WO2021024656A1 - 金属担持触媒、電池電極及び電池 - Google Patents
金属担持触媒、電池電極及び電池 Download PDFInfo
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- WO2021024656A1 WO2021024656A1 PCT/JP2020/026043 JP2020026043W WO2021024656A1 WO 2021024656 A1 WO2021024656 A1 WO 2021024656A1 JP 2020026043 W JP2020026043 W JP 2020026043W WO 2021024656 A1 WO2021024656 A1 WO 2021024656A1
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- metal
- catalyst
- carbon
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Definitions
- the present invention relates to a metal-supported catalyst, a battery electrode, and a battery.
- Patent Document 1 describes an electrode catalyst for an air electrode having the following configuration: (1) The electrode catalyst for an air electrode is composed of a first catalyst particle made of a Pt alloy and the first catalyst particle. Also includes second catalyst particles made of pure Pt having a small average particle size; (2) The Pt alloy has an atomic composition ratio represented by PtxM (1 ⁇ x ⁇ 4, M is a base metal element). Have.
- Patent Document 2 describes (i) a supporting material having a plurality of individual supporting particles or aggregates, (ii) a first particle containing a first metal and an alloy metal, and (iii) platinum or iridium.
- An electrode catalyst material comprising a second metal or a second particle composed of an oxide of the second metal, each of which is a separate carrying particle or aggregate of the first particle dispersed on itself.
- an electrode catalyst material having a second particle and characterized in that the average particle size of the second particle is smaller than the average particle size of the first particle.
- the present invention has been made in view of the above problems, and one of its objects is to provide a metal-supported catalyst, a battery electrode, and a battery having both excellent catalytic activity and durability.
- the metal-supported catalyst according to an embodiment of the present invention for solving the above problems includes a carbon carrier and catalyst metal particles containing a noble metal supported on the carbon carrier, and per unit weight of the carbon carrier.
- the volume of the first pore having a diameter of 0.5 nm or more and 2.0 nm or less is 0.20 (cm 3 / g-carrier) or more, and more than 2.0 nm per unit weight of the carbon carrier.
- the volume of the second pore having a diameter of 4.0 nm or less is 0.20 (cm 3 / g-carrier) or more, and the content (% by weight) of the noble metal measured by inductively coupled plasma mass analysis.
- the ratio of the content (% by weight) of the noble metal measured by X-ray photoelectron spectroscopy to is 0.35 or more and 0.75 or less. According to the present invention, there is provided a metal-supported catalyst having both excellent catalytic activity and durability.
- the volume of the third pore having a diameter of more than 4.0 nm and 50.0 nm or less per unit weight of the carbon carrier is 0.25 (cm 3 / g-carrier) or more. It may be. In the metal-supported catalyst, the volume of the third pore having a diameter of more than 4.0 nm and 50.0 nm or less per unit weight of the carbon carrier is 1.00 cm 3 / g-carrier or less. May be. In the metal-supported catalyst, the diameter of more than 4.0 nm and less than 50.0 nm with respect to the volume of the second pore having a diameter of more than 2.0 nm and less than 4.0 nm per unit weight of the carbon carrier. The volume ratio of the third pore having the volume may be 3.00 or less.
- Scheller's equation is used using the diffraction angles and half-value full widths of one or more diffraction peaks obtained by separating the diffraction lines having a diffraction angle 2 ⁇ of about 40 ° in the powder X-ray diffraction pattern by CuK ⁇ rays.
- the average crystallite diameter of the catalyst metal particles calculated according to the above may be 7.0 nm or less.
- the ratio of the nitrogen atom concentration to the carbon atom concentration measured by X-ray photoelectron spectroscopy may be 0.010 or more.
- the standardized specific surface area calculated by multiplying the BET specific surface area by the ratio of the weight of the metal-supported catalyst to the weight of the carbon carrier is 1100 (m 2 / g-carrier) or more. It may be that.
- the catalyst metal particles may be platinum particles.
- the amount of hydrogen-adsorbed electricity measured by cyclic voltammetry using a rotating disk electrode containing the metal-supported catalyst is used as the theoretical area-equivalent amount of electricity for hydrogen adsorption on platinum and the metal-supported catalyst.
- electrochemical surface area obtained by dividing the weight of supported platinum (H 2 -ECSA) is not less 20.0 m 2 / g- platinum or, stripping voltammetry using rotating disk electrode including the metal-supported catalyst.
- -ECSA) may be 20.0 m 2 / g-platinum or more.
- the metal-supported catalyst may contain a carbon structure showing a half-value width of 160 cm -1 or less in the D band having a peak top near 1360 cm -1 in the Raman spectrum obtained by Raman spectroscopy.
- the metal-supported catalyst may contain a carbon structure showing a half-value width of 90 cm -1 or less in the G band having a peak top near 1600 cm -1 in the Raman spectrum obtained by Raman spectroscopy.
- In the metal-supported catalyst in the Raman spectrum obtained by Raman spectroscopy, between the G band and the D band having a peak top near 1360 cm -1 with respect to the intensity of the G band having a peak top near 1600 cm -1. It may contain a carbon structure having a minimum intensity ratio of 0.20 or more and 0.50 or less.
- the metal-supported catalyst is a carbon exhibiting a nitrogen desorption amount of 1.20 ⁇ 10-5 (mol / g-carrier) or more from 600 ° C. to 1000 ° C. per unit weight of the carbon carrier in the temperature-temperature desorption method. It may include a structure.
- the metal-supported catalyst is a carbon exhibiting a nitrogen desorption amount of 0.75 ⁇ 10-5 (mol / g-carrier) or more from 800 ° C. to 1000 ° C. per unit weight of the carbon carrier in the temperature-temperature desorption method. It may include a structure.
- the battery electrode according to the embodiment of the present invention for solving the above problems includes any of the above metal-supported catalysts. According to the present invention, a battery electrode having both excellent catalytic activity and durability is provided.
- the battery according to the embodiment of the present invention for solving the above problems includes the battery electrode. According to the present invention, a battery having both excellent catalytic activity and durability is provided.
- a metal-supported catalyst, a battery electrode, and a battery having both excellent catalytic activity and durability are provided.
- the metal-supported catalyst hereinafter referred to as “the catalyst”
- the battery electrode hereinafter referred to as “the electrode”
- the battery hereinafter referred to as “the battery”
- the present catalyst contains a carbon carrier and catalyst metal particles containing a noble metal supported on the carbon carrier, and has a diameter of 0.5 nm or more and 2.0 nm or less per unit weight of the carbon carrier.
- the volume of the second pore having a diameter of more than 2.0 nm and not more than 4.0 nm per unit weight of the carbon carrier, which has a pore volume of 0.20 (cm 3 / g-carrier) or more.
- ICP-MS inductively coupled plasma mass analysis
- XPS X-ray photoelectron spectroscopy
- the carbon carrier contained in this catalyst is a carbon material mainly composed of carbon.
- the content of carbon atoms in the carbon carrier may be, for example, 70% by weight or more, 75% by weight or more, 80% by weight or more, or 85% by weight or more. Good.
- the carbon carrier may be a carbonized material. That is, the carbon carrier may be a carbonized material obtained by carbonizing a raw material containing an organic substance. Further, the carbon carrier may be a carbonized material obtained by carbonizing a raw material containing an organic substance and a metal.
- the metal is preferably a transition metal.
- the transition metal may be a transition metal other than platinum, or a noble metal (eg, ruthenium (Ru), palladium (Pd), rhodium (Rh), silver (Ag), osmium (Os), iridium (Ir), It may be a transition metal other than platinum (Pt) and gold (Au)).
- the carbon carrier may contain a transition metal inside its skeleton. That is, the carbon carrier may contain a transition metal inside the skeleton that constitutes its porous structure.
- the carbon carrier when the carbon carrier is a carbonized material produced by carbonization of a raw material containing an organic substance and a transition metal, the carbon carrier contains a transition metal derived from the raw material of carbonization at the time of its production. That is, the carbon carrier contains the transition metal inside its skeleton because the transition metal was contained in the raw material for carbonization. Even when the carbon carrier is manufactured through a metal removal treatment, a trace amount of transition metal derived from the raw material remains inside the carbon carrier.
- the transition metal inside the skeleton of the carbon carrier is detected by cutting the skeleton and analyzing the cross section exposed by the cutting. That is, when the carbon carrier is in the form of particles, when the particles of the carbon carrier are cut, a transition metal is detected in the cross section of the particles exposed by the cutting.
- the transition metal contained in this carbon carrier can be detected by, for example, ICP-MS.
- the ICP-MS transition metal content of a carbon carrier is calculated as the ratio (% by weight) of the weight of the transition metal atom to the total weight of the carbon carrier.
- the carbon carrier may contain 0.01% by weight or more of the transition metal (for example, a transition metal derived from the raw material for carbonization) inside the skeleton, and may contain 0.02% by weight or more of the transition metal. May be. Further, the transition metal content of the carbon carrier may be 15% by weight or less, or 10% by weight or less.
- the transition metal content of the carbon carrier may be specified by any combination of any of the above-mentioned lower limit values and any of the above-mentioned upper limit values.
- the transition metal contained in the carbon carrier derived from the raw material for carbonization may be a transition metal belonging to groups 3 to 12 of the periodic table, and a transition metal belonging to the 4th period of groups 3 to 12 of the periodic table. It is preferably a metal.
- the transition metals contained in the carbon carrier include, for example, scandium (Sc), titanium (Ti), vanadium (V), chromium (Cr), manganese (Mn), iron (Fe), cobalt (Co), and the like.
- the carbon carrier may be a carbon catalyst.
- the carbon carrier itself exhibits catalytic activity.
- the carbon carrier may exhibit, for example, reducing activity and / or oxidizing activity as catalytic activity, preferably exhibiting oxygen reducing activity and / or hydrogen oxidizing activity, and at least exhibiting oxygen reducing activity. Is particularly preferable.
- the carbon carrier may be a carbon catalyst containing a transition metal inside its skeleton. That is, when the carbon carrier is a carbon catalyst obtained by carbonizing a raw material containing an organic substance and a metal, the carbon structure of the carbon catalyst contains the metal. In this case, it is considered that the catalytic activity of the carbon catalyst is mainly due to the active sites contained in the carbon structure formed by the carbonization, rather than the metal derived from the raw material for carbonization. This means that even when a carbon catalyst containing a metal derived from a raw material for carbonization is subjected to a metal removal treatment for reducing the content of the metal, the catalytic activity of the carbon catalyst after the metal removal treatment remains unchanged.
- the catalytic metal particles supported on the carbon carrier in this catalyst are not particularly limited as long as they contain noble metals and exhibit catalytic activity, but are preferably noble metal particles.
- the noble metal particles consist of, for example, a group consisting of ruthenium (Ru), palladium (Pd), rhodium (Rh), silver (Ag), osmium (Os), iridium (Ir), platinum (Pt), and gold (Au). It is preferably a noble metal particle containing one or more selected species, and more preferably a noble metal particle containing one or more selected from the group consisting of Ru, Pd, Rh, Ir and Pt, which is a Pt particle. Is particularly preferred.
- the noble metal particles are pure noble metal particles and / or noble metal alloy particles.
- Precious metal alloy particles are made from noble metals (eg, ruthenium (Ru), palladium (Pd), rhodium (Rh), silver (Ag), osmium (Os), iridium (Ir), platinum (Pt), and gold (Au).
- the non-precious metal is a metal other than the noble metal and is not particularly limited as long as it forms an alloy with the noble metal, but is preferably a transition metal. That is, the noble metal alloy particles may include a noble metal alloy of a noble metal and a transition metal. In this case, the noble metal alloy may be an alloy of the noble metal and one kind of transition metal, or may be an alloy of the noble metal and two or more kinds of transition metals.
- the noble metal alloy is an alloy of a noble metal and one or more transition metals selected from the group consisting of Cu, Mn, Ce, Au, Pd, Ru, Nb, Ti, Fe, Co, and Ni. It is more preferable that the alloy is an alloy of the noble metal and one or more transition metals selected from the group consisting of Fe, Co, and Ni, and is selected from the group consisting of the noble metal and Co and Ni1. It is particularly preferred to be an alloy with more than one species of transition metal.
- the present catalyst may contain only pure noble metal particles, may contain only noble metal alloy particles, or may contain pure noble metal particles and noble metal alloy particles, but at least pure. It preferably contains a noble metal.
- the noble metal particles containing pure noble metal particles and / or noble metal alloy particles are, for example, noble metal particles containing one or more selected from the group consisting of Ru, Pd, Rh, Ag, Os, Ir, Pt, and Au. It is preferably a noble metal particle containing at least one selected from the group consisting of Ru, Pd, Rh, Ir and Pt, and particularly preferably a noble metal particle (Pt particle) containing Pt.
- the Pt particles are pure Pt particles and / or Pt alloy particles.
- Pure Pt indicates a diffraction line having a peak top at a position where the diffraction angle (2 ⁇ ) is 39.6 ° or more and less than 39.8 ° in the XRD diffraction pattern obtained by X-ray diffraction (XRD).
- the Pt alloy shows a diffraction line having a peak top at a position where the diffraction angle (2 ⁇ ) is 39.9 ° or more and less than 43.0 ° in the XRD diffraction pattern.
- the Pt alloy is an alloy of Pt and one or more other metals (metals other than Pt: non-Pt metal).
- the non-Pt metal is not particularly limited as long as it forms an alloy with Pt, but is preferably a transition metal. That is, the Pt alloy particles may contain a platinum alloy of platinum and a transition metal. In this case, the Pt alloy may be an alloy of Pt and one kind of transition metal, or may be an alloy of Pt and two or more kinds of transition metals.
- the Pt alloy is an alloy of Pt and one or more transition metals selected from the group consisting of Cu, Mn, Ce, Au, Pd, Ru, Nb, Ti, Fe, Co, and Ni. It is more preferable that it is an alloy of Pt and one or more transition metals selected from the group consisting of Fe, Co, and Ni, and it is more preferably selected from the group consisting of Pt, Co, and Ni1. It is particularly preferred to be an alloy with more than one species of transition metal.
- the catalyst may contain only pure Pt particles as Pt particles, may contain only Pt alloy particles, or may contain pure Pt particles and Pt alloy particles, but at least pure. It preferably contains Pt.
- the ratio of the amount of pure Pt supported to the total amount of pure Pt supported and the amount of Pt alloy supported in the present catalyst is, for example, preferably 5% or more, and particularly preferably 10% or more. ..
- Pt alloy particles of Pt and transition metal contributes to catalytic activity.
- Pt distorts the lattice and improves its oxygen reduction catalytic activity.
- the Pt alloy particles containing the above transition metals exhibit excellent catalytic activity by having a lattice in which appropriate strain is generated.
