | - | 7 | - | - | - | - | - | - | - |
Polymer 2-6 | - | - | 7 | - | - | - | - | - | - |
Polymer 2-7 | - | - | - | 7 | - | - | - | - | - |
SR-6100 (SMS社) | - | - | - | - | 7 | - | - | - | - |
프로필렌글리콜메틸에테르아세테이트 (다이셀社) | 55.5 | 55.5 | 55.5 | 55.5 | 55.5 | 55.5 | 55.5 | 55.5 | 55.5 |
실시예 1 | 실시예 2 | 실시예 3 | 실시예 4 | 실시예 5 | 실시예 6 | 실시예 7 | 실시예 8 | 실시예 9 | 실시예 10 | |
기재 위 최소 패턴 크기 (㎛) | 5.2 | 5.4 | 5.5 | 5.6 | 5.6 | 3.6 | 3.8 | 4.0 | 4.2 | 4.3 |
아웃 가스 발생량 (ppm) | 3.1 | 3.0 | 3.3 | 3.2 | 3.1 | 3.7 | 3.8 | 3.6 | 3.5 | 3.7 |
비교예 1 | 비교예 2 | 비교예 3 | 비교예 4 | 비교예 5 | 비교예 6 | 비교예 7 | 비교예 8 | 비교예 9 | |
기재 위 최소 패턴 크기 (㎛) | 7.4 | 7.8 | 6.2 | 6.3 | 12.6 | 5.4 | 14.9 | 4.5 | 13.1 |
아웃 가스 발생량 (ppm) | 3.4 | 3.1 | 4.1 | 3.9 | 4.8 | 8.9 | 3.2 | 9.2 | 3.7 |
Claims (15)
- 알칼리 가용성 수지; 반응성 불포화 화합물; 320 nm 내지 380 nm 영역에서의 최대 몰 흡광 계수 (molar absorption coefficient)가 10,000 (L/㏖·㎝) 이상이고 5무게% 감량이 200℃ 이하에서 일어나는 광개시제; 착색제(Colorant); 및 용매를 포함하는 감광성 수지 조성물.
- 제 1 항에 있어서, 상기 알칼리 가용성 수지가 하기 화학식 (1)로 표시되는 반복단위를 포함하는 것을 특징으로 하는 감광성 수지 조성물;화학식 (1)상기 화학식 (1)에서,1) *는 반복단위로 결합이 연결되는 부분을 나타내고,2) R1 및 R2 는 서로 독립적으로 수소; 중수소; 할로겐; C6~C30의 아릴기; O, N, S, Si 및 P 중 적어도 하나의 헤테로원자를 포함하는 C2~C30의 헤테로고리기; C6~C30의 지방족고리와 방향족고리의 융합고리기; C1~C20의 알킬기; C2~C20의 알케닐기; C2~C20의 알킨일기; C1~C20의 알콕시기; C6~C30의 아릴옥시기; 플루오렌일기; 카르보닐기; 에테르기; 또는 C1~C20의 알콕시카르보닐기이며,3) R1 및 R2 는 각각 인접한 기와 고리 형성이 가능하고,4) a 및 b는 서로 독립적으로 0~4의 정수이며,5) X1은 단일결합, O, CO, SO2, CR'R", SiR'R", 화학식 (A) 또는 화학식 (B)이며,6) X2는 C6~C30의 아릴기; O, N, S, Si 및 P 중 적어도 하나의 헤테로원자를 포함하는 C2~C30의 헤테로고리기; C6~C30의 지방족고리와 방향족고리의 융합고리기; C1~C20의 알킬기; C2~C20의 알케닐기; C2~C20의 알킨일기; C1~C20의 알콕시기; C6~C30의 아릴옥시기; 또는 이들의 조합이며,7) R' 및 R"은 서로 독립적으로 수소; 중수소; 할로겐; C6~C30의 