WO2022044566A1 - 水溶性金属加工油剤 - Google Patents
水溶性金属加工油剤 Download PDFInfo
- Publication number
- WO2022044566A1 WO2022044566A1 PCT/JP2021/025922 JP2021025922W WO2022044566A1 WO 2022044566 A1 WO2022044566 A1 WO 2022044566A1 JP 2021025922 W JP2021025922 W JP 2021025922W WO 2022044566 A1 WO2022044566 A1 WO 2022044566A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- mass
- water
- oil
- soluble
- less
- Prior art date
Links
- 238000005555 metalworking Methods 0.000 title claims abstract description 107
- 239000012530 fluid Substances 0.000 title abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 61
- 229920001515 polyalkylene glycol Polymers 0.000 claims abstract description 45
- 239000002199 base oil Substances 0.000 claims abstract description 16
- 239000003921 oil Substances 0.000 claims description 207
- 229910052751 metal Inorganic materials 0.000 claims description 141
- 239000002184 metal Substances 0.000 claims description 141
- 238000012545 processing Methods 0.000 claims description 140
- 239000003795 chemical substances by application Substances 0.000 claims description 80
- 239000007788 liquid Substances 0.000 claims description 64
- -1 amine compound Chemical class 0.000 claims description 59
- 239000000194 fatty acid Substances 0.000 claims description 43
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 39
- 229930195729 fatty acid Natural products 0.000 claims description 39
- 150000004665 fatty acids Chemical class 0.000 claims description 31
- 239000000463 material Substances 0.000 claims description 25
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 20
- 239000011593 sulfur Substances 0.000 claims description 20
- 229910052717 sulfur Inorganic materials 0.000 claims description 20
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 19
- 230000007797 corrosion Effects 0.000 claims description 17
- 238000005260 corrosion Methods 0.000 claims description 17
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 15
- 229910052802 copper Inorganic materials 0.000 claims description 15
- 239000010949 copper Substances 0.000 claims description 15
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 12
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 10
- 238000003672 processing method Methods 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 9
- 239000002736 nonionic surfactant Substances 0.000 claims description 7
- 229910052742 iron Inorganic materials 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 239000010751 BS 2869 Class A2 Substances 0.000 claims description 2
- 150000002334 glycols Chemical class 0.000 abstract description 3
- 235000019198 oils Nutrition 0.000 description 190
- 239000002253 acid Substances 0.000 description 22
- 125000000217 alkyl group Chemical group 0.000 description 18
- 150000001412 amines Chemical class 0.000 description 15
- 239000000839 emulsion Substances 0.000 description 14
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 13
- 238000000034 method Methods 0.000 description 11
- 239000002480 mineral oil Substances 0.000 description 11
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 10
- 239000004615 ingredient Substances 0.000 description 9
- 235000010446 mineral oil Nutrition 0.000 description 9
- 239000000654 additive Substances 0.000 description 8
- 125000001424 substituent group Chemical group 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 125000003342 alkenyl group Chemical group 0.000 description 6
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 238000002834 transmittance Methods 0.000 description 6
- 239000004711 α-olefin Substances 0.000 description 6
- 150000005215 alkyl ethers Chemical class 0.000 description 5
- 230000000844 anti-bacterial effect Effects 0.000 description 5
- 239000002518 antifoaming agent Substances 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 125000000753 cycloalkyl group Chemical group 0.000 description 5
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- 239000003945 anionic surfactant Substances 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 239000010779 crude oil Substances 0.000 description 4
- 238000005520 cutting process Methods 0.000 description 4
- 238000007865 diluting Methods 0.000 description 4
- 238000010790 dilution Methods 0.000 description 4
- 239000012895 dilution Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 238000004448 titration Methods 0.000 description 4
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 3
- HHPDFYDITNAMAM-UHFFFAOYSA-N 2-[cyclohexyl(2-hydroxyethyl)amino]ethanol Chemical compound OCCN(CCO)C1CCCCC1 HHPDFYDITNAMAM-UHFFFAOYSA-N 0.000 description 3
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 3
- GSCCALZHGUWNJW-UHFFFAOYSA-N N-Cyclohexyl-N-methylcyclohexanamine Chemical compound C1CCCCC1N(C)C1CCCCC1 GSCCALZHGUWNJW-UHFFFAOYSA-N 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- WUGQZFFCHPXWKQ-UHFFFAOYSA-N Propanolamine Chemical compound NCCCO WUGQZFFCHPXWKQ-UHFFFAOYSA-N 0.000 description 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 3
- 125000002947 alkylene group Chemical group 0.000 description 3
- 239000003242 anti bacterial agent Substances 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- CREXVNNSNOKDHW-UHFFFAOYSA-N azaniumylideneazanide Chemical group N[N] CREXVNNSNOKDHW-UHFFFAOYSA-N 0.000 description 3
- 239000004359 castor oil Substances 0.000 description 3
- 235000019438 castor oil Nutrition 0.000 description 3
- 238000002845 discoloration Methods 0.000 description 3
- 238000004945 emulsification Methods 0.000 description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 239000012188 paraffin wax Substances 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 3
- 229960003656 ricinoleic acid Drugs 0.000 description 3
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000011550 stock solution Substances 0.000 description 3
- 239000001993 wax Substances 0.000 description 3
- MGUMZJAQENFQKN-UHFFFAOYSA-N 2-(cyclohexylamino)ethanol Chemical class OCCNC1CCCCC1 MGUMZJAQENFQKN-UHFFFAOYSA-N 0.000 description 2
- GJYCVCVHRSWLNY-UHFFFAOYSA-N 2-butylphenol Chemical compound CCCCC1=CC=CC=C1O GJYCVCVHRSWLNY-UHFFFAOYSA-N 0.000 description 2
- YLAXZGYLWOGCBF-UHFFFAOYSA-N 2-dodecylbutanedioic acid Chemical compound CCCCCCCCCCCCC(C(O)=O)CC(O)=O YLAXZGYLWOGCBF-UHFFFAOYSA-N 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- XQVWYOYUZDUNRW-UHFFFAOYSA-N N-Phenyl-1-naphthylamine Chemical compound C=1C=CC2=CC=CC=C2C=1NC1=CC=CC=C1 XQVWYOYUZDUNRW-UHFFFAOYSA-N 0.000 description 2
- OPKOKAMJFNKNAS-UHFFFAOYSA-N N-methylethanolamine Chemical compound CNCCO OPKOKAMJFNKNAS-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 150000003973 alkyl amines Chemical class 0.000 description 2
- 150000004996 alkyl benzenes Chemical class 0.000 description 2
- MBMBGCFOFBJSGT-KUBAVDMBSA-N all-cis-docosa-4,7,10,13,16,19-hexaenoic acid Chemical compound CC\C=C/C\C=C/C\C=C/C\C=C/C\C=C/C\C=C/CCC(O)=O MBMBGCFOFBJSGT-KUBAVDMBSA-N 0.000 description 2
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 2
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 2
- YZXBAPSDXZZRGB-DOFZRALJSA-N arachidonic acid Chemical compound CCCCC\C=C/C\C=C/C\C=C/C\C=C/CCCC(O)=O YZXBAPSDXZZRGB-DOFZRALJSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000004985 diamines Chemical class 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- KEMQGTRYUADPNZ-UHFFFAOYSA-N heptadecanoic acid Chemical compound CCCCCCCCCCCCCCCCC(O)=O KEMQGTRYUADPNZ-UHFFFAOYSA-N 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 230000000415 inactivating effect Effects 0.000 description 2
- 239000008235 industrial water Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 2
- ISYWECDDZWTKFF-UHFFFAOYSA-N nonadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCCC(O)=O ISYWECDDZWTKFF-UHFFFAOYSA-N 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 229920000768 polyamine Polymers 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 238000010079 rubber tapping Methods 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 150000003871 sulfonates Chemical class 0.000 description 2
- 239000003784 tall oil Substances 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
- SZHOJFHSIKHZHA-UHFFFAOYSA-N tridecanoic acid Chemical compound CCCCCCCCCCCCC(O)=O SZHOJFHSIKHZHA-UHFFFAOYSA-N 0.000 description 2
- ZDPHROOEEOARMN-UHFFFAOYSA-N undecanoic acid Chemical compound CCCCCCCCCCC(O)=O ZDPHROOEEOARMN-UHFFFAOYSA-N 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- GWHCXVQVJPWHRF-KTKRTIGZSA-N (15Z)-tetracosenoic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCCCC(O)=O GWHCXVQVJPWHRF-KTKRTIGZSA-N 0.000 description 1
- OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical compound CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 description 1
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- GYSCBCSGKXNZRH-UHFFFAOYSA-N 1-benzothiophene-2-carboxamide Chemical compound C1=CC=C2SC(C(=O)N)=CC2=C1 GYSCBCSGKXNZRH-UHFFFAOYSA-N 0.000 description 1
- FRPZMMHWLSIFAZ-UHFFFAOYSA-N 10-undecenoic acid Chemical compound OC(=O)CCCCCCCCC=C FRPZMMHWLSIFAZ-UHFFFAOYSA-N 0.000 description 1
- QFGCFKJIPBRJGM-UHFFFAOYSA-N 12-[(2-methylpropan-2-yl)oxy]-12-oxododecanoic acid Chemical compound CC(C)(C)OC(=O)CCCCCCCCCCC(O)=O QFGCFKJIPBRJGM-UHFFFAOYSA-N 0.000 description 1
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 1
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical class CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 1
- DKCPKDPYUFEZCP-UHFFFAOYSA-N 2,6-di-tert-butylphenol Chemical compound CC(C)(C)C1=CC=CC(C(C)(C)C)=C1O DKCPKDPYUFEZCP-UHFFFAOYSA-N 0.000 description 1
- NEYNUNUKSPDPJM-UHFFFAOYSA-N 2-(16-methylheptadecyl)butanedioic acid Chemical compound CC(C)CCCCCCCCCCCCCCCC(C(O)=O)CC(O)=O NEYNUNUKSPDPJM-UHFFFAOYSA-N 0.000 description 1
- XNIOWJUQPMKCIJ-UHFFFAOYSA-N 2-(benzylamino)ethanol Chemical class OCCNCC1=CC=CC=C1 XNIOWJUQPMKCIJ-UHFFFAOYSA-N 0.000 description 1
- LJDSTRZHPWMDPG-UHFFFAOYSA-N 2-(butylamino)ethanol Chemical compound CCCCNCCO LJDSTRZHPWMDPG-UHFFFAOYSA-N 0.000 description 1
- LLTGNYZQUXACFO-UHFFFAOYSA-N 2-(dicyclohexylamino)ethanol Chemical compound C1CCCCC1N(CCO)C1CCCCC1 LLTGNYZQUXACFO-UHFFFAOYSA-N 0.000 description 1
- MIJDSYMOBYNHOT-UHFFFAOYSA-N 2-(ethylamino)ethanol Chemical compound CCNCCO MIJDSYMOBYNHOT-UHFFFAOYSA-N 0.000 description 1
- YGCMLNDQGHTAPC-UHFFFAOYSA-N 2-(octadecylamino)ethanol Chemical compound CCCCCCCCCCCCCCCCCCNCCO YGCMLNDQGHTAPC-UHFFFAOYSA-N 0.000 description 1
- UVYBWDBLVDZIOX-UHFFFAOYSA-N 2-(octylamino)ethanol Chemical compound CCCCCCCCNCCO UVYBWDBLVDZIOX-UHFFFAOYSA-N 0.000 description 1
- BCLSJHWBDUYDTR-UHFFFAOYSA-N 2-(propylamino)ethanol Chemical compound CCCNCCO BCLSJHWBDUYDTR-UHFFFAOYSA-N 0.000 description 1
- KIHBGTRZFAVZRV-UHFFFAOYSA-N 2-Hydroxyoctadecanoic acid Natural products CCCCCCCCCCCCCCCCC(O)C(O)=O KIHBGTRZFAVZRV-UHFFFAOYSA-N 0.000 description 1
- NDLNTMNRNCENRZ-UHFFFAOYSA-N 2-[2-hydroxyethyl(octadecyl)amino]ethanol Chemical compound CCCCCCCCCCCCCCCCCCN(CCO)CCO NDLNTMNRNCENRZ-UHFFFAOYSA-N 0.000 description 1
- QZQNMMLYACBCMJ-UHFFFAOYSA-N 2-[2-hydroxyethyl(octyl)amino]ethanol Chemical compound CCCCCCCCN(CCO)CCO QZQNMMLYACBCMJ-UHFFFAOYSA-N 0.000 description 1
- OZICRFXCUVKDRG-UHFFFAOYSA-N 2-[2-hydroxyethyl(propyl)amino]ethanol Chemical compound CCCN(CCO)CCO OZICRFXCUVKDRG-UHFFFAOYSA-N 0.000 description 1
- BITAPBDLHJQAID-KTKRTIGZSA-N 2-[2-hydroxyethyl-[(z)-octadec-9-enyl]amino]ethanol Chemical compound CCCCCCCC\C=C/CCCCCCCCN(CCO)CCO BITAPBDLHJQAID-KTKRTIGZSA-N 0.000 description 1
- MIZIOHLLYXVEHJ-UHFFFAOYSA-N 2-[benzyl(2-hydroxyethyl)amino]ethanol Chemical compound OCCN(CCO)CC1=CC=CC=C1 MIZIOHLLYXVEHJ-UHFFFAOYSA-N 0.000 description 1
- GVNHOISKXMSMPX-UHFFFAOYSA-N 2-[butyl(2-hydroxyethyl)amino]ethanol Chemical compound CCCCN(CCO)CCO GVNHOISKXMSMPX-UHFFFAOYSA-N 0.000 description 1
- OJPDDQSCZGTACX-UHFFFAOYSA-N 2-[n-(2-hydroxyethyl)anilino]ethanol Chemical compound OCCN(CCO)C1=CC=CC=C1 OJPDDQSCZGTACX-UHFFFAOYSA-N 0.000 description 1
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 description 1
- MWGATWIBSKHFMR-UHFFFAOYSA-N 2-anilinoethanol Chemical class OCCNC1=CC=CC=C1 MWGATWIBSKHFMR-UHFFFAOYSA-N 0.000 description 1
- RPGJJWLCCOPDAZ-UHFFFAOYSA-N 2-hydroxybehenic acid Chemical compound CCCCCCCCCCCCCCCCCCCCC(O)C(O)=O RPGJJWLCCOPDAZ-UHFFFAOYSA-N 0.000 description 1
- YDZIJQXINJLRLL-UHFFFAOYSA-N 2-hydroxydodecanoic acid Chemical compound CCCCCCCCCCC(O)C(O)=O YDZIJQXINJLRLL-UHFFFAOYSA-N 0.000 description 1
- JGHSBPIZNUXPLA-UHFFFAOYSA-N 2-hydroxyhexadecanoic acid Chemical compound CCCCCCCCCCCCCCC(O)C(O)=O JGHSBPIZNUXPLA-UHFFFAOYSA-N 0.000 description 1
- JYZJYKOZGGEXSX-UHFFFAOYSA-N 2-hydroxymyristic acid Chemical compound CCCCCCCCCCCCC(O)C(O)=O JYZJYKOZGGEXSX-UHFFFAOYSA-N 0.000 description 1
- JPUHAXBCXWSQMM-UHFFFAOYSA-N 2-hydroxyoctadec-2-enoic acid Chemical compound CCCCCCCCCCCCCCCC=C(O)C(O)=O JPUHAXBCXWSQMM-UHFFFAOYSA-N 0.000 description 1
- ZPJDFKVKOFGAFV-UHFFFAOYSA-N 2-octadecylbutanedioic acid Chemical compound CCCCCCCCCCCCCCCCCCC(C(O)=O)CC(O)=O ZPJDFKVKOFGAFV-UHFFFAOYSA-N 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- FDVCQFAKOKLXGE-UHFFFAOYSA-N 216978-79-9 Chemical compound C1CC(C)(C)C2=CC(C=O)=CC3=C2N1CCC3(C)C FDVCQFAKOKLXGE-UHFFFAOYSA-N 0.000 description 1
- WXBXVVIUZANZAU-UHFFFAOYSA-N 2E-decenoic acid Natural products CCCCCCCC=CC(O)=O WXBXVVIUZANZAU-UHFFFAOYSA-N 0.000 description 1
- DFOAUWHTDKZVPW-UHFFFAOYSA-N 3-(cyclohexylamino)propan-1-ol Chemical compound OCCCNC1CCCCC1 DFOAUWHTDKZVPW-UHFFFAOYSA-N 0.000 description 1
- GUUULVAMQJLDSY-UHFFFAOYSA-N 4,5-dihydro-1,2-thiazole Chemical compound C1CC=NS1 GUUULVAMQJLDSY-UHFFFAOYSA-N 0.000 description 1
- BLFRQYKZFKYQLO-UHFFFAOYSA-N 4-aminobutan-1-ol Chemical compound NCCCCO BLFRQYKZFKYQLO-UHFFFAOYSA-N 0.000 description 1
