WO2019243511A1 - Composition de coloration capillaire comprenant un colorant d'oxydation, une gomme de scléroglucane et un polymère cationique - Google Patents
Composition de coloration capillaire comprenant un colorant d'oxydation, une gomme de scléroglucane et un polymère cationique Download PDFInfo
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- WO2019243511A1 WO2019243511A1 PCT/EP2019/066368 EP2019066368W WO2019243511A1 WO 2019243511 A1 WO2019243511 A1 WO 2019243511A1 EP 2019066368 W EP2019066368 W EP 2019066368W WO 2019243511 A1 WO2019243511 A1 WO 2019243511A1
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/22—Peroxides; Oxygen; Ozone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/362—Polycarboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
- A61K8/4926—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having six membered rings
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
- A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
- A61K2800/432—Direct dyes
- A61K2800/4324—Direct dyes in preparations for permanently dyeing the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
- A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
- A61K2800/5426—Polymers characterized by specific structures/properties characterized by the charge cationic
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/88—Two- or multipart kits
- A61K2800/882—Mixing prior to application
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/88—Two- or multipart kits
- A61K2800/884—Sequential application
Definitions
- Hair coloring composition comprising an oxidation dye, a scleroglucan gum and a polymer
- the present invention relates to the field of dyeing keratin fibers and more particularly to that of hair dyeing.
- the methods of dyeing human keratin fibers, such as the hair mention may be made of oxidation or permanent dyeing. More particularly, this mode of coloring implements one or more oxidation dyes, usually one or more oxidation bases possibly associated with one or more couplers.
- oxidation bases are chosen from ortho- or para-phenylenediamines, ortho- or para-aminophenols as well as heterocyclic compounds. These oxidation bases are colorless or weakly colored compounds which, associated with oxidizing products, allow access to colored species.
- the nuances obtained with these oxidation bases are varied by associating them with one or more couplers, the latter being chosen in particular from aromatic meta-diamines, meta-aminophenols, meta-diphenols and certain heterocyclic compounds, such as indole compounds.
- the oxidation dyeing processes therefore consist in using with these dye compositions, a composition comprising at least one oxidizing agent, in general hydrogen peroxide, under alkaline pH conditions in the vast majority of cases.
- This oxidizing agent has the role of revealing the coloring, by a reaction of oxidative condensation of the oxidation dyes between them.
- Oxidation coloring must also meet a certain number of requirements. Thus, it must be without drawbacks from the toxicological point of view, it must make it possible to obtain nuances in the desired intensity and have good resistance to external aggressions such as light, bad weather, washing, permanent undulations, the sweating and rubbing.
- the coloring process must also make it possible to cover white hair, and finally be the least selective possible, that is to say allow to obtain the smallest possible color differences throughout the same keratin fiber, which generally comprises differently sensitized (that is to say damaged) zones from its tip to its root, in order to obtain the most homogeneous coloration of the keratin fibers.
- the coloring compositions must also make it possible to confer good cosmetic properties on keratin fibers, in particular care, softness and / or discipline, have good qualities of use, in particular be easy to apply, while allowing achieve visible (i.e. intense, chromatic), consistent and tenacious color results.
- compositions used in a coloring process must, moreover, have good mixing and application properties on keratin fibers, and in particular good rheological properties so as not to run, when they are applied, on the face, the scalp, or outside the areas that it is proposed to dye, this allows in particular a homogeneous application from the roots to the tips.
- composition according to the invention also has very good stability over time for several weeks.
- coloring compositions which are stable over time for several weeks.
- stable within the meaning of the present invention is meant in particular that physical characteristics such as appearance, pH and / or viscosity vary little or even do not vary over time, in particular that the viscosity of the composition does not change or changes little during storage and / or that the composition does not phase during storage.
- the coloring compositions are stable over time, in particular stable after 1 month at 45 ° C., or even after 2 months at 45 ° C.
- coloring compositions can sometimes be destabilized (phase shifted) by high contents of certain compounds, such as for example oxidation dyes and / or cationic compounds and in particular cationic polymers, and it is therefore desirable that these compositions are stable under these conditions, in particular that they do not phase.
- certain compounds such as for example oxidation dyes and / or cationic compounds and in particular cationic polymers
- composition (A) for dyeing keratin fibers, preferably human keratin fibers such as the hair, comprising:
- scleroglucan gum in a total content greater than or equal to 0.5% by weight, relative to the weight of the composition;
- composition (A) comprising:
- scleroglucan gum in a total content greater than or equal to 0.5% by weight, relative to the weight of the composition;
- ready-to-use composition is understood within the meaning of the invention, any composition intended to be applied immediately to keratin fibers.
- the invention also relates to a process for dyeing keratin fibers, and in particular human keratin fibers such as the hair, implementing the application to the fibers of a coloring composition (A) as defined above, and of an oxidizing composition (B) comprising at least one chemical oxidizing agent, preferably chosen from hydrogen peroxide and / or one or more system (s) generating (s) of hydrogen peroxide, preferably from peroxide hydrogen, the oxidizing composition (B) being mixed with the coloring composition just before use (application to said fibers) (extemporaneously) or at the time of use, or else the coloring and oxidizing compositions being applied sequentially without intermediate rinsing.
- a coloring composition (A) as defined above
- an oxidizing composition (B) comprising at least one chemical oxidizing agent, preferably chosen from hydrogen peroxide and / or one or more system (s) generating (s) of hydrogen peroxide, preferably from peroxide hydrogen, the oxidizing composition (B) being mixed
- a subject of the invention is also a device (or “kit”) with several compartments allowing the use of the composition for coloring keratin fibers, preferably comprising at least two compartments, a first compartment containing the coloring composition (A) as defined above, and the second compartment containing at least one oxidizing composition (B) comprising at least one chemical oxidizing agent, preferably chosen from hydrogen peroxide and / or one or more system (s) generating (s) hydrogen peroxide, preferably from hydrogen peroxide, the compositions of the compartments being intended to be mixed before application, to give the formulation after mixing; in particular the kit can be an aerosol device.
- kit can be an aerosol device.
- composition for coloring or by “coloring composition”
- oxidizing composition comprising at least one chemical oxidizing agent.
- ready-to-use coloring composition or “ready-to-use composition” means a composition resulting from the mixture of a coloring composition and an oxidizing composition.
- the ready-to-use coloring composition can be prepared just before application to said keratin fibers.
- compositions according to the invention thus make it possible to lead to very good dyeing performance of keratin fibers, in particular in terms of rise, intensity, chromaticity and / or selectivity. They also make it possible to obtain compositions having good rheological properties so as not to run, during their application, on the face, the scalp, or outside the areas which it is proposed to dye.
- compositions according to the invention are stable.
- stable within the meaning of the present invention is meant in particular that physical characteristics such as appearance, pH and / or viscosity vary little or even do not vary over time, in particular that the viscosity of the composition does not change or changes little during storage and / or that the composition does not phase during storage.
- compositions according to the invention have the advantage of being stable (do not phase shift) regardless of the pH and in particular with respect to extreme pH (for example at alkaline pH ranging from 9 to 12).
- compositions are preferably stable (do not phase shift) even in the presence of a high content of certain compounds such as, for example, oxidation dyes and / or cationic compounds, such as cationic polymers, as for example in the presence more than 0.5% by weight.
- compositions of the invention are advantageously translucent, which gives them an aesthetic and attractive visual appearance for the consumer, and allow a contribution in terms of qualities of care, softness of the fibers as well as ease of smoothing and of discipline.
- Other characteristics and advantages of the invention will appear more clearly on reading the description and the examples which follow.
- the keratin fibers are preferably human keratin fibers, preferably the hair.
- composition according to the invention has a thickened texture and are in the form of a cream or gel, preferably a gel, preferably it is translucent.
- the composition according to the invention generally exhibits at room temperature a viscosity greater than 50 cps, preferably between 200 and 100,000 cps, more preferably between 500 and 50,000 cps, and even more preferably between 800 to 10,000 cps, better still 1000 at 8000 cps measured at 25 ° C at a rotation speed of 200 rpm using a rheometer such as the rheomat RM 180 equipped with a mobile no.3 or 4, the measurement being carried out after 60 seconds of mobile rotation (time after which the viscosity and speed of rotation of the mobile stabilize.
