WO2018028276A1 - 空气清新剂组合物及其制备方法 - Google Patents

空气清新剂组合物及其制备方法 Download PDF

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WO2018028276A1
WO2018028276A1 PCT/CN2017/086159 CN2017086159W WO2018028276A1 WO 2018028276 A1 WO2018028276 A1 WO 2018028276A1 CN 2017086159 W CN2017086159 W CN 2017086159W WO 2018028276 A1 WO2018028276 A1 WO 2018028276A1
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weight
parts
extract
component
air freshener
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PCT/CN2017/086159
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English (en)
French (fr)
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王婧宁
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王婧宁
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Priority to US16/069,488 priority Critical patent/US10744219B2/en
Priority to ES17838408T priority patent/ES2800449T3/es
Priority to EP17838408.7A priority patent/EP3388137B1/en
Priority to JP2018537757A priority patent/JP6545913B2/ja
Publication of WO2018028276A1 publication Critical patent/WO2018028276A1/zh

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/01—Deodorant compositions
    • A61L9/013—Deodorant compositions containing animal or plant extracts, or vegetable material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/72—Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/015—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone
    • A61L9/04—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air without heating
    • A61L9/044—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air without heating with the help of an organic compound other than a macromolecular compound
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D11/00—Solvent extraction
    • B01D11/02—Solvent extraction of solids
    • B01D11/0211—Solvent extraction of solids in combination with an electric or magnetic field
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D11/00—Solvent extraction
    • B01D11/02—Solvent extraction of solids
    • B01D11/0288—Applications, solvents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/38—Removing components of undefined structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/54—Nitrogen compounds
    • B01D53/58—Ammonia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/81—Solid phase processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2209/00—Aspects relating to disinfection, sterilisation or deodorisation of air
    • A61L2209/20—Method-related aspects
    • A61L2209/21—Use of chemical compounds for treating air or the like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/10—Oxidants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/30—Alkali metal compounds
    • B01D2251/304—Alkali metal compounds of sodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/30—Alkali metal compounds
    • B01D2251/306—Alkali metal compounds of potassium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/40—Alkaline earth metal or magnesium compounds
    • B01D2251/404—Alkaline earth metal or magnesium compounds of calcium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/50—Inorganic acids
    • B01D2251/512—Phosphoric acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/60—Inorganic bases or salts
    • B01D2251/604—Hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/60—Inorganic bases or salts
    • B01D2251/606—Carbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/70—Organic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/80—Organic bases or salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/20—Organic adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/25—Coated, impregnated or composite adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/40—Nitrogen compounds
    • B01D2257/406—Ammonia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/702—Hydrocarbons
    • B01D2257/7027—Aromatic hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708—Volatile organic compounds V.O.C.'s
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography

Definitions

  • the present invention relates to an air freshener composition, and more particularly to an air freshening composition comprising a plant extract, and more particularly to the field of B01D.
  • the quality of the air environment has gradually decreased, and the requirements for air purification have become higher and higher.
  • air fresheners There are many kinds of air fresheners currently on the market, and the fragrances are various, but most of them are mixed with organic compounds such as aromatics and some monoterpenoids. Although these products can eliminate odor, they cannot be true.
  • some synthetic air fresheners usually the main component is phenol, are generally prepared as solid preparations. It is a chemical compound synthesized from perfume, ethanol and other components, and contains propellants such as formaldehyde, petroleum distillate, dichlorobenzene, mist catalyst, dimethyl ether, etc. A harmful substance called an aerosol.
  • Chlorine dioxide is basically non-toxic to the nuclear and plant fibers of higher animals, especially the reaction product after disinfection by chlorine dioxide is basically non-toxic, so chlorine dioxide is an ideal chemical disinfectant and can be widely used in households. Sterilization and disinfection of hospitals, restaurants, etc.
  • the present invention provides an air freshener composition which is safe and can be used for a long period of time.
  • a first aspect of the present invention provides an air freshener composition
  • an air freshener composition comprising component A and component B; the weight ratio of the component A and component B is 1: 0.5 ⁇ 3;
  • the component A in parts by weight, comprises 10 to 30 parts by weight of the active agent; 6 to 15 parts by weight of the carrier; 1 to 4 parts by weight of the pH adjusting agent; 0.01 to 0.2 parts by weight of the antioxidant;
  • the active agent includes a compound having at least two hydroxyl groups; the carrier includes an organic acid having 16 to 24 carbon atoms;
  • the component B is a plant extract, and the plant extract comprises at least 5 to 30 parts by weight of an extract of a mixture of Italian black poplar, grapefruit peel, and eucalyptus leaves; and 0.1 to 5 parts by weight.
  • Sophora flavescens extract 1 to 3 parts by weight of aloe extract; 1 to 10 parts by weight of fresh orange peel extract; 0.5 to 3 parts by weight of sassafras extract; 0.5 to 10 parts by weight of eucalyptus extract; 8 parts by weight of Hawthorn locust extract; 1 to 5 parts by weight of chrysanthemum extract; 0.1 to 2 parts by weight of artemisinin.
  • the air freshener composition comprises component A and component B; the weight ratio of component A and component B is 1:1 to 3;
  • the component A in parts by weight, comprises 18 to 28 parts by weight of the active agent; 8 to 12 parts by weight of the carrier; 2 to 3 parts by weight of the pH adjusting agent; 0.1 to 0.2 parts by weight of the antioxidant;
  • the active agent includes a compound having at least two hydroxyl groups; the carrier includes an organic acid having 16 to 24 carbon atoms;
  • the component B is a plant extract, and the plant extract comprises at least 15 to 28 parts by weight of an extract of a mixture of Italian black poplar, grapefruit peel and eucalyptus leaves; and 1 to 3 parts by weight.
  • Sophora flavescens extract 1.5 to 3 parts by weight of aloe extract; 3 to 8 parts by weight of fresh orange peel extract; 1 to 2 parts by weight of sassafras extract; 3 to 10 parts by weight of eucalyptus extract; 6 parts by weight of Hawthorn locust extract; 2 to 4 parts by weight of chrysanthemum extract; 0.5 to 1.5 parts by weight of artemisinin.
  • the air freshener composition comprises component A and component B; the weight ratio of component A and component B is 1:2;
  • the component A in parts by weight, comprises 25 parts by weight of an active agent, 10 parts by weight of a carrier, 2.5 parts by weight of a pH adjuster, 0.1 part by weight of an antioxidant;
  • the active agent includes a compound having at least two hydroxyl groups; the carrier includes an organic acid having 16 to 24 carbon atoms;
  • the component B is a plant extract, and the plant extract comprises at least 25 parts by weight of an extract of a mixture of Italian black poplar, grapefruit peel and eucalyptus leaves; and 2 parts by weight of the extract of Sophora flavescens ; 3 parts by weight of aloe extract; 7 parts by weight of fresh orange peel extract; 1.5 parts by weight of sassafras extract; 8 parts by weight of eucalyptus extract; 5 parts by weight of locust extract; 4 parts by weight of chrysanthemum extract 1 part by weight of artemisinin.
  • the active agent is selected from the group consisting of ethylene glycol, propylene glycol, butylene glycol, polyethylene glycol, glycerol, and 1,3,5-cyclohexanetriol. Mix of species or several.
  • the carrier is selected from the group consisting of: palmitic acid, stearic acid, arachidic acid, behenic acid, or a mixture of several.
  • the extraction method of the extract of the mixture of Italian black poplar, grapefruit peel and eucalyptus leaves is:
  • the dried Italian black poplar leaves, grapefruit peel and eucalyptus leaves are weighed and weighed according to the weight ratio of 10:5:2, and the mass fraction is 95%.
  • the ethanol is immersed for 3 to 10 hours, and then extracted by microwave heating for 2 to 3 times, filtered, and the filtrate is concentrated under reduced pressure until ethanol is obtained.
  • the extraction method of the cymbidium extract is:
  • the component B further comprises 1 part by weight of an extract of a mixture of spearmint and hemp seed.
  • a second aspect of the invention provides a method of preparing an air freshener composition comprising at least the following steps:
  • Component A The carrier is added to water, stirred at 60-90 ° C for 2-5 hours, then added with the corresponding parts by weight of activator, pH adjuster, antioxidant, and stirred at 40-60 ° C for 1-3 h. ;
  • Component B After mixing various plant extracts, stirring at 20 to 40 ° C for 1 to 2 hours, and standby;
  • Component A is added to component B, stirred at 30 to 50 ° C for 1 to 5 hours, and evaporated to dryness to obtain a paste-like solid air freshener composition.
  • a third aspect of the invention provides an air freshener article comprising the above air freshener composition.
  • compositions, step, method, article or device comprising the listed elements is not necessarily limited to those elements, but may include other elements not specifically listed or inherent to such compositions, steps, methods, articles or devices. Elements.
  • Approximating terms used in the specification and claims are used to modify the quantity, and the invention is not limited to the specific number, and includes a portion that is close to the quantity that is acceptable without causing a change in the relevant basic function.
  • a numerical value is modified by "about”, “about” or the like, meaning that the invention is not limited to the precise value. In some instances, the approximation may correspond to the accuracy of the instrument that measures the value.
  • the scope of the invention may be combined and/or interchanged, and if not stated otherwise, the scope includes all subranges.
  • a first aspect of the present invention provides an air freshener composition
  • Component A and Component B the weight ratio of Component A to Component B is 1: 0.5 ⁇ 3;
  • the component A in parts by weight, comprises 10 to 30 parts by weight of the active agent; 6 to 15 parts by weight of the carrier; 1 to 4 parts by weight of the pH adjusting agent; 0.01 to 0.2 parts by weight of the antioxidant;
  • the active agent includes a compound having at least two hydroxyl groups; the carrier includes an organic acid having 16 to 24 carbon atoms;
  • the component B is a plant extract, and the plant extract comprises at least 5 to 30 parts by weight of an extract of a mixture of Italian black poplar, grapefruit peel, and eucalyptus leaves; and 0.1 to 5 parts by weight.
  • Sophora flavescens extract 1 to 3 parts by weight of aloe extract; 1 to 10 parts by weight of fresh orange peel extract; 0.5 to 3 parts by weight of sassafras extract; 0.5 to 10 parts by weight of eucalyptus extract; 8 parts by weight of Hawthorn locust extract; 1 to 5 parts by weight of chrysanthemum extract; 0.1 to 2 parts by weight of artemisinin.
  • the "component A” includes 10 to 30 parts by weight of an active agent, 6 to 15 parts by weight of a carrier, 1 to 4 parts by weight of a pH adjuster, and 0.01 to 0.2 part by weight of an antioxidant.
  • the active agent includes a compound containing at least two hydroxyl groups, and examples thereof include:
  • the carrier includes an organic acid having 16 to 24 carbon atoms, and examples thereof include palmitic acid, leucovoric acid, stearic acid, nonadecanic acid, arachidic acid, behenic acid, behenic acid, and Tridecanoic acid, lignin acid.
  • the carrier is selected from the group consisting of: palmitic acid, stearic acid, arachidic acid, behenic acid, or a mixture of several.
  • Examples of the pH adjuster include a mixture of any one or a combination of sodium hydroxide, potassium hydroxide, calcium hydroxide, sodium hydrogencarbonate, and disodium hydrogen phosphate.
  • antioxidants examples include various antioxidants such as acetate vitamin E, phenol antioxidant, phosphorus antioxidant, and sulfur antioxidant; and hindered amines.
  • Various heat stabilizers such as heat stabilizers; inorganic antibacterial agents, organic antibacterial agents, antifungal agents, and the like.
  • phenolic antioxidant examples include, but are not limited to, 1-hydroxy-3-methyl-4-isopropylbenzene, 2,6-di-tert-butylphenol, 2, 6-di-tert-butyl-4-ethylphenol, 2,6-di-tert-butyl-p-cresol, 2,6-di-tert-butyl-4-n-butylphenol, 4-hydroxymethyl-2, 6-di-tert-butylphenol, tert-butylhydroxyanisole, 2-(1-methylcyclohexyl)-4,6-dimethylphenol, 2,4-dimethyl-6-tert-butylphenol, 2-methyl-4,6-dimercaptophenol, 2, 6-di-tert-butyl- ⁇ -dimethylamino-p-cresol, 2,4,6-tri-tert-butylphenol, 6-(4-hydroxy-3, 5-di-tert-butylanilino)-2, 4-bis(octylthio)
  • phosphite antioxidants include, but are not limited to, triphenyl phosphite, tris(phenylphenyl) phosphite, triisooctyl phosphite, triisodecyl phosphite, phenyl phosphite Isodecyl ester, trilauryl trithiophosphite, trilauryl phosphite, tris(octadecyl phosphite), diisodecyl pentaerythritol diphosphite, pentaerythritol distearyl diphosphate, 4, 4'-butyl fork bis [(3-methyl-6-tert-butylphenyl) bis (tridecyl) phosphite], diphenyl isooctyl phosphite, phenyl diisooctyl phosphite,
  • sulfur-containing ester antioxidant examples include, but are not limited to, dilauryl thiodipropionate, distearyl thiodipropionate or di(octadecyl thiodipropionate), ⁇ , ⁇ '-thiobisbutyric acid di(octadecyl) ester, thiodipropionic acid lauryl octaester, thiodipropionate di(tris) ester, thiodipropionate di(tetradecyl) ester Any one.
  • the component B is a plant extract, and the plant extract comprises at least 5 to 30 parts by weight of an extract of Italian black poplar, grapefruit peel, eucalyptus mixture, and 0.1 to 5 parts by weight of bitter by weight.
  • Reference extract 1 to 3 parts by weight of aloe extract, 1 to 10 parts by weight of fresh orange peel extract, 0.5 to 3 parts by weight of sassafras extract, 0.5 to 10 parts by weight of eucalyptus extract, 1 to 8
  • the parts of the extract of Hawthorn locust 0.1 to 5 parts by weight of the chrysanthemum extract, 0.1 to 2 parts by weight of artemisinin, and 0.5 to 3 parts by weight of matrine.
  • the "Italian black poplar” is also known as the Italian poplar, the deciduous large tree, the crown is long oval, the bark is taupe and lobed.
  • the leaves are triangular, the base is heart-shaped, with 2-4 glandular spots, the leaf length is slightly larger than the width, the leaves are dark green, and the quality is thicker. Petiole flat.
  • the "grapefruit peel” is the peel of the citronaceae plant pomelo. Collected at the end of autumn and early winter, it is cut into 5 ⁇ 7 petals of dried peel.
  • the length of the skin after stretching is about 25 ⁇ 32 cm.
  • Each single flap is 10-13 cm long, 5-7 cm wide and 0.5 ⁇ 1 cm thick. .
  • the edge of the skin is slightly curled inward; the outer surface is yellowish brown or yellowish, sometimes slightly golden yellow, extremely rough, with many concave dots and raised oil spots; the inner surface is white, slightly cotton-like. It is soft and has a strong aroma of grapefruit.
  • the "eucalyptus leaves” are also called eucalyptus leaves, blue eucalyptus leaves, and leymus leaves.
  • This product has a sickle-like lanceolate shape, 8-30cm long and 2-7cm wide; leathery and thick; tip of leaf tip, tip of leaf tip, asymmetrical leaf base, entire; petiole shorter, length 1-3cm, flat And reversed.
  • the surface is yellow-green, smooth and hairless, with many reddish-brown cork spots.
  • transparent dots for the light, there are countless transparent dots (oil chamber).
  • Feathery veins the ends of the lateral veins are joined at the leaf margin to form veins parallel to the leaf margin. It has a slight aroma and tastes bitter and cool. It is better to have large leaves, complete, less stalks and no impurities.
  • the foliar wax contains 5,4-dihydroxy-7-methoxymethylflavone (5, 4-dihydroxy-7-methoxy-6-methylflavone), chrysin, eucalyptin, 8-demethyleu-calyptin, and 4, 5-dihydroxy-7-methoxy-6, 8-dimethyl flavonoid (sideroxylin).
  • the hair oil in the leaves contains cineole and caryophyllene.
