WO2017199732A1 - Composition cosmétique - Google Patents

Composition cosmétique Download PDF

Info

Publication number
WO2017199732A1
WO2017199732A1 PCT/JP2017/016898 JP2017016898W WO2017199732A1 WO 2017199732 A1 WO2017199732 A1 WO 2017199732A1 JP 2017016898 W JP2017016898 W JP 2017016898W WO 2017199732 A1 WO2017199732 A1 WO 2017199732A1
Authority
WO
WIPO (PCT)
Prior art keywords
silicone
note
modified
alkyl
cosmetic composition
Prior art date
Application number
PCT/JP2017/016898
Other languages
English (en)
Japanese (ja)
Inventor
将幸 小西
Original Assignee
信越化学工業株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 信越化学工業株式会社 filed Critical 信越化学工業株式会社
Priority to JP2018518198A priority Critical patent/JP6969546B2/ja
Publication of WO2017199732A1 publication Critical patent/WO2017199732A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/29—Titanium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A61K8/892—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a hydroxy group, e.g. dimethiconol
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations

Definitions

  • the present invention relates to a cosmetic composition.
  • a composition for cosmetics is sometimes simply referred to as cosmetic.
  • Patent Literature 1 Japanese Patent Application Laid-Open No. 2014-043422.
  • the dispersion performance of the polyether-modified silicone surfactant may be insufficient.
  • metal oxide powders such as titanium oxide and zinc oxide are so-called fine particle metal oxides having an average primary particle diameter of 100 nm or less in order to improve transparency and enhance the ultraviolet shielding effect.
  • Material powder is widely used.
  • the finely divided metal oxide powder has a property that the bonding force between the particles is increased due to the increase in the surface area, and as a result, the metal oxide powder tends to aggregate. For this reason, when these fine particle metal oxide powders are used in sunscreen cosmetics, it is important that they can be stably contained without agglomeration.
  • Patent Document 2 JP 2013-035872 A
  • Patent Document 3 Japanese Patent Application Laid-Open No. 2007-182402
  • the polyglycerin-modified silicone used here was insufficient in improving the stability of the preparation in the presence of an ultraviolet absorber.
  • the present invention has been made in view of the above circumstances, and provides a cosmetic composition having excellent powder dispersibility even in the presence of an ultraviolet absorber, good usability and spreadability, and excellent formulation storage stability.
  • the purpose is to do.
  • the present inventor has found (a) silicone / alkyl branched polyglycerin-modified silicone, (b) powder, (c) ultraviolet absorber, (d) other than component (c) It has been found that the above problem can be solved by blending an oil agent having a viscosity of 1 to 100 mm 2 / s at 25 ° C., and has led to the present invention.
  • the present invention provides the following. [1].
  • the cosmetic composition of the present invention is excellent in powder dispersibility even in the presence of an ultraviolet absorber, and is excellent in use feeling, spreadability, and formulation storage stability.
  • the silicone-alkyl branched polyglycerin-modified silicone compound used in the present invention is a silicone-alkyl chain co-modified polyglycerin-modified silicone surfactant.
  • a silicone-alkyl branched polyglycerin-modified silicone represented by the following general formula (1) is preferable.
  • R 1 is an unsubstituted or substituted monovalent hydrocarbon group such as an alkyl group having 1 to 30 carbon atoms, an aryl group, an aralkyl group, a fluorine-substituted alkyl group, an amino-substituted alkyl group, a carboxyl-substituted alkyl group, and the following general formula (2) —C d H 2d —O— (C 2 H 4 O) e (C 3 H 6 O) f R 4 (2) (Wherein R 4 is a hydrogen atom, a monovalent hydrocarbon group having 1 to 30 carbon atoms, or R 5 — (CO) — (wherein R 5 is a monovalent hydrocarbon group having 1 to 30 carbon atoms).
  • R 2 is a polyglycerin derivative represented by the following general formula (3) and / or (4).
  • R 4 represents the same meaning as in the above formula (2)
  • Q represents a divalent hydrocarbon group having 2 to 20 carbon atoms which may contain an ether bond and an ester bond.
  • R 3 is a silicon-containing group represented by the following general formula (5).
  • R 1 is the same as in the above formula (1), g is an integer of 1 to 5, and h is 0 to 500)]
  • A is 1.0 to 2.5, preferably 1.2 to 2.3. If a is less than 1.0, the compatibility with the oil agent is poor and water resistance may be difficult to obtain. On the other hand, if it is larger than 2.5, the hydrophilicity becomes poor, so that the adsorptivity to the powder becomes poor and it is difficult to obtain a stable dispersibility.
  • b is from 0.001 to 1.5, preferably from 0.01 to 1.0. When b is less than 0.001, the hydrophilicity becomes poor, and therefore the adsorptivity to the powder becomes poor. If it is greater than 5, the hydrophilicity becomes too high, and it may be difficult to obtain stable dispersibility.
  • c is 0.001 to 1.5, preferably 0.01 to 1.0.
  • c is less than 0.001, the compatibility with silicone oil is poor and water resistance is difficult to obtain. If it is greater than 5, the hydrophilicity will be poor, so the adsorptivity to the powder will be poor and it may be difficult to obtain a stable dispersibility.
