WO2017008354A1 - Dispositif expérimental et procédé expérimental pour l'étude de la modification de squelette de milieu poreux dans un processus de décomposition d'hydrate de gaz naturel - Google Patents
Dispositif expérimental et procédé expérimental pour l'étude de la modification de squelette de milieu poreux dans un processus de décomposition d'hydrate de gaz naturel Download PDFInfo
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- WO2017008354A1 WO2017008354A1 PCT/CN2015/085928 CN2015085928W WO2017008354A1 WO 2017008354 A1 WO2017008354 A1 WO 2017008354A1 CN 2015085928 W CN2015085928 W CN 2015085928W WO 2017008354 A1 WO2017008354 A1 WO 2017008354A1
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- WIPO (PCT)
- Prior art keywords
- porous medium
- control unit
- gas
- skeleton
- natural gas
- Prior art date
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- 238000000354 decomposition reaction Methods 0.000 title claims abstract description 67
- 238000000034 method Methods 0.000 title claims abstract description 49
- NMJORVOYSJLJGU-UHFFFAOYSA-N methane clathrate Chemical compound C.C.C.C.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O NMJORVOYSJLJGU-UHFFFAOYSA-N 0.000 title claims abstract description 46
- 230000008569 process Effects 0.000 title claims abstract description 36
- 230000008859 change Effects 0.000 title claims abstract description 34
- 238000002474 experimental method Methods 0.000 title claims description 19
- 239000007788 liquid Substances 0.000 claims abstract description 55
- 238000005070 sampling Methods 0.000 claims abstract description 34
- 238000005191 phase separation Methods 0.000 claims abstract description 20
- 238000012545 processing Methods 0.000 claims abstract description 12
- 239000007787 solid Substances 0.000 claims description 42
- 238000006243 chemical reaction Methods 0.000 claims description 33
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 33
- 239000007789 gas Substances 0.000 claims description 25
- 239000003345 natural gas Substances 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 230000007246 mechanism Effects 0.000 claims description 15
- 230000015572 biosynthetic process Effects 0.000 claims description 11
- 239000002245 particle Substances 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 4
- 239000008247 solid mixture Substances 0.000 claims description 4
- 238000007789 sealing Methods 0.000 claims description 3
- 230000006698 induction Effects 0.000 claims description 2
- 239000002002 slurry Substances 0.000 claims 1
- 238000005065 mining Methods 0.000 description 20
- 239000012071 phase Substances 0.000 description 20
- -1 Natural gas hydrates Chemical class 0.000 description 11
- 238000002347 injection Methods 0.000 description 11
- 239000007924 injection Substances 0.000 description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 230000004660 morphological change Effects 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 238000004088 simulation Methods 0.000 description 5
- 239000007790 solid phase Substances 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 238000011160 research Methods 0.000 description 4
- 239000004576 sand Substances 0.000 description 4
- 238000005259 measurement Methods 0.000 description 3
- 230000005012 migration Effects 0.000 description 3
- 238000013508 migration Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000009530 blood pressure measurement Methods 0.000 description 2
- 238000009529 body temperature measurement Methods 0.000 description 2
- 230000001276 controlling effect Effects 0.000 description 2
- 239000008239 natural water Substances 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 239000013049 sediment Substances 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003034 coal gas Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 230000003436 cytoskeletal effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000005325 percolation Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
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- 238000012360 testing method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
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Images
Classifications
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- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
Definitions
- the invention relates to the field of multiphase seepage and natural gas hydrate exploitation in a porous medium, and particularly relates to an experimental device and an experimental method for studying a change of a skeleton of a porous medium during decomposition of a natural gas hydrate.
- Natural gas hydrate is a kind of cage-shaped crystalline compound produced by natural gas and water under low temperature and high pressure. Its shape is like ice and snow, and it is burned in case of fire. It is commonly called “combustible ice”. Natural gas hydrates in natural gas hydrates are mainly methane (>90%). At normal temperature and pressure, 1 m3 of natural gas hydrate decomposes and releases about 160 m 3 of natural gas, so natural gas hydrates have extremely high energy density. Natural gas hydrates in nature are mainly found in sedimentary layers of the continental shelf and terrestrial tundra. In 1964, scientists first discovered natural gas hydrates in the Siberian tundra. Soon after, natural gas hydrates found in seabed sediments were discovered in the Black Sea.
- natural gas hydrate mining technology is one of the key links to realize the development and utilization of natural gas hydrate resources.