  • Tridecane-16 is separated from the bark and xylem. 18-diketone, 3-O-methyl-galactic acid-4-rhamnoside, and gallic acid (ellagic) Acid) and elegans (el-lagitannin).
  • the extraction method of the extract of the Italian black poplar, grapefruit peel, and eucalyptus mixture is:
  • the dried Italian black poplar leaves, grapefruit peels, and eucalyptus leaves are weighed and weighed at a weight ratio of 10:5:2, and the mass fraction is 95%.
  • the ethanol is immersed for 3 to 10 hours, and then extracted by microwave heating for 2 to 3 times, filtered, and the filtrate is concentrated under reduced pressure until ethanol is obtained.
  • the microwave is an electromagnetic wave having a frequency of about 300 MHz to 300 GHz, that is, a wavelength in the range of 100 cm to 1 mm, which is located between the electromagnetic spectrum (light wave) and the radio wave.
  • Microwave is a very special electromagnetic band. Its performance is similar to that of sunlight.
  • the wave speed is the same as the speed of light, both of which are 3 ⁇ 10 8 m / s, the wavelength is 12.24 cm, and the oscillation frequency is 2.45 billion times per second.
  • Microwave extraction also known as microwave-assisted extraction, refers to a method in which the thermal effect of microwaves is used to heat the sample and its organic solvent, and the components to be tested are extracted from the sample matrix.
  • microwave extraction is actually mainly the heating effect of microwave on the extraction solvent and sample. It can penetrate the extraction solvent and materials to make the whole system more uniformly heated: microscopically, the electromagnetic field generated by microwave accelerates the sample orientation. The diffusion rate at the extraction solvent interface.
  • the mechanism of microwave extraction can be considered from two aspects: on the one hand, the electromagnetic field generated by microwave accelerates the diffusion rate of the extracted component to the interface of the extraction solvent.
  • the electromagnetic field generated by microwave accelerates the diffusion rate of the extracted component to the interface of the extraction solvent.
  • the water molecules turn into an excited state at high speed under the microwave field.
  • the time at which the molecules are diffused from the inside of the sample to the interface of the extraction solvent increases the extraction rate several times, while also lowering the extraction temperature to maximize the quality of the extraction.
  • microwave energy is a non-ionizing radiant energy that causes molecular motion caused by ion migration and dipole rotation. When it acts on the molecule, it promotes the rotational motion of the molecule. If the molecule has a certain polarity at this time, it will generate instantaneous polarization under the action of the microwave electromagnetic field, and 24.5 The speed of 100 million times/second is used to perform the polarity changing motion, thereby generating vibration and tear of the key and mutual friction and collision between the particles, thereby promoting better contact and reaction of the active portion (polar portion) of the molecule, and rapidly generating a large amount. Thermal energy.
  • the internal temperature of the cells rises rapidly, causing the internal pressure of the cells to exceed the capacity of the cell wall to expand and the cells to rupture.
  • the active components in the cells are free to flow out, and the extraction medium is captured and dissolved in a short period of time.
  • the extracting method of the extract of the mixture of Italian black poplar, grapefruit peel and eucalyptus leaves is:
  • the dried Italian black poplar leaves, grapefruit peel and eucalyptus leaves are weighed and weighed according to the weight ratio of 10:5:2, and the mass fraction is 95%.
  • the ethanol is immersed for 3 to 10 hours, and then extracted by microwave heating for 2 to 3 times, filtered, and the filtrate is concentrated under reduced pressure until ethanol is obtained.
  • the "bitter ginseng” is a dried root of the leguminous plant Sophora flavescens. In the spring and autumn season, the roots and small roots are removed, washed, dried, or sliced and dried.
  • This product has a long cylindrical shape, and the lower part often has branches, which are 10 to 30 cm long and 1 to 2 cm in diameter.
  • the surface is grayish brown or brownish yellow, with longitudinal wrinkles and horizontal long lenticels.
  • the outer skin is thin, and many ruptures and rewinds, easy to peel off, and the peeling surface is yellow and smooth.
  • Sophora flavescens matrine, oxymatrine, N-oxysophocarpine, sophoridine, dextrorotatory (- Allomatrine), I-somatrine, sophoranol, (+) ellaghol N-oxide (sophoranol) N-oxide), sophocarpine, sophoramine, N-methylcytisine, anagyrine, eucalyptine Baptifoline).
  • the root also contains a variety of flavonoids: Kushenol A, B, C, D, E, F, G, H, I, J, K, L, M, N, O, Kushen Kuraridin, kuraridinol, kurarinol, neokurarinol, norkurarinol, isokurarinone, thorn handle For-mononetin, kurarinone, norkurarinone, methyl Kushenol C), l- ⁇ ⁇ ( (lmaackiain), trifoliar h ⁇ (trifolirhizin) and lobly bean rosewood ⁇ malonate (rtifolirhizin-6"-O-malonate), kushenin (kushenin), different dehydration Isoamphos (isoanhy-droicaritin), noranhydroicaritin, xan-thohumol, isoxanthohumol, luteolin-7-glu
  • 2-alkyl chromone derivatives (2-alkylchromone Derivatives, wherein 2-n-hexadecyl-5,7-dihydroxy-6, 8-dimethylchromone (2-n-heneicosyl-5, 7-dihydroxy-6, 8-dimethyl chromone) and 2-n-tridecyl-5,7-dihydroxy-6, 8-dimethylchromone (2-n-tricosyl-5, 7-dihydroxy-6, 8-dimethylchromone), 2-n-tridecyl-, 2-n-pentadecyl-, 2-n-hexadecyl (2) -n-heptadecyl)-, 2-n-nonadecyl and 2-n-pentacosyl- 5,7-dihydroxy-6, 8-dimethyl chromone (5, 7-dihydroxy-6, 8-dimethyl chromone).
  • the method for extracting the Sophora flavescens is: taking 5 g of dried Angelica, grinding into a powder, and adding 100 at 40 ° C.
  • the concentration of mL is 80% ethanol, heated under reflux for 2 hours, extracted by ultrasonic for 2 to 5 h, extracted 5 times, combined with the extract, filtered and concentrated to no ethanol.
  • the "aloe vera” is a drought-tolerant herb of Liliaceae, mainly distributed in Africa and other places, has antibacterial, anti-inflammatory and laxative effects, and is commonly used for treating liver heat, flatulence, constipation, headache, wetness and Stones, etc.
  • Polysaccharides and terpenoids are abundant in fresh aloe vera and are the main active sites.
  • Aloe vera gel contains a large amount of sugar components, most of which are different kinds of glucomannan, among which acetylated mannan has high biological activity.
  • Other monosaccharides contained are common arabinose, galactose, glucose, mannose and rhamnose.
  • the terpenoids are mostly distributed in the subcutaneous palisade tissue, mainly aloin and aloe-emodin. They are partially combined with polysaccharides to form glycoproteins, and some are in the form of enzymes, such as hydroxypeptidase, peroxidase, cellulose.
  • Aloe vera contains lactic acid, succinic acid, malic acid, p-coumaric acid, succinic acid and citric acid.
  • the method for extracting the aloe vera is: after washing 20 g of aloe vera, chopping, mixing with the refining honey, heating to 60 ° C, keeping warm 3 h, after cooling, using water as a solvent, extracting with ultrasonic for 3 to 5 h, extracting 3 times, combining the extracts, filtering and concentrating to anhydrous, that is, obtaining.
  • defined honey means: placing the honey in a pot, heating it to a boil, changing to a simmer, keeping it slightly boiled, removing the foam and floating the wax, then filtering the dead bees and impurities with a sifting or gauze. Pour into the pot, heat to 100 ° C ⁇ 118 ° C, full of fish eye bubble, sticky with hand rub, no white silk between the two fingers appeared, quickly out of the pot.
  • the main component of the "fresh orange peel” is a monocyclic terpene of terpene (methacryl cyclohexene) having a boiling point of 175.5-176 ° C, having a citrus (lemon) fruit flavor, and the lemon oil itself is insoluble.
  • terpene methacryl cyclohexene
  • citrus (lemon) fruit flavor having a citrus (lemon) fruit flavor
  • lemon oil itself is insoluble.
  • water add active agent and mix with water in any ratio.
  • the fresh orange peel contains a lot of vitamin C and essential oil.
  • the orange peel contains volatile oil.
  • the main components in the oil are limonene, furfural, as well as catechin, hesperidin, inositol and vitamin B1. It has a stimulating effect on the digestive tract and is beneficial to the discharge of gastrointestinal gas. Promote the secretion of gastric juice; diastolic bronchus.
  • Orange peel has been isolated from more than 30 kinds of substances, including flavonoids, monoterpenes, coumarins, carotenoids, propanol, acridone, and glycerol glycol lipids.
  • Flavonoids There are three types of flavonoids contained in citrus fruits: Type I is a general flavonoid represented by rutin; Type II is a flavanoid which is characteristic of citrus fruits such as hesperidin and naringin; Type III is a special flavonoid containing polymethoxyl such as citrus flavonoids which have not been found yet in other vegetables and fruits.
  • Carrots As we all know, many vegetables and fruits contain carotenoids, which are important ingredients for human health. The research on the physiological functions and mechanisms of carotenoids has developed rapidly in recent years. China has also used these substances to develop some health foods and realize industrial production.
  • Coumarin contained in citrus is an anti-cancer substance that has been fully recognized by scientists.
  • the role of these two aspects is mainly to produce an inhibitory effect at the initial stage of cancer.
  • Monoterpenes and triterpenoids contain a large amount of terpenoids represented by limonene.
  • Earthworms are substances that make up the unique aroma of citrus and have the effect of calming the central nervous system.
  • Limonin is the bitter ingredient of orange peel.
  • the fresh orange peel extract is prepared by blasting 15 g of fresh orange peel to 100-200 mesh, blending with 2-mercaptobenzothiazole, and using ethanol as a solvent. extract.
  • the "Tianlan”, also known as the red scorpion, is a genus of the dicotyledonous family of the genus Dioscorea in the south of the Yangtze River basin in Jiangsu, Zhejiang, Shaanxi, Guangxi and other provinces, Japan and India. Most are born next to the wet valley. Under the sparse forest or shrub, it is a calcium soil indicator plant. It is cultivated in gardens in all parts of the north and south. Hi warm and humid and well ventilated in a semi-negative environment. It is more resistant to cold and can be cultivated in the south of the Yellow River. After the fruit is ripe, leave it on the branch and the temperature should be kept at around 10 degrees Celsius. Potted plants should be preserved in shade and shed in spring and summer. Resistant to slightly alkaline soil. Strong and strong, generally dry and bushy. It is an evergreen shrub. Its roots and stems can be dehumidified by heat and pass through.
  • the extract of the sapphire orchid is prepared by weighing 10 g After drying the dried sassafras, immerse in white vinegar for 1 ⁇ 3h, then add 60% ethanol, soak for 2 ⁇ 5h, then extract it by microwave for 2 ⁇ 3 times, filter, and concentrate the filtrate under reduced pressure until no white vinegar and ethanol. That is.
  • the "eucalyptus” is also known as the Eucalyptus tree, and is a collective name for the genus of the genus Myrtaceae, the genus Umbrella, and the genus Eucalyptus, and the origins of Indonesia and Australia.
  • the types of the "eucalyptus” may be listed as: blue dragonfly, straight dry blue dragonfly, lemon dragonfly, big leafhopper, leaf-shaped copper money dragonfly, Eucalyptus grandis, giant salamander, fine leafhopper, blue dragonfly, Deng Enzhen, Liu ⁇ , ⁇ ⁇ , giant ⁇ ⁇ , tail ⁇ ⁇ , tail ⁇ ⁇ , Akasaka, Deng En ⁇ and so on.
  • the main component of the bark extract is pentacyclic triterpenoids such as ursolic acid, betulinic acid, oleanolic acid, ursolic acid, betulinic acid, betulinic acid, betulinic acid, 3- ⁇ -O-anti P-hydroxycinnamoyl-12-ene-28-oleanolic acid, 3- ⁇ -O-trans p-hydroxycinnamoyl-2 ⁇ -hydroxy-12-enyl-ursolic acid.
  • pentacyclic triterpenoids such as ursolic acid, betulinic acid, oleanolic acid, ursolic acid, betulinic acid, betulinic acid, betulinic acid, 3- ⁇ -O-anti P-hydroxycinnamoyl-12-ene-28-oleanolic acid, 3- ⁇ -O-trans p-hydroxycinnamoyl-2 ⁇ -hydroxy-12-enyl-ursolic acid.
  • the main components of the eucalyptus leaves extract are 1,8-eucalyptol, terpene, orange, aldaldehyde, rosin and 1-acetyl-4-isopropylidenecyclopentene, and also contain musk and quercetin. Quercetin, homoserine, and eucalyptus. Other components in the loquat leaves, such as terpenoids, flavonoids, tannins, phloroglucins and glycosides, are also abundant in biological activity.
  • the eucalyptus extract is blended and extracted from the leaves of the big leafhopper and the eucalyptus bark according to a weight ratio of 1:18; the eucalyptus leaves are picked from the spring and the age of the tree is 3 years old.
  • the eucalyptus extract is prepared by weighing a powder of a 1:18 blend of the big leaf bark and the big leaf eucalyptus leaves, adding ethanol, soaking 2- After 3 h, it was extracted by microwave heating for 2-3 times, filtered, and the filtrate was concentrated under reduced pressure to give no ethanol.
  • the hedgehog is divided into straight hedgehog, golden leaf hedgehog, curved branch hedgehog, columnar hedgehog, ball crown hedgehog, tortoiseshell hedgehog, safflower hedgehog, thornless hedgehog, lobular hedgehog, arrowhead hedgehog, yellow leaf hedgehog, Ball python, pink thorns and ⁇ ⁇ .
  • the hedgehog is selected to be extracted by blending gold leaf locust, pink locust and safflower thorn by a ratio of 1:1:50 by weight.
  • the hedgehog extract preferably extracts leaves and flowers of the hedgehog.
  • the preparation method of the hedgehog extract is:
  • the "chrysanthemum” is a perennial perennial herb of the genus Asteraceae and Chrysanthemum in plant taxonomy. According to the cultivation form, it is divided into the cultivation type such as the multi-headed chrysanthemum, the single chrysanthemum, the daisy, the cliff chrysanthemum, the geisha, Sexually cool, bitter, spicy, return to the liver, heart.
  • the chemical composition of chrysanthemum is divided into: volatile oil components, flavonoids, phenolic acids and other components.
  • the volatile oil is mainly composed of monoterpenes, sesquiterpenes, oxygen-containing derivatives and aliphatic compounds, and also contains chrysanthemum lactone, chrysanthemum, chrysanthemum, chrysanthemum, cis-spilenol ether, Inverse-spilenol ether, angelic acid shikonin B, angelica quercetin, sulphate A, ragylin A, ursolic acid, ⁇ -sitosterol, and the like.
  • Flavonoids main ingredients are hibiscus flavonoids, leucoside, luteolin, celery, acacetin-7-rhamnose glucoside, luteolin-7-glucoside, quercetin quinone, Apigenin-7-O- ⁇ -D-glucopyranoside, geranin-7-O- ⁇ -D-glucopyranoside, quercetin-3,7-di-O- ⁇ -D-pyridin Glucoside, eriodictol-7-O- ⁇ -D-glucopyranoside, 1-phenyl-2,3-butanediol-3-O- ⁇ -D-glucopyranoside and orange peel -7-7-O- ⁇ -D-glucopyranoside.
  • Phenolic acid components 3-O-caffeoylquinic acid, 4-O-caffeoylquinic acid, 5-0-caffeoylquinic acid, methyl 3,5-dicaffeoylquinate, 3 , 5-dicaffeoylquinic acid, 3,5-dicis-caffeoquinic acid, 1,5-dicaffeoylquinic acid, 1,3-dicaffeoylquinic acid, chlorogenic acid and the like.
  • the chrysanthemum extract is extracted by weighing 5 g of chrysanthemum, chopping, adding ethanol, soaking for 2-3 h, extracting 2-3 times using microwave heating, filtering, and decompressing the filtrate. Concentrate to no ethanol, that is.