- composition according to the invention comprises one or more oxidation dyes.
- oxidation dye precursors which can be used in the present invention are generally chosen from oxidation bases, optionally combined with one or more couplers.
- the oxidation bases may preferably be chosen from para-phenylenediamines, bis-phenylalkylenediamines, para- aminophenols, ortho-aminophenols, heterocyclic bases and their addition salts.
- the oxidation base or bases of the invention are chosen from paraphenylenediamines and heterocyclic bases.
- paraphenylenediamines mention may be made, for example, of paraphenylenediamine, paratoluylenediamine, 2-chloro paraphenylenediamine, 2,3-dimethyl paraphenylenediamine, 2,6-dimethyl paraphenylenediamine, 2,6-diethyl paraphenylenediamine, 2,5-dimethyl paraphenylenediamine, N, N- dimethyl paraphenylenediamine, N, N-diethyl paraphenylenediamine, N, N-dipropyl paraphenylenediamine, 4-amino-N, N-diethyl-3-methylaniline, N, N -bis- (-hydroxyethyl) paraphenylenediamine, 4-N, N-bis- (-hydroxyethyl) amino 2-methyl aniline, 4-N, N-bis
- paraphenylenediamine paratoluylenediamine, 2-isopropyl paraphenylenediamine, 2 ⁇ -hydroxyethyl paraphenylenediamine, 2 ⁇ -hydroxyethyloxy paraphenylene diamine, 2,6-dimethyl paraphenylenediamine para-phenylenediamine, 2,3-dimethyl para-phenylenediamine, N, N-bis - ⁇ - hydroxyethyl) para-phenylenediamine, 2-chloro para-phenylenediamine, 2-b-acetylaminoethyloxy para-phenylenediamine, 2-methoxymethyl paraphenylenediamine and their acid addition salts are particularly preferred.
- N, N'-bis- (P-hydroxyethyl) N, N'-bis- (4'-aminophenyl) 1, 3-diamino propanol N , N'-bis- (P-hydroxyethyl) -N, N'-bis- (4'- aminophenyl) ethylenediamine, N, N'-bis- (4-aminophenyl) tetramethylenediamine, N, N'-bis- (-hydroxyethyl) -N, N'-bis- (4-aminophenyl) tetramethylenediamine, N, N'-bis- (4-methyl-aminophenyl) tetramethylenediamine, N, N'-bis- (ethyl) N, N '-bis- (4'- amino, 3' methylphenyl) ethylenediamine, 1, 8 -bis- (2, 5 -
- para-aminophenol there may be mentioned by way of example, para-amino phenol, 4-amino-3-methyl phenol, 4-amino-3-fluoro phenol, 4-amino-3-chlorophenol, 4-amino-3-hydroxymethyl phenol, 4-amino-2-methyl phenol, 4-amino-2-hydroxymethyl phenol, 4-amino-2-methoxymethyl phenol, 4-amino-2-aminomethyl phenol, 4-amino 2- (-hydroxyethyl aminomethyl) phenol, 4-amino-2-fluoro phenol, and their addition salts with an acid.
- para-amino phenol 4-amino-3-methyl phenol, 4-amino-3-fluoro phenol, 4-amino-3-chlorophenol, 4-amino-3-hydroxymethyl phenol, 4-amino-2-methyl phenol, 4-amino-2-hydroxymethyl phenol, 4-amino-2-methoxymethyl phenol, 4-amino-2-aminomethyl phenol, 4-
- ortho-aminophenols there may be mentioned by way of example, 2-amino phenol, 2-amino-5-methyl phenol, 2-amino-6-methyl phenol, 5-acetamido-2-amino phenol , and their addition salts.
- heterocyclic bases there may in particular be pyridine derivatives, pyrimidine derivatives and pyrazole derivatives.
- pyridine derivatives mention may be made of the compounds described for example in patents GB 1 026 978 and GB 1 153 196, such as 2,5 diamino pyridine, 2- (4-methoxyphenyl) amino 3 amino pyridine, 3, 4-diamino pyridine, and their addition salts.
- pyridine oxidation bases useful in the present invention are the 3-amino pyrazolo- [1,5 a] -pyridine oxidation bases or their addition salts described for example in patent application FR 2801308.
- pyrazolo [1,5-a] pyridin-3-ylamine 2-acetylamino pyrazolo- [1,5-a] pyridin-3-ylamine; 2-morpholin-4-yl-pyrazolo [1,5-a] pyridin-3-ylamine; 3-amino-pyrazolo [1,5-a] pyridin-2-carboxylic acid; 2-methoxy-pyrazolo [1,5-a] pyridine-3-ylamino; (3-amino-pyrazolo [1,5-a] pyridine-7-yl) - methanol; 2- (3-amino-pyrazolo [1,5-a] pyridine-5-yl) -ethanol;
- oxidation bases according to the invention are chosen from 3-aminopyrazolo- [1,5 a] -pyridines preferably substituted in position 2 by:
- a heterocycloalkyl group comprising from 5 to 7 members, and from 1 to 3 heteroatoms, cationic or not, optionally substituted by one or more (C 1 -C 6 ) alkyl groups such as di (C 1 -C 4 ) alkylpiperazinium;
- pyrimidine derivatives mention may be made of the compounds described, for example, in patents DE 2359399; JP 88 169571; JP 05-63 124; EP 0770375 or patent application WO 96/15765 such as 2,4,5,6-tetra-aminopyrimidine, 4 hydroxy 2,5,6-triaminopyrimidine, 2 hydroxy 4,5,6-triaminopyrimidine, 2,4 dihydroxy 5,6-diaminopyrimidine 2,5 6 triaminopyrimidine and their addition salts and their tautomeric forms, when there is a tautomeric equilibrium.
- the heterocyclic oxidation bases of the invention are chosen from 4,5-diaminopyrazoles such as 4,5-diamino-1 - (-hydroxyethyl) pyrazole. It is also possible to use 4-5-diamino-1 - (-methoxyethyl) pyrazole.
- a 4,5-diaminopyrazole and even more preferably 4,5-diamino-l - (-hydroxyethyl) -pyrazole and / or one of its salts will be used.
- diamino N, N-dihydropyrazolopyrazolones and in particular those described in application FR-A-2 886 136 such as the following compounds and their addition salts: 2,3-diamino-6 , 7-dihydro- 1 H, 5H-pyrazolo [1,2, ajpyrazol- 1 -one, 2-amino-3-ethylamino-6,7-dihydro- 1 H, 5H- pyrazolo [1, 2-a] pyrazol- 1 -one, 2-amino-3-isopropylamino-6,7-dihydro- l H, 5H-pyrazolo [1, 2-a] pyrazol- 1 -one, 2-amino -3- (pyrrolidin- 1 -yl) -6,7- dihydro- 1 H, 5H-pyrazolo [1, 2-a] pyrazol- 1 -one, 4,5
- heterocyclic bases use will preferably be made of 4,5-diamino-l - (-hydroxyethyl) pyrazole and / or 2,3-diamino-6,7-dihydro- 1 H, 5H-pyrazolo [l, 2- a] pyrazol-l -one and / or a salt thereof.
- the oxidation base or bases used in the context of the invention are generally present in an amount ranging from 0.001 to 10% by weight approximately of the total weight of the coloring composition, preferably ranging from 0.005 to 5%.
- the additional couplers conventionally used for dyeing keratin fibers are preferably chosen from meta-phenylenediamines, meta-aminophenols, meta-diphenols, naphthalene couplers, heterocyclic couplers and also their addition salts.
- the composition comprises at least one oxidation base and at least one coupler.
- addition salts of the oxidation bases and of the couplers which can be used in the context of the invention are in particular chosen from addition salts with an acid such as hydrochlorides, hydrobromides, sulfates, citrates, succinates, tartrates, lactates, tosylates, benzenesulfonates, phosphates and acetates.