  • R 1 specific examples of the unsubstituted or substituted monovalent hydrocarbon group include a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, a hexyl group, a heptyl group, an octyl group, a nonyl group, a decyl group, Alkyl groups such as undecyl, dodecyl, tridecyl and tetradecyl, cycloalkyl such as cyclopentyl and cyclohexyl, aryl such as phenyl and tolyl, aralkyl such as benzyl and phenethyl, trifluoropropyl And fluorine-substituted alkyl groups such as a heptadecafluorodecyl group.
  • R 1 has 1 to 30 carbon atoms, preferably 1 to 16 carbon atoms, preferably a long-chain alkyl group having 8 or more carbon atoms, more preferably 8 to 16 alkyl groups, and still more preferably 10 to 12 alkyl groups. More preferred are groups.
  • R 4 is a hydrogen atom, 1 to 30 carbon atoms, or R 5 — (CO) — (where R 5 is 1 to 30 carbon atoms, particularly an alkyl group having 1 to 4 carbon atoms such as a methyl group) Valent hydrocarbon group).
  • the monovalent hydrocarbon group for R 4 is preferably an alkyl group having 1 to 4 carbon atoms such as a methyl group.
  • 50 mol% or more of the entire R 4 is preferably a methyl group, more preferably 70 mol% or more is preferably a methyl group, and 100 mol% is more preferably a methyl group.
  • d, e, and f are integers of 0 ⁇ d ⁇ 15, 0 ⁇ e ⁇ 50, and 0 ⁇ f ⁇ 50, respectively.
  • the general formula (2) is an alcohol residue and an alkenyl ether adduct residue.
  • the alkoxy group include lower alkoxy groups such as methoxy group and butoxy group to cetyloxy groups such as cetyl alcohol, oleyl alcohol and stearyl alcohol, higher alkoxy groups such as oleyloxy group and stearoxy group.
  • fatty acid residues such as an acetic acid, lactic acid, a butyric acid, an oleic acid, a stearic acid, and behenylic acid, are mentioned.
  • e f> 1
  • d is preferably 3, 5, or 11, and in this case, it is a propyl ether, pentenyl ether, or undecenyl ether residue, depending on the substituent of R 4
  • an allyl stearyl ether residue, a pentenyl behenyl ether residue, or an undecenyl oleyl ether residue can be mentioned.
  • e or f is not 0, an alkoxy group or an ester group is present via polyoxyalkylene.
  • d may be inferior in hydrolysis resistance when d is 0, and when d is 15 or more, the oily odor is strong, so 3 to 5 is preferable.
  • R 2 is a polyglycerin derivative represented by the following general formula (3) and / or (4).
  • R 4 has the same meaning as in formula (2), and Q represents a C 2-20 divalent hydrocarbon group which may contain an ether bond and an ester bond.
  • Q represents a C 2-20 divalent hydrocarbon group which may contain an ether bond and an ester bond.
  • R 3 is a silicon-containing group represented by the following general formula (5).
  • R 1 is the same as in the above formula (1), g is an integer of 1 to 5, and particularly when synthesized from the reaction of a vinylsiloxy group and a SiH group, g is 2. is there. h is 0 to 500, and preferably 1 to 50. If h is greater than 500, problems such as poor reactivity with the main chain may occur.
  • the silicone-alkyl-branched polyglycerin-modified silicone used in the present invention is not particularly limited as long as the conditions are satisfied.
  • lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone, etc. preferably defined by a cosmetic label (such as methyl group of dimethicone). Is partially substituted with a lauryl group, a triglyceryl group and a polydimethylsiloxyethyl group).
  • Commercially available products include KF-6105 manufactured by Shin-Etsu Chemical Co., Ltd.
  • the blending amount of the component (a) is 0.1 to 12% by mass, preferably 0.5 to 5% by mass in the cosmetic composition.
  • the powder used in the present invention is not particularly limited as long as it is a raw material that can be usually blended in cosmetics, but dispersion tends to be difficult when the particle size is finer.
  • pigments color pigments
  • ultraviolet scattering agents and the like Shows remarkable dispersibility.
  • a cross-linked silicone powder that is, a so-called silicone rubber powder made of an organopolysiloxane having a structure in which a repeating chain of diorganosiloxane units is cross-linked
  • a silicone resin particle a three-dimensional network-structured polycrystal.
  • Organosilsesquioxane resin particles and the like, and specific examples are known by names such as (dimethicone / vinyl dimethicone) crosspolymer, polymethylsilsesquioxane and the like. These are commercially available as powders or as swelling products containing silicone oil or the like, and are commercially available under the trade names of, for example, KMP-598, 590, 591, KSG-016F (all manufactured by Shin-Etsu Chemical Co., Ltd.). These powders can be used alone or in combination of two or more.
  • the blending amount of the component (b) is 0.1 to 45% by mass, preferably 1 to 35% by mass in the cosmetic composition.
  • silicone resin-coated silicone rubber powder is applied to sunscreens, make-ups, concealers, etc. due to the effect of improving the feel such as prevention of stickiness and the effect of correcting the shape of wrinkles and pores.
  • Specific examples of the silicone resin-coated silicone rubber powder include (vinyl dimethicone / methicone silsesquioxane) cross polymer, (diphenyl dimethicone / vinyl diphenyl dimethicone / silsesquioxane) cross polymer, poly, It is known by names such as silicone-22 and polysilicone-1 crosspolymer. These are commercially available under the trade names of KSP-100, 101, 102, 105, 300, 411, 441, etc. (all manufactured by Shin-Etsu Chemical Co., Ltd.). These powders can be used alone or in combination of two or more.