- YPIFGDQKSSMYHQ-UHFFFAOYSA-N 7,7-dimethyloctanoic acid Chemical compound CC(C)(C)CCCCCC(O)=O YPIFGDQKSSMYHQ-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- DPUOLQHDNGRHBS-UHFFFAOYSA-N Brassidinsaeure Natural products CCCCCCCCC=CCCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- GHVNFZFCNZKVNT-UHFFFAOYSA-N Decanoic acid Natural products CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 1
- LVGKNOAMLMIIKO-UHFFFAOYSA-N Elaidinsaeure-aethylester Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC LVGKNOAMLMIIKO-UHFFFAOYSA-N 0.000 description 1
- AFSDNFLWKVMVRB-UHFFFAOYSA-N Ellagic acid Chemical compound OC1=C(O)C(OC2=O)=C3C4=C2C=C(O)C(O)=C4OC(=O)C3=C1 AFSDNFLWKVMVRB-UHFFFAOYSA-N 0.000 description 1
- ATJXMQHAMYVHRX-CPCISQLKSA-N Ellagic acid Natural products OC1=C(O)[C@H]2OC(=O)c3cc(O)c(O)c4OC(=O)C(=C1)[C@H]2c34 ATJXMQHAMYVHRX-CPCISQLKSA-N 0.000 description 1
- 229920002079 Ellagic acid Polymers 0.000 description 1
- URXZXNYJPAJJOQ-UHFFFAOYSA-N Erucic acid Natural products CCCCCCC=CCCCCCCCCCCCC(O)=O URXZXNYJPAJJOQ-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- OPGOLNDOMSBSCW-CLNHMMGSSA-N Fursultiamine hydrochloride Chemical compound Cl.C1CCOC1CSSC(\CCO)=C(/C)N(C=O)CC1=CN=C(C)N=C1N OPGOLNDOMSBSCW-CLNHMMGSSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 229910001182 Mo alloy Inorganic materials 0.000 description 1
- WOPLGMOOHTVXMC-KTKRTIGZSA-N N-[(Z)-octadec-9-enyl]cyclohexanamine Chemical compound CCCCCCCC/C=C\CCCCCCCCNC1CCCCC1 WOPLGMOOHTVXMC-KTKRTIGZSA-N 0.000 description 1
- ZHMPWNLQHMUFFG-KTKRTIGZSA-N N-cyclohexyl-N-[(Z)-octadec-9-enyl]cyclohexanamine Chemical compound CCCCCCCC/C=C\CCCCCCCCN(C1CCCCC1)C1CCCCC1 ZHMPWNLQHMUFFG-KTKRTIGZSA-N 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-O N-dimethylethanolamine Chemical compound C[NH+](C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-O 0.000 description 1
- AKNUHUCEWALCOI-UHFFFAOYSA-N N-ethyldiethanolamine Chemical compound OCCN(CC)CCO AKNUHUCEWALCOI-UHFFFAOYSA-N 0.000 description 1
- XTUVJUMINZSXGF-UHFFFAOYSA-N N-methylcyclohexylamine Chemical compound CNC1CCCCC1 XTUVJUMINZSXGF-UHFFFAOYSA-N 0.000 description 1
- PAMIQIKDUOTOBW-UHFFFAOYSA-N N-methylcyclohexylamine Natural products CN1CCCCC1 PAMIQIKDUOTOBW-UHFFFAOYSA-N 0.000 description 1
- 229910001257 Nb alloy Inorganic materials 0.000 description 1
- XJXROGWVRIJYMO-SJDLZYGOSA-N Nervonic acid Natural products O=C(O)[C@@H](/C=C/CCCCCCCC)CCCCCCCCCCCC XJXROGWVRIJYMO-SJDLZYGOSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 235000019482 Palm oil Nutrition 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 235000019774 Rice Bran oil Nutrition 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- 229910001362 Ta alloys Inorganic materials 0.000 description 1
- 229910001069 Ti alloy Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 229910001080 W alloy Inorganic materials 0.000 description 1
- 125000005073 adamantyl group Chemical group C12(CC3CC(CC(C1)C3)C2)* 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 1
- JAZBEHYOTPTENJ-JLNKQSITSA-N all-cis-5,8,11,14,17-icosapentaenoic acid Chemical compound CC\C=C/C\C=C/C\C=C/C\C=C/C\C=C/CCCC(O)=O JAZBEHYOTPTENJ-JLNKQSITSA-N 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000021342 arachidonic acid Nutrition 0.000 description 1
- 229940114079 arachidonic acid Drugs 0.000 description 1
- 150000008378 aryl ethers Chemical class 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 125000004369 butenyl group Chemical group C(=CCC)* 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000004517 catalytic hydrocracking Methods 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- VNTLIPZTSJSULJ-UHFFFAOYSA-N chromium molybdenum Chemical compound [Cr].[Mo] VNTLIPZTSJSULJ-UHFFFAOYSA-N 0.000 description 1
- GWHCXVQVJPWHRF-UHFFFAOYSA-N cis-tetracosenoic acid Natural products CCCCCCCCC=CCCCCCCCCCCCCCC(O)=O GWHCXVQVJPWHRF-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 125000001995 cyclobutyl group Chemical group [H]C1([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 125000000582 cycloheptyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000000640 cyclooctyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 description 1
- 125000003493 decenyl group Chemical group [H]C([*])=C([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 239000000539 dimer Substances 0.000 description 1
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical class C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 235000020669 docosahexaenoic acid Nutrition 0.000 description 1
- 229940090949 docosahexaenoic acid Drugs 0.000 description 1
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical class CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 125000005066 dodecenyl group Chemical group C(=CCCCCCCCCCC)* 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 235000020673 eicosapentaenoic acid Nutrition 0.000 description 1
- 229960005135 eicosapentaenoic acid Drugs 0.000 description 1
- JAZBEHYOTPTENJ-UHFFFAOYSA-N eicosapentaenoic acid Natural products CCC=CCC=CCC=CCC=CCC=CCCCC(O)=O JAZBEHYOTPTENJ-UHFFFAOYSA-N 0.000 description 1
- QYDYPVFESGNLHU-UHFFFAOYSA-N elaidic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCC(=O)OC QYDYPVFESGNLHU-UHFFFAOYSA-N 0.000 description 1
- 229960002852 ellagic acid Drugs 0.000 description 1
- 235000004132 ellagic acid Nutrition 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- DPUOLQHDNGRHBS-KTKRTIGZSA-N erucic acid Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(O)=O DPUOLQHDNGRHBS-KTKRTIGZSA-N 0.000 description 1
- 150000002169 ethanolamines Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- LVGKNOAMLMIIKO-QXMHVHEDSA-N ethyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC LVGKNOAMLMIIKO-QXMHVHEDSA-N 0.000 description 1
- 229940093471 ethyl oleate Drugs 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000010685 fatty oil Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- VZCCETWTMQHEPK-UHFFFAOYSA-N gamma-Linolensaeure Natural products CCCCCC=CCC=CCC=CCCCCC(O)=O VZCCETWTMQHEPK-UHFFFAOYSA-N 0.000 description 1
- VZCCETWTMQHEPK-QNEBEIHSSA-N gamma-linolenic acid Chemical compound CCCCC\C=C/C\C=C/C\C=C/CCCCC(O)=O VZCCETWTMQHEPK-QNEBEIHSSA-N 0.000 description 1
- 235000020664 gamma-linolenic acid Nutrition 0.000 description 1
- 229960002733 gamolenic acid Drugs 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000006038 hexenyl group Chemical group 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- YAQXGBBDJYBXKL-UHFFFAOYSA-N iron(2+);1,10-phenanthroline;dicyanide Chemical compound [Fe+2].N#[C-].N#[C-].C1=CN=C2C3=NC=CC=C3C=CC2=C1.C1=CN=C2C3=NC=CC=C3C=CC2=C1 YAQXGBBDJYBXKL-UHFFFAOYSA-N 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 229960004488 linolenic acid Drugs 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 125000002960 margaryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000006078 metal deactivator Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 description 1
- 229940073769 methyl oleate Drugs 0.000 description 1
- FAARLWTXUUQFSN-UHFFFAOYSA-N methylellagic acid Natural products O1C(=O)C2=CC(O)=C(O)C3=C2C2=C1C(OC)=C(O)C=C2C(=O)O3 FAARLWTXUUQFSN-UHFFFAOYSA-N 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 229940043348 myristyl alcohol Drugs 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- FRQONEWDWWHIPM-UHFFFAOYSA-N n,n-dicyclohexylcyclohexanamine Chemical compound C1CCCCC1N(C1CCCCC1)C1CCCCC1 FRQONEWDWWHIPM-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- XRKQMIFKHDXFNQ-UHFFFAOYSA-N n-cyclohexyl-n-ethylcyclohexanamine Chemical compound C1CCCCC1N(CC)C1CCCCC1 XRKQMIFKHDXFNQ-UHFFFAOYSA-N 0.000 description 1
- WLGOOBSDLVLWKW-UHFFFAOYSA-N n-cyclohexyl-n-propylcyclohexanamine Chemical compound C1CCCCC1N(CCC)C1CCCCC1 WLGOOBSDLVLWKW-UHFFFAOYSA-N 0.000 description 1
- AGVKXDPPPSLISR-UHFFFAOYSA-N n-ethylcyclohexanamine Chemical compound CCNC1CCCCC1 AGVKXDPPPSLISR-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- PXKCSKRXWAZGFK-UHFFFAOYSA-N n-propylcyclohexanamine Chemical compound CCCNC1CCCCC1 PXKCSKRXWAZGFK-UHFFFAOYSA-N 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 125000005187 nonenyl group Chemical group C(=CCCCCCCC)* 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 125000005064 octadecenyl group Chemical group C(=CCCCCCCCCCCCCCCCC)* 0.000 description 1
- 125000004365 octenyl group Chemical group C(=CCCCCCC)* 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002255 pentenyl group Chemical group C(=CCCC)* 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229960000395 phenylpropanolamine Drugs 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920013636 polyphenyl ether polymer Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 125000004368 propenyl group Chemical group C(=CC)* 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- FGVVTMRZYROCTH-UHFFFAOYSA-N pyridine-2-thiol N-oxide Chemical class [O-][N+]1=CC=CC=C1S FGVVTMRZYROCTH-UHFFFAOYSA-N 0.000 description 1
- 150000003230 pyrimidines Chemical class 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000008165 rice bran oil Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 230000001568 sexual effect Effects 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- JIWBIWFOSCKQMA-UHFFFAOYSA-N stearidonic acid Natural products CCC=CCC=CCC=CCC=CCCCCC(O)=O JIWBIWFOSCKQMA-UHFFFAOYSA-N 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000013076 target substance Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 125000005063 tetradecenyl group Chemical group C(=CCCCCCCCCCCCC)* 0.000 description 1
- VLLMWSRANPNYQX-UHFFFAOYSA-N thiadiazole Chemical compound C1=CSN=N1.C1=CSN=N1 VLLMWSRANPNYQX-UHFFFAOYSA-N 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- WXBXVVIUZANZAU-CMDGGOBGSA-N trans-2-decenoic acid Chemical compound CCCCCCC\C=C\C(O)=O WXBXVVIUZANZAU-CMDGGOBGSA-N 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 125000005040 tridecenyl group Chemical group C(=CCCCCCCCCCCC)* 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
- C10M107/20—Lubricating compositions characterised by the base-material being a macromolecular compound containing oxygen
- C10M107/30—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M107/32—Condensation polymers of aldehydes or ketones; Polyesters; Polyethers
- C10M107/34—Polyoxyalkylenes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
- C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
- C10M129/26—Carboxylic acids; Salts thereof
- C10M129/28—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M129/38—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms
- C10M129/40—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms monocarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
- C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
- C10M133/04—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M133/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M133/08—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
- C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
- C10M133/04—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M133/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M133/10—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms cycloaliphatic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
- C10M135/20—Thiols; Sulfides; Polysulfides
- C10M135/22—Thiols; Sulfides; Polysulfides containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
- C10M141/08—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic sulfur-, selenium- or tellurium-containing compound
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
- C10M145/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M145/10—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate
- C10M145/12—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate monocarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
- C10M145/18—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M145/24—Polyethers
- C10M145/26—Polyoxyalkylenes
- C10M145/36—Polyoxyalkylenes etherified
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M161/00—Lubricating compositions characterised by the additive being a mixture of a macromolecular compound and a non-macromolecular compound, each of these compounds being essential
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/02—Water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
- C10M2207/046—Hydroxy ethers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/127—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids polycarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
- C10M2209/082—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type monocarboxylic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/1033—Polyethers, i.e. containing di- or higher polyoxyalkylene groups used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/108—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/108—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
- C10M2209/1085—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/26—Amines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/01—Physico-chemical properties
- C10N2020/02—Viscosity; Viscosity index
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/24—Emulsion properties
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/40—Low content or no content compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/243—Cold working
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/245—Soft metals, e.g. aluminum
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/246—Iron or steel
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/01—Emulsions, colloids, or micelles
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/01—Emulsions, colloids, or micelles
- C10N2050/011—Oil-in-water
Definitions
- the present invention relates to a water-soluble metal processing oil, a metal processing liquid obtained by mixing diluted water with the water-soluble metal processing oil, and a metal processing method for processing a work material made of metal by applying the metal processing liquid. ..
