WO2012157529A1 - 封止用エポキシ樹脂成形材料及び電子部品装置 - Google Patents
封止用エポキシ樹脂成形材料及び電子部品装置 Download PDFInfo
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- WO2012157529A1 WO2012157529A1 PCT/JP2012/062063 JP2012062063W WO2012157529A1 WO 2012157529 A1 WO2012157529 A1 WO 2012157529A1 JP 2012062063 W JP2012062063 W JP 2012062063W WO 2012157529 A1 WO2012157529 A1 WO 2012157529A1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/16—Solid spheres
- C08K7/18—Solid spheres inorganic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/541—Silicon-containing compounds containing oxygen
- C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
- C08K5/5419—Silicon-containing compounds containing oxygen containing at least one Si—O bond containing at least one Si—C bond
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
- C08L63/04—Epoxynovolacs
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/02—Polycondensates containing more than one epoxy group per molecule
- C08G59/04—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof
- C08G59/06—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols
- C08G59/063—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols with epihalohydrins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/02—Polycondensates containing more than one epoxy group per molecule
- C08G59/04—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof
- C08G59/06—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols
- C08G59/08—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols from phenol-aldehyde condensates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/62—Alcohols or phenols
- C08G59/621—Phenols
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
- C08G59/688—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used containing phosphorus
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/544—Silicon-containing compounds containing nitrogen
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/10—Materials in mouldable or extrudable form for sealing or packing joints or covers
- C09K3/1006—Materials in mouldable or extrudable form for sealing or packing joints or covers characterised by the chemical nature of one of its constituents
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/28—Encapsulations, e.g. encapsulating layers, coatings, e.g. for protection
- H01L23/29—Encapsulations, e.g. encapsulating layers, coatings, e.g. for protection characterised by the material, e.g. carbon
- H01L23/293—Organic, e.g. plastic
- H01L23/295—Organic, e.g. plastic containing a filler
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/28—Encapsulations, e.g. encapsulating layers, coatings, e.g. for protection
- H01L23/29—Encapsulations, e.g. encapsulating layers, coatings, e.g. for protection characterised by the material, e.g. carbon
- H01L23/293—Organic, e.g. plastic
- H01L23/296—Organo-silicon compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/005—Additives being defined by their particle size in general
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/006—Additives being defined by their surface area
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/10—Materials in mouldable or extrudable form for sealing or packing joints or covers
- C09K2003/1034—Materials or components characterised by specific properties
- C09K2003/1078—Fire-resistant, heat-resistant materials
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/0001—Technical content checked by a classifier
- H01L2924/0002—Not covered by any one of groups H01L24/00, H01L24/00 and H01L2224/00
Definitions
- the present invention relates to an epoxy resin molding material for sealing, and an electronic component device including an element sealed with the molding material.
- the entire electronic component device is processed by a solder bath, a reflow device or the like, so that the package is directly exposed to a soldering temperature (reflow temperature).
- a soldering temperature reflow temperature
- the package absorbs moisture
- the moisture absorption moisture expands rapidly during soldering, and the generated vapor pressure acts as a peeling stress, causing peeling between the element and lead frame inserts and the sealing material.
- this causes package cracks and poor electrical characteristics. For this reason, development of the sealing material excellent in solder heat resistance (reflow resistance) is desired.
- the adhesion improving effect may not be sufficient.
- the amino group-containing silane coupling agent described in Patent Document 1 has high reactivity, and when used in an epoxy resin molding material for sealing, fluidity decreases and the silane coupling agent itself gels. There is a problem in handling. Further, when a sulfur atom-containing silane coupling agent is used, the effect of improving the adhesion with noble metals such as Ag and Au is not sufficient, and the effect of improving the reflow resistance is insufficient.
- an epoxy resin molding material for sealing that sufficiently satisfies reflow resistance and moldability has not been obtained.
- the present invention has been made in view of such circumstances, and an epoxy resin molding material for sealing excellent in reflow resistance and moldability without reducing flame retardancy, and an electronic component device including an element sealed thereby It is something to be offered.
- the present invention relates to a sealing epoxy resin molding material containing both a specific amino group-containing silane compound and an epoxy group-containing silane compound, and an electronic component device including an element sealed with the sealing epoxy resin molding material. . More specifically, it is as follows.
- the present invention includes (1) (A) an epoxy resin, (B) a curing agent, (C) a curing accelerator, (D) an inorganic filler, (E1) an arylamino group-containing alkoxysilane compound, E2) It is related with the epoxy resin molding material for sealing containing an epoxy-group-containing alkoxysilane compound.
- this invention relates to the epoxy resin molding material for sealing as described in said (1) whose (2) said (E1) arylamino group containing alkoxysilane compound is a compound shown by the following general formula (I).
- R 1 and R 2 each independently represents a hydrocarbon group having 1 to 6 carbon atoms which may have a substituent.
- p represents an integer of 1 to 3
- q represents 2 or 3.
- this invention is described in said (1) or (2) whose (3) said (E2) epoxy group containing alkoxysilane compound is at least 1 sort (s) of the compound shown by the following general formula (II) and (III).
- the present invention relates to an epoxy resin molding material for sealing.
- R 1 and R 2 each independently represent a hydrocarbon group having 1 to 6 carbon atoms which may have a substituent.
- p represents an integer of 1 to 3
- q represents 2 or 3.
- R 1 and R 2 each independently represents a hydrocarbon group having 1 to 6 carbon atoms which may have a substituent.
- p represents an integer of 1 to 3
- q represents 2 or 3.
- the total amount of the (E1) arylamino group-containing alkoxysilane compound in (4) the epoxy resin molding material for sealing is the (E1) arylamino group-containing content in the epoxy resin molding material for sealing.
- the present invention relates to an epoxy resin molding material.
- the total amount of the (E1) arylamino group-containing alkoxysilane compound and the (E2) epoxy group-containing alkoxysilane compound in the epoxy resin molding material for sealing is an epoxy resin molding for sealing.
- the present invention also relates to (6) an electronic component device including an element sealed with the sealing epoxy resin molding material according to any one of (1) to (5).
- a numerical range indicated using “to” indicates a range including the numerical values described before and after “to” as the minimum value and the maximum value, respectively.
- the amount of each component in the composition is the total amount of the plurality of substances present in the composition unless there is a specific indication when there are a plurality of substances corresponding to each component in the composition. means.
- the epoxy resin molding material for sealing of the present invention comprises (A) an epoxy resin, (B) a curing agent, (C) a curing accelerator, (D) an inorganic filler, and (E1) an arylamino group-containing alkoxy. It contains a silane compound and (E2) an epoxy group-containing alkoxysilane compound, and includes other components as necessary.
- the sealing epoxy resin molding material is preferably a solid epoxy resin composition that is in a solid state at room temperature (25 ° C.). Thereby, it is excellent in storage stability. Moreover, there is no restriction
- the sealing epoxy resin molding material of the present invention contains (E1) an arylamino group-containing alkoxysilane compound.
- (E2) the epoxy group-containing alkoxysilane compound reacts with an amino group, so it is difficult to think of using an amino group-containing compound in combination with the epoxy group-containing alkoxysilane compound.
- the (E1) arylamino group-containing alkoxysilane compound is used, even when it is mixed with the (E2) epoxy group-containing alkoxysilane compound, a decrease in the storage stability of the mixture is suppressed, Increase in viscosity and gelation of the mixture are suppressed. And each function of (E1) arylamino group containing alkoxysilane compound and (E2) epoxy group containing alkoxysilane compound is exhibited, and it becomes the epoxy resin molding material for sealing excellent in reflow resistance and moldability.
- the structure of the (E1) arylamino group-containing alkoxysilane compound in the present invention is not particularly limited as long as it is an alkoxysilane compound having an aryl group adjacent to the amino group.
- examples of the arylamino group in the (E1) arylamino group-containing alkoxysilane compound include a phenylamino group and a naphthylamino group.
- the hydrogen atoms of the phenylamino group and the naphthylamino group may each independently be substituted with a hydrocarbon group having 1 to 9 carbon atoms, an amino group, an aminophenyl group, or an aminonaphthyl group.
- hydrocarbon group having 1 to 9 carbon atoms examples include methyl group, ethyl group, propyl group, isopropyl group, butyl group, isobutyl group, ter-butyl group, pentyl group, hexyl group, cyclohexyl group, vinyl group, phenyl group, Examples thereof include a methylphenyl group, an ethylphenyl group, a benzyl group, a methylbenzyl group, an ethylbenzyl group, and a vinylbenzyl group.
- the (E1) arylamino group-containing alkoxysilane compound used in the present invention preferably has a structure represented by the following general formula (I).
- R 1 and R 2 each independently represent a hydrocarbon group having 1 to 6 carbon atoms which may have a substituent.
- p represents an integer of 1 to 3
- q represents 2 or 3.
- Examples of the hydrocarbon group having 1 to 6 carbon atoms represented by R 1 and R 2 in the general formula (I) include a methyl group, an ethyl group, a propyl group, a butyl group, an isopropyl group, an isobutyl group, and a t-butyl group.
- linear, branched and cyclic alkyl groups such as pentyl group and hexyl group, alkenyl groups such as vinyl group, allyl group, butenyl group, pentenyl group and hexenyl group, and phenyl group.
- the hydrogen atom of these hydrocarbon groups may be substituted.
- the hydrocarbon group may have a substituent.
- substituents in the hydrocarbon group include a hydroxy group, an alkoxy group having 1 to 6 carbon atoms, and an acetoxy group.
- the hydrocarbon group having 1 to 6 carbon atoms represented by R 1 and R 2 is preferably an alkyl group having 1 to 4 carbon atoms, more preferably a methyl group or an ethyl group, from the viewpoint of fluidity and adhesiveness. From the viewpoint of availability, a methyl group is more preferable.
- p in the general formula (I) 2 or 3 is preferable from the viewpoint of fluidity and adhesiveness, and 3 is more preferable from the viewpoint of easy availability.
- Q in the general formula (I) is preferably 3 from the viewpoint of storage stability and availability of the silane compound.
- (E1) arylamino group-containing alkoxysilane compound Z-6883 manufactured by Toray Dow Corning Co., Ltd. is commercially available. These (E1) arylamino group-containing alkoxysilane compounds may be used alone or in combination of two or more.
- the epoxy resin molding material for sealing of the present invention contains (E2) an epoxy group-containing alkoxysilane compound.
- the structure of the epoxy group-containing alkoxysilane compound in the present invention is not particularly limited as long as it is an alkoxysilanesilane compound having an epoxy group.
- the (E2) epoxy group-containing alkoxysilane compound used in the present invention is preferably at least one compound represented by the following general formulas (II) and (III).
- R 1 and R 2 each independently represent a hydrocarbon group having 1 to 6 carbon atoms which may have a substituent.
- p represents an integer of 1 to 3
- q represents 2 or 3.
- R 1 and R 2 each independently represents a hydrocarbon group having 1 to 6 carbon atoms which may have a substituent.
- p represents an integer of 1 to 3
- q represents 2 or 3.
- Examples of the hydrocarbon group having 1 to 6 carbon atoms represented by R 1 and R 2 in the general formula (II) and the general formula (III) include a methyl group, an ethyl group, a propyl group, a butyl group, an isopropyl group, and isobutyl.
- the hydrocarbon group may have a substituent.
- substituents in the hydrocarbon group include a hydroxy group, an alkoxy group having 1 to 6 carbon atoms, and an acetoxy group.
