WO2012165703A1 - Lubricant composition for cleaning internal combustion engines - Google Patents

Lubricant composition for cleaning internal combustion engines Download PDF

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Publication number
WO2012165703A1
WO2012165703A1 PCT/KR2011/005336 KR2011005336W WO2012165703A1 WO 2012165703 A1 WO2012165703 A1 WO 2012165703A1 KR 2011005336 W KR2011005336 W KR 2011005336W WO 2012165703 A1 WO2012165703 A1 WO 2012165703A1
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WO
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Prior art keywords
weight
internal combustion
engine
mixture
lubricant composition
Prior art date
Application number
PCT/KR2011/005336
Other languages
French (fr)
Korean (ko)
Inventor
이기현
김형준
Original Assignee
인텍케미칼(주)
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Publication of WO2012165703A1 publication Critical patent/WO2012165703A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M161/00—Lubricating compositions characterised by the additive being a mixture of a macromolecular compound and a non-macromolecular compound, each of these compounds being essential
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04—Elements
    • C10M2201/041—Carbon; Graphite; Carbon black
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/06—Well-defined aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/022—Ethene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084—Acrylate; Methacrylate
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/041—Triaryl phosphates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/02—Unspecified siloxanes; Silicones
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/041—Siloxanes with specific structure containing aliphatic substituents
    • C10M2229/0415—Siloxanes with specific structure containing aliphatic substituents used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04—Detergent property or dispersant property
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines

Definitions

  • the present invention relates to an engine cleaning lubricant composition for cleaning the inside of an engine. More specifically, the present invention relates to an engine cleaning lubricant composition for cleaning the inside of an engine without disassembling the engine of various impurities, carbon, sludge, gum, etc., which are generated and accumulated in the engine during long-term use of an internal combustion engine such as an automobile engine. .
  • the most commonly used method is to add an engine cleaner with fuel directly to the fuel tank and to use it in a mixture of engine oils, but these methods have a wide range of solubility to clean the engine efficiently.
  • the detergent composition which has is preferable.
  • U.S. Patent No. 3,676,089, U.S. Patent No. 3,649,229, U.S. Patent No. 4,247,301, and Korean Patent No.1994-8390 disclose compositions containing polyamines and derivatives thereof.
  • Korean Patent Laid-Open Publication No. 2002-15162 discloses a cleaning composition for an internal combustion engine in which a composition containing trichloroethane and methylene chloride is mixed with an automobile lubricating oil.
  • a disadvantage in that only the surface of the contaminant is cleaned and effective cleaning of thick accumulated contaminants is not achieved.
  • the present invention is to provide an engine cleaning lubricant composition which is excellent in the cleaning effect against the dirt accumulation accumulated in the long-term use of the engine in order to solve the problems of the prior art, the cleaning effect can be long lasting. have.
  • the present invention is an engine cleaning lubricant comprising oil for internal combustion engine, xylene (C 6 H 4 (CH 3 ) 2 ), antioxidant, clean dispersant, rust preventive agent, extreme pressure agent, silicone antifoaming agent, viscosity index improver, fluid depressant, synthetic oil It relates to a composition.
  • the present invention is 20 to 60% by weight of oil for internal combustion engines, 5 to 15% by weight of xylene (C 6 H 4 (CH 3 ) 2 ), 5 to 10% by weight of dibutylhydroxytoluene as an antioxidant, clean dispersant 5-15% by weight of rhobenzylamine, 10-15% by weight of sulfonate as rust inhibitor, 5-10% by weight of tricresyl phosphate or sulfide terpene as extreme pressure agent, 1-8% by weight of silicone antifoaming agent, ethylene-propylene as viscosity index improver It relates to an engine cleaning lubricant composition comprising 5 to 10% by weight of copolymer, 1 to 5% by weight of polyalkyl (meth) acrylate as fluid depressant, and 1 to 5% by weight of dimethylpolysiloxane as synthetic oil.
  • xylene C 6 H 4 (CH 3 ) 2
  • dibutylhydroxytoluene as an antioxidant
  • the present invention may further include 0.1 to 2% by weight of carbon nanoparticles, ultra high molecular weight polyethylene powder having a weight average molecular weight of 1 ⁇ 10 6 to 5 ⁇ 10 6 , or a mixture thereof.
  • it may further comprise 0.1 to 2% by weight of pigments, perfumes or mixtures thereof.
  • the oil for the internal combustion engine serves to maintain the smooth operation of the machinery, all of the usual internal combustion engine oil is possible, but 7.5W / 30, three kinds of special land 10/30 is preferred. It is preferable to use the content of 20 to 60% by weight. If the content is less than 20% by weight, it is not suitable for use as a lubricant, and when it exceeds 60% by weight, the use amount of other additives is reduced. The cleaning effect of pollutants (carbon, sludge, etc.) can be reduced.
  • the xylene serves to decompose and remove contaminants such as sludge produced and fixed on the metal surface.
  • the inventors of the present invention in the process of research for the efficient removal of contaminants and development of a composition that does not contain environmental harmful substances, xylene is not an environmental regulatory substance, the removal efficiency of contaminants is better than other aromatic hydrocarbon materials, especially In the case of using a specific content range, it has been found that the removal efficiency of the contaminant is greatly improved, thereby completing the present invention.
  • the xylene is characterized by using 5 to 15% by weight. When the content of xylene is used less than 5% by weight, the removal efficiency of the pollutants is insignificant, and when using 5% by weight or more and 15% by weight, the removal efficiency of the pollutants is very excellent.
  • the antioxidants as a component that acts to enable long-term use by delaying the oxidation rate of the lubricating oil, in the present invention, when dibutyl hydroxytoluene is used, further improved effect with other components Expresses.
  • the content expresses the best effect in the range using 5 to 10% by weight.
  • the dispersant disperses insoluble substances in oil due to the surfactant activity, thereby preventing aggregation of contaminants such as sludge in the engine, neutralizing acidic substances, and common surfactants.
  • benzylamine in the composition of the present invention, especially when used in 5 to 15% by weight is very excellent decontamination and prevention effect.
  • the anti-rust additives serves to prevent the formation of rust generated due to moisture in the engine, and sulfonate, carboxylate or methanol may be used, but the composition of the present invention It is preferable to use a sulfonate salt, and specific examples of such sulfonate salts include ammonium sulfonate, barium sulfonate, and the like. The content range is 10 to 15% by weight when used in corrosion prevention and decontamination efficiency is very good.
  • the extreme press additives react with the metal surface by heat generation due to local fusion when metal contacts occur to form a film of the metal inorganic compound at a high speed to prevent extreme wear. It is preferable to use tricresil phosphate or sulfide terpene in the composition of the present invention.
  • the content is 5 to 10% by weight when used in the extreme wear protection efficiency of the metal surface is very excellent.
  • silicone antifoam agents are used to alleviate or eliminate lubricating oil bubbles.
  • silicone oil is preferable, and in particular, a silicone viscosity of 250 to 2500 mPas (25 ° C) is used.
  • Simethicone is (- (CH 3) 2 -SiO- ) stabilized with trimethylsiloxy end protected units (- (CH 2) 2 -SiO- ) dimethicone compounds consisting of linear siloxane polymers containing repeating units of the n It means a mixture of and silicon dioxide. The content is very good decontamination efficiency when used in 1 to 8% by weight.
  • the viscosity index improvers (viscosity index improvers) is used to improve the viscosity characteristics of the lubricating oil
  • the organic material including the lubricating oil is sensitive to changes in temperature, the viscosity is increased at low temperatures and very viscous at high temperatures Becomes smaller. At low temperatures, the startability of the machinery is poor, and at high temperatures, the lubricating film is weak, and wear is easily caused.
  • a viscosity index improver for improving such a viscosity characteristic an ethylene-propylene copolymer is preferable. Specifically, it is preferable to use an ethylene-propylene copolymer having a weight average molecular weight of 5000 to 50000. When the content is used in 5 to 10% by weight, the lubricating viscosity stability is very excellent.
  • the pour point depressants are used to lower the pour point. Since the main components of the lubricating oil are various hydrocarbon mixtures, the fluid contained in the lubricating oil is high while the water contained in the lubricating oil is frozen. Are expressed, resulting in the deterioration of the lubricant. The so-called structural viscosity phenomenon appears, in which case the addition of pour point depressants acts to lower the pour point.
  • polyalkyl (meth) acrylate it is preferable to use polyalkyl (meth) acrylate as the fluid lowering agent.
  • the alkyl may be an alkyl of (C1-C10), of which methyl and ethyl are preferred.
  • the synthetic oil is used to improve the mixing of the components of the present invention and to improve the storage stability, specifically, it is preferable to use dimethylpolysiloxane.
  • the content of 1 to 5% by weight is very effective in decontamination and antifouling.
  • the engine cleaning lubricant according to the present invention may further include 0.1 to 2% by weight of carbon nanoparticles, ultra high molecular weight polyethylene powder having a weight average molecular weight of 1 ⁇ 10 6 to 5 ⁇ 10 6 , or a mixture thereof, as necessary.
  • the ultra high molecular weight polyethylene powder is a material having excellent wear resistance and excellent mechanical strength, and can further improve the removal efficiency of contaminants.
  • the carbon nanoparticles are used to reduce the friction coefficient of the cylinder pump of the engine and to further improve the removal efficiency of contaminants. It is preferable to use those having an average particle diameter of 10 to 100 nm, and the shape is not limited.