아릴기; O, N, S, Si 및 P 중 적어도 하나의 헤테로원자를 포함하는 C2~C30의 헤테로고리기; C6~C30의 지방족고리와 방향족고리의 융합고리기; C1~C20의 알킬기; C2~C20의 알케닐기; C2~C20의 알킨일기; C1~C20의 알콕시기; C6~C30의 아릴옥시기; 플루오렌일기; 카르보닐기; 에테르기; 또는 C1~C20의 알콕시카르보닐기이고,8) R' 및 R"는 각각 인접한 기와 고리를 형성할 수 있으며,9) A1 및 A2는 서로 독립적으로 화학식 (C) 또는 화학식 (D)이고,10) 화학식 (1)로 표시되는 반복 단위를 포함하는 수지의 고분자 사슬 내에 화학식 (C)와 화학식 (D)의 비율은 1:9 내지 9:1을 만족하며,화학식 (A)화학식 (B)상기 화학식 (A) 및 화학식 (B)에서,11-1) *는 결합 위치를 나타내고,11-2) X3는 O, S, SO2 또는 NR'이며,11-3) R'는 수소; 중수소; 할로겐; C6~C30의 아릴기; O, N, S, Si 및 P 중 적어도 하나의 헤테로원자를 포함하는 C2~C30의 헤테로고리기; C6~C30의 지방족고리와 방향족고리의 융합고리기; C1~C20의 알킬기; C2~C20의 알케닐기; C2~C20의 알킨일기; C1~C20의 알콕시기; C6~C30의 아릴옥시기; 플루오렌일기; 카르보닐기; 에테르기; 또는 C1~C20의 알콕시카르보닐기이고,11-4) R3~R6는 서로 독립적으로 수소; 중수소; 할로겐; C6~C30의 아릴기; O, N, S, Si 및 P 중 적어도 하나의 헤테로원자를 포함하는 C2~C30의 헤테로고리기; C6~C30의 지방족고리와 방향족고리의 융합고리기; C1~C20의 알킬기; C2~C20의 알케닐기; C2~C20의 알킨일기; C1~C20의 알콕시기; C6~C30의 아릴옥시기; 플루오렌일기; 카르보닐기; 에테르기; 또는 C1~C20의 알콕시카르보닐기이며,11-5) R3~R6은 각각 인접한 기와 고리 형성이 가능하며,11-6) c~f는 서로 독립적으로 0~4의 정수이고,화학식 (C)화학식 (D)상기 화학식 (C) 및 화학식 (D)에서,12-1) *는 결합 위치를 나타내고,12-2) R7~R10은 서로 독립적으로 수소; 중수소; 할로겐; C6~C30의 아릴기; O, N, S, Si 및 P 중 적어도 하나의 헤테로원자를 포함하는 C2~C30의 헤테로고리기; C6~C30의 지방족고리와 방향족고리의 융합고리기; C1~C20의 알킬기; C2~C20의 알케닐기; C2~C20의 알킨일기; C1~C20의 알콕시기; C6~C30의 아릴옥시기; 플루오렌일기; 카르보닐기; 에테르기; 또는 C1~C20의 알콕시카르보닐기이며,12-3) Y1 및 Y2는 서로 독립적으로 화학식 (E) 또는 화학식 (F)이고,화학식 (E)화학식 (F)상기 화학식 (E) 및 화학식 (F)에서,13-1) *는 결합 위치를 나타내고,13-2) R11~R15은 서로 독립적으로 수소; 중수소; 할로겐; C6~C30의 아릴기; O, N, S, Si 및 P 중 적어도 하나의 헤테로원자를 포함하는 C2~C30의 헤테로고리기; C6~C30의 지방족고리와 방향족고리의 융합고리기; C1~C20의 알킬기; C2~C20의 알케닐기; C2~C20의 알킨일기; C1~C20의 알콕시기; C6~C30의 아릴옥시기; 플루오렌일기; 카르보닐기; 에테르기; 또는 C1~C20의 알콕시카르보닐기이며,13-3) L1~L3은 서로 독립적으로 