- the hydrocarbon group having 1 to 6 carbon atoms represented by R 1 and R 2 is preferably an alkyl group having 1 to 4 carbon atoms from the viewpoint of fluidity and adhesiveness, and is preferably a methyl group or an ethyl group. Is more preferable, and a methyl group is more preferable from the viewpoint of availability.
- p is preferably 2 or 3 from the viewpoint of fluidity and adhesiveness, and 3 is more preferable from the viewpoint of availability.
- Q in the general formula (II) is preferably 3 from the viewpoints of storage stability and availability of the silane compound.
- q in the said general formula (III) 2 is preferable from a viewpoint of the storage stability and availability of a silane compound.
- epoxy group-containing alkoxysilane compound Z-6040 (3-glycidoxypropyltrimethoxysilane), Z-6041 (3-glycidoxypropyltriethoxysilane) manufactured by Toray Dow Corning Co., Ltd., Z-6042 (3-glycidoxypropylmethyldiethoxysilane), Z-6043 (2- (3,4-epoxycyclohexyl) ethyltrimethoxysilane), Z-6044 (3-glycidoxypropylmethyldimethoxysilane) Etc. are available as commercial products.
- These (E2) epoxy group-containing alkoxysilane compounds may be used alone or in combination of two or more.
- the E1 content is preferably 5% by mass or more and 90% by mass or less, and from the viewpoint of reducing the elastic modulus and improving the reflow resistance, it is more preferably 10% by mass or more and 80% by mass or less.
- E1 content rate is 10 mass% or more and 80 mass% or less.
- the E1 + E2 content is not particularly limited as long as the effects of the present invention are not impaired.
- the E1 + E2 content is preferably 1% by mass or more and 20% by mass or less, more preferably 2% by mass or more and 15% by mass or less from the viewpoint of reflow resistance. More preferably, the content is 12% by mass or less. Further, within this range, the higher the “E1 + E2 content”, the better the fluidity.
- R 1 and R 2 in formula (I) are each independently an alkyl group having 1 to 4 carbon atoms
- (E2) as an epoxy group-containing alkoxysilane compound R 1 and R 2 in the general formula (II) are alkyl groups having 1 to 4 carbon atoms
- P is 2 or 3 and q is 3
- R 1 and R 2 in the general formula (III) are each independently an alkyl group having 1 to 4 carbon atoms, and p is 2 or 3
- Q is 2 and at least one silane compound is used
- the E1 content is 10% by mass to 80% by mass
- the E1 + E2 content is 2% by mass to 15% by mass.
- R 1 and R 2 in the general formula (I) are each independently a methyl group or an ethyl group, p is 2 or 3, and q is 3.
- R 1 and R 2 in the general formula (II) are each independently a methyl group or an ethyl group, p is 2 or 3, and q is And at least one silane compound in which R 1 and R 2 in formula (III) are each independently a methyl group or an ethyl group, p is 2 or 3, and q is 2
- the E1 content is 20% by mass or more and 60% by mass or less, and the E1 + E2 content is 4% by mass or more and 12% by mass or less.
- the method of blending (E1) arylamino group-containing alkoxysilane compound and (E2) epoxy group-containing alkoxysilane compound when producing an epoxy resin molding material for sealing is not particularly limited.
- the order in particular is not restrict
- epoxy resin used in this invention is generally used for the epoxy resin molding material for sealing, there will be no restriction
- phenol novolac type epoxy resin, orthocresol novolak type epoxy resin, phenol resin including epoxy resin having triphenylmethane skeleton, phenols such as cresol, xylenol, resorcin, catechol, bisphenol A, bisphenol F and the like At least one selected from the group consisting of naphthols such as ⁇ -naphthol, ⁇ -naphthol and dihydroxynaphthalene and a compound having an aldehyde group such as formaldehyde, acetaldehyde, propionaldehyde, benzaldehyde, salicylaldehyde and the like are condensed in an acidic catalyst.
- the epoxy resin preferably contains a biphenyl type epoxy resin which is diglycidyl ether of alkyl-substituted, aromatic ring-substituted or unsubstituted biphenol from the viewpoint of compatibility between fluidity and curability. From the viewpoint of curability, it is preferable to contain a novolac type epoxy resin. Moreover, it is preferable to contain the dicyclopentadiene type epoxy resin from a low hygroscopic viewpoint. Moreover, it is preferable to contain a naphthalene type epoxy resin from a viewpoint of heat resistance and low warpage.
- the bisphenol F type epoxy resin which is the diglycidyl ether of alkyl substituted, aromatic ring substituted, or unsubstituted bisphenol F from a viewpoint of coexistence of fluidity
- the thiodiphenol type epoxy resin which is the diglycidyl ether of alkyl substituted, aromatic ring substituted, or unsubstituted thiodiphenol.
- it contains an epoxidized phenol / aralkyl resin synthesized from alkyl-substituted, aromatic ring-substituted or unsubstituted phenol and dimethoxyparaxylene or bis (methoxymethyl) biphenyl.
- it is.
- it preferably contains an epoxidized naphthol / aralkyl resin synthesized from alkyl-substituted, aromatic-ring-substituted or unsubstituted naphthols and dimethoxyparaxylene.
- Examples of the biphenyl type epoxy resin include an epoxy resin represented by the following general formula (IV).
- R 1 to R 8 each independently represents a hydrogen atom, a monovalent hydrocarbon group having 1 to 10 carbon atoms, or an alkoxy group having 1 to 10 carbon atoms.
- n represents an integer of 0 to 3.
- Specific examples of R 1 to R 8 in the general formula (IV) include hydrogen atoms; 1 to 10 carbon atoms such as methyl, ethyl, propyl, butyl, isopropyl, isobutyl, and tert-butyl groups.
- alkenyl group having 1 to 10 carbon atoms such as a vinyl group, an allyl group and a butenyl group; an alkoxy group having 1 to 10 carbon atoms such as a methoxy group and an ethoxy group; Of these, a hydrogen atom or a methyl group is preferable.
- the biphenyl type epoxy resin represented by the general formula (IV) can be obtained by reacting a biphenol compound with epichlorohydrin by a known method.
- examples of such an epoxy resin include 4,4′-bis (2,3-epoxypropoxy) biphenyl or 4,4′-bis (2,3-epoxypropoxy) -3,3 ′, 5,5 ′.
- an epoxy resin mainly composed of 4,4′-bis (2,3-epoxypropoxy) -3,3 ′, 5,5′-tetramethylbiphenyl is preferable.
- Such epoxy resins are commercially available as trade names YX-4000 and YL-6121H manufactured by Mitsubishi Chemical Corporation.
- the content of the biphenyl type epoxy resin is preferably 20% by mass or more based on the total amount of the epoxy resin in order to exhibit its performance, 30 More preferably, it is more preferably 50% by mass or more.
- Examples of the thiodiphenol type epoxy resin include an epoxy resin represented by the following general formula (V).
- R 1 to R 8 each independently represents a hydrogen atom, a monovalent hydrocarbon group having 1 to 10 carbon atoms, or an alkoxy group having 1 to 10 carbon atoms.
- n represents an integer of 0 to 3.
- Specific examples of R 1 to R 8 in the general formula (V) include hydrogen atoms; 1 to 10 carbon atoms such as methyl, ethyl, propyl, butyl, isopropyl, isobutyl, and tert-butyl groups.
- alkenyl group having 1 to 10 carbon atoms such as a vinyl group, an allyl group or a butenyl group; an alkoxy group having 1 to 10 carbon atoms such as a methoxy group or an ethoxy group; Of these, a hydrogen atom, a methyl group or a tert-butyl group is preferable.
- the thiodiphenol type epoxy resin represented by the general formula (V) can be obtained by reacting a thiodiphenol compound with epichlorohydrin by a known method.
- an epoxy resin include an epoxy resin mainly composed of 4,4′-dihydroxydiphenyl sulfide diglycidyl ether, and 2,2 ′, 5,5′-tetramethyl-4,4′-dihydroxydiphenyl.
- Epoxy resin mainly composed of diglycidyl ether of sulfide epoxy resin mainly composed of diglycidyl ether of 2,2′-dimethyl-4,4′-dihydroxy-5,5′-di-tert-butyldiphenyl sulfide
- an epoxy mainly composed of an epoxy resin mainly composed of diglycidyl ether of 2,2′-dimethyl-4,4′-dihydroxy-5,5′-di-tert-butyldiphenyl sulfide Resins are preferred.
- Such an epoxy resin is commercially available under the trade name YSLV-120TE manufactured by Nippon Steel Chemical Co., Ltd.
- the content of the thiodiphenol type epoxy resin is 20% by mass or more in the total amount of the epoxy resin in order to exert its performance. Is preferable, 30 mass% or more is more preferable, and 50 mass% or more is more preferable.
- Examples of the bisphenol F type epoxy resin include an epoxy resin represented by the following general formula (VI).
- R 1 to R 8 each independently represents a hydrogen atom, a monovalent hydrocarbon group having 1 to 10 carbon atoms, or an alkoxy group having 1 to 10 carbon atoms.
- n represents an integer of 0 to 3.
- Specific examples of R 1 to R 8 in the general formula (VI) include hydrogen atoms; 1 to 10 carbon atoms such as methyl, ethyl, propyl, butyl, isopropyl, isobutyl, and tert-butyl groups.
- alkenyl group having 1 to 10 carbon atoms such as a vinyl group, an allyl group and a butenyl group; an alkoxy group having 1 to 10 carbon atoms such as a methoxy group and an ethoxy group; Of these, a hydrogen atom or a methyl group is preferable.
- the bisphenol F type epoxy resin represented by the general formula (VI) can be obtained by reacting a bisphenol F compound with epichlorohydrin by a known method.
- an epoxy resin include an epoxy resin mainly composed of 4,4'-methylenebis (2,6-dimethylphenol) diglycidyl ether, and 4,4'-methylenebis (2,3,6-trimethyl).
- An epoxy resin mainly composed of diglycidyl ether of phenol) is preferred.
- Such an epoxy resin is commercially available as trade name YSLV-80XY manufactured by Nippon Steel Chemical Co., Ltd.
- the content of the bisphenol F type epoxy resin is preferably 20% by mass or more based on the total amount of the epoxy resin in order to exhibit its performance. 30 mass% or more is more preferable, and 50 mass% or more is further more preferable.
- novolac type epoxy resin examples include an epoxy resin represented by the following general formula (VII).
- each R independently represents a hydrogen atom, a monovalent hydrocarbon group having 1 to 10 carbon atoms, or an alkoxy group having 1 to 10 carbon atoms.
- n represents an integer of 0 to 10.
- R in the general formula (VII) represents a hydrogen atom; an alkyl group having 1 to 10 carbon atoms such as methyl group, ethyl group, propyl group, butyl group, isopropyl group, isobutyl group; methoxy group, ethoxy group An alkoxy group having 1 to 10 carbon atoms such as a group, a propoxy group or a butoxy group; a hydrogen atom or a methyl group is more preferable.
- n is preferably an integer of 0 to 3.
- the novolak type epoxy resin represented by the general formula (VII) can be easily obtained by reacting a novolak type phenol resin with epichlorohydrin.
- the novolak epoxy resins represented by the general formula (VII) orthocresol novolac epoxy resins are preferable.
- an epoxy resin trade name: ESCN-190 manufactured by Sumitomo Chemical Co., Ltd. is commercially available.
- the content of the novolac type epoxy resin is preferably 20% by mass or more based on the total amount of the epoxy resin in order to exhibit its performance, and 30% by mass. % Or more is more preferable.