  • the ultra high molecular weight polyethylene powder having the carbon nanoparticles or the weight average molecular weight of 1 ⁇ 10 6 to 5 ⁇ 10 6 can be economically and effectively used in the range of 0.1 to 2% by weight.
  • the engine cleaning lubricant according to the present invention may further comprise 0.1 to 2% by weight of pigments, perfumes or mixtures thereof as necessary.
  • the internal combustion engine cleaning lubricant according to the present invention adds 3% to 5% of the present composition according to the amount of the existing engine oil to the engine oil, and then idles for a predetermined period of time (100 km to 300 km) or idle (60 minutes to 180 minutes). Min) and use it to replace oil.
  • the engine cleaning lubricating composition of the present invention is characterized by the order of loading and the input temperature, and when the mixing temperature is outside the following range, the composition may not be mixed and layer separation may occur, and dispersibility and storage stability may be reduced. .
  • step b) heating the mixture of step a) to 80-85 ° C. and then adding and mixing dimethylpolysiloxane with synthetic oil;
  • step c) after cooling the mixture of step b) to 0 ⁇ 10 °C, mixing by rotating at high speed to 10000 ⁇ 30000rpm by adding xylene;
  • step d) heating the mixture of step c) to 65-75 ° C. and then adding and mixing tricresil phosphate with extreme pressure agent;
  • step d) lowering the temperature of the mixture of step d) to 40-45 ° C., adding and mixing oil for an internal combustion engine;
  • step e) mixing the mixture of step e) by adding benzylamine as a clean dispersant, a silicone-based antifoaming agent, an ethylene-propylene copolymer as a viscosity index improver, and polymethyl methacrylate as a fluidity lowering agent;
  • carbon nanoparticles a weight average molecular weight of 1 ⁇ 10 6 to 5 ⁇ 10 6 in step f) may be added to the ultra-high molecular weight polyethylene powder or a mixture thereof as necessary.
  • the present invention may add a pigment, a fragrance or a mixture thereof in step d) as necessary.
  • the engine cleaning lubricant according to the present invention decomposes and cleans various impurities, carbon, sludge, gum, etc., which are generated and stuck inside the engine, to form a high-strength, low-friction surface, and improve adhesion of the adhesion surface by improving the performance of the engine.
  • By normalizing the performance of the engine to normalize it has the effect of efficient use of energy due to improved fuel economy and environmental protection by reducing the emission of environmental substances.
  • the physical properties were measured by the following measurement method.
  • Oxidation stability test was conducted according to KS M 2008.
  • Antirust performance test was conducted according to KS M 2009.
  • the removal rate (%) was measured by measuring the concentrations of carbon monoxide, carbon dioxide, and hydrocarbon in the engine exhaust gas before and after cleaning using a passenger car having an exhaust volume of 2000 cc and a driving distance of 14,523 km. .
  • the car was driven 300 km in normal driving conditions (driving speed 50 ⁇ 60km (2 ⁇ 3 gears) for 1 hour and 4 steps after that). After running, the lid of the engine was opened, and the initial state of the engine was visually observed. The concentrations of carbon monoxide, carbon dioxide, and hydrocarbons and the excess air ratio of the engine exhaust gas were measured.
  • Carbon monoxide removal rate (%) (concentration of carbon monoxide before washing-concentration of carbon monoxide after washing) / concentration of carbon monoxide before washing ⁇ 100
  • % Hydrocarbon removal rate (the concentration of hydrocarbon before washing-the concentration of hydrocarbon after washing) / the concentration of hydrocarbon before washing ⁇ 100
  • Ethylene-propylene copolymer (weight average molecular weight 15,000) as 10% by weight of the benzylamine, a clean dispersant, 5% by weight of a silicone antifoaming agent (shinetsu, KS-66, SIMETHICONE with a viscosity of 300 mPas) and a viscosity index improver 8% by weight and 4% by weight of polymethyl methacrylate (weight average molecular weight 20,000) were added as a fluid lowering agent.
  • a silicone antifoaming agent shinetsu, KS-66, SIMETHICONE with a viscosity of 300 mPas
  • a viscosity index improver 8% by weight 4% by weight of polymethyl methacrylate
  • Example 1 Except for changing the content of the internal combustion engine oil and xylene in Example 1 as shown in Table 1 to prepare a composition in the same manner.
  • fragrance acacia emulsifying perfume
  • the temperature was lowered to 40 ° C, and 30% by weight of oil for internal combustion engines (GS Caltex Deluxe Gold V 7.5W / 30, Hyundai gear oil 85W / 140) was added. And mixed.
  • Ethylene-propylene copolymer (weight average molecular weight 15,000) as 10% by weight of the benzylamine, a clean dispersant, 5% by weight of a silicone antifoaming agent (shinetsu, KS-66, SIMETHICONE with a viscosity of 300 mPas) and a viscosity index improver 8% by weight, 4% by weight of polymethyl methacrylate (weight average molecular weight 20,000) and 0.5% by weight of carbon nanoparticles (average particle diameter: 50 nm) were added as a fluid lowering agent.
  • a silicone antifoaming agent shinetsu, KS-66, SIMETHICONE with a viscosity of 300 mPas
  • a viscosity index improver 8% by weight 4% by weight of polymethyl methacrylate (weight average molecular weight 20,000) and 0.5% by weight of carbon nanoparticles (average particle diameter: 50 nm) were added as a
  • fragrance acacia emulsifying perfume
  • the temperature was lowered to 40 ° C, and 30% by weight of oil for internal combustion engines (GS Caltex Deluxe Gold V 7.5W / 30, Hyundai gear oil 85W / 140) was added. And mixed.
  • Ethylene-propylene copolymer (weight average molecular weight 15,000) as 10% by weight of the benzylamine, a clean dispersant, 5% by weight of a silicone antifoaming agent (shinetsu, KS-66, SIMETHICONE with a viscosity of 300 mPas) and a viscosity index improver ) 8% by weight, Ultra High Molecular Weight Polyethylene Powder (Ticona GmbH, Hostalen GUR 4113) with 0.5% by weight of polymethyl methacrylate (weight average molecular weight 20,000), weight average molecular weight 3.8 ⁇ 10 6 Add and mix.
  • a silicone antifoaming agent shinetsu, KS-66, SIMETHICONE with a viscosity of 300 mPas
  • a viscosity index improver 8% by weight
  • Ultra High Molecular Weight Polyethylene Powder (Ticona GmbH, Hostalen GUR 4113) with 0.5% by weight of polymethyl methacryl
  • Ethylene-propylene copolymer (weight average molecular weight 15,000) as 10% by weight of the benzylamine, a clean dispersant, 5% by weight of a silicone antifoaming agent (shinetsu, KS-66, SIMETHICONE with a viscosity of 300 mPas) and a viscosity index improver 8% by weight, 4% by weight of polymethyl methacrylate (weight average molecular weight 20,000) as a fluid depressant, 0.3% by weight of carbon nanoparticles (average particle diameter 50nm), ultra-high molecular weight polyethylene powder having a weight average molecular weight of 3.8 ⁇ 10 6 ( 0.2 wt% of Ticona GmbH, Hostalen GUR 4113) was
  • composition was prepared in the same manner as in Example, except that the composition was prepared without using xylene.
  • the content of each component is summarized in Table 2 below, and measured and shown in Table 3 below.
  • the cleaning lubricant composition according to the present invention is smoothly lubricated by dissolving and removing carbon sludge adhered to metal surfaces such as a catalyst muffler such as a cylinder head, a carburetor, and an injector of an automobile engine and adsorbed to the inside of the engine, thereby enhancing output. And it was found that there is an effect to reduce the exhaust gas.
  • the cleaning lubricant composition according to the present invention smoothly removes carbon sludge adhered to a metal surface such as a catalyst muffler such as a cylinder head, a carburetor, an injector of an automobile engine and adsorbed to the inside of the engine to smooth lubrication, and enhances output and discharges. It is highly industrially available because of its excellent gas-reducing effect.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The present invention relates to an engine-cleaning lubricant composition for cleaning internal combustion engines. According to the present invention, the engine-cleaning lubricant composition comprises an internal combustion engine oil, xylene, an antioxidizing agent, a detergent-dispersant, an anticorrosive, an extreme pressure additive, a silicone-based antifoaming agent, a viscosity index improver, a pour point depressant, and a synthetic oil. According to the present invention, the engine-cleaning lubricant composition cleans various kinds of impurities, such as carbon, sludge, gum and the like, generated and adhered inside of an engine, increases formation of surfaces with high strength and low friction, and increases adhesion thereby normalizing the performance of the engine.

Description

내연기관 세정윤활제 조성물Internal combustion engine cleaning lubricant composition
본 발명은 엔진 내부를 세정하기 위한 엔진 세정윤활제 조성물에 관한 것이다. 보다 상세하게는 자동차 엔진 등의 내연기관의 장기간 사용 시 엔진의 내부에 생성되어 축적되는 각종 불순물, 카본, 슬럿지, 검 등을 엔진을 해체하지 않고 엔진내부를 세정하기 위한 엔진 세정윤활제 조성물에 관한 것이다.The present invention relates to an engine cleaning lubricant composition for cleaning the inside of an engine. More specifically, the present invention relates to an engine cleaning lubricant composition for cleaning the inside of an engine without disassembling the engine of various impurities, carbon, sludge, gum, etc., which are generated and accumulated in the engine during long-term use of an internal combustion engine such as an automobile engine. .