  • the "artemisinin” is a colorless needle crystal extracted from the compound inflorescence plant Artemisia annua L., and the chemical name is (3R, 5aS, 6R, 8aS, 9R, 12S, 12aR) - eight Hydrogen-3,6,9-trimethyl-3,12-oxooxy-12H-pyrano[4,3-j]-1,2-benzodioxan-10(3H)-one.
  • the formula is C 15 H 22 O 5 , a sesquiterpene lactone having a peroxy linkage and a 6-lactone ring, and having a 1,2,4-trioxane structural unit including a peroxide.
  • the molecule includes seven chiral centers, characterized by A and B rings cis-linked, and isopropyl is in trans-relationship with bridgehead hydrogen.
  • the artemisinin is purchased from Shaanxi Senlang Biochemical Co., Ltd.
  • the air freshener composition comprises component A and component B; the weight ratio of component A and component B is 1:1 to 3;
  • the component A in parts by weight, comprises 18 to 28 parts by weight of the active agent; 8 to 12 parts by weight of the carrier; 2 to 3 parts by weight of the pH adjusting agent; 0.1 to 0.2 parts by weight of the antioxidant;
  • the active agent includes a compound having at least two hydroxyl groups; the carrier includes an organic acid having 16 to 24 carbon atoms;
  • the component B is a plant extract, and the plant extract comprises at least 15 to 28 parts by weight of an extract of a mixture of Italian black poplar, grapefruit peel and eucalyptus leaves; and 1 to 3 parts by weight.
  • Sophora flavescens extract 1.5 to 3 parts by weight of aloe extract; 3 to 8 parts by weight of fresh orange peel extract; 1 to 2 parts by weight of sassafras extract; 3 to 10 parts by weight of eucalyptus extract; 6 parts by weight of Hawthorn locust extract; 2 to 4 parts by weight of chrysanthemum extract; 0.5 to 1.5 parts by weight of artemisinin.
  • the air freshener composition comprises component A and component B; the weight ratio of component A and component B is 1:2;
  • the component A in parts by weight, comprises 25 parts by weight of an active agent, 10 parts by weight of a carrier, 2.5 parts by weight of a pH adjuster, 0.1 part by weight of an antioxidant;
  • the active agent includes a compound having at least two hydroxyl groups; the carrier includes an organic acid having 16 to 24 carbon atoms;
  • the component B is a plant extract, and the plant extract comprises at least 25 parts by weight of an extract of a mixture of Italian black poplar, grapefruit peel and eucalyptus leaves; and 2 parts by weight of the extract of Sophora flavescens ; 3 parts by weight of aloe extract; 7 parts by weight of fresh orange peel extract; 1.5 parts by weight of sassafras extract; 8 parts by weight of eucalyptus extract; 5 parts by weight of locust extract; 4 parts by weight of chrysanthemum extract 1 part by weight of artemisinin.
  • component B further comprises 1 part by weight of an extract of a mixture of spearmint and hemp seed.
  • the "spoon” also known as spearmint, fragrant mint, spearmint, spearmint, broccoli, fish coriander. It is a erect perennial herb of the family Lamiaceae, with erect stems, purple or white flowers, flowering from July to September. The temperature adapts to a large range, like moist, hi-light, suitable for weakly acidic soil. The stem and leaves are distilled to extract the spearmint oil.
  • the plant contains aromatic oil with an oil content of 0.6-0.7%.
  • the oil is called spearmint oil or spearmint oil.
  • the main ingredient is fragrant succulent oleic acid (content 60-65%), in addition to lemon hydrocarbon and water cress. Oil and hydrocarbon, etc., mainly used for confectionery, toothpaste and spices, also for medical use. Leaves, twigs or whole grass are also used as medicine to treat cold, fever, cough, numbness, cough, cold, headache, sore throat, nervous headache, flatulence, bruises, redness, snot, sputum Treatment, numbness and pediatric sores.
  • Hemp is a cannabis family, commonly known as marijuana, also known as chillies, linseed, kumay, ramie, hemp, etc. It is a herb with short sunshine, annual, palm-like division and mostly dioecious. It is resistant to barrenness and stress resistance, has a wide range of growth, and has the characteristics of high illumination and high photosynthesis efficiency in biology. It grows vigorously under long sunshine conditions, and the plant height can be as high as 3.5 m. Hemp can be divided into three types: fiber, medicinal and seed.
  • Hemp seed oil is a yellow-green translucent oily liquid at room temperature. It turns yellow brown after a long time and has a special scent of hemp seeds.
  • Oral sesame seed oil contains 30%-40% oil, and the ratio of linoleic acid to linolenic acid is close. 2.5, this ratio is the optimal ratio of fatty acids required by the human body, and the respective metabolically active products of linoleic acid and stearic acid are also quite rich.
  • the fatty acid composition of hemp seed oil is mainly C16 and The C18 fatty acid, diunsaturated linoleic acid and triunsaturated linolenic acid have a high fraction of 85.80% and high unsaturation.
  • hemp seed oil contains 29 compounds, of which fatty acids are 18 Species, accounting for 99.12% of the total content, l1 kinds of saturated fatty acids, mainly palmitic acid, stearic acid, arachidic acid, content 8.81%, 2.76%, 0.59%, unsaturated fatty acid 7 Species, accounting for about 87% of the total content, monounsaturated fatty acids are palm oleic acid, oleic acid, arachidonic acid, the content is 0.08%, 8.92%, 0.26%.
  • fatty acids are 18 Species, accounting for 99.12% of the total content, l1 kinds of saturated fatty acids, mainly palmitic acid, stearic acid, arachidic acid, content 8.81%, 2.76%, 0.59%, unsaturated fatty acid 7 Species, accounting for about 87% of the total content, monounsaturated fatty acids are palm oleic acid, oleic acid, arachidonic acid, the content is 0.08%, 8.92%
  • the polyunsaturated fatty acids were ⁇ -linolenic acid, linolenic acid and linoleic acid, respectively, which were 0.61%, 24.42%, 52.32% and 20-carbon-5, 8, respectively. 11, 14, 17-pentenoic acid, the content is 0.34%, the fat-soluble component in hemp seed oil also includes 4 kinds of ketones, 2 kinds of alcohols and 3 Hydrocarbons. In addition, dimethyl butyric acid, heptanoic acid, 2-methylpentanoic acid and eicos-5, 8, 11, 14, 17-pentenoic acid, and 13 kinds of ketones, hydrocarbons, alcohols, etc. were also identified. ingredient.
  • hemp seed oil there are many methods for extracting hemp seed oil, such as water enzymatic method, supercritical fluid extraction method, solvent leaching method, and pressing method.
  • the water agent method is mainly used to extract the hemp seed oil.
  • the main extraction steps in the present invention are:
  • the hemp seed is washed and then baked at a certain temperature and time.
  • the baking denatures the protein, the soluble protein becomes an insoluble protein, and the original tissue is destroyed.
  • the globulin in the oil changes, the hydrophilic group is transferred to an irregular distribution state, the hydrophobic group is transferred to the outside, and the oil contained in the globulin is exposed on the surface and aggregated. Therefore, baking facilitates the extraction of fats and oils.
  • the hemp seeds are crushed, mixed with tap water at a certain temperature according to a certain ratio, thoroughly stirred and mixed, and fully dispersed and dissolved in water.
  • the oil exposed on the surface of the hemp seed is extracted, and then the oil in the pulverized granule is further extracted.
  • Stir the homogenate at a certain temperature and stirring speed to maximize the extraction of the oil in the homogenate.
  • the water is immersed in the hemp seed particles and combined with the hydrophilic protein to replace the fat in the hemp seed cells. Position so that grease is released from the slurry.
  • the obtained slurry was centrifuged at 4000 r/min for 20 min to obtain an upper oil layer and a lower layer residue to obtain hemp seed oil.
  • the extract of the mixture of spearmint and hemp seed is extracted by weighing 5 g of spearmint, chopping, adding hemp seed oil, soaking for 2-3 h, and then adding mass.
  • the ethanol having a solubility of 50% was extracted by microwave heating 2-3 times, filtered, and the filtrate was concentrated under reduced pressure to give no ethanol.
  • the air freshener composition is compounded with component A and component B, and can have very good removal of formaldehyde, benzene pollutants, ammonia pollutants and volatile organic compounds in the air. effect.
  • component B Among the plant extracts, tannins, terpenoids, ketones and the like can be obtained, which can not only physically adsorb formaldehyde, benzene pollutants, ammonia pollutants and volatile organic compounds in the air but also There is also a chemisorption force to achieve the purpose of purifying the air.
  • the component A can be combined with the component B to further enhance the adsorption effect of the component B, and at the same time, the use time of the air purifying agent composition can be enhanced to achieve a long-term use effect.
  • a second aspect of the invention provides a method of preparing an air freshener composition comprising at least the following steps:
  • Component A The carrier is added to water, stirred at 60-90 ° C for 2-5 hours, then added with the corresponding parts by weight of activator, pH adjuster, antioxidant, and stirred at 40-60 ° C for 1-3 h. ;
  • Component B After mixing various plant extracts, stirring at 20 to 40 ° C for 1 to 2 hours, and standby;
  • Component A is added to component B, stirred at 30 to 50 ° C for 1 to 5 hours, and evaporated to dryness to obtain a paste-like solid air freshener composition.
  • a third aspect of the invention provides an air freshener article comprising the above air freshener composition.
  • Embodiment 1 of the present invention provides an air freshener composition characterized by comprising Component A and Component B; the weight ratio of Component A to Component B is 1:0.5 3;
  • the component A in parts by weight, comprises 10 to 30 parts by weight of the active agent; 6 to 15 parts by weight of the carrier; 1 to 4 parts by weight of the pH adjusting agent; 0.01 to 0.2 parts by weight of the antioxidant;
  • the active agent includes a compound having at least two hydroxyl groups; the carrier includes an organic acid having 16 to 24 carbon atoms;
  • the component B is a plant extract, and the plant extract comprises at least 5 to 30 parts by weight of an extract of a mixture of Italian black poplar, grapefruit peel, and eucalyptus leaves; and 0.1 to 5 parts by weight.
  • Sophora flavescens extract 1 to 3 parts by weight of aloe extract; 1 to 10 parts by weight of fresh orange peel extract; 0.5 to 3 parts by weight of sassafras extract; 0.5 to 10 parts by weight of eucalyptus extract; 8 parts by weight of Hawthorn locust extract; 1 to 5 parts by weight of chrysanthemum extract; 0.1 to 2 parts by weight of artemisinin.
  • Embodiment 2 of the present invention is the same as Embodiment 1, except that the air freshener composition includes Component A and Component B; and the weight ratio of Component A to Component B is 1:1 ⁇ 3;
  • the component A in parts by weight, comprises 18 to 28 parts by weight of the active agent; 8 to 12 parts by weight of the carrier; 2 to 3 parts by weight of the pH adjusting agent; 0.1 to 0.2 parts by weight of the antioxidant;
  • the active agent includes a compound having at least two hydroxyl groups; the carrier includes an organic acid having 16 to 24 carbon atoms;
  • the component B is a plant extract, and the plant extract comprises at least 15 to 28 parts by weight of an extract of a mixture of Italian black poplar, grapefruit peel and eucalyptus leaves; and 1 to 3 parts by weight.
  • Sophora flavescens extract 1.5 to 3 parts by weight of aloe extract; 3 to 8 parts by weight of fresh orange peel extract; 1 to 2 parts by weight of sassafras extract; 3 to 10 parts by weight of eucalyptus extract; 6 parts by weight of Hawthorn locust extract; 2 to 4 parts by weight of chrysanthemum extract; 0.5 to 1.5 parts by weight of artemisinin.
  • Embodiment 3 of the present invention is the same as Embodiment 2, except that the air freshener composition includes Component A and Component B; and the weight ratio of Component A to Component B is 1:2;
  • the component A in parts by weight, comprises 25 parts by weight of an active agent, 10 parts by weight of a carrier, 2.5 parts by weight of a pH adjuster, 0.1 part by weight of an antioxidant;
  • the active agent includes a compound having at least two hydroxyl groups; the carrier includes an organic acid having 16 to 24 carbon atoms;
  • the component B is a plant extract, and the plant extract comprises at least 25 parts by weight of an extract of a mixture of Italian black poplar, grapefruit peel and eucalyptus leaves; and 2 parts by weight of the extract of Sophora flavescens ; 3 parts by weight of aloe extract; 7 parts by weight of fresh orange peel extract; 1.5 parts by weight of sassafras extract; 8 parts by weight of eucalyptus extract; 5 parts by weight of locust extract; 4 parts by weight of chrysanthemum extract 1 part by weight of artemisinin.
  • Embodiment 4 of the present invention is the same as Embodiment 1, except that the active agent is selected from the group consisting of ethylene glycol, propylene glycol, butylene glycol, polyethylene glycol, glycerin, and 1,3. Mixture of any one or more of 5-cyclohexanetriol.
  • Embodiment 5 of the present invention is the same as Embodiment 1, except that the carrier is selected from any one or a mixture of palmitic acid, stearic acid, arachidic acid, and behenic acid.
  • Embodiment 6 of the present invention is the same as Embodiment 1, except that the extraction method of the extract of the mixture of Italian black poplar, grapefruit peel and eucalyptus leaves is:
  • the dried Italian black poplar leaves, grapefruit peel and eucalyptus leaves are weighed and weighed according to the weight ratio of 10:5:2, and the mass fraction is 95%.
  • the ethanol is immersed for 3 to 10 hours, and then extracted by microwave heating for 2 to 3 times, filtered, and the filtrate is concentrated under reduced pressure until ethanol is obtained.
  • Embodiment 7 of the present invention is the same as Embodiment 1, except that the extraction method of the Lycium barbarum extract is:
  • Embodiment 8 of the present invention is the same as Embodiment 1, except that Component B further includes 1 part by weight of an extract of a mixture of spearmint and hemp seed.
  • Embodiment 9 of the present invention provides a method for preparing an air freshener composition according to any one of Embodiments 1 to 8, comprising at least the following steps:
  • Component A The carrier is added to water, stirred at 60-90 ° C for 2-5 hours, then added with the corresponding parts by weight of activator, pH adjuster, antioxidant, and stirred at 40-60 ° C for 1-3 h. ;
  • Component B After mixing various plant extracts, stirring at 20 to 40 ° C for 1 to 2 hours, and standby;
  • Component A is added to component B, stirred at 30 to 50 ° C for 1 to 5 hours, and evaporated to dryness to obtain a paste-like solid air freshener composition.
  • Embodiment 10 of the present invention provides an air freshener preparation comprising the air freshener composition according to Embodiments 1 to 8.
  • Embodiment 1 of the present invention provides an air freshener composition comprising component A and component B; the weight ratio of component A and component B is 1:0.5;
  • the component A in parts by weight, comprises 10 parts by weight of an active agent (the active agent is propylene glycol); 15 parts by weight of a carrier (the carrier is palmitic acid, stearic acid; palmitic acid, stearic acid) a weight ratio of 2:1); 1 part by weight of a pH adjuster (the pH adjuster is sodium hydroxide); 0.01 part by weight of an antioxidant (the antioxidant is acetate vitamin E);
  • the component B is a plant extract, and the plant extract comprises: 5 parts by weight of an extract of a mixture of Italian black poplar, grapefruit peel, and eucalyptus leaves; 0.1 parts by weight of Sophora flavescens extract; 1 part by weight of aloe extract; 1 part by weight of fresh orange peel extract; 0.5 part by weight of sassafras extract; 0.5 part by weight of eucalyptus extract; 1 part by weight of locust extract; 1 part by weight of chrysanthemum extract 0.1 parts by weight of artemisinin.
  • the powder of the big leaf bark and the big leaf eucalyptus leaves with a weight ratio of 1:18 was weighed and added to the mass concentration of 80% ethanol. After soaking for 3 hours, it was extracted by microwave heating for 3 times, filtered, and the filtrate was concentrated under reduced pressure until no. Ethanol, that is.