- natural gas hydrates exist in a solid form in a porous medium.
- the basic idea of mining is to change the natural gas hydrate stable temperature-pressure environment, that is, the hydrate phase equilibrium conditions, causing the solid hydrate to be decomposed into natural gas and water in situ after the reservoir is produced. Accordingly, scientists have proposed several conventional mining techniques, such as: the pressure reduction method, the heat shock method, and the chemical reagent method.
- the particle size of the porous medium in the actual hydrate deposit is composed of 0.01 um microparticles to 500 um large particles, and the deformation of the porous medium skeleton is unavoidable during hydrate mining.
- One of the difficulties in the current hydrate mining technology is the lack of understanding of the gas-solid-liquid three-phase percolation mechanism of the porous medium-containing skeleton. It is necessary to obtain experimental data, and the phase change seepage in the hydrate decomposition process is directed to the hydrate sediment skeleton. The impact lacks basic experimental data, which is a key issue in the safety assessment of hydrate mining and requires experimental research.
- the technical problem to be solved by the present invention is to provide an experimental apparatus and an experimental method which can visually observe the morphological change of the porous medium skeleton with the hydrate decomposition.
- An experimental device for studying changes in the skeleton of a porous medium during decomposition of natural gas hydrates comprising a rapid sampling high pressure reactor, an inlet control unit, an outlet control unit, an ambient temperature control unit, a gas-solid liquid three-phase separation unit, and a data processing unit;
- the rapid sampling high pressure reaction kettle is placed in an ambient temperature control unit, and a porous medium can be filled in a rapid sampling high pressure reactor to simulate a geological environment;
- the inlet control unit is used to inject water and natural gas into the rapidly sampleable high pressure reactor;
- the export control unit is used to control the rapid sampling high pressure reaction during the gas hydrate decomposition experiment.
- the ambient temperature control unit is used to control the gas hydrate formation/decomposition process and the temperature of the sampling process;
- the gas-solid liquid three-phase separation unit is used for separating the gas-solid liquid mixture discharged after the decomposition of the weather hot water compound, and real-time metering the data of the gas-solid liquid three-phase output;
- the high-speed reaction kettle, the ambient temperature control unit, the gas-solid liquid three-phase separation unit, the outlet control unit, and the induction component in the inlet control unit can be connected to the data processing unit through a signal line; the data processing unit is used for collecting and processing The sensing signal of each sensing element.
- the rapid sampling high-pressure reactor of the experimental device can visually observe the morphological change of the porous medium skeleton with the hydrate decomposition, and meter the gas, solid and liquid three-phase production of the outlet. It is used to study the multi-phase seepage problem with solid phase migration in the process of decomposition and gas production of hydrate under different formation conditions under different formation conditions.
- the quick sampling high pressure reaction kettle comprises a kettle lid, a kettle body and a quick opening mechanism for quick sampling
- the quick opening mechanism comprises a clamp for fixedly connecting the kettle lid and the kettle body, and the kettle lid and the kettle body Sealed rubber ring.
- the quick opening mechanism is set so that the lid and the kettle body are quickly closed/opened, and the clamp is fixed, and the rubber ring seal makes it possible to quickly sample the high pressure reaction vessel, including the top pressure of the kettle lid to 25 MPa.
- the quick-sampling high-pressure reactor has a cylindrical or rectangular parallelepiped inside, and a thin inner sleeve is disposed on the inner wall thereof. After the lid is quickly opened, the thin inner sleeve can be arranged to take out the porous medium sample conveniently and quickly.
- the high-speed reactor can be quickly sampled and the opening time is shorter than 30s.
- the high pressure reactors related to hydrate mining research basically use bolts to fix the lid and the kettle body, and the opening time is often more than one hour.
- the porous medium skeleton Due to the long opening time of the lid and the kettle body in the prior art, the porous medium skeleton has been When the morphological changes occur under the change of external conditions, the morphological change conditions of the observed porous medium skeleton with the decomposition of natural gas hydrate are lost.
- the gas-solid liquid three-phase separation unit includes a screen sand remover and a gas-liquid separator connected in series with the screen sand remover.
- the internal volume of the rapidly sampled high pressure reactor is greater than 0.5L.
- the high pressure reactor is made to reflect the multiphase seepage flow conditions in the real hydrate reservoir mining.
- the porous medium has a particle size of less than 100 um.
- large particles were used to form a porous medium (particle size > 100 um), so that the porous medium skeleton during the decomposition of the hydrate could not be changed.