  • the pigment (colored pigment) is not particularly limited as long as it is generally used for makeup cosmetics.
  • the average primary particle diameter of the color pigment is preferably 1.0 ⁇ m or less.
  • LL-100P needle shape, average primary particle diameter: 0.07 ⁇ m ⁇ 0.8 ⁇ m
  • R-516P needle shape, Average primary particle size: 0.08 ⁇ m ⁇ 0.7 ⁇ m
  • BL-100P average primary particle size: 0.3 ⁇ m
  • CR-50 average primary particle size: 0.25 ⁇ m (Ishihara Sangyo) Can be used as well, and can be used after being surface-treated with silicone, etc.
  • the lower limit is not particularly limited, but can also be 0.02 ⁇ m. According to the invention, good dispersibility is remarkable, and the average primary particle size can be measured by a transmission electron micrograph.
  • the blending amount is not particularly limited, but it is preferably 0.1 to 25% by mass in the cosmetic composition, and 1 to 20% by mass from the viewpoint of usability. % Is more preferable. If the amount is less than 0.1% by mass, a sufficient hiding effect or coloring effect cannot be obtained. If the amount exceeds 25% by mass, the spread at the time of use becomes worse, or a powdery appearance appears in the cosmetic film. Sometimes.
  • the ultraviolet scattering agent used in the present invention is not particularly limited as long as it is a raw material that can be usually blended in cosmetics. Specifically, it is a metal oxide selected from one or more of titanium oxide, zinc oxide, and cerium oxide.
  • the metal oxide may be a composite powder of two or more of titanium oxide, zinc oxide and cerium oxide, or may be a composite powder with other powders.
  • the average primary particle size is preferably 200 nm or less, more preferably 120 nm or less. If the particle diameter is larger than this, the ultraviolet protection function is lowered and white is left. Although a minimum is not specifically limited, It can also be 10 nm.
  • the average primary particle diameter of the powder used as the ultraviolet scattering agent as defined in the present invention can be measured by a transmission electron micrograph.
  • the average primary particle diameter is determined by the average value of the long diameters of the particles.
  • an ultraviolet scattering agent particularly titanium oxide, it is difficult to disperse, but good dispersibility is remarkable according to the present invention.
  • the powder is not particularly limited even if it is untreated or a known surface treatment generally used for cosmetics.
  • the inorganic treatment include silica coating, alumina coating, aluminum hydroxide coating, etc.
  • organic treatment includes silanes such as caprylylsilane (manufactured by Shin-Etsu Chemical Co., Ltd .: AES-3083) or silylating agents, Dimethyl silicone (manufactured by Shin-Etsu Chemical Co., Ltd .: KF-96A series), methylhydrogen type polysiloxane (manufactured by Shin-Etsu Chemical Co., Ltd .: KF-99P, KF-9901, etc.), silicone branching silicone treatment agent (manufactured by Shin-Etsu Chemical Co., Ltd .: KF- 9908, KF-9909, etc.) silicone oils, waxes, paraffins, perfluoroalkyl organic fluorine compounds such as phosphates, surfactants,
  • KF-9909 manufactured by Shin-Etsu Chemical Co., Ltd.
  • KF-9909 manufactured by Shin-Etsu Chemical Co., Ltd.
  • sunscreens and foundations because it exhibits high dispersibility in both oils such as silicone oil and ester oil.
  • These surface treatments may be used alone or in combination of two or more according to the purpose, and may be any combination of inorganic / inorganic, organic / organic, inorganic / organic, and the like.
  • UV scattering agents with these surface treatments can be used.
  • fine particle titanium oxide MT-01, 05, 100Z, 100TV, 100AQ, 100WP, 150EX, 500B, 505SAS, 700B, 014Z, SMT-500SAS (manufactured by Teica), ST-455, 455WS, 457ECS, 495M (Titanium Industry) And TTO-S1, S4, 51 (C), 55 (A), 55 (C), and 80 (A) (manufactured by Ishihara Sangyo).
  • the blending amount is not particularly limited, but it is desirable to blend 0.1 to 45% by mass in the cosmetic composition, and 1 to 40% by mass from the viewpoint of usability. Is more preferable. If it is less than 0.1% by mass, a sufficient ultraviolet shielding effect cannot be obtained, and if it exceeds 45% by mass, the spread at the time of use deteriorates and whiteness and powderiness appear in the decorative film. Sometimes.
  • the (b) powder is dispersed in advance in an oil phase containing (I) (a) component and (d) component or (II) (a) component, (c) component and (d) component. You may mix
  • the ultraviolet absorber used in the present invention is not particularly limited as long as it is a raw material that can be usually blended in cosmetics. Specifically, homomenthyl salicylate, octocrylene, 4-tert-butyl-4′-methoxydibenzoylmethane, 4- (2- ⁇ -glucopyranosyloxy) propoxy-2-hydroxybenzophenone, octyl salicylate, 2- [4 -(Diethylamino) -2-hydroxybenzoyl] benzoic acid hexyl ester, dihydroxydimethoxybenzophenone, dihydroxydimethoxybenzophenone sodium disulfonate, dihydroxybenzophenone, dimethicodiethylbenzalmalonate, 1- (3,4-dimethoxyphenyl) -4, 4-dimethyl-1,3-pentanedione, dimethoxybenzylidenedioxoimid
  • a UVA absorber for example, diethylaminohydroxybenzoyl hexyl benzoate
  • a UVB absorber for example, ethyl hexyl methoxycinnamate
  • the blending amount of the component (c) is 0.1 to 20% by mass, more preferably 3.5 to 18% by mass, and further preferably 6.5 to 16% by mass based on the entire cosmetic of the present invention.