- dicyclopentadiene type epoxy resin examples include an epoxy resin represented by the following general formula (VIII).
- each R 1 independently represents a hydrogen atom or a monovalent hydrocarbon group having 1 to 10 carbon atoms.
- R 2 independently represents a monovalent hydrocarbon group having 1 to 10 carbon atoms.
- n represents an integer of 0 to 10
- m represents an integer of 0 to 6.
- R 1 in the general formula (VIII) is a hydrogen atom; an alkyl group such as a methyl group, an ethyl group, a propyl group, a butyl group, an isopropyl group or a tert-butyl group, a vinyl group, an allyl group, or a butenyl group. And monovalent hydrocarbon groups having 1 to 10 carbon atoms such as alkenyl groups. Of these, an alkyl group such as a methyl group or an ethyl group or a hydrogen atom is preferable, and a methyl group or a hydrogen atom is more preferable.
- R 2 is a non-carbon group having 1 to 10 carbon atoms such as an alkyl group such as a methyl group, an ethyl group, a propyl group, a butyl group, an isopropyl group or a tert-butyl group, an alkenyl group such as a vinyl group, an allyl group or a butenyl group.
- a substituted monovalent hydrocarbon group may be mentioned.
- m is preferably 0.
- the content of the dicyclopentadiene type epoxy resin may be 20% by mass or more in the total amount of the epoxy resin in order to exert its performance. Preferably, 30 mass% or more is more preferable.
- naphthalene type epoxy resin examples include an epoxy resin represented by the following general formula (IX).
- R 1 to R 3 each independently represents a monovalent hydrocarbon group having 1 to 12 carbon atoms or an alkoxy group having 1 to 10 carbon atoms.
- p represents 1 or 0.
- m and n are each independently an integer of 0 to 11, wherein (m + n) is an integer of 1 to 11 and (m + p) is an integer of 1 to 12.
- i represents an integer of 0 to 3
- j represents an integer of 0 to 2
- k represents an integer of 0 to 4, respectively.
- R 1 to R 3 in the general formula (IX) include alkyl groups having 1 to 10 carbon atoms such as methyl, ethyl, propyl, butyl, isopropyl, isobutyl, and tert-butyl groups.
- An alkenyl group having 1 to 10 carbon atoms such as a vinyl group, an allyl group or a butenyl group; an alkoxy group having 1 to 10 carbon atoms such as a methoxy group or an ethoxy group; Of these, a methyl group is preferable, and it is also preferable that at least one of i, j and k is 0.
- naphthalene type epoxy resin represented by the general formula (IX) there are a random copolymer containing m constituent units and n constituent units at random, an alternating copolymer containing alternating units, and a copolymer containing regularly. Examples thereof include block copolymers which are included in a combined or block form, and any one of these may be used alone, or two or more may be used in combination.
- an epoxy resin trade name: NC-7300 manufactured by Nippon Kayaku Co., Ltd. is commercially available.
- the content of the naphthalene type epoxy resin is preferably 20% by mass or more in the total amount of the epoxy resin in order to exhibit its performance, 30 More preferably, it is more preferably 50% by mass or more.
- Examples of the epoxidized phenol / aralkyl resin include an epoxy resin represented by the following general formula (X) and an epoxy resin represented by the following general formula (XI).
- R 1 to R 8 each independently represents a hydrogen atom or a monovalent hydrocarbon group having 1 to 12 carbon atoms.
- R 9 independently represents a monovalent hydrocarbon group having 1 to 12 carbon atoms.
- i represents an integer of 0 to 3
- n represents an integer of 0 to 10.
- R 1 to R 4 each independently represents a hydrogen atom or a monovalent hydrocarbon group having 1 to 12 carbon atoms.
- R 5 each independently represents a monovalent hydrocarbon group having 1 to 12 carbon atoms.
- i represents an integer of 0 to 3
- n represents an integer of 0 to 10.
- the epoxidized product of the biphenylene skeleton-containing phenol / aralkyl resin represented by the general formula (X) is obtained by adding epichlorohydrin to a phenol / aralkyl resin synthesized from alkyl-substituted, aromatic ring-substituted or unsubstituted phenol and bis (methoxymethyl) biphenyl. It can be obtained by reacting by a known method.
- Examples of the monovalent hydrocarbon group represented by R 1 to R 9 in the general formula (X) include a methyl group, an ethyl group, a propyl group, an isopropyl group, an n-butyl group, a sec-butyl group, a tert-butyl group, and pentyl.
- Aryl group-substituted alkyl group alkoxy group-substituted alkyl group such as methoxy group-substituted alkyl group, ethoxy group-substituted alkyl group, butoxy group-substituted alkyl group; amino group-substituted alkyl group such as aminoalkyl group, dimethylaminoalkyl group, diethylaminoalkyl group Hydroxyl group-substituted alkyl group; phenyl group, naphthyl group, biphenyl group An unsubstituted aryl group; an alkyl group-substituted aryl group such as a tolyl group, dimethylphenyl group, ethylphenyl group, butylphenyl group, tert-butylphenyl group, dimethylnaphthyl group; methoxyphenyl group, ethoxyphenyl group, butoxyphenyl group
- R 1 to R 8 are preferably a hydrogen atom, and i is preferably 0. Further, n in the general formula (X) is more preferably 6 or less on average.
- Such an epoxy resin is commercially available under the trade name NC-3000S manufactured by Nippon Kayaku Co., Ltd.
- CER-3000L trade name, manufactured by Nippon Kayaku Co., Ltd.
- Examples of the monovalent hydrocarbon group represented by R 1 to R 5 in the general formula (XI) include a methyl group, an ethyl group, a propyl group, an isopropyl group, an n-butyl group, a sec-butyl group, and a tert-butyl group.
- Chain alkyl groups such as pentyl group, hexyl group, octyl group, decyl group, dodecyl group, cyclic alkyl groups such as cyclopentyl group, cyclohexyl group, cycloheptyl group, cyclopentenyl group, cyclohexenyl group, benzyl group, phenethyl group
- Aryl group-substituted alkyl groups such as, methoxy group-substituted alkyl groups, ethoxy group-substituted alkyl groups, alkoxy groups-substituted alkyl groups such as butoxy group-substituted alkyl groups, aminoalkyl groups, dimethylaminoalkyl groups, amino groups substituted such as diethylaminoalkyl groups Alkyl group, hydroxyl group-substituted alkyl group, phenyl group, naphthyl group, Unsubsti
- R 1 to R 4 are preferably a hydrogen atom, and i is preferably 0. Further, n in the general formula (XI) is more preferably 6 or less on average.
- Such an epoxy resin is available as a commercial product under the trade name NC-2000L manufactured by Nippon Kayaku Co., Ltd.
- the epoxy resin molding material for sealing contains the epoxidized product of the phenol / aralkyl resin
- the content is preferably 20% by mass or more based on the total amount of the epoxy resin in order to exhibit its performance, and 30% by mass. The above is more preferable.
- Examples of the epoxidized product of naphthol / aralkyl resin include an epoxy resin represented by the following general formula (XII).
- each R independently represents a monovalent hydrocarbon group having 1 to 12 carbon atoms.
- i represents an integer of 0 to 3.
- X represents a divalent organic group containing an aromatic ring.
- n represents an integer of 0 to 10.
- X is derived from an arylene group such as a phenylene group, a biphenylene group or a naphthylene group; an alkyl group-substituted arylene group such as a tolylene group; an alkoxy group-substituted arylene group or an aralkyl group-substituted arylene group; an aralkyl group such as a benzyl group or a phenethyl group And a divalent organic group containing an arylene group such as a xylylene group.
- a phenylene group and a biphenylene group are preferable from the viewpoint of achieving both flame retardancy and storage stability.
- the epoxidized naphthol / aralkyl resin represented by the general formula (XII) is an epichlorohydrin synthesized from naphthol / aralkyl resin synthesized from alkyl-substituted, aromatic ring-substituted or unsubstituted naphthol and dimethoxyparaxylene or bis (methoxymethyl) biphenyl. Can be obtained by a known method.
- R in the general formula (XII) is, for example, methyl group, ethyl group, propyl group, isopropyl group, n-butyl group, sec-butyl group, tert-butyl group, pentyl group, hexyl group, octyl group, decyl group.
- Chain alkyl groups such as dodecyl group, cyclopentyl group, cyclohexyl group, cycloheptyl group, cyclopentenyl group, cyclohexenyl group and other cyclic alkyl groups, benzyl group, phenethyl group and other aryl group substituted alkyl groups, methoxy group substituted alkyl Group, alkoxy group-substituted alkyl group such as ethoxy group-substituted alkyl group, butoxy group-substituted alkyl group, amino group-substituted alkyl group such as aminoalkyl group, dimethylaminoalkyl group, diethylaminoalkyl group, hydroxyl group-substituted alkyl group, phenyl group, naphthyl Group, unsubstituted aryl group such as biphenyl group, Alkyl group-substituted aryl groups such as
- epoxidized product of the naphthol / aralkyl resin represented by the general formula (XII) include an epoxidized product of a naphthol / aralkyl resin represented by the following general formula (XIII) and a naphthol / aralkyl resin represented by the following general formula (XIV).
- An epoxidized product of an aralkyl resin can be mentioned.
- an epoxy resin represented by the following general formula (XIII) a product name ESN-375 manufactured by Nippon Steel Chemical Co., Ltd. can be mentioned as a commercially available product.
- an epoxy resin represented by the following general formula (XIV) A trade name ESN-175 manufactured by Sakai Chemical Co., Ltd. can be mentioned.
- n represents an integer of 0 to 10.
- n represents an integer of 0 to 10.
- the epoxy resin molding material for sealing contains an epoxidized product of the naphthol / aralkyl resin
- the content of the epoxidized product of the naphthol / aralkyl resin is 20% by mass or more based on the total amount of the epoxy resin in order to exhibit its performance.
- it is more preferably 30% by mass or more, and further preferably 50% by mass or more.
- an epoxy resin having the following structural formula (XV) can also be used as the (A) epoxy resin.
- R 1 and R 2 in the general formula (XV) each independently represent a hydrocarbon group having 1 to 12 carbon atoms or an alkoxy group having 1 to 12 carbon atoms.
- n represents an integer of 0 to 4.
- m represents an integer of 0-2.
- Examples of the epoxy resin represented by the general formula (XV) include epoxy resins represented by the following general formulas (XVI) to (XXXIV).
- the epoxy resin represented by the general formula (XVI) is preferable from the viewpoint of flame retardancy and moldability.
- YX-8800 trade name, manufactured by Mitsubishi Chemical Corporation
- the epoxy resin molding material for sealing contains the epoxy resin represented by the general formula (XVI), in order for the epoxy resin to exhibit performance from each viewpoint, its content is based on the total amount of the epoxy resin. It is preferably 30% by mass or more, more preferably 50% by mass or more, and further preferably 60% by mass or more.
- an epoxy resin of the following structural formula (XXXXV) can also be used as the (A) epoxy resin.
- R 1 and R 2 in the general formula (XXXXV) each independently represent a hydrocarbon group having 1 to 12 carbon atoms or an alkoxy group having 1 or 2 carbon atoms.
- n represents an integer of 0 to 10.