- an acid such as hydrochlorides, hydrobromides, sulfates, citrates, succinates, tartrates, lactates, tosylates, benzenesulfonates, phosphates and acetates.
- the coupler (s) when they are present, are generally present in a total amount ranging from 0.001 to 10% by weight approximately of the total weight of the coloring composition, preferably ranging from 0.005 to 5% by weight. weight relative to the total weight of the coloring composition.
- the total content of oxidation dyes in the composition according to the invention is between 0.001 to 20% by weight; preferably between 0.001% and 10% by weight, preferably between 0.01% and 5% by weight, relative to the weight of the composition.
- the composition (A) comprises one or more scleroglucan gums, in a total content greater than or equal to 0.5% by weight relative to the weight of the composition.
- Scleroglucan gums are polysaccharides of microbial origin produced by a fungus of the Sclerotium type, in especially Sclerotium rolfsii. These are polysaccharides made up solely of glucose units.
- Scleroglucan gums can be modified or not. Preferably the scleroglucan gums used in the present invention are unmodified.
- scleroglucan gums which can be used in the present invention are, without limitation, the products sold under the name ACTIGUM CS, in particular ACTIGUM CS 11, by the company SANOFI BIO INDUSTRIES and under the name AMIGUM or AMIGEL by the company ALBAN MULLER INTERNATIONAL.
- scleroglucan gums such as that treated with glyoxal described in French patent application No. 2,633,940, can also be used.
- the scleroglucan gum (s) which can be used according to the invention preferably represent from 0.5 to 10% by weight, more preferably from 0.5 to 5% by weight, and even more preferably from 0.5 to 3% by weight, better from 0.5% to 2% by weight and even more preferably from 0.7 to 1.5% by weight, relative to the total weight of the composition (A).
- the oxidizing composition (B) comprises one or more scleroglucan gums, preferably in a total content greater than or equal to 0.5% by weight relative to the weight of the composition.
- the scleroglucan gum (s) which can be used according to the invention preferably represent from 0.5 to 10% by weight, more preferably from 0.5 to 5% by weight, and even more preferably from 0 , 5 to 3% by weight, even more preferably and even more preferably from 0.5 to 2%, or even from 0.7 to 2% by weight, relative to the total weight of the oxidizing composition (B).
- composition according to the invention comprises one or more cationic polymers.
- cationic polymer designates any polymer containing groups cationic and / or ionizable groups into cationic groups.
- the cationic polymers optionally present in the composition according to the invention can be chosen from all those already known per se as improving the cosmetic properties of the hair, namely in particular those described in patent application EP-A-337 354 and in patents French FR-2 270 846, 2 383 660, 2 598 61 1, 2 470 596 and 2 5 19 863.
- the preferred cationic polymers are chosen from those which contain units comprising primary, secondary, tertiary and / or quaternary amine groups which can either be part of the main polymer chain or be carried by a lateral substituent directly linked thereto.
- the cationic polymers used generally have a number average molecular mass of between 500 and 5.10 6 approximately, and preferably between 10 3 and 3. 10 6 approximately.
- cationic polymers mention may be made more particularly of polymers of the polyamine, polyaminoamide and polyquaternary ammonium type.
- the cationic polymer (s) according to the invention are not associative; in particular does not contain a fatty chain containing from 8 to 30 carbon atoms.
- the cationic polymer (s) are chosen from:
- R3 identical or different, denote a hydrogen atom or a CH3 radical
- A identical or different, represent an alkyl group, linear or branched, from 1 to 6 carbon atoms, preferably 2 or 3 carbon atoms or a hydroxyalkyl group from 1 to 4 carbon atoms;
- R4, R5, R6, identical or different represent an alkyl group having from 1 to 18 carbon atoms or a benzyl radical and preferably an alkyl group having from 1 to 6 carbon atoms;
- Rl and R2 identical or different, represent hydrogen or an alkyl group having from 1 to 6 carbon atoms and preferably methyl or ethyl;
- X denotes an anion derived from a mineral or organic acid such as a methosulfate anion or a halide such as chloride or bromide.
- the polymers of family (1) may also contain one or more units deriving from comonomers which can be chosen from the family of acrylamides, methacrylamides, diacetones, acrylamides, acrylamides and methacrylamides substituted on nitrogen by lower alkyls (C 1 -C4), acrylic or methacrylic acids or their esters, vinyllactams such as vinylpyrrolidone or vinylcaprolactam, vinyl esters .
- comonomers which can be chosen from the family of acrylamides, methacrylamides, diacetones, acrylamides, acrylamides and methacrylamides substituted on nitrogen by lower alkyls (C 1 -C4), acrylic or methacrylic acids or their esters, vinyllactams such as vinylpyrrolidone or vinylcaprolactam, vinyl esters .
- polymers of family (1) are chosen from
- copolymers of acrylamide and methacryloyloxyethyltrimethylammonium chloride described for example in patent application EP-A-080976 and sold under the name BINA QUAT P 100 by the company CIBA GEIGY,
- a crosslinked acrylamide / methacryloyloxyethyltrimethylammonium chloride copolymer (20/80 by weight) may more particularly be used in the form of a dispersion containing 50% by weight of said copolymer in mineral oil.
- This dispersion is marketed under the name of “SALCARE® SC 92” by the company CIBA.
- These dispersions are marketed under the names of “SALCARE® SC 95” and “SALCARE® SC 96” by the company CIBA.
- Cellulose copolymers or cellulose derivatives grafted with a water-soluble quaternary ammonium monomer such as hydroxyalkyl celluloses, such as grafted hydroxymethyl-, hydroxyethyl- or hydroxypropyl celluloses in particular with a salt of methacryloylethyl trimethylammonium, of methacrylmidopropyl trimethylammonium, of dimethyl-diallylammonium.
- guar gums described more particularly in US patents 3,589,578 and 4,031,307 such as guar gums containing cationic groups trialkylammonium.
- Guar gums modified with a salt (eg chloride) of 2,3-epoxypropyl trimethylammonium are used, for example.
- Such products are marketed in particular under the trade names of JAGUAR C 13 S, JAGUAR C 15, JAGUAR C 17 or JAGUAR C 162 by the company RHODIA.
- Water-soluble polyaminoamides prepared in particular by polycondensation of an acidic compound with a polyamine; these polyaminoamides can be crosslinked with an epihalohydrin, a diepoxide, a dianhydride, an unsaturated dianhydride, a bis-unsaturated derivative, a bis-halohydrin, a bis-azetidinium, a bis-haloacyldiamine, a bis-halide of alkyl or also with an oligomer resulting from the reaction of a bifunctional compound reactive with a bis-halohydrin, a bis-azetidinium, a bis-haloacyldiamine, an alkyl bis-halide, d 'an epilhalohydrin, a diepoxide or a bis-unsaturated derivative; the crosslinking agent being used in proportions ranging from 0.025 to 0.35 mol per amine group of the polyaminoamide; these polyaminoamide
- Polyaminoamide derivatives resulting from the condensation of polyalkylene polyamines with polycarboxylic acids followed by alkylation by bifunctional agents Mention may be made, for example, of the adipic acid-diacoylaminohydroxyalkoyldialoylene triamine polymers in which the alkyl radical contains from 1 to 4 carbon atoms and preferably denotes methyl, ethyl, propyl. Such polymers are described in particular in French patent 1,583,363. Among these derivatives, there may be mentioned more particularly the adipic acid / dimethylaminohydroxypropyl / diethylene triamine polymers sold under the name "Cartaretine F, F4 or F8" by the company Sandoz.
- the molar ratio between the polyalkylene polylamine and the dicarboxylic acid being between 0.8: 1 and 1.4: 1; the resulting polyaminoamide being reacted with epichlorohydrin in a molar ratio of epichlorohydrin relative to the secondary amine group of the polyaminoamide of between 0.5: 1 and 1.8: 1.
- Such polymers are described in particular in US patents 3,227,615 and 2,961,347.