  • the preparation method of the air freshener composition comprises at least the following steps:
  • Component A the carrier was added to water, stirred at 60 ° C for 2 h, then added the corresponding parts by weight of activator, pH adjuster, antioxidant, stirred at 40 ° C for 3 h, set aside;
  • Component B After mixing various plant extracts, stirring at 40 ° C for 1 h, and set aside;
  • Component A was added to component B, stirred at 50 ° C for 5 h, and evaporated to dryness to give a creamy solid air freshener composition.
  • Embodiment 2 of the present invention provides an air freshener composition comprising component A and component B; the weight ratio of component A and component B is 1:3;
  • the component A in parts by weight, comprises 30 parts by weight of an active agent (the active agent is propylene glycol); 6 parts by weight of a carrier (the carrier is palmitic acid, stearic acid; palmitic acid, stearic acid) a weight ratio of 2:1); 4 parts by weight of a pH adjuster (the pH adjuster is sodium hydroxide); 0.2 parts by weight of an antioxidant (the antioxidant is acetate vitamin E);
  • the component B is a plant extract, and the plant extract comprises at least 30 parts by weight of an extract of a mixture of Italian black poplar, grapefruit peel and eucalyptus leaves; and 5 parts by weight of Sophora flavescens extract 3 parts by weight of aloe extract; 10 parts by weight of fresh orange peel extract; 3 parts by weight of sassafras extract; 10 parts by weight of eucalyptus extract; 8 parts by weight of locust extract; 5 parts by weight of chrysanthemum Extract; 2 parts by weight of artemisinin.
  • Embodiment 3 of the present invention provides an air freshener composition comprising component A and component B; the weight ratio of component A and component B is 1:2;
  • the component A in parts by weight, comprises 25 parts by weight of an active agent (the active agent is propylene glycol); 10 parts by weight of a carrier (the carrier is palmitic acid, stearic acid; palmitic acid, stearic acid) a weight ratio of 2:1); 2.5 parts by weight of a pH adjuster (the pH adjuster is sodium hydroxide); 0.1 part by weight of an antioxidant (the antioxidant is acetate vitamin E);
  • the component B is a plant extract, and the plant extract comprises at least 25 parts by weight of an extract of a mixture of Italian black poplar, grapefruit peel and eucalyptus leaves; and 2 parts by weight of the extract of Sophora flavescens ; 3 parts by weight of aloe extract; 7 parts by weight of fresh orange peel extract; 1.5 parts by weight of sassafras extract; 8 parts by weight of eucalyptus extract; 5 parts by weight of locust extract; 4 parts by weight of chrysanthemum extract 1 part by weight of artemisinin.
  • Example 4 (Optimum range + extract of a mixture of spearmint and hemp seed)
  • Embodiment 4 of the present invention provides an air freshener composition comprising component A and component B; the weight ratio of component A and component B is 1:2;
  • the component A in parts by weight, comprises 25 parts by weight of an active agent (the active agent is propylene glycol); 10 parts by weight of a carrier (the carrier is palmitic acid, stearic acid; palmitic acid, stearic acid) a weight ratio of 2:1); 2.5 parts by weight of a pH adjuster (the pH adjuster is sodium hydroxide); 0.1 part by weight of an antioxidant (the antioxidant is acetate vitamin E);
  • the component B is a plant extract, and the plant extract comprises at least 25 parts by weight of an extract of a mixture of Italian black poplar, grapefruit peel and eucalyptus leaves; and 2 parts by weight of the extract of Sophora flavescens ; 3 parts by weight of aloe extract; 7 parts by weight of fresh orange peel extract; 1.5 parts by weight of sassafras extract; 8 parts by weight of eucalyptus extract; 5 parts by weight of locust extract; 4 parts by weight of chrysanthemum extract 1 part by weight of artemisinin; 1 part by weight of an extract of a mixture of spearmint and hemp seed.
  • hemp seeds 300 g were washed clean and then baked at 100 ° C for 8 hours.
  • the baked hemp seeds are subjected to crushing treatment.
  • the crushed hemp seeds were crushed, 1 liter of water was added, the temperature was raised to 80 ° C, and the mixture was stirred for 4 hours.
  • the obtained slurry was centrifuged at 4000 r/min for 20 min to obtain an upper oil layer and a lower layer residue to obtain hemp seed oil.
  • the extract of the mixture of spearmint and hemp seed is extracted by weighing 5 g of spearmint, chopping, adding the hemp seed oil obtained by the above method, and after soaking for 2 h, adding ethanol having a mass solubility of 50%.
  • the mixture was extracted three times with microwave heating, filtered, and the filtrate was concentrated under reduced pressure to give no ethanol.
  • Comparative Example 1 was specifically the same as Example 4 except that the air freshener composition contained no component A.
  • Comparative Example 2 was specifically the same as Example 4 except that the air freshener composition contained no component B.
  • Comparative Example 3 is specifically the same as Example 4 except that the air freshener composition does not contain an extract of a mixture of Italian black poplar, grapefruit peel, and eucalyptus leaves.
  • Comparative Example 4 was specifically the same as Example 4 except that "the extract of Italian black poplar, grapefruit peel, and eucalyptus leaves mixture” was changed to "Italian black poplar extract". Among them, the extraction method of "Italian black poplar extract” is the same as that of Example 1, except that grapefruit peel and eucalyptus leaves are not included.
  • Comparative Example 5 was specifically the same as Example 4 except that "the extract of Italian black poplar, grapefruit peel, and eucalyptus leaves mixture” was changed to "Italian black poplar extract".
  • the extraction method of "Italian black poplar extract” is the same as that of the first embodiment except that the grapefruit peel and the eucalyptus leaves are not included, and the leaves of the Italian black poplar are changed to the bark of the Italian black poplar.
  • Comparative Example 6 was specifically the same as Example 4 except that "the extract of the mixture of Italian black poplar, grapefruit peel, and eucalyptus leaves” was changed to "the extract of the mixture of Italian black poplar and grapefruit peel".
  • the extraction method of "the extract of Italian black poplar and grapefruit peel mixture” is the same as that of the first embodiment except that the eucalyptus leaves are not included.
  • Comparative Example 7 was specifically the same as Example 4 except that the "extract of a mixture of Italian black poplar, grapefruit peel, and eucalyptus leaves” was changed to "an extract of a mixture of Italian black poplar and eucalyptus leaves". Among them, the extraction method of "the extract of Italian black poplar and eucalyptus leaves mixture” is the same as that of Example 1, except that grapefruit peel is not included.