- R 1 and R 2 in the general formula (XXXXV) are, for example, methyl group, ethyl group, propyl group, isopropyl group, n-butyl group, sec-butyl group, tert-butyl group, pentyl group, hexyl group, octyl
- a chain alkyl group such as a group, decyl group or dodecyl group; a cyclic alkyl group such as a cyclopentyl group, a cyclohexyl group, a cycloheptyl group, a cyclopentenyl group or a cyclohexenyl group; a benzyl group, a phenethyl group, a methoxy group or an ethoxy group Among them, R 1 is preferably a methyl group and R 2 is preferably a methoxy group.
- An example of such a compound is DIC Corporation trade name: HP
- the content of the epoxy resin represented by the general formula (XXXXV) is the total amount of the epoxy resin in order to exhibit its performance
- the content is preferably 20% by mass or more, more preferably 30% by mass or more, and further preferably 50% by mass or more.
- the epoxy equivalent of the epoxy resin is not particularly limited.
- 150 g / eq. To 500 g / eq.
- the softening point or melting point of the epoxy resin is not particularly limited.
- it is preferably 40 ° C. to 180 ° C., and from the viewpoint of handleability when producing an epoxy resin molding material for sealing, it is more preferably 50 ° C. to 130 ° C. .
- the content of the (A) epoxy resin in the sealing epoxy resin molding material is not particularly limited. From the viewpoint of balance of various properties such as moldability, reflow resistance and electrical reliability, the content is preferably 0.4% by mass to 28% by mass, and 1.1% by mass in the total mass of the epoxy resin molding material for sealing. More preferably, the content is from 26 to 26% by mass.
- the epoxy resin molding material for sealing contains at least one curing agent. If the said hardening
- phenols such as phenol, cresol, resorcin, catechol, bisphenol A, bisphenol F, phenylphenol, thiodiphenol, aminophenol, and naphthols such as ⁇ -naphthol, ⁇ -naphthol, and dihydroxynaphthalene.
- Selected from the group consisting of phenols and naphthols obtained by condensing or co-condensing at least one kind of a compound having an aldehyde group such as formaldehyde, benzaldehyde, and salicylaldehyde with an acidic catalyst.
- Phenol / aralkyl resins synthesized from at least one kind and dimethoxyparaxylene or bis (methoxymethyl) biphenyl; aralkyl-type phenol resins such as naphthol / aralkyl resins; Copolymer-type phenol-aralkyl resin in which an enol-novolak structure and a phenol-aralkyl structure are randomly, block, or alternately repeated; paraxylylene-modified phenol resin; metaxylylene-modified phenol resin; melamine-modified phenol resin; terpene-modified phenol resin; Examples thereof include pentadiene-modified phenol resins; cyclopentadiene-modified phenol resins; polycyclic aromatic ring-modified phenol resins. These may be used alone or in combination of two or more.
- phenol / aralkyl resins and naphthol / aralkyl resins are preferred from the viewpoints of fluidity, flame retardancy, and reflow resistance. Further, from the viewpoint of low hygroscopicity, dicyclopentadiene-modified phenol resin is preferable. From the viewpoint of curability, a novolac type phenol resin is preferable.
- the curing agent preferably contains at least one of these phenol resins.
- phenol-aralkyl resin examples include resins represented by the following general formula (XXXV).
- each R independently represents a substituted or unsubstituted monovalent hydrocarbon group having 1 to 12 carbon atoms.
- i represents an integer of 0 to 3.
- X represents a divalent organic group containing an aromatic ring.
- n represents an integer of 0 to 10. Examples of the substituent in the hydrocarbon group include an aryl group, an alkoxy group, an amino group, and a hydroxyl group.
- R in the general formula (XXXV) include a methyl group, an ethyl group, a propyl group, an isopropyl group, an n-butyl group, a sec-butyl group, a tert-butyl group, a pentyl group, a hexyl group, and an octyl group.
- alkyl groups such as decyl and dodecyl groups; cyclic alkyl groups such as cyclopentyl, cyclohexyl, cycloheptyl, cyclopentenyl, and cyclohexenyl; aryl groups such as benzyl and phenethyl Substituted alkyl group; alkoxy group-substituted alkyl group such as methoxy group-substituted alkyl group, ethoxy group-substituted alkyl group, butoxy group-substituted alkyl group; amino group-substituted alkyl group such as aminoalkyl group, dimethylaminoalkyl group, diethylaminoalkyl group; hydroxyl group Substituted alkyl group; phenyl group, naphthyl group, biphenyl group An unsubstituted aryl group; an alkyl group-substituted aryl
- X represents a divalent organic group containing an aromatic ring.
- an arylene group such as a phenylene group, a biphenylene group, or a naphthylene group; an alkyl group-substituted arylene group such as a tolylene group; an alkoxy group-substituted arylene group; a divalent organic group derived from an aralkyl group such as a benzyl group or a phenethyl group
- a divalent organic group containing an arylene group such as an aralkyl group-substituted arylene group or a xylylene group;
- a substituted or unsubstituted biphenylene group is preferable from the viewpoint of achieving both flame retardancy and reflow resistance, and examples thereof include a phenol-aralkyl resin represented by the following general formula (XXXVI).
- a substituted or unsubstituted phenylene group is preferable, and examples thereof include a phenol / aralkyl resin represented by the following general formula (XXXVII).
- XXXVII phenol / aralkyl resin represented by the following general formula (XXXVII).
- n represents an integer of 0 to 10, preferably 6 or less on average.
- biphenylene skeleton-containing phenol / aralkyl resin represented by the general formula (XXXVI) MEH-7851 manufactured by Meiwa Kasei Co., Ltd. may be mentioned as a commercial product.
- a phenol aralkyl resin shown by general formula (XXXVII) Mitsui Chemicals make brand name XLC is mentioned as a commercial item.
- the epoxy resin molding material for sealing contains the phenol / aralkyl resin as a curing agent
- the content of the phenol / aralkyl resin should be 20% by mass or more in the total amount of the curing agent in order to exert its performance. Is preferable, 30 mass% or more is more preferable, and 50 mass% or more is more preferable.
- naphthol / aralkyl resins examples include resins represented by the following general formula (XXXVIII).
- each R independently represents a substituted or unsubstituted monovalent hydrocarbon group having 1 to 12 carbon atoms.
- i represents an integer of 0 to 3
- X represents a divalent organic group containing an aromatic ring.
- n represents an integer of 0 to 10.
- substituent in the hydrocarbon group include an aryl group, an alkoxy group, an amino group, and a hydroxyl group.
- R in the general formula (XXXVIII) include methyl, ethyl, propyl, isopropyl, n-butyl, sec-butyl, tert-butyl, pentyl, hexyl, and octyl.
- Chain and branched alkyl groups such as decyl and dodecyl groups; cyclic alkyl groups such as cyclopentyl, cyclohexyl, cycloheptyl, cyclopentenyl, and cyclohexenyl; aryl groups such as benzyl and phenethyl Substituted alkyl group; alkoxy group-substituted alkyl group such as methoxy group-substituted alkyl group, ethoxy group-substituted alkyl group, butoxy group-substituted alkyl group; amino group-substituted alkyl group such as aminoalkyl group, dimethylaminoalkyl group, diethylaminoalkyl group; hydroxyl group Substituted alkyl group; phenyl group, naphthyl group, biphe An unsubstituted aryl group such as a tolu group; an alky
- X represents a divalent organic group containing an aromatic ring.
- an arylene group such as a phenylene group, a biphenylene group, and a naphthylene group
- an alkyl group-substituted arylene group such as a tolylene group
- an alkoxy group-substituted arylene group an aralkyl group-substituted arylene group
- an aralkyl group such as a benzyl group and a phenethyl group
- Examples thereof include a divalent organic group to be derived; a divalent organic group containing an arylene group such as a xylylene group.
- naphthol-aralkyl resins include naphthol-aralkyl resins represented by the following general formula (XXXIX) and naphthol-aralkyl resins represented by (XXXXX).
- XXXIX naphthol-aralkyl resins represented by the following general formula (XXXIX) and the following general formula (XXXX)
- n represents an integer of 0 to 10, and is preferably 6 or less on average.
- a product name SN-475 manufactured by Nippon Steel Chemical Co., Ltd. can be mentioned.
- a naphthol / aralkyl resin represented by the above general formula (XXXX) a commercially available product name SN-170 manufactured by Nippon Steel Chemical Co., Ltd. may be mentioned.
- the sealing epoxy resin molding material contains the naphthol / aralkyl resin as a curing agent
- the content of the naphthol / aralkyl resin should be 20% by mass or more in the total amount of the curing agent in order to exert its performance. Is preferable, 30 mass% or more is more preferable, and 50 mass% or more is more preferable.
- the phenol / aralkyl resin represented by the general formula (XXXV) and the naphthol / aralkyl resin represented by the general formula (XXXVIII) are partially mixed with a polymerizable monomer such as acenaphthylene from the viewpoint of flame retardancy. It is preferable.
- acenaphthylene can be obtained by dehydrogenating acenaphthene, a commercially available product may be used.
- it can also be used as a polymer of acenaphthylene or a polymer of acenaphthylene and other aromatic olefins instead of acenaphthylene.
- Examples of a method for obtaining a polymer of acenaphthylene or a polymer of acenaphthylene and another aromatic olefin include radical polymerization, cationic polymerization, and anionic polymerization.
- a conventionally known catalyst can be used, but it can also be carried out only by heat without using a catalyst.
- the polymerization temperature is preferably 80 ° C. to 160 ° C., more preferably 90 ° C. to 150 ° C.
- the softening point of the resulting polymer of acenaphthylene or the polymer of acenaphthylene and another aromatic olefin is preferably 60 ° C to 150 ° C, more preferably 70 ° C to 130 ° C.
- the polymer has a softening point of 60 ° C. or higher, seepage during molding tends to be suppressed and moldability tends to be improved.
- aromatic olefins copolymerized with acenaphthylene examples include styrene, ⁇ -methylstyrene, indene, benzothiophene, benzofuran, vinylnaphthalene, vinylbiphenyl, and alkyl-substituted products thereof.
- aliphatic olefins can be used in combination as long as the effects of the present invention are not hindered.
- the aliphatic olefin include (meth) acrylic acid and esters thereof, maleic anhydride, itaconic anhydride, fumaric acid and esters thereof.
- the amount of these aliphatic olefins to be used is preferably 20% by mass or less, more preferably 9% by mass or less, based on the total amount of the polymerization monomer used for the preliminary mixing with the phenol / aralkyl resin and naphthol / aralkyl resin.
- the curing agent and acenaphthylene are finely pulverized and mixed in a solid state with a mixer or the like, or both components are uniformly dissolved in a solvent that dissolves them.
- the method can be performed by a method of removing the solvent, a method of melt-mixing both at a temperature equal to or higher than the softening point of at least one of the curing agent and acenaphthylene.
- the melt mixing method is preferable because a uniform mixture is obtained and impurities are less mixed.
- a premix (acenaphthylene-modified curing agent) is produced by the above method.
- the melt mixing is not limited as long as the temperature is at least the softening point of at least one of the curing agent and acenaphthylene. Of these, 100 ° C to 250 ° C is preferable, and 120 ° C to 200 ° C is more preferable. In the melt mixing, there is no limitation on the mixing time as long as both are mixed uniformly, but among these, 1 to 20 hours is preferable, and 2 to 15 hours is more preferable.
- the curing agent and acenaphthylene are premixed, the acenaphthylene may polymerize or react with the curing agent during mixing.
- dicyclopentadiene type phenol resin examples include a phenol resin represented by the following general formula (XXXI).