- Polymers of this type are in particular marketed under the name "Hercosett 57” by the company Hercules Inc. or else under the name of "PD 170” or “Delsette 101” by the company Hercules in the case of the acid copolymer adipic / epoxypropyl / diethylenetriamine.
- R9 denotes a hydrogen atom or a methyl radical
- R7 and R8 independently of one another preferably denote an alkyl group having from 1 to 4 carbon atoms;
- Y- is an anion such as bromide, chloride, acetate, borate, citrate, tartrate, bisulfate, bisulfite, sulfate, phosphate.
- polymers defined above there may be mentioned more particularly the homopolymer of dimethyldiallylammonium chloride sold under the name "Merquat 100" by the company NALCO (and its low molecular weight average counterparts) whose INCI name is POLYQUATERNIUM -6 and the copolymers of diallyldimethylammonium chloride and of acrylamide marketed under the name "MERQUAT 550", MERQUAT 7SPR whose INCI name is POLYQUATERNIUM-7. Mention may also be made of the copolymers of diallyldimethylammonium chloride and of (meth) acrylic acid known under the name INCI POLYQUATERNIUM-22.
- R10, R11, R12 and R13 identical or different, represent aliphatic, alicyclic or arylaliphatic radicals containing from 1 to 6 carbon atoms or hydroxyalkylaliphatic radicals lower, or R10, Rl l, R12 and R13, together or separately, constitute with the nitrogen atoms to which they are attached heterocycles possibly containing a second heteroatom other than nitrogen or R10, Rl l, R12 and R13 represent a linear or branched C 1 -C 6 alkyl radical substituted by a nitrile, ester, acyl, amide or -CO-O- R14-D or -CO-NH- R14-D group where R14 is an alkylene and D a group quaternary ammonium;
- Al and B l represent polymethylenic groups containing from 2 to 8 carbon atoms which may be linear or branched, saturated or unsaturated, and which may contain, linked to or intercalated in the main chain, one or more aromatic rings, or one or more atoms oxygen, sulfur or sulfoxide, sulfone, disulfide, amino, alkylamino, hydroxyl, quaternary ammonium, ureido, amide or ester groups, and
- X denotes an anion derived from a mineral or organic acid
- A1, R10 and R12 can form with the two nitrogen atoms to which they are attached a piperazine ring; in addition if A l denotes a linear or branched, saturated or unsaturated alkylene or hydroxyalkylene radical, B l can also denote a group - (CH2) n- CO-D-OC- (CH2) n- in which D denotes:
- X is an anion such as chloride or bromide.
- These polymers have a number average molecular weight generally between 1000 and 100,000.
- R10, R11, R12 and R13 identical or different, denote an alkyl or hydroxyalkyl radical having from 1 to 4 carbon atoms approximately, n and p are whole numbers varying from 2 to 8 approximately and, X- is a anion derived from a mineral or organic acid.
- MEXOMERE PO sold by the company CHIMEX (Hexadimethrine Chloride).
- D may be zero or may represent a group - (CH2) r - CO- in which r denotes a number equal to 4 or 7, X- is an anion.
- Such polymers can be prepared according to the methods described in the US patents. A. No. 4,157,388, 4,702,906, 4,719,282. They are described in particular in patent application EP-A-122 324. Among them, there may be mentioned, for example, the products "Mirapol A 15", “Mirapol AD 1", “Mirapol AZ 1" and “Mirapol 175" sold by the company Miranol.
- Quaternary polymers of vinylpyrrolidone and of vinylimidazole such as for example the products marketed under the names Luviquat FC 905, FC 550 and FC 370 by the company B.
- These polymers may also include other monomers such as diallyldialkylammonium halides. Mention may be made, in particular, of the product sold under the name Luviquat Sensation by the company B. A. S. F.
- Polyamines such as Polyquart H sold by HENKEL, referenced under the name of “POLYETHYLENEGLYCOL (15) TALLOW POLY AMINE” in the CTFA dictionary, or polyamines of oxyethylenated coconut (15 OE)
- cationic polymers which can be used in the context of the invention are polyalkyleneimines, in particular polyethyleneimines, polymers containing vinylpyridine or vinylpyridinium units, condensates of polyamines and epichlorohydrin, quaternary polyuretylenes and chitin derivatives.
- cationic polymers capable of being used in the context of the present invention, polymers of families (1), (9) and (10) and their mixtures are preferred.
- the cationic polymer (s) are chosen from families (9) and / or (10), preferably mixtures thereof.
- the polymers of family (1) are chosen from copolymers comprising a monomer of family (1) further containing one or more units derived from comonomers which can be chosen from the family of acrylamides, methacrylamides, diacetones-acrylamides, acrylamides and methacrylamides substituted on nitrogen by lower alkyl groups (C 1 -C4), groups derived from acrylic or methacrylic acids or their esters, vinyllactams such as vinylpyrrolidone or vinylcaprolactam, of vinyl esters.
- comonomers which can be chosen from the family of acrylamides, methacrylamides, diacetones-acrylamides, acrylamides and methacrylamides substituted on nitrogen by lower alkyl groups (C 1 -C4), groups derived from acrylic or methacrylic acids or their esters, vinyllactams such as vinylpyrrolidone or vinylcaprolactam, of vinyl esters.
- they are chosen from vinylpyrrolidone / acrylate copolymers or dialkyl-aminoalkyl methacrylate, quaternized or not, preferably such as the products whose INCI name is Polyquaternium-1 1, and / or whose INCI name is VP / dimethylaminoethylmethacrylate copolymer, preferably the compound whose INCI name is Polyquaternium 1 1.
- the polymers of family (9) are chosen from homopolymers of dialkyl diallyl ammonium, preferably homopolymers of dimethyldiallylammonium, preferably from the homopolymer of halide (in particular chloride) of dimethyldiallylammonium, in particular sold under the name "Merquat 100" by the company NALCO (and its counterparts of low molecular weight average weight) whose INCI designation is Polyquaternium-6 and the halides (in particular chloride) of diallyldimethylammonium and acrylamide in particular marketed under the name "MERQUAT 550 "whose INCI appointment is Polyquaternium- 7.
- the family polymers (10) are chosen from the family polymers (10) consisting of recurring units corresponding to the formula:
- R1, R2, R3 and R4, identical or different denote an alkyl or hydroxyalkyl radical having from 1 to 4 carbon atoms, n and p are whole numbers varying from 2 to 20, and X- is an anion derived from 'a mineral or organic acid;
- the cationic polymer (s) are chosen from vinylpyrrolidone / acrylate or methacrylate of dialkyl-amino-'alkyl quaternized or not, preferably such as the products whose name INCI is Polyquaternium-1 1,, Hexadimethrine chloride and homopolymers or copolymers of dimethyldiallylammonium halides (Polyquaternium-6 and Polyquaternium-7).
- the composition comprises one or more polymers chosen from homopolymers or copolymers of dimethyldiallylammonium halides (Polyquaternium-6 and Polyquaternium-7) and Hexadimethrine chloride.
- the total content of cationic polymer (s) in the composition (A) according to the invention varies from 0.1 to 12% by weight relative to the total weight of the composition, preferably from 0.1 to 10% by weight, and more preferably from 0.4 to 7% by weight, relative to the total weight of the composition, preferably from 0.5 to 6% by weight.
- the coloring composition (A) according to the invention may advantageously comprise one or more carboxylic acids, and / or their addition salts and / or their solvates, said one or more acids carboxylic being aliphatic compounds, comprising from 2 to 10 carbon atoms, and preferably comprising at least two carboxylic groups.
- they are chosen from aliphatic dicarboxylic and / or tricarboxylic acids comprising from 2 to 10 carbon atoms, preferably from 2 to 8 carbon atoms, better still from 2 to 6 carbon atoms.
- carboxylic acid (s) is / are saturated or unsaturated, substituted or unsubstituted.
- the carboxylic acids can be chosen from oxalic acid, malonic acid, malic acid, glutaric acid, citraconic acid, citric acid, maleic acid, succinic acid, adipic acid, tartaric acid, fumaric acid, and mixtures thereof.
