WO2021212656A1 - 一种低温用高锰奥氏体钢快速合金化工艺 - Google Patents
一种低温用高锰奥氏体钢快速合金化工艺 Download PDFInfo
- Publication number
- WO2021212656A1 WO2021212656A1 PCT/CN2020/098814 CN2020098814W WO2021212656A1 WO 2021212656 A1 WO2021212656 A1 WO 2021212656A1 CN 2020098814 W CN2020098814 W CN 2020098814W WO 2021212656 A1 WO2021212656 A1 WO 2021212656A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- ladle
- alloying
- manganese
- steel
- tapping
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
- C21C5/28—Manufacture of steel in the converter
- C21C5/30—Regulating or controlling the blowing
- C21C5/34—Blowing through the bath
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/04—Removing impurities by adding a treating agent
- C21C7/072—Treatment with gases
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C33/00—Making ferrous alloys
- C22C33/04—Making ferrous alloys by melting
- C22C33/06—Making ferrous alloys by melting using master alloys
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B7/00—Rotary-drum furnaces, i.e. horizontal or slightly inclined
- F27B7/20—Details, accessories, or equipment peculiar to rotary-drum furnaces
- F27B7/22—Rotary drums; Supports therefor
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/001—Austenite
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Definitions
- the invention relates to a fast alloying process of high-manganese austenitic steel for low temperature.
- High-manganese austenitic steel for low temperature use (15% ⁇ [Mn] ⁇ 30%), due to the high manganese content of molten steel and easy oxidation of manganese, it cannot be added to the converter together with the scrap steel.
- Manganese can only be carried out through the converter tapping and LF refining process
- the alloying of manganese leads to long manganese alloying time (more than 8 hours), low production efficiency, which is not conducive to continuous casting production; and long-term LF furnace alloying is likely to cause high content of molten steel hydrogen and nitrogen gas, which will affect the quality of continuous casting billets. Have a greater impact.
- the technical problem to be solved by the present invention is to provide a rapid alloying process for high manganese austenitic steel at low temperature in view of the shortcomings of the above prior art, reducing the manganese alloying time of high manganese austenitic steel from 8 hours to Within 3 hours, the production efficiency and the quality of molten steel were improved, and the rapid alloying of high-manganese austenitic steel for low temperature was realized.
- the technical solution of the present invention to solve the above technical problems is: a rapid alloying process of high manganese austenitic steel for low temperature, including manganese alloy baking ⁇ converter tapping and tapping alloying ⁇ LF slag alloying, specifically:
- the grid plate is welded into a support with the same diameter as the bottom of the ladle, and the support is put into the bottom of the ladle; then the manganese alloy that needs to be baked is added to the ladle, and the amount of manganese alloy added is 230-260Kg/ t steel, and the addition amount does not exceed three-quarters of the volume of the ladle;
- the tapping amount the weight of the standard ladle holding steel-the weight of the baked manganese alloy -1/3*The weight of the standard ladle containing steel, the converter tapping temperature is 1660°C-1700°C, and the tapping time is 3-5min;
- LF refining furnace electrode heating and heating, stirring and desulfurization under 400-500NL/min large argon gas, large argon gas stirring and heating, heating and alloying, raising the temperature of molten steel to 1580°C-1600°C, and the heating time is more than 60 minutes;
- the present invention further defines the scheme:
- the ladle age of the aforementioned prepared ladle is before one third of the total ladle age.
- a layer of lime for steelmaking is added on the manganese alloy.
- the amount of lime added is 8-10Kg/t steel.
- the baked alloy steel ladle is hoisted to the tapping station of the converter, and the bottom blowing of the ladle is turned on, and the flow rate of the bottom blowing of the ladle is 600-800 Nl/min.
- the aforementioned lime is added in batches during the cooling process of large argon gas to accelerate the cooling, each batch of lime is added 1.5Kg/t, and the total amount added in the cooling process is not more than 6Kg/t.
- the present invention carries out the process control of suitable alloy amount, suitable baking temperature, baking time and baking batch in advance through the steel ladle, and at the same time optimizing the converter steel tapping temperature and LF alloying process, greatly shortening LF refining furnace alloying time.
- the LF refining furnace alloying time is shortened from 9 hours to 3 hours, which reduces the probability of increasing the molten steel gas content caused by the long-term heating of the LF refining furnace for alloying, which not only ensures continuous production, but also improves product quality .