  • the oil agent having a viscosity of 1 to 100 mm 2 / s at 25 ° C. other than the component (c) is not particularly limited as long as it is a raw material that can be usually blended in cosmetics. Specifically, silicone oil, ester oil, hydrocarbon oil, and fluorine-based oil agent can be used.
  • Silicone oil is not particularly limited as long as it is a raw material that can be usually blended into cosmetics. Specifically, dimethylpolysiloxane, cyclopentasiloxane (decamethylcyclopentasiloxane), cyclohexasiloxane, disiloxane, Methylphenyl polysiloxanes such as trisiloxane, methyltrimethicone, caprylylmethicone, diphenyldimethicone (cosmetic label), diphenylsiloxyphenyl trimethicone (cosmetic label), methylhexylpolysiloxane, methylhydrogenpolysiloxane, dimethylsiloxane Examples include methylphenylsiloxane copolymer.
  • volatile silicones that can provide a refreshing feeling of use (commercially available from Shin-Etsu Chemical: TMF-1.5, KF-995, KF-96A-1cs, KF-96A-1.5cs, KF-96A) -2cs, etc.], low-viscosity silicone (commercially available from Shin-Etsu Chemical Co., Ltd .: KF-96A-6cs, etc.) and phenyl silicone used for the purpose of improving compatibility with other oils and polishing (commercial product) As such, Shin-Etsu Chemical Co., Ltd .: KF-56A] is preferred. These silicone oils can be used alone or in combination of two or more.
  • oil agents include cetyl ethylhexanoate, triethylhexanoin, glyceryl tri (caprylate / caprate), isononyl isononanoate, isotridecyl isononanoate, isopropyl palmitate, dicaprylyl ether, isopropyl myristate, ethylhexyl palmitate, carbonic acid
  • examples include diethylhexyl, dicaprylyl carbonate, alkyl benzoate (C12-15), ester oils such as neopentyl glycol diethylhexanoate, hydrocarbon oils such as isododecane and undecane, and fluorine-based oils such as perfluorohexane and perfluoropolyether. It is done.
  • the viscosity of the component (d) is 1 to 100 mm 2 / s at 25 ° C., preferably 1 to 50 mm 2 / s, and more preferably 1 to 30 mm 2 / s.
  • the blending amount is 0.1 to 60% by mass in the cosmetic composition, and more preferably 5 to 55% by mass.
  • the kinematic viscosity is a value measured at 25 ° C. using an Ostwald viscometer.
  • ⁇ Other optional components> In the cosmetic of the present invention, various components used in normal cosmetics can be blended within a range that does not impair the effects of the present invention. Examples of components include oil agents other than (1) (c) and (d) components, (2) aqueous components, (3) coating agents, (4) surfactants other than (a) components, and (5) cross-linked type. Organopolysiloxane, (6) wax, (7) other additives may be included. These can be used individually by 1 type or in combination of 2 or more types.
  • oils other than the components (c) and (d) used in the present invention are raw materials that can be blended in ordinary cosmetics used for improving touch and emollient effects.
  • a high-viscosity linear or branched organopolysiloxane an amino-modified organopolysiloxane, a pyrrolidone-modified organopolysiloxane, a pyrrolidone carboxylic acid-modified organopolysiloxane, a highly polymerized gum-like dimethylpolysiloxane, a gum Amino-modified organopolysiloxane, cyclic organopolysiloxane solution such as silicone gum, higher alkoxy-modified silicone such as stearoxy silicone, higher fatty acid-modified silicone, alkyl-modified silicone, long-chain alkyl-modified silicone, amino-acid-modified silicone, fluor
  • silicone waxes used for the purpose of glossing and adjustment of feeling of use are preferably used.
  • silicone waxes used for the purpose of glossing and adjustment of feeling of use are preferably used.
  • high viscosity hydrocarbon oils such as petrolatum and hydrogenated polyisobutene can be used.
  • the blending amount when oils other than the components (c) and (d) are blended is preferably 0.1 to 20% by mass in the cosmetic composition.
  • the aqueous component is not particularly limited as long as it is a raw material that can be blended in a normal cosmetic used as a moisturizing effect or a refreshing effect, but a lower alcohol such as ethanol or isopropanol; a sugar such as sorbitol, maltose, or xylitol
  • Polyhydric alcohols such as alcohol, butylene glycol, dibutylene glycol, propylene glycol, dibutylene glycol, pentylene glycol, decanediol, octanediol, hexanediol, erythritol, glycerin, diglycerin, polyethylene glycol; glucose, glyceryl glucoside, betaine , Hyaluronic acid, chondroitin sulfate, pyrrolidone carboxylate, polyoxyethylene methyl glucoside, polyoxypropylene methyl glucoside and the like.
  • the coating agent is not particularly limited as long as it is a raw material that can be usually blended in cosmetics.
  • Cellulose derivatives such as alkyl cellulose and nitrocellulose, silicone-modified polysaccharide compounds such as tri (trimethylsiloxy) silylpropylcarbamic acid pullulan, acrylic-silicone graft copolymers such as (alkyl acrylate / dimethicone) copolymers, trimethylsiloxysilicate Silicone resins such as acids, silicone resins such as silicone-modified polynorbornene and fluorine-modified silicone resins, fluorine resins, aromatic hydrocarbon resins, polymer emulsion resins, terpene resins, polybutene, polyisoprene , Alkyd resin, polyvinylpyrrolidone-modified polymer, rosin-modified resin, polyurethane and the like are used.
  • the blending amount when blending the film agent is preferably 0.1 to 20% by