최근 들어 가솔린 엔진, 디젤렌진, LPG 엔진 등을 장착한 일반 승용차, 버스, 트럭 및 오토바이 등이 급격하게 증가하고 있으며, 상기 엔진들은 기술 향상으로 인하여 내구성이 증가하여 종래의 엔진에 비하여 사용기간이 상당히 길어졌으나, 이에 비례하여 엔진은 장기간의 사용으로 인하여 엔진의 트로틀밸브, 분사기, 흡입밸브 및 연소실 등에 카본, 검 등의 오염 퇴적물이 생성 축적되어 엔진 운전시 엔진내부의 마찰저항의 증가시키고, 연소실 내의 기밀성 및 압축성의 저하를 초래하여 연료의 불완전 연소를 초래하는 원인이 되고 있다.Recently, general passenger cars, buses, trucks and motorcycles equipped with gasoline engines, diesel engines, LPG engines, etc. are rapidly increasing, and the engines have increased durability due to technology improvement and thus have a considerably longer service life than conventional engines. However, in proportion to the engine, due to long-term use, contaminant deposits such as carbon and gums are generated and accumulated in the engine throttle valve, injector, intake valve, and combustion chamber to increase frictional resistance in the engine during engine operation. It causes a decrease in airtightness and compressibility, which causes incomplete combustion of the fuel.
상기와 같은 문제점으로 인하여 엔진의 세정을 위하여 다음의 여러 방법을 사용하고 있다.Due to the above problems, the following various methods are used to clean the engine.
(a) 높은 rpm에서 엔진을 운전하면서 기화기의 개방 공기 트로틀에 직접 엔진 세정제 조성물을 투입하여 세정제를 연료와 혼합되도록 하여 연소공정동안 연소와 세정을 시키는 방법.(a) Combustion and cleaning during the combustion process by injecting the engine cleaning composition directly into the open air throttle of the carburetor while running the engine at high rpm to mix the cleaning agent with fuel.
(b) 엔진연료 및 세정제를 포함하는 압축용기의 사용을 포함하는 분사기의 세정방법.(b) A method of cleaning an injector comprising the use of a compressed container comprising an engine fuel and a cleaning agent.
(c) 공기 흡입 다기관에 연결된 진공 포트로부터 진공라인을 단절시킨 후 고무 가용성 라인을 진공포트에 연결시키는 것을 포함하는 진공단절기술을 이용하는 방법.and (c) disconnecting the vacuum line from the vacuum port connected to the air intake manifold and then connecting the rubber soluble line to the vacuum port.
(d) 차량의 연료탱크에 직접 첨가하는 엔진 세정제 조성물을 사용하는 방법.(d) A method of using an engine cleaner composition that is added directly to a vehicle's fuel tank.
(e) 내연기관의 엔진오일에 혼합한 엔진 세정제 조성물을 사용하는 방법.(e) A method of using an engine cleaner composition mixed with engine oil of an internal combustion engine.
상기의 세정방법 중에서 가장 흔히 사용하는 방법이 직접 연료탱크에 연료와 함께 엔진 세정제를 첨가하는 방법과 엔진오일에 혼합하여 사용하는 방법이나, 이 방법들은 엔진을 효율적으로 세정하기 위하여 넓은 용해도의 범위를 갖는 세정제 조성물이 바람직하다.Among the above cleaning methods, the most commonly used method is to add an engine cleaner with fuel directly to the fuel tank and to use it in a mixture of engine oils, but these methods have a wide range of solubility to clean the engine efficiently. The detergent composition which has is preferable.
연료에 첨가하는 방식의 세정제로서는 미합중국특허 제3,676,089호 미합중국특허 제3,649,229호, 미합중국특허 제4,247,301호, 대한민국특허 제1994-8390호 등에서는 폴리아민류 및 그 유도체들을 함유하는 조성물을 개시하고 있으나, 운전시 엔진 부품을 오염시키는 문제점이 있으며, 대한민국 공개특허 제2002-15162호에는 트리클로로에탄, 메틸렌클로라이드를 포함하는 조성물을 자동차 윤활유와 혼합한 내연기관용 세정제 조성물이 공지되어 있으나, 상기의 세정제 조성물만으로는 세정 시 오염물의 표면만을 세정하고 두텁게 축적된 오염물들의 효과적인 세정이 이루어지지 않는 단점이 있다.As a cleaning agent added to the fuel, U.S. Patent No. 3,676,089, U.S. Patent No. 3,649,229, U.S. Patent No. 4,247,301, and Korean Patent No.1994-8390 disclose compositions containing polyamines and derivatives thereof. There is a problem of contaminating an engine part, Korean Patent Laid-Open Publication No. 2002-15162 discloses a cleaning composition for an internal combustion engine in which a composition containing trichloroethane and methylene chloride is mixed with an automobile lubricating oil. There is a disadvantage in that only the surface of the contaminant is cleaned and effective cleaning of thick accumulated contaminants is not achieved.
본 발명은 상기한 종래 기술의 문제점을 해결하기 위하여 엔진의 장기 사용시 발생하는 투터운 오염 축적물들에 대한 세정효과가 우수하며, 그 세정 효과가 오래 지속될 수 있는 엔진 세정윤활제 조성물을 제공하는데 그 목적이 있다.The present invention is to provide an engine cleaning lubricant composition which is excellent in the cleaning effect against the dirt accumulation accumulated in the long-term use of the engine in order to solve the problems of the prior art, the cleaning effect can be long lasting. have.
특히, 본 발명은 카본을 효율적으로 제거할 수 있으며, 환경 유해물질을 포함하지 않아 친환경적인 엔진 세정윤활제 조성물을 제공하는데 그 목적이 있다.In particular, it is an object of the present invention to efficiently remove carbon, and does not include environmentally harmful substances to provide an environment-friendly engine cleaning lubricant composition.
본 발명은 내연기관용 오일, 자일렌(C6H4(CH3)2), 산화방지제, 청정분산제, 방청제, 극압제, 실리콘계 소포제, 점도지수향상제, 유동성 강하제, 합성오일을 포함하는 엔진 세정윤활제 조성물에 관한 것이다.The present invention is an engine cleaning lubricant comprising oil for internal combustion engine, xylene (C 6 H 4 (CH 3 ) 2 ), antioxidant, clean dispersant, rust preventive agent, extreme pressure agent, silicone antifoaming agent, viscosity index improver, fluid depressant, synthetic oil It relates to a composition.
보다 구체적으로 본 발명은 내연기관용 오일 20 내지 60중량%, 자일렌(C6H4(CH3)2) 5 내지 15 중량%, 산화방지제로 디부틸하이드록시톨루엔 5 ~ 10 중량%, 청정분산제로 벤질아민 5 ~ 15 중량%, 방청제로 술폰산염 10 ~ 15 중량%, 극압제로 트리크레질 포스페이트 또는 황화 테르펜 5 ~ 10 중량%, 실리콘계 소포제 1 ~ 8 중량%, 점도지수향상제로 에틸렌-프로필렌 공중합체 5 ~ 10 중량%, 유동성 강하제로 폴리알킬(메타)아크릴레이트 1 ~ 5 중량%, 합성오일로 디메틸폴리실록산 1 ~ 5 중량%을 포함하는 엔진 세정윤활제 조성물에 관한 것이다.More specifically, the present invention is 20 to 60% by weight of oil for internal combustion engines, 5 to 15% by weight of xylene (C 6 H 4 (CH 3 ) 2 ), 5 to 10% by weight of dibutylhydroxytoluene as an antioxidant, clean dispersant 5-15% by weight of rhobenzylamine, 10-15% by weight of sulfonate as rust inhibitor, 5-10% by weight of tricresyl phosphate or sulfide terpene as extreme pressure agent, 1-8% by weight of silicone antifoaming agent, ethylene-propylene as viscosity index improver It relates to an engine cleaning lubricant composition comprising 5 to 10% by weight of copolymer, 1 to 5% by weight of polyalkyl (meth) acrylate as fluid depressant, and 1 to 5% by weight of dimethylpolysiloxane as synthetic oil.
본 발명은 필요에 따라 탄소나노입자, 중량평균분자량이 1×106 ~ 5×106인 초고분자량폴리에틸렌 분말 또는 이들의 혼합물을 0.1 ~ 2 중량% 더 포함할 수 있다. The present invention may further include 0.1 to 2% by weight of carbon nanoparticles, ultra high molecular weight polyethylene powder having a weight average molecular weight of 1 × 10 6 to 5 × 10 6 , or a mixture thereof.
또한, 필요에 따라 안료, 향료 또는 이들의 혼합물을 0.1 내지 2 중량% 더 포함할 수 있다.In addition, if necessary, it may further comprise 0.1 to 2% by weight of pigments, perfumes or mixtures thereof.
이하는 본 발명의 각 구성에 대하여 보다 구체적으로 설명한다.Hereinafter, each configuration of the present invention will be described in more detail.
본 발명에서 상기 내연기관용 오일은 기계류의 원활한 작동을 유지시키는 작용을 하며, 통상의 내연기관용 오일이면 모두 가능하나 7.5W/30, 육상 3종 특 10/30 정도가 바람직하다. 그 함량은 20 내지 60중량%를 사용하는 것이 바람직하며, 20 중량%미만으로 사용하는 경우는 윤활제로 사용하기에 적합하지 않으며, 60 중량%를 초과하는 경우는 다른 첨가제들의 사용함량이 감소하여 목적으로 하는 오염물질(카본, 슬럿지 등)의 세정효과가 감소될 수 있다.In the present invention, the oil for the internal combustion engine serves to maintain the smooth operation of the machinery, all of the usual internal combustion engine oil is possible, but 7.5W / 30, three kinds of special land 10/30 is preferred. It is preferable to use the content of 20 to 60% by weight. If the content is less than 20% by weight, it is not suitable for use as a lubricant, and when it exceeds 60% by weight, the use amount of other additives is reduced. The cleaning effect of pollutants (carbon, sludge, etc.) can be reduced.