단일결합, C1~C30의 알킬렌, C6~C30의 아릴렌 또는 C2~C30의 헤테로고리이고,13-4) g 및 h는 서로 독립적으로 0~3의 정수이고; 단, g+h= 3 이며,14) 상기 R1~R15, R', R", X1~X2 및 L1~L3 및 이웃한 기끼리 서로 결합하여 형성한 고리는 각각 중수소; 할로겐; C1~C30의 알킬기 또는 C6~C30의 아릴기로 치환 또는 비치환된 실란기; 실록산기; 붕소기; 게르마늄기; 시아노기; 아미노기; 니트로기; C1~C30의 알킬싸이오기; C1~C30의 알콕시기; C6~C30의 아릴알콕시기; C1~C30의 알킬기; C2~C30의 알켄일기; C2~C30의 알킨일기; C6~C30의 아릴기; 중수소로 치환된 C6~C30의 아릴기; 플루오렌일기; O, N, S, Si 및 P로 이루어진 군에서 선택된 적어도 하나의 헤테로원자를 포함하는 C2~C30의 헤테로고리기; C3~C30의 지방족고리기; C7~C30의 아릴알킬기; C8~C30의 아릴알켄일기; 및 이들의 조합으로 이루어진 군에서 선택된 하나 이상의 치환기로 더 치환될 수 있고, 인접한 치환기끼리 고리를 형성할 수 있다.
- 제 1 항에 있어서, 상기 알칼리 가용성 수지의 무게평균 분자량이 1,000 내지 100,000 g/mol인 것을 특징으로 하는 감광성 수지 조성물.
- 제 1 항에 있어서, 상기 화학식 (1)로 표시되는 반복단위를 포함하는 수지의 고분자 사슬 내에 화학식 (E)와 화학식 (F)의 비율이 2:0 내지 1:1 것을 특징으로 하는 감광성 수지 조성물.
- 제 1 항에 있어서, 상기 반응성 불포화 화합물이 상기 감광성 수지 조성물 총량에 대하여 1 내지 40 중량%로 포함되는 것을 특징으로 하는 감광성 수지 조성물,
- 제 1 항에 있어서, 상기 반응성 불포화 화합물이 하기 화학식 (2)로 표시되는 화합물을 포함하는 것을 특징으로 하는 감광성 수지 조성물:화학식 (2)상기 화학식 (2)에서, Z1~Z4 중 2개 이상이 서로 독립적으로 하기 화학식 (G)의 구조를 가지며; 나머지 Z1~Z4는 서로 독립적으로 수소, 중수소, 할로겐, 메틸기, 에틸기; 메틸히드록시기; C6~C30의 아릴기; O, N, S, Si 및 P 중 적어도 하나의 헤테로원자를 포함하는 C2~C30의 헤테로고리기; C6~C30의 지방족고리와 방향족고리의 융합고리기; C1~C20의 알킬기; C2~C20의 알케닐기; C2~C20의 알킨일기; C1~C20의 알콕시기; C6~C30의 아릴옥시기; 플루오렌일기; 카르보닐기; 에테르기; 또는 C1~C20의 알콕시카르보닐기이며,화학식 (G)상기 화학식 (G)에서,1) t는 1~20의 정수이고,2) L4는 단일결합, C1~C30의 알킬렌, C6~C30의 아릴렌 또는 C2~C30의 헤테로고리이고,3) Y3는 하기 화학식 (H) 또는 화학식 (I)이며,화학식 (H)화학식 (I)상기 화학식 (H)에서, R21은 수소, 중수소, 할로겐, 메틸기, 에틸기; 메틸히드록시기; C6~C30의 아릴기; O, N, S, Si 및 P 중 적어도 하나의 헤테로원자를 포함하는 C2~C30의 헤테로고리기; C6~C30의 지방족고리와 방향족고리의 융합고리기; C1~C20의 알킬기; C2~C20의 알케닐기; C2~C20의 알킨일기; C1~C20의 알콕시기; C6~C30의 아릴옥시기; 플루오렌일기; 카르보닐기; 에테르기; 또는 C1~C20의 알콕시카르보닐기이다.