- a metal processing liquid is used for the purpose of improving the workability of the work material and suppressing the wear of the processing tool.
- the metal processing liquid includes an oil-based metal processing liquid containing oil such as mineral oil, synthetic oil, and animal and vegetable oil as a main component, and a water-soluble metal processing liquid in which a compound having surface activity is blended with the oil to impart water solubility.
- oil-based metal processing liquid containing oil such as mineral oil, synthetic oil, and animal and vegetable oil as a main component
- water-soluble metal processing liquid in which a compound having surface activity is blended with the oil to impart water solubility.
- water-soluble metal processing liquids have come to be used for safety reasons such as low risk of fire.
- Patent Document 1 describes 60 to 90% by weight of a base oil selected from the group consisting of water-soluble polyalkylene glycols, methoxypolyethylene glycols, and combinations of two or more thereof, and 5 to 20% by weight of glycols.
- the invention of a concentrated metal processing fluid comprising ether, 0.01-5% by weight oil-soluble polyalkylene glycol and 0.2-6% by weight of additive is disclosed.
- Patent Document 2 discloses an invention relating to a water-soluble processing oil containing methyldicyclohexylamine.
- the present invention provides a water-soluble metalworking oil containing oil-soluble polyalkylene glycol as a base oil and having a content of water-soluble polyalkylene glycol and methoxypolyethylene glycol of a predetermined amount or less.
- the present invention provides, for example, the following aspects [1] to [16].
- [1] Contains a base oil (A) containing an oil-soluble polyalkylene glycol (A1), A water-soluble metalworking oil having a total content of water-soluble polyalkylene glycol and methoxypolyethylene glycol of less than 60% by mass based on the total amount excluding water.
- the metal processing method according to the above [14], wherein the material to be processed has a member containing at least iron or aluminum.
- the water-soluble metalworking oil according to a preferred embodiment of the present invention can be prepared into a metalworking liquid having excellent various properties such as processability by diluting with diluting water.
- the upper limit value and the lower limit value can be arbitrarily combined.
- the numerical range is described as “preferably 30 to 100, more preferably 40 to 80”
- the range of "30 to 80” and the range of "40 to 100” are also described in the present specification. It is included in the numerical range.
- the numerical range is described as "preferably 30 or more, more preferably 40 or more, preferably 100 or less, more preferably 80 or less”
- the range and the range of "40-100” are also included in the numerical range described herein.
- the description of "60 to 100” means that the range is "60 or more and 100 or less”.
- the "metalworking oil” is a stock solution of a metalworking liquid before being diluted with diluted water to make a metalworking liquid, and is a suitable form for transportation and storage before being used for metalworking. .. Further, the “metalworking liquid” is obtained by adding diluted water to a metalworking oil which is a stock solution to dilute it, and is a suitable form when used for metalworking.
- the "metalworking oil” and the “metalworking liquid” can also be distinguished by the water content, for example, as follows.
- “Metalworking liquid” The content of water is more than 400 parts by mass with respect to 100 parts by mass of all the components other than water.
- the water-soluble metalworking oil of the present invention contains a base oil (A) containing an oil-soluble polyalkylene glycol (hereinafter, also referred to as “oil-soluble PAG”) (A1), and is a water-soluble polyalkylene glycol (hereinafter, “water-soluble”). It is an oil agent in which the total content of (also referred to as “sexual PAG”) and methoxypolyethylene glycol (hereinafter, also referred to as “MPEG”) is adjusted to a predetermined content.
- water-soluble means a solution at 25 ° C. prepared by adding 20 g of a target substance to 100 g of water at 25 ° C.
- the component described as "water-soluble" is a component having the above-mentioned characteristics.
- the total content of water-soluble PAG and MPEG is less than 60% by mass, less than 50% by mass, and less than 40% by mass based on the total amount (100% by mass) excluding water. , Less than 30% by mass, less than 20% by mass, less than 10% by mass, less than 5% by mass, less than 1% by mass, or less than 0.1% by mass.
- the total content of the water-soluble PAG and MPEG is less than 10 parts by mass and less than 5 parts by mass with respect to 100 parts by mass of the total amount of the component (A1). It may be less than parts by mass, less than 0.1 parts by mass, less than 0.01 parts by mass, or less than 0.001 parts by mass.
- the water-soluble metalworking oil according to one aspect of the present invention described above may further contain water (B).
- water (B) By adjusting the content of water (B), it is possible to prepare an emulsion type oil agent classified into A1 type or a solve type oil agent classified into A2 type specified in JIS K2241: 2017. ..
- the water-soluble metalworking oil agent according to one aspect of the present invention described above contains at least one selected from an amine compound (C), fatty acids (D), and a nonionic surfactant (E). Is preferable, at least the components (C) and (D) are more preferably contained, and it is further preferable to contain all of the components (C), (D) and (E).
- the water-soluble metalworking oil according to one aspect of the present invention may contain components other than the components (A) to (E) as long as the effects of the present invention are not impaired.
- the total content of the components (A) and (B) is preferably 20% by mass or more based on the total amount (100% by mass) of the water-soluble metal processing oil. More preferably 30% by mass or more, further preferably 40% by mass or more, still more preferably 45% by mass or more, particularly preferably 50% by mass or more, and 100% by mass or less, 95% by mass or less, 90% by mass.
- it may be 85% by mass or less, 80% by mass or less, 75% by mass or less, 70% by mass or less, 65% by mass or less, or 60% by mass or less.
- the total content of the components (A) to (D) is preferably 30% by mass or more based on the total amount (100% by mass) of the water-soluble metal processing oil. More preferably 40% by mass or more, more preferably 50% by mass or more, still more preferably 60% by mass or more, still more preferably 70% by mass or more, particularly preferably 80% by mass or more, and 100% by mass or less. It may be 98% by mass or less, 95% by mass or less, 93% by mass or less, or 90% by mass or less.
- the total content of the components (A) to (E) is preferably 35% by mass or more based on the total amount (100% by mass) of the water-soluble metal processing oil. It is preferably 45% by mass or more, more preferably 55% by mass or more, further preferably 65% by mass or more, still more preferably 75% by mass or more, particularly preferably 85% by mass or more, and 100% by mass or less, 98. It may be mass% or less, 96 mass% or less, or 94 mass% or less.
- each component contained in the water-soluble metalworking oil according to one aspect of the present invention will be described.
- the water-soluble metalworking oil of the present invention contains a base oil (A) containing an oil-soluble PAG (A1). Since the water-soluble metalworking oil of the present invention contains an oil-soluble PAG as the base oil, the workability of the metalworking liquid obtained by blending the water-soluble metalworking oil with diluted water can be improved.
- the water-soluble metal processing oil which is the undiluted solution contains a sulfur-based extreme pressure agent. ..
- the sulfur extreme pressure agent causes corrosion of the copper-containing member constituting the processing machine used for metal processing of the material to be processed.
- the water-soluble metalworking oil of the present invention can be prepared into a metalworking liquid having excellent processability by containing the component (A1), even if it does not substantially contain a sulfur-based extreme pressure agent. Moreover, the problem of corrosion of the copper member can be avoided.
- the component (A) used in one aspect of the present invention may contain a base oil (A2) other than the component (A1).
- the content ratio of the component (A1) in the component (A) in the water-soluble metal processing oil according to one aspect of the present invention is. 10 to 100% by mass, 20 to 100% by mass, 30 to 100% by mass, 40 to 100% by mass, 50 to 100 based on the total amount (100% by mass) of the component (A) contained in the water-soluble metalworking oil.
- Mass% 60-100% by mass, 70-100% by mass, 75-100% by mass, 80-100% by mass, 85-100% by mass, 90-100% by mass, 95-100% by mass, or 98-100% by mass. May be%.
- the content of the component (A) is based on the total amount (100% by mass) of the water-soluble metal processing oil excluding water, and is a metal processing liquid having excellent workability. From the viewpoint of obtaining a water-soluble metal processing oil, preferably 0.01% by mass or more, more preferably 0.05% by mass or more, more preferably 0.1% by mass or more, still more preferably 0.5% by mass or more.
- It is 0% by mass or more, particularly preferably 9.0% by mass or more, and may be 9.5% by mass or more, 10.0% by mass or more, 11.0% by mass or more, or 12.0% by mass or more. Further, it may be 100% by mass or less, 99% by mass or less, 95% by mass or less, 90% by mass or less, 85% by mass or less, 80% by mass or less, 75% by mass or less, or 70% by mass or less.
- the content of the component (A) is 10% by mass based on the total amount (100% by mass) excluding water of the oil agent. % Or more, 15% by mass or more, 20% by mass or more, 30% by mass or more, 40% by mass or more, 45% by mass or more, or 50% by mass or more, and the upper limit is as described above.
- the content of the component (A) is 60% by mass or less based on the total amount (100% by mass) excluding water of the oil agent. , 50% by mass or less, 40% by mass or less, 30% by mass or less, 25% by mass or less, or 20% by mass or less, and the lower limit is as described above.
- the content of the component (A) can be a metal processing liquid having excellent workability based on the total amount (100% by mass) of the water-soluble metal processing oil.
- it is preferably 0.01% by mass or more, more preferably 0.05% by mass or more, more preferably 0.1% by mass or more, more preferably 0.3% by mass or more, and more. More preferably 0.5% by mass or more, further preferably 0.7% by mass or more, still more preferably 1.0% by mass or more, still more preferably 1.5% by mass or more, still more preferably 2.0% by mass or more, and more.
- the content of the component (A) is 10% by mass or more based on the total amount (100% by mass) of the oil agent. It may be 15% by mass or more, 20% by mass or more, 30% by mass or more, 40% by mass or more, 45% by mass or more, or 50% by mass or more, and the upper limit is as described above.
- the content of the component (A) is 60% by mass or less and 50% by mass based on the total amount (100% by mass) of the oil agent. % Or less, 40% by mass or less, 30% by mass or less, 25% by mass or less, 20% by mass or less, 15% by mass or less, or 10% by mass or less, and the lower limit is as described above.
- Oil-soluble polyalkylene glycol (oil-soluble PAG) Oil-soluble polyalkylene glycol (oil-soluble PAG)
- the component (A1) used in one embodiment of the present invention is not particularly limited as long as it is a polyalkylene glycol (PAG) having a structural unit derived from an alkylene oxide and exhibiting oil solubility.
- PAG polyalkylene glycol
- whether or not the target PAG is oil-soluble is determined by its miscibility with mineral oil classified into Group 1 of the API (American Petroleum Institute) base oil category.
- a sample having a mass ratio of 10/90 or 90/10 in the content ratio [PAG / mineral oil] of the control PAG and the mineral oil classified into the above group 1 is prepared, and the sample and the standard are prepared.
- the total light transmittance of the sample at 25 ° C. is measured, and if the following criteria (i) and (ii) are satisfied, it is judged to be an oil-soluble PAG.
- the component described as "oil-soluble" is a component satisfying the above criteria (i) and (ii) unless otherwise specified.
- Examples of the component (A1) used in one embodiment of the present invention include polymers having a structural unit derived from at least one of propylene oxide and butylene oxide, which are propylene oxide homopolymers, butylene oxide homopolymers, and propylene oxide / butylene oxide. Examples include copolymers.
- the component (A1) may be used alone or in combination of two or more.
- the kinematic viscosity of the component (A1) used in one aspect of the present invention at 40 ° C. is preferably 9 to 800 mm 2 / s, more preferably from the viewpoint of making a water-soluble metal processing oil that can be a metal processing liquid having excellent processability. Is 15 to 350 mm 2 / s, more preferably 20 to 250 mm 2 / s, even more preferably 23 to 180 mm 2 / s, even more preferably 25 to 100 mm 2 / s, even more preferably 28.8 to 90 mm 2 / s. s, particularly preferably 40-80 mm 2 / s.
- the viscosity grades specified in ISO 3448 of the component (A1) used in one aspect of the present invention are VG10, VG15, VG22, VG32. , VG46, VG68, VG100, VG150, VG220, VG320, VG460, or VG680, more preferably VG22, VG32, VG46, VG68, or VG100, and more preferably VG32, VG46, or VG68. It is even more preferably VG46 or VG68, even more preferably VG68.
- the content of the component (A1) is based on the total amount (100% by mass) of the water-soluble metal processing oil excluding water, resulting in a metal processing liquid having excellent workability.
- a water-soluble metal processing oil preferably 0.01% by mass or more, more preferably 0.05% by mass or more, more preferably 0.1% by mass or more, still more preferably 0.5% by mass or more.
- the content of the component (A1) is 10% by mass based on the total amount (100% by mass) excluding water of the oil agent. % Or more, 15% by mass or more, 20% by mass or more, 30% by mass or more, 40% by mass or more, 45% by mass or more, or 50% by mass or more, and the upper limit is as described above.
- the content of the component (A1) is 60% by mass or less based on the total amount (100% by mass) excluding water of the oil agent. , 50% by mass or less, 40% by mass or less, 30% by mass or less, 25% by mass or less, or 20% by mass or less, and the lower limit is as described above.
- Base oil other than ingredient (A1) Base oil other than ingredient (A1)
- Examples of the base oil (A2) other than the component (A1) used in one embodiment of the present invention include at least one selected from mineral oils and synthetic oils other than oil-soluble PAGs.
- the above-mentioned water-soluble polyalkylene glycol (water-soluble PAG) and methoxypolyethylene glycol (MPEG) are also contained in the component (A2), but the total content of the water-soluble PAG and MPEG is as described above. It will be adjusted.