- each R 1 independently represents a hydrogen atom or a substituted or unsubstituted monovalent hydrocarbon group having 1 to 10 carbon atoms.
- R 2 independently represents a substituted or unsubstituted monovalent hydrocarbon group having 1 to 10 carbon atoms.
- n represents an integer of 0 to 10.
- m represents an integer of 0-6.
- substituent in the hydrocarbon group include a halogen atom, an amino group, and a sulfanyl group.
- R 1 in the general formula (XXXXI) include a hydrogen atom +; an alkyl group such as a methyl group, an ethyl group, a propyl group, a butyl group, an isopropyl group, and a tert-butyl group, a vinyl group, an allyl group, Examples thereof include substituted or unsubstituted monovalent hydrocarbon groups having 1 to 10 carbon atoms such as alkenyl groups such as butenyl groups, halogenated alkyl groups, amino group-substituted alkyl groups, and sulfanyl group-substituted alkyl groups.
- an alkyl group such as a methyl group or an ethyl group and a hydrogen atom are preferable, and a methyl group and a hydrogen atom are more preferable.
- R 2 include alkyl groups such as methyl group, ethyl group, propyl group, butyl group, isopropyl group and tert-butyl group, alkenyl groups such as vinyl group, allyl group and butenyl group, halogenated alkyl groups, Examples thereof include substituted or unsubstituted monovalent hydrocarbon groups having 1 to 10 carbon atoms such as amino group-substituted alkyl groups and sulfanyl group-substituted alkyl groups.
- n is an integer of 0 to 6, but is preferably 0.
- DPP (trade name, manufactured by Nippon Petrochemical Co., Ltd.) and the like are available as commercial products.
- the content of the dicyclopentadiene type phenol epoxy resin should be 20% by mass or more in the total amount of the curing agent in order to exert its performance. Is preferable, 30 mass% or more is more preferable, and 50 mass% or more is more preferable.
- novolak-type phenol resin examples include novolak-type phenol resins such as a phenol resin represented by the following general formula (XXXXII), cresol novolak resins, and the like. Among these, novolak-type phenol resins represented by the following general formula (XXXXII) preferable.
- R represents a substituted or unsubstituted monovalent hydrocarbon group having 1 to 10 carbon atoms.
- i represents an integer of 0 to 3
- n represents an integer of 0 to 10.
- substituent in the hydrocarbon group include a halogen atom, an amino group, and a mercapto group.
- R in the general formula (XXXXII) include alkyl groups such as methyl group, ethyl group, propyl group, butyl group, isopropyl group, and tert-butyl group, and alkenyl groups such as vinyl group, allyl group, and butenyl group.
- a substituted or unsubstituted monovalent hydrocarbon group having 1 to 10 carbon atoms such as a group, a halogenated alkyl group, an amino group-substituted alkyl group and a mercapto group-substituted alkyl group.
- R is preferably an alkyl group such as a methyl group or an ethyl group.
- i is 0.
- the average value of n is preferably 0-8.
- a novolak type phenol resin represented by the above general formula (XXXXII) trade name: H-4 manufactured by Meiwa Kasei Co., Ltd. is available as a commercial product.
- the content of the novolac type phenol resin is preferably 30% by mass or more in the total amount of the curing agent in order to exert its performance, and 50% by mass. % Or more is more preferable.
- the above curing agents may be used alone or in combination of two or more.
- the content is preferably 50% by mass or more, more preferably 60% by mass or more, and even more preferably 80% by mass or more in the total amount of the curing agent.
- the hydroxyl equivalent of the curing agent is not particularly limited. Especially, from the viewpoint of balance of various properties such as moldability, reflow resistance and electrical reliability, 70 g / eq. -1000 g / eq. It is preferable that 80 g / eq. To 500 g / eq. It is more preferable that The softening point or melting point of the curing agent is not particularly limited. In particular, from the viewpoint of moldability and reflow resistance, it is preferably 40 ° C. to 180 ° C., and from the viewpoint of handleability when producing an epoxy resin molding material for sealing, it is more preferably 50 ° C. to 130 ° C. .
- the equivalent ratio of (A) epoxy resin and (B) curing agent that is, the ratio of the number of hydroxyl groups in the curing agent to the epoxy group (number of hydroxyl groups in curing agent / in epoxy resin)
- the number of epoxy groups is not particularly limited. In order to keep each unreacted component small, it is preferably set in the range of 0.5 to 2.0, more preferably 0.6 to 1.3. Further, in order to obtain a sealing epoxy resin molding material excellent in moldability and solder reflow resistance, it is more preferably set in the range of 0.8 to 1.2.
- the epoxy resin molding material for sealing contains at least one curing accelerator.
- the curing accelerator is not particularly limited as long as it is generally used in an epoxy resin molding material for sealing.
- a compound having intramolecular polarization formed by adding a compound having a ⁇ bond benzyldimethylamine, triethanolamine, di Tertiary amine compounds such as tilaminoethanol and tris (dimethylaminomethyl) phenol; derivatives of these tertiary amine compounds, 2-methylimidazole, 2-phenylimidazole, 2-phenyl-4-methylimidazole, 2- Imidazole compounds such as heptadecylimidazole; derivatives of these imidazole compounds; organic phosphine compounds such as tributylphosphine, methyldiphenylphosphine, triphenylphosphine, tris (4-methylphenyl) phosphine, diphenylphosphine, phenylphosphine; Phosphorus compound having intramolecular polarization formed by adding a compound having a ⁇ bond such as maleic anhydride, the above quinone compound, diazophen
- the curing accelerator is preferably an adduct of a tertiary phosphine and a quinone compound from the viewpoint of curability and fluidity, more preferably an adduct of triphenylphosphine and benzoquinone or an adduct of tributylphosphine and benzoquinone. preferable.
- an adduct of a cycloamidine compound and a phenol resin is preferable, and a novolak-type phenol resin salt of diazabicycloundecene is more preferable (hereinafter also referred to as “specific curing accelerator”).
- the content of these specific curing accelerators is preferably 60% by mass or more and more preferably 80% by mass or more in the total amount of the curing accelerator.
- the third phosphine used for the adduct of the third phosphine and the quinone compound is not particularly limited.
- a quinone compound used for the adduct of a tertiary phosphine and a quinone compound examples include o-benzoquinone, p-benzoquinone, diphenoquinone, 1,4-naphthoquinone, and anthraquinone. From the viewpoint of moisture resistance or storage stability, p-benzoquinone is preferred.
- the content rate of a hardening accelerator will not be specifically limited if it is the quantity by which a hardening acceleration effect is achieved, it is 0.00 with respect to 100 mass parts of total amounts of (A) epoxy resin and (B) hardening agent. 1 to 10 parts by mass is preferable, and 0.3 to 5 parts by mass is more preferable. When it is 0.1 part by mass or more, it can be cured in a shorter time. Moreover, when it is 10 mass parts or less, it will be suppressed that a cure rate becomes quick too much, and there exists a tendency for a better molded article to be obtained.
- the said epoxy resin molding material for sealing contains at least 1 sort (s) of an inorganic filler.
- s sort of an inorganic filler.
- the inorganic filler is not particularly limited as long as it is generally used for an epoxy resin molding material for sealing.
- powders such as titania, beads formed by spheroidizing these, and glass fibers. These may be used alone or in combination of two or more.
- fused silica is preferable from the viewpoint of reducing the linear expansion coefficient.
- Alumina is preferred from the viewpoint of high thermal conductivity.
- the shape of the inorganic filler is preferably spherical from the viewpoint of fluidity during molding and mold wear.
- spherical fused silica is particularly preferable from the viewpoint of a balance between cost and performance.
- the average particle diameter of the inorganic filler is not particularly limited. Among these, from the viewpoint of moldability, the thickness is preferably 5 ⁇ m to 50 ⁇ m, and more preferably 10 ⁇ m to 30 ⁇ m. In addition, the average particle diameter of an inorganic filler is measured as a volume average particle diameter using a laser diffraction scattering system particle size distribution measuring apparatus.
- the specific surface area of the inorganic filler is not particularly limited. Among these, from the viewpoint of moldability and strength, it is preferably 0.5 m 2 / g to 12 m 2 / g, and more preferably 1 m 2 / g to 5 m 2 / g. The specific surface area of the inorganic filler is measured from the nitrogen adsorption ability at 77K according to JIS Z 8830.
- the content of the inorganic filler is not particularly limited as long as the present invention is achieved.
- 70% by mass to 95% by mass in the epoxy resin molding material for sealing is preferable.
- 85% by mass to 95% by mass is more preferable.
- There exists a tendency for a flame retardance and reflow resistance to improve that the content rate of an inorganic filler is 70 mass% or more.
- the epoxy resin molding material for sealing contains the (E1) arylamino group as necessary from the viewpoint of improving the adhesion between the resin component and the inorganic component in the molding material.
- Other silane compounds other than the alkoxysilane compound and the (E2) epoxy group-containing alkoxysilane compound may be included.
- examples of other silane compounds include various silane compounds such as mercaptosilane, aminosilane, alkylsilane, ureidosilane, and vinylsilane.
- the silane compound which overlaps with (E1) arylamino group containing alkoxysilane compound and (E2) epoxy group containing alkoxysilane compound is excluded from other silane compounds.
- silane compounds include vinyltrichlorosilane, vinyltrimethoxysilane, vinyltriethoxysilane, vinyltris ( ⁇ -methoxyethoxy) silane, ⁇ -methacryloxypropyltrimethoxysilane, ⁇ -methacryloxypropyltriethoxysilane, ⁇ -Methacryloxypropylmethyldimethoxysilane, ⁇ -methacryloxypropylmethyldiethoxysilane, ⁇ -methacryloxypropyldimethylmethoxysilane, ⁇ -methacryloxypropyldimethylethoxysilane, ⁇ -acryloxypropyltrimethoxysilane, ⁇ -acryloxypropyl Silane compounds having an unsaturated bond such as triethoxysilane and vinyltriacetoxysilane; ⁇ -mercaptopropyltrimethoxysilane, ⁇ -mercaptopropyltriethoxy Silane-containing silane compounds such as
- the total content is preferably 0.06% by mass to 2% by mass in the sealing epoxy resin molding material from the viewpoint of moldability and adhesiveness. 0.1 mass% to 0.75 mass% is more preferable, and 0.2 mass% to 0.7 mass% is still more preferable. There exists a tendency for adhesiveness to improve more that the total content rate is 0.06 mass% or more. Moreover, there exists a tendency which can suppress generation
- the sealing epoxy resin molding material may contain a conventionally known coupling agent other than the silane compound from the viewpoint of improving the adhesion between the resin component and the inorganic component in the molding material.
- coupling agents include isopropyl triisostearoyl titanate, isopropyl tris (dioctyl pyrophosphate) titanate, isopropyl tri (N-aminoethyl-aminoethyl) titanate, tetraoctyl bis (ditridecyl phosphite) titanate, tetra (2, 2-diallyloxymethyl-1-butyl) bis (ditridecyl) phosphite titanate, bis (dioctylpyrophosphate) oxyacetate titanate, bis (dioctylpyrophosphate) ethylene titanate, isopropyltrioctanoyl titanate, isopropyldimethacrylisostearoy
- the total content rate is 0.06 mass% in the epoxy resin molding material for sealing from a moldability and an adhesive viewpoint. Is preferably 2% by mass, more preferably 0.1% by mass to 0.75% by mass, and even more preferably 0.2% by mass to 0.7% by mass is 0.06% by mass or more.