본 발명에서 상기 자일렌(xylene)은 금속표면에 생성 고착된 슬럿지 등의 오염물질 등을 분해 제거하는 작용을 한다. 본 발명자는 오염물질의 효율적인 제거 및 환경 유해물질을 포함하지 않는 조성물을 개발하기 위하여 연구하는 과정에서 자일렌이 환경규제물질이 아니며, 다른 방향족탄화수소 물질들에 비하여 오염물질의 제거 효율이 좋으며, 특히, 특정 함량범위로 사용하는 경우 오염물질의 제거 효율이 매우 향상됨을 발견하여 본 발명을 완성한 것이다. 본 발명에서 상기 자일렌은 5 내지 15 중량%로 사용하는데 특징이 있다. 상기 자일렌의 함량이 5 중량% 미만으로 사용되는 경우는 오염물질의 제거효율이 미미하며, 5중량% 이상 15중량% 사용시 오염물질 제거 효율이 매우 우수하다.In the present invention, the xylene (xylene) serves to decompose and remove contaminants such as sludge produced and fixed on the metal surface. The inventors of the present invention in the process of research for the efficient removal of contaminants and development of a composition that does not contain environmental harmful substances, xylene is not an environmental regulatory substance, the removal efficiency of contaminants is better than other aromatic hydrocarbon materials, especially In the case of using a specific content range, it has been found that the removal efficiency of the contaminant is greatly improved, thereby completing the present invention. In the present invention, the xylene is characterized by using 5 to 15% by weight. When the content of xylene is used less than 5% by weight, the removal efficiency of the pollutants is insignificant, and when using 5% by weight or more and 15% by weight, the removal efficiency of the pollutants is very excellent.
본 발명에서 상기 산화방지제(antioxidants)는 윤활유의 산화속도를 지연시켜 장기간 사용이 가능하도록 하는 작용을 하는 구성성분으로서, 본 발명에서는 디부틸하이드록시톨루엔을 사용하는 경우 다른 성분들과 함께 더욱 향상된 효과를 발현한다. 그 함량은 5 ~ 10 중량%를 사용하는 범위에서 가장 우수한 효과를 발현한다.In the present invention, the antioxidants (antioxidants) as a component that acts to enable long-term use by delaying the oxidation rate of the lubricating oil, in the present invention, when dibutyl hydroxytoluene is used, further improved effect with other components Expresses. The content expresses the best effect in the range using 5 to 10% by weight.
본 발명에서 상기 청정분산제(dispersant)는 계면활성 작용으로 인하여 오일에 들어있는 불용성 물질을 분산시켜 엔진 내부에 슬럿지 등 오염물질의 응집을 막아주며, 산성 물질을 중화시키는 작용을 하며, 통상의 계면활성제는 가능하나, 본 발명의 조성에는 벤질아민을 사용하는 것이 바람직하며, 특히 5 ~ 15 중량%로 사용하는 경우 오염제거 및 방지 효과가 매우 우수하다.In the present invention, the dispersant disperses insoluble substances in oil due to the surfactant activity, thereby preventing aggregation of contaminants such as sludge in the engine, neutralizing acidic substances, and common surfactants. Although be possible, it is preferable to use benzylamine in the composition of the present invention, especially when used in 5 to 15% by weight is very excellent decontamination and prevention effect.
본 발명에서 상기 방청제(anti-rust additives)는 엔진내부에 수분으로 인하여 발생하는 녹 등의 생성을 방지하는 작용을 하며, 술폰산염, 카르복실산염 또는 메탄올 등이 사용될 수 있으나, 본 발명의 조성에는 술폰산염을 사용하는 것이 바람직하며, 이러한 술폰산염으로는 구체적으로 예를 들면, 암모늄설포네이트, 바륨설포네이트 등을 사용할 수 있다. 그 함량범위는 10 ~ 15 중량%로 사용하는 경우 부식방지및 오염제거 효율이 매우 우수하다.In the present invention, the anti-rust additives (anti-rust additives) serves to prevent the formation of rust generated due to moisture in the engine, and sulfonate, carboxylate or methanol may be used, but the composition of the present invention It is preferable to use a sulfonate salt, and specific examples of such sulfonate salts include ammonium sulfonate, barium sulfonate, and the like. The content range is 10 to 15% by weight when used in corrosion prevention and decontamination efficiency is very good.
본 발명에서 상기 극압제(extreme press additives)는 금속끼리의 접촉이 일어날 때 국부적 융착에 의한 발열로 금속면과 반응하여 금속무기 화합물의 피막을 빠른 속도로 형성하여 극한 마모를 방지하는 작용을 한다. 본 발명의 조성에는 트리크레질 포스페이트 또는 황화 테르펜을 사용하는 것이 바람직하다. 그 함량은 5 ~ 10 중량%로 사용하는 경우 금속표면의 극한 마모방지 효율이 매우 우수하다.In the present invention, the extreme press additives react with the metal surface by heat generation due to local fusion when metal contacts occur to form a film of the metal inorganic compound at a high speed to prevent extreme wear. It is preferable to use tricresil phosphate or sulfide terpene in the composition of the present invention. The content is 5 to 10% by weight when used in the extreme wear protection efficiency of the metal surface is very excellent.
본 발명에서 실리콘계 소포제(antifoam agents)는 윤활유 기포현상을 완화시키거나 없애주는 작용을 하기 위하여 사용되는 것으로, 본 발명의 조성에는 실리콘 오일이 바람직하며, 특히 콘점도(25℃) 250 ~ 2500mPas인 시메티콘(Simethicone)을 사용하는 것이 바람직하다. 시메티콘은 (-(CH3)2-SiO-)의 트리메틸실록시 말단 보호 단위로 안정화시킨 (-(CH2)2-SiO-)n의 반복 단위를 함유하는 선형 실록산 중합체로 이루어진 디메티콘 화합물과 이산화규소의 혼합물을 의미한다. 그 함량은 1 ~ 8 중량%로 사용하는 경우 오염제거 효율이 매우 우수하다.In the present invention, silicone antifoam agents are used to alleviate or eliminate lubricating oil bubbles. In the composition of the present invention, silicone oil is preferable, and in particular, a silicone viscosity of 250 to 2500 mPas (25 ° C) is used. Preference is given to using Simethicone. Simethicone is (- (CH 3) 2 -SiO- ) stabilized with trimethylsiloxy end protected units (- (CH 2) 2 -SiO- ) dimethicone compounds consisting of linear siloxane polymers containing repeating units of the n It means a mixture of and silicon dioxide. The content is very good decontamination efficiency when used in 1 to 8% by weight.
본 발명에서 상기 점도지수 향상제(viscosity index improvers)는 윤활유의 점도 특성을 개선하는 작용을 위하여 사용되는 것으로, 윤활유를 비롯한 유기물질은 온도변화에 민감하게 변화하는데, 저온에서는 점성이 커지고 고온에서는 매우 점성이 작아진다. 저온에서는 기계류의 시동성이 좋지 않고 고온에서는 윤활 피막이 약해져 마모현상이 쉽게 일어난다. 이러한 점도 특성을 개선하기 위한 점도지수 향상제로는 에틸렌-프로필렌 공중합체가 바람직하다. 구체적으로 중량평균분자량이 5000 ~ 50000인 에틸렌-프로필렌 공중합체를 사용하는 것이 바람직하다. 그 함량은 5 ~ 10 중량%로 사용하는 경우 윤활점도 안정성이 매우 우수하다.In the present invention, the viscosity index improvers (viscosity index improvers) is used to improve the viscosity characteristics of the lubricating oil, the organic material including the lubricating oil is sensitive to changes in temperature, the viscosity is increased at low temperatures and very viscous at high temperatures Becomes smaller. At low temperatures, the startability of the machinery is poor, and at high temperatures, the lubricating film is weak, and wear is easily caused. As a viscosity index improver for improving such a viscosity characteristic, an ethylene-propylene copolymer is preferable. Specifically, it is preferable to use an ethylene-propylene copolymer having a weight average molecular weight of 5000 to 50000. When the content is used in 5 to 10% by weight, the lubricating viscosity stability is very excellent.
본 발명에서 상기 유동성 강하제(pour point depressants)는 유동점을 낮추기 위하여 사용하는 것으로, 윤활유의 주성분이 각종의 탄화수소 혼합물이므로 윤활유 냉각 시 0℃ 부근에서 함유된 수분이 얼면서 윤활유에 포함된 유동성이 높은 물질들이 표출되어 윤활유를 변질시키는 결과를 초래한다. 이른바 구조점성 현상이 나타나게 되는데 이 경우 유동성 강하제(pour point depressants)를 첨가하면 유동점이 낮아지게 하는 작용을 한다. 본 발명에서는 유동성 강하제로는 폴리알킬(메타)아크릴레이트를 사용하는 것이 바람직하다. 이때 상기 알킬은 (C1-C10)의 알킬을 사용할 수 있으며, 이 중 메틸, 에틸이 바람직하다. 상기 폴리알킬(메타)아크릴레이트의 중량평균분자량은 5000 ~ 15000인 것을 사용하는 것이 바람직하다. 그 함량은 1 ~ 5 중량%를 사용하는 것이 구조점성 현상을 막아주는 효율이 매우 우수하다.In the present invention, the pour point depressants are used to lower the pour point. Since the main components of the lubricating oil are various hydrocarbon mixtures, the fluid contained in the lubricating oil is high while the water contained in the lubricating oil is frozen. Are expressed, resulting in the deterioration of the lubricant. The so-called structural viscosity phenomenon appears, in which case the addition of pour point depressants acts to lower the pour point. In the present invention, it is preferable to use polyalkyl (meth) acrylate as the fluid lowering agent. In this case, the alkyl may be an alkyl of (C1-C10), of which methyl and ethyl are preferred. It is preferable to use the weight average molecular weights of the said polyalkyl (meth) acrylate that are 5000-15000. The content of 1 to 5% by weight is very effective in preventing structural viscosity.