- the carboxylic acid (s) comprise at least two carboxylic groups and are chosen from malonic acid, citric acid, maleic acid, glutaric acid, succinic acid and their mixtures; preferably selected from malonic acid, citric acid, maleic acid, and mixtures thereof.
- the carboxylic acid is citric acid.
- the total content of carboxylic acid (s) and / or their addition salts and / or their solvates preferably ranges from 0.1% to 20% by weight, relative to the total weight of the composition (A) .
- the total content of carboxylic acid (s) varies from 0.1 to 20, preferably from 0.5% to 10% by weight, better still from 1% to 7% by weight, relative to the total weight of the composition, better still from 2 to 5% by weight relative to the total weight of the composition (A).
- the composition according to the invention comprises one or more alkaline agents.
- the alkaline agent (s) also called basifying agents
- the alkaline agent (s) are chosen from the mineral alkaline agent (s), preferably chosen from ammonia, also called ammonium hydroxide (or ammonia precursors such as ammonium salts, for example ammonium halides and in particular ammonium chloride), silicates, phosphates, carbonates or bicarbonates of alkali or alkali metals - earthy, such as metasilicates of alkali or alkaline earth metals, sodium or potassium carbonates or bicarbonates, sodium or potassium hydroxides, or mixtures thereof.
- ammonia also called ammonium hydroxide (or ammonia precursors such as ammonium salts, for example ammonium halides and in particular ammonium chloride)
- silicates phosphates, carbonates or bicarbonates of alkali or alkali metals - earthy, such as metasilicates of alkali or alkaline earth metals, sodium or potassium carbonates or bicarbonates, sodium or potassium hydroxides, or mixtures
- the alkaline agents are chosen from ammonia (or ammonia precursor agents such as ammonium salts, for example ammonium halides and in particular ammonium chloride) and / or metasilicates of alkali or alkaline earth metals.
- ammonia or ammonia precursor agents such as ammonium salts, for example ammonium halides and in particular ammonium chloride
- metasilicates of alkali or alkaline earth metals are chosen from ammonia (or ammonia precursor agents such as ammonium salts, for example ammonium halides and in particular ammonium chloride) and / or metasilicates of alkali or alkaline earth metals.
- the alkaline agent (s) are chosen from alkanolamines and / or amino acids.
- the alkaline agent (s) are chosen from alkanolamines.
- alkanolamine an organic amine comprising a primary, secondary or tertiary amine function, and one or more alkyl groups, linear or branched, in Ci to Cs carrying one or more hydroxy radicals.
- organic amines selected from alkanolamines such as mono-, di- or tri-alkanolamine having one to three hydroxy radicals, identical or different, C l -C 4.
- the compounds of this type are preferably chosen from monoethanolamine (MEA), diethanolamine, triethanolamine, monoisopropanolamine, diisopropanolamine, N, N-dimethylethanolamine, 2-amino-2-methyl-1-propanol, triisopropanol-amine, 2-amino-2-methyl- 1, 3-propanediol, 3-amino- 1, 2-propanediol, 3-dimethylamino- l, 2-propanedio l, tris-hydroxymethylamino-methane, and their mixtures, preferably monoethanolamine (MEA).
- MEA monoethanolamine
- the alkaline agent (s) are chosen from amino acids.
- the amino acids are chosen from basic amino acids, in particular comprising an additional amine function possibly included in a cycle or in a ureido function.
- rhistidine By way of example, mention may be made of rhistidine, lysine, arginine, ornithine, citrulline.
- the organic amine can also be chosen from organic amines of heterocyclic type. Mention may in particular be made, in addition to the histidine already mentioned in the amino acids, pyridine, piperidine, imidazole, triazole, tetrazole, benzimidazole.
- the alkaline agent (s) present in the composition according to the invention are chosen from ammonia, alkanolamines, and / or amino acids in neutral or ionic form, in particular basic amino acids, such as l arginine, metasilicates of alkali or alkaline earth metals.
- composition according to the invention comprises one or more alkaline agents.
- composition according to the invention comprises:
- alkaline mineral agent preferably chosen from ammonia and / or metasilicates of alkali or alkaline earth metals, preferably ammonia;
- organic alkaline agents preferably chosen from alkanolamines and / or amino acids, preferably from alkanolamines, preferably monoethanolamine.
- the composition according to the invention preferably comprises one or more alkaline agent (s), preferably it comprises one or more mineral alkaline agent (s) and one or more alkaline agent (s) ( s) organic chosen from alkanolamines.
- the composition comprises ammonia (ammonium hydroxide)
- its content preferably ranges from 0.1 to 10% by weight, more preferably from 0.5 to 8% by weight, better still from 1 to 6% by weight relative to the total weight of the composition.
- composition comprises one or more alkanolamines
- their total content preferably ranges from 0.5 to 10% by weight, more preferably from 1 to 9% by weight, better still from 2 to 8% by weight relative to the total weight of the composition.
- the composition according to the invention comprises one or more alkaline agents, and they are present in a total content ranging from 1 to 20% by weight, more preferably from 3 to 18% by weight, better still from 5 to 16% by weight. weight relative to the total weight of the composition.
- composition according to the invention can also comprise one or more associative polymers different from the cationic polymers previously described.
- Said associative polymers can be chosen from nonionic, anionic and amphoteric associative polymers, preferably from nonionic associative polymers.
- the associative polymers according to the invention are polymers comprising at least one fatty chain in Cs - C 30 and the molecules of which are capable, in the formulation medium, of associating with each other or with molecules of other compounds.
- the fatty chain contains from 10 to 30 carbon atoms.
- amphiphilic polymers that is to say polymers comprising one or more hydrophilic parts which make them soluble in water and one or more hydrophobic zones (comprising at least one fatty chain) by which polymers interact and collect with each other or with other molecules.
- the associative polymers which can be used in the composition according to the invention are preferably chosen from nonionic associative polymers.
- the associative polymer (s) is / are chosen from: - (1) celluloses modified by groups comprising at least one fatty chain;
- hydroxyethylcelluloses modified by groups comprising at least one fatty chain such as alkyl, arylalkyl, alkylaryl groups, or their mixtures, and in which the alkyl groups are preferably Cs-C 2 2, preferably such as cetylhydroxyethyl cellulose marketed in particular under the reference NATROSOL PLUS GRADE 330 CS (Ci 6 alkyls) sold by the company Ashland, or the product Polysurf 67CS sold by the company Ashland,
- polyalkylene glycol alkyl phenol ether groups such as the product AMERCELL POLYMER HM- 1500 (polyethylene glycol (15) nonyl phenol ether) sold by the company AMERCHOL
- hydroxypropyl guars modified with groups comprising at least one fatty chain such as the product ESAFLOR HM 22 (C22 alkyl chain) sold by the company Lamberti, and the products 18 RE210- (alkyl chain 4) and RE205- 1 (C20 alkyl chain) sold by the company RHODIA.
- the associative polymer or polymers are nonionic, and preferably chosen from celluloses modified by groups comprising at least one fatty chain.
- the nonionic associative polymer or polymers are chosen from hydroxyethylcelluloses modified by groups comprising at least one fatty chain such as alkyl, arylalkyl, alkylaryl groups, or their mixtures, and in which the alkyl groups are preferably C8 -C22, and hydroxyethylcelluloses modified with polyalkylene glycol ether groups of alkyl phenol, and their mixtures, preferably cetylhydroxyethylcellulose.
- the associative polymer or polymers are present in the composition in a total weight content preferably between 0.01 and 10%, and even more preferably between 0.05 and 5% of the total weight of the composition, better between 0, 1 and 2% by weight relative to the total weight of the composition.
- the composition according to the present invention also comprises one or more surfactants, these can be chosen from anionic surfactants, amphoteric or zwitterionic surfactants, nonionic surfactants and cationic surfactants, and their mixtures, preferably from nonionic surfactants, cationic surfactants and mixtures thereof.
- surfactants these can be chosen from anionic surfactants, amphoteric or zwitterionic surfactants, nonionic surfactants and cationic surfactants, and their mixtures, preferably from nonionic surfactants, cationic surfactants and mixtures thereof.