- adhesiveness to improve more.
- the epoxy resin molding material for sealing can contain an anion exchanger as required from the viewpoint of improving the moisture resistance and high temperature storage characteristics of the sealed element.
- an anion exchanger There is no restriction
- the content of the anion exchanger is not particularly limited as long as it is a sufficient amount to capture anions such as halogen ions.
- 0.1 to 30 parts by mass is preferable with respect to 100 parts by mass of (A) epoxy resin, and 1 to 5 parts by mass is more preferable.
- an adhesion promoter can be used as necessary from the viewpoint of further improving the adhesiveness.
- the adhesion promoter include derivatives such as imidazole, triazole, tetrazole and triazine, anthranilic acid, gallic acid, malonic acid, malic acid, maleic acid, aminophenol, quinoline and the like, and derivatives thereof, aliphatic acid amide compounds, Examples include dithiocarbamate and thiadiazole derivatives. These may be used alone or in combination of two or more.
- the sealing epoxy resin molding material may contain a release agent as necessary.
- a release agent for example, an oxidized or non-oxidized polyolefin is preferably contained in an amount of 0.01 to 10 parts by weight, and 0.1 to 5 parts by weight with respect to 100 parts by weight of the epoxy resin (A). More preferably. There exists a tendency for favorable mold release property to be acquired as it is 0.01 mass part or more. Moreover, there exists a tendency for adhesiveness to improve that it is 10 mass parts or less.
- the oxidized or non-oxidized polyolefin include low molecular weight polyethylene having a number average molecular weight of about 500 to 10,000, such as the trade name H4, PE, and PED series manufactured by Hoechst Corporation.
- release agents other than the oxidized or non-oxidized polyolefin for example, carnauba wax, montanic acid ester, montanic acid, and stearic acid can be mentioned. These may be used alone or in combination of two or more.
- the total content of the release agent is 0.1 to 10 parts by mass with respect to 100 parts by mass of (A) epoxy resin. Part is preferable, and 0.5 part by weight to 3 parts by weight is more preferable.
- the sealing epoxy resin molding material may contain a conventionally known flame retardant as required from the viewpoint of improving the flame retardancy of the molding material.
- the flame retardant include brominated epoxy resin, antimony trioxide, red phosphorus, aluminum hydroxide, magnesium hydroxide, zinc oxide, and other inorganic substances and / or red phosphorus coated with a thermosetting resin such as a phenol resin, Phosphorus compounds such as phosphate esters, melamine, melamine derivatives, melamine-modified phenol resins, compounds having a triazine ring, nitrogen-containing compounds such as cyanuric acid derivatives and isocyanuric acid derivatives, phosphorus and nitrogen-containing compounds such as cyclophosphazene, aluminum hydroxide , Compounds containing metal elements such as magnesium hydroxide, zinc oxide, zinc stannate, zinc borate, iron oxide, molybdenum oxide, zinc molybdate, dicyclopentadienyl iron, and a composite metal represented by the following
- M 1 and M 2 represent different metal elements, and a, b, c, d, p, q, and m represent positive numbers.
- M 1 and M 2 in the composition formula (XXXXIV) are not particularly limited as long as they are different metal elements.
- M 1 is selected from metal elements belonging to the third period metal element, group IIA alkaline earth metal element, group IVB, group IIB, group VIII, group IB, group IIIA and group IVA
- M 2 is preferably selected from Group IIIB to IIB transition metal elements
- M 1 is selected from magnesium, calcium, aluminum, tin, titanium, iron, cobalt, nickel, copper and zinc
- M 2 is iron. More preferably, it is selected from cobalt, nickel, copper and zinc.
- M 1 is magnesium and M 2 is zinc or nickel.
- the molar ratio of p and q is not particularly limited. It is preferable that p / q is 1/99 to 1/1.
- A, b, c and d are appropriately selected according to M 1 and M 2 .
- the metal element is classified into a long-period periodic table in which the typical element is the A group and the transition element is the B group (Source: Kyoritsu Shuppan Co., Ltd., “Chemical Dictionary 4”, February 15, 1987). (Reduced plate 30th printing).
- Examples of the flame retardant include compounds containing metal elements such as zinc oxide, zinc stannate, zinc borate, iron oxide, molybdenum oxide, zinc molybdate, and dicyclopentadienyl iron. These flame retardants may be used alone or in combination of two or more.
- the content of the flame retardant is not particularly limited. Among them, (A) 1 part by mass to 30 parts by mass is preferable with respect to 100 parts by mass of the epoxy resin, and 2 parts by mass to 15 parts by mass are more preferable.
- the sealing epoxy resin molding material may contain a colorant such as carbon black, organic dye, organic pigment, titanium oxide, red lead, bengara and the like.
- a colorant such as carbon black, organic dye, organic pigment, titanium oxide, red lead, bengara and the like.
- other additives include polyphenylene ether, thermoplastic resins such as indene oligomers which are copolymer resins of indenes such as indene and alkylindene, and styrenes and phenols such as styrene and alkylstyrene, and silicone oil.
- a stress relaxation agent such as silicone rubber powder can be included as necessary.
- the sealing epoxy resin molding material of the present invention can be prepared by any method as long as various components can be uniformly dispersed and mixed.
- a general method there can be mentioned a method in which components of a predetermined blending amount are sufficiently mixed by a mixer or the like, then melt-kneaded by a mixing roll, an extruder or the like, and then cooled and pulverized.
- a predetermined amount of the above-mentioned components can be obtained by a method of uniformly stirring and mixing, kneading with a kneader, roll, extruder, or the like that has been heated to 70 ° C. to 140 ° C., cooling, and pulverizing. . It is easy to use if it is tableted with dimensions and mass that match the molding conditions.
- the electronic component device of the present invention includes an element sealed with the sealing epoxy resin molding material, and includes other components as necessary.
- a semiconductor chip is mounted on a support member such as a lead frame, a wired tape carrier, a wiring board, glass, or a silicon wafer.
- Electronic component devices, etc. in which active elements such as transistors, diodes, thyristors, etc., passive elements such as capacitors, resistors, coils, etc. are mounted and necessary parts are sealed with the above-mentioned epoxy resin molding material for sealing, etc. Can be mentioned.
- the sealing epoxy resin molding material DIP Device Inline Package
- PLCC Physical Leaded Chip Carrier
- QFP Quad Flat Package
- SOP Small Outline Package
- SOJ Small Outline J-lead package
- TSOP Thin Small Outline Package
- TQFP Thin Quad Flat Package
- other general resin-sealed ICs and semiconductor chips connected to tape carriers by bumps are sealed with the above-mentioned epoxy resin molding material for sealing TCP (Tape Carrier Package), wiring formed on wiring boards and glass, wire bonding, flip chip bonding, soldering
- a COB Chip On Board
- active elements such as semiconductor chips, transistors, diodes, thyristors and / or passive elements such as capacitors, resistors, coils, etc.
- the low pressure transfer molding method is the most common, but an injection molding method, a compression molding method, or the like may be used.
- the conditions for sealing the element can be appropriately selected according to the configuration of the sealing epoxy resin molding material.
- Epoxy resin 1 Ortho-cresol novolac type epoxy resin having an epoxy equivalent of 200 and a softening point of 67 ° C. (trade name ESCN-190, manufactured by Sumitomo Chemical Co., Ltd.)
- Epoxy resin 2 biphenyl type epoxy resin having an epoxy equivalent of 196 and a melting point of 106 ° C. (trade name YX-4000H manufactured by Japan Epoxy Resin Co., Ltd.)
- Epoxy resin 3 thiodiphenol type epoxy resin having an epoxy equivalent of 242 and a melting point of 118 ° C.
- Epoxy resin 4 Phenolic aralkyl epoxy resin containing biphenylene skeleton having an epoxy equivalent of 241 and a softening point of 96 ° C. (trade name CER-3000L manufactured by Nippon Kayaku Co., Ltd.)
- Epoxy resin 5 Epoxy product of phenol aralkyl resin having an epoxy equivalent of 238 and a softening point of 52 ° C.
- Epoxy resin 6 Epoxy equivalent 375, softening point 80 ° C., bromine content 48 mass% bisphenol A type brominated epoxy resin
- Epoxy resin 7 Epoxy equivalent 251, represented by the general formula (XXXXV) having a softening point of 60 degrees
- Epoxy resin (trade name HP-5000, manufactured by DIC Corporation)
- Curing agent 1 Phenol aralkyl resin having a hydroxyl group equivalent of 199 and a softening point of 89 ° C. (trade name MEH-7851 manufactured by Meiwa Kasei Co., Ltd.)
- Curing agent 2 Phenol aralkyl resin having a hydroxyl group equivalent of 176 and a softening point of 70 ° C. (trade name: Millex XLC, manufactured by Mitsui Chemicals, Inc.)
- Curing agent 3 novolak-type phenolic resin having a hydroxyl group equivalent of 106 and a softening point of 64 ° C. (trade name H-4, manufactured by Meiwa Kasei Co., Ltd.)
- Curing accelerator 1 Betaine-type adduct of triphenylphosphine and p-benzoquinone
- Curing accelerator 2 Betaine-type adduct of tributylphosphine and p-benzoquinone
- D As an inorganic filler, the average particle size is 17 Spherical fused silica having a specific surface area of 3.8 m 2 / g was used.
- (E1) As the arylamino group-containing alkoxysilane compound, ⁇ -anilinopropyltrimethoxysilane ((E1) silane compound 1) was used.
- (E2) As the epoxy group-containing alkoxysilane compound, the following was used.
- ⁇ -aminopropyltrimethoxysilane (other silane compound 1) was used as a silane compound other than the components (E1) and (E2).
- carnauba wax manufactured by Clariant Japan Co., Ltd.
- antimony trioxide and carbon black (manufactured by Mitsubishi Chemical Corporation) were used.
- the epoxy resin molding material for sealing is molded into a disk having a diameter of 50 mm and a thickness of 3 mm under the above conditions, and immediately after molding, a Shore D hardness meter (HD-1120 (type D )).
- Reflow resistance 80 mm flat package (QFP) with external dimensions of 20 mm x 14 mm x 2 mm with 8 mm x 10 mm x 0.4 mm silicon chip (Lead frame material: copper alloy, die pad top surface and lead tip silver plating Processed product) was molded under the above conditions using an epoxy resin molding material for sealing and post-cured.
- the resulting package is humidified for 168 hours under conditions of 85 ° C. and 85% RH, and then subjected to a reflow treatment at a predetermined temperature (235 ° C., 245 ° C., 255 ° C.) for 10 seconds to check for cracks outside the package.
- a predetermined temperature 235 ° C., 245 ° C., 255 ° C.
- Comparative Examples 1 to 13 in which the compounds of the components (E1) and (E2) are not used in combination are inferior in terms of fluidity and reflow resistance. Comparative Examples 3, 5, 8, and 11 using the compound (E1) alone are inferior in reflow resistance, and Comparative Examples 1, 2, 4, 6, 7, and 11 using the compound (E2) alone, 9, 10, 12, 14 are inferior in fluidity and reflow resistance.
- Comparative Example 13 in which an amino group-containing silane compound having a structure different from that of the component (E1) is blended significantly reduces fluidity and reflow resistance, and is inferior in flame retardancy, achieving UL-94 V-0. Not done.
- Examples 1 to 24 the compounds (E1) and (E2) are used in combination, and the composition of the silane compounds other than the components (E1) and (E2) is partially different. Compared with comparative examples having the same resin composition, reflow resistance is good, moldability such as fluidity and heat hardness is good, all achieve UL-94 V-0, and good flame retardancy.