본 발명에서 상기 합성오일은 본 발명의 조성성분들의 혼합을 향상시키고, 보관안정성을 향상시키기 위하여 사용하는 것으로, 구체적으로는 디메틸폴리실록산을 사용하는 것이 바람직하다. 그 함량은 1 ~ 5 중량%를 사용하는 것이 오염제거및 오염방지 효율이 매우 우수하다.In the present invention, the synthetic oil is used to improve the mixing of the components of the present invention and to improve the storage stability, specifically, it is preferable to use dimethylpolysiloxane. The content of 1 to 5% by weight is very effective in decontamination and antifouling.
본 발명에 따른 엔진 세정윤활제는 필요에 따라 탄소나노입자, 중량평균분자량이 1×106 ~ 5×106인 초고분자량폴리에틸렌 분말 또는 이들의 혼합물을 0.1 ~ 2 중량% 더 포함할 수 있다. 상기 초고분자량폴리에틸렌 분말은 내마모성이 뛰어나고 기계적 강도가 우수한 물질로, 오염물질의 제거효율을 더욱 향상시킬 수 있다. 상기 탄소나노입자는 엔진의 실린더 펌프의 마찰계수를 감소시키고, 오염물질의 제거효율을 더욱 향상시키기 위하여 사용되는 것으로, 평균입경이 10 ~ 100nm인 것을 사용하는 것이 바람직하며, 형태는 제한이 없다. 상기 탄소나노입자 또는 중량평균분자량이 1×106 ~ 5×106인 초고분자량폴리에틸렌 분말은 0.1 ~ 2 중량% 범위에서 경제적이면서 효과적으로 사용할 수 있다.The engine cleaning lubricant according to the present invention may further include 0.1 to 2% by weight of carbon nanoparticles, ultra high molecular weight polyethylene powder having a weight average molecular weight of 1 × 10 6 to 5 × 10 6 , or a mixture thereof, as necessary. The ultra high molecular weight polyethylene powder is a material having excellent wear resistance and excellent mechanical strength, and can further improve the removal efficiency of contaminants. The carbon nanoparticles are used to reduce the friction coefficient of the cylinder pump of the engine and to further improve the removal efficiency of contaminants. It is preferable to use those having an average particle diameter of 10 to 100 nm, and the shape is not limited. The ultra high molecular weight polyethylene powder having the carbon nanoparticles or the weight average molecular weight of 1 × 10 6 to 5 × 10 6 can be economically and effectively used in the range of 0.1 to 2% by weight.
또한, 본 발명에 따른 엔진 세정윤활제는 필요에 따라 안료, 향료 또는 이들의 혼합물을 0.1 내지 2 중량% 더 포함할 수 있다. In addition, the engine cleaning lubricant according to the present invention may further comprise 0.1 to 2% by weight of pigments, perfumes or mixtures thereof as necessary.
본 발명에 따른 내연기관 세정윤활제는 기존의 엔진오일량에 따른 본 조성물질을 3%~5%를 엔진오일에 첨가한 후 일정기간 주행(100km~300km) 또는 아이들 상태로 공회전(60분~180분) 시킨 후 오일을 교환하는 방법으로 사용한다. The internal combustion engine cleaning lubricant according to the present invention adds 3% to 5% of the present composition according to the amount of the existing engine oil to the engine oil, and then idles for a predetermined period of time (100 km to 300 km) or idle (60 minutes to 180 minutes). Min) and use it to replace oil.
다음으로 본 발명의 엔진 세정윤활제를 제조하는 방법에 대하여 구체적으로 설명한다.Next, the method of manufacturing the engine cleaning lubricant of the present invention will be described in detail.
본 발명의 엔진 세정윤활용 조성물은 투입순서 및 투입온도에 특징이 있으며, 혼합온도가 하기 범위를 벗어나는 경우는 조성이 혼합되지 않고 층 분리가 일어날 수 있으며, 분산성 및 보관안정성이 저하될 수 있다.The engine cleaning lubricating composition of the present invention is characterized by the order of loading and the input temperature, and when the mixing temperature is outside the following range, the composition may not be mixed and layer separation may occur, and dispersibility and storage stability may be reduced. .
본 발명의 엔진 세정윤활제를 제조하는 방법은The method for producing the engine cleaning lubricant of the present invention
a) 반응기에 산화방지제로 디부틸하이드록시톨루엔을 넣고, 50 ~ 70 ℃로 가열한 후, 방청제로 술폰산염을 첨가하여 혼합하는 단계;a) dibutyl hydroxytoluene as an antioxidant in the reactor, heated to 50 ~ 70 ℃, and then added by adding a sulfonate salt as a rust inhibitor;
b) a)단계의 혼합물을 80 ~ 85℃로 가열한 후, 합성오일로 디메틸폴리실록산을 첨가하여 혼합하는 단계;b) heating the mixture of step a) to 80-85 ° C. and then adding and mixing dimethylpolysiloxane with synthetic oil;
c) 상기 b)단계의 혼합물을 0 ~ 10℃로 냉각시킨 후, 자일렌을 첨가하여 10000 ~ 30000rpm으로 고속 회전하여 믹싱하는 단계;c) after cooling the mixture of step b) to 0 ~ 10 ℃, mixing by rotating at high speed to 10000 ~ 30000rpm by adding xylene;
d) 상기 c)단계의 혼합물을 65 ~ 75℃로 가열한 후, 극압제로 트리크레질 포스페이트를 첨가하여 혼합하는 단계;d) heating the mixture of step c) to 65-75 ° C. and then adding and mixing tricresil phosphate with extreme pressure agent;
e) 상기 d)단계의 혼합물의 온도를 40 ~ 45℃로 낮추고, 내연기관용 오일을 첨가하여 혼합하는 단계;e) lowering the temperature of the mixture of step d) to 40-45 ° C., adding and mixing oil for an internal combustion engine;
f) 상기 e)단계의 혼합물에 청정분산제인 벤질아민, 실리콘계 소포제, 점도지수향상제로 에틸렌-프로필렌 공중합체, 유동성 강하제로 폴리메틸메타크릴레이트를 첨가하여 혼합하는 단계;f) mixing the mixture of step e) by adding benzylamine as a clean dispersant, a silicone-based antifoaming agent, an ethylene-propylene copolymer as a viscosity index improver, and polymethyl methacrylate as a fluidity lowering agent;
를 포함한다.It includes.
본 발명은 필요에 따라 상기 f)단계에서 탄소나노입자, 중량평균분자량이 1×106 ~ 5×106인 초고분자량폴리에틸렌 분말 또는 이들의 혼합물을 첨가할 수 있다.According to the present invention, carbon nanoparticles, a weight average molecular weight of 1 × 10 6 to 5 × 10 6 in step f) may be added to the ultra-high molecular weight polyethylene powder or a mixture thereof as necessary.
본 발명은 필요에 따라 상기 d)단계에서 안료, 향료 또는 이들의 혼합물을 첨가할 수 있다.The present invention may add a pigment, a fragrance or a mixture thereof in step d) as necessary.
본 발명에 따른 엔진 세정윤활제는 엔진 내부에 생성되어 고착되어 있는 각종 불순물, 카본, 슬럿지, 검 등을 분해, 세정시키고 고강도의 최저 마찰의 표면을 형성하며, 접착면의 밀착도를 높여 엔진의 성능을 정상화 시켜 엔진의 성능을 정상화시켜 연비의 개선으로 인한 에너지의 효율적인 사용과 환경물질의 배출 감소로 인한 환경보호의 효과가 있다.The engine cleaning lubricant according to the present invention decomposes and cleans various impurities, carbon, sludge, gum, etc., which are generated and stuck inside the engine, to form a high-strength, low-friction surface, and improve adhesion of the adhesion surface by improving the performance of the engine. By normalizing the performance of the engine to normalize it has the effect of efficient use of energy due to improved fuel economy and environmental protection by reducing the emission of environmental substances.
이하는 본 발명의 구체적인 설명을 위하여 일예를 들어 설명하는 바, 본 발명이 하기 실시예에 한정되는 것은 아니다.Hereinafter, the present invention will be described by way of example for specific description of the present invention, but the present invention is not limited to the following examples.
이하 물성은 다음의 측정방법으로 측정하였다.The physical properties were measured by the following measurement method.
1) 비중1) Specific gravity
비중시험은 KS M 2002에 따라 실험하였다.Specific gravity test was conducted according to KS M 2002.
2) 동점도2) kinematic viscosity
동점도 시험은 KS M 2014에 따라 실험하였다.Kinematic viscosity test was conducted according to KS M 2014.
3) 동판부식3) Copper plate corrosion
동판부식 시험은 KS M 2018에 따라 실험하였다.Copper plate corrosion test was conducted according to KS M 2018.