- anionic surfactant is understood to mean a surfactant comprising only anionic groups as ionic or ionizable groups. These anionic groups are preferably chosen from the groups C0 2 H, C0 2 , SO3H, SO3, OSO3H, OSO3-, H 2 P0 3 , HPO3-, PO3 2 -, H 2 P0 2 , HP0 2 , P0 2 2 , POH and PO ⁇
- the composition according to the invention comprises one or more nonionic surfactants.
- nonionic surfactants which can be used according to the invention can be chosen from:
- polyethoxylated fatty amides preferably having from 2 to 30 ethylene oxide units, polyglycerolated fatty amides comprising on average from 1 to 5 glycerol groups and in particular from 1 to 5 to 4;
- - fatty acid esters of sucrose - esters of polyoxyalkylenated fatty acids, preferably polyoxyethylenated having from 2 to 150 moles of ethylene oxide including oxyethylenated vegetable oils;
- amine oxides such as the oxides of alkyl (Ci ClO 4) amines or oxides of N- (acyl Cio-Ci 4) - aminopropyl morpholine;
- C 8 / Ci 6 alkyls are used (poly) glycoside 1, 4, in particular in 53% aqueous solution, such as those sold by COGNIS under the reference PLANTACARE® 818 UP.
- nonionic surfactants are chosen from:
- - oxyethylenated fatty alcohols comprising at least one Cs to C 4 o alkyl chain, in particular C8-C20, even better in Cio-Ci s, saturated or not, linear or branched, and comprising from 1 to 100 moles of ethylene oxide, preferably from 2 to 50, more particularly from 2 to 40 moles, or even from 3 to 20 moles of ethylene oxide; and
- the composition according to the invention comprises one or more non-surfactants ionic, preferably chosen from alkyl (poly) glycosides.
- the composition according to the invention comprises one or more surfactants selected from (C6-C2 alkyl 4) (poly) glycosides, more preferably from (C 8 -C 8) (poly) glycosides, preferably from C 8 / Ci 6 alkyl - (poly) glucosides, preferably of type 1, 4, and preferably chosen from decylglucosides and / or caprylyl / capryl glucosides and / or cocoglucosides.
- the surfactant (s) are non-ionic, preferably chosen from (C 6 -C 2 alkyl) polyglycosides.
- the composition according to the invention comprises at least one or more cationic surfactants.
- the surfactant (s) are chosen from the salts of primary, secondary or tertiary fatty amines, optionally polyoxyalkylenated, quaternary ammonium salts, and their mixtures.
- tetraalkylammonium chlorides are preferred, such as, for example, dialkyldimethylammonium or alkyltrimethylammonium chlorides in which the alkyl group contains approximately from 12 to 22 carbon atoms, in particular the behenyltrimethylammonium chlorides, distearldimethylammonium, cetyltrimethylammonium, benzyldimethylstearylammonium or, on the other hand, distearoylethylhydroxyethylmethylammonium methosulfate, dipalmitoylethylhydroxyethylammonium methosulfate, or methosulfurylmethylhydroxyethylammonium (myristylacetate) -ammonium sold under the name CERAPHYL® 70 by the company VAN DYK.
- Such compounds are for example the Finquat CT-P offered by the company FINETEX (Quaternium 89), the Finquat CT offered by the company FINETEX (Quaternium 75).
- acyl groups preferably have 14 to 18 carbon atoms and more particularly come from a vegetable oil such as palm or sunflower oil. When the compound contains several acyl groups, these can be the same or different.
- Such compounds are for example sold under the names DEHYQUART® by the company HENKEL, STEPANQUAT® by the company STEPAN, NOXAMIUM® by the company CECA, REWOQUAT® WE 18 by the company REWO-WITCO.
- composition according to the invention can contain, for example, a mixture of mono-, di- and triester salts of quaternary ammonium with a majority by weight of diester salts.
- ammonium salts containing at least one ester function described in patents US-A-4,874,554 and US-A-4,137,180.
- the ammonium salts containing at least one ester function contain two ester functions.
- the cationic surfactant (s) are chosen from cetyltrimethylammonium salts, behenyltrimethylammonium salts, dipalmitoylethylhydroxy ethylmethylammonium salts, and their mixtures, and more particularly behenyltrimethylammonium chloride, cetyltrimethylammonium chloride, methosethylethylammonium hydroxide mixtures.
- the composition preferably comprises one or more surfactants in a total content ranging from 0.01 to 20% by weight, more preferably from 0.05 to 10% by weight, better still from 0.1 to 5% by weight, relative to the total weight of the composition.
- the composition preferably comprises one or more nonionic surfactants in a total content ranging from 0.01 to 10% by weight, more preferably from 0.05 to 5% by weight, better still from 0.1 to 3% by weight , based on the total weight of the composition
- the composition preferably comprises one or more cationic surfactants in a total content ranging from 0.01 to 10% by weight, more preferably from 0.05 to 5% by weight, better still from 0.1 to 3% by weight, per relative to the total weight of the composition.
- the surfactant (s) are chosen from cationic or nonionic surfactants, and their mixtures, preferably cationic.
- the composition according to the invention comprises at least one or more cationic surfactants and one or more nonionic surfactants.
- the cosmetically acceptable medium suitable for dyeing keratin fibers also called dye "support” generally comprises water or a mixture of water and at least one organic solvent to dissolve the compounds which would not be sufficiently soluble. in water.
- the organic solvents are chosen from monoalcohols or diols, linear or branched, preferably saturated, comprising from 2 to 10 carbon atoms, such as ethyl alcohol, isopropyl alcohol, hexylene glycol (2- methyl 2,4-pentanediol), neopentylglycol and 3-methyl- 1,5-pentanediol; glycerol; aromatic alcohols such as benzyl alcohol, phenylethyl alcohol; glycols or glycol ethers such as, for example, monomethyl, monoethyl and monobutyl ethers of ethylene glycol, propylene glycol or its ethers such as, for example, propylene glycol monomethyl ether, butylene glycol, dipropylene glycol; as well as the alkyl ethers of diethylene glycol, in particular Ci-C 4 , such as for example, the monoethyl ether or the monobutyl ether of di
- compositions used according to the invention generally comprise water or a mixture of water and one or more organic solvents or a mixture of organic solvents.
- composition according to the invention preferably comprises water.
- the water content varies from 5 to 95% by weight, more preferably from 10 to 90% by weight, better still from 20 to 80% by weight, relative to the total weight of the composition.
- the pH of the composition according to the invention generally varies from 1 to 12.
- the pH of the composition (A) according to the invention is basic.
- basic pH within the meaning of the present invention, is meant a pH greater than 7.
- the pH of the composition (A) according to the invention is greater than 8, and particularly ranges from 8.5 to 12.
- the pH of the composition is between 9 and 12.
- the cosmetically acceptable medium can be adjusted to the desired value by means of acidifying or basifying agents usually used in dyeing keratin fibers or even using conventional buffer systems.
- acidifying agents there may be mentioned, by way of example, mineral acids such as for example hydrochloric acid, (ortho) phosphoric acid, boric acid, nitric acid, sulfuric acid or organic acids such as for example the compounds comprising at least one sulfonic acid function, a phosphonic acid function or a phosphoric acid function, or the compounds with a carboxylic acid function such as those described above.
- mineral acids such as for example hydrochloric acid, (ortho) phosphoric acid, boric acid, nitric acid, sulfuric acid or organic acids
- organic acids such as for example the compounds comprising at least one sulfonic acid function, a phosphonic acid function or a phosphoric acid function, or the compounds with a carboxylic acid function such as those described above.
- composition according to the invention may also contain various additives conventionally used in compositions for coloring the hair, such as mineral thickening agents, and in particular fillers such as clays, talc; organic thickening agents other than scleroglucan gums, antioxidants; penetration agents; sequestering agents; perfumes ; dispersing agents; film-forming agents; ceramides; preservatives; opacifying agents, fatty substances and / or additional direct dyes.