- the content of the noble metal (for example, Pt) of the present catalyst (for example, the ratio of the weight of the noble metal contained in the catalyst metal particles carried on the metal-supporting catalyst to the weight of the metal-supporting catalyst) obtained by ICP-MS measurement is determined. For example, it may be 1.0% by weight or more, preferably 5.0% by weight or more, more preferably 10.0% by weight or more, and particularly preferably 20.0% by weight or more. preferable.
- the noble metal content of the present catalyst obtained by ICP-MS measurement may be, for example, 60.0% by weight or less.
- the molar ratio of the noble metal to the non-noble metal contained in the present catalyst (precious metal / non-noble metal ratio) (for example, Pt to the non-Pt metal) obtained by ICP-MS measurement.
- the molar ratio (Pt / non-Pt metal ratio)) may be, for example, 0.5 or more, preferably 1.0 or more, and particularly preferably 2.0 or more.
- the Pt / non-Pt metal ratio may be, for example, 20.0 or less, preferably 15.0 or less, and particularly preferably 10.0 or less.
- the noble metal / non-precious metal ratio may be specified by arbitrarily combining any of the above-mentioned lower limit values and any of the above-mentioned upper limit values.
- the catalyst contains pores. Specifically, the present catalyst contains pores in its carbon carrier.
- This catalyst contains first pores having a diameter of 0.5 nm or more and 2.0 nm or less.
- the first pores are relatively small pores among the pores of the carbon carrier contained in the present catalyst.
- the first pores are expected to function as a field for nucleation and particle growth of catalytic metal particles having a relatively small particle size and exhibiting high catalytic activity.
- the volume of the first pores per unit weight of the catalyst may be 0.15 (cm 3 / g) or more, preferably 0.20 (cm 3 / g) or more, and is 0. It is particularly preferable that it is .25 (cm 3 / g) or more.
- the volume of the first pores per unit weight of the catalyst may be, for example, 3.00 (cm 3 / g) or less, or 2.00 (cm 3 / g) or less. However, it may be 1.00 (cm 3 / g) or less.
- the volume of the first pores per unit weight of the catalyst may be specified by arbitrarily combining any of the above-mentioned lower limit values and any of the above-mentioned upper limit values.
- the volume of the first pores per unit weight of the carbon carrier of this catalyst is 0.20 (cm 3 / g-carrier) or more.
- the volume of the first pores per unit weight of the carbon carrier is preferably, for example, 0.25 (cm 3 / g-carrier) or more, and 0.30 (cm 3 / g-carrier) or more. More preferably, it is 0.35 (cm 3 / g-carrier) or more, and it is particularly preferable.
- the volume of the first pores per unit weight of the carbon carrier may be, for example, 3.00 (cm 3 / g-carrier) or less, or 2.00 (cm 3 / g-carrier) or less. It may be 1.00 (cm 3 / g-carrier) or less.
- the volume of the first pores per unit weight of the carbon carrier may be specified by any combination of any of the above-mentioned lower limit values and any of the above-mentioned upper limit values.
- the large volume of the first pores contributes to the catalytic activity of this catalyst. That is, for example, when this catalyst is used as an oxygen reduction catalyst, the large volume of the first pores provides a place where catalytic metal particles having a relatively small particle size showing high catalytic activity are preferentially generated. , Contributes to the excellent oxygen reduction catalytic activity of this catalyst.
- This catalyst contains a second pore having a diameter of more than 2.0 nm and less than 4.0 nm.
- the second pores are relatively small but larger than the first pores.
- the second pores are expected to function as a place for transporting reactants and products of the chemical reaction of this catalyst.
- the volume of the second pores per unit weight of the catalyst may be 0.15 (cm 3 / g) or more, and is particularly preferably 0.20 (cm 3 / g) or more.
- the volume of the second pores per unit weight of the present catalyst may be, for example, 3.00 (cm 3 / g) or less, or 2.50 (cm 3 / g) or less. However, it may be 2.00 (cm 3 / g) or less, 1.50 (cm 3 / g) or less, or 1.00 (cm 3 / g) or less. Good.
- the volume of the second pores per unit weight of the catalyst may be specified by any combination of any of the above-mentioned lower limit values and any of the above-mentioned upper limit values.
- the volume of the second pores per unit weight of the carbon carrier of this catalyst is 0.20 (cm 3 / g-carrier) or more.
- the volume of the second pore per unit weight of the carbon carrier is preferably 0.25 (cm 3 / g-carrier) or more, and preferably 0.30 (cm 3 / g-carrier) or more. More preferably, it is 0.33 (cm 3 / g-carrier) or more, and particularly preferably 0.35 (cm 3 / g-carrier) or more.
- the volume of the second pore per unit weight of the carbon carrier may be, for example, 3.00 (cm 3 / g-carrier) or less, or 2.50 (cm 3 / g-carrier) or less. It may be 2.00 (cm 3 / g-carrier) or less, 1.50 (cm 3 / g-carrier) or less, or 1.00 (cm 3). / G-carrier) or less.
- the volume of the second pores per unit weight of the carbon carrier may be specified by any combination of any of the above-mentioned lower limit values and any of the above-mentioned upper limit values.
- the large volume of the second pore contributes to the durability of this catalyst. That is, for example, when this catalyst is used as an oxygen reduction catalyst for a fuel cell electrode, the second pores are expected to promote the drainage of generated water, so that the volume of the second pores is large. , The retention of the produced water in the carbon carrier of the present catalyst and the accompanying oxidative corrosion of carbon are effectively suppressed, and the aggregation and desorption of the catalyst metal particles are suppressed. Further, since the second pores are expected to support the catalyst metal particles relatively firmly, the large volume of the second pores causes the catalyst metal particles to aggregate from the carbon carrier of the present catalyst. Desorption is effectively suppressed.
- the catalyst may include a third pore having a diameter of more than 4.0 nm and less than 50.0 nm.
- the third pore is a pore larger than the second pore.
- the third pore is a place where catalytic metal particles having a relatively large particle size are supported.
- the volume of the third pore per unit weight of the catalyst may be, for example, 0.20 (cm 3 / g) or more, and preferably 0.25 (cm 3 / g) or more. , 0.30 (cm 3 / g) or more is particularly preferable.
- the volume of the third pore per unit weight of the present catalyst may be, for example, 3.00 (cm 3 / g) or less, or 2.50 (cm 3 / g) or less. However, it may be 2.00 (cm 3 / g) or less, 1.50 (cm 3 / g) or less, or 1.00 (cm 3 / g) or less. Good.
- the volume of the third pore per unit weight of the present catalyst is preferably, for example, 0.75 (cm 3 / g) or less, and is preferably 0.70 (cm 3 / g) or less. It is more preferably 0.65 (cm 3 / g) or less, and particularly preferably 0.60 (cm 3 / g) or less.
- the volume of the third pore per unit weight of the catalyst may be specified by arbitrarily combining any of the above-mentioned lower limit values and any of the above-mentioned upper limit values.
- the volume of the third pores per unit weight of the carbon carrier of the present catalyst may be, for example, 0.25 (cm 3 / g-carrier) or more.
- the volume of the third pore per unit weight of the carbon carrier is preferably, for example, 0.30 (cm 3 / g-carrier) or more, and is 0.35 (cm 3 / g-carrier) or more. More preferably, it is more preferably 0.40 (cm 3 / g-carrier) or more, and particularly preferably 0.45 (cm 3 / g-carrier) or more.
- the volume of the third pore per unit weight of the carbon carrier may be, for example, 3.00 (cm 3 / g-carrier) or less, or 2.50 (cm 3 / g-carrier) or less. It may be 2.00 (cm 3 / g-carrier) or less, 1.50 (cm 3 / g-carrier) or less, and 1.00 (cm 3 / g-carrier) or less. ) It may be as follows. Further, the volume of the third pore per unit weight of the carbon carrier is preferably 0.90 (cm 3 / g-carrier) or less, preferably 0.80 (cm 3 / g-carrier) or less.
- the volume of the third pore per unit weight of the carbon carrier may be specified by any combination of any of the above-mentioned lower limit values and any of the above-mentioned upper limit values.
- the ratio of the volume of the third pore to the volume of the second pore (third pore / second pore volume ratio) per unit weight of the catalyst is, for example, 3.00 or less. It may be 2.50 or less, and particularly preferably 2.00 or less.
- the third pore / second pore volume ratio per unit weight of the catalyst may be, for example, 0.1 or more, or 0.5 or more.
- the third pore / second pore volume ratio per unit weight of the catalyst may be specified by any combination of any of the above-mentioned lower limit values and any of the above-mentioned upper limit values.
- the ratio of the volume of the third pore to the volume of the second pore (third pore / second pore volume ratio) per unit weight of the carbon carrier of this catalyst is, for example, 3.00. It may be as follows.
- the third pore / second pore volume ratio per unit weight of the carbon carrier of the present catalyst is, for example, preferably 2.50 or less, and particularly preferably 2.00 or less.
- the third pore / second pore volume ratio may be, for example, 0.1 or more, or 0.5 or more.
- the third pore / second pore volume ratio of the present catalyst may be specified by arbitrarily combining any of the above-mentioned lower limit values and any of the above-mentioned upper limit values.
- the ratio (precious metal-XPS / ICP ratio) of the noble metal content (% by weight) measured by XPS to the content (% by weight) of the noble metal (for example, Pt) measured by ICP-MS of this catalyst is , 0.35 or more, 0.75 or less.
- the noble metal-XPS / ICP ratio is obtained by dividing the noble metal content (% by weight) in the present catalyst obtained by XPS by the noble metal content (% by weight) in the present catalyst obtained by ICP-MS. It is calculated.
- the noble metal-XPS / ICP ratio of this catalyst is, for example, preferably 0.36 or more, more preferably 0.38 or more, and particularly preferably 0.41 or more.
- the noble metal-XPS / ICP ratio of this catalyst is, for example, preferably 0.70 or less, more preferably 0.65 or less, and particularly preferably 0.60 or less.
- the noble metal-XPS / ICP ratio of the present catalyst may be specified by arbitrarily combining any of the above-mentioned lower limit values and any of the above-mentioned upper limit values.
- the metal measurement by XPS in addition to the metal supported on the surface of the catalyst (strictly speaking, the surface of the carbon carrier), it is supported inside (near the surface) to a depth of about 3 nm from the surface. The metal is also detected.
- the metal measurement by ICP-MS all the metals contained in the surface and the inside of the catalyst are detected.
- the small noble metal-XPS / ICP ratio is contained in the deep inside of the carbon carrier (for example, the inside at a depth of 3 nm or more from the outer surface) among the metals supported on the metal-supporting catalyst. It means that the proportion of metal is large. Therefore, if the noble metal-XPS / ICP ratio is too small, the proportion of metals that do not sufficiently contribute to catalytic activity increases. When the noble metal forms an alloy with the non-noble metal, it is considered that the noble metal and the non-noble metal function at the same position as the catalyst metal in the present catalyst. Therefore, the noble metal-XPS / ICP ratio of the present catalyst is determined. It can be said that it represents the position information of the catalyst metal.
- the large noble metal-XPS / ICP ratio is contained in the vicinity of the surface of the carbon carrier (on the surface and inside at a depth of 3 nm or less from the surface) among the catalyst metals supported on the metal-supported catalyst. It means that the proportion of the catalytic metal is large. Therefore, if the noble metal-XPS / ICP ratio is too large, poisoning and deterioration (for example, dissolution and aggregation) of the catalyst metal particles due to the external environment are likely to occur.
- the catalyst has a noble metal-XPS / ICP ratio within a specific range, as described above.
- the fact that the noble metal-XPS / ICP ratio of the present catalyst is within the above-mentioned specific range means that a specific appropriate proportion of the catalytic metal particles supported on the present catalyst is near the surface of the carbon carrier ( Contained on the surface and inside at a depth of less than 3 nm from the surface) and the remaining specific appropriate proportion of catalytic metal particles contained deep inside the carbon carrier (eg, inside at a depth of 3 nm or more from the outer surface). It means that it is. That is, the present catalyst having a noble metal-XPS / ICP ratio within the above specific range contains catalyst metal particles that sufficiently contribute to the catalytic activity and are not easily poisoned or deteriorated by the external environment.
- the average crystallite diameter of the catalyst metal particles to be formed may be, for example, 7.0 nm or less.
- the average crystallite diameter of the catalyst metal particles measured by XRD is, for example, preferably 6.5 nm or less, more preferably 6.0 nm or less, and particularly preferably 5.5 nm or less. Further, the average crystallite diameter of the catalyst metal particles may be, for example, 1.0 nm or more.
- the average crystallite diameter of the catalyst metal particles by XRD may be specified by arbitrarily combining any of the above-mentioned lower limit values and the above-mentioned upper limit values.
- the average crystallite diameter of the catalyst metal particles is determined by the method described in Examples described later.
- This catalyst has one or more diffraction peaks (for example, diffraction peaks of a carbon carrier) obtained by separating diffraction lines having a diffraction angle 2 ⁇ of about 40 ° in a powder X-ray diffraction pattern using CuK ⁇ rays with respect to the total amount of catalytic metal particles.
- the amount of the catalytic metal particles having an average crystallite diameter of 5.0 nm or less calculated by Scheller's equation using the diffraction angle and half-value full width of the diffraction peak of pure noble metal particles and the diffraction peak of one or more noble metal alloy particles.
- the ratio of the above may be 65% or more.
- the proportion of the catalyst metal particles having an average crystallite diameter of 5.0 nm or less measured by XRD is, for example, preferably 70% or more, more preferably 75% or more, and more preferably 80% or more. Especially preferable.
- the proportion (%) of the catalyst metal particles having a particle size of 5.0 nm or less obtained by observation of the present catalyst with a transmission electron microscope (TEM) may be, for example, 60% or more, and 65% or more. It is preferably 70% or more, more preferably 75% or more, and particularly preferably 80% or more.
- the proportion (%) of the catalytic metal particles having a particle size of 5.0 nm or less as observed by TEM is such that the length of the longest portion of the 100 catalytic metal particles randomly selected in the TEM image of the present catalyst is 5. It is calculated by multiplying the value obtained by dividing the number of catalyst particles having a diameter of 0 nm or less by 100, which is the total number of the catalyst particles, by 100.
- a large proportion of the catalyst metal particles having a particle size of 5.0 nm or less in the catalyst metal particles of this catalyst contributes to excellent catalytic activity. Since the catalyst metal particles having a particle size of 5.0 nm or less have a large roughness factor, the substance transport resistance is reduced. For example, when this catalyst is used as an oxygen reduction catalyst for a fuel cell, the oxygen transport resistance is reduced, so that the voltage loss is reduced and a larger maximum output can be obtained.