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Abstract
Description
特定構造のアミノ基含有シラン化合物と、エポキシ基含有シラン化合物とを含むことで、耐リフロー性及び成形性に優れる。
本発明の封止用エポキシ樹脂成形材料は、(E1)アリールアミノ基含有アルコキシシラン化合物を含有する。
一般に、(E2)エポキシ基含有アルコキシシラン化合物は、アミノ基によって反応してしまうことから、エポキシ基含有アルコキシシラン化合にアミノ基含有化合物を併用することは考え難い。しかしながら、本発明において、(E1)アリールアミノ基含有アルコキシシラン化合物を用いると、(E2)エポキシ基含有アルコキシシラン化合物と混合した場合であっても、その混合物の保存安定性の低下が抑えられ、混合物の粘度の上昇やゲル化が抑制される。そして、(E1)アリールアミノ基含有アルコキシシラン化合物、及び(E2)エポキシ基含有アルコキシシラン化合物のそれぞれの機能が発揮され、耐リフロー性及び成形性に優れる封止用エポキシ樹脂成形材料となる。
これら(E1)アリールアミノ基含有アルコキシシラン化合物は、1種を単独で用いても2種以上を組み合わせて用いてもよい。
本発明の封止用エポキシ樹脂成形材料は、(E2)エポキシ基含有アルコキシシラン化合物を含有する。
本発明における、エポキシ基含有アルコキシシラン化合物は、エポキシ基を有するアルコキシシランシラン化合物であれば、その構造は特に制限されない。例えば、本発明で用いられる(E2)エポキシ基含有アルコキシシラン化合物は、下記一般式(II)および(III)で示される化合物の少なくとも1種であることが好ましい。
これら(E2)エポキシ基含有アルコキシシラン化合物は、1種を単独で用いても2種以上を組み合わせて用いてもよい。2種以上の(E2)エポキシ基含有アルコキシシラン化合物を用いる場合、上記一般式(II)で示される化合物のみ又は上記一般式(III)で示される化合物のみであってもよく、または上記一般式(II)で示される化合物及び上記一般式(III)で示される化合物を併用してもよい。
更にこの範囲の中でも、E1含有率が高いほど、吸水率が低減するとともに難燃性に優れる傾向にある。またE1含有率が10質量%以上80質量%以下であると、耐リフロー性、成形性及び難燃性を同時にかつ十分に向上することができる。
更にこの範囲の中でも、「E1+E2含有率」が高いほど流動性に優れる傾向にある。
本発明において用いられるエポキシ樹脂は、封止用エポキシ樹脂成形材料に一般的に使用されているものであれば、特に制限はない。中でも1分子中にエポキシ基を2個以上含有するものであることが好ましい。具体的には、フェノールノボラック型エポキシ樹脂、オルトクレゾールノボラック型エポキシ樹脂、トリフェニルメタン骨格を有するエポキシ樹脂をはじめとするフェノール、クレゾール、キシレノール、レゾルシン、カテコール、ビスフェノールA、ビスフェノールF等のフェノール類及びα-ナフトール、β-ナフトール、ジヒドロキシナフタレン等のナフトール類からなる群より選ばれる少なくとも1種と、ホルムアルデヒド、アセトアルデヒド、プロピオンアルデヒド、ベンズアルデヒド、サリチルアルデヒド等のアルデヒド基を有する化合物とを酸性触媒下で縮合又は共縮合させて得られるノボラック樹脂をエポキシ化したノボラック型エポキシ樹脂;アルキル置換、芳香環置換又は非置換のビスフェノールA、ビスフェノールF、ビスフェノールS、ビフェノール、チオジフェノール等のジグリシジルエーテルであるエポキシ樹脂;スチルベン型エポキシ樹脂;ハイドロキノン型エポキシ樹脂;フタル酸、ダイマー酸等の多塩基酸とエピクロルヒドリンの反応により得られるグリシジルエステル型エポキシ樹脂;ジアミノジフェニルメタン、イソシアヌル酸等のポリアミンとエピクロルヒドリンの反応により得られるグリシジルアミン型エポキシ樹脂;ジシクロペンタジエンとフェノール類の共縮合樹脂をエポキシ化したジシクロペンタジエン型エポキシ樹脂;ナフタレン環を有するエポキシ樹脂;フェノール類及びナフトール類の少なくとも1種とジメトキシパラキシレン又はビス(メトキシメチル)ビフェニルから合成されるフェノール・アラルキル樹脂;ナフトール・アラルキル樹脂等のアラルキル型フェノール樹脂のエポキシ化物;トリメチロールプロパン型エポキシ樹脂;テルペン変性エポキシ樹脂;オレフィン結合を過酢酸等の過酸で酸化して得られる線状脂肪族エポキシ樹脂;脂環族エポキシ樹脂などが挙げられる。これらは1種を単独で用いても2種以上を組み合わせて用いてもよい。
一般式(IV)中のR1~R8として具体的には、水素原子;メチル基、エチル基、プロピル基、ブチル基、イソプロピル基、イソブチル基、tert-ブチル基等の炭素数1~10のアルキル基;ビニル基、アリル基、ブテニル基等の炭素数1~10のアルケニル基;メトキシ基、エトキシ基等の炭素数1~10のアルコキシ基;などが挙げられる。なかでも水素原子又はメチル基が好ましい。
そのようなエポキシ樹脂としては市販品として三菱化学社製商品名YX-4000、YL-6121Hとして入手可能である。
一般式(V)中のR1~R8として具体的には、水素原子;メチル基、エチル基、プロピル基、ブチル基、イソプロピル基、イソブチル基、tert-ブチル基等の炭素数1~10のアルキル基;ビニル基、アリル基、ブテニル基等の炭素数1~10のアルケニル基;メトキシ基、エトキシ基等の炭素数1~10アルコキシ基;などが挙げられる。なかでも水素原子、メチル基又はtert-ブチル基が好ましい。
一般式(VI)中のR1~R8として具体的には、水素原子;メチル基、エチル基、プロピル基、ブチル基、イソプロピル基、イソブチル基、tert-ブチル基等の炭素数1~10のアルキル基;ビニル基、アリル基、ブテニル基等の炭素数1~10のアルケニル基;メトキシ基、エトキシ基等の炭素数1~10のアルコキシ基;などが挙げられる。なかでも水素原子又はメチル基が好ましい。
なかでも、前記一般式(VII)中のRとしては、水素原子;メチル基、エチル基、プロピル基、ブチル基、イソプロピル基、イソブチル基等の炭素数1~10のアルキル基;メトキシ基、エトキシ基、プロポキシ基、ブトキシ基等の炭素数1~10のアルコキシ基;が好ましく、水素原子又はメチル基がより好ましい。
nは0~3の整数が好ましい。
また一般式(X)中のnとしては平均で6以下がより好ましい。
そのようなエポキシ樹脂としては、市販品として日本化薬株式会社製商品名NC-3000Sとして入手可能である。
nは0又は1~10の整数を示し、平均で6以下がより好ましい。
また前記エポキシ樹脂の軟化点又は融点は特に制限されない。なかでも成形性、耐リフロー性の観点から、40℃~180℃であることが好ましく、封止用エポキシ樹脂成型材料作製時における取扱い性の観点からは50℃~130℃であることがより好ましい。
前記封止用エポキシ樹脂成形材料は、硬化剤の少なくとも1種を含む。前記硬化剤は、封止用エポキシ樹脂成形材料に一般に使用されているものであれば特に制限はない。たとえば、フェノール、クレゾール、レゾルシン、カテコール、ビスフェノールA、ビスフェノールF、フェニルフェノール、チオジフェノール、アミノフェノール等のフェノール類及びα-ナフトール、β-ナフトール、ジヒドロキシナフタレン等のナフトール類からなる群より選択される少なくとも1種と、ホルムアルデヒド、ベンズアルデヒド、サリチルアルデヒド等のアルデヒド基を有する化合物とを酸性触媒下で縮合又は共縮合させて得られるノボラック型フェノール樹脂;フェノール類及びナフトール類からなる群より選択される少なくとも1種と、ジメトキシパラキシレン又はビス(メトキシメチル)ビフェニルとから合成されるフェノール・アラルキル樹脂;ナフトール・アラルキル樹脂等のアラルキル型フェノール樹脂;フェノール・ノボラック構造とフェノール・アラルキル構造とがランダム、ブロック又は交互に繰り返された共重合型フェノール・アラルキル樹脂;パラキシリレン変性フェノール樹脂;メタキシリレン変性フェノール樹脂;メラミン変性フェノール樹脂;テルペン変性フェノール樹脂;ジシクロペンタジエン変性フェノール樹脂;シクロペンタジエン変性フェノール樹脂;多環芳香環変性フェノール樹脂が挙げられる。これらは1種を単独で用いても2種以上を組み合わせて用いてもよい。
下記一般式(XXXVI)及び一般式(XXXVII)中、nは0~10の整数を示し、平均で6以下が好ましい。
前記重合物の軟化点が60℃以上であると、成形時の染み出しが抑制され成形性が向上する傾向にある。また150℃以下であると、エポキシ樹脂及び硬化剤との相溶性が向上する傾向にある。
これら脂肪族オレフィンの使用量は、フェノール・アラルキル樹脂及びナフトール・アラルキル樹脂との予備混合に供される重合モノマー全量中20質量%以下が好ましく、9質量%以下がより好ましい。
前記の方法により予備混合物(アセナフチレン変性硬化剤)が、製造される。溶融混合は、硬化剤及びアセナフチレンの少なくとも一方の軟化点以上の温度であれば制限はない。中でも100℃~250℃が好ましく、120℃~200℃がより好ましい。また、溶融混合は両者が均一に混合すれば混合時間に制限はないが、中でも1時間~20時間が好ましく、2時間~15時間がより好ましい。硬化剤とアセナフチレンを予備混合する場合、混合中にアセナフチレンが重合もしくは硬化剤と反応しても構わない。
R1が水素原子であり、mが0である前記ジシクロペンタジエン型フェノール樹脂としてはDPP(新日本石油化学株式会社製商品名)等が市販品として入手可能である。
またnの平均値は0~8であることが好ましい。
上記一般式(XXXXII)で示されるノボラック型フェノール樹脂としては、明和化成株式会社製商品名:H-4が市販品として入手可能である。
また前記硬化剤の軟化点又は融点は特に制限されない。なかでも成形性と耐リフロー性の観点から、40℃~180℃であることが好ましく、封止用エポキシ樹脂成型材料作製時における取扱い性の観点からは50℃~130℃であることがより好ましい。