4) 유동점4) Pour point
유동점 시험은 KS M 2016에 따라 실험하였다.Pour point test was conducted according to KS M 2016.
5) 산화안정도5) Oxidation Stability
산화안정도 시험은 KS M 2008에 따라 실험하였다.Oxidation stability test was conducted according to KS M 2008.
6) 방청성능시험6) Antirust performance test
방청성능 시험은 KS M 2009에 따라 실험하였다.Antirust performance test was conducted according to KS M 2009.
7) 내하중성능시험7) Load capacity test
내하중성능 시험은 KS M 2026에 따라 실험하였다.Load capacity test was conducted according to KS M 2026.
8) 엔진 내부 세정성 및 배출가스 제거율(%)8) Cleanliness of engine and emission rate (%)
- 준비물 : 시험용 중고 자동차(배기량 2000cc, 주행거리 14,523 km)-Things to prepare: used cars for test (exhaust volume 2000cc, mileage 14,523 km)
- 성능시험 : -Performance test:
본 발명에 따른 엔진 세정제의 엔진 세정력 평가를 위하여, 배기량 2000cc, 주행거리 14,523 km인 승용차를 이용하여 세정전과 세정후의 엔진 배기가스의 일산화탄소, 이산화탄소, 탄화수소의 농도를 측정하여 제거율(%)을 측정하였다.In order to evaluate the engine cleaning power of the engine cleaner according to the present invention, the removal rate (%) was measured by measuring the concentrations of carbon monoxide, carbon dioxide, and hydrocarbon in the engine exhaust gas before and after cleaning using a passenger car having an exhaust volume of 2000 cc and a driving distance of 14,523 km. .
세정 전 통상의 자동차 운전조건(주행속도 50 ~ 60Km(기어 2~3단)으로 1시간 운행하고 이후부터는 4단 운행함)에서 300 km를 주행하였다. 주행 후 엔진의 뚜껑을 열고, 엔진의 초기 상태를 육안으로 관찰하였으며, 엔진배기가스의 일산화탄소, 이산화탄소, 탄화수소의 농도 및 공기 과잉률을 측정하였다.The car was driven 300 km in normal driving conditions (driving speed 50 ~ 60km (2 ~ 3 gears) for 1 hour and 4 steps after that). After running, the lid of the engine was opened, and the initial state of the engine was visually observed. The concentrations of carbon monoxide, carbon dioxide, and hydrocarbons and the excess air ratio of the engine exhaust gas were measured.
이후, 엔진오일과 함께 실시예 및 비교예의 엔진 세정액 80 ml를 엔진에 직접 첨가한 후, 세정 전과 동일한 운전조건에서 300 km를 주행하여 세정 후 일산화탄소, 이산화탄소, 탄화수소 농도 및 공기 과잉률을 측정하였다. 또한 머플러 및 엔진내부의 상태를 육안으로 관찰하였다. Thereafter, 80 ml of the engine cleaning solution of the Examples and Comparative Examples were directly added to the engine together with the engine oil, and then 300 km was driven under the same operating conditions as before the cleaning, and the carbon monoxide, carbon dioxide, hydrocarbon concentration, and excess air ratio were measured after the cleaning. In addition, the state of the muffler and the engine inside were visually observed.
세정전과 세정후의 공기과잉률(λ:ben)은 1.00±0.02의 편차로 유지하였고, 하기 식 1 ~ 식 3에 따른 제거율을 계산하여 표 3에 나타내었다. The excess air ratio (λ: ben) before and after washing was maintained at a deviation of 1.00 ± 0.02, and the removal rate according to the following Equations 1 to 3 was calculated and shown in Table 3.
[식 1] [Equation 1]
일산화탄소 제거율(%)= (세정 전 일산화탄소의 농도 - 세정 후 일산화탄소의 농도)/세정 전 일산화탄소의 농도 × 100Carbon monoxide removal rate (%) = (concentration of carbon monoxide before washing-concentration of carbon monoxide after washing) / concentration of carbon monoxide before washing × 100
[식 2][Equation 2]
이산화탄소 제거율(%)= (세정 전 이산화탄소의 농도 - 세정 후 이산화탄소의 농도)/세정 전 이산화탄소의 농도 × 100% Removal of carbon dioxide = (concentration of carbon dioxide before washing-concentration of carbon dioxide after washing) / concentration of carbon dioxide before washing × 100
[식 3][Equation 3]
탄화수소 제거율(%)= (세정 전 탄화수소의 농도 - 세정 후 탄화수소의 농도)/세정 전 탄화수소의 농도 × 100% Hydrocarbon removal rate = (the concentration of hydrocarbon before washing-the concentration of hydrocarbon after washing) / the concentration of hydrocarbon before washing × 100
[실시예 1 ~ 3][Examples 1 to 3]
엔진 세정제 조성물의 제조Preparation of Engine Cleanser Composition
반응기에 산화방지제로 디부틸하이드록시톨루엔 8 중량%를 넣고, 60℃로 가열한 후, 방청제로 술폰산염(암모늄설포네이트)을 12 중량% 첨가하여 혼합하였다. 80℃로 가열 후 합성오일로 디메틸폴리실록산(shinetsu사, KF-96)을 4 중량% 첨가하여 혼합하였다. 상기 혼합물을 0℃로 냉각시킨 후, 자일렌을 5 중량% 첨가하여 20000rpm으로 고속 회전하여 믹싱 하였다. 다시 70℃로 가열한 후, 극압제로 트리크레질 포스페이트를 8 중량% 첨가하여 혼합하였다. 상기 혼합물에 안료(프탈로시아닌블루) 0.5 중량%와 향료(아카시아 유화향료) 0.5 중량%를 첨가한 후, 온도를 40℃로 낮추고, 내연기관용 오일(GS Caltex Deluxe Gold V 7.5W/30, Hyundai gear oil 85W/140)을 35 중량% 첨가하여 혼합하였다. 상기 혼합물에 청정분산제인 벤질아민 10 중량%, 실리콘계 소포제(shinetsu사, KS-66, 점도(25℃) 300mPas인 SIMETHICONE)를 5 중량%, 점도지수향상제로 에틸렌-프로필렌 공중합체(중량평균분자량 15,000) 8 중량%, 유동성 강하제로 폴리메틸메타크릴레이트(중량평균분자량 20,000) 4 중량%를 첨가하여 혼합하였다.8% by weight of dibutylhydroxytoluene was added to the reactor as an antioxidant, heated to 60 ° C, and 12% by weight of sulfonate (ammonium sulfonate) was added as a rust preventive and mixed. After heating to 80 ° C, 4% by weight of dimethylpolysiloxane (shinetsu, KF-96) was added and mixed with a synthetic oil. After the mixture was cooled to 0 ° C., 5% by weight of xylene was added, and the mixture was mixed at high speed by rotating at 20000 rpm. After heating to 70 DEG C, 8% by weight of tricresyl phosphate was added and mixed with an extreme pressure agent. After adding 0.5% by weight of pigment (phthalocyanine blue) and 0.5% by weight of fragrance (acacia emulsifying perfume) to the mixture, the temperature was lowered to 40 ° C., and the internal combustion engine oil (GS Caltex Deluxe Gold V 7.5W / 30, Hyundai gear oil) 85 W / 140) was added and mixed. Ethylene-propylene copolymer (weight average molecular weight 15,000) as 10% by weight of the benzylamine, a clean dispersant, 5% by weight of a silicone antifoaming agent (shinetsu, KS-66, SIMETHICONE with a viscosity of 300 mPas) and a viscosity index improver 8% by weight and 4% by weight of polymethyl methacrylate (weight average molecular weight 20,000) were added as a fluid lowering agent.
각 성분의 함량은 하기 표 1에 정리하였으며, 물성을 측정하여 하기 표 3에 나타내었다.The content of each component is summarized in Table 1 below, and measured and shown in Table 3 below.
[실시예 2 ~ 3][Examples 2 to 3]
상기 실시예 1에서 내연기관용 오일과 자일렌의 함량을 표 1과 같이 변화시킨 것을 제외하고는 동일한 방법으로 조성물을 제조하였다.Except for changing the content of the internal combustion engine oil and xylene in Example 1 as shown in Table 1 to prepare a composition in the same manner.
각 성분의 함량은 하기 표 1에 정리하였으며, 물성을 측정하여 하기 표 3에 나타내었다.The content of each component is summarized in Table 1 below, and measured and shown in Table 3 below.