- the average particle size of the catalyst may be, for example, 1.00 ⁇ m or less, preferably 0.80 ⁇ m or less, more preferably 0.60 ⁇ m or less, and more preferably 0.40 ⁇ m or less. It is more preferably 0.30 ⁇ m or less, and particularly preferably 0.30 ⁇ m or less.
- the average particle size of the catalyst may be, for example, 0.01 ⁇ m or more. The average particle size of this catalyst is measured by laser diffraction.
- the average particle size of the present catalyst is equal to or less than the above-mentioned specific threshold contributes to the efficiency of the chemical reaction by the present catalyst, contributes to the excellent catalytic activity of the present catalyst, and prepares a battery electrode containing the present catalyst. It also contributes to efficiency improvement in.
- the ratio of the number of catalyst metal particles in the STEM secondary electron image of the metal-supported catalyst to the number of catalyst metal particles in the HAADF-STEM image of the metal-supported catalyst is, for example, , 12% or less, preferably 11% or less, and particularly preferably 10% or less.
- the secondary electron image / HAADF image ratio (%) is equal to or less than the above-mentioned specific threshold contributes to the catalytic activity of the present catalyst. That is, for example, when this catalyst is used as an oxygen reduction catalyst for a fuel cell electrode, the catalyst metal existing on the outermost surface of the carbon carrier is caused by the secondary electron image / HAADF image ratio (%) being equal to or less than the above specific threshold value. Since the proportion of the catalyst metal is reduced, the poisoning of the catalyst metal by the electrolyte or the like is suppressed.
- the BET specific surface area of the present catalyst may be, for example, 400 m 2 / g or more, preferably 500 m 2 / g or more, more preferably 600 m 2 / g or more, and 800 m 2 / g or more. Is particularly preferable.
- the BET specific surface area of the present catalyst may be, for example, 3000 (m 2 / g) or less, or 2500 (m 2 / g) or less.
- the BET specific surface area of the present catalyst may be specified by arbitrarily combining any of the above-mentioned lower limit values and any of the above-mentioned upper limit values.
- the standardized specific surface area calculated by multiplying the BET specific surface area of the catalyst by the ratio of the weight of the catalyst to the weight of the carbon carrier contained in the catalyst is, for example, 1100 (m 2 / g-carrier) or more. It may be.
- the standardized specific surface area of this catalyst is, for example, preferably 1150 (m 2 / g-carrier) or more, more preferably 1200 (m 2 / g-carrier) or more, and 1250 (m 2 / g-carrier) or more.
- -Carrier) or more is even more preferable, and 1300 (m 2 / g-carrier) or more is particularly preferable.
- the standardized specific surface area of the present catalyst may be, for example, 3000 (m 2 / g-carrier) or less, or 2500 (m 2 / g-carrier) or less.
- the normalized specific surface area of the present catalyst may be specified by arbitrarily combining any of the above-mentioned lower limit values and any of the above-mentioned upper limit values.
- a large specific surface area (BET specific surface area and / or standardized specific surface area, particularly standardized specific surface area) of this catalyst contributes to its catalytic activity.
- the specific surface area increases, the catalytic metal particles are more likely to be more uniformly supported in the pores inside the carbon carrier. Therefore, for example, when the present catalyst having a large specific surface area is used as an electrode catalyst of a fuel cell, aggregation of catalyst metal particles and coating of catalyst metal particles by an electrolyte are effectively suppressed.
- the catalyst metal particles are efficiently used by suppressing the coating with the electrolyte.
- the ratio (XPS-N / C ratio) of the nitrogen atom concentration (atomic%) to the carbon atom concentration (atomic%) measured by XPS may be, for example, 0.010 or more.
- the N / C ratio measured by XPS is, for example, preferably 0.011 or more, and particularly preferably 0.012 or more.
- the N / C ratio measured by XPS of this catalyst may be, for example, 0.15 or less.
- the ratio (XPS-N / C weight ratio) of the nitrogen atom content (% by weight) to the carbon atom content (% by weight) can be obtained from the atomic weight ratio of the carbon atom and the nitrogen atom.
- the ratio (CHN—N / C ratio) of the nitrogen atom content (% by weight) to the carbon atom content (% by weight) measured by elemental analysis (CHN) using the combustion method is 0. It may be .010 or more, preferably 0.015 or more, and particularly preferably 0.020 or more.
- the CHN—N / C ratio of this catalyst may be, for example, 0.20 or less.
- N / C ratio of the present catalyst is equal to or higher than the above-mentioned specific threshold means that the surface of the carbon structure of the present catalyst (more specifically, the carbon structure of the carbon carrier) has a nitrogen-containing functional group or the inside of the carbon network.
- Non-catalytic metal active points catalytic metal active points supported on a carbon carrier
- specific type nitrogen atoms such as pyridine type nitrogen, pyrrole type nitrogen, graphite type nitrogen, and carbon curved structure formed by these. It reflects that the carbon carrier itself contains a large amount of active points other than the above, which contributes to the excellent catalytic activity of the present catalyst.
- the ratio of the CHN-N / C ratio (N-CHN / XPS ratio) to the XPS-N / C weight ratio of the present catalyst may be, for example, 0.90 or more.
- the N-CHN / XPS ratio is, for example, preferably 1.00 or more, more preferably 1.10 or more, and particularly preferably 1.20 or more.
- the N-CHN / XPS ratio may be, for example, 3.00 or less.
- the high N-CHN / XPS ratio of this catalyst contributes to the durability of this catalyst.
- the nitrogen atom content by XPS indicates the nitrogen atom content present on the surface of the carbon carrier and within a depth of several nm from the surface.
- the nitrogen atom content by elemental analysis using the combustion method indicates the nitrogen atom content present on the entire surface and inside of the carbon carrier.
- the high N-CHN / XPS ratio of this catalyst indicates that more nitrogen atoms are present inside than on the surface of the carbon carrier. Since the nitrogen atom binds to the metal, if the nitrogen atom is present inside, the catalyst metal particles are supported inside and the elution of the catalyst metal is suppressed, so that the durability of the present catalyst is improved.
- This catalyst exhibits in the Raman spectrum obtained by Raman spectroscopy, 1360 cm around -1 (e.g., 1250 cm -1 or more, 1450 cm -1 in the range) to the following D FWHM of band 160cm -1 having a peak top in It may include a carbon structure.
- the N / C ratio measured by XPS of this catalyst is equal to or higher than the above-mentioned lower limit value, and / or the N / C ratio measured by elemental analysis using the combustion method of this catalyst is It is preferably at least the above-mentioned lower limit value.
- the half width of the D band of the present catalyst is, for example, preferably 155 cm -1 or less, and particularly preferably 150 cm -1 or less.
- the half width of the D band of the present catalyst may be, for example, 80 cm -1 or more.
- the half width of the D band indicates the crystallinity of the curved structure contained in the carbon structure. That is, a small half-value width of the D band means that the crystallinity of the curved structure is high. Therefore, the fact that the D-band half-value width of the carbon structure of the present catalyst (specifically, the carbon structure of the carbon carrier) is equal to or less than the above-mentioned specific threshold value means that the carbon structure includes a highly crystalline curved structure. means.
- the fact that the present catalyst has a carbon structure including a highly crystalline curved structure contributes to excellent durability and oxidation resistance of the present catalyst.
- the present catalyst may contain a carbon structure showing a half width of 90 cm -1 or less in the G band having a peak top near 1600 cm -1 in the Raman spectrum obtained by Raman spectroscopy.
- the N / C ratio measured by XPS of this catalyst is equal to or higher than the above-mentioned lower limit value, and / or the N / C ratio measured by elemental analysis using the combustion method of this catalyst is It is preferably at least the above-mentioned lower limit value.
- the half width of the G band of this catalyst is, for example, preferably 85 cm -1 or less, and particularly preferably 80 cm -1 or less.
- the half width of the G band of the present catalyst may be, for example, 40 cm -1 or more.
- the half width of the G band indicates the crystallinity of the graphite structure contained in the carbon structure. That is, a small half-value width of the G band means that the graphite structure has high crystallinity. Therefore, the fact that the G band half width of the carbon structure of the present catalyst (specifically, the carbon structure of the carbon carrier) is equal to or less than the above-mentioned specific threshold value means that the carbon structure contains a highly crystalline graphite structure. means.
- the fact that the present catalyst has a carbon structure including a graphite structure with high crystallinity contributes to excellent durability and oxidation resistance of the present catalyst.
- this catalyst has the minimum intensity between the G band and the D band having a peak top near 1360 cm -1 with respect to the intensity of the G band having a peak top near 1600 cm -1. It may contain a carbon structure showing a ratio (Iv / Ig ratio) of 0.20 or more and 0.50 or less.
- the N / C ratio measured by XPS of this catalyst is equal to or higher than the above-mentioned lower limit value, and / or the N / C ratio measured by elemental analysis using the combustion method of this catalyst is It is preferably at least the above-mentioned lower limit value.
- the Iv / Ig ratio of the present catalyst is, for example, preferably 0.20 or more and 0.45 or less, more preferably 0.25 or more and 0.45 or less, and 0.25 or more and 0.40. The following is particularly preferable.
- the G band is a component derived from an ideal graphite structure
- the D band is a component derived from a curved structure including defects and edges.
- the minimum intensity I v between G band and D band is dependent on the components derived from amorphous. Therefore, the I v / Ig ratio is the ratio of the amount of amorphous to the amount of ideal graphite structure.
- the carbon carrier for example, the carbon carrier that is a carbon catalyst
- the fact that the I v / Ig ratio of the carbon structure of the present catalyst is within the above-mentioned specific range is that the carbon carrier in the present catalyst is excellent other than the catalyst metal. It means having a catalytically active point (non-catalytic metal active point).
- This catalyst has a carbon structure exhibiting a nitrogen desorption amount of 0.85 ⁇ 10-5 (mol / g) or more from 600 ° C. to 1000 ° C. per unit weight of this catalyst in the thermal desorption method (TPD). It may be included. Further, for example, in TPD, the present catalyst includes a carbon structure exhibiting a nitrogen desorption amount of 1.00 ⁇ 10 -1 (mol / g) or less from 600 ° C. to 1000 ° C. per unit weight of the present catalyst. May be good.
- the N / C ratio measured by XPS of this catalyst is equal to or higher than the above-mentioned lower limit value, and / or the N / C ratio measured by elemental analysis using the combustion method of this catalyst is It is preferably at least the above-mentioned lower limit value.
- the amount of nitrogen desorbed from 600 ° C. to 1000 ° C. per unit weight of the present catalyst is preferably, for example, 3.00 ⁇ 10-5 (mol / g) or more. It is more preferably 00 ⁇ 10 -4 (mol / g) or more, and particularly preferably 5.00 ⁇ 10 -4 (mol / g) or more.
- the present catalyst may contain a carbon structure having a nitrogen desorption amount of 0.61 ⁇ 10-5 (mol / g) or more from 800 ° C. to 1000 ° C. per unit weight of the present catalyst in TPD. Further, for example, in TPD, the present catalyst includes a carbon structure exhibiting a nitrogen desorption amount of 1.00 ⁇ 10 -1 (mol / g) or less from 800 ° C. to 1000 ° C. per unit weight of the present catalyst. May be good.
- the N / C ratio measured by XPS of this catalyst is equal to or higher than the above-mentioned lower limit value, and / or the N / C ratio measured by elemental analysis using the combustion method of this catalyst is It is preferably at least the above-mentioned lower limit value.
- the amount of nitrogen desorbed from 800 ° C. to 1000 ° C. per unit weight of the present catalyst is preferably 2.50 ⁇ 10-5 (mol / g) or more, for example. It is more preferably 00 ⁇ 10 -5 (mol / g) or more, and particularly preferably 1.00 ⁇ 10 -4 (mol / g) or more.
- the present catalyst may contain a carbon structure exhibiting a nitrogen desorption amount of 1.20 ⁇ 10-5 (mol / g-carrier) or more from 600 ° C. to 1000 ° C. per unit weight of the carbon carrier in TPD. .. Further, the present catalyst contains, for example, a carbon structure showing a nitrogen desorption amount of 1.00 ⁇ 10 -1 (mol / g-carrier) or less from 600 ° C. to 1000 ° C. per unit weight of the carbon carrier in TPD. It may be that.
- the N / C ratio measured by XPS of this catalyst is equal to or higher than the above-mentioned lower limit value, and / or the N / C ratio measured by elemental analysis using the combustion method of this catalyst is It is preferably at least the above-mentioned lower limit value.
- the amount of nitrogen desorption from 600 ° C. to 1000 ° C. per unit weight of the carbon carrier is preferably, for example, 5.00 ⁇ 10 -5 (mol / g-carrier) or more. It is more preferably 1.00 ⁇ 10 -4 (mol / g-carrier) or more, further preferably 5.00 ⁇ 10 -4 (mol / g-carrier) or more, and 1.00 ⁇ 10 It is particularly preferably -3 (mol / g-carrier) or more.
- the present catalyst may contain a carbon structure exhibiting a nitrogen desorption amount of 0.75 ⁇ 10-5 (mol / g-carrier) or more from 800 ° C. to 1000 ° C. per unit weight of the carbon carrier in TPD. .. Further, the present catalyst contains, for example, a carbon structure showing a nitrogen desorption amount of 1.00 ⁇ 10 -1 (mol / g-carrier) or less from 800 ° C. to 1000 ° C. per unit weight of the carbon carrier in TPD. It may be that.
- the N / C ratio measured by XPS of this catalyst is equal to or higher than the above-mentioned lower limit value, and / or the N / C ratio measured by elemental analysis using the combustion method of this catalyst is It is preferably at least the above-mentioned lower limit value.
- the amount of nitrogen desorbed from 800 ° C. to 1000 ° C. per unit weight of the carbon carrier is preferably 3.00 ⁇ 10-5 (mol / g-carrier) or more, for example. It is more preferably 5.00 ⁇ 10 -5 (mol / g-carrier) or more, and particularly preferably 1.00 ⁇ 10 -4 (mol / g-carrier) or more.
- the amount of nitrogen desorbed in TPD which is defined as one of the characteristics of this catalyst, reflects the quality and quantity of nitrogen atoms contained in the carbon structure of this catalyst (specifically, the carbon structure of the carbon carrier). There is. That is, the catalyst has a carbon structure containing a specific quality and amount of nitrogen atoms such that the amount of nitrogen desorption in the relatively high specific temperature range is equal to or less than the specific threshold value in the TPD. , Shows excellent durability.
- the N / C ratio of the present catalyst (specifically, the XPS-N / C ratio of the carbon carrier or the CHN-N / C ratio) is equal to or higher than the above-mentioned specific lower limit, according to the Raman spectroscopy of the present catalyst.