- Mineral oils include, for example, normal pressure residual oil obtained by atmospheric distillation of crude oils such as paraffin crude oil, intermediate base crude oil, and naphthenic crude oil; and distillate oil obtained by vacuum distillation of these normal pressure residual oils. ; Refined oil obtained by subjecting the distillate oil to one or more refining treatments such as solvent removal, solvent extraction, hydrocracking, solvent dewaxing, catalytic dewaxing, and hydrorefining; and the like.
- the synthetic oil examples include poly such as an ⁇ -olefin homopolymer or an ⁇ -olefin copolymer (for example, an ⁇ -olefin copolymer having 8 to 14 carbon atoms such as an ethylene- ⁇ -olefin copolymer).
- Examples thereof include synthetic oil (GTL) obtained by isomerizing (GTL wax (Gas To Liquids WAX)).
- the kinematic viscosity of the component (A2) used in one aspect of the present invention at 40 ° C. is preferably 2.0 to 150 mm 2 / s from the viewpoint of making a water-soluble metal processing oil that can be a metal processing liquid having excellent processability. It is more preferably 3.0 to 120 mm 2 / s, still more preferably 5.0 to 100 mm 2 / s, even more preferably 6.0 to 90 mm 2 / s, and particularly preferably 7.0 to 80 mm 2 / s. ..
- the viscosity index of the component (A2) used in one embodiment of the present invention is preferably 70 or more, more preferably 80 or more, still more preferably 90 or more, still more preferably 100 or more, and particularly preferably 105 or more.
- the water-soluble metalworking oil according to one aspect of the present invention may further contain water (B).
- water (B) By using a water-soluble metalworking oil containing water, flame retardancy can be imparted to make it a non-dangerous substance, and handleability during storage can be improved.
- the water as the component (B) used in one aspect of the present invention is not particularly limited, and may be, for example, distilled water, ion-exchanged water, tap water, industrial water, or the like.
- the content of the component (B) is 400 parts by mass or less with respect to 100 parts by mass of all the components other than water in the water-soluble metalworking oil. It is preferably 1 to 350 parts by mass, more preferably 2 to 300 parts by mass, still more preferably 3 to 250 parts by mass, and even more preferably 5 to 200 parts by mass.
- the content of the component (B) is 100 parts by mass of the total amount of the components other than water in the water-soluble metal processing oil agent.
- the content of the component (B) is 100 parts by mass of the total amount of the components other than water in the water-soluble metal processing oil agent.
- it may be 10 parts by mass or more, 30 parts by mass or more, 50 parts by mass or more, 60 parts by mass or more, 70 parts by mass or more, 80 parts by mass or more, 90 parts by mass or more, or 100 parts by mass or more.
- the upper limit is as described above.
- the content of the component (B) is preferably 1 to 99% by mass, more preferably 2 based on the total amount (100% by mass) of the water-soluble metalworking oil. It is ⁇ 90% by mass, more preferably 3 to 85% by mass, and even more preferably 5 to 80% by mass.
- the content of the component (B) is 70 based on the total amount (100% by mass) of the water-soluble metal processing oil agent.
- the content of the component (B) is 10 based on the total amount (100% by mass) of the water-soluble metal processing oil agent. It may be mass% or more, 15% by mass or more, 20% by mass or more, 25 parts by mass or more, 30% by mass or more, 35% by mass or more, 40% by mass or more, 45 parts by mass or more, or 50% by mass or more.
- the upper limit is as described above.
- the water-soluble metalworking oil according to one aspect of the present invention preferably further contains an amine compound (C).
- the water-soluble metalworking oil containing the component (C) has a good emulsified state when diluted water is mixed to form a metalworking liquid, and has further improved antibacterial properties, rust resistance, processability and the like. It can be a metalworking liquid.
- the component (C) may be used alone or in combination of two or more.
- the content of the component (C) is preferably based on the total amount (100% by mass) of the water-soluble metal processing oil excluding water. It is 3 to 70% by mass, more preferably 5 to 60% by mass, further preferably 7 to 50% by mass, still more preferably 10 to 45% by mass, particularly preferably 12 to 40% by mass, and further 15% by mass.
- the above may be 17% by mass or more, 20% by mass or more, 22% by mass or more, or 24% by mass or more, and 37% by mass or less, 35% by mass or less, 33% by mass or less, 31% by mass or less, 27% by mass. % Or less, or 25% by mass or less.
- the content of the component (C) is preferably 2 based on the total amount (100% by mass) of the water-soluble metal processing oil. -40% by mass, more preferably 4 to 35% by mass, still more preferably 6 to 30% by mass, still more preferably 8 to 25% by mass, particularly preferably 10 to 20% by mass, and further preferably 11% by mass or more. , Or 12% by mass or more, and 18% by mass or less, or 16% by mass or less.
- the content ratio [(C) / (A1)] of the component (C) to the component (A1) is preferably 0.01 to (A1) in terms of mass ratio. 30, more preferably 0.05 to 25, still more preferably 0.10 to 20, even more preferably 0.20 to 15, particularly preferably 0.25 to 9.0, and further preferably 0.28 or more.
- the component (C) used in one embodiment of the present invention is a monoamine having one aminonitrogen atom in one molecule, a diamine having two aminonitrogen atoms in one molecule, and three aminonitrogen atoms in one molecule. It may be any of polyamines having two or more. However, the component (C) used in one embodiment of the present invention contains a monoamine from the viewpoint of making a water-soluble metal processing oil that can be a metal processing liquid having further improved antibacterial properties, rust preventive properties, processability and the like. Is preferable.
- the content ratio of monoamine is preferably 50 to 100% by mass, more preferably 60 to 100% by mass, and more preferably 70 to 70, based on the total amount (100% by mass) of the component (C) contained in the water-soluble metal processing oil. 100% by mass, more preferably 75 to 100% by mass, still more preferably 80 to 100% by mass, still more preferably 85 to 100% by mass, still more preferably 90 to 100% by mass, still more preferably 95 to 100% by mass. Particularly preferably, it is 98 to 100% by mass.
- the monoamine used as the component (C) in one aspect of the present invention includes a primary monoamine represented by the following formula (i) and a secondary monoamine represented by the following formula (ii) depending on the number of substituents R. , And a tertiary monoamine represented by the following formula (iii).
- a water-soluble metalworking oil that can be a metalworking liquid with good emulsification and improved antibacterial, rustproof, processability, etc. when diluted water is mixed to make a metalworking liquid.
- the component (C) used in one embodiment of the present invention preferably contains at least a tertiary monoamine, and more preferably contains at least one of a primary monoamine and a secondary monoamine and a tertiary monoamine. , At least secondary monoamines and tertiary monoamines are more preferably included.
- R independently indicates a substituent.
- the plurality of Rs may be the same or different from each other.
- the substituent include an alkyl group, an alkyl group having a hydroxyl group, an alkenyl group, a cycloalkyl group, a phenyl group, a benzyl group and the like.
- the alkyl group may be a linear alkyl group or a branched chain alkyl group.
- the number of carbon atoms of the alkyl group is preferably 1 to 30, more preferably 1 to 20, still more preferably 1 to 10, still more preferably 1 to 6, and particularly preferably 1 to 4.
- Examples of the alkyl group having a hydroxyl group that can be selected as the substituent R include a group in which at least one hydrogen atom of the above-mentioned alkyl group is substituted with a hydroxyl group.
- the alkyl group constituting the group may also be a linear alkyl group or a branched chain alkyl group.
- the alkyl group having a hydroxyl group preferably has 1 to 30, more preferably 1 to 20, still more preferably 1 to 10, still more preferably 1 to 6, and particularly preferably 2 to 4.
- Examples thereof include a tridecenyl group, a tetradecenyl group, a pentadecenyl group, a hexadecenyl group, an octadecenyl group and the like.
- the alkenyl group may be a linear alkenyl group or a branched chain alkenyl group.
- the carbon number of the alkenyl group is preferably 1 to 30, more preferably 1 to 20, still more preferably 1 to 10, still more preferably 1 to 6, and particularly preferably 1 to 3.
- Examples of the cycloalkyl group that can be selected as the substituent R include a cyclopropyl group, a cyclobutyl group, a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, a cyclooctyl group, an adamantyl group and the like.
- the component (C) used in one embodiment of the present invention is a metal having a good emulsified state and further improved antibacterial property, rust resistance, processability, etc. when diluted water is mixed to prepare a metal processing solution.
- an alkanolamine having at least one alkyl group having a hydroxyl group examples include a primary alkanolamine in which R in the formula (i) is an alkyl group having a hydroxyl group, and a secondary alkanol in which at least one of R in the formula (ii) is an alkyl group having a hydroxyl group.
- Examples thereof include amines and tertiary alkanolamines in which at least one of R in the formula (iii) is an alkyl group having a hydroxyl group.
- Examples of the primary alkanolamine include ethanolamine, propanolamine, butanolamine, 2-amino-2-methyl-1-propanol and the like.
- Examples of the secondary alkanolamine include N-methylethanolamine, N-ethylethanolamine, N-propylethanolamine, N-butylethanolamine, N-octylethanolamine, N-stearylethanolamine and N-oleylethanol.
- Monoethanolamines such as amines, N-cyclohexylethanolamines, N-phenylethanolamines, N-benzylethanolamines; N-methylpropanolamines, N-ethylpropanolamines, N-propylpropanolamines, N-butylpropanolamines, N -Monopropanol amines such as octylpropanolamine, N-stearylpropanolamine, N-oleylpropanolamine, N-cyclohexylpropanolamine, N-phenylpropanolamine, N-benzylpropanolamine; diethanolamine, dipropanolamine and the like can be mentioned.
- tertiary alkanolamine examples include N-dimethylethanolamine, N-diethylethanolamine, N-dipropylethanolamine, N-dibutylethanolamine, N-dioctylethanolamine, N-distearylethanolamine, and N-.
- Monoethanolamine such as dioleylethanolamine, N-dicyclohexylethanolamine, N-diphenylethanolamine, N-dibenzylethanolamine; N-dimethylpropanolamine, N-diethylpropanolamine, N-dipropylpropanolamine, N- Monopropanolamines such as dibutylpropanolamine, N-dioctylpropanolamine, N-distearylpropanolamine, N-diorail propanolamine, N-dicyclohexylpropanolamine, N-diphenylpropanolamine, N-dibenzylpropanolamine; N- Diethanolamines such as methyldiethanolamine, N-ethyldiethanolamine, N-propyldiethanolamine, N-butyldiethanolamine, N-octyldiethanolamine, N-stearyldiethanolamine, N-oleyld
- a water-soluble metal processing oil that can be a metal processing liquid that has a good emulsified state and further improved antibacterial, rust-preventive, processability, etc. when diluted water is mixed to make a metal processing liquid.
- the component (C) used in one embodiment of the present invention preferably contains at least a tertiary alkanolamine, and at least one of a primary alkanolamine and a secondary alkanolamine and a tertiary alkanolamine. It is more preferable to contain at least a secondary alkanolamine and a tertiary alkanolamine.
- the content ratio of alkanolamine is preferably 5% by mass or more, more preferably 10% by mass or more, and more preferably 20% by mass based on the total amount (100% by mass) of the component (C) contained in the water-soluble metal processing oil.
- the above is more preferably 30% by mass or more, further preferably 35% by mass or more, particularly preferably 40% by mass or more, and further preferably 45% by mass or more, 50% by mass or more, or 55% by mass or more. Further, it may be 100% by mass or less, 95% by mass or less, 90% by mass or less, 85% by mass or less, 80% by mass or less, 75% by mass or less, 70% by mass or less, or 65% by mass or less.
- the component (C) used in one embodiment of the present invention preferably contains an alicyclic amine.
- the alicyclic amine is a primary alicyclic amine in which R in the formula (i) is a cycloalkyl group, and a secondary alicyclic amine in which at least one of R in the formula (ii) is a cycloalkyl group. Examples thereof include a cyclic amine and a tertiary alicyclic amine in which at least one of R in the formula (iii) is a cycloalkyl group.
- Examples of the primary alicyclic amine include N-cyclohexylamine and the like.
- Examples of the secondary alicyclic amine include monocyclohexylamines such as N-methylcyclohexylamine, N-ethylcyclohexylamine, N-propylcyclohexylamine and N-oleylcyclohexylamine; N-cyclohexylethanolamine and N-cyclohexyl.
- Monocyclohexylalkanolamines such as propanolamine; N-dicyclohexylamines and the like can be mentioned.
- tertiary alicyclic amine examples include dialkyl monocyclohexylamines such as N-dimethylcyclohexylamine, N-diethylcyclohexylamine, N-dipropylcyclohexylamine, N-diorailcyclohexylamine and N-dicyclohexylamine; -Monocyclohexyldialkanolamines such as cyclohexyldiethanolamine and N-cyclohexyldipropanolamine; monoalkyldicyclohexylamines such as N-methyldicyclohexylamine, N-ethyldicyclohexylamine, N-propyldicyclohexylamine and N-oleyldicyclohexylamine; N- Dicyclohexylalkanolamines such as dicyclohexylethanolamine and N-dicyclohexylpropanolamine; tri
- the component (C) preferably contains one or more selected from dialkyl monocyclohexylamine and monoalkyldicyclohexylamine. , More preferably containing monoalkyldicyclohexylamine.
- the component (C) may contain one or more selected from monocyclohexyldialkanolamine and dicyclohexylalkanolamine. It is preferable to contain monocyclohexyldialkanolamine.
- the content ratio of the alicyclic amine is preferably 10% by mass or more, more preferably 20% by mass or more, still more preferably 25, based on the total amount (100% by mass) of the component (C) contained in the water-soluble metal processing oil.
- mass or more more preferably 30% by mass or more, particularly preferably 35% by mass or more, further 37% by mass or more, or 40% by mass or more, and 100% by mass or less, 95% by mass or less.
- the water-soluble metalworking oil according to one aspect of the present invention may contain amines (including diamines and polyamines) other than alkanolamines and alicyclic amines as the component (C).
- the content of other amines is 0 to 50% by mass, 0 to 40% by mass, 0 to 30% by mass, 0 based on the total amount (100% by mass) of the component (C) contained in the water-soluble metal processing oil. ⁇ 20% by mass, 0 to 10% by mass, 0 to 5.0% by mass, 0 to 2.0% by mass, 0 to 1.0% by mass, 0 to 0.10% by mass, 0 to 0.01% by mass. , 0 to 0.001% by mass, 0 to 0.0001% by mass, or 0 to 0.00001% by mass.
- the water-soluble metalworking oil according to one aspect of the present invention preferably further contains fatty acids (D).
- fatty acids (D) By containing the component (D), it is possible to obtain a water-soluble metal processing oil which can be a metal processing liquid having further improved emulsion stability, rust prevention, processability and the like.
- the component (D) may be used alone or in combination of two or more.