- the porous medium of the present invention has a particle diameter of less than 100 um, and is intuitively observed to change the skeleton of the porous medium due to decomposition of the hydrate. Chemical.
- Simulated injection wells and production wells are arranged in the fast sampling high pressure reactor according to requirements. A more realistic geological simulation environment can be obtained.
- the outlet control unit is connected to the gas-solid liquid three-phase separation unit by a straight pipe or a large arc angle pipe. It can make the gas-solid liquid three-phase mixture output smoothly, effectively avoiding the blockage of the mixture in the pipeline.
- S1 placing the rapidly sampled high pressure reaction kettle in the ambient temperature control unit, filling a porous medium in a rapidly sampled high pressure reaction vessel to simulate a geological environment; and setting an experimental ambient temperature through the inlet control The unit injects water and natural gas into the rapidly sampled high pressure reactor to generate a gas hydrate sample;
- the screen de-sander is used in series with the gas-liquid separator, and the solid-state separation is first performed, and the weight change of the weighing screen de-slicer is recorded to record the solid output, and then the solid output is recorded.
- the gas and liquid were separated and metered with a balance and a gas flow meter, respectively.
- the gas-solid liquid three-phase output data can be obtained accurately in real time, and the structure is simple.
- the outlet control unit When it is necessary to study the change of the porous medium skeleton at a certain moment, firstly, the outlet control unit is closed, and the overall temperature of the rapidly sampled high-pressure reaction reactor is lowered to -20 ° C to -40 ° C by the ambient temperature control unit, and the temperature is lowered. After fully releasing the outlet control unit, the pressure in the rapidly sampled high pressure reactor is reduced to one atmosphere, the lid is opened within 30 seconds, the porous medium skeleton is taken out, and the porous medium skeleton is directly observed or instrumentally measured with natural gas hydration. Morphological changes in the decomposition of matter.
- the reaction vessel was opened in 30 seconds by the quick opening mechanism in the reaction vessel.
- the porous medium skeleton was completely taken out, and the influence of hydrate decomposition on the morphological changes of the porous medium skeleton was studied by direct observation or instrumental measurement.
- the reactor can be quickly opened, and the porous medium skeleton can be completely taken out, so that the change of the porous medium skeleton due to the decomposition of the hydrate can be visually observed; the multiphase seepage problem containing the solid phase migration in the decomposition process of the natural gas hydrate can be studied; Accurately obtain the real-time output of gas-solid liquid three-phase in the decomposition process of natural gas hydrate; easy to operate, easy to control, suitable for reactors of various sizes and shapes; provide basic experimental data and theory for hydrate mining technology in accordance with.
- FIG. 1 is a block diagram of an experimental apparatus for changing a skeleton of a porous medium during decomposition of a natural gas hydrate according to the present invention
- FIG. 2 is a schematic view of an experimental apparatus for studying changes in the skeleton of a porous medium during decomposition of natural gas hydrate according to an embodiment of the present invention.
- an experimental apparatus for studying the change of the skeleton of a porous medium in the decomposition process of natural gas hydrates includes: a rapid sampling high pressure reactor, an ambient temperature control unit, a gas-solid liquid three-phase separation unit, an outlet control unit, and an inlet control unit. And a data processing unit.
- the rapid sampling high pressure reactor is placed in an ambient temperature control unit for controlling the hydrate formation/decomposition process and the temperature of the sampling process.
- the high-speed reaction kettle can be quickly sampled to achieve quick opening by setting a quick-opening kettle lid.
- the lid and the kettle body are fixedly connected by a clamp, and the rubber ring is used for sealing; in the rapid sampling high-pressure reaction kettle, the simulated injection well is arranged according to requirements.
- the inlet control unit, the rapid sampling high pressure reaction kettle, the outlet control unit, and the gas-solid liquid three-phase separation unit are sequentially connected through the control valve and the pipeline.
- the rapid sampling high-pressure reaction kettle, the ambient temperature control unit, the gas-solid liquid three-phase separation unit, the outlet control unit, and the inlet control unit are all provided with sensing elements, and each sensing element is connected to the data processing unit through a signal line.
- the rapid sampling high pressure reactor is filled with porous medium, water and natural gas are injected from the inlet control unit, and the hydrate formation temperature is controlled by the ambient temperature control unit to generate a hydrate sample.
- Decomposition experiments and porous media skeleton deformation studies can be started when the hydrate sample is formed.