- the half-price width of the D band is below the above-mentioned specific upper limit value
- the half-price width of the G band is below the above-mentioned specific upper limit value
- the Iv / Ig ratio is within the above-mentioned specific range.
- the amount of nitrogen desorption from 600 ° C. to 1000 ° C.
- the carbon carrier of this catalyst has an active point (non-catalytic metal active point) other than the catalyst metal and has excellent oxidation resistance.
- the carbon carrier for example, the carbon carrier which is a carbon catalyst
- the carbon carrier has a non-catalytic metal active point, for example, when this catalyst is used as an oxygen reduction catalyst for a fuel cell electrode, it is placed on the catalyst metal during high load operation. The concentration of oxygen is relaxed and the voltage drop in the high current density range is suppressed. Further, since the carbon carrier has excellent oxidation resistance, oxidative corrosion of the carbon carrier when a high potential is applied due to load fluctuation during operation, start / stop, etc. is suppressed, so that a catalyst metal (for example, Pt) is suppressed. ) Desorption and aggregation are alleviated, and excellent durability can be obtained.
- the amount of hydrogen adsorption electricity measured by cyclic voltammetry using a rotating disk electrode containing this catalyst is the theoretical area-equivalent amount of electricity for hydrogen adsorption to platinum and the present amount.
- catalyst obtained from the resultant hydrogen adsorbed amount of electricity by cyclic voltammetry effective platinum catalyst surface area: H 2 -ECSA
- electrochemical surface area obtained by dividing the weight of platinum supported is 20.0 m 2 /
- the amount of carbon monoxide adsorption measured by stripping voltammetry using a rotating disk electrode that is greater than or equal to g-platinum and contains this catalyst is the theoretical area-equivalent amount of electricity for carbon monoxide adsorption to platinum.
- the electrochemical surface area (effective platinum catalyst surface area obtained from the amount of carbon monoxide adsorption electricity obtained by stripping voltammetry: CO-ECSA) obtained by dividing by the weight of platinum supported on the catalyst is 20.0 m 2. It may be / g-platinum or more.
- the catalyst for example, shows a 25.0 m 2 / g- platinum more H 2 -ECSA, and preferably to exhibit 30.0 m 2 / g- platinum more CO-ECSA, 30.0m 2 / g It is more preferable to show H 2 -ECSA of -platinum or higher and CO-ECSA of 40.0 m 2 / g-platinum or higher, and to show H 2 -ECSA of 35.0 m 2 / g-platinum or higher. Moreover, it is particularly preferable to exhibit CO-ECSA of 50.0 m 2 / g-platinum or more.
- the catalyst for example, 200 meters 2 / g- platinum exhibited the following H 2 -ECSA, and, it is also possible to show the following CO-ECSA 200m 2 / g- platinum.
- H 2 -ECSA and CO-ECSA of the catalyst, and any lower value respectively above, may be identified in any combination of the upper limit of the above.
- H 2 -ECSA and CO-ECSA of the catalyst is large, contribute to excellent catalytic activity.
- the H 2 -ECSA and CO-ECSA catalyst metal particles is small, the oxygen concentration resistance occurs, leading to reduced output as the result.
- the larger the H 2 -ECSA and CO-ECSA of the catalyst by oxygen concentration resistance decreases, the less the loss of the voltage, the larger the maximum output can be obtained.
- the platinum equivalent amount of the non-catalytic metal active site in the carbon carrier of this catalyst may be, for example, 1.0 (mg-Pt / g-carrier) or more, and 3.0 (mg-Pt / g-carrier). The above is preferable, and 5.0 (mg-Pt / g-carrier) or more is particularly preferable.
- the large number of non-catalytic metal active sites of this catalyst contributes to excellent catalytic activity. For example, when the active point of the present catalyst used as the oxygen reduction catalyst of the fuel cell electrode is only the catalyst metal particles, oxygen is excessively concentrated on the catalyst metal particles and the catalytic activity of the present catalyst is lowered. Since the present catalyst has a non-catalytic metal active point (specifically, the carbon carrier itself has an active point), excessive concentration of oxygen on the catalytic metal particles can be suppressed, and the catalytic activity of the present catalyst is improved. ..
- This catalyst is manufactured by supporting catalyst metal particles on a carbon carrier.
- the method for producing the present catalyst is to impregnate the carbon carrier with a catalyst metal, and to heat the carbon carrier impregnated with the catalyst metal using electromagnetic waves to obtain the catalyst metal supported on the carbon carrier. Includes forming particles.
- the electromagnetic wave used for heating the carbon carrier is not particularly limited as long as it generates heat of the carbon carrier itself and / or the catalyst metal itself impregnated in the carbon carrier, and is, for example, millimeter wave (Extra High Frequency). Is preferably used. Millimeter waves are electromagnetic waves having wavelengths of 1 mm or more and 15 mm or less.
- the carbon carrier When forming noble metal alloy particles supported on a carbon carrier, the carbon carrier is impregnated with a noble metal (for example, Pt) and a non-noble metal (for example, a transition metal) that forms an alloy with the noble metal.
- a noble metal for example, Pt
- a non-noble metal for example, a transition metal
- the carbon carrier is first impregnated with a non-precious metal, and then the carbon carrier impregnated with the non-precious metal is impregnated with the noble metal.
- the carbon carrier is impregnated with the catalyst metal, for example, by immersing the carbon carrier in a solution containing the catalyst metal. That is, when forming the noble metal alloy particles supported on the carbon carrier, the carbon carrier is immersed in a solution containing the noble metal and a solution containing a non-noble metal, respectively. In this case, it is preferable that the carbon carrier is first impregnated with the solution containing the noble metal, and then the carbon carrier impregnated with the non-precious metal is impregnated with the solution containing the noble metal.
- the carbon carrier is first impregnated with a solution containing a non-precious metal, then the carbon carrier impregnated with the non-precious metal is dried, and the carbon carrier impregnated with the non-precious metal and dried is further subjected to the noble metal. Is impregnated with a solution containing, and then the non-precious metal and the carbon carrier impregnated with the noble metal are dried.
- the carbon carrier itself and / or the catalyst metal itself is obtained by irradiating the carbon carrier with the electromagnetic wave.
- the method is not particularly limited as long as it is a method of generating heat.
- the rate of temperature rise in heating of the carbon carrier using electromagnetic waves may be, for example, 10 ° C./min or more, preferably 50 ° C./min or more, and 100 ° C./min or more. It is more preferable that the temperature is 200 ° C./min or higher.
- the rate of temperature rise in heating the carbon carrier using millimeter waves may be, for example, 1000 ° C./min or less.
- the carbon carrier may be heated to a temperature of 200 ° C. or higher, preferably to a temperature of 300 ° C. or higher, and a temperature of 500 ° C. or higher. It is more preferable to heat it to a temperature of 700 ° C. or higher.
- the carbon carrier In heating a carbon carrier using electromagnetic waves (for example, millimeter waves), the carbon carrier may be heated to a temperature of 1500 ° C. or lower, preferably to a temperature of 1200 ° C. or lower, and a temperature of 1000 ° C. or lower. It is particularly preferable to heat to.
- the temperature at which the carbon carrier is heated by using electromagnetic waves may be specified by arbitrarily combining any of the above-mentioned lower limit values and any of the above-mentioned upper limit values.
- the carbon carrier In heating a carbon carrier using electromagnetic waves (for example, millimeter waves), the carbon carrier may be held at the above-mentioned heating temperature for 1 second or longer, preferably for 10 minutes or longer.
- the time for holding the carbon carrier at the above-mentioned heating temperature may be, for example, 24 hours or less.
- Heating of the carbon carrier using electromagnetic waves is preferably performed in a reducing atmosphere, and preferably in a hydrogen atmosphere.
- the carbon carrier is produced, for example, by carbonizing a raw material containing an organic substance.
- a carbon carrier as a carbon catalyst is produced by a method including carbonizing a raw material containing an organic substance under pressure will be described.
- the organic matter contained in the raw material is not particularly limited as long as it can be carbonized. That is, as the organic substance, for example, a high molecular weight organic compound (for example, a resin such as a thermosetting resin and / or a thermoplastic resin) and / or a low molecular weight organic compound is used. Moreover, biomass may be used as an organic substance.
- a high molecular weight organic compound for example, a resin such as a thermosetting resin and / or a thermoplastic resin
- biomass may be used as an organic substance.
- a nitrogen-containing organic substance is preferably used as the organic substance.
- the nitrogen-containing organic substance is not particularly limited as long as it is an organic substance containing an organic compound containing a nitrogen atom in its molecule.
- the carbon catalyst is a carbonized material of a raw material containing a nitrogen-containing organic substance, the carbon structure of the carbon catalyst contains a nitrogen atom.
- examples of the organic substance include polyacrylonitrile, polyacrylonitrile-polyacrylic acid copolymer, polyacrylonitrile-methyl polyacrylic acid copolymer, polyacrylonitrile-polymethacrylic acid copolymer, and polyacrylonitrile-polymethacrylic acid.
- -Polymetallicyl sulfonic acid copolymer polyacrylonitrile-polymethylmethacrylate copolymer, phenol resin, polyfurfuryl alcohol, furan, furan resin, phenol formaldehyde resin, melamine, melamine resin, epoxy resin, nitrogen-containing chelate resin (for example, one or more selected from the group consisting of polyamine type, iminodiacetic acid type, aminophosphate type and aminomethylphosphonic acid type), polyamideimide resin, pyrrole, polypyrrole, polyvinylpyrrole, 3-methylpolypyrrole, acrylic nitrile, polyvinylidene chloride.
- the content of the organic substance in the raw material is not particularly limited as long as a carbon catalyst can be obtained, but may be, for example, 5% by mass or more and 90% by mass or less, preferably 10% by mass or more and 80% by mass. % Or less.
- the raw material for carbonization may further contain a metal. That is, in this case, the raw material containing an organic substance and a metal is carbonized under pressure.
- the carbon catalyst is a carbonized material obtained by carbonizing a raw material containing an organic substance and a metal, the carbon catalyst contains the metal.
- the metal contained in the raw material (that is, the metal contained in the carbon catalyst) is preferably a transition metal.
- the raw material may contain one kind of transition metal or may contain two or more kinds of transition metals.
- the transition metal is preferably a metal belonging to groups 3 to 12 of the periodic table, and preferably a transition metal belonging to the 4th period of groups 3 to 12 of the periodic table.
- the transition metals contained in the raw materials include, for example, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Y, Zr, Nb, Mo, Ru, Rh, Pd, Ag, A group consisting of lanthanoids (eg Gd) and actinoids, or Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Y, Zr, Nb, Mo, Ag, lanthanides (eg Gd) and It may be one or more or two or more selected from the group consisting of actinoids.
- the transition metal is preferably one or more selected from the group consisting of Fe, Co, Ni, Cu, and Zn, or preferably two or more kinds, and is selected from the group consisting of Fe, Co, Ni, and Zn. It is particularly preferable that there are one or more types, or two or more types.
- the raw material may not contain Pt.
- the raw material may not contain one or more selected from the group consisting of Pt, Ru, Rh, Pd, Ir, Au and Os.
- metal contained in the raw material a simple substance of the metal and / or a compound of the metal is used.
- the metal compound for example, one or more selected from the group consisting of metal salts, metal oxides, metal hydroxides, metal nitrides, metal sulfides, metal carbides and metal complexes may be used.
- the metal content in the raw material (when two or more kinds of metals are used, the total content of the two or more kinds of metals) is not particularly limited as long as the present catalyst can be obtained, but for example, It may be 1% by mass or more and 90% by mass or less, and preferably 2% by mass or more and 80% by mass or less.
- Carbonization is performed by heating the raw material under pressure and holding it at a temperature at which the raw material is carbonized (hereinafter referred to as "carbonization temperature").
- the carbonization temperature is not particularly limited as long as the raw material is carbonized, and is, for example, 300 ° C. or higher. That is, in this case, the raw material containing an organic substance is carbonized at a temperature of 300 ° C. or higher under pressure.
- the carbonization temperature may be, for example, 700 ° C. or higher, preferably 900 ° C. or higher, more preferably 1000 ° C. or higher, and particularly preferably 1100 ° C. or higher.
- the upper limit of the carbonization temperature is not particularly limited, but the carbonization temperature is, for example, 3000 ° C. or lower.
- the rate of temperature rise to the carbonization temperature is, for example, 0.5 ° C./min or more and 300 ° C./min or less.
- the time for holding the raw material at the carbonization temperature may be, for example, 1 second or more and 24 hours or less, and 5 minutes or more. It may be 24 hours or less.
- Carbonization is preferably carried out in an inert gas atmosphere such as a nitrogen atmosphere. That is, carbonization is preferably carried out under the flow of an inert gas such as nitrogen gas.
- the pressure of the atmosphere for carbonization is not particularly limited as long as it is higher than the atmospheric pressure, but for example, the gauge pressure is 0.05 MPa or more. Further, the pressure of the atmosphere for carbonization may be 0.15 MPa or more, preferably 0.20 MPa or more, more preferably 0.40 MPa or more, and 0.50 MPa or more in gauge pressure. The above is particularly preferable. That is, in these cases, in the production of the carbon catalyst, the raw material containing an organic substance is carbonized under a pressure whose gauge pressure is equal to or higher than the above threshold value (MPa).
- the method for producing a carbon catalyst may include further processing the carbonized material obtained by carbonizing the raw material containing an organic substance. That is, for example, the carbonized material may be treated with ammonia. In this case, for example, the raw material containing an organic substance is carbonized under pressure, and the carbonized material obtained by the carbonization is subjected to an ammonia treatment.
- Ammonia treatment is not particularly limited as long as it is a treatment in which the carbonized material is brought into contact with ammonia. That is, the ammonia treatment is, for example, a treatment of heating the carbonized material in an ammonia-containing gas atmosphere.
- the ammonia content of the ammonia-containing gas is not particularly limited as long as the effect of the ammonia treatment can be obtained, but may be, for example, 0.1% by volume or more, and 1.0% by volume or more. It may be 3.0% by volume or more.
- the temperature at which the carbonized material is heated during the ammonia treatment is not particularly limited as long as the effect of the ammonia treatment can be obtained, but for example, it may be 300 ° C. or higher, and may be 500 ° C. or higher. It is preferably 700 ° C. or higher, and particularly preferably 700 ° C. or higher.
- the upper limit of the heating temperature is not particularly limited, but the heating temperature may be, for example, 1300 ° C. or lower, preferably 1000 ° C. or lower.
- the range of the heating temperature during the ammonia treatment is defined by arbitrarily combining each of the above-mentioned lower limit values and each of the above-mentioned upper limit values.