  • Comparative Example 8 was specifically the same as Example 4 except that the "extract of the mixture of spearmint and hemp seed” was changed to the spearmint extract.
  • the extraction method of the spearmint extract was the same as in Example 4 except that hemp seed oil was not added.
  • Comparative Example 9 was specifically the same as Example 4 except that the "extract of the mixture of spearmint and hemp seed” was changed to hemp seed oil.
  • the extraction method of hemp seed oil was the same as in Example 4.
  • the air freshener composition prepared above was tested.
  • TVOC is total volatile organic matter, all indoor organic gaseous substances.
  • Example 2 90.4 90.5 88.1 85.9
  • Example 3 94.2 90.2 90.2 88.2
  • Example 4 98.0 97.2 99.9 99.1 Comparative example 1 66.1 60.4 62.1 50.5 Comparative example 2 50.2 68.6 59.7 48.7 Comparative example 3 80.4 84.4 79.2 73.1 Comparative example 4 82.2 86.7 81.4 75.9 Comparative example 5 79.2 83.4 78.2 70.5 Comparative example 6 85.6 84.2 82.5 78.2 Comparative example 7 84.8 84.3 83.2 77.4 Comparative example 8 93.7 92.5 72.5 70.9 Comparative example 9 93.3 90.9 75.8 74.5
  • Example 1 80.7 79.2 78.9 76.8
  • Example 2 81.4 82.7 80.7 77.8
  • Example 3 90.2 85.6 84.9 82.6
  • Example 4 96.9 95.2 98.9 97.1 Comparative example 1 36.9 34.8 30.5 29.5 Comparative example 2 25.4 29.6 34.7 20.9 Comparative example 3 60.7 68.8 67.2 64.9 Comparative example 4 76.5 79.5 72.6 68.4 Comparative example 5 70.4 74.5 68.1 61.5 Comparative example 6 74.8 72.7 70.8 67.2 Comparative example 7 72.3 70.9 69.2 66.8 Comparative example 8 90.2 89.5 60.9 60.4 Comparative example 9 88.9 88.7 62.5 62.9
  • the air freshener composition obtained by the method for preparing a specific sequence and the combined method for extracting plant extracts, for formaldehyde, benzene, ammonia and TVOC Both have a good removal effect.
  • the air freshener composition of the present invention has a good removal effect on formaldehyde, benzene, ammonia and TVOC after being left for two months.

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Abstract

涉及空气清洁领域，具体公开了一种空气清新剂组合物，包括组分A和组分B；所述组分A和组分B的重量比为1∶0.5～3；所述组分A，以重量份计，包括10～30重量份的活性剂；6～15重量份的载体；1～4重量份的pH调节剂；0.01～0.2重量份的抗氧化剂；所述组分B为植物提取液，以重量份计，所述植物提取液至少包括：5～30重量份的意大利黑杨、葡萄柚皮、桉树叶混合物的提取物；0.1～5重量份的苦参提取物；1～3重量份的芦荟提取物；1～10重量份的鲜橘皮提取物；0.5～3重量份的天竺兰提取物；0.5～10重量份的桉树提取物；1～8重量份的山刺槐提取物；1～5重量份的菊花提取物；0.1～2重量份的青蒿素。

Description

空气清新剂组合物及其制备方法
技术领域
本发明涉及一种空气清新剂组合物，特别涉及一种含有植物提取物的空气清新组合物，更加进一步涉及B01D领域。
背景技术
随着生活水平的逐渐提高，相反空气环境的质量却逐渐降低，对空气净化的要求也越来越高。目前市场上出售的空气清新剂种类繁多，香型各异，但大部分是通过有机化合物如芳香族和一些单萜类化合物在加入香精混合而成，这类产品虽然能够消除异味，但是不能真正改善空气质量，一些人工合成的空气清新剂，通常主要成分是苯酚，一般制备成固体制剂。是一种由香精、乙醇等成分合成的化学制剂，并含有甲醛、石油蒸馏物、二氯（代）苯、雾体催化剂、二甲醚等推进剂，由液体变气体的过程会产生一种叫做气溶胶的有害物质。使用时通过散发香味混淆人的嗅觉来淡化和掩盖异味，不能净化、灭菌，甚至本身就是空气污染源。其次，还含有二甲苯、甲酮类化合物，大剂量使用会造成神经衰弱、上呼吸道***病变等疾病，甚至能够诱发癌症。
新型原料空气清新剂处于产品研发阶段，暂无毒副作用报道。二氧化氯对高等动物细胞核、植物纤维基本无毒，尤其是经二氧化氯消毒杀菌后的反应生成物基本无毒，所以二氧化氯是较理想的化学消毒杀菌剂，可被广泛应用于家庭、医院、饭店等的杀菌消毒。
中药空气清新剂不仅要具备杀灭各种有害微生物和消除有毒物质的特点，而且还应具备安全、高效、广谱、无副作用、储存和使用方便等优点。
针对上述问题，本发明提供一种即安全又可以长期使用的空气清新剂组合物。
发明内容
为了解决以上问题，本发明的第一个方面提供了一种空气清新剂组合物，包括组分A和组分B；所述组分A和组分B的重量比为1：0.5～3；
所述组分A，以重量份计，包括10～30重量份的活性剂；6～15重量份的载体；1～4重量份的pH调节剂；0.01～0.2重量份的抗氧化剂；
所述活性剂包括至少含有两个羟基的化合物；所述载体包括碳原子数为16～24的有机酸；
所述组分B为植物提取液，以重量份计，所述植物提取液至少包括：5～30重量份的意大利黑杨、葡萄柚皮、桉树叶混合物的提取物；0.1～5重量份的苦参提取物；1～3重量份的芦荟提取物；1～10重量份的鲜橘皮提取物；0.5～3重量份的天竺兰提取物；0.5～10重量份的桉树提取物；1～8重量份的山刺槐提取物；1～5重量份的菊花提取物；0.1～2重量份的青蒿素。
在一种优选的实施方式中，所述空气清新剂组合物，包括组分A和组分B；所述组分A和组分B的重量比为1：1～3；
所述组分A，以重量份计，包括18～28重量份的活性剂；8～12重量份的载体；2～3重量份的pH调节剂；0.1～0.2重量份的抗氧化剂；
所述活性剂包括至少含有两个羟基的化合物；所述载体包括碳原子数为16～24的有机酸；
所述组分B为植物提取液，以重量份计，所述植物提取液至少包括：15～28重量份的意大利黑杨、葡萄柚皮、桉树叶混合物的提取物；1～3重量份的苦参提取物；1.5～3重量份的芦荟提取物；3～8重量份的鲜橘皮提取物；1～2重量份的天竺兰提取物；3～10重量份的桉树提取物；2～6重量份的山刺槐提取物；2～4重量份的菊花提取物；0.5～1.5重量份的青蒿素。
在一种优选的实施方式中，所述空气清新剂组合物，包括组分A和组分B；所述组分A和组分B的重量比为1：2；
所述组分A，以重量份计，包括25重量份的活性剂、10重量份的载体、2.5重量份的pH调节剂、0.1重量份的抗氧化剂；
所述活性剂包括至少含有两个羟基的化合物；所述载体包括碳原子数为16～24的有机酸；
所述组分B为植物提取液，以重量份计，所述植物提取液至少包括：25重量份的意大利黑杨、葡萄柚皮、桉树叶混合物的提取物；2重量份的苦参提取物； 3重量份的芦荟提取物；7重量份的鲜橘皮提取物；1.5重量份的天竺兰提取物；8重量份的桉树提取物；5重量份的山刺槐提取物；4重量份的菊花提取物；1重量份的青蒿素。
在一种优选的实施方式中，所述活性剂选自：乙二醇、丙二醇、丁二醇、聚乙二醇、丙三醇、1,3,5-环己烷三醇中的任意一种或几种的混合。
在一种优选的实施方式中，所述载体选自：棕榈酸、硬脂酸、花生酸、山嵛酸中的任意一种或几种的混合。
在一种优选的实施方式中，所述空气清新剂组合物中，所述意大利黑杨、葡萄柚皮、桉树叶混合物的提取物的提取方法为：
将干燥的意大利黑杨树叶、葡萄柚皮、桉树叶按重量比为10：5：2称取后粉碎，加入质量分数为95% 的乙醇，浸泡3～10h后使用微波加热提取2～3次，过滤，滤液经减压浓缩至无乙醇，即得。
在一种优选的实施方式中，所述天竺兰提取物的提取方法为：
将称取干燥的天竺兰粉碎后，采用白醋浸泡1～3h后，再加入60% 的乙醇，浸泡2～5h后使用微波加热提取2～3次，过滤，滤液经减压浓缩至无白醋和乙醇，即得。
在一种优选的实施方式中，所述空气清新剂组合物中，所述组分B中还包括1重量份的留兰香和麻籽混合物的提取物。
本发明的第二个方面提供了一种空气清新剂组合物的制备方法，至少包括以下步骤：
组分A：将载体加入到水中，在60～90℃下，搅拌2～5h后加入相应重量份的活化剂、pH调节剂、抗氧化剂，在40～60℃下，搅拌1～3h，备用；
组分B：将各种植物提取物混合后，在20～40℃下，搅拌1～2h，备用；
将组分A加入到组分B，在30～50℃下，搅拌1～5h，蒸干，得到膏状固体型空气清新剂组合物。
本发明的第三个方面提供了一种空气清新剂制品，所述空气清新剂制品包括上述空气清新剂组合物。
具体实施方式
参选以下本发明的优选实施方法的详述以及包括的实施例可更容易地理解本发明的内容。除非另有限定，本文使用的所有技术以及科学术语具有与本发明所属领域普通技术人员通常理解的相同的含义。当存在矛盾时，以本说明书中的定义为准。
如本文所用术语“由…制备”与“包含”同义。本文中所用的术语“包含”、“包括”、“具有”、“含有”或其任何其它变形，意在覆盖非排它性的包括。例如，包含所列要素的组合物、步骤、方法、制品或装置不必仅限于那些要素，而是可以包括未明确列出的其它要素或此种组合物、步骤、方法、制品或装置所固有的要素。
连接词“由…组成”排除任何未指出的要素、步骤或组分。如果用于权利要求中，此短语将使权利要求为封闭式，使其不包含除那些描述的材料以外的材料，但与其相关的常规杂质除外。当短语“由…组成”出现在权利要求主体的子句中而不是紧接在主题之后时，其仅限定在该子句中描述的要素；其它要素并不被排除在作为整体的所述权利要求之外。
当量、浓度、或者其它值或参数以范围、优选范围、或一系列上限优选值和下限优选值限定的范围表示时，这应当被理解为具体公开了由任何范围上限或优选值与任何范围下限或优选值的任一配对所形成的所有范围，而不论该范围是否单独公开了。例如，当公开了范围“1至5”时，所描述的范围应被解释为包括范围“1至4”、“1至3”、“1至2”、“1至2和4至5”、“1至3和5”等。当数值范围在本文中被描述时，除非另外说明，否则该范围意图包括其端值和在该范围内的所有整数和分数。
单数形式包括复数讨论对象，除非上下文中另外清楚地指明。“任选的”或者“任意一种”是指其后描述的事项或事件可以发生或不发生，而且该描述包括事件发生的情形和事件不发生的情形。
说明书和权利要求书中的近似用语用来修饰数量，表示本发明并不限定于该具体数量，还包括与该数量接近的可接受的而不会导致相关基本功能的改变的修正的部分。相应的，用“大约”、“约”等修饰一个数值，意为本发明不限于该精确数值。在某些例子中，近似用语可能对应于测量数值的仪器的精度。在本申请说明书和权利要求书中，范围限定可以组合和/或互换，如果没有另外说明这些范围包括其间所含有的所有子范围。
此外，本发明要素或组分前的不定冠词“一种”和“一个”对要素或组分的数量要求(即出现次数)无限制性。因此“一个”或“一种”应被解读为包括一个或至少一个，并且单数形式的要素或组分也包括复数形式，除非所述数量明显旨指单数形式。
本发明的第一个方面提供了一种空气清新剂组合物，包括组分A和组分B；所述组分A和组分B的重量比为1：0.5～3；
所述组分A，以重量份计，包括10～30重量份的活性剂；6～15重量份的载体；1～4重量份的pH调节剂；0.01～0.2重量份的抗氧化剂；
所述活性剂包括至少含有两个羟基的化合物；所述载体包括碳原子数为16～24的有机酸；
所述组分B为植物提取液，以重量份计，所述植物提取液至少包括：5～30重量份的意大利黑杨、葡萄柚皮、桉树叶混合物的提取物；0.1～5重量份的苦参提取物；1～3重量份的芦荟提取物；1～10重量份的鲜橘皮提取物；0.5～3重量份的天竺兰提取物；0.5～10重量份的桉树提取物；1～8重量份的山刺槐提取物；1～5重量份的菊花提取物；0.1～2重量份的青蒿素。
组分A
本发明中，所述“组分A”包括10～30重量份的活性剂、6～15重量份的载体、1～4重量份的pH调节剂、0.01～0.2重量份的抗氧化剂。
所述活性剂包括至少含有两个羟基的化合物，可以列举的有：
乙二醇、丙二醇、丁二醇、聚乙二醇、丙三醇、1,3,5-环己烷三醇中的任意一种或几种的混合。
所述载体包括碳原子数为16～24的有机酸，可以列举的有：棕榈酸、珠光脂酸、硬脂酸、十九烷酸、花生酸、二十一烷酸、山嵛酸、二十三烷酸、木质素酸。
在一种优选的实施方式中，所述载体选自：棕榈酸、硬脂酸、花生酸、山嵛酸中的任意一种或几种的混合。
所述pH调节剂，可以列举的有：氢氧化钠、氢氧化钾、氢氧化钙、碳酸氢钠、磷酸氢二钠中的任意一种或几种的混合。
所述抗氧化剂，可以列举的有：作为添加剂的具体例子，可列举醋酸盐维他命E、苯酚类抗氧剂、磷类抗氧剂、硫类抗氧剂等各种抗氧剂；受阻胺类热稳定剂等各种热稳定剂；无机抗菌剂、有机抗菌剂、防霉剂等。