- the content of the component (D) is preferably based on the total amount (100% by mass) of the water-soluble metal processing oil excluding water. It is 5 to 70% by mass, more preferably 7 to 60% by mass, further preferably 10 to 50% by mass, still more preferably 13 to 45% by mass, particularly preferably 16 to 40% by mass, and further 18% by mass. As mentioned above, it may be 20% by mass or more, 22% by mass or more, or 25% by mass or more, and may be 38% by mass or less, 35% by mass or less, or 32% by mass or less.
- the content of the component (D) is preferably 2 based on the total amount (100% by mass) of the water-soluble metal processing oil. -60% by mass, more preferably 3 to 50% by mass, further preferably 5 to 40% by mass, still more preferably 7 to 30% by mass, particularly preferably 9 to 25% by mass, and further 10% by mass or more. , 12% by mass or more, or 14% by mass or more, and may be 22% by mass or less, 20% by mass or less, or 18% by mass or less.
- the content ratio [(D) / (A1)] of the component (D) to the component (A1) is preferably 0.01 to (A1) in terms of mass ratio. 30, more preferably 0.05 to 25, more preferably 0.10 to 20, still more preferably 0.20 to 15, still more preferably 0.25 to 12.0, particularly preferably 0.30 to 8. It is 0, and further, 0.32 or more, 0.35 or more, 0.50 or more, 0.70 or more, 0.90 or more, 1.00 or more, 1.20 or more, 1.40 or more, or 1.50.
- the above may be applied, and 7.0 or less, 6.0 or less, 5.0 or less, 4.5 or less, 4.0 or less, 3.8 or less, 3.6 or less, 3.4 or less, 3.2 or less.
- it may be 3.0 or less, 2.8 or less, 2.6 or less, or 2.4 or less.
- the component (C) and the component from the viewpoint of making a water-soluble metal processing oil that can be a metal processing liquid having good undiluted stability of the oil and further improved workability is preferably 0.01 to 5.0, more preferably 0.05 to 4.0, and more preferably 0.1 in terms of mass ratio. ⁇ 3.0, more preferably 0.2 to 2.5, still more preferably 0.3 to 2.0, particularly preferably 0.5 to 1.5, and further 0.6 or more, 0. It may be 65 or more, 0.7 or more, 0.75 or more, or 0.8 or more, and may be 1.4 or less, 1.3 or less, 1.2 or less, or 1.15 or less.
- Examples of the component (D) used in one embodiment of the present invention include fatty acids, hydroxy fatty acids, aliphatic dicarboxylic acids, fatty acid dimer acids, and polymerized fatty acids of hydroxy unsaturated fatty acids.
- fatty acid examples include octanoic acid, 2-ethylhexanoic acid, decanoic acid, neodecanoic acid, undecanoic acid, dodecanoic acid, tridecanoic acid, pentadecanoic acid, heptadecanoic acid, nonadecanoic acid, myristic acid, palmitic acid, stearic acid and arakin.
- Saturated aliphatic monocarboxylic acids such as acids, behenic acids and isostearic acids, and octenoic acid, nonenic acid, decenoic acid, undecenoic acid, oleic acid, ellagic acid, erucic acid, nervonic acid, linoleic acid, ⁇ -linolenic acid, Examples thereof include unsaturated aliphatic monocarboxylic acids such as arachidonic acid, ⁇ -linolenic acid, stearidonic acid, eicosapentaenoic acid and docosahexaenoic acid.
- a mixture of unsaturated fatty acids such as tall oil fatty acid, soybean oil fatty acid, palm oil fatty acid, flaxseed oil fatty acid, rice bran oil fatty acid, and cottonseed oil fatty acid may be used.
- the number of carbon atoms of the fatty acid is preferably 8 to 30, more preferably 10 to 25, and even more preferably 10 to 20.
- hydroxy fatty acid examples include hydroxylauric acid, hydroxymyristic acid, hydroxypalmitic acid, hydroxystearic acid, hydroxyarakinic acid, hydroxybehenic acid, hydroxyoctadecenoic acid and the like.
- the number of carbon atoms of the hydroxy fatty acid is preferably 8 to 30, more preferably 10 to 25, and even more preferably 10 to 20.
- aliphatic dicarboxylic acid examples include saturated aliphatic dicarboxylic acids such as sebacic acid, dodecanedioic acid, dodecylsuccinic acid, laurylsuccinic acid, stearylsuccinic acid, and isostearylsuccinic acid.
- the carbon number of the aliphatic dicarboxylic acid is preferably 8 to 30, more preferably 10 to 25, and even more preferably 10 to 20.
- hydroxy unsaturated fatty acid constituting the polymerd fatty acid of the hydroxy unsaturated fatty acid examples include ricinoleic acid (12-hydroxyoctadeca-9-enonic acid). Further, a fatty acid mixture containing ricinoleic acid such as castor oil may be used.
- a condensed fatty acid which is a dehydrated polycondensate of the hydroxy unsaturated fatty acid for example, a castor oil polymerized fatty acid which is a dehydrated condensate of a fatty acid mixture containing lysynolic acid as a main component
- the component (D) used in one embodiment of the present invention is one or more (preferably two or more, more preferably two or more) selected from polymerized fatty acids of unsaturated aliphatic monocarboxylic acid, saturated aliphatic dicarboxylic acid, and hydroxy unsaturated fatty acid. 3 or more) is preferably contained, and at least all of the unsaturated aliphatic monocarboxylic acid, the saturated aliphatic dicarboxylic acid, and the polymerized fatty acid of the hydroxy unsaturated fatty acid are more preferably contained.
- the acid value of the component (D) is usually 0 mgKOH / g or more, preferably 10 to 100 mgKOH / g, more preferably 10 to 100 mgKOH / g, from the viewpoint of making a water-soluble metalworking oil that can be a metalworking liquid with further improved workability. Is 20 to 90 mgKOH / g, more preferably 30 to 80 mgKOH / g.
- the hydroxyl value of the component (D) is preferably 0 to 80 mgKOH / g, more preferably 0 to 60 mgKOH / g, and even more preferably 0 to 40 mgKOH / g.
- the ratio [acid value / hydroxyl value] of the acid value of the component (D) to the hydroxyl value is preferably 1.5 to 15, more preferably 2.0 to 10, and even more preferably 2.5 to. It is 9.5.
- the saponification value of the component (D) is preferably 180 to 220 mgKOH / g, more preferably 190 to 210 mgKOH / g, and even more preferably 195 to 205 mgKOH / g.
- the acid value means a value measured according to JIS K2501: 2003 (indicator photometric titration method)
- the hydroxyl value means a value measured according to JIS K0070: 1992.
- Titration value means a value measured based on JIS K2503: 1996.
- the water-soluble metalworking oil according to one aspect of the present invention preferably further contains a nonionic surfactant (E).
- a nonionic surfactant (E) By containing the component (E), it is possible to obtain a water-soluble metal processing oil which can be a metal processing liquid having further improved emulsion stability and processability.
- the component (E) may be used alone or in combination of two or more.
- the content of the component (E) is preferably 0.5 based on the total amount (100% by mass) of the water-soluble metal processing oil excluding water. ⁇ 35.0% by mass, more preferably 1.0 to 30.0% by mass, still more preferably 1.2 to 25.0% by mass, still more preferably 1.5 to 20.0% by mass, particularly preferably. It is 1.7 to 16.0% by mass.
- the content of the component (E) is based on the total amount (100% by mass) of the water-soluble metal processing oil agent excluding water.
- the content of the component (E) is based on the total amount (100% by mass) of the water-soluble metal processing oil agent excluding water.
- the content of the component (E) is preferably 0.1 to 15. Based on the total amount (100% by mass) of the water-soluble metal processing oil. 0% by mass, more preferably 0.2 to 12.0% by mass, still more preferably 0.3 to 10.0% by mass, still more preferably 0.5 to 8.0% by mass, particularly preferably 0.7. It is about 6.0% by mass.
- the content of the component (E) is 5 based on the total amount (100% by mass) of the water-soluble metalworking oil agent.
- the content of the component (E) is 1.0 based on the total amount (100% by mass) of the water-soluble metal processing oil agent. Mass% or more, 1.2% by mass or more, 1.5% by mass or more, 2.0% by mass or more, 2.5% by mass or more, 3.0% by mass or more, 3.5% by mass or more, or 4.0 It may be mass% or more, and the upper limit is as described above.
- the HLB of the component (E) used in one embodiment of the present invention is preferably 6.0 or more, more preferably 6.0 or more, from the viewpoint of making a water-soluble metal processing oil which can be a metal processing liquid having further improved emulsion stability and processability.
- HLB means the value calculated by the Griffin method.
- Examples of the component (E) used in one embodiment of the present invention include alkylene glycol, polyoxyalkylene alkyl ether, polyoxyalkylene aryl ether, polyoxyalkylene alkylamine (cocoamine alkylene oxide adduct), and alkylphenol alkylene oxide adduct. , Higher alcohol alkylene oxide adducts, polyoxyalkylene fatty acid esters, glycerin and pentaerythritol fatty acid esters, sucrose fatty acid esters, polyhydric alcohol polyoxyalkylene adduct fatty acid esters, alkyl polyglycosides, fatty acid alkanolamides, etc. Can be mentioned.
- the component (E) used in one embodiment of the present invention is a polyoxyalkylene alkyl ether and a poly from the viewpoint of making a water-soluble metal processing oil which can be a metal processing liquid having further improved emulsion stability and processability. It is preferable to contain one or more selected from oxyalkylene alkyl amines.
- the total content of the polyoxyalkylene alkyl ether and the polyoxyalkylene alkyl amine is preferably 50 to 100% by mass, more preferably 50 to 100% by mass, based on the total amount (100% by mass) of the component (E) contained in the water-soluble metalworking oil. It is 70 to 100% by mass, more preferably 80 to 100% by mass, still more preferably 90 to 100% by mass, and particularly preferably 95 to 100% by mass.
- the water-soluble metalworking oil of the present invention contains an oil-soluble PAG (A1) as the base oil (A), it is excellent even if it does not contain a sulfur-based extreme pressure agent that causes corrosion of members containing copper. It is possible to prepare a metal processing liquid having a high workability. Therefore, from the viewpoint of making a water-soluble metal processing oil that can be a metal processing liquid having a high effect of suppressing corrosion of members containing copper, the water-soluble metal processing oil according to one aspect of the present invention is substantially a sulfur-based extreme pressure agent. It is preferable not to contain it.
- the sulfur-based extreme pressure agent include olefin sulfide, lard sulfide, alkylpolysulfide, and fatty acid sulfide.
- substantially free of sulfur-based extreme pressure agent is a provision denying the mode of containing a sulfur-based extreme pressure agent for a predetermined purpose, and is used as an impurity of other components. It is not a rule to deny the mode in which a sulfur-based extreme pressure agent is unintentionally mixed and contained. However, even considering the mode in which the sulfur-based extreme pressure agent is unintentionally mixed in, the viewpoint of making a water-soluble metal processing oil that can be a metal processing liquid having a high effect of suppressing corrosion of members containing copper is obtained. Therefore, the content of the sulfur-based extreme pressure agent is preferably as small as possible.
- the content of the specific sulfur-based extreme pressure agent is preferably less than 10 parts by mass, more preferably less than 1 part by mass, based on 100 parts by mass of the total amount of the component (A1) contained in the water-soluble metalworking oil. It is more preferably less than 0.1 parts by mass, still more preferably less than 0.01 parts by mass, and particularly preferably less than 0.001 parts by mass.
- the water-soluble metalworking oil according to one aspect of the present invention may further contain various additives other than the above-mentioned components (A) to (E), if necessary, as long as the effects of the present invention are not impaired. good.
- additives include anionic surfactants, cationic surfactants, petroleum sulfonates, non-sulfur-based extreme pressure agents, metal deactivators, emulsification aids, antibacterial agents, and defoamers.
- foaming agents antioxidants, oily agents and the like.
- the content of each of these various additives is appropriately set depending on the type and function of each component, and the water of the water-soluble metalworking oil is used. Based on the total amount (100% by mass) excluding, preferably 0.001 to 50% by mass, more preferably 0.01 to 40% by mass, still more preferably 0.07 to 30% by mass, still more preferably 0.1 to 0.1. It is 20% by mass.
- the content of each of these various additives is appropriately set depending on the type and function of each component, but the total amount of the water-soluble metalworking oil ( 100% by mass), preferably 0.001 to 25% by mass, more preferably 0.01 to 20% by mass, still more preferably 0.03 to 15% by mass, still more preferably 0.05 to 10% by mass. Is.
- anionic surfactant examples include polyoxyethylene alkyl ether carboxylic acid, polyoxyethylene alkyl ether phosphoric acid, alkylbenzene sulfonic acid, ⁇ -olefin sulfonic acid, and salts thereof.
- the acid value of the anionic surfactant is preferably 20 to 250 mgKOH / g, more preferably 30 to 200 mgKOH / g, still more preferably 40 to 190 mgKOH / g, and even more preferably 50 to 180 mgKOH / g.
- the cationic surfactant include an alkyltrimethylammonium salt, a dialkyldimethylammonium salt, an alkyldimethylbenzylammonium salt and the like.
- Examples of petroleum sulfonates include calcium sulfonates, sodium sulfonates, magnesium sulfonates and the like.
- non-sulfur-based extreme pressure agents include chlorine-based extreme pressure agents such as chlorinated paraffins, chlorinated fatty acids, and chlorinated fatty oils; Phosphorus-based, phosphorus-based extreme pressure agents such as tricresyl phosphate; and the like can be mentioned.
- metal inactivating agent examples include benzotriazole, imidazoline, pyrimidine derivative, thiadiazole and the like.
- emulsifying aid examples include unsaturated fatty acid esters such as methyl oleate, ethyl oleate, and propyl oleate; aromatic alcohols such as 2-phenoxyethanol and 2-phenylethyl alcohol; and the like.
- antibacterial agent examples include isothiazolin-based compounds, triazine-based compounds, alkylbenzimidazole-based compounds, metal pyrithione salts, and the like.
- defoaming agent examples include silicone-based defoaming agents, fluorosilicone-based defoaming agents, and polyacrylates.
- antioxidants examples include amine-based antioxidants such as alkylated diphenylamine, phenylnaphthylamine, and alkylated phenylnaphthylamine; 2,6-di-t-butylphenol, 4,4'-methylenebis (2,6-g-t-). Butylphenol), isooctyl-3- (3,5-di-t-butyl-4-hydroxyphenyl) propionate, n-octadecyl-3- (3,5-di-t-butyl-4-hydroxyphenyl) propionate, etc. Phenolic antioxidants; etc.