  • silicone-based film agents are particularly preferred, and tri (trimethylsiloxy) silylpropyl carbamate pullulan [as a commercially available product, dissolved in a solvent, manufactured by Shin-Etsu Chemical Co., Ltd .: TSPL-30-D5, ID] Or (alkyl acrylate / dimethicone) copolymer [commercially available as a product dissolved in a solvent, manufactured by Shin-Etsu Chemical Co., Ltd .: KP-543, 545, 549, 550, 545 L, etc.], trimethylsiloxysilicate [commercially available As a product dissolved in a solvent, manufactured by Shin-Etsu Chemical Co., Ltd .: KF-7312J, X-21-5250, etc.) or silicone-modified polynorbornene [as a commercially available product, manufactured by Shin-Etsu Chemical Co., Ltd .: NBN -30-ID etc.] can be used, but is not
  • Surfactant other than component (a) Surfactants include nonionic, anionic, cationic and amphoteric active agents, but are not particularly limited and are used in normal cosmetics. Any of these can be used. Among these surfactants, partially crosslinked polyether-modified silicone, partially crosslinked polyglycerin-modified silicone, linear or branched polyoxyethylene-modified organopolysiloxane, linear or branched polyoxyethylene polyoxypropylene-modified organo Polysiloxane, linear or branched polyoxyethylene / alkyl co-modified organopolysiloxane, linear or branched polyoxyethylene polyoxypropylene / alkyl co-modified organopolysiloxane, linear or branched polyglycerin-modified organopolysiloxane, A linear or branched polyglycerin / alkyl co-modified organopolysiloxane is preferred.
  • the content of hydrophilic polyoxyethylene group, polyoxyethylene polyoxypropylene group or polyglycerin residue preferably accounts for 10 to 70% by mass in the molecule.
  • Specific examples include KSG-210, 240, 310, 320, 330, 340, 320Z, 350Z, 710, 810, 820, 830, 840, 820Z, 850Z, KF-6011, 6013, 6043, manufactured by Shin-Etsu Chemical Co., Ltd. 6028, 6038, 6048, 6100, 6104, 6106 and the like.
  • the amount of the surfactant other than the component (a) is preferably 0.1 to 10% by mass in the cosmetic composition.
  • crosslinkable organopolysiloxane is not particularly limited as long as it is usually used in cosmetics, and can be used singly or in appropriate combination of two or more.
  • the component (5) unlike the component (4), is a compound that does not have a polyether or polyglycerin structure in the molecular structure, and is an elastomer having a structural viscosity by swelling an oil agent.
  • (dimethicone / vinyl dimethicone) crosspolymer for example, (dimethicone / vinyl dimethicone) crosspolymer, (dimethicone / phenylvinyldimethicone) crosspolymer, (vinyldimethicone / lauryldimethicone) crosspolymer, (laurylpolydimethylsiloxyethyl dimethicone / bisvinyldimethicone) crosspolymer, and the like can be mentioned. These are commercially available as swollen substances containing liquid oil at room temperature. Specific examples include KSG-15, 1510, 16, 1610, 18A, 19, 41A, 42A, 43, 44, 042Z, and 045Z manufactured by Shin-Etsu Chemical Co., Ltd. , 048Z and the like. These products may contain a part of the component (d) as a solvent.
  • Wax The wax used in the present invention is not particularly limited as long as it is a raw material that can be usually blended in cosmetics. Specific examples include ceresin, ozokerite, paraffin, synthetic wax, microcrystalline wax, polyethylene wax and other hydrocarbon waxes, carnauba wax, rice wax, rice bran wax, jojoba wax (including extremely hydrogenated jojoba oil), and candelilla wax. And waxes derived from plants such as whale wax, beeswax, snow wax, etc., and these waxes can be used alone or in combination.
  • the blending amount when the wax is blended is preferably 0.1 to 10% by mass in the cosmetic composition.
  • additives include oil-soluble gelling agents, antiperspirants, moisturizers, preservatives / bactericides, fragrances, salts, antioxidants, pH adjusters, chelating agents, and refreshing agents.
  • Anti-inflammatory agents include skin-beautifying agents (whitening agents, cell activators, rough skin improving agents, blood circulation promoters, skin astringents, antiseborrheic agents, etc.), vitamins, amino acids, water-soluble polymer compounds, plant extracts, etc. Is mentioned.
  • Oil-soluble gelling agents include metal soaps such as aluminum stearate, magnesium stearate and zinc myristate; amino acids such as N-lauroyl-L-glutamic acid and ⁇ , ⁇ -di-n-butylamine Derivatives; dextrin fatty acid esters such as dextrin palmitic acid ester, dextrin stearic acid ester, dextrin 2-ethylhexanoic acid palmitic acid ester; sucrose fatty acid esters such as sucrose palmitic acid ester and sucrose stearic acid ester; fructooligosaccharide stearic acid ester Fructooligosaccharide fatty acid esters such as fructooligosaccharide 2-ethylhexanoate; benzylidene derivatives of sorbitol such as monobenzylidene sorbitol and dibenzylidene sorbitol; disteadidi
  • Preservatives and fungicides As preservatives and fungicides, paraoxybenzoic acid alkyl ester, benzoic acid, sodium benzoate, sorbic acid, potassium sorbate, phenoxyethanol, imidazolidinyl urea, benzoic acid, salicylic acid, isopropylmethylphenol, Examples include coalic acid, paraoxybenzoic acid alkyl ester, parachloromethcresol, hexachlorophene, benzalkonium chloride, chlorhexidine chloride, trichlorocarbanilide, propynyl butylcarbamate, polylysine, photosensitizer, silver, plant extract and the like.
  • the cosmetic composition of the present invention may be either an emulsified composition or a non-aqueous composition, and the emulsified composition is selected when it is desired to give a fresh feeling to use.
  • an emulsification form any form of an O / W type emulsion, a W / O type emulsion, and a W / O / W type emulsion may be used, and a non-aqueous composition can be selected when oily feeling and water resistance are desired. Even in this case, a good cosmetic can be obtained.