- the carbonized material may be subjected to a metal removal treatment.
- the raw material containing an organic substance is carbonized under pressure, and then the carbonized material obtained by the carbonization is subjected to a metal removal treatment.
- a raw material containing an organic substance is carbonized under pressure, then the carbonized material obtained by the carbonization is subjected to a metal removal treatment, and then the carbonized material after the metal removal treatment is subjected to an ammonia treatment.
- the metal removal treatment is a treatment for reducing the amount of raw material-derived metal contained in the carbonized material.
- the metal removal treatment is, for example, an acid cleaning treatment and / or an electrolytic treatment.
- the present electrode contains the above-mentioned catalyst. That is, the present electrode is, for example, a battery electrode on which the present catalyst is supported. Specifically, the present electrode is, for example, a battery electrode including an electrode base material and the present catalyst supported on the electrode base material.
- This electrode is, for example, an electrode of a fuel cell (for example, a polymer electrolyte fuel cell), an air cell, a water electrolytic cell (for example, a solid polymer water electrolytic cell), a redox flow battery, or a halogen battery. Further, the present electrode is, for example, a cathode or an anode, preferably a cathode.
- the present electrode is a cathode or an anode of a fuel cell, an air cell, a water electrolytic cell, a redox flow battery, or a halogen battery, preferably a fuel cell cathode, an air cell cathode, a water electrolytic cell cathode, a redox flow battery cathode, and the like.
- a halogen battery cathode preferably a fuel cell cathode, an air cell cathode, a water electrolytic cell cathode, a redox flow battery cathode, and the like.
- it is a halogen battery cathode.
- the present battery includes the battery electrodes described above. That is, the present battery is, for example, a fuel cell including the present electrode (for example, a solid polymer fuel cell), an air battery, a redox flow battery, or a halogen battery.
- the battery may have a membrane / electrode assembly (MEA) containing the electrodes.
- MEA membrane / electrode assembly
- the present battery is a battery having the main electrode as a cathode or an anode, and preferably a battery having the main electrode as a cathode.
- the present battery is a fuel cell, an air battery, a redox flow battery, or a halogen battery having the main electrode as a cathode or an anode, and preferably a fuel cell, an air battery, a redox flow battery, or a halogen having the main electrode as a cathode. It is a battery.
- Carbon carrier A 1.0 g of polyacrylonitrile (PAN), 1.0 g of 2-methylimidazole, 6.0 g of zinc chloride (ZnCl 2 ), and 0.18 g of iron (III) chloride hexahydrate (FeCl 3. and 6H 2 O), it was mixed with dimethylformamide 30g. The solvent was removed from the resulting mixture by drying. The dried mixture was heated in air to insolubilize at 250 ° C.
- the infusible mixture was carbonized by heating and holding it at 1300 ° C. in a nitrogen atmosphere under a gauge pressure of 0.90 MPa.
- Dilute hydrochloric acid was added to the carbonized material obtained by carbonization, and the mixture was stirred. Then, the suspension containing the carbonized material was filtered using a filtration membrane, and the carbonized material was washed with distilled water until the filtrate became neutral. In this way, the metal removal treatment by acid cleaning was performed.
- the carbonized material after the metal removal treatment was pulverized by a fine pulverizer until the median particle size was 300 nm or less.
- Nitric acid was added to the pulverized carbonized material, and the mixture was stirred. Then, the suspension containing the carbonized material was filtered using a filtration membrane, and the carbonized material was washed with distilled water until the filtrate became neutral. In this way, the oxidation treatment with nitric acid was performed.
- the carbonized material after the oxidation treatment was heated at a heating rate of 50 ° C./min in an atmosphere in which 100% ammonia gas was circulated at 0.15 L / min, and kept at 900 ° C. for 1 hour. Then, the ammonia gas was replaced with nitrogen, and the carbonized material was held at 500 ° C. for 10 minutes in a nitrogen atmosphere. In this way, ammonia treatment with ammonia gas was performed. Then, a carbonized material cooled by natural cooling in a nitrogen atmosphere was obtained as a carbon carrier A. [Carbon carrier B]
- a carbon carrier B was obtained in the same manner as the above-mentioned carbon carrier A except that 12.0 g of zinc chloride (ZnCl 2 ) was used instead of 6.0 g.
- ZnCl 2 zinc chloride
- a carbon carrier C was obtained in the same manner as the above-mentioned carbon carrier A except that the oxidation treatment with nitric acid and the ammonia treatment were not performed.
- the infusible mixture was carbonized by heating and holding it at 1200 ° C. under normal pressure in a nitrogen atmosphere. Dilute hydrochloric acid was added to the carbonized material obtained by carbonization, and the mixture was stirred. Then, the suspension containing the carbonized material was filtered using a filtration membrane, and the carbonized material was washed with distilled water until the filtrate became neutral. In this way, the metal removal treatment by acid cleaning was performed.
- the carbonized material after the metal removal treatment was pulverized by a fine pulverizer until the median particle size was 600 nm or less.
- Nitric acid was added to the pulverized carbonized material, and the mixture was stirred. Then, the suspension containing the carbonized material was filtered using a filtration membrane, and the carbonized material was washed with distilled water until the filtrate became neutral. In this way, the oxidation treatment with nitric acid was performed.
- the carbonized material after the oxidation treatment was heated at a heating rate of 50 ° C./min in an atmosphere in which 100% ammonia gas was circulated at 0.15 L / min, and kept at 900 ° C. for 1 hour. Then, the ammonia gas was replaced with nitrogen, and the carbonized material was held at 500 ° C. for 10 minutes in a nitrogen atmosphere. In this way, ammonia treatment with ammonia gas was performed. Then, a carbonized material cooled by natural cooling in a nitrogen atmosphere was obtained as a carbon carrier D. [Carbon carrier E]
- Carbon carrier F was obtained in the same manner as the carrier A.
- Carbon carrier M Iron (III) chloride hexahydrate (FeCl 3 ⁇ 6H 2 O) 0.16g of cobalt chloride instead of (II) hexahydrate (NiCo ⁇ 6H 2 O) of the above carbon support except for using Carbon carrier G was obtained in the same manner as in A. [Carbon carrier M]
- Nitric acid was added to commercially available mesoporous carbon and stirred. Then, the suspension containing mesoporous carbon was filtered using a filtration membrane, and the mesoporous carbon was washed with distilled water until the filtrate became neutral. In this way, the oxidation treatment with nitric acid was performed.
- the mesoporous carbon after the oxidation treatment was heated at a heating rate of 50 ° C./min in an atmosphere in which 100% ammonia gas was circulated at 0.15 L / min, and maintained at 900 ° C. for 1 hour. Then, the ammonia gas was replaced with nitrogen, and the mesoporous carbon was maintained at 500 ° C. for 10 minutes in a nitrogen atmosphere. In this way, ammonia treatment with ammonia gas was performed. Then, mesoporous carbon cooled by natural cooling in a nitrogen atmosphere was obtained as a carbon carrier M. [Carbon carrier KB]
- a carbon carrier KB was obtained in the same manner as the carbon carrier M described above except that Ketjen Black EC600JD (manufactured by Lion Specialty Chemicals Co., Ltd.) was used instead of the mesoporous carbon.
- Ketjen Black EC600JD manufactured by Lion Specialty Chemicals Co., Ltd.
- a carbon carrier V was obtained in the same manner as the carbon carrier M described above except that Vulcan XC72R (manufactured by Cabot Corporation) was used instead of the mesoporous carbon.
- Vulcan XC72R manufactured by Cabot Corporation
- a carbon carrier DB was obtained by the same method as the above-mentioned carbon carrier M except that Denka Black HS-100 (manufactured by Denka Co., Ltd.) was used instead of mesoporous carbon. [Example 1]
- the concentration of iron was prepared aqueous solution of iron chloride by iron chloride so that 0.1 wt% (III) hexahydrate (FeCl 3 ⁇ 6H 2 O) dissolved in water.
- Carbon carrier A was added to this iron chloride aqueous solution, and the mixture was stirred for 16 hours to obtain a suspension.
- the obtained suspension was filtered and then dried at 100 ° C. for 16 hours to obtain a powder of carbon carrier A impregnated with iron.
- An aqueous solution of chloroplatinic acid was prepared by dissolving chloroplatinic acid (H 2 PtCl 6 ) in water so that the concentration of platinum was 1.6 wt%.
- a powder of carbon carrier A impregnated with iron was added to this aqueous solution of chloroplatinic acid, and the mixture was stirred for 16 hours to obtain a suspension.
- the amount of the chloroplatinic acid aqueous solution was adjusted so that the final amount of platinum supported was 20 wt%.
- the obtained suspension was filtered and then dried at 100 ° C. for 16 hours to obtain a powder of carbon carrier A impregnated with platinum and iron.
- the powder of carbon carrier A impregnated with platinum and iron thus obtained is subjected to millimeter waves (irradiation source: gyrotron oscillation tube, frequency: 28 GHz, output) under a hydrogen atmosphere in which hydrogen gas is circulated at a flow rate of 100 mL / min.
- a metal-supported catalyst was obtained by heating from room temperature to 900 ° C. at a heating rate of 450 ° C./min and holding for 1 hour using 1 kW).
- the platinum-supported amount of the metal-supporting catalyst (ratio of the weight of platinum supported on the metal-supporting catalyst to the weight of the metal-supporting catalyst) obtained by ICP-MS measurement was 20 wt%.
- the molar ratio (Pt / Fe ratio) of platinum to iron contained in the metal-supporting catalyst obtained by ICP-MS measurement was 5.0.
- the ratio of the supported amount of pure Pt to the total of the supported amount of pure Pt and the supported amount of Pt alloy in the metal-supporting catalyst obtained by XRD was 10% or more.
- Example 3 The same method as in Example 1 above except that the carbon carrier B was used instead of the carbon carrier A and the amount of the chloroplatinic acid aqueous solution was adjusted so that the final amount of platinum supported was 30 wt%.
- a metal-supported catalyst was obtained.
- the platinum-supported amount of the metal-supporting catalyst obtained by ICP-MS measurement was 20 wt%.
- the molar ratio (Pt / Fe ratio) of platinum to nickel contained in the metal-supporting catalyst obtained by ICP-MS measurement was 7.0. Further, the ratio of the supported amount of pure Pt to the total of the supported amount of pure Pt and the supported amount of Pt alloy in the metal-supporting catalyst obtained by XRD was 10% or more.
- a metal-supported catalyst was obtained by the same method as in Example 1 described above except that the carbon carrier C was used instead of the carbon carrier A.
- the platinum-supported amount of the metal-supporting catalyst obtained by ICP-MS measurement was 20 wt%.
- the molar ratio (Pt / Fe ratio) of platinum to iron contained in the metal-supporting catalyst obtained by ICP-MS measurement was 5.0.
- the ratio of the supported amount of pure Pt to the total of the supported amount of pure Pt and the supported amount of Pt alloy in the metal-supporting catalyst obtained by XRD was 10% or more.
- Cobalt concentration was prepared aqueous solution of cobalt chloride by cobalt (II) chloride hexahydrate such that 0.1 wt% of (CoCl 2 ⁇ 6H 2 O) dissolved in water.
- Carbon carrier A was added to this aqueous cobalt chloride solution, and the mixture was stirred for 16 hours to obtain a suspension.
- the obtained suspension was filtered and then dried at 100 ° C. for 16 hours to obtain a powder of carbon carrier A impregnated with cobalt.
- An aqueous solution of chloroplatinic acid was prepared by dissolving chloroplatinic acid (H 2 PtCl 6 ) in water so that the concentration of platinum was 1.6 wt%.
- a powder of carbon carrier A impregnated with cobalt was added to this aqueous solution of chloroplatinic acid, and the mixture was stirred for 16 hours to obtain a suspension.
- the amount of the chloroplatinic acid aqueous solution was adjusted so that the final amount of platinum supported was 30 wt%.
- the obtained suspension was filtered and then dried at 100 ° C. for 16 hours to obtain a powder of carbon carrier A impregnated with platinum and cobalt.
- the powder of carbon carrier A impregnated with platinum and cobalt thus obtained is subjected to millimeter waves (irradiation source: gyrotron oscillation tube, frequency: 28 GHz, output) under a hydrogen atmosphere in which hydrogen gas is circulated at a flow rate of 100 mL / min.
- a metal-supported catalyst was obtained by heating from room temperature to 900 ° C. at a heating rate of 450 ° C./min using 1 kW) and holding for 1 hour.
- the platinum-supported amount of the metal-supporting catalyst obtained by ICP-MS measurement was 30 wt%.
- the molar ratio of platinum to cobalt contained in the metal-supporting catalyst (Pt / Co ratio) obtained by ICP-MS measurement was 7.0. Further, the ratio of the supported amount of pure Pt to the total of the supported amount of pure Pt and the supported amount of Pt alloy in the metal-supporting catalyst obtained by XRD was 10% or more.
- a metal-supported catalyst was obtained by the same method as in Example 4 described above except that the carbon carrier E was used instead of the carbon carrier A.
- the platinum-supported amount of the obtained metal-supporting catalyst obtained by ICP-MS measurement was 30 wt%.
- the molar ratio of platinum to cobalt contained in the metal-supporting catalyst (Pt / Co ratio) was 7.0. Further, the ratio of the supported amount of pure Pt to the total of the supported amount of pure Pt and the supported amount of Pt alloy in the metal-supporting catalyst obtained by XRD was 10% or more.
- a metal-supported catalyst was obtained by the same method as in Example 4 described above except that the carbon carrier F was used instead of the carbon carrier A.
- the platinum-supported amount of the obtained metal-supporting catalyst obtained by ICP-MS measurement was 30 wt%.
- the molar ratio of platinum to cobalt contained in the metal-supporting catalyst (Pt / Co ratio) was 7.0. Further, the ratio of the supported amount of pure Pt to the total of the supported amount of pure Pt and the supported amount of Pt alloy in the metal-supporting catalyst obtained by XRD was 10% or more.
- a metal-supported catalyst was obtained by the same method as in Example 4 described above except that the carbon carrier G was used instead of the carbon carrier A.
- the platinum-supported amount of the obtained metal-supporting catalyst obtained by ICP-MS measurement was 30 wt%.
- the molar ratio of platinum to cobalt contained in the metal-supporting catalyst (Pt / Co ratio) was 7.0. Further, the ratio of the supported amount of pure Pt to the total of the supported amount of pure Pt and the supported amount of Pt alloy in the metal-supporting catalyst obtained by XRD was 10% or more.
- Example 9 instead of cobalt chloride, but using nickel chloride (II) hexahydrate (NiCl 2 ⁇ 6H 2 O) in the same manner as in Example 4 above, to obtain a metal-supported catalyst.