作为苯酚类抗氧剂的实例，包括但不限于：1-羟基-3-甲基-4-异丙基苯、2, 6-二叔丁基苯酚、2, 6-二叔丁基-4-乙基苯酚、2, 6-二叔丁基对甲酚、2, 6-二叔丁基-4-正丁基苯酚、4-羟甲基-2, 6-二叔丁基苯酚、叔丁基羟基茴香醚、2-(1-甲基环己基)-4, 6-二甲基苯酚、2, 4-二甲基-6-叔丁基苯酚、2-甲基-4, 6-二壬基苯酚、2, 6-二叔丁基-α-二甲氨基-对甲酚、2, 4, 6-三叔丁基苯酚、6-(4-羟基-3, 5-二叔丁基苯胺基)-2, 4-双(辛基硫代)-1, 3, 5-三嗪、4, 6-双(4-羟基-3, 5-二叔丁基苯氧基)-2-正辛基硫代-1, 3, 5-三嗪、β-(3, 5-二叔丁基-4-羟基苯基)丙酸甲酯、β-(4—羟基—3, 5—二叔丁基苯基)丙酸正十八碳醇酯、苯乙烯化苯酚、4, 4′-二羟基联苯、丁基化辛基化苯酚、丁基化苯乙烯化甲酚、2, 2′-甲撑双(4-甲基-6-叔丁基苯酚)或2, 2′-甲撑双(6-叔丁基-4-甲酚)、2, 2′-甲撑双(4-乙基-6-叔丁基苯酚)、2, 2′-甲撑双(4-甲基-6-环己基苯酚)、4, 4′-甲撑双(2, 6-二叔丁基苯酚)、2, 2′-甲撑双(6-α-甲基苄基对甲酚)、1, 1-双(4-羟基苯)环己烷、2, 2′-甲撑双〔4-甲基-6-(α-甲基环己基)苯酚〕或2, 2′-二羟基-3, 3′-二(α-甲基环己基)-5, 5′-二甲基二苯基甲烷、1, 3, 5-三甲基-2, 4, 6-三(3, 5-二叔丁基-4-羟基苄基)苯、1, 1, 3-三(2-甲基-4-羟基-5-叔丁基苯基)丁烷、四〔3-(3′5′-二叔丁基-4′-羟基苯基)丙酸〕季戊四醇酯、4, 4′-硫代双(6-叔丁基-3-甲基苯酚)或4, 4′-硫代双(6-叔丁基间甲酚)、4, 4′-硫代双(2-甲基-6-叔丁基苯酚)或4, 4′-硫代双(6-叔丁基邻甲酚)、2, 2′-硫代双(4-甲基-6-叔丁基苯酚)、己二醇双〔β-(3, 5-二叔丁基-4-羟基苯基)丙酸酯〕、2, 2′-硫代双〔3, -(3, 5-二叔丁基-4-羟基苯基)丙酸乙酯〕、N, N′-六甲撑双(3, 5-二叔丁基-4-羟基苯丙酰胺)、1, 3, 5-三(4-叔丁基-3-羟基-2, 6-二甲基苄基)1, 3, 5—三嗪-2, 4, 6-(1H, 3H, 5H)-三酮、1, 3, 5-三(3, 5-二叔丁基-4-羟基苄基)均三嗪-2, 4, 6-(1H, 3H, 5H)三酮或异氰脲酸三(3, 5-二叔丁基-4-羟基苄基酯)、异氰脲酸三[β-(3, 5-二叔丁基-4-羟基苯基)丙酰氧基乙酯]、双[3, 3-双(3′-叔丁基-4′-羟基苯基)丁酸]乙二醇酯、1, 1′-硫代双(2-萘酚)、双(3, 5-二叔丁基-4-羟基苄基)硫醚、2, 5-二叔丁基对苯二酚、2, 5-二叔戊基对苯二酚、3, 5-二叔丁基-4-羟基苄基磷酸二(十八)酯、3, 5-二叔丁基-4-羟基苄基磷酸二乙酯、三甘醇双-3-(3-叔丁基-4-羟基-5-甲基苯基)丙酸酯、对苯二酚二苄醚中的任意一种。
作为亚磷酸酯类抗氧剂的实例，包括但不限于：亚磷酸三苯酯、亚磷酸三(壬基苯酯)、亚磷酸三异辛酯、亚磷酸三异癸酯、亚磷酸苯二异癸酯、三硫代亚磷酸三月桂酯、亚磷酸三月桂酯、亚磷酸三(十八酯)、二亚磷酸季戊四醇二异癸酯、二亚磷酸季戊四醇二硬脂醇酯、4, 4′-丁叉双〔亚磷酸(3-甲基-6-叔丁基苯基)二(十三烷基)酯〕、亚磷酸二苯异辛酯、亚磷酸苯二异辛酯、亚磷酸二苯辛酯、亚磷酸二苯异癸酯、亚磷酸二辛酯、亚磷酸二月桂酯、亚磷酸二甲酯、亚磷酸二油醇酯、亚磷酸二癸酯、亚磷酸二丁酯、亚磷酸双十三酯、亚磷酸双十四酯、亚磷酸三乙酯、亚磷酸三丁酯、亚磷酸三异丙酯、亚磷酸三辛酯或亚磷酸三(2-乙基己酯)、亚磷酸-苯双(壬基苯)酯、亚磷酸二苯壬基苯酯、亚磷酸三(2, 4-二叔丁基苯基)酯中的任意一种。
作为含硫酯类抗氧剂的实例，包括但不限于：硫代二丙酸二月桂酯、硫代二丙酸二硬脂醇酯或硫代二丙酸二(十八酯)、β, β′-硫代二丁酸二(十八)酯、硫代二丙酸月桂十八酯、硫代二丙酸二(十三)酯、硫代二丙酸二(十四)酯中的任意一种。
组分B
所述组分B为植物提取液，以重量份计，所述植物提取液至少包括：5～30重量份的意大利黑杨、葡萄柚皮、桉树混合物的提取物、0.1～5重量份的苦参提取物、1～3重量份的芦荟提取物、1～10重量份的鲜橘皮提取物、0.5～3重量份的天竺兰提取物、0.5～10重量份的桉树提取物、1～8重量份的山刺槐提取物、1～5重量份的菊花提取物0.1～2重量份的青蒿素、0.5～3重量份的苦参碱。
意大利黑杨
本发明中，所述“意大利黑杨”又称意大利杨树，落叶大乔木，树冠长卵形，树皮灰褐色，浅裂。叶片三角形，基部心形，有2-4腺点，叶长略大于宽，叶深绿色，质较厚。叶柄扁平。
葡萄柚皮
本发明中，所述“葡萄柚皮”为芸香科植物柚的果皮。秋末、冬初收集，剖成5～7瓣的干燥果皮，伸长后的皮片直径约为25～32厘米，每单瓣长10～13厘米，宽5～7厘米，厚0.5～1厘米。皮片边缘略向内卷曲；外表面黄棕色或枯黄色，有时呈微金黄色，极粗糙，有多数凹下的圆点及突起的油点；内表面白色，稍呈棉絮状。质柔软，有浓厚的柚子香气。
桉树叶
本发明中，所述“桉树叶”又称为桉树叶、蓝桉叶、羊草果叶。本品呈镰刀状披针形，长8-30cm，宽2-7cm；革质而厚；叶端尖，叶端尖，叶基不对称，全缘；叶柄较短，长1-3cm，扁平而扭转。表面黄绿色，光滑无毛，有多数红棕色木栓斑点，对光透视，可见无数透明小点（油室）。羽状网脉，侧脉末端于叶缘处连合，形成与叶缘相平行的脉纹。揉之微有香气，味稍苦而凉。以叶大、完整、梗少、无杂质者为佳。
自叶中分离到大果桉醛（macrocarpal)A，B，C，D，E，正三十三烷-16，18-二酮（n-tritriacontane-16,18-dione)，叶和花蕾中含有蓝桉醛（euglobal)，叶中还含有黄酮类化合物：槲皮素（quercetol即quercetin)，槲皮甙（querictrin)，芸香甙（rutin），金丝桃甙（hyperoside)，槲皮素葡萄糖甙（quercetol-3-glucoside)，以及没食子酸（gallic acid)，咖啡酸（caffeic acid)，阿魏酸（ferulic acid)，龙胆酸（gallic acid)，原儿茶酸（protocate-chuic acid)。叶面的蜡中含有5, 4-二羟基-7-甲氧基甲基黄酮（5, 4-dihydroxy-7-methoxy-6-methylflavone)，白杨素（chrysin)，桉树素（eucalyptin)，8-去甲基桉树素（8-demethyleu-calyptin)，及4, 5-二羟基-7-甲氧基-6, 8-二甲基黄酮（sideroxylin)。叶中的按发油主含桉叶素（cineole)，另有丁香烯（caryophyllene)。树皮和木质部中分离到三十三烷-16, 18-二酮，3-O-甲基并没食子酸-4-鼠李糖甙（3-O-methylellagic acid-4-rhamnoside)，并没食子酸（ellagic acid)及并没食子鞣质（el-lagitannin)。
在一种优选的实施方式中，所述意大利黑杨、葡萄柚皮、桉树混合物的提取物的提取方法为：
将干燥的意大利黑杨树叶、葡萄柚皮、桉树树叶按重量比为10：5：2称取后粉碎，加入质量分数为95% 的乙醇，浸泡3～10h后使用微波加热提取2～3次，过滤，滤液经减压浓缩至无乙醇，即得。
微波是频率大约在300 MHz~300 GHz，即波长在100 cm~1 mm范围内的电磁波，它位于电磁波谱(光波)和无线电波之间。微波是一个十分特殊的电磁波段，其性能近似太阳光的性质，波速与光速相同，都为3×108m/s，波长为12.24 cm，振荡频率为每秒24.5亿次。
微波萃取，亦称微波辅助萃取是指主要应用微波的热效应对样品及其有机溶剂进行加热，将待测组分从样品基体中提取出来的一种方法。从宏观上讲，微波萃取实际上主要是微波对萃取溶剂及样品的加热作用，它能够穿透萃取溶剂和物料使整个***更加均匀地加热：从微观上讲，微波所产生的电磁场加速样品向萃取溶剂界面的扩散速率。
微波萃取的机理可从两方面考虑：一方面，微波所产生的电磁场加速被萃取部分成分向萃取溶剂界面扩散速率，用水作溶剂时，在微波场下，水分子高速转动成为激发态，这是一种高能量不稳定状态，或者水分子气化，加强萃取组分的驱动力；或者水分子本身释放能量回到基态，所释放的能量传递给其他物质分子，加速其热运动，缩短萃取组分的分子由样品内部扩散到萃取溶剂界面的时间，从而使萃取速率提高数倍，同时还降低了萃取温度，最大限度保证萃取的质量。另一方面，微波能是一种由离子迁移和偶极子转动引起分子运动的非离子化辐射能。当它作用于分子上时，促进了分子的转动运动，分子若此时具有一定的极性，便在微波电磁场作用下产生瞬时极化，并以 24.5 亿次/秒的速度做极性变换运动，从而产生键的振动、撕裂和粒子之间的相互摩擦、碰撞，促进分子活性部分(极性部分)更好地接触和反应，同时迅速生成大量的热能。由于吸收微波能，细胞内部温度迅速上升，使其细胞内部压力超过细胞壁膨胀承受能力，细胞破裂。细胞内有效成分自由流出，在较短的时间内萃取介质被捕获并溶解。
在一种优选的实施方式中，所述意大利黑杨、葡萄柚皮、桉树叶混合物的提取物的提取方法为：
将干燥的意大利黑杨树叶、葡萄柚皮、桉树叶按重量比为10：5：2称取后粉碎，加入质量分数为95% 的乙醇，浸泡3～10h后使用微波加热提取2～3次，过滤，滤液经减压浓缩至无乙醇，即得。
苦参
本发明中，所述“苦参”为豆科植物苦参的干燥根。春、秋二季采挖，除去根头及小支根，洗净，干燥，或趁鲜切片，干燥。
本品呈长圆柱形，下部常有分枝，长10～30cm，直径1～2cm。表面灰棕色或棕黄色，具纵皱纹及横长皮孔，外皮薄，多破裂反卷，易剥落，剥落处显黄色，光滑。质硬，不易折断，断面纤维性；切片厚3～6mm；切面黄白色，具放射状纹理及裂隙，有的可见同心性环纹。气微，味极苦。
自苦参根中分离到：苦参碱（matrine），氧化苦参碱（oxymatrine），N-氧化槐根碱（N-oxysophocarpine）、槐定碱（sophoridine），右旋别苦参碱（-allomatrine），右旋异苦参碱（I-somatrine），右旋槐花醇（sophoranol），（＋）槐花醇N-氧化物（sophoranol N-oxide），左旋槐根碱（sophocarpine），左旋槐胺碱（sophoramine），右旋-N-甲基金雀花碱（N-methylcytisine），左旋臭豆碱（anagyrine），赝靛叶碱（baptifoline）。根中还含多种黄酮类化合物：苦参新醇（kushenol）A、B、C、D、E、F、G、H、I、J、K、L、M、N、O，苦参查耳酮（kuraridin），苦参查耳酮醇（kuraridinol），苦参醇（kurarinol），新苦参醇（neokurarinol），降苦参醇（norkurarinol），异苦参酮（isokurarinone），刺芒柄花素（for-mononetin），苦参酮（kurarinone），降苦参酮（norkurarinone），甲基苦参新醇C（methylkushenol C），l-山槐素（lmaackiain），三叶豆紫檀甙（trifolirhizin）及三叶豆紫檀甙丙二酸酯（rtifolirhizin-6”-O-malonate），苦参素（kushenin），异脱水淫羊藿素（isoanhy-droicaritin），降脱水淫羊藿素（noranhydroicaritin），黄腐醇（xan-thohumol），异黄腐酸（isoxanthohumol），木犀草素-7-葡萄糖甙（luteolin-7-glucoside）。此外，根中还含有三萜皂甙：苦参皂甙（sophoraflavoside）Ⅰ，Ⅱ、Ⅲ、Ⅳ，大豆皂甙（soyasaponin）I以及醌类化合物：苦参醌（kushequinone）A。地上部分含生物碱：苦参碱，氧化苦参碱，右旋一别苦参减，异苦参碱，槐花醇，槐花醇N-氧化物，臭豆碱，赝靛叶碱，左旋-N-甲基金雀花碱，左旋-槐根碱，左旋-槐胺碱，右旋-N-氧化槐根碱，左族-△7-脱氢槐胺碱（△7-dehydrosophoramine），异槐根碱（isosophocarpine），左旋-13, 14去氢槐定碱（13, 14-dehy-drosophoridine），右旋-9a-羟基苦参碱（9a-hydroxymatrine），左旋-9a-羟基槐根碱（9a-hydroxysophocarpine），左旋-9a-羟基槐根碱-N-氧化物（9a-hydroxysophocarpine N-oxide），左旋-7, 8-脱氢槐胺碱（7, 8-dehydrosophoramine），左旋-9a-羟基槐胺碱（9a-hydrox-ysophoramine），N-甲基金雀花碱二聚体（dimer of N-methyleyti-sine），槐定碱，有旋-12-去氢苦参碱（lehmannine）。还含2-烷基色酮衍生物（2-alkylchromone derivatives），其中以2-正二十一烷基-5, 7-二羟基-6, 8-二甲基色酮（2-n-heneicosyl-5, 7-dihydroxy-6, 8-dimethyl chromone）和2-正二十三烷基-5, 7-二羟基-6, 8-二甲基色酮（2-n-tricosyl-5, 7-dihydroxy-6, 8-dimethylchromone）为主，还有2-正十三烷基（2-n-tridecyl）-、2-正十五烷基（2-n-pentadecyl）-、2-正十七烷基（2-n-heptadecyl）-、2-正十九烷基（2-n-nonadecyl）和2-正二十五烷基（2-n-pentacosyl）-的5,7-二羟基-6, 8-二甲基色酮（5, 7-dihydroxy-6, 8-dimethyl chromone）。
在一种优选的实施方式中，所述苦参的提取方法为：取5 g干燥的当归，碾成粉末，在40℃下加入100 mL的质量浓度为80% 的乙醇，加热回流2小时用超声波提取2～5 h，提取5次，合并提取液，过滤后浓缩至无乙醇，即得。
芦荟
本发明中，所述“芦荟”为百合科耐旱性草本植物，主要分布于非洲等地，具有抗菌、消炎和通便的作用，常用于治疗肝热、胀气、便秘、头痛、湿癣和结石等。多糖类和蒽醌类物质在新鲜芦荟中含量丰富，是主要活性部位。芦荟凝胶含有大量的糖类成分，大多是不同种类的葡甘聚糖，其中乙酰化的甘露聚糖有较高的生物活性。含有的其它单糖则为常见的***糖、半乳糖、葡萄糖、甘露糖和鼠李糖等。蒽醌类物质多分布于皮下栅栏组织中，以芦荟苷和芦荟大黄素为主，它们部分与多糖结合成糖蛋白，部分以酶的形式存在，如羟基肽酶、过氧化氧酶、纤维素酶和超氧化物歧化酶等，芦荟中还含有乳酸、琥珀酸、苹果酸、对香豆酸、丁二酸和柠檬酸等。
在一种优选的实施方式中，所述芦荟的提取方法为：将20g芦荟洗净后，切碎，和炼蜜混匀后加热至60℃，保温3 h，冷却后以水作为溶剂，用超声波提取3～5 h，提取3次，合并提取液，过滤后浓缩至无水，即得。
术语“炼蜜”是指：将蜂蜜置锅内，加热至徐徐沸腾后，改用文火，保持微沸，并除去泡沫及上浮蜡质，然后用罗筛或纱布滤去死蜂、杂质，再倾入锅内，加热至100℃～118℃，满锅起鱼眼泡，用手捻之有粘性，两指间尚无长白丝出现时，迅速出锅。
鲜桔皮提取物
本发明中，所述“鲜桔皮”主要成分为苎烯(甲基丙烯基环己烯)的单环萜烯，沸点为175.5-176℃，具有柑橘(柠檬)水果香味，柠檬油本身不溶于水，添加活性剂后与水任意比例混配。
鲜桔子皮中含有大量的维生素C和香精油，桔皮含有挥发油，油中的主要成分是柠檬烯、枸橼醛，还有川陈皮酮、橙皮甙、肌醇、维生素B1等。对消化道有缓和的刺激作用，有利于胃肠积气的排出。促进胃液的分泌；舒张支气管。桔皮粥，有理气化痰之力，增强健胃养胃之效。降血脂、升血压或对急性乳腺炎的治疗。
桔子皮目前已分离出30余种物质，其中主要有：类黄酮、单萜、香豆素、类胡萝卜素、类丙醇、吖啶酮、甘油糖脂质等。
类黄酮：柑橘类水果所含的类黄酮有三种类型：Ⅰ型是以芦丁为代表的一般性黄酮类；Ⅱ型是橘皮苷、柚皮苷之类柑橘类水果特有的黄烷酮；Ⅲ型是其他蔬菜水果中至今尚未发现而只有柑橘类才具有的柑橘黄酮等含有聚甲氧基的特殊黄酮类物质。
类胡萝卜：众所周知，许多蔬菜、水果中含有类胡萝卜素，这是对人体健康具有重要作用的成分。对类胡萝卜素的生理功能及其机理的研究近年发展很快，我国也已利用这类物质研制成一些保健食品并实现了工业化生产。
香豆素：柑橘中所含有的香豆素是目前已被科学家充分肯定的抗癌物质。研究结果表明，香豆素的抗癌功能形成途径主要有二：一是香豆素通过解毒酶的作用使癌物质解毒；二是与癌物质拮抗抑制其代谢的活性化。这两方面的作用主要在癌的起始阶段产生抑制效果。
单萜、三萜柑橘中含有大量以柠檬烯为代表的萜类化合物。萜是构成柑橘独特芳香的物质，具有使人的中枢神经镇静化的作用。
柠檬苦素：柠檬苦素是桔子皮的苦味成分。
在一种优选的实施方式中，所述鲜橘皮提取物的制备方法为：将15g的鲜桔皮***粉碎至100-200目，和2-巯基苯并噻唑共混，用乙醇作为溶剂进行提取。
天竺兰
本发明中，所述“天竺兰”，又名红天竹，是双子叶植物纲南小檗科天竹属科属，产我国长江流域江苏、浙江及陕西、广西等省区，日本、印度也有。大多生在湿润的沟谷旁。疏林下或灌丛中，为钙质土指标植物。南北各地园林中均有栽培。喜温暖多湿及通风良好的半阴环境。较耐寒，黄河以南可露地栽培。果实成熟后留枝上观赏，温度需保持在10摄氏度左右。盆栽者春、夏季宜置荫棚中养护。能耐微碱性土壤。萌蘖力强，一般为多干丛生。为常绿灌木。其根、茎可清热除湿，通经活络。
在一种优选的实施方式中，所述天竺兰的提取物的制备方法为：称取10 g干燥的天竺兰粉碎后，采用白醋浸泡1～3h后，再加入60% 的乙醇，浸泡2～5h后使用微波加热提取2～3次，过滤，滤液经减压浓缩至无白醋和乙醇，即得。