- oily agent examples include alcohols such as lauryl alcohol, myristyl alcohol, palmityl alcohol, stearyl alcohol, and oleyl alcohol.
- the method for producing the water-soluble metalworking oil according to one aspect of the present invention is not particularly limited, and the above-mentioned component (A),, if necessary, the components (B) to (E) and various other additives are blended. It is preferable that the method has a step of performing. The order of blending each component can be appropriately set.
- the acid value of the water-soluble metalworking oil according to one aspect of the present invention is preferably 10 to 70 mgKOH / g, more preferably 15 to 60 mgKOH / g, still more preferably 20 to 50 mgKOH / g, still more preferably 25 to 40 mgKOH / g. g.
- the base value of the water-soluble metalworking oil according to one aspect of the present invention is preferably 10 to 100 mgKOH / g, more preferably 20 to 90 mgKOH / g, still more preferably 30 to 80 mgKOH / g, still more preferably 40 to 70 mgKOH / g. g.
- the base value means a value measured according to JIS K2501: 2003 (hydrochloric acid method).
- the ratio [base value / acid value] of the base value to the acid value of the water-soluble metalworking oil according to one aspect of the present invention is preferably 1.0 to 4.0, more preferably 1.1 to 3.5. It is more preferably 1.3 to 3.2, still more preferably 1.5 to 3.0, and particularly preferably 1.7 to 2.8.
- the ratio is 1.0 or more, a water-soluble metalworking oil having good putrefaction resistance can be obtained.
- the ratio is 4.0 or less, the irritation to the skin of the human body can be reduced, which is preferable in terms of handleability.
- the metalworking liquid of the present invention is obtained by using the above-mentioned metalworking oil agent of one aspect of the present invention as a stock solution and mixing diluted water with the metalworking oil agent.
- the diluted water may be, for example, distilled water, ion-exchanged water, tap water, industrial water, or the like.
- the blending amount of the diluted water when preparing the metalworking liquid is more than 400 parts by mass with respect to 100 parts by mass of the total amount of the components other than water of the water-soluble metalworking oil, but the desired dilution concentration is obtained. It is preferable to make appropriate adjustments.
- the diluted concentration of the metal processing liquid according to one aspect of the present invention is preferably 1 to 50% by volume, more preferably 3 to 40% by volume, and further preferably 5 to 20% by volume.
- the metal processing liquid of one preferred embodiment of the present invention has excellent workability as compared with the conventional metal processing liquid, and can be suitably used for metal processing. Further, the metal processing liquid of one preferred embodiment of the present invention can exhibit excellent processability even if it does not contain a sulfur-based extreme pressure agent. Therefore, it is possible to effectively suppress the corrosion of the copper-containing member constituting the processing machine, which is caused by the sulfur-based extreme pressure agent.
- the work material to be processed using the metal processing liquid of one aspect of the present invention is not particularly limited, but is iron, titanium, aluminum, titanium alloy, alloy steel, nickel-based alloy, niobium alloy, tantalum alloy, molybdenum alloy. , Tungsten alloys, stainless steels, aluminum alloys, and materials made of metals selected from the group consisting of high manganese steels are particularly suitable. Among these, it is particularly suitable for a work material having a member containing at least iron or aluminum.
- the present invention may also provide the following [1] and [2].
- [1] A method of use in which the above-mentioned metal processing liquid of one aspect of the present invention is applied to the processing of a work material made of metal.
- [2] A metal processing method for processing a work material made of metal by applying the above-mentioned metal processing liquid according to one aspect of the present invention.
- the work material described in the above [1] and [2] is as described above, but a work material having a member containing at least iron or aluminum is suitable. Further, according to the methods described in [1] and [2] above, it is possible to suppress corrosion of members containing copper constituting the processing machine used for processing the work material.
- the metal processing liquid is prepared by mixing diluted water with the water-soluble metal processing oil of one aspect of the present invention. It is used by supplying it to the work material and bringing it into contact with the work material. The metal processing liquid lubricates between the work material and the processing tool. Furthermore, it is also used for removing chips, preventing rust on the work material, cooling tools and the work material, and the like.
- Oil-soluble PAG (a-1) An oil-soluble polyalkylene glycol conforming to VG32 having a viscosity grade specified by ISO 3448.
- Oil-soluble PAG (a-2) An oil-soluble polyalkylene glycol conforming to VG46 having a viscosity grade specified by ISO 3448.
- Oil-soluble PAG (a-3) An oil-soluble polyalkylene glycol conforming to VG68 having a viscosity grade specified by ISO 3448.
- the metal processing liquid prepared by diluting the water-soluble metal processing oils of Examples 1 to 8 has suppressed copper plate corrosion in both the solve type and the emulsion type, and has good workability. It was good.
- the metalworking liquid prepared by diluting the water-soluble metalworking oils of Comparative Examples 1 to 4 was inferior in at least one of the effect of suppressing copper plate corrosion and the workability.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Lubricants (AREA)
Abstract
Description
金属加工液には、鉱油、合成油、動植物油等の油分を主成分した油性金属加工液と、油分に界面活性を有する化合物を配合して水溶性を付与した水溶性金属加工液がある。近年では、火災の危険性が低い等の安全性の理由から、水溶性金属加工液が用いられるようになってきている。
また、特許文献2には、メチルジシクロヘキシルアミンを配合してなる水溶性加工油剤に関する発明が開示されている。
[1]油溶性ポリアルキレングリコール(A1)を含む基油(A)を含有し、
水溶性ポリアルキレングリコール及びメトキシポリエチレングリコールの合計含有量が、水を除く全量基準で60質量%未満である、水溶性金属加工油剤。
[2]水溶性ポリアルキレングリコール及びメトキシポリエチレングリコールの合計含有量が、成分(A1)の全量100質量部に対して、10質量部未満である、上記[1]に記載の水溶性金属加工油剤。
[3]硫黄系極圧剤を実質的に含有しない、上記[1]又は[2]に記載の水溶性金属加工油剤。
[4]さらに水(B)を含有する、上記[1]~[3]のいずれか一項に記載の水溶性金属加工油剤。
[5]成分(A)中の成分(A1)の含有割合が、前記水溶性金属加工油剤に含まれる成分(A)の全量基準で、10~100質量%である、上記[1]~[4]のいずれか一項に記載の水溶性金属加工油剤。
[6]成分(A1)の含有量が、前記水溶性金属加工油剤の水を除く全量基準で、0.01質量%以上である、上記[1]~[5]のいずれか一項に記載の水溶性金属加工油剤。
[7]さらにアミン系化合物(C)を含有する、上記[1]~[6]のいずれか一項に記載の水溶性金属加工油剤。
[8]さらに脂肪酸類(D)を含有する、上記[1]~[7]のいずれか一項に記載の水溶性金属加工油剤。
[9]さらに非イオン性界面活性剤(E)を含有する、上記[1]~[8]のいずれか一項に記載の水溶性金属加工油剤。
[10]JIS K2241:2017で規定するA1種に分類されるエマルション型の油剤である、上記[1]~[9]のいずれか一項に記載の水溶性金属加工油剤。
[11]JIS K2241:2017で規定するA2種に分類されるソルブル型の油剤である、上記[1]~[9]のいずれか一項に記載の水溶性金属加工油剤。
[12]油溶性ポリアルキレングリコール(A1)を含む基油(A)を含有し、
水溶性ポリアルキレングリコール及びメトキシポリエチレングリコールの合計含有量が、成分(A)の全量100質量部に対して、10質量部未満である、水溶性金属加工油剤。
[13]上記[1]~[12]のいずれか一項に記載の水溶性金属加工油剤に、希釈水を配合してなる、金属加工液。
[14]上記[13]に記載の金属加工液を適用して、金属からなる被加工材を加工する、金属加工方法。
[15]前記被加工材が、鉄又はアルミニウムを少なくとも含む部材を有する、上記[14]に記載の金属加工方法。
[16]前記被加工材の加工に用いる加工機を構成する銅を含む部材の腐食を抑制する、上記[14]又は[15]に記載の金属加工方法。
加えて、本明細書に記載された数値範囲として、例えば「60~100」との記載は、「60以上、100以下」という範囲であることを意味する。
「金属加工油剤」と「金属加工液」とは、例えば、以下のように、水の含有量によって区別することもできる。
・「金属加工油剤」:水の含有量が、水以外の成分の全量100質量部に対して0質量部以上400質量部以下である。
・「金属加工液」:水の含有量が、水以外の成分の全量100質量部に対して、400質量部超である。
本発明の水溶性金属加工油剤は、油溶性ポリアルキレングリコール(以下、「油溶性PAG」ともいう)(A1)を含む基油(A)を含有し、水溶性ポリアルキレングリコール(以下、「水溶性PAG」ともいう)及びメトキシポリエチレングリコール(以下、「MPEG」ともいう)の合計含有量を所定の含有量になるように調整した油剤である。
なお、本明細書において、「水溶性」とは、25℃の水100gへの溶解量が20g以上であって、25℃の水100gに対象物質を20g添加して調製した25℃の溶液の全光線透過率が90%以上である成分を意味する。
なお、本明細書の以下の記載において、「水溶性」と記載された成分は、上記の特性を有する成分である。
なお、本発明の一態様の水溶性金属加工油剤は、本発明の効果を損なわない範囲で、成分(A)~(E)以外の他の成分を含有してもよい。
以下、本発明の一態様の水溶性金属加工油剤に含まれる各成分について説明する。
本発明の水溶性金属加工油剤は、油溶性PAG(A1)を含む基油(A)を含有する。
本発明の水溶性金属加工油剤は、基油として油溶性PAGを含むため、当該水溶性金属加工油剤に希釈水を配合してなる金属加工液の加工性を向上させることができる。