- 제 1 항에 있어서, 상기 착색제가 상기 감광성 수지 조성물 총량에 대하여 5 내지 40 중량%로 포함되는 것을 특징으로 하는 감광성 수지 조성물.
- 제 1 항에 있어서, 상기 착색제가 흑색, 적색, 청색, 녹색, 황색, 자주색, 오렌지색, 백색, 은색 또는 금색의 무기염료, 유기염료, 무기안료 및 유기안료 중 적어도 하나 이상을 포함하는 것을 특징으로 하는 감광성 수지 조성물.
- 제 1 항에 있어서, 상기 광개시제가 상기 감광성 수지 조성물 총량에 대하여 0.01 내지 10 중량%로 포함되는 것을 특징으로 하는 감광성 수지 조성물.
- 제 1 항에 있어서, 상기 개시제가 하기 화학식 (3)으로 표시되는 화합물을 포함하는 것을 특징으로 하는 수지 조성물:화학식 (3)상기 화학식 (3)에서,1) u1~u3은 서로 독립적으로 0 또는 1의 정수이고,2) L5 및 L8은 하기 화학식 (J)이고,3) L6, L7 및 L9는 서로 독립적으로 C6~C30의 아릴기; O, N, S, Si 및 P 중 적어도 하나의 헤테로원자를 포함하는 C2~C30의 헤테로고리기; C6~C30의 지방족고리와 방향족고리의 융합고리기; C3~C30의 지방족고리기 C1~C20의 알킬기; C2~C20의 알케닐기; C2~C20의 알킨일기; C1~C20의 알콕시기; C6~C30의 아릴옥시기; 플루오렌일기; 카르보닐기; 에테르기; C1~C20의 알콕시카르보닐; C1~C30의 알킬렌 또는 C6~C30의 아릴렌이며,화학식 (J)상기 화학식 (J)에서, R31은 수소, 중수소, 할로겐, 메틸기, 에틸기; 메틸히드록시기; C6~C30의 아릴기; O, N, S, Si 및 P 중 적어도 하나의 헤테로원자를 포함하는 C2~C30의 헤테로고리기; C6~C30의 지방족고리와 방향족고리의 융합고리기; C1~C20의 알킬기; C2~C20의 알케닐기; C2~C20의 알킨일기; C1~C20의 알콕시기; C6~C30의 아릴옥시기; 플루오렌일기; 카르보닐기; 에테르기; 또는 C1~C20의 알콕시카르보닐기이다.
- 제 10 항에 있어서, 상기 화학식 (3)의 L6, L7 및 L9가 서로 독립적으로 하기 화학식 (K) 내지 화학식 (N) 중 하나인 것을 특징으로 하는 감광성 수지 조성물:화학식 (K)화학식 (L)화학식 (M)화학식 (N)상기 화학식 (M) 및 화학식 (N)에서,1) A는 수소; O; S; 실란기; 실록산기; 붕소기; 게르마늄기; 시아노기; 니트로기; 니트릴기; C1~C30의 알킬기, C6~C30의 아릴기 또는 C2~C30의 헤테로고리기로 치환 또는 비치환된 아미노기; C1~C30의 알킬싸이오기; C1~C30의 알킬기; C1~C30의 알콕시기; C6~C30의 아릴알콕시기; C2~C30의 알켄일기; C2~C30의 알킨일기; C6~C30의 아릴기; 중수소로 치환된 C6~C30의 아릴기; 플루오렌일기; O, N, S, Si 및 P로 이루어진 군에서 선택된 적어도 하나의 헤테로원자를 포함하는 C2~C30의 헤테로고리기; C3~C30의 지방족고리기; C7~C30의 아릴알킬기; C8~C30의 아릴알켄일기; 및 이들의 조합이고,2) R32~R34는 서로 독립적으로 수소; 중수소; 할로겐; C6~C30의 아릴기; O, N, S, Si 및 P 중 적어도 하나의 헤테로원자를 포함하는 C2~C30의 헤테로고리기; C6~C30의 지방족고리와 방향족고리의 융합고리기; C1~C20의 알킬기; C2~C20의 알케닐기; C2~C20의 알킨일기; C1~C20의 알콕시기; C6~C30의 아릴옥시기; 플루오렌일기; 카르보닐기; 에테르기; 또는 C1~C20의 알콕시카르보닐기이며,3) T는 S, O 또는 Se이다.