[실시예 4]Example 4
반응기에 산화방지제로 디부틸하이드록시톨루엔 8 중량%를 넣고, 60℃로 가열한 후, 방청제로 술폰산염(암모늄설포네이트)을 12 중량% 첨가하여 혼합하였다. 80℃로 가열 후 합성오일로 디메틸폴리실록산(shinetsu사, KF-96)을 4 중량% 첨가하여 혼합하였다. 상기 혼합물을 0℃로 냉각시킨 후, 자일렌을 10 중량% 첨가하여 20000rpm으로 고속 회전하여 믹싱 하였다. 다시 70℃로 가열한 후, 극압제로 트리크레질 포스페이트를 8 중량% 첨가하여 혼합하였다. 상기 혼합물에 향료(아카시아 유화향료) 0.5 중량%를 첨가한 후, 온도를 40℃로 낮추고, 내연기관용 오일(GS Caltex Deluxe Gold V 7.5W/30, Hyundai gear oil 85W/140)을 30 중량% 첨가하여 혼합하였다. 상기 혼합물에 청정분산제인 벤질아민 10 중량%, 실리콘계 소포제(shinetsu사, KS-66, 점도(25℃) 300mPas인 SIMETHICONE)를 5 중량%, 점도지수향상제로 에틸렌-프로필렌 공중합체(중량평균분자량 15,000) 8 중량%, 유동성 강하제로 폴리메틸메타크릴레이트(중량평균분자량 20,000) 4 중량%, 탄소나노입자(평균입경 50nm)를 0.5 중량%를 첨가하여 혼합하였다.8% by weight of dibutylhydroxytoluene was added to the reactor as an antioxidant, heated to 60 ° C, and 12% by weight of sulfonate (ammonium sulfonate) was added as a rust preventive and mixed. After heating to 80 ° C, 4% by weight of dimethylpolysiloxane (shinetsu, KF-96) was added and mixed with a synthetic oil. After the mixture was cooled to 0 ° C., 10% by weight of xylene was added, and the mixture was mixed at high speed by rotating at 20000 rpm. After heating to 70 DEG C, 8% by weight of tricresyl phosphate was added and mixed with an extreme pressure agent. After adding 0.5% by weight of fragrance (acacia emulsifying perfume) to the mixture, the temperature was lowered to 40 ° C, and 30% by weight of oil for internal combustion engines (GS Caltex Deluxe Gold V 7.5W / 30, Hyundai gear oil 85W / 140) was added. And mixed. Ethylene-propylene copolymer (weight average molecular weight 15,000) as 10% by weight of the benzylamine, a clean dispersant, 5% by weight of a silicone antifoaming agent (shinetsu, KS-66, SIMETHICONE with a viscosity of 300 mPas) and a viscosity index improver 8% by weight, 4% by weight of polymethyl methacrylate (weight average molecular weight 20,000) and 0.5% by weight of carbon nanoparticles (average particle diameter: 50 nm) were added as a fluid lowering agent.
각 성분의 함량은 하기 표 1에 정리하였으며, 물성을 측정하여 하기 표 3에 나타내었다.The content of each component is summarized in Table 1 below, and measured and shown in Table 3 below.
[실시예 5]Example 5
반응기에 산화방지제로 디부틸하이드록시톨루엔 8 중량%를 넣고, 60℃로 가열한 후, 방청제로 술폰산염(암모늄설포네이트)을 12 중량% 첨가하여 혼합하였다. 80℃로 가열 후 합성오일로 디메틸폴리실록산(shinetsu사, KF-96)을 4 중량% 첨가하여 혼합하였다. 상기 혼합물을 0℃로 냉각시킨 후, 자일렌을 10 중량% 첨가하여 20000rpm으로 고속 회전하여 믹싱 하였다. 다시 70℃로 가열한 후, 극압제로 트리크레질 포스페이트를 8 중량% 첨가하여 혼합하였다. 상기 혼합물에 향료(아카시아 유화향료) 0.5 중량%를 첨가한 후, 온도를 40℃로 낮추고, 내연기관용 오일(GS Caltex Deluxe Gold V 7.5W/30, Hyundai gear oil 85W/140)을 30 중량% 첨가하여 혼합하였다. 상기 혼합물에 청정분산제인 벤질아민 10 중량%, 실리콘계 소포제(shinetsu사, KS-66, 점도(25℃) 300mPas인 SIMETHICONE)를 5 중량%, 점도지수향상제로 에틸렌-프로필렌 공중합체(중량평균분자량 15,000) 8 중량%, 유동성 강하제로 폴리메틸메타크릴레이트(중량평균분자량 20,000) 4 중량%, 중량평균분자량이 3.8×106인 초고분자량폴리에틸렌 분말(Ticona GmbH사, Hostalen GUR 4113)을 0.5 중량%를 첨가하여 혼합하였다.8% by weight of dibutylhydroxytoluene was added to the reactor as an antioxidant, heated to 60 ° C, and 12% by weight of sulfonate (ammonium sulfonate) was added as a rust preventive and mixed. After heating to 80 ° C, 4% by weight of dimethylpolysiloxane (shinetsu, KF-96) was added and mixed with a synthetic oil. After the mixture was cooled to 0 ° C., 10% by weight of xylene was added, and the mixture was mixed at high speed by rotating at 20000 rpm. After heating to 70 DEG C, 8% by weight of tricresyl phosphate was added and mixed with an extreme pressure agent. After adding 0.5% by weight of fragrance (acacia emulsifying perfume) to the mixture, the temperature was lowered to 40 ° C, and 30% by weight of oil for internal combustion engines (GS Caltex Deluxe Gold V 7.5W / 30, Hyundai gear oil 85W / 140) was added. And mixed. Ethylene-propylene copolymer (weight average molecular weight 15,000) as 10% by weight of the benzylamine, a clean dispersant, 5% by weight of a silicone antifoaming agent (shinetsu, KS-66, SIMETHICONE with a viscosity of 300 mPas) and a viscosity index improver ) 8% by weight, Ultra High Molecular Weight Polyethylene Powder (Ticona GmbH, Hostalen GUR 4113) with 0.5% by weight of polymethyl methacrylate (weight average molecular weight 20,000), weight average molecular weight 3.8 × 10 6 Add and mix.
각 성분의 함량은 하기 표 1에 정리하였으며, 물성을 측정하여 하기 표 3에 나타내었다.The content of each component is summarized in Table 1 below, and measured and shown in Table 3 below.
[실시예 6]Example 6
반응기에 산화방지제로 디부틸하이드록시톨루엔 8 중량%를 넣고, 60℃로 가열한 후, 방청제로 술폰산염(암모늄설포네이트)을 12 중량% 첨가하여 혼합하였다. 80℃로 가열 후 합성오일로 디메틸폴리실록산(shinetsu사, KF-96)을 4 중량% 첨가하여 혼합하였다. 상기 혼합물을 0℃로 냉각시킨 후, 자일렌을 10 중량% 첨가하여 20000rpm으로 고속 회전하여 믹싱 하였다. 다시 70℃로 가열한 후, 극압제로 트리크레질 포스페이트를 8 중량% 첨가하여 혼합하였다. 상기 혼합물에 향료 0.5 중량%를 첨가한 후, 온도를 40℃로 낮추고, 내연기관용 오일(GS Caltex Deluxe Gold V 7.5W/30, Hyundai gear oil 85W/140)을 30 중량% 첨가하여 혼합하였다. 상기 혼합물에 청정분산제인 벤질아민 10 중량%, 실리콘계 소포제(shinetsu사, KS-66, 점도(25℃) 300mPas인 SIMETHICONE)를 5 중량%, 점도지수향상제로 에틸렌-프로필렌 공중합체(중량평균분자량 15,000) 8 중량%, 유동성 강하제로 폴리메틸메타크릴레이트(중량평균분자량 20,000) 4 중량%, 탄소나노입자(평균입경 50nm)를 0.3 중량%, 중량평균분자량이 3.8×106인 초고분자량폴리에틸렌 분말(Ticona GmbH사, Hostalen GUR 4113)을 0.2 중량%를 첨가하여 혼합하였다.8% by weight of dibutylhydroxytoluene was added to the reactor as an antioxidant, heated to 60 ° C, and 12% by weight of sulfonate (ammonium sulfonate) was added as a rust preventive and mixed. After heating to 80 ° C, 4% by weight of dimethylpolysiloxane (shinetsu, KF-96) was added and mixed with a synthetic oil. After the mixture was cooled to 0 ° C., 10% by weight of xylene was added, and the mixture was mixed at high speed by rotating at 20000 rpm. After heating to 70 DEG C, 8% by weight of tricresyl phosphate was added and mixed with an extreme pressure agent. After adding 0.5% by weight of fragrance to the mixture, the temperature was lowered to 40 ° C, and 30% by weight of an internal combustion engine oil (GS Caltex Deluxe Gold V 7.5W / 30, Hyundai gear oil 85W / 140) was added and mixed. Ethylene-propylene copolymer (weight average molecular weight 15,000) as 10% by weight of the benzylamine, a clean dispersant, 5% by weight of a silicone antifoaming agent (shinetsu, KS-66, SIMETHICONE with a viscosity of 300 mPas) and a viscosity index improver 8% by weight, 4% by weight of polymethyl methacrylate (weight average molecular weight 20,000) as a fluid depressant, 0.3% by weight of carbon nanoparticles (average particle diameter 50nm), ultra-high molecular weight polyethylene powder having a weight average molecular weight of 3.8 × 10 6 ( 0.2 wt% of Ticona GmbH, Hostalen GUR 4113) was added and mixed.
각 성분의 함량은 하기 표 1에 정리하였으며, 물성을 측정하여 하기 표 3에 나타내었다.The content of each component is summarized in Table 1 below, and measured and shown in Table 3 below.
[표 1]TABLE 1
Figure PCTKR2011005336-appb-I000001
Figure PCTKR2011005336-appb-I000001
[비교예 1]Comparative Example 1
자일렌을 사용하지 않고 조성물을 제조한 것을 제외하고는 실시예와 동일한 방법으로 조성물을 제조하였다. 각 성분의 함량은 하기 표 2에 정리하였으며, 물성을 측정하여 하기 표 3에 나타내었다.The composition was prepared in the same manner as in Example, except that the composition was prepared without using xylene. The content of each component is summarized in Table 2 below, and measured and shown in Table 3 below.
[비교예 2]Comparative Example 2
상기 실시예 1에서 각 성분의 함량을 표 1과 같이 변화시킨 것을 제외하고는 동일한 방법으로 조성물을 제조하였다.Except for changing the content of each component in Example 1 as in Table 1 to prepare a composition in the same manner.