なお、一般的に加工性(特に、鉄を含む被加工材の加工性)に優れた金属加工液とするためには、その原液である水溶性金属加工油剤は硫黄系極圧剤を含有する。しかしながら、硫黄性極圧剤は、被加工材の金属加工の際に用いる加工機を構成する銅を含む部材の腐食を引き起こす要因となる。一方で、本発明の水溶性金属加工油剤は、成分(A1)を含有することで、硫黄系極圧剤を実質的に含有しなくても、優れた加工性を有する金属加工液に調製可能であり、また銅部材の腐食の問題も回避できる。
ただし、加工性に優れた金属加工液となり得る水溶性金属加工油剤とする観点から、本発明の一態様の水溶性金属加工油剤において、成分(A)中の成分(A1)の含有割合は、当該水溶性金属加工油剤に含まれる成分(A)の全量(100質量%)基準で、10~100質量%、20~100質量%、30~100質量%、40~100質量%、50~100質量%、60~100質量%、70~100質量%、75~100質量%、80~100質量%、85~100質量%、90~100質量%、95~100質量%、又は98~100質量%としてもよい。
本発明の一態様で用いる成分(A1)としては、アルキレンオキシドに由来する構成単位を有し、油溶性を示すポリアルキレングリコール(PAG)であれば特に制限はない。
なお、本明細書において、対象となるPAGが油溶性か否かの判断は、API(米国石油協会)基油カテゴリーのグループ1に分類される鉱油に対する混和性により判断される。具体的には、対照となるPAGと前記グループ1に分類される鉱油の含有量比〔PAG/鉱油〕が、質量比で、10/90又は90/10となるサンプルを調製し、サンプル及び標準試料の25℃での全光線透過率を測定して、以下の基準(i)及び(ii)を満たす場合に、油溶性PAGであると判断する。
・(i)含有量比〔PAG/鉱油〕=10/90のサンプルの場合、[当該サンプルの全光線透過率(%)]-[前記鉱油のみの全光線透過率(%)]≦20%である。
・(ii)含有量比〔PAG/鉱油〕=90/10のサンプルの場合、[当該サンプルの全光線透過率(%)]-[前記PAGの全光線透過率(%)]≦20%である。
なお、本明細書の以下の記載において、「油溶性」と記載された成分は、特に断りが無い限り、上記の基準(i)及び(ii)を満たす成分である。
なお、成分(A1)は、単独で用いてもよく、2種以上を併用してもよい。
本発明の一態様で用いる成分(A1)以外の基油(A2)としては、油溶性PAG以外の、鉱油及び合成油から選ばれる少なくとも1種が挙げられる。
なお、本明細書において、上述の水溶性ポリアルキレングリコール(水溶性PAG)及びメトキシポリエチレングリコール(MPEG)も成分(A2)に含まれるが、水溶性PAG及びMPEGの合計含有量は、上述のとおり調整される。
また、本発明の一態様で用いる成分(A2)の粘度指数は、好ましくは70以上、より好ましくは80以上、更に好ましくは90以上、より更に好ましくは100以上、特に好ましくは105以上である。
本発明の一態様の水溶性金属加工油剤は、さらに水(B)を含有してもよい。水を含有する水溶性金属加工油剤とすることで、難燃性を付与して非危険物とし、保管時の取扱性を良好とすることができる。
本発明の一態様で用いる成分(B)である水としては、特に限定されず、例えば、蒸留水、イオン交換水、水道水、工業用水等のいずれであってもよい。
なお、JIS K2241:2017で規定する、A1種に分類されるエマルション型の油剤とする場合、成分(B)の含有量は、当該水溶性金属加工油剤中の水以外の成分の全量100質量部に対して、150質量部以下、100質量部以下、70質量部以下、50質量部以下、40質量部以下、30質量部以下、20質量部以下、又は15質量部以下としてもよく、また、下限は上記のとおりである。
また、JIS K2241:2017で規定する、A2種に分類されるソルブル型の油剤とする場合、成分(B)の含有量は、当該水溶性金属加工油剤中の水以外の成分の全量100質量部に対して、10質量部以上、30質量部以上、50質量部以上、60質量部以上、70質量部以上、80質量部以上、90質量部以上、又は100質量部以上としてもよく、また、上限は上記のとおりである。
なお、JIS K2241:2017で規定する、A1種に分類されるエマルション型の油剤とする場合、成分(B)の含有量は、当該水溶性金属加工油剤の全量(100質量%)基準で、70質量%以下、60質量%以下、50質量%以下、40質量%以下、30質量%以下、25質量%以下、20質量%以下、又は15質量%以下としてもよく、また、下限は上記のとおりである。
また、JIS K2241:2017で規定する、A2種に分類されるソルブル型の油剤とする場合、成分(B)の含有量は、当該水溶性金属加工油剤の全量(100質量%)基準で、10質量%以上、15質量%以上、20質量%以上、25質量部以上、30質量%以上、35質量%以上、40質量%以上、45質量部以上、又は50質量%以上としてもよく、また、上限は上記のとおりである。
本発明の一態様の水溶性金属加工油剤は、さらにアミン系化合物(C)を含有することが好ましい。成分(C)を含有する水溶性金属加工油剤は、希釈水を配合して金属加工液とした際に、乳化状態を良好とし、抗菌性、防錆性、及び加工性等をより向上させた金属加工液となり得る。
なお、成分(C)は、単独で用いてもよく、2種以上を併用してもよい。
ただし、抗菌性、防錆性、及び加工性等をより向上させた金属加工液となり得る水溶性金属加工油剤とする観点から、本発明の一態様で用いる成分(C)は、モノアミンを含むことが好ましい。
モノアミンの含有割合は、水溶性金属加工油剤に含まれる成分(C)の全量(100質量%)基準で、好ましくは50~100質量%、より好ましくは60~100質量%、より好ましくは70~100質量%、より好ましくは75~100質量%、更に好ましくは80~100質量%、更に好ましくは85~100質量%、より更に好ましくは90~100質量%、より更に好ましくは95~100質量%、特に好ましくは98~100質量%である。
なお、希釈水を配合して金属加工液とした際に、乳化状態を良好とし、抗菌性、防錆性、及び加工性等をより向上させた金属加工液となり得る水溶性金属加工油剤とする観点から、本発明の一態様で用いる成分(C)は、少なくとも第3級モノアミンを含むことが好ましく、第1級モノアミン及び第2級モノアミンの少なくとも一方と第3級モノアミンを含むことがより好ましく、少なくとも第2級モノアミン及び第3級モノアミンを含むことが更に好ましい。
当該アルキル基は、直鎖アルキル基であってもよく、分岐鎖アルキル基であってもよい。
また、当該アルキル基の炭素数は、好ましくは1~30、より好ましくは1~20、更に好ましくは1~10、より更に好ましくは1~6、特に好ましくは1~4である。
当該基を構成するアルキル基も、直鎖アルキル基であってもよく、分岐鎖アルキル基であってもよい。
前記水酸基を有するアルキル基の炭素数は、好ましくは1~30、より好ましくは1~20、更に好ましくは1~10、より更に好ましくは1~6、特に好ましくは2~4である。
当該アルケニル基は、直鎖アルケニル基であってもよく、分岐鎖アルケニル基であってもよい。
また、当該アルケニル基の炭素数は、好ましくは1~30、より好ましくは1~20、更に好ましくは1~10、より更に好ましくは1~6、特に好ましくは1~3である。
アルカノールアミンとしては、前記式(i)中のRが水酸基を有するアルキル基である第1級アルカノールアミン、前記式(ii)中のRの少なくとも1つが水酸基を有するアルキル基である第2級アルカノールアミン、及び、前記式(iii)中のRの少なくとも1つが水酸基を有するアルキル基である第3級アルカノールアミンが挙げられる。
脂環式アミンとしては、前記式(i)中のRがシクロアルキル基である第1級脂環式アミン、前記式(ii)中のRの少なくとも1つがシクロアルキル基である第2級脂環式アミン、及び、前記式(iii)中のRの少なくとも1つがシクロアルキル基である第3級脂環式アミンが挙げられる。
第2級脂環式アミンとしては、例えば、N-メチルシクロヘキシルアミン、N-エチルシクロヘキシルアミン、N-プロピルシクロヘキシルアミン、N-オレイルシクロヘキシルアミン等のモノシクロヘキシルアミン;N-シクロヘキシルエタノールアミン、N-シクロヘキシルプロパノールアミン等のモノシクロヘキシルアルカノールアミン;N-ジシクロヘキシルアミン等が挙げられる。
第3級脂環式アミンとしては、例えば、N-ジメチルシクロヘキシルアミン、N-ジエチルシクロヘキシルアミン、N-ジプロピルシクロヘキシルアミン、N-ジオレイルシクロヘキシルアミン、N-ジシクロヘキシルアミン等のジアルキルモノシクロヘキシルアミン;N-シクロヘキシルジエタノールアミン、N-シクロヘキシルジプロパノールアミン等のモノシクロヘキシルジアルカノールアミン;N-メチルジシクロヘキシルアミン、N-エチルジシクロヘキシルアミン、N-プロピルジシクロヘキシルアミン、N-オレイルジシクロヘキシルアミン等のモノアルキルジシクロヘキシルアミン;N-ジシクロヘキシルエタノールアミン、N-ジシクロヘキシルプロパノールアミン等のジシクロヘキシルアルカノールアミン;トリシクロヘキシルアミン等が挙げられる。
また、JIS K2241:2017で規定する、A2種に分類されるソルブル型の油剤とする場合、成分(C)は、モノシクロヘキシルジアルカノールアミン、及びジシクロヘキシルアルカノールアミンから選ばれる1種以上を含むことが好ましく、モノシクロヘキシルジアルカノールアミンを含むことがより好ましい。
他のアミンの含有量は、前記水溶性金属加工油剤に含まれる成分(C)の全量(100質量%)基準で、0~50質量%、0~40質量%、0~30質量%、0~20質量%、0~10質量%、0~5.0質量%、0~2.0質量%、0~1.0質量%、0~0.10質量%、0~0.01質量%、0~0.001質量%、0~0.0001質量%、又は0~0.00001質量%としてもよい。
本発明の一態様の水溶性金属加工油剤は、さらに脂肪酸類(D)を含有することが好ましい。
成分(D)を含有することで、乳化安定性、防錆性、及び加工性等をより向上させた金属加工液となり得る水溶性金属加工油剤とすることができる。
なお、本発明の一態様の水溶性金属加工油剤において、成分(D)は、単独で用いてもよく、2種以上を併用してもよい。
また、不飽和脂肪酸の混合物である、トール油脂肪酸、大豆油脂肪酸、パーム油脂肪酸、亜麻仁油脂肪酸、米糠油脂肪酸、綿実油脂肪酸等を用いてもよい。
前記脂肪酸の炭素数としては、好ましくは8~30、より好ましくは10~25、更に好ましくは10~20である。
前記ヒドロキシ脂肪酸の炭素数としては、好ましくは8~30、より好ましくは10~25、更に好ましくは10~20である。
前記脂肪族ジカルボン酸の炭素数としては、好ましくは8~30、より好ましくは10~25、更に好ましくは10~20である。
そして、前記ヒドロキシ不飽和脂肪酸の重合脂肪酸としては、ヒドロキシ不飽和脂肪酸の脱水重縮合物である縮合脂肪酸(例えば、リシノール酸を主成分とする脂肪酸混合物の脱水縮合物であるひまし油重合脂肪酸)や、ヒドロキシ不飽和脂肪酸の脱水重縮合物である縮合脂肪酸のアルコール性水酸基とモノカルボン酸とを脱水縮合した縮合脂肪酸等が挙げられる。
成分(D)の水酸基価としては、好ましくは0~80mgKOH/g、より好ましくは0~60mgKOH/g、更に好ましくは0~40mgKOH/gである。
成分(D)の酸価と水酸基価との比〔酸価/水酸基価〕は、上記観点から、好ましくは1.5~15、より好ましくは2.0~10、更に好ましくは2.5~9.5である。
成分(D)のけん化価は、好ましくは180~220mgKOH/g、より好ましくは190~210mgKOH/g、更に好ましくは195~205mgKOH/gである。
なお、本明細書において、酸価は、JIS K2501:2003(指示薬光度滴定法)に準拠して測定した値を意味し、水酸基価は、JIS K0070:1992に準拠して測定した値を意味し、けん化価は、JIS K2503:1996に基づいて測定した値を意味する。
本発明の一態様の水溶性金属加工油剤は、さらに非イオン界面活性剤(E)を含有することが好ましい。成分(E)を含有することで、乳化安定性及び加工性をより向上させた金属加工液となり得る水溶性金属加工油剤とすることができる。
なお、本発明の一態様の水溶性金属加工油剤において、成分(E)は、単独で用いてもよく、2種以上を併用してもよい。
なお、JIS K2241:2017で規定する、A1種に分類されるエマルション型の油剤とする場合、成分(E)の含有量は、当該水溶性金属加工油剤の水を除く全量(100質量%)基準で、15.0質量%以下、12.0質量%以下、10.0質量%以下、8.0質量%以下、6.0質量%以下、5.0質量%以下、4.0質量%以下、又は3.5質量%以下としてもよく、また、下限は上記のとおりである。
JIS K2241:2017で規定する、A2種に分類されるソルブル型の油剤とする場合、成分(E)の含有量は、当該水溶性金属加工油剤の水を除く全量(100質量%)基準で、2.0質量%以上、3.0質量%以上、4.0質量%以上、5.0質量%以上、6.0質量%以上、7.0質量%以上、8.0質量%以上、9.0質量%以上、又は10.0質量%以上としてもよく、また、上限は上記のとおりである。
なお、JIS K2241:2017で規定する、A1種に分類されるエマルション型の油剤とする場合、成分(E)の含有量は、当該水溶性金属加工油剤の全量(100質量%)基準で、5.0質量%以下、4.5質量%以下、4.0質量%以下、3.5質量%以下、3.0質量%以下、又は2.5質量%以下としてもよく、また、下限は上記のとおりである。
JIS K2241:2017で規定する、A2種に分類されるソルブル型の油剤とする場合、成分(E)の含有量は、当該水溶性金属加工油剤の全量(100質量%)基準で、1.0質量%以上、1.2質量%以上、1.5質量%以上、2.0質量%以上、2.5質量%以上、3.0質量%以上、3.5質量%以上、又は4.0質量%以上としてもよく、また、上限は上記のとおりである。
なお、本明細書において、HLBは、グリフィン法により算出された値を意味する。
ポリオキシアルキレンアルキルエーテル及びポリオキシアルキレンアルキルアミンの合計含有割合は、水溶性金属加工油剤に含まれる成分(E)の全量(100質量%)基準で、好ましくは50~100質量%、より好ましくは70~100質量%、更に好ましくは80~100質量%、より更に好ましくは90~100質量%、特に好ましくは95~100質量%である。
本発明の水溶性金属加工油剤は、基油(A)として油溶性PAG(A1)を含むため、銅を含む部材の腐食を引き起こす要因となる硫黄系極圧剤を含有しなくても、優れた加工性を有する金属加工液を調製することができる。そのため、銅を含む部材の腐食を抑制効果が高い金属加工液となり得る水溶性金属加工油剤とする観点から、本発明の一態様の水溶性金属加工油剤は、硫黄系極圧剤を実質的に含有しないことが好ましい。
なお、硫黄系極圧剤としては、例えば、硫化オレフィン、硫化ラード、アルキルポリサルファイド、硫化脂肪酸等が挙げられる。
具体的な硫黄系極圧剤の含有量は、前記水溶性金属加工油剤に含まれる成分(A1)の全量100質量部に対して、好ましくは10質量部未満、より好ましくは1質量部未満、更に好ましくは0.1質量部未満、より更に好ましくは0.01質量部未満、特に好ましくは0.001質量部未満である。
本発明の一態様の水溶性金属加工油剤は、本発明の効果を損なわない範囲で、必要に応じて、上記成分(A)~(E)以外の他の各種添加剤をさらに含有してもよい。
そのような他の各種添加剤としては、例えば、アニオン性界面活性剤、カチオン性界面活性剤、石油スルホネート、硫黄系以外の極圧剤、金属不活性化剤、乳化助剤、抗菌剤、消泡剤、酸化防止剤、油性剤等が挙げられる。
なお、これらの各種添加剤は、それぞれ単独で用いてもよく、2種以上を併用してもよい。
なお、アニオン性界面活性剤の酸価は、好ましくは20~250mgKOH/g、より好ましくは30~200mgKOH/g、更に好ましくは40~190mgKOH/g、より更に好ましくは50~180mgKOH/gである。
カチオン性界面活性剤としては、例えば、アルキルトリメチルアンモニウム塩、ジアルキルジメチルアンモニウム塩、アルキルジメチルベンジルアンモニウム塩等が挙げられる。
本発明の一態様の水溶性金属加工油剤の製造方法としては、特に制限はなく、上述の成分(A)、必要に応じて、成分(B)~(E)及び他の各種添加剤を配合する工程を有する、方法であることが好ましい。各成分の配合の順序は適宜設定することができる。
本発明の一態様の水溶性金属加工油剤の酸価は、好ましくは10~70mgKOH/g、より好ましくは15~60mgKOH/g、更に好ましくは20~50mgKOH/g、より更に好ましくは25~40mgKOH/gである。
本発明の一態様の水溶性金属加工油剤の塩基価は、好ましくは10~100mgKOH/g、より好ましくは20~90mgKOH/g、更に好ましくは30~80mgKOH/g、より更に好ましくは40~70mgKOH/gである。
なお、本明細書において、塩基価は、JIS K2501:2003(塩酸法)に準拠して測定した値を意味する。
当該比が1.0以上であれば、耐腐敗性が良好な水溶性金属加工油剤とすることができる。一方、当該比が4.0以下であれば、人体の皮膚への刺激性を小さくすることができ、取扱性の点で好ましい。
本発明の金属加工液は、上述の本発明の一態様の金属加工油剤を原液とし、当該金属加工油剤に希釈水を配合してなるものである。
希釈水としては、例えば、蒸留水、イオン交換水、水道水、工業用水等のいずれであってもよい。
本発明の一態様の金属加工液の希釈濃度としては、好ましくは1~50体積%、より好ましくは3~40体積%、更に好ましくは5~20体積%である。
なお、本明細書において、上記の「金属加工液の希釈濃度」は、下記式から算出された値を意味する。
・「金属加工液の希釈濃度(体積%)」=〔希釈前の金属加工油剤としての体積〕/[〔希釈前の金属加工油剤としての体積〕+〔希釈水の体積〕]×100
本発明の好適な一態様の金属加工液は、従来の金属加工液に比べて、加工性に優れており、金属加工に好適に使用し得る。また、本発明の好適な一態様の金属加工液は、硫黄系極圧剤を含有せずとも、優れた加工性を発現させることができる。そのため、硫黄系極圧剤が要因となる、加工機を構成する銅を含む部材の腐食を効果的に抑制することができる。
〔1〕上述の本発明の一態様の金属加工液を金属からなる被加工材の加工に適用する、使用方法。
〔2〕上述の本発明の一態様の金属加工液を適用して、金属からなる被加工材を加工する、金属加工方法。