  • the “non-aqueous composition” refers to an oily composition containing substantially no water. It is also possible to use a non-aqueous composition as a dispersion and adjust it in cosmetics. When a UV scattering agent is blended, the dispersibility of the dispersion is improved, etc. The degree of freedom increases.
  • the cosmetic is not particularly limited as long as it contains an essential component, but for example, a cosmetic liquid, milky lotion, cream, hair care, foundation, makeup base, concealer, cheek color, It can be applied to various products such as lipstick, eye shadow, eyeliner, body makeup, deodorant agent and the like.
  • a cosmetic liquid, milky lotion, cream, hair care, foundation, makeup base, concealer, cheek color It can be applied to various products such as lipstick, eye shadow, eyeliner, body makeup, deodorant agent and the like.
  • Various properties such as liquid, cream, solid, paste, gel, mousse, souffle, clay, and powder can be selected as the properties of the cosmetic of the present invention.
  • Example 1 Comparative Examples 1 to 4
  • a slurry was prepared using a paint shaker (media diameter 1.5 mm) according to the formulation shown in Table 1. Viscosity was measured under the conditions of 25 ° C./B type viscometer, spindle LV-3, 30 rotations after 30 seconds. The unit is mPa ⁇ s.
  • the present invention is excellent in powder dispersibility and can prepare a paste having a lower viscosity. Further, from the results of Table 3 above, when the dispersibility of the paste is improved, the viscosity of the cosmetic containing the paste is lowered and the degree of freedom of formulation is increased. Further, it was found that the present invention has good dispersibility regardless of the type of powder and the dispersion process.
  • Example 3 Comparative Examples 9 to 12
  • a cosmetic composition shown in Table 6 was prepared by the following method. Viscosity was measured at 25 ° C./B type viscometer, spindle LV-4, 6 rotations after 60 seconds. The unit is mPa ⁇ s.
  • Example 3 Characteristic Evaluation Regarding the cosmetic compositions of Example 3 and Comparative Examples 9 to 12 below, the feeling of use (no stickiness) and elongation (extensibility) of the cosmetics were evaluated from the evaluation criteria shown in Table 5. did. The results were determined according to the following criteria based on the average value of 10 people. In addition, the storage stability of the preparation was determined according to the following criteria based on the conditions of 1 month each at 50 ° C. and ⁇ 5 ° C. and compared with that before storage. The results are also shown in the table.
  • Alkyl-modified / partially cross-linked polyglycerin-modified silicone composition (Note 14) 4 (2) Silicone / alkyl branched polyglycerin-modified silicone (Note 1) 1 (3) Silicone / alkyl-modified / partially crosslinked dimethylpolysiloxane composition (Note 15) 3 (4) Decamethylcyclopentasiloxane (Note 7) 10 (5) Ethylhexyl methoxycinnamate 6 (6) Titanium oxide dispersion 1 13 (7) Zinc oxide dispersion 120 (8) Glycerin 4 (9) Ethanol 9 (10) Phenoxyethanol 0.3 (11) Sodium citrate 0.2 (12) Magnesium sulfate 0.5 (13) Water remaining Total 100.0% (Note 14) Alkyl-modified / partially crosslinked polyglycerin-modified silicone composition (KSG-830 ⁇ crosslinked product: 15 to 25%, triethylhexanoin: 75 to 85%>: manufactured by Shin
  • Alkyl-modified / partially cross-linked polyglycerin-modified silicone composition (Note 23) 3 (2) Alkyl-modified / partially crosslinked dimethylpolysiloxane composition (Note 12) 3 (3) Silicone / alkyl branched polyglycerin-modified silicone (Note 1) 1.5 (4) Diphenylsiloxyphenyl trimethicone (Note 6) 12 (5) Ethylhexyl methoxycinnamate 6 (6) Silicone composite powder (Note 24) 3 (7) Xanthan gum 0.3 (8) Dipropylene glycol 5 (9) Glycerin 3 (10) Methylparaben 0.1 (11) Sodium citrate 0.2 (12) Sodium chloride 0.5 (13) Water remaining Total 100.0% (Note 23) Alkyl-modified / partially crosslinked polyglycerin-modified silicone composition (KSG-840 ⁇ crosslinked product: 25-35%, squalane: 65-75%>: manufactured by Shin-Etsu Chemical
  • Silicone / alkyl-modified / partially crosslinked dimethylpolysiloxane composition (Note 15) 33 (2) Trimethylsiloxysilicate composition (Note 28) 10 (3) Diphenylsiloxyphenyl trimethicone (Note 6) 5 (4) Squalane 0.5 (5) Ethylhexyl methoxycinnamate 5 (6) Silicone composite powder (Note 24) 15.5 (7) Polymethyl methacrylate 2 (8) Dimethylpolysiloxane (Note 29) 8.5 (9) Silicone / alkyl branched polyglycerin-modified silicone (Note 1) 0.5 (10) Silicone-treated titanium oxide (average primary particle size: 0.25 ⁇ m) (Note 19) 6 (11) Silicone-treated yellow iron oxide (average primary particle size: 0.07 ⁇ m ⁇ 0.8 ⁇ m) (Note 19) 0.75 (12) Silicone-treated red iron oxide (average primary particle size: 0.08 ⁇ m ⁇ 0.7 ⁇ m) (Note 19
  • Alkyl-modified / partially crosslinked polyether-modified silicone composition (Note 11) 3.5 (2) Silicone / alkyl branched polyglycerin-modified silicone (Note 1) 1.5 (3) Alkyl branched polyether-modified silicone (Note 5) 1.5 (4) Alkyl-modified / partially crosslinked dimethylpolysiloxane composition (Note 12) 3 (5) Decamethylcyclopentasiloxane (Note 7) 4 (6) Cetyl ethylhexanoate 6 (7) Octocrylene 6 (8) Polysilicone-15 3 (9) Dimethylpolysiloxane (2cs) 10.5 (10) Silicone-treated fine particle zinc oxide (average primary particle size: 30 nm) 18 (11) Dipropylene glycol 4 (12) Ethanol 8 (13) Ethylhexylglycerin 0.1 (14) Sodium citrate 0.2 (15) Sodium chloride 0.5 (16) Water remaining Total 100.0% The W / O sunscreen had good us