桉树
本发明中，所述的“桉树”又称尤加利树，是桃金娘科杯果木属、伞房属和桉树属植物的统称，原产地印尼和澳大利亚等地。
所述“桉树”的种类可以列举的有：蓝桉、直干蓝桉、柠檬桉、大叶桉、观叶型铜钱桉、尾叶桉、巨桉、细叶桉、蓝桉、邓恩桉、柳桉、尾巨桉、巨尾桉、尾赤桉、尾赤桉、赤桉、邓恩桉等。
桉树皮提取物主要的成分是五环三萜化合物，例如乌索酸、桦木酸、齐墩果酸、熊果酸、白桦脂酸、桦木脂酸、桦木酮酸、3-β-O-反式对羟基肉桂酰基-12-烯-28-齐墩果酸、3-β-O-反式对羟基肉桂酰基-2σ-羟基-12-烯蕊-乌苏酸。
桉树叶提取物主要成分是1,8-桉叶素、蒎烯、香橙烯、枯醛、松香芹醇和1-乙酰-4-异丙叉环戊烯等，又含芸香甙、槲皮甙、槲皮素、高丝氨酸、还分出桉树素。桉叶中的其他成分，如萜类、黄酮类、鞣质、间苯三酚类和糖苷类等也具有丰富的生物活性。
本发明中所述桉树提取物为大叶桉的树叶和桉树皮按照重量比为1：18共混，提取；所述桉树叶由春季采摘，树龄为3年生。
在一种优选的实施方式中，所述桉树提取物的制备方法为：称取重量比为1：18共混的大叶桉桉树皮和大叶桉桉树叶的粉末，加入乙醇，浸泡2-3h后使用微波加热提取2-3次，过滤，滤液经减压浓缩至无乙醇，即得。
山刺槐
本发明中的“山刺槐”，又名刺槐，洋槐，豆科、刺槐属落叶乔木，树皮灰褐色至黑褐色，浅裂至深纵裂，稀光滑。按品种分类，刺槐又分为直杆刺槐、金叶刺槐、曲枝刺槐、柱状刺槐、球冠刺槐、龟甲皮刺槐、红花刺槐、无刺刺槐、小叶刺槐、箭杆刺槐、黄叶刺槐、球槐、粉花刺槐和泓森槐。
本发明中，所述刺槐选择金叶刺槐、粉花刺槐和红花刺槐按照重量份比为1：1：50共混进行提取。
所述刺槐提取物优选对刺槐的叶和花进行提取。
在一种优选的实施方式中，所述刺槐提取物的制备方法为：
（1）将金叶刺槐的叶子、粉花刺槐的叶子和红花刺槐的叶子按照重量份比为1：1：50共混、洗净、切碎，然后用氨水湿润后，加入乙醇，回流1-3小时，趁热过滤，浓缩至无乙醇，即得刺槐的叶的提取物。
（2）将金叶刺槐的花、粉花刺槐的花和红花刺槐的花按照重量份比为0.5：0.8：1.2共混、洗净、切碎，加入蜂蜜，回流1-3小时，趁热过滤，浓缩至无乙醇，即得刺槐的花的提取物。
（3）将步骤1和步骤2中刺槐的叶的提取物和花的提取物共混，加入乙醇，超声搅拌2.5小时，浓缩至无乙醇，即得刺槐的提取物。
菊花
本发明中，所述“菊花”，在植物分类学中是菊科、菊属的多年生宿根草本植物。按栽培形式分为多头菊、独本菊、大立菊、悬崖菊、艺菊、案头菊等栽培类型。性凉，味苦、辛，归肝、心经。
菊花的化学成分分为：挥发油成分、黄酮类成分、酚酸类成分和其他成分。
挥发油的组成主要为单萜烯类、倍半萜烯类及其含氧衍生物和脂肪族化合物等，还含有菊花内酯、菊花醇、菊花三醇、菊花酮、顺-螺烯醇醚、反-螺烯醇醚、当归酰豚草素B、当归酰亚菊素、苏格兰蒿素A、豚草素A、熊果酸、β-谷甾醇等。
黄酮类成分：主要成分有木樨黄酮甙、蒙花苷、木犀草素、洋芹素、金合欢素-7-鼠李糖葡萄糖甙、木犀草素-7-葡萄糖甙、槲皮素甙类、芹菜素-7-O-β-D-吡喃葡萄苷、香叶木素-7-O-β-D-吡喃葡糖苷、槲皮素-3,7-二-O-β-D-吡喃葡糖苷、圣草酚-7-O-β-D-吡喃葡糖苷酸、1-苯基-2,3-丁二醇-3-O-β-D-吡喃葡糖苷和橙皮素-7-O-β-D-吡喃葡萄糖醛酸苷。
酚酸类成分：有3-O-咖啡酰基奎宁酸，4-O-咖啡酰基奎宁酸，5-0-咖啡酰基奎宁酸，3,5-二咖啡酰奎宁酸甲酯，3,5-二咖啡酰奎宁酸，3,5-二顺式咖啡酰奎宁酸，1,5-二咖啡酰奎宁酸，1,3-二咖啡酰奎宁酸和绿原酸等。
其他成分：除挥发油类成分、黄酮类成分和酚酸类成分以外，还含有各种微量元素，如Ca、Mg、Fe等，还含有蛋白质、氨基酸、胆碱、水苏碱、嘌呤、鞣质、维生素、叶绿素、胡萝卜素、山箭酸甘油酯和棕桐酸等。
菊花提取物的方法有很多种，例如：回流提取法、超声提取法、水蒸气蒸馏法、微波提取法、组织破碎提取法及超临界二氧化碳萃取法。
在一种优选的实施方式中，所述菊花提取物的提取方法为：称取5g菊花，切碎，加入乙醇，浸泡2-3h后使用微波加热提取2-3次，过滤，滤液经减压浓缩至无乙醇，即得。
青蒿素
本发明中，所述“青蒿素”为从复合花序植物黄花蒿中提取得到的一种无色针状晶体，化学名称为（3R,5aS,6R,8aS,9R,12S,12aR）-八氢-3,6,9-三甲基-3,12-桥氧-12H-吡喃〔4,3-j〕-1,2-苯并二塞-10（3H）-酮。分子式为C15H22O5，属倍半萜内酯，具有过氧键和6-内酯环，有一个包括过氧化物在内的1,2,4-三呃烷结构单元，这在自然界中十分罕见，分子中包括有7个手性中心，其特征是A，B环顺联，异丙基与桥头氢呈反式关系。制备熔点为156-157℃，[a]D17=+66.3°（C=1.64氯仿）。易溶于氯仿、丙酮、乙酸、乙酯和苯，可溶于乙醇、***，微溶于冷石油醚，几乎不溶于水。因其具有特殊的过氧基团，它对热不稳定，易受湿、热和还原性物质的影响而分解。
本发明中，所述青蒿素购买于陕西森朗生物化工有限公司。
在一种优选的实施方式中，所述空气清新剂组合物，包括组分A和组分B；所述组分A和组分B的重量比为1：1～3；
所述组分A，以重量份计，包括18～28重量份的活性剂；8～12重量份的载体；2～3重量份的pH调节剂；0.1～0.2重量份的抗氧化剂；
所述活性剂包括至少含有两个羟基的化合物；所述载体包括碳原子数为16～24的有机酸；
所述组分B为植物提取液，以重量份计，所述植物提取液至少包括：15～28重量份的意大利黑杨、葡萄柚皮、桉树叶混合物的提取物；1～3重量份的苦参提取物；1.5～3重量份的芦荟提取物；3～8重量份的鲜橘皮提取物；1～2重量份的天竺兰提取物；3～10重量份的桉树提取物；2～6重量份的山刺槐提取物；2～4重量份的菊花提取物；0.5～1.5重量份的青蒿素。
在一种优选的实施方式中，所述空气清新剂组合物，包括组分A和组分B；所述组分A和组分B的重量比为1：2；
所述组分A，以重量份计，包括25重量份的活性剂、10重量份的载体、2.5重量份的pH调节剂、0.1重量份的抗氧化剂；
所述活性剂包括至少含有两个羟基的化合物；所述载体包括碳原子数为16～24的有机酸；
所述组分B为植物提取液，以重量份计，所述植物提取液至少包括：25重量份的意大利黑杨、葡萄柚皮、桉树叶混合物的提取物；2重量份的苦参提取物； 3重量份的芦荟提取物；7重量份的鲜橘皮提取物；1.5重量份的天竺兰提取物；8重量份的桉树提取物；5重量份的山刺槐提取物；4重量份的菊花提取物；1重量份的青蒿素。
在一种优选的实施方式中，所述空气清新剂组合物中，组分B中还包括1重量份的留兰香和麻籽混合物的提取物。
留兰香
本发明中，所述“留兰香”，又名绿薄荷、香薄荷、荷兰薄荷、青薄荷、香花菜、鱼香菜。是一种唇形科直立多年生草本植物，茎直立，紫色或白色花，花期7-9月。温度适应范围大，喜湿润、喜光，适宜弱酸性土壤。茎、叶经蒸馏可提取留兰香油。
对唇形科薄荷属植物留兰香的活性部位进行***研究。采用溶剂法和各种层析方法。结果：分离得到7个化合物，分别鉴定为乌索烷，3-甲氧基-4-甲基苯甲醛，藜芦酸，5-羟基-6,7,3',4'-四甲氧基黄酮，香叶木素，5,6,4’-三羟基-7,8,3'-三甲氧基黄酮，胡萝卜苷。
植株含芳香油，含油率0.6-0.7%，其油称留兰香油或绿薄荷油，主要成分为香旱芹子油菇酮（含量为60-65%），此外亦有柠檬烃、水芹香油烃等，主用于糖果、牙膏用香料，亦供医药用。叶、嫩枝或全草亦入药，治感冒发热、咳嗽、虚劳咳嗽、伤风感冒、头痛、咽痛、神经性头痛、胃肠胀气、跌打瘀痛、目赤辣痛、鼻衄、乌疗、全身麻木及小儿疮疖。
全草（留兰香）：辛、甘，微温。祛风散寒，止咳，消肿解毒。用于感冒，咳嗽，胃痛，腹胀，神经性头痛；外用于跌打肿痛，目赤红痛，小儿疮疖。
麻籽
本发明中，所述“麻籽”，别名白麻籽、冬麻籽、火麻籽等，味甘、平，无毒。火麻属***科，俗称***，又称寒麻、线麻、魁麻、露麻、汉麻等，是一种日照短、一年生、叶掌状***且多为雌雄异株的草本植物，具有耐贫瘠性、抗逆性特点，生长范围广，在生物学方面具有喜光照、光合作用效率高的特性，在日照长的条件下生长状态旺盛，植株高度可高达3.5m。火麻可分为纤维用、药用和籽用三种。
麻籽油在常温下呈黄绿色半透明油状液体，放久后变成黄棕色，具有火麻籽特殊的清香气味。
普通火麻籽仁含油量为 30％-40％，亚油酸与亚麻酸的比例接近 2.5，这一比例是人体所需脂肪酸的最佳比例，同时各自的代谢活性产物亚油酸和硬脂酸含量也相当丰富。火麻籽油的脂肪酸组成中，主要为 C16和 C18脂肪酸,二不饱和亚油酸和三不饱和亚麻酸的量分数高达 85.80%，具有高不饱和度。目前鉴定，火麻籽油中含有 29 种化合物，其中脂肪酸有 18 种，占总含量的 99.12％，饱和脂肪酸 l1 种，以棕搁酸、硬脂酸、花生酸为主，含量分别为 8.81%、2.76%、0.59%，不饱和脂肪酸共 7 种，占总含量的 87％左右，单不饱和脂肪酸为棕搁油酸、油酸、花生烯酸，含量分别为 0.08%、8.92%、0.26%。多不饱和脂肪酸分别为γ—亚麻酸、亚麻酸、亚油酸，含量分别为 0.61％、24.42％、52.32％和二十碳-5, 8, 11, 14, 17-五烯酸，含量为 0.34％，火麻籽油中的脂溶性成分还包括 4 种酮、2 种醇和 3 种烃类物质。除此之外，还鉴定出二甲基丁酸、庚酸、2-甲基戊酸和二十碳-5, 8, 11, 14, 17—五烯酸以及酮、烃、醇等 13 种成分。
现阶段，提取麻籽油的方法有很多，例如：水酶法、超临界流体萃取法、溶剂浸出法、压榨法等。
本发明中，主要采取水剂法来提取麻籽油。
本发明中主要的提取步骤为：
(1) 原料预处理及烘烤
将火麻籽淘洗干净后再在一定的温度和时间下烘烤，烘烤使蛋白质发生变性，可溶性蛋白质变成不溶性蛋白质，原来的组织被破坏。油料中球蛋白发生变化，使亲水基转入不规则的分布状态，疏水基转入外部，包含在球蛋白内部的油脂露于表面并聚集。因此烘烤便于油脂的提取。
(2) 破碎
在利用水剂法提油时，需要对火麻籽进行研磨破碎，使油料细胞充分破裂，以便在兑浆搅油时浆与料浆充分混合使非油物质和水充分结合，尽量完全提取油脂并保证油的质量。
(3) 兑浆搅拌
首先将火麻籽破碎后按一定比例与一定温度的自来水混合，充分搅拌混匀，充分分散溶解到水中。此时，裸露在火麻籽表面的油脂被提取出来，然后对粉碎颗粒里的油脂进行进一步提取。在一定温度和搅拌速度下搅拌匀浆，最大限度提取匀浆中的油脂，进行恒温搅拌的过程中，水浸入火麻籽颗粒中与结合亲水性蛋白质，取代了火麻籽细胞中油脂的位置，从而使得油脂从料浆中释放出来。
(4) 离心分离
将得到浆料在 4000r／min条件下，离心20min，得到上层油层，下层料渣，得到麻籽油。
在一种优选的实施方式中，所述留兰香和麻籽混合物的提取物的提取方法为：称取5g留兰香，切碎，加入麻籽油，浸泡2-3h后，再加入质量溶度为50%的乙醇，使用微波加热提取2-3次，过滤，滤液经减压浓缩至无乙醇，即得。
本发明人意外的发现，空气清新剂组合物采用组分A和组分B进行复配，可以对空气中的甲醛、苯类污染物、氨类污染物以及挥发性有机物等具有非常好的去除效果。本发明人猜测可能的原因为，组分B 中的植物提取物中可以得到单宁类化合物、萜类化合物、酮类化合物等物质，这些物质可以对空气中的甲醛、苯类污染物、氨类污染物以及挥发性有机物不仅产生物理吸附而且还存在化学吸附作用力，从而达到净化空气的目的。同时，组分A可以与组分B配合，进一步增强组分B吸附效果，同时，还可以增强空气净化剂组合物的使用时间，达到长久的使用效果。
本发明的第二个方面提供了一种空气清新剂组合物的制备方法，至少包括以下步骤：
组分A：将载体加入到水中，在60～90℃下，搅拌2～5h后加入相应重量份的活化剂、pH调节剂、抗氧化剂，在40～60℃下，搅拌1～3h，备用；
组分B：将各种植物提取物混合后，在20～40℃下，搅拌1～2h，备用；
将组分A加入到组分B，在30～50℃下，搅拌1～5h，蒸干，得到膏状固体型空气清新剂组合物。
本发明的第三个方面提供了一种空气清新剂制品，所述空气清新剂制品包括上述空气清新剂组合物。
实施方式
实施方式1：本发明的实施方式1提供了一种空气清新剂组合物，其特征在于，包括组分A和组分B；所述组分A和组分B的重量比为1：0.5～3；
所述组分A，以重量份计，包括10～30重量份的活性剂；6～15重量份的载体；1～4重量份的pH调节剂；0.01～0.2重量份的抗氧化剂；
所述活性剂包括至少含有两个羟基的化合物；所述载体包括碳原子数为16～24的有机酸；
所述组分B为植物提取液，以重量份计，所述植物提取液至少包括：5～30重量份的意大利黑杨、葡萄柚皮、桉树叶混合物的提取物；0.1～5重量份的苦参提取物；1～3重量份的芦荟提取物；1～10重量份的鲜橘皮提取物；0.5～3重量份的天竺兰提取物；0.5～10重量份的桉树提取物；1～8重量份的山刺槐提取物；1～5重量份的菊花提取物；0.1～2重量份的青蒿素。
实施方式2：本发明的实施方式2与实施方式1相同，不同点在于，所述空气清新剂组合物，包括组分A和组分B；所述组分A和组分B的重量比为1：1～3；
所述组分A，以重量份计，包括18～28重量份的活性剂；8～12重量份的载体；2～3重量份的pH调节剂；0.1～0.2重量份的抗氧化剂；
所述活性剂包括至少含有两个羟基的化合物；所述载体包括碳原子数为16～24的有机酸；
所述组分B为植物提取液，以重量份计，所述植物提取液至少包括：15～28重量份的意大利黑杨、葡萄柚皮、桉树叶混合物的提取物；1～3重量份的苦参提取物；1.5～3重量份的芦荟提取物；3～8重量份的鲜橘皮提取物；1～2重量份的天竺兰提取物；3～10重量份的桉树提取物；2～6重量份的山刺槐提取物；2～4重量份的菊花提取物；0.5～1.5重量份的青蒿素。
实施方式3：本发明的实施方式3与实施方式2相同，不同点在于，所述空气清新剂组合物，包括组分A和组分B；所述组分A和组分B的重量比为1：2；
所述组分A，以重量份计，包括25重量份的活性剂、10重量份的载体、2.5重量份的pH调节剂、0.1重量份的抗氧化剂；
所述活性剂包括至少含有两个羟基的化合物；所述载体包括碳原子数为16～24的有机酸；
所述组分B为植物提取液，以重量份计，所述植物提取液至少包括：25重量份的意大利黑杨、葡萄柚皮、桉树叶混合物的提取物；2重量份的苦参提取物； 3重量份的芦荟提取物；7重量份的鲜橘皮提取物；1.5重量份的天竺兰提取物；8重量份的桉树提取物；5重量份的山刺槐提取物；4重量份的菊花提取物；1重量份的青蒿素。
实施方式4：本发明的实施方式4与实施方式1相同，不同点在于，所述活性剂选自：乙二醇、丙二醇、丁二醇、聚乙二醇、丙三醇、1,3,5-环己烷三醇中的任意一种或几种的混合。
实施方式5：本发明的实施方式5与实施方式1相同，不同点在于，所述载体选自：棕榈酸、硬脂酸、花生酸、山嵛酸中的任意一种或几种的混合。
实施方式6：本发明的实施方式6与实施方式1相同，不同点在于，所述意大利黑杨、葡萄柚皮、桉树叶混合物的提取物的提取方法为：
将干燥的意大利黑杨树叶、葡萄柚皮、桉树叶按重量比为10：5：2称取后粉碎，加入质量分数为95% 的乙醇，浸泡3～10h后使用微波加热提取2～3次，过滤，滤液经减压浓缩至无乙醇，即得。
实施方式7：本发明的实施方式7与实施方式1相同，不同点在于，所述天竺兰提取物的提取方法为：
将称取干燥的天竺兰粉碎后，采用白醋浸泡1～3h后，再加入60% 的乙醇，浸泡2～5h后使用微波加热提取2～3次，过滤，滤液经减压浓缩至无白醋和乙醇，即得。
实施方式8：本发明的实施方式8与实施方式1相同，不同点在于，所述组分B中还包括1重量份的留兰香和麻籽混合物的提取物。
实施方式9：本发明的实施方式9提供了如实施方式1～8所述的空气清新剂组合物的制备方法，至少包括以下步骤：
组分A：将载体加入到水中，在60～90℃下，搅拌2～5h后加入相应重量份的活化剂、pH调节剂、抗氧化剂，在40～60℃下，搅拌1～3h，备用；
组分B：将各种植物提取物混合后，在20～40℃下，搅拌1～2h，备用；
将组分A加入到组分B，在30～50℃下，搅拌1～5h，蒸干，得到膏状固体型空气清新剂组合物。
实施方式10：本发明的实施方式10提供了空气清新剂制品，包括如实施方式1～8所述的空气清新剂组合物。
下面通过实施例对本发明进行具体描述。有必要在此指出的是，以下实施例只用于对本发明作进一步说明，不能理解为对本发明保护范围的限制，该领域的专业技术人员根据上述本发明的内容做出的一些非本质的改进和调整，仍属于本发明的保护范围。
