WO2014199349A3 - Metal impregnated amorphous silicates for the selective conversion of ethanol to butadiene - Google Patents

Metal impregnated amorphous silicates for the selective conversion of ethanol to butadiene Download PDF

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Publication number
WO2014199349A3
WO2014199349A3 PCT/IB2014/062203 IB2014062203W WO2014199349A3 WO 2014199349 A3 WO2014199349 A3 WO 2014199349A3 IB 2014062203 W IB2014062203 W IB 2014062203W WO 2014199349 A3 WO2014199349 A3 WO 2014199349A3
Authority
WO
WIPO (PCT)
Prior art keywords
butadiene
ethanol
amorphous silicates
selective conversion
metal impregnated
Prior art date
Application number
PCT/IB2014/062203
Other languages
French (fr)
Other versions
WO2014199349A2 (en
Inventor
Mathias Feyen
Kirsten SPANNHOFF
Ulrich Müller
Xinhe Bao
Weiping Zhang
Dirk De Vos
Hermann Gies
Takashi Tatsumi
Feng-Shou Xiao
Yokoi TOSHIYUKI
Yilmaz BILGE
Original Assignee
Basf Se
Basf (China) Company Limited
Tokyo Institute Of Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se, Basf (China) Company Limited, Tokyo Institute Of Technology filed Critical Basf Se
Publication of WO2014199349A2 publication Critical patent/WO2014199349A2/en
Publication of WO2014199349A3 publication Critical patent/WO2014199349A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/94—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/02—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/14—Silica and magnesia
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/72—Copper
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Abstract

Providing a catalyst and a process for the preparation of butadiene, and the catalyst comprising Hf and two or more further catalytically active metals M1 and M2, wherein the two or more further catalytically active metals M1 and M2 are selected from the group consisting of Zr, Zn, Cu and combinations of two or more thereof, and wherein M1 is different from M2.
PCT/IB2014/062203 2013-06-13 2014-06-13 Metal impregnated amorphous silicates for the selective conversion of ethanol to butadiene WO2014199349A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN2013077179 2013-06-13
CNPCT/CN2013/077179 2013-06-13

Publications (2)

Publication Number Publication Date
WO2014199349A2 WO2014199349A2 (en) 2014-12-18
WO2014199349A3 true WO2014199349A3 (en) 2015-07-02

Family

ID=52022858

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2014/062203 WO2014199349A2 (en) 2013-06-13 2014-06-13 Metal impregnated amorphous silicates for the selective conversion of ethanol to butadiene

Country Status (1)

Country Link
WO (1) WO2014199349A2 (en)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10358395B2 (en) 2014-09-16 2019-07-23 Sekisui Chemical Co., Ltd. Method for producing butadiene and device for producing butadiene
US10556801B2 (en) 2015-02-12 2020-02-11 Basf Se Process for the preparation of a dealuminated zeolitic material having the BEA framework structure
MX2017014148A (en) 2015-05-04 2018-03-15 Basf Se Process for the preparation of melonal.
FR3038849B1 (en) 2015-07-13 2019-11-29 IFP Energies Nouvelles MESOPOROUS MIXED OXIDE CATALYST COMPRISING SILICON
FR3038850B1 (en) 2015-07-13 2019-11-08 IFP Energies Nouvelles CATALYST TA-NB FOR THE PRODUCTION OF 1,3-BUTADIENE
JP6619255B2 (en) * 2016-02-15 2019-12-11 積水化学工業株式会社 1,3-butadiene synthesis catalyst, 1,3-butadiene production apparatus, and 1,3-butadiene production method
JP7160604B2 (en) * 2017-08-30 2022-10-25 積水化学工業株式会社 Method for producing 1,3-butadiene and acetaldehyde diethyl acetal
EP3689452A4 (en) 2017-09-27 2021-06-30 Sekisui Chemical Co., Ltd. Catalyst, device for manufacturing conjugated diene, and method for manufacturing conjugated diene
EP3733285A4 (en) 2017-12-27 2021-09-15 Sekisui Chemical Co., Ltd. Catalyst and method for producing same, and method for producing diene compound using said catalyst
EP3738670A4 (en) 2018-01-12 2021-10-06 Sekisui Chemical Co., Ltd. Catalyst, method for producing same, and method for producing diene compound using said catalyst
JPWO2019142865A1 (en) * 2018-01-17 2021-01-14 積水化学工業株式会社 A catalyst and a method for producing a diene compound using the catalyst.
US20210339226A1 (en) * 2018-09-21 2021-11-04 Sekisui Chemical Co., Ltd. Catalyst, and method for producing 1,3-butadiene using same
US20220288562A1 (en) 2019-06-25 2022-09-15 Sekisui Chemical Co., Ltd. Catalyst and method for producing diene compound
CN112275270A (en) * 2019-07-25 2021-01-29 中国科学院大连化学物理研究所 Supported catalyst and preparation method thereof
CN112295556A (en) * 2019-07-29 2021-02-02 中国科学院大连化学物理研究所 Supported catalyst and preparation method thereof
JP6816241B2 (en) * 2019-11-14 2021-01-20 積水化学工業株式会社 1,3-butadiene synthesis catalyst, 1,3-butadiene production equipment and 1,3-butadiene production method

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101152768B1 (en) * 2010-04-22 2012-06-18 금호석유화학 주식회사 Nano-silica based catalysts for the production of 1,3-butadiene and production method of 1,3-butadiene thereof
CN102728370A (en) * 2012-06-28 2012-10-17 烟台万华聚氨酯股份有限公司 Catalyst for preparing neopentyl glycol by hydrogenation and preparation method of catalyst
CN102781571A (en) * 2009-12-03 2012-11-14 巴斯夫欧洲公司 Catalyst and method for producing an amine

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102781571A (en) * 2009-12-03 2012-11-14 巴斯夫欧洲公司 Catalyst and method for producing an amine
KR101152768B1 (en) * 2010-04-22 2012-06-18 금호석유화학 주식회사 Nano-silica based catalysts for the production of 1,3-butadiene and production method of 1,3-butadiene thereof
CN102728370A (en) * 2012-06-28 2012-10-17 烟台万华聚氨酯股份有限公司 Catalyst for preparing neopentyl glycol by hydrogenation and preparation method of catalyst

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
ANGELICI, CARLO ET AL.: "Chemocatalytic Conversion of Ethanol into Butadiene and Other Bulk Chemicals", CHEMSUSCHEM, vol. 6, 23 May 2013 (2013-05-23) *
JONES, MATTHEW D. ET AL.: "Investigations into the conversion of ethanol into 1, 3- butadiene", CATALYSIS SCIENCE & TECHNOLOGY, vol. 1, 14 February 2011 (2011-02-14), pages 271 *

Also Published As

Publication number Publication date
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