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Emergency Medicine (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne une composition cosmétique ayant une excellente dispersibilité de la poudre même en présence d'une huile fortement polaire, une sensation agréable lors de l'utilisation et une bonne aptitude à l'étalement, ainsi qu'une excellente stabilité de la formulation. L'invention concerne une composition cosmétique contenant (A) de la silicone modifiée par de la polyglycérine ramifiée de silicone-alkyle: représentant de 0,1 à 12 % en masse, (b) de la poudre: représentant de 0,1 à 45 % en masse, (c) un absorbeur d'ultraviolets: représentant de 0,1 à 20 % en masse, et (d) une huile autre que (c) ayant une viscosité à 25 °C comprise entre 1 et 100 mm2/s: représentant de 0,1 à 60 % en masse.
PCT/JP2017/016898 2016-05-16 2017-04-28 Composition cosmétique WO2017199732A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2018518198A JP6969546B2 (ja) 2016-05-16 2017-04-28 化粧料組成物

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2016-097742 2016-05-16
JP2016097742 2016-05-16

Publications (1)

Publication Number Publication Date
WO2017199732A1 true WO2017199732A1 (fr) 2017-11-23

Family

ID=60326304

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2017/016898 WO2017199732A1 (fr) 2016-05-16 2017-04-28 Composition cosmétique

Country Status (2)

Country Link
JP (2) JP6969546B2 (fr)
WO (1) WO2017199732A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2019094280A (ja) * 2017-11-20 2019-06-20 花王株式会社 水中油型乳化化粧料
CN114340585A (zh) * 2019-08-26 2022-04-12 信越化学工业株式会社 固体化妆料
EP4056235A4 (fr) * 2019-11-08 2024-01-10 Shiseido Company, Ltd. Composition d'huile dans l'eau