另外，如果没有其它说明，所用原料都是市售的，且以下物料所用份数均为重量份。
实施例1：（小范围）
本发明的实施例1提供了一种空气清新剂组合物，包括组分A和组分B；所述组分A和组分B的重量比为1：0.5；
所述组分A，以重量份计，包括10重量份的活性剂（所述活性剂为丙二醇）；15重量份的载体（所述载体为棕榈酸、硬脂酸；棕榈酸、硬脂酸的重量比为2：1）；1重量份的pH调节剂（所述pH调节剂为氢氧化钠）；0.01重量份的抗氧化剂（所述抗氧化剂为醋酸盐维他命E）；
所述组分B为植物提取液，以重量份计，所述植物提取液包括：5重量份的意大利黑杨、葡萄柚皮、桉树叶混合物的提取物；0.1重量份的苦参提取物；1重量份的芦荟提取物；1重量份的鲜橘皮提取物；0.5重量份的天竺兰提取物；0.5重量份的桉树提取物；1重量份的山刺槐提取物；1重量份的菊花提取物；0.1重量份的青蒿素。
意大利黑杨、葡萄柚皮、桉树叶混合物的提取物的提取方法：
称取81g干燥的意大利黑杨树叶、葡萄柚皮、桉树叶的混合物，且意大利黑杨树叶、葡萄柚皮、桉树叶的重量比为10：5：2；加入1升质量分数为95% 的乙醇，浸泡10h后使用微波加热提取3次，过滤，滤液经减压浓缩至无乙醇，即得。
苦参提取物的提取方法：
取5 g干燥的当归，碾成粉末，在40℃下加入100 mL的质量浓度为80% 的乙醇，加热回流2小时用超声波提取5 h，提取5次，合并提取液，过滤后浓缩至无乙醇，即得。
芦荟提取物的提取方法：
将20g芦荟洗净后，切碎，和炼蜜混匀后加热至60℃，保温3 h，冷却后以水作为溶剂，用超声波提取3 h，提取3次，合并提取液，过滤后浓缩至无水，即得。
鲜橘皮提取物的提取方法：
将15g的鲜桔皮***粉碎至100-200目，和2-巯基苯并噻唑共混后，在30℃下加入100 mL的质量浓度为50% 的乙醇，加热回流2小时用超声波提取5 h，提取3次，合并提取液，过滤后浓缩至无乙醇，即得。
天竺兰提取物的提取方法：
称取10 g干燥的天竺兰粉碎后，采用白醋浸泡1h后，再加入质量浓度为60% 的乙醇，浸泡5h后使用微波加热提取3次，过滤，滤液经减压浓缩至无白醋和乙醇，即得。
桉树提取物的提取方法：
称取重量比为1：18共混的大叶桉树皮和大叶桉树叶的粉末，加入质量浓度为80%乙醇，浸泡3h后使用微波加热提取3次，过滤，滤液经减压浓缩至无乙醇，即得。
山刺槐提取物的提取方法：
（1）将金叶刺槐的叶子、粉花刺槐的叶子和红花刺槐的叶子按照重量份比为1：1：50共混、洗净、切碎，然后用氨水湿润后，加入质量浓度为50%的乙醇，回流1小时，趁热过滤，浓缩至无乙醇，即得刺槐的叶的提取物。
（2）将金叶刺槐的花、粉花刺槐的花和红花刺槐的花按照重量份比为0.5：0.8：1.2共混、洗净、切碎，加入蜂蜜，回流3小时，趁热过滤，浓缩至无乙醇，即得刺槐的花的提取物。
（3）将步骤1和步骤2中刺槐的叶的提取物和花的提取物共混，加入乙醇，超声搅拌2.5小时，浓缩至无乙醇，即得刺槐的提取物。
菊花提取物的提取方法：
称取5g菊花，切碎，加入质量浓度为80%乙醇，浸泡2h后使用微波加热提取3次，过滤，滤液经减压浓缩至无乙醇，即得。
空气清新剂组合物的制备方法，至少包括以下步骤：
组分A：将载体加入到水中，在60℃下，搅拌2h后加入相应重量份的活化剂、pH调节剂、抗氧化剂，在40℃下，搅拌3h，备用；
组分B：将各种植物提取物混合后，在40℃下，搅拌1h，备用；
将组分A加入到组分B，在50℃下，搅拌5h，蒸干，得到膏状固体型空气清新剂组合物。
实施例2：（大范围）
本发明的实施例2提供了一种空气清新剂组合物，包括组分A和组分B；所述组分A和组分B的重量比为1：3；
所述组分A，以重量份计，包括30重量份的活性剂（所述活性剂为丙二醇）；6重量份的载体（所述载体为棕榈酸、硬脂酸；棕榈酸、硬脂酸的重量比为2：1）；4重量份的pH调节剂（所述pH调节剂为氢氧化钠）；0.2重量份的抗氧化剂（所述抗氧化剂为醋酸盐维他命E）；
所述组分B为植物提取液，以重量份计，所述植物提取液至少包括：30重量份的意大利黑杨、葡萄柚皮、桉树叶混合物的提取物；5重量份的苦参提取物；3重量份的芦荟提取物；10重量份的鲜橘皮提取物；3重量份的天竺兰提取物；10重量份的桉树提取物；8重量份的山刺槐提取物；5重量份的菊花提取物；2重量份的青蒿素。
组分B中各种植物提取液的提取方法以及空气清新剂组合物同实施例1。
实施例3：（最佳范围）
本发明的实施例3提供了一种空气清新剂组合物，包括组分A和组分B；所述组分A和组分B的重量比为1：2；
所述组分A，以重量份计，包括25重量份的活性剂（所述活性剂为丙二醇）；10重量份的载体（所述载体为棕榈酸、硬脂酸；棕榈酸、硬脂酸的重量比为2：1）；2.5重量份的pH调节剂（所述pH调节剂为氢氧化钠）；0.1重量份的抗氧化剂（所述抗氧化剂为醋酸盐维他命E）；
所述组分B为植物提取液，以重量份计，所述植物提取液至少包括：25重量份的意大利黑杨、葡萄柚皮、桉树叶混合物的提取物；2重量份的苦参提取物； 3重量份的芦荟提取物；7重量份的鲜橘皮提取物；1.5重量份的天竺兰提取物；8重量份的桉树提取物；5重量份的山刺槐提取物；4重量份的菊花提取物；1重量份的青蒿素。
组分B中各种植物提取液的提取方法以及空气清新剂组合物同实施例1。
实施例4：（最佳范围+留兰香和麻籽混合物的提取物）
本发明的实施例4提供了一种空气清新剂组合物，包括组分A和组分B；所述组分A和组分B的重量比为1：2；
所述组分A，以重量份计，包括25重量份的活性剂（所述活性剂为丙二醇）；10重量份的载体（所述载体为棕榈酸、硬脂酸；棕榈酸、硬脂酸的重量比为2：1）；2.5重量份的pH调节剂（所述pH调节剂为氢氧化钠）；0.1重量份的抗氧化剂（所述抗氧化剂为醋酸盐维他命E）；
所述组分B为植物提取液，以重量份计，所述植物提取液至少包括：25重量份的意大利黑杨、葡萄柚皮、桉树叶混合物的提取物；2重量份的苦参提取物； 3重量份的芦荟提取物；7重量份的鲜橘皮提取物；1.5重量份的天竺兰提取物；8重量份的桉树提取物；5重量份的山刺槐提取物；4重量份的菊花提取物；1重量份的青蒿素；1重量份的留兰香和麻籽混合物的提取物。
留兰香和麻籽混合物的提取物的提取方法：
麻籽提取物的提取步骤：
(1) 原料预处理及烘烤
将300g麻籽淘洗干净后再在100℃下烘烤8小时。
(2) 破碎
将烘烤后的麻籽，进行破碎处理。
(3) 兑浆搅拌
将进行破碎处理的麻籽破碎后加入1升水，升高温度至80℃，搅拌4h。
(4) 离心分离
将得到浆料在 4000r／min条件下，离心20min，得到上层油层，下层料渣，得到麻籽油。
所述留兰香和麻籽混合物的提取物的提取方法为：称取5g留兰香，切碎，加入上述方法得到的麻籽油，浸泡2h后，再加入质量溶度为50%的乙醇，使用微波加热提取3次，过滤，滤液经减压浓缩至无乙醇，即得。
组分B中各种植物提取液的提取方法以及空气清新剂组合物同实施例1。
对比例1：
对比例1具体同实施例4，不同点在于，所述空气清新剂组合物中不含有组分A。
对比例2：
对比例2具体同实施例4，不同点在于，所述空气清新剂组合物中不含有组分B。
对比例3：
对比例3具体同实施例4，不同点在于，所述空气清新剂组合物中不含有意大利黑杨、葡萄柚皮、桉树叶混合物的提取物。
对比例4：
对比例4具体同实施例4，不同点在于，将“意大利黑杨、葡萄柚皮、桉树叶混合物的提取物”改为“意大利黑杨提取物”。其中，“意大利黑杨提取物”的提取方法同实施例1，只是不包括葡萄柚皮、桉树叶。
对比例5：
对比例5具体同实施例4，不同点在于，将“意大利黑杨、葡萄柚皮、桉树叶混合物的提取物”改为“意大利黑杨提取物”。其中，“意大利黑杨提取物”的提取方法同实施例1，只是不包括葡萄柚皮、桉树叶，将意大利黑杨的树叶改换为意大利黑杨的树皮。
对比例6：
对比例6具体同实施例4，不同点在于，将“意大利黑杨、葡萄柚皮、桉树叶混合物的提取物”改为“意大利黑杨、葡萄柚皮混合物的提取物”。其中，“意大利黑杨、葡萄柚皮混合物的提取物”的提取方法同实施例1，只是不包括桉树叶。
对比例7：
对比例7具体同实施例4，不同点在于，将“意大利黑杨、葡萄柚皮、桉树叶混合物的提取物”改为“意大利黑杨、桉树叶混合物的提取物”。其中，“意大利黑杨、桉树叶混合物的提取物”的提取方法同实施例1，只是不包括葡萄柚皮。
对比例8：
对比例8具体同实施例4，不同点在于，将“留兰香和麻籽混合物的提取物”改为留兰香提取物。
留兰香提取物的提取方法同实施例4，不同点在于，不加入麻籽油。
对比例9：
对比例9具体同实施例4，不同点在于，将“留兰香和麻籽混合物的提取物”改为麻籽油。
麻籽油的提取方法同实施例4。
测试
将上述制备得到的空气清新剂组合物进行测试。
1、空气清新剂组合物有效性持续时间试验：
1.1 新鲜空气清新剂组合物
在1m3密封的实验仓中，注入一定体积化学纯甲醛(或苯或氨)，开启仓内风扇，1小时后立即采样测试仓中气体浓度为初始浓度。在1m3密封的实验仓中，将刚制得的空气清新剂组合物放入该仓中，72小时后立即采样测试仓内气体浓度，计算去除率。去除率=(初始浓度-试样浓度)×100/初始浓度，测试结果见表1。
1.2 放置两个月的空气清新剂组合物
具体实验步骤同1.1，不同点在于将空气清新剂组合物放置两个月后用于同样的测试，测试结果见表1。
其中，TVOC为总挥发性有机物，所有室内有机气态物质。
表1 新鲜空气清新剂去除率测试
实施例 甲醛去除率 (%) 苯去除率 (%) 氨去除率 (%) TVOC( 去除率 )
实施例 1 89.7 88.4 87.8 86.8
实施例 2 90.4 90.5 88.1 85.9
实施例 3 94.2 90.2 90.2 88.2
实施例 4 98.0 97.2 99.9 99.1
对比例 1 66.1 60.4 62.1 50.5
对比例 2 50.2 68.6 59.7 48.7
对比例 3 80.4 84.4 79.2 73.1
对比例 4 82.2 86.7 81.4 75.9
对比例 5 79.2 83.4 78.2 70.5
对比例 6 85.6 84.2 82.5 78.2
对比例 7 84.8 84.3 83.2 77.4
对比例 8 93.7 92.5 72.5 70.9
对比例 9 93.3 90.9 75.8 74.5
表 2 放置两个月的空气清新剂组合物的去除率测试
实施例 甲醛去除率 (%) 苯去除率 (%) 氨去除率 (%) TVOC( 去除率 )
实施例 1 80.7 79.2 78.9 76.8
实施例 2 81.4 82.7 80.7 77.8
实施例 3 90.2 85.6 84.9 82.6
实施例 4 96.9 95.2 98.9 97.1
对比例 1 36.9 34.8 30.5 29.5
对比例 2 25.4 29.6 34.7 20.9
对比例 3 60.7 68.8 67.2 64.9
对比例 4 76.5 79.5 72.6 68.4
对比例 5 70.4 74.5 68.1 61.5
对比例 6 74.8 72.7 70.8 67.2
对比例 7 72.3 70.9 69.2 66.8
对比例 8 90.2 89.5 60.9 60.4
对比例 9 88.9 88.7 62.5 62.9
从表 1 和 2 中可以看出，通过对含有特定顺序的制备方法和组合式的提取植物提取物的方法得到的空气清新剂组合物，对甲醛、苯、氨以及 TVOC 均具有较好的去除效果。且本发明中的空气清新剂组合物放置时间长达两个月后，仍对甲醛、苯、氨以及 TVOC 具有较好的去除效果。
前述的实例仅是说明性的，用于解释本公开的特征的一些特征。所附的权利要求旨在要求可以设想的尽可能广的范围，且本文所呈现的实施例仅是根据所有可能的实施例的组合的选择的实施方式的说明。因此，申请人的用意是所附的权利要求不被说明本发明的特征的示例的选择限制。而且在科技上的进步将形成由于语言表达的不准确的原因而未被目前考虑的可能的等同物或子替换，且这些变化也应在可能的情况下被解释为被所附的权利要求覆盖。

Claims (10)

  1. 一种空气清新剂组合物，其特征在于，包括组分A和组分B；所述组分A和组分B的重量比为1：0.5～3；
    所述组分A，以重量份计，包括10～30重量份的活性剂；6～15重量份的载体；1～4重量份的pH调节剂；0.01～0.2重量份的抗氧化剂；
    所述活性剂包括至少含有两个羟基的化合物；所述载体包括碳原子数为16～24的有机酸；
    所述组分B为植物提取液，以重量份计，所述植物提取液至少包括：5～30重量份的意大利黑杨、葡萄柚皮、桉树叶混合物的提取物；0.1～5重量份的苦参提取物；1～3重量份的芦荟提取物；1～10重量份的鲜橘皮提取物；0.5～3重量份的天竺兰提取物；0.5～10重量份的桉树提取物；1～8重量份的山刺槐提取物；1～5重量份的菊花提取物；0.1～2重量份的青蒿素。
  2. 如权利要求1所述的空气清新剂组合物，其特征在于，所述空气清新剂组合物，包括组分A和组分B；所述组分A和组分B的重量比为1：1～3；
    所述组分A，以重量份计，包括18～28重量份的活性剂；8～12重量份的载体；2～3重量份的pH调节剂；0.1～0.2重量份的抗氧化剂；
    所述活性剂包括至少含有两个羟基的化合物；所述载体包括碳原子数为16～24的有机酸；
    所述组分B为植物提取液，以重量份计，所述植物提取液至少包括：15～28重量份的意大利黑杨、葡萄柚皮、桉树叶混合物的提取物；1～3重量份的苦参提取物；1.5～3重量份的芦荟提取物；3～8重量份的鲜橘皮提取物；1～2重量份的天竺兰提取物；3～10重量份的桉树提取物；2～6重量份的山刺槐提取物；2～4重量份的菊花提取物；0.5～1.5重量份的青蒿素。
  3. 如权利要求2所述的空气清新剂组合物，其特征在于，所述空气清新剂组合物，包括组分A和组分B；所述组分A和组分B的重量比为1：2；
    所述组分A，以重量份计，包括25重量份的活性剂、10重量份的载体、2.5重量份的pH调节剂、0.1重量份的抗氧化剂；
    所述活性剂包括至少含有两个羟基的化合物；所述载体包括碳原子数为16～24的有机酸；
    所述组分B为植物提取液，以重量份计，所述植物提取液至少包括：25重量份的意大利黑杨、葡萄柚皮、桉树叶混合物的提取物；2重量份的苦参提取物； 3重量份的芦荟提取物；7重量份的鲜橘皮提取物；1.5重量份的天竺兰提取物；8重量份的桉树提取物；5重量份的山刺槐提取物；4重量份的菊花提取物；1重量份的青蒿素。
  4. 如权利要求1所述的空气清新剂组合物，其特征在于，所述活性剂选自：乙二醇、丙二醇、丁二醇、聚乙二醇、丙三醇、1,3,5-环己烷三醇中的任意一种或几种的混合。
  5. 如权利要求1所述的空气清新剂组合物，其特征在于，所述载体选自：棕榈酸、硬脂酸、花生酸、山嵛酸中的任意一种或几种的混合。
  6. 如权利要求1所述的空气清新剂组合物，其特征在于，所述意大利黑杨、葡萄柚皮、桉树叶混合物的提取物的提取方法为：
    将干燥的意大利黑杨树叶、葡萄柚皮、桉树叶按重量比为10：5：2称取后粉碎，加入质量分数为95% 的乙醇，浸泡3～10h后使用微波加热提取2～3次，过滤，滤液经减压浓缩至无乙醇，即得。
  7. 如权利要求1所述的空气清新剂组合物，其特征在于，所述天竺兰提取物的提取方法为：
    将称取干燥的天竺兰粉碎后，采用白醋浸泡1～3h后，再加入60% 的乙醇，浸泡2～5h后使用微波加热提取2～3次，过滤，滤液经减压浓缩至无白醋和乙醇，即得。
  8. 如权利要求1所述的空气清新剂组合物，其特征在于，所述组分B中还包括1重量份的留兰香和麻籽混合物的提取物。
  9. 一种空气清新剂组合物的制备方法，其特征在于，至少包括以下步骤：
    组分A：将载体加入到水中，在60～90℃下，搅拌2～5h后加入相应重量份的活化剂、pH调节剂、抗氧化剂，在40～60℃下，搅拌1～3h，备用；
    组分B：将各种植物提取物混合后，在20～40℃下，搅拌1～2h，备用；
    将组分A加入到组分B，在30～50℃下，搅拌1～5h，蒸干，得到膏状固体型空气清新剂组合物。
  10. 一种空气清新剂制品，所述空气清新剂制品包括如权利要求1～8所述的空气清新剂组合物。
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CN106039949A (zh) 2016-10-26
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