- the platinum-supported amount of the obtained metal-supporting catalyst obtained by ICP-MS measurement was 30 wt%.
- the molar ratio of platinum to nickel contained in the metal-supporting catalyst (Pt / Ni ratio) was 7.0.
- the ratio of the supported amount of pure Pt to the total of the supported amount of pure Pt and the supported amount of Pt alloy in the metal-supporting catalyst obtained by XRD was 10% or more.
- a metal-supported catalyst was obtained in the same manner as in Example 4 above except that cobalt chloride was not used.
- the platinum-supported amount of the obtained metal-supporting catalyst obtained by ICP-MS measurement was 30 wt%. Further, the ratio of the supported amount of pure Pt to the total of the supported amount of pure Pt and the supported amount of Pt alloy in the metal-supporting catalyst obtained by XRD was 99% or more.
- a metal-supported catalyst was obtained in the same manner as in Example 1 above, except that instead of heating with millimeter waves in a hydrogen atmosphere, heating was performed in a vacuum atmosphere at a heating rate of 50 ° C./min using a high-frequency furnace. It was.
- the platinum-supported amount of the metal-supporting catalyst obtained by ICP-MS measurement was 20 wt%.
- the molar ratio (Pt / Fe ratio) of platinum to iron contained in the metal-supporting catalyst obtained by ICP-MS measurement was 5.0.
- the ratio of the supported amount of pure Pt to the total of the supported amount of pure Pt and the supported amount of Pt alloy in the metal-supporting catalyst obtained by XRD was 1% or less.
- a metal-supported catalyst was obtained by the same method as in Example 1 described above except that the carbon carrier D was used instead of the carbon carrier A.
- the platinum-supported amount of the metal-supporting catalyst obtained by ICP-MS measurement was 20 wt%.
- the molar ratio (Pt / Fe ratio) of platinum to iron contained in the metal-supporting catalyst obtained by ICP-MS measurement was 5.0.
- the ratio of the supported amount of pure Pt to the total of the supported amount of pure Pt and the supported amount of Pt alloy in the metal-supporting catalyst obtained by XRD was 10% or more.
- a metal-supported catalyst was obtained by the same method as in Example 1 described above except that the carbon carrier KB was used instead of the carbon carrier A.
- the platinum-supported amount of the metal-supporting catalyst obtained by ICP-MS measurement was 20 wt%.
- the molar ratio (Pt / Fe ratio) of platinum to iron contained in the metal-supporting catalyst obtained by ICP-MS measurement was 5.0.
- the ratio of the supported amount of pure Pt to the total of the supported amount of pure Pt and the supported amount of Pt alloy in the metal-supporting catalyst obtained by XRD was 10% or more.
- a metal-supported catalyst was obtained by the same method as in Example 1 described above except that the carbon carrier V was used instead of the carbon carrier A.
- the platinum-supported amount of the metal-supporting catalyst obtained by ICP-MS measurement was 20 wt%.
- the molar ratio (Pt / Fe ratio) of platinum to iron contained in the metal-supporting catalyst obtained by ICP-MS measurement was 5.0.
- the ratio of the supported amount of pure Pt to the total of the supported amount of pure Pt and the supported amount of Pt alloy in the metal-supporting catalyst obtained by XRD was 10% or more.
- a metal-supported catalyst was obtained by the same method as in Example 1 described above except that the carbon carrier DB was used instead of the carbon carrier A.
- the platinum-supported amount of the metal-supporting catalyst obtained by ICP-MS measurement was 20 wt%.
- the molar ratio (Pt / Fe ratio) of platinum to iron contained in the metal-supporting catalyst obtained by ICP-MS measurement was 5.0.
- the ratio of the supported amount of pure Pt to the total of the supported amount of pure Pt and the supported amount of Pt alloy in the metal-supporting catalyst obtained by XRD was 10% or more.
- a metal-supported catalyst was obtained by the same method as in Example 1 described above except that the carbon carrier M was used instead of the carbon carrier A.
- the platinum-supported amount of the metal-supporting catalyst obtained by ICP-MS measurement was 20 wt%.
- the molar ratio (Pt / Fe ratio) of platinum to iron contained in the metal-supporting catalyst obtained by ICP-MS measurement was 5.0.
- the ratio of the supported amount of pure Pt to the total of the supported amount of pure Pt and the supported amount of Pt alloy in the metal-supporting catalyst obtained by XRD was 10% or more.
- a metal-supported catalyst was obtained by the same method as in Example 4 described above except that the carbon carrier KB was used instead of the carbon carrier A.
- the platinum-supported amount of the obtained metal-supporting catalyst obtained by ICP-MS measurement was 30 wt%.
- the molar ratio of platinum to cobalt contained in the metal-supporting catalyst (Pt / Co ratio) was 7.0. Further, the ratio of the supported amount of pure Pt to the total of the supported amount of pure Pt and the supported amount of Pt alloy in the metal-supporting catalyst obtained by XRD was 10% or more.
- a metal-supported catalyst was obtained by the same method as in Example 4 described above except that the carbon carrier M was used instead of the carbon carrier A.
- the platinum-supported amount of the obtained metal-supporting catalyst obtained by ICP-MS measurement was 30 wt%.
- the molar ratio of platinum to cobalt contained in the metal-supporting catalyst (Pt / Co ratio) was 7.0. Further, the ratio of the supported amount of pure Pt to the total of the supported amount of pure Pt and the supported amount of Pt alloy in the metal-supporting catalyst obtained by XRD was 10% or more.
- the metal content of the metal-supporting catalyst was measured by ICP-MS. That is, first, a 25 mg metal-supported catalyst was heated and held at 800 ° C. for 3 hours in an air atmosphere to remove non-metal components in the metal-supported catalyst. Next, the metal contained in the metal-supporting catalyst was dissolved by immersing the metal-supporting catalyst in 5 mL of aqua regia. Further, distilled water was added and diluted so that the total weight became 25 g to obtain a metal solution. Then, the Pt concentration and the transition metal concentration of the obtained metal solution were measured using a sequential type plasma emission spectrometer (ICP-8100, manufactured by Shimadzu Corporation).
- ICP-8100 sequential type plasma emission spectrometer
- the value obtained by multiplying the Pt concentration (mg / g) of the metal solution by the weight of the metal solution (25 g) is divided by the weight of the metal-supporting catalyst (25 mg), and the value obtained is multiplied by 100.
- the Pt content (% by weight) of the metal-supporting catalyst was calculated.
- the value obtained by multiplying the transition metal concentration (mg / g) of the metal solution by the weight of the metal solution (25 g) is divided by the weight of the metal-supporting catalyst (25 mg), and 100 is added to the value obtained. Multiply to calculate the transition metal content (% by weight) of the metal-bearing catalyst.
- the molar ratio of Pt / transition metal is calculated by dividing the value obtained by dividing the Pt content (% by weight) by the Pt atomic weight by the value obtained by dividing the transition metal content (% by weight) by the said transition metal atomic weight. did. Further, the total of the Pt content (% by weight) and the transition metal content (% by weight) of the metal-supporting catalyst was obtained as the metal content (% by weight) of the metal-supporting catalyst. [Elemental analysis by combustion method (CHN)]
- Elemental analysis was performed by the combustion method of the metal-supported catalyst. That is, the nitrogen atom content, the carbon atom content, and the hydrogen atom content of the metal-supporting catalyst were measured by the combustion method using an organic trace element analyzer (2400II, PerkinElmer Co., Ltd.). Specifically, helium was used as a carrier gas, and a 2 mg metal-supported catalyst was analyzed under the conditions of a combustion tube temperature of 980 ° C. and a reduction tube temperature of 640 ° C.
- the weight of the nitrogen atom, the weight of the carbon atom, and the weight of hydrogen contained in the metal-supporting catalyst are each divided by the weight of the metal-supporting catalyst and multiplied by 100 to multiply the nitrogen atom of the metal-supporting catalyst.
- the content (% by weight), carbon atom content (% by weight), and hydrogen atom content (% by weight) were calculated. Further, the nitrogen atom content (% by weight) was divided by the carbon atom content (% by weight) to calculate the N / C ratio by elemental analysis.
- XPS X-ray Photoelectron Spectroscopy
- the atomic concentrations (atomic%) of platinum atoms, carbon atoms, and nitrogen atoms on the surface of the metal-supported catalyst were determined from the peak area and the detection sensitivity coefficient in the photoelectron spectrum. Further, the nitrogen atom concentration (atomic%) was divided by the carbon atom concentration (atomic%) to calculate the N / C ratio by XPS. Further, the ratio (XPS-N / C weight ratio) of the nitrogen atom content (% by weight) to the carbon atom content (% by weight) was calculated from the atomic weight ratio of the carbon atom and the nitrogen atom.
- the platinum content (% by weight) of the metal-supported catalyst by XPS was determined from the platinum peak area, the detection sensitivity coefficient, and the atomic weight.
- the metal-supported catalyst does not contain atoms other than platinum atom, iron atom, cobalt atom, nickel atom, oxygen atom, chlorine atom, carbon atom and nitrogen atom. [Specific surface area, pore volume]
- the specific surface area and pore volume of the metal-supporting catalyst were measured using a specific surface area / pore distribution measuring device (Tristar 3000, manufactured by Shimadzu Corporation). That is, first, water adsorbed on the metal-supporting catalyst was removed by holding 0.1 g of the metal-supporting catalyst at 100 ° C. and 6.7 ⁇ 10 -2 Pa for 3 hours. Then, the specific surface area (m 2 / g) of the metal-supported catalyst was obtained from the nitrogen adsorption isotherm at 77 K by the BET method. The nitrogen adsorption isotherm at 77K was obtained by measuring the change in the amount of nitrogen adsorbed on the metal-supporting catalyst with the change in the pressure of the nitrogen gas at the temperature of 77K.
- the volume of pores with a diameter of 0.5 nm or more and 2.0 nm or less (cm 3 / g) and a diameter of more than 2.0 nm and 4.0 nm or less by the BJH method.
- the volume of the pores (cm 3 / g) and the volume of the pores having a diameter of more than 4.0 nm and 50.0 nm or less were obtained.
- the BJH method is a typical method for obtaining the distribution of mesopores proposed by Barrett, Joyner, and Halenda (EP Barrett, LG Joyner and PP Halenda, J Am Chem Soc, 73, 373, (1951)). ..
- the diffraction angle (2 ⁇ ) is around 40 ° (for example, in the X-ray diffraction diagram obtained by powder X-ray diffraction using CuK ⁇ rays).
- a platinum (111) diffraction line appears at a position (within the range of 36 ° to 44 °).
- a diffraction line having a peak top at a position where the diffraction angle (2 ⁇ ) is around 40 ° in the X-ray diffraction pattern is generated.
- the diffraction line includes at least three types of diffraction lines, that is, a diffraction line derived from pure platinum, a diffraction line derived from a platinum alloy, and a diffraction line derived from the carbon structure of a carbon carrier.
- the diffraction line derived from pure platinum is defined as a diffraction line having a peak top at a position where the diffraction angle (2 ⁇ ) is 39.6 ° or more and less than 39.8 °.
- a diffraction line derived from a platinum alloy is defined as a diffraction line having a peak top at a position where the diffraction angle (2 ⁇ ) is 39.9 ° or more and less than 43.0 °.
- a diffraction line derived from the carbon structure of a carbon carrier is defined as a diffraction line having a peak top at a position where the diffraction angle (2 ⁇ ) is 43.3 ° or more and less than 43.7 °.
- the diffraction angle (2 ⁇ ) peaks at a position near 40 ° in the X-ray diffraction pattern.
- the diffraction line having the above can be separated into at least three types of diffraction lines.
- the metal-supporting catalyst contains a plurality of types of platinum alloys having different compositions and / or crystal structures
- a plurality of diffraction lines derived from the platinum alloy appear.
- the diffraction angle at which the peak top of the diffraction line derived from the platinum alloy is located is determined by its composition and crystal structure.
- a diffraction line derived from an iron-platinum alloy represented by the composition FePt is defined as a diffraction line having a peak top at a position where the diffraction angle is 41.1 ° or more and less than 41.5 °.
- the diffraction line derived from the iron-platinum alloy represented by the composition FePt 3 is defined as a diffraction line having a peak top at a position where the diffraction angle is 40.1 ° or more and less than 40.5 °.
- the diffraction angle at which the peak top of the diffraction line is located is, for example, 39.9 ° or more and less than 40.1 ° for the iron-platinum alloy FePt 7 , 41.1 ° or more for the cobalt-platinum alloy CoPt, 41.
- the metal-supporting catalyst contains a plurality of types of platinum particles having the same composition and crystal structure but different crystallite diameters, a plurality of diffraction lines having a peak top at the same diffraction angle position and different full width at half maximum. Appears.
- the metal-supporting catalyst contains a plurality of types of platinum alloys having different compositions and / or crystal structures, and / or when a plurality of platinum particles having the same composition and crystal structure but different crystallite diameters are contained, CuK ⁇ rays.
- the diffraction lines having the peak top at the position where the diffraction angle (2 ⁇ ) is around 40 ° include four or more types of diffraction lines.
- the diffraction lines having the peak top at the position where the diffraction angle (2 ⁇ ) is around 40 ° are four or more types of diffraction lines (diffraction lines derived from pure platinum, diffraction lines derived from two or more types of platinum alloys). It can be separated into a line and a diffraction line derived from the carbon structure of the carbon carrier).
- a method for analyzing a metal-supported catalyst using powder XRD will be specifically described.
- a powdered metal-supported catalyst sample is placed in a recess (2 cm x 2 cm x thickness 0.5 mm) of a glass sample plate and pressed with a slide glass so that the surface of the sample and the reference surface coincide with each other.
- the recess was uniformly filled.
- the glass sample plate was fixed to the wide-angle X-ray diffraction sample table so that the shape of the filled sample did not collapse.
- XRD powder X-ray diffraction
- the baseline correction was performed. That is, a straight line connecting the diffraction intensity with a diffraction angle (2 ⁇ ) of about 35 ° to 37 ° and the diffraction intensity with a diffraction angle of about 50 ° to 52 ° is determined as the baseline, and the baseline is subtracted from each intensity of the diffraction line. By doing so, the baseline correction was performed.
- the baseline-corrected diffraction line was separated into a peak derived from pure Pt, a peak derived from one or more Pt alloys, and a peak derived from carbon. Separation of diffraction lines assumes that each of the plurality of peaks obtained by the separation is represented by a Gaussian function, and is the sum of the intensity of the diffraction line and the intensity of each of the plurality of peaks at each diffraction angle of the XRD figure.