また、上記〔1〕及び〔2〕に記載の方法によれば、前記被加工材の加工に用いる加工機を構成する銅を含む部材の腐食を抑制ことができる。
なお、上記〔1〕の使用方法、及び、上記〔2〕の金属加工方法において、金属加工液は、上述の本発明の一態様の水溶性金属加工油剤に希釈水を配合した上で、被加工材に供給して、被加工材に接触させて使用される。金属加工液は、被加工材と加工具との間を潤滑する。更には、切り屑の除去、被加工材の錆止め、工具及び被加工材の冷却等のためにも使用される。
なお、以下の実施例において、下記の物性値の測定方法及び算出方法は以下に示すとおりである。
(1)動粘度、粘度指数
JIS K2283:2000に準拠して測定及び算出した。
(2)HLB
グリフィン法に基づいて算出した。
(3)酸価(指示薬光度滴定法)
JIS K2501:2003(指示薬光度滴定法)に準拠して測定した。
(4)塩基価(塩酸法)
JIS K2501:2003(塩酸法)に準拠して測定した。
表2及び表3に示す種類の各種成分を、表2及び表3に示す配合量にて添加して混合して、水溶性金属加工油剤をそれぞれ調製した。当該水溶性金属加工油剤の調製に使用した、各成分の詳細は以下のとおりである。
・油溶性PAG(a-1):ISO 3448で規定の粘度グレードのVG32に適合する油溶性ポリアルキレングリコール。
・油溶性PAG(a-2):ISO 3448で規定の粘度グレードのVG46に適合する油溶性ポリアルキレングリコール。
・油溶性PAG(a-3):ISO 3448で規定の粘度グレードのVG68に適合する油溶性ポリアルキレングリコール。
<成分(A2)>
・パラフィン系鉱油:40℃動粘度=7.117mm2/s、粘度指数=109のパラフィン系鉱油。
<成分(B)>
・水:イオン交換水
<成分(C)>
・アミン(c-1):N-メチルエタノールアミン、第2級モノアミン
・アミン(c-2):N-シクロヘキシルジエタノールアミン、第3級モノアミン
・アミン(c-3):N-メチルジエタノールアミン、第3級モノアミン
・アミン(c-4):トリイソプロパノールアミン、第3級モノアミン
・アミン(c-5):N-メチルジシクロヘキシルアミン、第3級モノアミン
<成分(D)>
・脂肪酸類(d-1):ネオデカン酸
・脂肪酸類(d-2):トール油脂肪酸
・脂肪酸類(d-3):ドデカン二酸
・脂肪酸類(d-4):ひまし油重合脂肪酸(リシノレイン酸6量体、酸価:31.6mgKOH/g、水酸基価:9.4mgKOH/g、酸価/水酸基価=3.36)
<成分(E)>
・非イオン性界面活性剤(e-1):ココアミンエチレンオキサイド2モル付加物、HLB=6.3
・非イオン性界面活性剤(e-2):ポリオキシアルキレンアルキルエーテル、HLB=12.7
<硫黄系極圧剤>
・ジオクチルポリスルフィド
<他の成分>
・アニオン性界面活性剤:ポリオキシエチレンオレイルエーテルカルボン酸、酸価=69.3mgKOH/g。
・金属不活性化剤:ベンゾトリアゾール
・乳化助剤:2-フェノキシエタノール
・抗菌剤:1,2-ベンゾイソチアゾリン-3-オン
・消泡剤:シリコーン系消泡剤
(1)油剤タイプの分類
JIS K2241:2017の規定に準拠して、同規定のA1種のエマルション型油剤もしくはA2種のソルブル型油剤に分類した。なお、表2及び表3においては、A1種のエマルション型油剤に分類された場合は「E」、A2種のソルブル型油剤に分類された場合は「S」と記載した。
JIS K2513に準拠した試験方法にて、油温50℃で48時間の条件で試験を行い、銅板の変色度合いを観察し、下記表1に示すJIS K2513の「表1 銅板腐食標準による腐食の分類」に基づいて、銅板の腐食の程度を評価した。なお、表2及び3においては、「変色番号(細分記号)」で記載しており、変色番号は、1~4の数値で銅板の腐食の程度を示しており、数値が大きいほど腐食が進行していることを示す。
水溶性金属加工油剤にイオン交換水を加えて希釈し、希釈濃度5体積%の金属加工液を調製した。調製した金属加工液を用いて、以下の条件で下穴ドリル加工を行った後、タッピングトルク試験を行い、加工時の最大タップトルクを測定した。測定は3回行い、その結果の平均値及び最大値を表2及び表3に記載した。
当該平均値及び最大値が小さいほど、用いた金属加工液の金属加工性が優れているといえる。
<下穴加工条件>
・使用機械:タッピングセンターMTV-T350(株式会社メクトロン製)
・ドリル:SG-ESS(株式会社不二越製)、ドリル径:5.56mm
・切削速度:31m/min
・回転速度:1798min-1
・送り速度:260mm/min
・一回転あたりの送り量:0.145mm/rev
・深さ:15mm
<タッピングトルク試験>
・使用試験機:Megatap II(micro-electronische Gerate GmbH)
・タップ:ニューロールタップ VP-NRT B M6×1(オーエスジー株式会社製)
・切削速度:10m/min
・送り量:1.0mm/rev
・深さ:12mm
・加工n数:3
・被削材:SCM440(JIS規格)(クロムモリブデン鋼)
Claims (16)
- 油溶性ポリアルキレングリコール(A1)を含む基油(A)を含有し、
水溶性ポリアルキレングリコール及びメトキシポリエチレングリコールの合計含有量が、水を除く全量基準で60質量%未満である、水溶性金属加工油剤。 - 水溶性ポリアルキレングリコール及びメトキシポリエチレングリコールの合計含有量が、成分(A1)の全量100質量部に対して、10質量部未満である、請求項1に記載の水溶性金属加工油剤。
- 硫黄系極圧剤を実質的に含有しない、請求項1又は2に記載の水溶性金属加工油剤。
- さらに水(B)を含有する、請求項1~3のいずれか一項に記載の水溶性金属加工油剤。
- 成分(A)中の成分(A1)の含有割合が、前記水溶性金属加工油剤に含まれる成分(A)の全量基準で、10~100質量%である、請求項1~4のいずれか一項に記載の水溶性金属加工油剤。
- 成分(A1)の含有量が、前記水溶性金属加工油剤の水を除く全量基準で、0.01質量%以上である、請求項1~5のいずれか一項に記載の水溶性金属加工油剤。
- さらにアミン系化合物(C)を含有する、請求項1~6のいずれか一項に記載の水溶性金属加工油剤。
- さらに脂肪酸類(D)を含有する、請求項1~7のいずれか一項に記載の水溶性金属加工油剤。
- さらに非イオン性界面活性剤(E)を含有する、請求項1~8のいずれか一項に記載の水溶性金属加工油剤。
- JIS K2241:2017で規定するA1種に分類されるエマルション型の油剤である、請求項1~9のいずれか一項に記載の水溶性金属加工油剤。
- JIS K2241:2017で規定するA2種に分類されるソルブル型の油剤である、請求項1~9のいずれか一項に記載の水溶性金属加工油剤。
- 油溶性ポリアルキレングリコール(A1)を含む基油(A)を含有し、
水溶性ポリアルキレングリコール及びメトキシポリエチレングリコールの合計含有量が、成分(A)の全量100質量部に対して、10質量部未満である、水溶性金属加工油剤。 - 請求項1~12のいずれか一項に記載の水溶性金属加工油剤に、希釈水を配合してなる、金属加工液。
- 請求項13に記載の金属加工液を適用して、金属からなる被加工材を加工する、金属加工方法。
- 前記被加工材が、鉄又はアルミニウムを少なくとも含む部材を有する、請求項14に記載の金属加工方法。
- 前記被加工材の加工に用いる加工機を構成する銅を含む部材の腐食を抑制する、請求項14又は15に記載の金属加工方法。
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2022545509A JPWO2022044566A1 (ja) | 2020-08-31 | 2021-07-09 | |
CN202180053115.5A CN115989312A (zh) | 2020-08-31 | 2021-07-09 | 水溶性金属加工油剂 |
US18/042,787 US20230357663A1 (en) | 2020-08-31 | 2021-07-09 | Water-soluble metalworking fluid |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2020-146021 | 2020-08-31 | ||
JP2020146021 | 2020-08-31 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2022044566A1 true WO2022044566A1 (ja) | 2022-03-03 |
Family
ID=80353212
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2021/025922 WO2022044566A1 (ja) | 2020-08-31 | 2021-07-09 | 水溶性金属加工油剤 |
Country Status (4)
Country | Link |
---|---|
US (1) | US20230357663A1 (ja) |
JP (1) | JPWO2022044566A1 (ja) |
CN (1) | CN115989312A (ja) |
WO (1) | WO2022044566A1 (ja) |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5714696A (en) * | 1980-07-01 | 1982-01-25 | Cosmo Co Ltd | Flame retardant lubricating oil |
JPS6317994A (ja) * | 1986-07-10 | 1988-01-25 | Cosmo Co Ltd | 難燃性潤滑油 |
JPH09176738A (ja) * | 1995-12-27 | 1997-07-08 | Kobe Steel Ltd | 銅管コイルの製造方法 |
JPH10130675A (ja) * | 1996-10-25 | 1998-05-19 | Kobe Steel Ltd | 抽伸加工用潤滑油 |
JPH10140176A (ja) * | 1996-11-07 | 1998-05-26 | Sanyo Chem Ind Ltd | 含水潤滑剤 |
JP2000160186A (ja) * | 1998-11-30 | 2000-06-13 | Yushiro Chem Ind Co Ltd | 水溶性金属加工用油剤 |
JP2003238978A (ja) * | 2001-12-10 | 2003-08-27 | Sanyo Chem Ind Ltd | 金属加工油 |
WO2010021299A1 (ja) * | 2008-08-22 | 2010-02-25 | 出光興産株式会社 | 水溶性金属加工油剤および金属加工用クーラント |
JP2016503822A (ja) * | 2012-12-12 | 2016-02-08 | ダウ グローバル テクノロジーズ エルエルシー | 濃縮金属加工流体および金属加工プロセス |
JP2017527664A (ja) * | 2014-09-19 | 2017-09-21 | ヴァンダービルト ケミカルズ、エルエルシー | ポリアルキレングリコール系工業用潤滑剤組成物 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2014155870A1 (ja) * | 2013-03-26 | 2014-10-02 | 住友精化株式会社 | 水溶性金属加工油剤 |
JP6283552B2 (ja) * | 2014-03-28 | 2018-02-21 | 出光興産株式会社 | 水溶性金属加工油および金属加工用クーラント |
-
2021
- 2021-07-09 US US18/042,787 patent/US20230357663A1/en active Pending
- 2021-07-09 WO PCT/JP2021/025922 patent/WO2022044566A1/ja active Application Filing
- 2021-07-09 JP JP2022545509A patent/JPWO2022044566A1/ja active Pending
- 2021-07-09 CN CN202180053115.5A patent/CN115989312A/zh active Pending
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5714696A (en) * | 1980-07-01 | 1982-01-25 | Cosmo Co Ltd | Flame retardant lubricating oil |
JPS6317994A (ja) * | 1986-07-10 | 1988-01-25 | Cosmo Co Ltd | 難燃性潤滑油 |
JPH09176738A (ja) * | 1995-12-27 | 1997-07-08 | Kobe Steel Ltd | 銅管コイルの製造方法 |
JPH10130675A (ja) * | 1996-10-25 | 1998-05-19 | Kobe Steel Ltd | 抽伸加工用潤滑油 |
JPH10140176A (ja) * | 1996-11-07 | 1998-05-26 | Sanyo Chem Ind Ltd | 含水潤滑剤 |
JP2000160186A (ja) * | 1998-11-30 | 2000-06-13 | Yushiro Chem Ind Co Ltd | 水溶性金属加工用油剤 |
JP2003238978A (ja) * | 2001-12-10 | 2003-08-27 | Sanyo Chem Ind Ltd | 金属加工油 |
WO2010021299A1 (ja) * | 2008-08-22 | 2010-02-25 | 出光興産株式会社 | 水溶性金属加工油剤および金属加工用クーラント |
JP2016503822A (ja) * | 2012-12-12 | 2016-02-08 | ダウ グローバル テクノロジーズ エルエルシー | 濃縮金属加工流体および金属加工プロセス |
JP2017527664A (ja) * | 2014-09-19 | 2017-09-21 | ヴァンダービルト ケミカルズ、エルエルシー | ポリアルキレングリコール系工業用潤滑剤組成物 |
Also Published As
Publication number | Publication date |
---|---|
US20230357663A1 (en) | 2023-11-09 |
CN115989312A (zh) | 2023-04-18 |
JPWO2022044566A1 (ja) | 2022-03-03 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6051026B2 (ja) | 水溶性金属加工油剤、金属加工液、及び金属加工方法 | |
US9587197B2 (en) | Additive compositions and industrial process fluids | |
CN103958655B (zh) | 水溶性金属加工油剂、金属加工液,以及金属加工方法 | |
CN108138076B (zh) | 水溶性金属加工油组合物 | |
JP2011111593A (ja) | 水溶性金属加工油剤およびその使用方法 | |
EP2705128A1 (en) | Amine-free voc-free metal working fluid | |
KR20160137981A (ko) | 수용성 금속 가공유 및 금속 가공용 쿨런트 | |
JP2013107938A (ja) | 水溶性金属加工油剤、金属加工液、及び金属加工方法 | |
CN106459822B (zh) | 水溶性金属加工油和金属加工用冷却剂 | |
WO2022024719A1 (ja) | 水溶性金属加工油剤 | |
JP5576361B2 (ja) | 水溶性加工油剤 | |
WO2022044566A1 (ja) | 水溶性金属加工油剤 | |
TW201437360A (zh) | 水性金屬加工油劑 | |
JP7305751B2 (ja) | 水溶性金属加工油組成物 | |
WO2023162707A1 (ja) | 水溶性潤滑剤 | |
WO2023106341A1 (ja) | 水溶性金属加工油剤 | |
WO2021182605A1 (ja) | 水溶性金属加工油組成物 | |
WO2021143804A1 (zh) | 水溶性金属加工液组合物及其使用方法 | |
JP6355339B2 (ja) | 金属加工油剤組成物、それを用いた加工方法及びその金属加工方法により製造される金属加工部品 | |
JP2008214510A (ja) | 金属用水溶性加工油剤 | |
JP2023141499A (ja) | 金属加工油剤組成物 | |
JP5492602B2 (ja) | 水溶性金属加工液 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 21860996 Country of ref document: EP Kind code of ref document: A1 |
|
ENP | Entry into the national phase |
Ref document number: 2022545509 Country of ref document: JP Kind code of ref document: A |
|
WWE | Wipo information: entry into national phase |
Ref document number: 202347020976 Country of ref document: IN |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
122 | Ep: pct application non-entry in european phase |
Ref document number: 21860996 Country of ref document: EP Kind code of ref document: A1 |