- 제 1 항에 따른 감광성 조성물로 형성된 패턴 또는 필름.
- 기판 상에 형성된 제 1 전극과, 제 1 전극에 대향하여 설치된 제2 전극과, 제 1 항에 따른 감광성 수지 조성물로 형성된 패턴 또는 필름을 포함하는 것을 특징으로 하는 표시장치.
- 제 13 항에 있어서, 상기 패턴이 컬러부 또는 컬러분리부인 것을 특징으로 하는 표시장치.
- 제 13 항의 표시장치 및 상기 표시장치를 구동하는 제어부;를 포함하는 전자장치.
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US (1) | US20230408914A1 (ko) |
KR (1) | KR20220045693A (ko) |
CN (1) | CN116670589A (ko) |
WO (1) | WO2022075673A1 (ko) |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2010037223A (ja) * | 2008-08-01 | 2010-02-18 | Toyo Ink Mfg Co Ltd | 新規オキシムエステル化合物およびそれを含んでなるラジカル重合開始剤および重合性組成物 |
JP2010091753A (ja) * | 2008-10-08 | 2010-04-22 | Toyo Ink Mfg Co Ltd | 重合性組成物およびそれを用いたネガ型レジストおよびそれを用いた画像パターン形成方法。 |
KR20120009736A (ko) * | 2010-07-21 | 2012-02-02 | 주식회사 엘지화학 | 광중합 개시제 및 이를 이용한 감광성 수지 조성물 |
KR20160085409A (ko) * | 2015-01-07 | 2016-07-18 | 삼성디스플레이 주식회사 | 포토레지스트 조성물 및 이를 이용한 블랙 매트릭스의 제조방법 |
KR20200011477A (ko) * | 2017-07-13 | 2020-02-03 | 후지필름 가부시키가이샤 | 조성물, 막, 적외선 투과 필터, 고체 촬상 소자, 화상 표시 장치 및 적외선 센서 |
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- 2020-10-06 KR KR1020200128620A patent/KR20220045693A/ko active Search and Examination
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- 2021-10-04 CN CN202180067925.6A patent/CN116670589A/zh active Pending
- 2021-10-04 US US18/247,703 patent/US20230408914A1/en active Pending
- 2021-10-04 WO PCT/KR2021/013547 patent/WO2022075673A1/ko active Application Filing
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010037223A (ja) * | 2008-08-01 | 2010-02-18 | Toyo Ink Mfg Co Ltd | 新規オキシムエステル化合物およびそれを含んでなるラジカル重合開始剤および重合性組成物 |
JP2010091753A (ja) * | 2008-10-08 | 2010-04-22 | Toyo Ink Mfg Co Ltd | 重合性組成物およびそれを用いたネガ型レジストおよびそれを用いた画像パターン形成方法。 |
KR20120009736A (ko) * | 2010-07-21 | 2012-02-02 | 주식회사 엘지화학 | 광중합 개시제 및 이를 이용한 감광성 수지 조성물 |
KR20160085409A (ko) * | 2015-01-07 | 2016-07-18 | 삼성디스플레이 주식회사 | 포토레지스트 조성물 및 이를 이용한 블랙 매트릭스의 제조방법 |
KR20200011477A (ko) * | 2017-07-13 | 2020-02-03 | 후지필름 가부시키가이샤 | 조성물, 막, 적외선 투과 필터, 고체 촬상 소자, 화상 표시 장치 및 적외선 센서 |
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CN116670589A (zh) | 2023-08-29 |
US20230408914A1 (en) | 2023-12-21 |
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