- a diffraction line having a diffraction angle (2 ⁇ ) of about 40 ° is composed of three components, a peak derived from the first platinum alloy, a peak derived from the second platinum alloy, and a peak derived from carbon. Separated into.
- the “after baseline correction” diffraction line indicates the diffraction line obtained by subjecting the diffraction line obtained by the XRD measurement to the baseline correction, and the peak of “alloy 1” and the diffraction line of “alloy 2”.
- the peak and the "carbon” peak are the peak derived from the first platinum alloy, the peak derived from the second platinum alloy, and the peak derived from carbon, respectively, obtained by the peak separation of the diffraction line after the "baseline correction". Shows the peak of.
- the peak of "alloy 1 + 2 + carbon” indicates a peak obtained by adding the peak of "alloy 1", the peak of "alloy 2" and the peak of "carbon”.
- the peak separation of the diffraction line after baseline correction is performed so that the widening of the hem at which the diffraction angle (2 ⁇ ) is around 37 ° matches the shape of the peak top near 40 °.
- shoulders around 39.6 ° and around 41.0 ° could not be reproduced.
- the diffraction line derived from pure platinum has a peak top at a position where the diffraction angle (2 ⁇ ) is 39.6 ° or more and less than 39.8 °, and the diffraction line derived from the platinum alloy has a peak top.
- the peak top is located at a position where the diffraction angle (2 ⁇ ) is 39.9 ° or more and less than 43.0 °. Therefore, the diffraction lines after baseline correction include a diffraction line derived from pure Pt having a peak top at a position near 39.6 ° and a third platinum alloy having a peak top at a position near 41.0 °. It was considered that the diffraction line of was mixed.
- the diffraction line having a diffraction angle (2 ⁇ ) of about 40 ° is divided into a peak derived from pure platinum, a peak derived from the first platinum alloy, a peak derived from the second platinum alloy, and a third platinum. It was separated into five components composed of a peak derived from an alloy and a peak derived from carbon.
- the “after baseline correction” diffraction line indicates the diffraction line obtained by subjecting the diffraction line obtained by the XRD measurement to the baseline correction, and is the peak of “pure Pt”, that of “Alloy 1”.
- the peak, the peak of "alloy 2", the peak of "alloy 3", and the peak of "carbon” are the peaks derived from pure platinum obtained by the peak separation of the diffraction lines "after baseline correction", respectively.
- a peak derived from one platinum alloy, a peak derived from a second platinum alloy, a peak derived from a third platinum alloy, and a peak derived from carbon are shown.
- the metal-supported catalyst of Example 4 was supported with pure platinum particles, a first platinum alloy particle, a second platinum alloy particle, and a third platinum alloy particle as Pt particles.
- crystallite diameter K ⁇ /. ⁇ cos ⁇ .
- K is the Scheller constant (0.94)
- ⁇ is the wavelength of the CuK ⁇ line (0.15418 nm)
- ⁇ is the full width at half maximum (radian)
- ⁇ is. It is a diffraction angle (radian). That is, for example, the crystallite diameter of the pure platinum particles was calculated by substituting the diffraction angle and the full width at half maximum of the separation peak of "pure Pt" in the XRD figure shown in FIG. 1B into the above Scheller's equation.
- each Pt separation peak obtained by the above-mentioned peak separation (that is, the peak area of "pure Pt", the peak area of "alloy 1", the peak area of "alloy 2", and the peak area of "alloy 3” ) was divided by the total area of the Pt separation peaks to calculate the peak area ratio of each Pt separation peak. Then, the average crystallite diameter of the catalyst metal particles was calculated as a weighted average using these peak area ratios as weights.
- FIG. 2 shows the crystallite diameters and peak area ratios of "pure Pt", "alloy 1", “alloy 2", and “alloy 3" calculated for the metal-supported catalyst of Example 4. Shown.
- the proportion (%) of the catalytic metal particles having a particle size of 5.0 nm or less was calculated by the following method. Using a JEM-2010 transmission electron microscope manufactured by JEOL Ltd., TEM observation of a metal-supported catalyst was performed at a magnification of 400,000 times or more. That is, in the obtained TEM image, the length of the longest portion of 100 randomly selected catalytic metal particles was measured as the particle size. Then, by multiplying the value obtained by dividing the number of catalyst metal particles having a particle size of 5.0 nm or less by the total number of catalyst metal particles 100 by 100, the ratio of the catalyst metal particles having a particle size of 5.0 nm or less is obtained. (%) Was calculated.
- FIG. 3 shows a TEM image of the metal-supported catalyst of Example 4 as an example of the TEM image used for evaluating the ratio of the catalyst metal particles having a particle size of 5.0 nm or less. As shown for one of the particles shown in FIG. 3, the length of the longest portion indicated by the arrow was measured as the particle size. [Average particle size of metal-supported catalyst ( ⁇ m)]
- the average particle size of the metal-supported catalyst containing the carbon carrier and the catalyst metal particles was measured. That is, the particle size of the metal-supported catalyst was measured by a laser diffraction method using a nanoparticle size distribution measuring device (SALD-7100H, manufactured by Shimadzu Corporation).
- the HAADF-STEM image is a transmission electron image, not only the metal particles on the surface of the carbon carrier particles but also the metal particles inside can be observed.
- the STEM secondary electron image only the metal particles on the outermost surface of the carbon carrier can be observed.
- image analysis of the HAADF-STEM image and the STEM secondary electron image was performed. That is, an image analysis of the HAADF-STEM image was performed using an image processing analysis device (LUZEX AP, manufactured by Nireco Corporation), and the number of metal particles in a specific field of view of the HAADF-STEM image was calculated. Similarly, image analysis of the STEM secondary electron image was performed, and the number of metal particles in the specific field of view corresponding to the specific field of view of the HAADF-STEM image was calculated from the STEM secondary electron image.
- image processing analysis device LZEX AP, manufactured by Nireco Corporation
- FIG. 4A and 4B show the HAADF-STEM image and the STEM secondary electron image obtained for the metal-supported catalyst of Example 4, respectively.
- FIG. 4A in the HAADF-STEM image, metal particles existing on the surface and inside of the carbon carrier were observed.
- FIG. 4B in the STEM secondary electron image, only the metal particles existing on the surface of the carbon carrier were observed.
- the number of metal particles in the visual field surrounded by the broken line in FIG. 4A was 1219.
- the number of metal particles in the visual field surrounded by the broken line in FIG. 4B was 125. Therefore, in the metal-supported catalyst of Example 4, the ratio of the catalyst metal particles on the outermost surface was calculated to be about 10%. Similarly, the proportion of catalytic metal particles on the outermost surface of the metal-supported catalyst was about 4% for Example 8 and about 13% for Example C1. [Raman spectroscopy]
- the metal-supported catalyst was analyzed by Raman spectroscopy.
- the Raman spectrum was measured using a HORIBA microlaser Raman spectroscopic measuring device (LabRAM, HORIBA Jobin Yvon).
- the laser used for the measurement had an excitation wavelength of 532 nm, an output of 50 mW, and was measured through a neutral density filter D3 under the conditions of exposure 90 seconds ⁇ integration 2 times to obtain a Raman spectrum.
- Baseline correction was applied to the obtained Raman spectrum. That is, the scattering intensity in the vicinity of -1 Raman shift (cm -1) is 800 cm, a straight line connecting the scattering intensity at around 2000 cm -1 was determined to baseline, from the intensity of the scattered spectrum by subtracting the baseline Baseline correction was performed.
- a G band having a peak top near 1600 cm -1 and a D band having a peak top near 1360 cm -1 were identified. Further, the intensity Ig of the G band (the intensity of the peak top of the G band), the intensity I d of the D band (the intensity of the peak top of the D band), and the minimum intensity I v between the G band and the D band. based on the half width (cm -1) of the G-band half width of the D-band (cm -1), and to obtain a I v / I g ratio.
- FIG. 5 shows, as an example of the Raman spectrum, the result of analyzing the Raman spectrum obtained by the Raman spectroscopy of the metal-supported catalyst obtained in Example 1.
- the horizontal axis represents Raman shift (cm -1)
- the vertical axis represents the scattering intensity
- the broken line indicates the baseline
- a d is Raman shift (cm -1) corresponding to the peak top of the D-band are shown
- B d represents a Raman shift (cm -1) corresponding to the Raman spectra showing the intensity of the half of the a d from a low frequency side in the D band intensity I d
- a g is the peak top of G band shows the corresponding Raman shift (cm -1)
- B g represents a Raman shift (cm -1) corresponding to the Raman spectra showing the intensity of the half of the a g the G band intensity from a high wave number side I g.
- Hot temperature desorption method [Hot temperature desorption method]
- a metal-supporting catalyst is installed in a temperature-temperature desorption device (manufactured by Microtrac Bell Co., Ltd.), a carrier gas (He) is circulated at 20 mL / min to heat the carbon catalyst, and the desorbed gas is quadrupole. It was measured with a mass spectrometer (Quadrupole Mass Catalyst: QMS).
- pretreatment of the metal-supported catalyst was performed. That is, first, 0.05 g of the metal-supported catalyst was filled in the central portion of the reaction tube made of quartz, and the metal-supported catalyst was set in the temperature desorption device. Pretreatment was performed by heating the reaction tube to 600 ° C. at a heating rate of 10 ° C./min in a nitrogen atmosphere and holding the reaction tube at 600 ° C. for 30 minutes.
- the measurement atmosphere was stabilized. That is, the atmosphere in the apparatus was stabilized by holding the reaction tube at 25 ° C. for 120 minutes in a helium (He) atmosphere. Then, the metal-supporting catalyst was heat-treated, and the amount of nitrogen desorption in each of the temperature range from 600 ° C. to 1000 ° C. and the temperature range from 800 ° C. to 1000 ° C. was measured. That is, after the above stabilization, the metal-supporting catalyst is heated again and heated to 1000 ° C. at a heating rate of 10 ° C./min to heat-treat the metal-supporting catalyst, and the amount of nitrogen functional groups on the surface thereof is Was measured.
- He helium
- the metal-supported catalyst was heat-treated and the amount of nitrogen gas (N 2 ) desorbed was measured. That is, after stabilizing the atmosphere in the apparatus, the temperature of the reaction tube was raised to 1000 ° C. at a heating rate of 10 ° C./min. During this temperature rise to 1000 ° C., while helium (He) gas was circulated at 20 mL / min, nitrogen generated by desorption of nitrogen-containing compounds was detected by mass number 14 (when mass number 28 is used, N 2 In addition to this, gases such as CO and C 2 H 4 are also contained (especially CO is mainly contained), so a mass number of 14 was used.) First, the obtained spectrum was subjected to baseline correction. After that, the correlation between the temperature (horizontal axis) and the detected intensity (vertical axis) was recorded.
- N 2 nitrogen gas
- Cyclic voltammetry (CV) measurement was performed on the metal-supported catalyst produced as described above using the rotating disc electrode measurement method.
- 500 ⁇ L of an aqueous solution prepared by mixing 5.0 mg of a metal-supporting catalyst, distilled water, and isopropyl alcohol in a weight ratio of 8: 2, and 50 ⁇ L of an electrolyte resin solution (Dupont, DE2020CS, (Electrolyte resin concentration 20 wt%) and was mixed.
- the obtained suspension was subjected to ultrasonic dispersion treatment for 5 minutes, and then further subjected to dispersion treatment using a homogenizer for 2 minutes to obtain a catalyst ink.
- the obtained catalyst ink was applied to the rotating disk electrode so that the supported amount of the metal-supported catalyst (the total of the supported amount of the catalyst metal and the supported amount of the carbon carrier) was 0.1 mg / cm 2.
- the rotating disc electrode on which the catalyst layer was formed was installed in an electrochemical cell (manufactured by BAS).
- a reversible hydrogen electrode (RHE) was used as a reference electrode
- a 0.1 M perchloric acid aqueous solution was used as an electrolytic solution.
- the electrolytic solution was saturated with nitrogen gas for 10 minutes, and potential scanning was performed for 5 cycles from a low potential of 0.06 V to a high potential of 1.2 V at a scanning speed of 0.05 V / sec.
- This amount of hydrogen adsorption electricity is divided by the theoretical area-equivalent electricity amount (2.10 C / m 2 ) of hydrogen adsorption with respect to platinum, and further divided by the weight of platinum (g) to obtain effective platinum in hydrogen adsorption.
- the catalyst surface area (m 2 / g- platinum) hereinafter, referred to as "H 2 -ECSA (electrochemical surface area)”.
- CO stripping voltammetry measurement was performed using a rotating disc electrode.
- a rotating disc electrode was prepared by the same method as the above-mentioned CV measurement, and installed in an electrochemical cell.
- the reference electrode and the electrolytic solution were also prepared in the same manner as the above-mentioned CV.
- pretreatment was performed. That is, the electrolytic solution was saturated with nitrogen gas for 10 minutes, and potential scanning was performed for 20 cycles from a low potential of 0.06 V to a high potential of 1.2 V at a scanning speed of 0.1 V / sec.
- CV measurement was carried out by the same method as the above-mentioned CV measurement. Next, the 0.3% CO gas was saturated for 5 minutes, and the rotating disk electrode was rotated at 1600 rpm from a low potential of 0.06 V to a high potential of 1.2 V at a scanning speed of 0.1 V / sec. Potential scanning was performed for 5 cycles.
- the reduction current value at 0.6V is used as a reference.
- the amount of CO-adsorbed electricity (unit: C) was obtained by reducing the amount of electricity due to the non-Faraday current in the potential range of 0.6 V to 1.1 V.
- This amount of CO-adsorbed electricity is divided by the theoretical area-equivalent amount of electricity (4.20 C / m 2 ) for CO adsorption with respect to platinum, and further divided by the weight (g) of platinum to make effective platinum in CO adsorption.
- the catalyst surface area (m 2 / g-platinum) (hereinafter referred to as "CO-ECSA") was calculated. [Pt equivalent of non-platinum active site]
- the amount of platinum carried per cathode unit area is 0.012 mg / cm 2 , 0.028 mg / cm 2 , 0.045 mg / cm 2. It was prepared 0.067 mg / cm 2, and a 0.100 mg / cm 2 5 membranes / electrode assembly (MEA).
- the platinum catalyst was composed of carbon black as a carrier and 39% by weight of platinum particles supported on the carrier.
- a power generation test was conducted using each of the plurality of MEAs. That is, by supplying hydrogen to the anode side and oxygen to the cathode side and sweeping the current under the conditions of a cell temperature of 75 ° C. and a relative humidity of 100% RH, the voltage (mV) at a current density of 0.1 A / cm 2 And the platinum carrying amount of MEA were obtained. As a result, the voltage when the amount of supported platinum was used an MEA of 0.012 mg / cm 2, voltage when the amount of platinum supported was used an MEA of 0.1 mg / cm 2 (hereinafter, referred to as "reference voltage". ) was 120 mV lower.