- the outlet pressure is controlled by the outlet control unit, and with the decomposition of the hydrate, the gas-solid mixture in the high-pressure reactor can be quickly sampled and released to the outside of the rapidly sampled high-pressure reactor, and the gas-solid mixture is discharged.
- the compound is separated by a gas-solid liquid three-phase separation unit and metered in real time and recorded by a data processing unit.
- the outlet control unit In the process of decomposition of the whole hydrate, when it is necessary to study the change of the skeleton of the porous medium at any moment, the outlet control unit is first closed, and the overall temperature of the rapidly sampled high-pressure reactor is rapidly lowered to -20 ° C by the ambient temperature control unit. At 40 ° C, after the temperature is lowered, the outlet control unit is completely released, so that the pressure in the high-speed reaction vessel can be rapidly reduced to atmospheric pressure. At this time, the remaining water in the high-pressure reaction vessel can be quickly sampled to become an ice state, and the hydrate hardly decomposes due to the "self-protection effect" under low temperature conditions. At this time, the rapid sampling high pressure reactor is opened by a quick opening mechanism in the rapid sampling high pressure reactor.
- the porous medium skeleton is completely taken out within 30 s, and the influence of hydrate decomposition on the morphology change of the porous medium skeleton is studied by direct observation or instrumental measurement.
- the lid of the high-pressure reaction vessel that can be quickly sampled is closed/opened by a quick opening mechanism, and the maximum design pressure can reach 25 MPa.
- the inside of the reaction vessel can be designed as a cylindrical or rectangular parallelepiped.
- a thin inner sleeve is arranged on the inner wall of the reaction vessel, and after the quick opening of the kettle lid is opened, the entire porous medium block can be completely taken out without breaking the porous medium skeleton.
- the internal volume of the high-pressure reactor can be quickly sampled to be greater than 0.5L, and the volume is too small to reflect the multi-phase flow conditions in the real hydrate reservoir mining.
- Physical sensors such as temperature measurement and pressure measurement can be designed as needed to study physical and chemical changes in porous media during hydrate decomposition. It is also possible to increase the confining pressure or axial compression system to obtain a more realistic geological simulation environment.
- the outlet control unit includes an outlet pressure control mechanism and a well cluster extending into the simulated cavity of the rapidly sampleable high pressure reactor.
- the equipment technical requirements that the export control unit needs to meet include well settings that conform to different hydrate production methods, and the outlet control unit can accurately control the outlet pressure, so that the gas-solid liquid three-phase mixture can be smoothly produced, and the gas-solid liquid mixture can be effectively avoided. Blockage inside the pipe.
- a straight pipe connection can be used in the outlet control unit to avoid bending and valves as much as possible.
- the ambient temperature control unit needs to control the ambient temperature at which the hydrate is formed and decomposed, and can rapidly reduce the temperature of the high-pressure reactor to be quickly sampled to between minus 20 and 40 degrees. Therefore, the ambient temperature control unit is preferably designed to control the temperature using a common water bath during hydrate formation or decomposition, with a temperature range of 0-30 ° C and a high precision of 0.1 ° C. In the case of rapid cooling, the water in the water bath is evacuated, and liquid nitrogen or other coolant is injected to rapidly cool down. Stop adding liquid nitrogen when the temperature reaches minus 20 degrees, when the temperature When the degree is higher than minus 20 degrees, the liquid nitrogen is kept at a low temperature.
- the gas-solid liquid three-phase separation unit can realize separation and real-time metering of the produced gas-solid liquid three-phase.
- a screen desander can be used in series with the gas-liquid separator. The solid state is separated first, and the weight change of the weighing screen de-sander is recorded to record the solid output, and then the gas-liquid is separated and used separately. The balance is metered with a gas flow meter. The advantage of using this combination is that the gas-solid liquid three-phase output data can be obtained accurately in real time, and the structure is simple.
- the high-speed reaction vessel 1 can be quickly sampled, including a kettle lid, a kettle body and a quick opening mechanism; the quick opening mechanism includes a clamp for fixing the lid of the kettle lid and the kettle body, and sealing the kettle lid and the kettle body Rubber ring.
- the high pressure reactor 1 can be quickly sampled and placed in an ambient temperature control unit (cold tank 10) for controlling the hydrate formation/decomposition process and the temperature of the sampling process.
- the simulated injection well and the production well can be arranged in the high-speed reactor 1 and the porous medium can be filled in the rapid sampling high-pressure reactor to simulate the geological environment.