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021241444A1 (fr) * 2020-05-29 2021-12-02 株式会社Ｄｎｐファインケミカル Dispersion
WO2022245029A1 (fr) * 2021-05-18 2022-11-24 주식회사 엘지생활건강 Composition cosmétique sous forme d'émulsion ou de dispersion huileuse contenant une teneur élevée en poudre
WO2023218971A1 (fr) * 2022-05-10 2023-11-16 株式会社 資生堂 Composition cosmétique d'écran solaire d'eau dans l'huile

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002363031A (ja) * 2001-06-06 2002-12-18 Mikuni Color Ltd 化粧品用顔料分散液並びに化粧品組成物及びその製造方法
JP2010143852A (ja) * 2008-12-18 2010-07-01 Shiseido Co Ltd 酸化チタン分散体およびそれを配合した化粧料
JP2010195694A (ja) * 2009-02-24 2010-09-09 Miyoshi Kasei Inc 粉体分散物とこの粉体分散物を含有する化粧料
JP2013071931A (ja) * 2011-09-29 2013-04-22 Kose Corp 油中水型乳化化粧料
JP2013216583A (ja) * 2012-04-04 2013-10-24 Shin-Etsu Chemical Co Ltd 化粧料
JP2014177453A (ja) * 2013-02-13 2014-09-25 Kose Corp 油性メークアップ化粧料
JP2014181218A (ja) * 2013-03-21 2014-09-29 Kose Corp 油性固形化粧料
WO2015093258A1 (fr) * 2013-12-17 2015-06-25 信越化学工業株式会社 Produit cosmétique

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002363031A (ja) * 2001-06-06 2002-12-18 Mikuni Color Ltd 化粧品用顔料分散液並びに化粧品組成物及びその製造方法
JP2010143852A (ja) * 2008-12-18 2010-07-01 Shiseido Co Ltd 酸化チタン分散体およびそれを配合した化粧料
JP2010195694A (ja) * 2009-02-24 2010-09-09 Miyoshi Kasei Inc 粉体分散物とこの粉体分散物を含有する化粧料
JP2013071931A (ja) * 2011-09-29 2013-04-22 Kose Corp 油中水型乳化化粧料
JP2013216583A (ja) * 2012-04-04 2013-10-24 Shin-Etsu Chemical Co Ltd 化粧料
JP2014177453A (ja) * 2013-02-13 2014-09-25 Kose Corp 油性メークアップ化粧料
JP2014181218A (ja) * 2013-03-21 2014-09-29 Kose Corp 油性固形化粧料
WO2015093258A1 (fr) * 2013-12-17 2015-06-25 信越化学工業株式会社 Produit cosmétique

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2019094280A (ja) * 2017-11-20 2019-06-20 花王株式会社 水中油型乳化化粧料
JP7043803B2 (ja) 2017-11-20 2022-03-30 花王株式会社 水中油型乳化化粧料
CN114340585A (zh) * 2019-08-26 2022-04-12 信越化学工业株式会社 固体化妆料
EP4056235A4 (fr) * 2019-11-08 2024-01-10 Shiseido Company, Ltd. Composition d'huile dans l'eau

Also Published As

Publication number Publication date
JP2020040994A (ja) 2020-03-19
JP7160023B2 (ja) 2022-10-25
JPWO2017199732A1 (ja) 2018-12-20
JP6969546B2 (ja) 2021-11-24

Similar Documents

Publication Publication Date Title
JP7160023B2 (ja) 化粧料組成物
JP6848987B2 (ja) 凹凸補正化粧料
JP6930589B2 (ja) ウォーターブレイク型日焼け止め化粧料
US10588849B2 (en) Cosmetic composition
KR20210088592A (ko) 화장료
JP7310795B2 (ja) 化粧料
JP2022105201A (ja) 連続油性相、液体β，β－ジフェニルアクリレートＵＶ遮蔽剤、液体サリチレートＵＶ遮蔽剤及び非環状揮発性シリコーン油を含有する組成物
JPWO2018221174A1 (ja) ウォーターブレイク化粧料
KR20220053625A (ko) 고형 화장료
WO2020017346A1 (fr) Dispersion, procédé pour sa production et produit cosmétique
JP7287458B2 (ja) 化粧料
KR20230157366A (ko) 실리콘 고무 입자의 수분산물 및 화장료
US11419796B2 (en) Stick-shaped cosmetic product
JP7444808B2 (ja) 化粧料
WO2024058171A1 (fr) Particules de silicone pour produits cosmétiques et produits cosmétiques
WO2022172816A1 (fr) Organopolysiloxane et produit cosmétique le contenant
WO2024058043A1 (fr) Composition cosmétique eau-dans-huile
WO2022239649A1 (fr) Produit cosmétique de maquillage résistant à l'eau
US20200281836A1 (en) Cosmetic

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 2018518198

Country of ref document: JP

NENP Non-entry into the national phase

Ref country code: DE

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 17799162

Country of ref document: EP

Kind code of ref document: A1

122 Ep: pct application non-entry in european phase

Ref document number: 17799162

Country of ref document: EP

Kind code of ref document: A1