- mineral thickening agents such as clays, talc; organic thickening agents other than scleroglucan gums, antioxidants; penetration agents; sequestering agents; perfumes ; dispersing agents; film-forming agents; ceramides; preservatives; opacifying agents, fatty substances and / or additional direct dyes.
- the above additives are generally present in an amount for each of them of between 0.01 and 40% by weight relative to the weight of the composition, preferably between 0.1 and 20% by weight relative to the weight of the composition.
- Another object of the invention is a coloring process using a coloring composition (A) as described above, with an oxidizing composition (B) comprising one or more chemical oxidizing agents.
- the invention also relates to a process for dyeing keratin fibers, and in particular human keratin fibers such as the hair, implementing the application to the fibers of a coloring composition (A) as defined above, and an oxidizing composition (B) comprising at least one chemical oxidizing agent, preferably chosen from hydrogen peroxide and / or one or more system (s) generating (s) of hydrogen peroxide, preferably from hydrogen peroxide, the oxidizing composition (B) being mixed with the coloring composition (A) just before use (application to said fibers) (extemporaneously) or at the time of use, or else the coloring and oxidizing compositions being applied sequentially without intermediate rinsing.
- Composition B comprising at least one chemical oxidizing agent, preferably chosen from hydrogen peroxide and / or one or more system (s) generating (s) of hydrogen peroxide, preferably from hydrogen peroxide, the oxidizing composition (B) being mixed with the coloring composition (A) just before use (application to said fiber
- the oxidizing composition (B) used with the coloring composition (A) according to the invention contains one or more chemical oxidizing agent (s), preferably chosen from hydrogen peroxide and / or one or more hydrogen peroxide generating system (s).
- chemical oxidizing agent is meant an oxidizing agent other than air oxygen.
- the chemical oxidizing agent (s) are chosen from hydrogen peroxide, peroxygenated salts such as, for example, persulfates, perborates, peracids and their precursors, alkali or alkaline earth metal percarbonates such as hydrogen peroxide.
- alkali metal bromates or ferricyanides solid chemical oxidizing agents generating hydrogen peroxide such as urea peroxide and polymer complexes which can release hydrogen peroxide, in particular those comprising a vinyl heterocyclic monomer such as polyvinylpyrrolidone complexes / LLCL in particular in the form of powders; oxidases producing hydrogen peroxide in the presence of a suitable substrate (e.g. glucose in the case of glucose oxidase or uric acid with uricase).
- a suitable substrate e.g. glucose in the case of glucose oxidase or uric acid with uricase.
- the chemical oxidizing agent (s) are chosen from hydrogen peroxide, urea peroxide, bromates or ferricyanides of alkali metals, peroxygenated salts, and mixtures of these compounds,
- the chemical oxidizing agent is hydrogen peroxide.
- the chemical oxidizing agent (s) represent from 0.05 to 40% by weight, preferably from 0.5 to 30% by weight, more preferably from 1 to 20% by weight, and better still from 1.5 to 15% by weight relative to the total weight of the oxidizing composition (B).
- the oxidizing composition (B) does not contain peroxygenated salts.
- the oxidizing composition (B) comprises one or more scleroglucan gums, preferably in a total content greater than or equal to 0.5% by weight relative to the weight of the composition.
- the scleroglucan gum (s) which can be used according to the invention preferably represent from 0.5 to 10% by weight, more preferably from 0.5 to 5% by weight, and even more preferably from 0 , 5 to 3% by weight, or even 0.7 to 2% by weight, relative to the total weight of the oxidizing composition (B).
- the oxidizing composition (B) can also contain various additional compounds or various adjuvants conventionally used in compositions for coloring the hair, in particular as defined above.
- the oxidizing composition (B) is generally an aqueous composition.
- aqueous composition means a composition comprising more than 20% by weight of water, preferably more than 30% by weight of water, and even more advantageously more than 40% by weight of 'water.
- the oxidizing composition (B) usually comprises water which generally represents from 10 to 98% by weight, preferably from 20 to 96% by weight, preferably from 50 to 95% by weight, relative to the weight total of the composition.
- This oxidizing composition (B) can also comprise one or more water-soluble organic solvents as described above. It can also include one or more acidifying agents.
- composition (B) is less than 7.
- the pH of the composition (B) of the invention is advantageously between 1 and 7, preferably between 1 and 4, and more preferably from 1.5 to 3.5.
- the oxidizing composition (B) is in various forms, such as, for example, a solution, an emulsion or a gel.
- the method of the invention can be implemented by applying the coloring composition (A) as defined above and the oxidizing composition (B) successively and without intermediate rinsing, the order being indifferent.
- a ready-to-use composition obtained by extemporaneous mixing, at the time of use, of the coloring composition (A) as defined above and of the composition is applied to the keratin materials, dry or wet. oxidizing (B).
- the weight ratio R of the quantities of (A) / (B) varies from 0.1 to 10, preferably from 0.2 to 2, better still from 0.3 to 1.
- the application of the ready-to-use composition to the keratin materials is left in place for a duration, in general, of the order of 1 minute to 1 hour, preferably from 5 minutes to 30 minutes.
- the temperature during the process is conventionally between room temperature (between 15 and 25 ° C) and 80 ° C, preferably between room temperature and 60 ° C.
- the keratin materials are optionally rinsed with water, possibly undergo a washing followed by a rinsing with water, before being dried or left to dry.
- the keratin fibers are human keratin fibers, preferably human hair.
- the invention also relates to and a ready-to-use coloring composition for keratin fibers, in particular human keratin fibers, such as the hair, obtained by extemporaneous mixing, at the time of use of a composition (A ) including:
- one or more scleroglucan gums in a total content greater than or equal to 0.5% by weight, relative to the weight of the composition
- composition (B) comprising
- one or more chemical oxidizing agent s.
- extemporaneous is meant in particular less than 30 minutes, preferably less than 15 minutes before application to the keratin fibers, preferably less than 5 minutes. In particular, the mixture is applied immediately after its preparation.
- the chemical oxidizing agent (s) preferably represent a total content varying from 0.1 to 20% by weight, preferably from 0.5 to 15% by weight, or even more preferably from 1 to 10% by weight, relative to the total weight of the ready-to-use composition.
- the invention relates to a device with several compartments comprising in a first compartment a coloring composition (A) as described above, and in a second, an oxidizing composition (B) comprising one or more oxidizing agents, these compositions having been described previously .
- the invention also has for its object and a device (or “kit”) with several compartments allowing the implementation of the composition for coloring keratin fibers, preferably comprising at least two compartments, a first compartment containing the composition coloring agent (A) as defined above, and the second compartment containing at least one oxidizing composition (B) comprising at least one chemical oxidizing agent, preferably chosen from hydrogen peroxide and / or one or more generating system (s) (s) hydrogen peroxide, preferably hydrogen peroxide, the compositions of the compartments being intended to be mixed before application, to give the formulation after mixing; in particular the kit can be an aerosol device.
- a device or “kit” with several compartments allowing the implementation of the composition for coloring keratin fibers, preferably comprising at least two compartments, a first compartment containing the composition coloring agent (A) as defined above, and the second compartment containing at least one oxidizing composition (B) comprising at least one chemical oxidizing agent, preferably chosen from hydrogen peroxide and / or
- the coloration of the keratin fibers obtained in these examples can be advantageously evaluated in the CIE L * a * b * system, by means of a Datacolor Spectraflash SF600X spectrocolorimeter.
- L * a * b * system the three parameters respectively designate the intensity of the color (L *), a * indicates the green / red color axis and b * the blue / yellow color axis.
- L * the lighter the color.
- a * the redder the color
- the higher the value of b * the more yellow the color.
- the parameters L *, a * and b * represent the values measured on the locks of hair after coloring and the parameters Lo *, ao * and bo * represent the values measured on the locks of untreated hair.
- DE * the higher the value of DE *, the better the coloration of the keratin fibers.
- compositions were prepared from the following ingredients in the following proportions indicated in grams of active material:
- the stability of the coloring compositions was evaluated by observing the compositions at T0 (immediately after preparation of the composition) and then after 2 months of storage at 45 ° C.