- the porous medium has a particle size of less than 100 ⁇ m.
- the inlet control unit consists of a liquid injection system 11, a gas injection system 12 and an evacuation system 13.
- the liquid injection system 11 is composed of a double plunger pump 111, a preheater 112, and a pressure sensor 113.
- the double plunger pump 111 controls the water injection flow rate
- the preheater 112 controls the water injection temperature
- the pressure sensor 113 monitors the inlet pressure.
- the gas injection system 12 is composed of a gas cylinder 121, a pressure regulating valve 122, an air compressor 123, a gas boosting pump 124 and a flow meter 125.
- the gas cylinder 121 provides a gas source
- the pressure regulating valve 122 sets the gas source pressure and air pressure.
- the machine 123 and the gas booster pump 124 inject gas into the reactor for gas pressurization, while the flow meter 125 meters the injected gas flow.
- the evacuation system 13 is composed of a vacuum gauge 131, a buffer tank 132, and a vacuum pump 133, and the exhaust gas in the reaction vessel can be discharged to form a vacuum.
- the outlet control unit includes an outlet pressure control mechanism 100 and a well cluster 101 that extends into the simulated cavity of the rapidly sampleable high pressure reactor.
- the gas-solid liquid three-phase separation unit is composed of a screen sand remover 21, a back pressure valve 22, a gas-liquid separator 23, a gas flow meter 24, a liquid collection cylinder 25, and an electronic scale 26, and an outlet control unit outlet is connected to the screen to remove sand.
- the device 21 realizes solid phase separation.
- the screen remover 21 is connected to a back pressure valve 22 composed of a buffer container 221, a pointer pressure gauge 222, and a hand pump 223, and the back pressure valve 22 controls the outlet pressure.
- the back pressure valve 22 is connected to the gas-liquid separator 23 to achieve gas-liquid separation.
- the exhaust gas is metered by the gas flow meter 24, and the liquid is collected by the liquid collection cylinder 25, and then the electronic scale 26 is metered.
- the experiment needs to study the change of the porous medium skeleton at 30 minutes after the start of hydrate decomposition.
- the outlet control unit is first closed, the cooling water in the water bath is taken out, and the overall temperature of the rapidly sampling high-pressure reactor is rapidly lowered to -20 ° C to -40 by injecting liquid nitrogen. °C, after the temperature is lowered, the back pressure valve is completely released, so that the pressure in the high-pressure reaction vessel can be rapidly reduced to atmospheric pressure. At this time, the remaining water in the high-pressure reaction vessel can be quickly sampled to become an ice state, and the hydrate hardly decomposes due to the "self-protection effect" under low temperature conditions.
- the experimental device for studying the change of the porous medium skeleton in the decomposition process of natural gas hydrate can study the multiphase seepage problem containing solid phase migration in the decomposition process of natural gas hydrate; and can accurately obtain natural gas hydrate
- the real-time output of gas-solid liquid three-phase in the decomposition process; the change of porous medium skeleton caused by hydrate decomposition can be visually observed; the operation is simple and easy to control, and it is suitable for reactors of various sizes and shapes;
- the mining technology provides basic experimental data and theoretical basis.
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Abstract
L'invention concerne un dispositif expérimental pour l'étude de la modification de squelette de milieu poreux dans un processus de décomposition d'hydrate de gaz naturel, comprenant un autoclave (1) pouvant échantillonner rapidement, une unité de commande d'admission, une unité de commande d'échappement, une unité de réglage de température environnementale, une unité de séparation en trois phases gazeuse, solide et liquide et une unité de traitement de données. L'autoclave (1) peut être démarré rapidement, et un squelette de milieu poreux peut être extrait complètement, de sorte que la modification de squelette de milieu poreux causée par la décomposition d'hydrate peut être observée visuellement. Puisqu'il est simple et facile à commander, le dispositif et le procédé expérimentaux sont applicables à des autoclaves (1) de tailles et de formes diverses.
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CN201510404617.4A CN105044284B (zh) | 2015-07-10 | 2015-07-10 | 一种研究天然气水合物分解过程中多孔介质骨架变化的实验装置的实验方法 |
CN201510404617.4 | 2015-07-10 |
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PCT/CN2015/085928 WO2017008354A1 (fr) | 2015-07-10 | 2015-08-03 | Dispositif expérimental et procédé expérimental pour l'étude de la modification de squelette de milieu poreux dans un processus de décomposition d'hydrate de gaz naturel |
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