- 150t converter, 150t LF refining furnace smelting, 25Mn steel grade are selected, and a high-manganese austenitic steel rapid alloying process for low temperature is provided, including manganese alloy baking ⁇ converter tapping and tapping alloying ⁇ LF
- the process flow of slag alloying is as follows:
- Ladle preparation The total ladle age is 100 furnaces, and the No. 23 ladle with the ladle age of 19 furnaces is selected as the alloy baking ladle;
- the electrodes of LF refining furnace are heated and sampled. For details, see Table 1. Large argon gas is stirred for desulfurization, the bottom blowing of the ladle is turned on, the argon flow rate is 500 NL/min, the large argon gas is stirred and heated for alloying for 77 minutes, and the molten steel temperature is 1593°C;
- the present invention can also have other embodiments. All technical solutions formed by equivalent replacements or equivalent transformations fall within the protection scope of the present invention.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- General Engineering & Computer Science (AREA)
- Treatment Of Steel In Its Molten State (AREA)
- Carbon Steel Or Casting Steel Manufacturing (AREA)
Abstract
Description
Claims (5)
- 一种低温用高锰奥氏体钢快速合金化工艺,包括锰合金烘烤→转炉出钢和出钢合金化→LF化渣合金化,其特征在于:具体为:(一):锰合金烘烤:(1)准备钢包包龄在前期的钢包;(2)采用格栅板焊接成与钢包底直径大小相同的支撑件,将制作的支撑件放入钢包底部;然后加入需要烘烤的锰合金至钢包内,该锰合金加入量230-260Kg/t钢,且加入量不超过钢包容积的四分之三;(3)将准备好的装有锰合金的钢包,放置到正常上线钢包烘烤工位开始烘烤,烘烤火焰温度调整至1000℃,烘烤时间24小时以上;(二):转炉出钢和出钢合金化:(1)将烘烤好的合金钢包吊运至转炉出钢工位,接通钢包底吹,打开钢包底吹进行出钢,其出钢量=标准钢包盛钢重量-烘烤锰合金的重量-1/3*标准钢包盛钢重量,转炉出钢温度1660℃-1700℃,出钢时间为3-5min;(三):LF化渣合金化:(1)LF精炼炉升温合金化过程:LF精炼炉电极加热升温,在流量为400-500NL/min大氩气下搅拌脱硫,大氩气搅拌加热升温合金化,将钢水温度提升至1580℃-1600℃,升温时间为60分钟以上;(2)LF精炼炉大氩气搅拌降温合金化过程:当钢水温度升至1580℃-1600℃后,停止升温操作,调整钢包底吹氩气流量至600NL/min,落下LF精炼炉钢包小炉盖,进行大氩气搅拌降温操作,钢水温度降低至1480℃后,合金化工作完成,停止大氩气搅拌,调整钢包底吹氩气流量至50-80NL/min继续搅拌15分钟,吊至连铸工位进行浇铸作业,在大氩气搅拌降温过程中取样测温,根据取样分析钢水中成分情况,若小于钢种要求成分范围,则加入合金进行钢水成分微调,逐步将钢水成分调整至钢种要求的成分范围内。
- 根据权利要求1所述的低温用高锰奥氏体钢快速合金化工艺,其特征在于:准备钢包的包龄在总包龄三分之一之前。
- 根据权利要求1所述的低温用高锰奥氏体钢快速合金化工艺,其特征在于:在锰合金加入钢包后,在锰合金上面加入一层炼钢用石灰,石灰加入量8-10Kg/t钢。
- 根据权利要求1所述的低温用高锰奥氏体钢快速合金化工艺,其特征在于:将烘烤好的合金钢包吊运至转炉出钢工位,接通钢包底吹,钢包底吹流量600-800Nl/min。
- 根据权利要求1所述的低温用高锰奥氏体钢快速合金化工艺,其特征在于:在大氩气搅拌降温过程中分批次加入石灰加速降温,每批次石灰加入1.5Kg/t,降温过程总加入量不大于6Kg/t。
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KR1020227036492A KR102581522B1 (ko) | 2020-04-24 | 2020-06-29 | 저온용 고(高) 망간 오스테나이트강의 급속 합금화 공정 |
AU2020443584A AU2020443584B2 (en) | 2020-04-24 | 2020-06-29 | Low-temperature high-manganese austenitic steel rapid alloying process |
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CN202010333385.9A CN111394644A (zh) | 2020-04-24 | 2020-04-24 | 一种低温用高锰奥氏体钢快速合金化工艺 |
CN202010333385.9 | 2020-04-24 |
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KR (1) | KR102581522B1 (zh) |
CN (1) | CN111394644A (zh) |
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WO (1) | WO2021212656A1 (zh) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114032473A (zh) * | 2021-11-29 | 2022-02-11 | 东北大学 | 一种免涂层热成形钢的合金加入方法 |
CN114686784A (zh) * | 2022-04-02 | 2022-07-01 | 四川罡宸不锈钢有限责任公司 | 一种节镍型奥氏体不锈钢材料及制备方法 |
CN114908208A (zh) * | 2022-04-18 | 2022-08-16 | 包头钢铁(集团)有限责任公司 | 一种利用转炉终点温度冶炼Mn含量12%以上高合金钢方法 |