각 성분의 함량은 하기 표 2에 정리하였으며, 물성을 측정하여 하기 표 3에 나타내었다.The content of each component is summarized in Table 2 below, and measured and shown in Table 3 below.
[표 2]TABLE 2
Figure PCTKR2011005336-appb-I000002
Figure PCTKR2011005336-appb-I000002
[표 3]TABLE 3
Figure PCTKR2011005336-appb-I000003
Figure PCTKR2011005336-appb-I000003
상기의 표 1에서 보는 바와 같이 본 발명에 의한 세정윤활제 조성물을 사용하여 엔진을 세정하였을 때 일산화 탄소, 이산화탄소 및 탄화수소의 제거율이 99%이상임을 알 수 있었으며, 이러한 결과들은 본 발명에 따른 엔진 세정윤활제는 엔진 내부에 축적되어 있는 오염물질은 세정하는데 우수한 효과를 보임을 알 수 있다.As shown in Table 1 above, when the engine was cleaned using the cleaning lubricant composition according to the present invention, the removal rate of carbon monoxide, carbon dioxide, and hydrocarbons was 99% or more. These results indicate that the engine cleaning lubricant according to the present invention. It can be seen that the contaminants accumulated in the engine have an excellent effect on cleaning.
또한, 본 발명에 따른 세정윤활제 조성물은 자동차 엔진의 실린더 헤드, 기화기, 인젝터 등 촉매 머플러 등 금속 표면에 붙어있는 카본슬러지와 엔진 내부에 흡착된 수준까지 분해 제거하여 윤활작용을 원활하게 하고, 출력증강 및 배출가스를 감소해주는 효과가 있음을 알 수 있었다.In addition, the cleaning lubricant composition according to the present invention is smoothly lubricated by dissolving and removing carbon sludge adhered to metal surfaces such as a catalyst muffler such as a cylinder head, a carburetor, and an injector of an automobile engine and adsorbed to the inside of the engine, thereby enhancing output. And it was found that there is an effect to reduce the exhaust gas.
본 발명에 따른 세정윤활제 조성물은 자동차 엔진의 실린더 헤드, 기화기, 인젝터 등 촉매 머플러 등 금속 표면에 붙어있는 카본슬러지와 엔진 내부에 흡착된 수준까지 분해 제거하여 윤활작용을 원활하게 하고, 출력증강 및 배출가스를 감소해주는 효과가 우수하므로 산업상 이용가능성이 높다.The cleaning lubricant composition according to the present invention smoothly removes carbon sludge adhered to a metal surface such as a catalyst muffler such as a cylinder head, a carburetor, an injector of an automobile engine and adsorbed to the inside of the engine to smooth lubrication, and enhances output and discharges. It is highly industrially available because of its excellent gas-reducing effect.

Claims (9)

  1. 내연기관용 오일 20 내지 60중량%, 자일렌(C6H4(CH3)2) 5 내지 15 중량%, 산화방지제로 디부틸하이드록시톨루엔 5 ~ 10 중량%, 청정분산제로 벤질아민 5 ~ 15 중량%, 방청제로 술폰산염 10 ~ 15 중량%, 극압제로 트리크레질 포스페이트 또는 황화 테르펜 5 ~ 10 중량%, 실리콘계 소포제 1 ~ 8 중량%, 점도지수향상제로 에틸렌-프로필렌 공중합체 5 ~ 10 중량%, 유동성 강하제로 폴리알킬(메타)아크릴레이트 1 ~ 5 중량%, 합성오일로 디메틸폴리실록산 1 ~ 5 중량%을 포함하는 내연기관 세정윤활제 조성물.20 to 60 wt% oil for internal combustion engines, 5 to 15 wt% xylene (C 6 H 4 (CH 3 ) 2 ), 5 to 10 wt% dibutylhydroxytoluene as antioxidant, 5 to 15 benzylamine as clean dispersant 5% by weight of sulfonic acid salt as antirust agent, 5 to 10% by weight of tricresyl phosphate or sulfide terpene as extreme pressure agent, 1 to 8% by weight of silicone antifoaming agent, 5 to 10% by weight of viscosity index improver %, 1 to 5% by weight of polyalkyl (meth) acrylate as the fluidity lowering agent, 1 to 5% by weight of dimethylpolysiloxane as synthetic oil.
  2. 제 1항에 있어서,The method of claim 1,
    탄소나노입자, 중량평균분자량이 1×106 ~ 5×106인 초고분자량폴리에틸렌 분말 또는 이들의 혼합물을 0.1 ~ 2 중량% 더 포함하는 내연기관 세정윤활제 조성물.An internal combustion engine cleaning lubricant composition further comprising 0.1 to 2% by weight of carbon nanoparticles, ultra high molecular weight polyethylene powder having a weight average molecular weight of 1 × 10 6 to 5 × 10 6 , or a mixture thereof.
  3. 제 2항에 있어서,The method of claim 2,
    상기 탄소나노입자는 평균입경이 10 ~ 100nm인 것을 사용하는 내연기관 세정윤활제 조성물. The carbon nanoparticles of the internal combustion engine cleaning lubricant composition using an average particle diameter of 10 ~ 100nm.
  4. 제 1항에 있어서,The method of claim 1,
    안료, 향료 또는 이들의 혼합물을 0.1 내지 2 중량% 더 포함하는 내연기관 세정윤활제 조성물. An internal combustion engine cleaning lubricant composition further comprising 0.1 to 2% by weight of a pigment, a fragrance or a mixture thereof.
  5. 제 1항에 있어서,The method of claim 1,
    상기 실리콘계 소포제는 점도(25℃) 250 ~ 2500mPas인 시메티콘(Simethicone)을 사용하는 내연기관 세정윤활제 조성물. The silicone-based antifoaming agent cleaning agent composition using an internal combustion engine using simethicone (Simethicone) of viscosity (25 ℃) 250 ~ 2500mPas.
  6. 제 1항에 있어서,The method of claim 1,
    상기 술폰산염은 암모늄설포네이트 또는 바륨설포네이트인 내연기관 세정윤활제 조성물. The sulfonate salt is an internal combustion engine cleaning lubricant composition is ammonium sulfonate or barium sulfonate.
  7. a) 반응기에 산화방지제로 디부틸하이드록시톨루엔을 넣고, 50 ~ 70 ℃로 가열한 후, 방청제로 술폰산염을 첨가하여 혼합하는 단계;a) adding dibutylhydroxytoluene as an antioxidant to the reactor, heating to 50 ~ 70 ℃, and then adding by adding a sulfonic acid salt as a rust inhibitor;
    b) a)단계의 혼합물을 80 ~ 85℃로 가열한 후, 합성오일로 디메틸폴리실록산을 첨가하여 혼합하는 단계;b) heating the mixture of step a) to 80-85 ° C. and then adding and mixing dimethylpolysiloxane with synthetic oil;
    c) 상기 b)단계의 혼합물을 0 ~ 10℃로 냉각시킨 후, 자일렌을 첨가하여 10000 ~ 30000rpm으로 고속 회전하여 믹싱하는 단계;c) after cooling the mixture of step b) to 0 ~ 10 ℃, mixing by rotating at high speed to 10000 ~ 30000rpm by adding xylene;
    d) 상기 c)단계의 혼합물을 65 ~ 75℃로 가열한 후, 극압제로 트리크레질 포스페이트를 첨가하여 혼합하는 단계;d) heating the mixture of step c) to 65-75 ° C. and then adding and mixing tricresil phosphate with extreme pressure;
    e) 상기 d)단계의 혼합물의 온도를 40 ~ 45℃로 낮추고, 내연기관용 오일을 첨가하여 혼합하는 단계;e) lowering the temperature of the mixture of step d) to 40-45 ° C., adding and mixing oil for an internal combustion engine;
    f) 상기 e)단계의 혼합물에 청정분산제인 벤질아민, 실리콘계 소포제, 점도지수향상제로 에틸렌-프로필렌 공중합체, 유동성 강하제로 폴리메틸메타크릴레이트를 첨가하여 혼합하는 단계;f) mixing the mixture of step e) by adding benzylamine as a dispersant, a silicone-based antifoaming agent, an ethylene-propylene copolymer as a viscosity index improver, and polymethyl methacrylate as a fluidity lowering agent;
    를 포함하는 내연기관 세정윤활제 조성물의 제조방법.Method for producing an internal combustion engine cleaning lubricant composition comprising a.
  8. 제 7항에 있어서,The method of claim 7, wherein
    상기 f)단계에서 탄소나노입자, 중량평균분자량이 1×106 ~ 5×106인 초고분자량폴리에틸렌 분말 또는 이들의 혼합물을 첨가하는 내연기관 세정윤활제 조성물의 제조방법.The carbon nanoparticles, the weight average molecular weight of 1 × 10 6 ~ 5 × 10 6 Ultra-high molecular weight polyethylene powder or a mixture thereof is added in step f) of the internal combustion engine cleaning lubricant composition.
  9. 제 7항에 있어서,The method of claim 7, wherein
    상기 d)단계에서 안료, 향료 또는 이들의 혼합물을 더 첨가하는 내연기관 세정윤활제 조성물의 제조방법.Method of producing an internal combustion engine cleaning lubricant composition is further added to the pigment, the fragrance or a mixture thereof in step d).
PCT/KR2011/005336 2011-06-03 2011-07-20 Lubricant composition for cleaning internal combustion engines WO2012165703A1 (en)

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