- composition Al according to the invention is homogeneous and forms a translucent gel at T0. After 2 months at 45 ° the composition Al according to the invention is stable; it is homogeneous and translucent. Comparative compositions C l, C2 and C3 in which the scleroglucan gum has been replaced weight for weight by another thickening agent of the polysaccharide type are not stable. Indeed, they are liquid and are not homogeneous, from T0 there is a phase shift of these compositions.
- composition was prepared from the following ingredients in the following proportions indicated in grams:
- the stability of the coloring composition was evaluated by observing it at T0 then after 48 hours at room temperature (25 ° C), then after 2 months of storage at 45 ° C.
- composition A2 according to the invention is homogeneous and forms a translucent gel at T0. After 2 months at 45 °, composition A2 according to the invention is stable and in the form of a gel; it is homogeneous and translucent.
- Composition A2 of the example was mixed with 1 time its weight of oxidant 20 volumes (6 g% ai in H2O2); the mixture thus obtained was applied to locks of natural hair containing 90% white BN,
- the bath ratio "mixture / wick” is respectively 10/1
- the color of the locks was evaluated in the CIE L * a * b * system using a Datacolor Spectraflash SF600X spectrocolorimeter.
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Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US17/252,870 US11291617B2 (en) | 2018-06-20 | 2019-06-20 | Hair dyeing composition comprising an oxidation dye, a scleroglucan gum and a cationic polymer |
EP19732628.3A EP3810287A1 (fr) | 2018-06-20 | 2019-06-20 | Composition de coloration capillaire comprenant un colorant d'oxydation, une gomme de scléroglucane et un polymère cationique |
CN201980040728.8A CN112312972A (zh) | 2018-06-20 | 2019-06-20 | 包含氧化染料、硬葡聚糖胶及阳离子聚合物的头发染色组合物 |
BR112020025648-0A BR112020025648B1 (pt) | 2018-06-20 | 2019-06-20 | Composição pronta a usar para a coloração, processo de coloração de fibras queratínicas e dispositivo |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1855433 | 2018-06-20 | ||
FR1855433A FR3082738B1 (fr) | 2018-06-20 | 2018-06-20 | Composition de coloration capillaire comprenant un colorant d’oxydation, une gomme de scleroglucane et un polymere cationique. |
Publications (1)
Publication Number | Publication Date |
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WO2019243511A1 true WO2019243511A1 (fr) | 2019-12-26 |
Family
ID=64049326
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/EP2019/066368 WO2019243511A1 (fr) | 2018-06-20 | 2019-06-20 | Composition de coloration capillaire comprenant un colorant d'oxydation, une gomme de scléroglucane et un polymère cationique |
Country Status (5)
Country | Link |
---|---|
US (1) | US11291617B2 (fr) |
EP (1) | EP3810287A1 (fr) |
CN (1) | CN112312972A (fr) |
FR (1) | FR3082738B1 (fr) |
WO (1) | WO2019243511A1 (fr) |
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US11266589B2 (en) | 2018-06-20 | 2022-03-08 | L'oreal | Hair dyeing composition comprising an oxidation dye, a scleroglucan gum, and an alkylpolyglycoside |
US11273115B2 (en) | 2018-06-20 | 2022-03-15 | L'oreal | Hair dyeing method using a dye composition and an oxidizing composition, said compositions comprising a scleroglucan gum |
US11278486B2 (en) | 2018-06-20 | 2022-03-22 | L'oreal | Hair dyeing composition comprising an oxidation dye, a scleroglucan gum and an associative cellulose polymer |
US11278487B2 (en) | 2018-06-20 | 2022-03-22 | L'oreal | Hair dyeing composition comprising an oxidation dye, a scleroglucan gum and an alkaline agent such as an amino acid |
US11413225B2 (en) | 2018-06-20 | 2022-08-16 | L'oreal | Hair dyeing composition comprising an oxidation dye, a scleroglucan gum, an alcanolamine and a mineral alkaline agent |
US20230096297A1 (en) * | 2021-08-13 | 2023-03-30 | L'oreal | Hair treatment compositions providing brightening and shine |
US11701311B2 (en) | 2018-06-20 | 2023-07-18 | L'oreal | Device for dispensing a hair dyeing product using a dye composition and an oxidizing composition comprising a scleroglucan gum |
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US9789034B2 (en) | 2012-04-24 | 2017-10-17 | L'oreal | Dyeing process using a mixture obtained from an aerosol device comprising a liquid fatty, alcohol and surfactants |
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FR3029409B1 (fr) * | 2014-12-08 | 2016-12-09 | Oreal | Procede de coloration capillaire mettant en œuvre au moins un colorant, un sel organique de titane, et un polysaccharide non cellulosique |
FR3082742B1 (fr) | 2018-06-20 | 2020-05-29 | L'oreal | Composition de coloration capillaire comprenant un colorant d’oxydation, une gomme de scleroglucane, et un alkylpolyglycoside. |
FR3082740B1 (fr) | 2018-06-20 | 2020-05-29 | L'oreal | Composition de coloration capillaire comprenant un colorant d’oxydation, une gomme de scleroglucane, une alcalnolamine et un agent alcalin mineral. |
FR3082736B1 (fr) | 2018-06-20 | 2020-05-29 | L'oreal | Composition de coloration capillaire comprenant un colorant d’oxydation, une gomme de scleroglucane et agent alcalin de type acide amine. |
FR3082735B1 (fr) | 2018-06-20 | 2022-03-11 | Oreal | Composition de coloration capillaire comprenant un colorant d’oxydation, une gomme de scleroglucane et un polymere associatif. |
FR3082739B1 (fr) | 2018-06-20 | 2020-05-29 | L'oreal | Procede de coloration capillaire mettant en œuvre une composition colorante et une composition oxydante, lesdites compositions comprenant une gomme de scleroglucane. |
FR3082710B1 (fr) | 2018-06-20 | 2021-11-26 | Oreal | Dispositif de distribution d’un produit de coloration capillaire mettant en œuvre une composition colorante et une composition oxydante comprenant une gomme de scleroglucane. |
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2019
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- 2019-06-20 WO PCT/EP2019/066368 patent/WO2019243511A1/fr unknown
- 2019-06-20 US US17/252,870 patent/US11291617B2/en active Active
- 2019-06-20 EP EP19732628.3A patent/EP3810287A1/fr active Pending
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11266589B2 (en) | 2018-06-20 | 2022-03-08 | L'oreal | Hair dyeing composition comprising an oxidation dye, a scleroglucan gum, and an alkylpolyglycoside |
US11273115B2 (en) | 2018-06-20 | 2022-03-15 | L'oreal | Hair dyeing method using a dye composition and an oxidizing composition, said compositions comprising a scleroglucan gum |
US11278486B2 (en) | 2018-06-20 | 2022-03-22 | L'oreal | Hair dyeing composition comprising an oxidation dye, a scleroglucan gum and an associative cellulose polymer |
US11278487B2 (en) | 2018-06-20 | 2022-03-22 | L'oreal | Hair dyeing composition comprising an oxidation dye, a scleroglucan gum and an alkaline agent such as an amino acid |
US11413225B2 (en) | 2018-06-20 | 2022-08-16 | L'oreal | Hair dyeing composition comprising an oxidation dye, a scleroglucan gum, an alcanolamine and a mineral alkaline agent |
US11701311B2 (en) | 2018-06-20 | 2023-07-18 | L'oreal | Device for dispensing a hair dyeing product using a dye composition and an oxidizing composition comprising a scleroglucan gum |
US20230096297A1 (en) * | 2021-08-13 | 2023-03-30 | L'oreal | Hair treatment compositions providing brightening and shine |
Also Published As
Publication number | Publication date |
---|---|
US20210113448A1 (en) | 2021-04-22 |
FR3082738B1 (fr) | 2020-07-10 |
EP3810287A1 (fr) | 2021-04-28 |
FR3082738A1 (fr) | 2019-12-27 |
CN112312972A (zh) | 2021-02-02 |
BR112020025648A2 (pt) | 2021-03-23 |
US11291617B2 (en) | 2022-04-05 |
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