Families Citing this family (2)
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CN111974980A (zh) * | 2020-07-22 | 2020-11-24 | 南京钢铁股份有限公司 | 一种转炉炼钢过程中冶炼高合金钢的合金预热工艺 |
CN114317882A (zh) * | 2021-12-21 | 2022-04-12 | 中车长江铜陵车辆有限公司 | 一种双联冶炼的合金烘烤方法 |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002097516A (ja) * | 2000-09-21 | 2002-04-02 | Kawasaki Steel Corp | 真空脱ガス槽内での高マンガン鋼の溶製方法 |
WO2006061261A1 (en) * | 2004-12-06 | 2006-06-15 | F.A.R. - Fonderie Acciaierie Roiale - Spa | Method to obtain a manganese steel alloy, and manganese steel alloy thus obtained |
CN103882181A (zh) * | 2012-12-21 | 2014-06-25 | 鞍钢股份有限公司 | 一种含锰钢合金化的工艺 |
JP2016065274A (ja) * | 2014-09-24 | 2016-04-28 | Jfeスチール株式会社 | 低炭素高マンガン鋼の溶製方法 |
CN107586915A (zh) * | 2017-09-06 | 2018-01-16 | 东北大学 | 一种中高锰钢中锰元素的合金化方法 |
CN109750210A (zh) * | 2018-12-29 | 2019-05-14 | 广西长城机械股份有限公司 | 低氧、氢含量高锰钢的生产方法 |
CN110616362A (zh) * | 2019-09-30 | 2019-12-27 | 河钢股份有限公司 | 一种低温环境用高锰钢的炼钢方法 |
CN110724792A (zh) * | 2019-09-30 | 2020-01-24 | 河钢股份有限公司 | 一种用lf精炼炉生产低温环境用高锰钢的冶炼方法 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000034545A (ja) * | 1998-07-14 | 2000-02-02 | Daido Steel Co Ltd | 熱間加工性の改善されたオーステナイト系耐熱鋼およびその製造方法 |
CN105420440A (zh) * | 2014-09-19 | 2016-03-23 | 鞍钢股份有限公司 | 一种转炉冶炼中、高锰合金钢的合金加入方法 |
CN105420446A (zh) * | 2014-09-22 | 2016-03-23 | 南京钢铁股份有限公司 | 一种lf炉轻处理冶炼方法 |
-
2020
- 2020-04-24 CN CN202010333385.9A patent/CN111394644A/zh active Pending
- 2020-06-29 KR KR1020227036492A patent/KR102581522B1/ko active IP Right Grant
- 2020-06-29 WO PCT/CN2020/098814 patent/WO2021212656A1/zh active Application Filing
- 2020-06-29 AU AU2020443584A patent/AU2020443584B2/en active Active
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002097516A (ja) * | 2000-09-21 | 2002-04-02 | Kawasaki Steel Corp | 真空脱ガス槽内での高マンガン鋼の溶製方法 |
WO2006061261A1 (en) * | 2004-12-06 | 2006-06-15 | F.A.R. - Fonderie Acciaierie Roiale - Spa | Method to obtain a manganese steel alloy, and manganese steel alloy thus obtained |
CN103882181A (zh) * | 2012-12-21 | 2014-06-25 | 鞍钢股份有限公司 | 一种含锰钢合金化的工艺 |
JP2016065274A (ja) * | 2014-09-24 | 2016-04-28 | Jfeスチール株式会社 | 低炭素高マンガン鋼の溶製方法 |
CN107586915A (zh) * | 2017-09-06 | 2018-01-16 | 东北大学 | 一种中高锰钢中锰元素的合金化方法 |
CN109750210A (zh) * | 2018-12-29 | 2019-05-14 | 广西长城机械股份有限公司 | 低氧、氢含量高锰钢的生产方法 |
CN110616362A (zh) * | 2019-09-30 | 2019-12-27 | 河钢股份有限公司 | 一种低温环境用高锰钢的炼钢方法 |
CN110724792A (zh) * | 2019-09-30 | 2020-01-24 | 河钢股份有限公司 | 一种用lf精炼炉生产低温环境用高锰钢的冶炼方法 |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114032473A (zh) * | 2021-11-29 | 2022-02-11 | 东北大学 | 一种免涂层热成形钢的合金加入方法 |
CN114686784A (zh) * | 2022-04-02 | 2022-07-01 | 四川罡宸不锈钢有限责任公司 | 一种节镍型奥氏体不锈钢材料及制备方法 |
CN114908208A (zh) * | 2022-04-18 | 2022-08-16 | 包头钢铁(集团)有限责任公司 | 一种利用转炉终点温度冶炼Mn含量12%以上高合金钢方法 |
CN114908208B (zh) * | 2022-04-18 | 2023-09-26 | 包头钢铁(集团)有限责任公司 | 一种利用转炉终点温度冶炼Mn含量12%以上高合金钢方法 |
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KR102581522B1 (ko) | 2023-09-22 |
KR20220154813A (ko) | 2022-11-22 |
AU2020443584B2 (en) | 2023-02-02 |
CN111394644A (zh) | 2020-07-10 |
AU2020443584A1 (en) | 2022-12-08 |
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