- an MEA containing a carbon carrier that does not support the catalyst metal particles is prepared, and a power generation test is performed in the same manner as in the above case using the commercially available platinum catalyst, and the current density is obtained.
- the voltage (mV) at 0.1 A / cm 2 was measured.
- the voltage (mV) at a current density of 0.1 A / cm 2 was 120 mV lower than the reference voltage. Therefore, the carbon support A of 0.3 mg / cm 2, it was confirmed to have a catalytic activity corresponding to a platinum catalyst 0.012 mg / cm 2. That is, the carbon support A of 0.1 mg / cm 2 were evaluated as having a catalytic activity corresponding to a platinum catalyst 0.004 mg / cm 2.
- the metal-supported catalyst of Example 1 (content of platinum particles 20% by weight, content of carbon carrier A 80% by weight) is replaced with the above-mentioned commercially available platinum catalyst, and the platinum content is 0.1 mg /
- the content of carbon carrier A (content 80% by weight in the metal-supported catalyst) in the cathode catalyst layer is 0.4 mg / cm 2 , which is metal-supported.
- the content of the catalyst is 0.5 mg / cm 2 .
- the carbon support A of 0.1 mg / cm 2 is because it has a catalytic activity corresponding to a platinum catalyst 0.004 mg / cm 2, a cathode catalyst layer containing a carbon support A 0.4 mg / cm 2 is It is evaluated to have a catalytic activity corresponding to 0.016 mg / cm 2 of the platinum catalyst. Then, the amount 0.016 mg / cm 2 of platinum catalyst having a catalytic activity corresponding to a carbon support A of 0.4 mg / cm 2, by dividing in a loading amount of the carbon support A (0.0004g / cm 2) A platinum equivalent of 40.0 (mg-Pt / g-carrier) of the non-platinum active site in the carbon carrier A was calculated. [Initial performance and durability]
- a battery cathode having a catalyst layer containing a metal-supported catalyst was manufactured. That is, first, an electrolyte (EW700) having an amount of 0.9 by weight with respect to the carbon carrier was added to 0.25 g of the metal-supporting catalyst, and 2 g of distilled water and 1-propanol were added to prepare an electrolyte solution. .. This electrolyte solution and 25 g of balls were put into a pot and mixed with a ball mill at 200 rpm for 50 minutes to obtain a slurry-like composition for a catalyst layer containing a uniformly dispersed metal-supporting catalyst.
- EW700 electrolyte having an amount of 0.9 by weight with respect to the carbon carrier
- 2 g of distilled water and 1-propanol were added to prepare an electrolyte solution. ..
- This electrolyte solution and 25 g of balls were put into a pot and mixed with a ball mill at 200 rpm for 50 minutes to obtain a slurry-like composition
- the obtained slurry-like catalyst layer composition is placed on a gas diffusion layer (“29BC”, manufactured by SGL Carbon Co., Ltd.) (2.3 cm ⁇ 2.3 cm) in an area of 5 cm 2 per unit area of the battery electrode.
- a catalyst layer was formed on the gas diffusion layer by applying and drying the metal-supported catalyst so as to have a content of 0.1 mg / cm 2 . In this way, a battery electrode on which a catalyst layer containing a metal-supported catalyst was formed was obtained.
- a fuel cell including a battery electrode on which a catalyst layer containing a metal-supported catalyst was formed was manufactured. That is, as the positive electrode, a battery electrode including a catalyst layer (positive electrode catalyst layer) manufactured as described above was used.
- the negative electrode was manufactured as follows. Add 0.5 g of Pt / C (UNPC40-II, manufactured by Ishifuku Metal Industry Co., Ltd.), 10 g of 5% Nafion (registered trademark), 2 g of distilled water, and 25 g of balls into a pot, and use a ball mill at 200 rpm for 50 minutes. By mixing, a slurry-like Pt / C composition was prepared. This slurry-like Pt / C composition is the same as the above-mentioned positive electrode except that the amount of Pt / C applied per unit area on the gas diffusion layer (5 cm 2 ) is 0.1 mg / cm 2. A negative electrode containing a catalyst layer (negative electrode catalyst layer) formed from the Pt / C composition was produced.
- NAFION registered trademark
- DuPont a solid polymer electrolyte membrane
- the single cell manufactured as described above was installed in the fuel cell automatic evaluation system (manufactured by Toyo Corporation), and the power generation test was first performed, and then the durability test was performed.
- the output density obtained from the potential and the current density was calculated for each potential, and the highest value was measured as the maximum output density (mW / cm 2 ).
- the voltage (mV) at 1.0 A / cm 2 at the start of the durability test was recorded.
- the cell temperature was set to 75 ° C.
- saturated humidified nitrogen was supplied to both sides of the single cell at a back pressure of 35 kPa at 0.5 L / min (relative humidity 100%), and saturated humidified hydrogen was supplied to the anode side in 0.5 mL.
- Durability tests were performed by repeating cycles of rectangular waves fed at / min (relative humidity 100%), held at 0.6 V for 30 seconds, and held at 1.0 V for 60 seconds.
- the power generation test was performed again, and the voltage (mV) at 1.0 A / cm 2 after the durability test was recorded. Then, from the voltage (mV) measured as the initial performance in the power generation test before the durability test, the voltage (mV) measured in the power generation test after the durability test (voltage (mV) after 2100 cycles). The value obtained by subtracting the above was obtained as the amount of voltage decrease (mV) after 2100 cycles.
- [result] 6A, 6B and 6C show the results of evaluating the characteristics of the metal-supported catalysts of each example.
- the initial performance and durability of the MEA using the metal-supported catalysts of Examples 1 to 9 were superior to those of Examples C1 to C9.
- MEA using the metal-supported catalysts of Examples C1, C4, C5 and Example 8 was significantly inferior in durability.
- the MEA using the metal-supported catalyst of Example C2 had a low maximum output density.
- the MEAs using the metal-supported catalysts of Examples C3 to C9 had significantly lower voltage, maximum output density, and durability at a current density of 0.2 A / cm 2 .
- the volume of the first pores of the metal-supported catalysts of Examples 1 to 9 was larger than that of Examples C3 to C9.
- the volumes of the second pores and the third pores of the metal-supported catalysts of Examples 1 to 9 were larger than those of Examples C2, C4 to C6, and C8.
- the volume of the third pores of Examples C3, C7 and C9 was significantly larger than that of the metal-supported catalysts of Examples 1 to 9. Therefore, the third pore / second pore volume ratio of the metal-supported catalysts of Examples 1 to 9 was smaller than that of Examples C3 to C9.
- the noble metal (Pt) -XPS / ICP ratios of the metal-supported catalysts of Examples C1, C4 and C5 were significantly larger than those of Examples 1 to 9. That is, in the metal-supported catalysts of Examples C1, C4 and C5, a relatively large number of Pt particles were supported near the surface of the carbon carrier.
- the CHN-N / C ratio and the XPS-N / C ratio of the metal-supported catalysts of Examples 1 to 9 were significantly larger than those of Examples C3 to C9.
- the amount of nitrogen desorption in the TPD of the metal-supported catalysts of Examples 1 to 9 was significantly larger than that of Examples C2 to C9.
- the average crystallite diameter of the catalyst metal (Pt) particles obtained by XRD of the metal-supported catalysts of Examples 1 to 9 is significantly higher than that of Examples C2, C4 to C6 and C8. It was small. Further, the proportion of the catalyst metal (Pt) particles having a particle size of 5.0 nm or less obtained by TEM observation of the metal-supported catalysts of Examples 1 to 9 was significantly larger than that of Examples C1 to C9.
- the crystallite diameter corresponding to the primary particles is evaluated in XRD, whereas the particles of the secondary particles are evaluated in TEM observation. In order to evaluate the diameter, the crystallite diameter obtained by XRD and the particle size obtained by TEM observation do not always match.
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Abstract
Description
1.0gのポリアクリロニトリル(PAN)と、1.0gの2-メチルイミダゾールと、6.0gの塩化亜鉛(ZnCl2)と、0.18gの塩化鉄(III)六水和物(FeCl3・6H2O)と、30gのジメチルホルムアミドとを混合した。得られた混合物から乾燥により溶媒を除去した。乾燥した混合物を大気中で加熱して、250℃で不融化を行った。
[炭素担体B]
[炭素担体C]
[炭素担体D]
[炭素担体E]
[炭素担体F]
[炭素担体G]
[炭素担体M]
[炭素担体KB]
[炭素担体V]
[炭素担体DB]
[例1]
[例2]
[例3]
[例4]
[例5]
[例6]
[例7]
[例8]
[例9]
[例C1]
[例C2]
[例C3]
[例C4]
[例C5]
[例C6]
[例C7]
[例C8]
[例C9]
[誘導結合プラズマ質量分析(ICP-MS)]
[燃焼法による元素分析(CHN)]
[X線光電子分光法(XPS)]
[比表面積、細孔容積]
[粉末X線回折(XRD)]
[粒径5.0nm以下の触媒金属粒子の割合(TEM観察)]
[金属担持触媒の平均粒子径(μm)]
[最表面の触媒金属粒子の割合]
[ラマン分光法]
[昇温脱離法]
[有効白金触媒表面積(ECSA)]
[非白金活性点のPt相当量]
[初期性能及び耐久性]
図6A、図6B及び図6Cには、各例の金属担持触媒の特性を評価した結果を示す。図6Aに示すように、例1~例9の金属担持触媒を用いたMEAの初期性能及び耐久性は、例C1~例C9のそれらより優れていた。例えば、例C1、例C4、例C5及び例8の金属担持触媒を用いたMEAは、耐久性が顕著に劣っていた。また、例C2の金属担持触媒を用いたMEAは、最大出力密度が低かった。例C3~例C9の金属担持触媒を用いたMEAは、電流密度0.2A/cm2での電圧、最大出力密度、及び耐久性の2つ以上が顕著に低かった。
Claims (16)
- 炭素担体と、前記炭素担体に担持された、貴金属を含む触媒金属粒子とを含み、
前記炭素担体の単位重量あたりの、0.5nm以上、2.0nm以下の直径を有する第一の細孔の容積が0.20(cm3/g-担体)以上であり、
前記炭素担体の単位重量あたりの、2.0nm超、4.0nm以下の直径を有する第二の細孔の容積が0.20(cm3/g-担体)以上であり、
誘導結合プラズマ質量分析で測定される前記貴金属の含有量(重量%)に対する、X線光電子分光法で測定される前記貴金属の含有量(重量%)の比が0.35以上、0.75以下である、
金属担持触媒。 - 前記炭素担体の単位重量あたりの、4.0nm超、50.0nm以下の直径を有する第三の細孔の容積が、0.25(cm3/g-担体)以上である、
請求項1に記載の金属担持触媒。 - 前記炭素担体の単位重量あたりの、4.0nm超、50.0nm以下の直径を有する第三の細孔の容積が、1.00(cm3/g-担体)以下である、
請求項1又は2に記載の金属担持触媒。 - 前記炭素担体の単位重量あたりの、2.0nm超、4.0nm以下の直径を有する第二の細孔の容積に対する、4.0nm超、50.0nm以下の直径を有する第三の細孔の容積の比が、3.00以下である、
請求項1乃至3のいずれかに記載の金属担持触媒。 - CuKα線による粉末X線回折図形における回折角2θが40°付近の回折線を分離することで得られる1以上の回折ピークの回折角及び半値全幅を用いてシェラーの式により算出される前記触媒金属粒子の平均結晶子径が7.0nm以下である、
請求項1乃至4のいずれかに記載の金属担持触媒。 - X線光電子分光法で測定される炭素原子濃度に対する窒素原子濃度の比が0.010以上である、
請求項1乃至5のいずれかに記載の金属担持触媒。 - BET比表面積に、前記炭素担体の重量に対する前記金属担持触媒の重量の比を乗じて算出される、規格化比表面積が1100(m2/g-担体)以上である、
請求項1乃至6のいずれかに記載の金属担持触媒。 - 前記触媒金属粒子は、白金粒子である、
請求項1乃至7のいずれかに記載の金属担持触媒。 - 前記金属担持触媒を含む回転ディスク電極を用いたサイクリックボルタンメトリーにおいて測定される水素吸着電気量を、白金に対する水素吸着の理論的な面積換算電気量及び前記金属担持触媒に担持された白金の重量で除して得られる電気化学的表面積(H2-ECSA)が20.0m2/g-白金以上であり、
前記金属担持触媒を含む回転ディスク電極を用いたストリッピングボルタンメトリーにおいて測定される一酸化炭素吸着電気量を、白金に対する一酸化炭素吸着の理論的な面積換算電気量及び前記金属担持触媒に担持された白金の重量で除して得られる電気化学的表面積(CO-ECSA)が20.0m2/g-白金以上である、
請求項8に記載の金属担持触媒。 - ラマン分光法により得られるラマンスペクトルにおいて、1360cm-1付近にピークトップを有するDバンドの半値幅160cm-1以下を示す炭素構造を含む、請求項1
乃至9のいずれかに記載の金属担持触媒。 - ラマン分光法により得られるラマンスペクトルにおいて、1600cm-1付近にピークトップを有するGバンドの半値幅90cm-1以下を示す炭素構造を含む、請求項1乃至10のいずれかに記載の金属担持触媒。
- ラマン分光法により得られるラマンスペクトルにおいて、1600cm-1付近にピークトップを有するGバンドの強度に対する、前記Gバンドと1360cm-1付近にピークトップを有するDバンドとの間の最小強度の比0.20以上、0.50以下を示す炭素構造を含む、請求項1乃至11のいずれかに記載の金属担持触媒。
- 昇温脱離法において、前記炭素担体の単位重量あたり、600℃から1000℃までの窒素脱離量1.20×10-5(mol/g-担体)以上を示す炭素構造を含む、請求項1乃至12のいずれかに記載の金属担持触媒。
- 昇温脱離法において、前記炭素担体の単位重量あたり、800℃から1000℃までの窒素脱離量0.75×10-5(mol/g-担体)以上を示す炭素構造を含む、請求項1乃至13のいずれかに記載の金属担持触媒。
- 請求項1乃至14のいずれかに記載の金属担持触媒を含む、電池電極。
- 請求項15に記載の電池電極を含む、電池。
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WO2023166755A1 (ja) * | 2022-03-04 | 2023-09-07 | 日清紡ホールディングス株式会社 | 金属担持触媒及びその製造方法並びに電極及び電池 |
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KR20220038752A (ko) | 2022-03-29 |
CN114206494B (zh) | 2024-05-14 |
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US20220263100A1 (en) | 2022-08-18 |
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