前記封止用エポキシ樹脂成形材料は硬化促進剤の少なくとも1種を含む。硬化促進剤としては、封止用エポキシ樹脂成形材料で一般に使用されているものであれば特に限定はない。例えば、1,8-ジアザビシクロ[5.4.0]ウンデセン-7、1,5-ジアザビシクロ[4.3.0]ノネン-5、5,6-ジブチルアミノ-1,8-ジアザビシクロ[5.4.0]ウンデセン-7等のシクロアミジン化合物;これらのシクロアミジン化合物に無水マレイン酸、1,4-ベンゾキノン、2,5-トルキノン、1,4-ナフトキノン、2,3-ジメチルベンゾキノン、2,6-ジメチルベンゾキノン、2,3-ジメトキシ-5-メチル-1,4ベンゾキノン、2,3-ジメトキシ-1,4-ベンゾキノン、フェニル-1,4-ベンゾキノン等のキノン化合物、ジアゾフェニルメタン、フェノール樹脂等のπ結合をもつ化合物を付加してなる分子内分極を有する化合物;ベンジルジメチルアミン、トリエタノールアミン、ジメチルアミノエタノール、トリス(ジメチルアミノメチル)フェノール等の第三級アミン化合物;これらの第三級アミン化合物の誘導体、2-メチルイミダゾール、2-フェニルイミダゾール、2-フェニル-4-メチルイミダゾール、2-ヘプタデシルイミダゾール等のイミダゾール化合物;これらのイミダゾール化合物の誘導体、トリブチルホスフィン、メチルジフェニルホスフィン、トリフェニルホスフィン、トリス(4-メチルフェニル)ホスフィン、ジフェニルホスフィン、フェニルホスフィン等の有機ホスフィン化合物;これらの有機ホスフィン化合物に無水マレイン酸、上記キノン化合物、ジアゾフェニルメタン、フェノール樹脂等のπ結合をもつ化合物を付加してなる分子内分極を有するリン化合物;テトラフェニルホスホニウムテトラフェニルボレート、テトラフェニルホスホニウムエチルトリフェニルボレート、テトラブチルホスホニウムテトラブチルボレート等のテトラ置換ホスホニウム・テトラ置換ボレート;2-エチル-4-メチルイミダゾール・テトラフェニルボレート、N-メチルモルホリン・テトラフェニルボレート等のテトラフェニルボロン塩;これらのテトラ置換ホスホニウム・テトラ置換ボレート及びテトラフェニルボロン塩の誘導体などが挙げられる。これらは1種を単独で用いても2種以上組み合わせて用いてもよい。
これらの特定硬化促進剤の含有率は、硬化促進剤全量中に、合わせて60質量%以上とすることが好ましく、80質量%以上がより好ましい。
前記封止用エポキシ樹脂成形材料は無機充てん剤の少なくとも1種を含む。前記無機充てん剤を含むことで、吸湿性抑制、線膨張係数低減、熱伝導性向上及び強度向上がより効果的に達成される。前記無機充てん剤は、封止用エポキシ樹脂成形材料に一般に使用されているものであれば特に制限されるものではない。例えば、溶融シリカ、結晶シリカ、アルミナ、ジルコン、珪酸カルシウム、炭酸カルシウム、チタン酸カリウム、炭化珪素、窒化珪素、窒化アルミ、窒化ホウ素、ベリリア、ジルコニア、ジルコン、フォステライト、ステアタイト、スピネル、ムライト、チタニア等の粉体、又はこれらを球形化したビーズ、ガラス繊維が挙げられる。これらは1種を単独で用いても2種以上を組み合わせて用いてもよい。なかでも、線膨張係数低減の観点からは溶融シリカが好ましい。また高熱伝導性の観点からはアルミナが好ましい。一方、無機充てん剤形状は、成形時の流動性及び金型摩耗性の点から球形が好ましい。
前記無機充てん剤としては、特にコストと性能のバランスの観点からは球状溶融シリカが好ましい。
また前記無機充てん剤の比表面積は特に制限されない。なかでも成形性と強度の観点から、0.5m2/g~12m2/gであることが好ましく、1m2/g~5m2/gであることがより好ましい。なお、無機充てん剤の比表面積は、比表面積は、JIS Z 8830に準じて77Kでの窒素吸着能から測定される。
前記封止用エポキシ樹脂成形材料は、成形材料中の樹脂成分と無機成分との接着性の向上等の観点から、必要に応じて、前記(E1)アリールアミノ基含有アルコキシシラン化合物及び(E2)エポキシ基含有アルコキシシラン化合物以外のその他のシラン化合物を含むことができる。その他のシラン化合物としては、メルカプトシラン、アミノシラン、アルキルシラン、ウレイドシラン、ビニルシラン等の各種シラン系化合物を挙げることができる。なお、その他のシラン化合物からは、(E1)アリールアミノ基含有アルコキシシラン化合物及び(E2)エポキシ基含有アルコキシシラン化合物と重複するシラン系化合物は除かれる。
また前記封止用エポキシ樹脂成形材料がシラン化合物以外のカップリング剤を含有する場合、その全含有率は、成形性及び接着性の観点から、封止用エポキシ樹脂成形材料中0.06質量%~2質量%が好ましく、0.1質量%~0.75質量%がより好ましく、0.2質量%~0.7質量%がさらに好ましい全含有率が0.06質量%以上であると、接着性がより向上する傾向がある。また2質量%以下であると、ボイド等の成形不良の発生を抑制できる傾向がある。
式(XXXXIII)中、0<X≦0.5を満たす数であり、mは正の数を示す。
酸化型又は非酸化型のポリオレフィンとしては、ヘキスト株式会社製商品名H4やPE、PEDシリーズ等の数平均分子量が500~10000程度の低分子量ポリエチレンなどが挙げられる。
式(XXXXIV)において、M1及びM2は互いに異なる金属元素を示し、a、b、c、d、p、q及びmは正の数を示す。
なお、金属元素の分類は、典型元素をA亜族、遷移元素をB亜族とする長周期型の周期律表(出典:共立出版株式会社発行「化学大辞典4」1987年2月15日縮刷版第30刷)に基づいて行った。
本発明の封止用エポキシ樹脂成形材料は、各種成分を均一に分散混合できるのであれば、いかなる手法を用いても調製できる。一般的な手法として、所定の配合量の成分をミキサー等によって十分混合した後、ミキシングロール、押出機等によって溶融混練した後、冷却、粉砕する方法を挙げることができる。たとえば、上述した成分の所定量を均一に撹拌、混合し、予め70℃~140℃に加熱してあるニーダー、ロール、エクストルーダーなどで混練、冷却し、粉砕するなどの方法で得ることができる。成形条件に合うような寸法及び質量でタブレット化すると使いやすい。
本発明の電子部品装置は、前記封止用エポキシ樹脂成形材料により封止した素子を備え、必要に応じてその他の構成要素を含んで構成される。
前記封止用エポキシ樹脂成形材料により封止した素子を備えた電子部品装置としては具体的には、リードフレーム、配線済みのテープキャリア、配線板、ガラス、シリコンウエハ等の支持部材に、半導体チップ、トランジスタ、ダイオード、サイリスタ等の能動素子、コンデンサ、抵抗体、コイル等の受動素子等の素子を搭載し、必要な部分を前記封止用エポキシ樹脂成形材料で封止した、電子部品装置などが挙げられる。このような電子部品装置としては、たとえば、リードフレーム上に半導体素子を固定し、ボンディングパッド等の素子の端子部とリード部をワイヤボンディングやバンプで接続した後、前記封止用エポキシ樹脂成形材料を用いてトランスファ成形等により封止してなる、DIP(Dual Inline Package)、PLCC(Plastic Leaded Chip Carrier)、QFP(Quad Flat Package)、SOP(Small Outline Package)、SOJ(Small Outline J-lead package)、TSOP(Thin Small Outline Package)、TQFP(Thin Quad Flat Package)等の一般的な樹脂封止型IC、テープキャリアにバンプで接続した半導体チップを、前記封止用エポキシ樹脂成形材料で封止したTCP(Tape Carrier Package)、配線板やガラス上に形成した配線に、ワイヤボンディング、フリップチップボンディング、はんだ等で接続した半導体チップ、トランジスタ、ダイオード、サイリスタ等の能動素子及び/又はコンデンサ、抵抗体、コイル等の受動素子を、前記封止用エポキシ樹脂成形材料で封止したCOB(Chip On Board)モジュール、ハイブリッドIC、マルチチップモジュール、裏面に配線板接続用の端子を形成した有機基板の表面に素子を搭載し、バンプ又はワイヤボンディングにより素子と有機基板に形成された配線を接続した後、前記封止用エポキシ樹脂成形材料で素子を封止したBGA(Ball Grid Array)、CSP(Chip Size Package)などが挙げられる。また、プリント回路板にも前記封止用エポキシ樹脂成形材料は有効に使用できる。
本明細書に記載された全ての文献、特許出願、および技術規格は、個々の文献、特許出願、および技術規格が参照により取り込まれることが具体的かつ個々に記された場合と同程度に、本明細書中に参照により取り込まれる。
(実施例1~24、比較例1~14)
以下の成分をそれぞれ下記表1~表6に示す質量部で配合し、混練温度80℃、混練時間10分の条件でロール混練を行い、実施例1~24及び比較例1~14の封止用エポキシ樹脂成形材料をそれぞれ作製した。なお表中の空欄は無配合を表す。
・エポキシ樹脂1:エポキシ当量200、軟化点67℃のオルソクレゾールノボラック型エポキシ樹脂(住友化学工業株式会社製商品名ESCN-190)
・エポキシ樹脂2:エポキシ当量196、融点106℃のビフェニル型エポキシ樹脂(ジャパンエポキシレジン株式会社製商品名YX-4000H)
・エポキシ樹脂3:エポキシ当量242、融点118℃のチオジフェノール型エポキシ樹脂(新日鐵化学株式会社製商品名YSLV-120TE)
・エポキシ樹脂4:エポキシ当量241、軟化点96℃のビフェニレン骨格含有フェノール・アラルキル型エポキシ樹脂(日本化薬株式会社製商品名CER-3000L)
・エポキシ樹脂5:エポキシ当量238、軟化点52℃のフェノール・アラルキル樹脂のエポキシ化物(日本化薬株式会社製商品名NC-2000L)
・エポキシ樹脂6:エポキシ当量375、軟化点80℃、臭素含有量48質量%のビスフェノールA型ブロム化エポキシ樹脂
・エポキシ樹脂7:エポキシ当量251、軟化点60度の一般式(XXXXV)で表されるエポキシ樹脂(DIC株式会社製商品名HP-5000)
・硬化剤1:水酸基当量199、軟化点89℃のフェノール・アラルキル樹脂(明和化成株式会社製商品名MEH-7851)
・硬化剤2:水酸基当量176、軟化点70℃のフェノール・アラルキル樹脂(三井化学株式会社製商品名ミレックスXLC)
・硬化剤3:水酸基当量106、軟化点64℃のノボラック型フェノール樹脂(明和化成株式会社製商品名H-4)
・硬化促進剤1:トリフェニルホスフィンとp-ベンゾキノンとのベタイン型付加物
・硬化促進剤2:トリブチルホスフィンとp-ベンゾキノンとのベタイン型付加物
(D)無機充てん剤としては、平均粒径17.5μm、比表面積3.8m2/gの球状溶融シリカ使用した。
(E2)エポキシ基含有アルコキシシラン化合物としては、以下を使用した。
・(E2)シラン化合物1:γ-グリシドキシプロピルトリメトキシシラン
・(E2)シラン化合物2:β-(3,4-エポキシシクロヘキシル)エチルトリメトキシシラン
実施例1~24及び比較例1~14で作製した封止用エポキシ樹脂成形材料の特性を、次の(1)~(6)の各特性試験により評価した。評価結果を下記表1~表6に示した。なお、封止用エポキシ樹脂成形材料の成形は、明記しない限りトランスファ成形機により、金型温度180℃、成形圧力6.9MPa、硬化時間90秒で成形した。また、必要に応じて後硬化を180℃で5時間の条件で行った。
EMMI-1-66に準じたスパイラルフロー測定用金型を用いて、封止用エポキシ成形材料を上記条件で成形し、流動距離(cm)を求めた。
封止用エポキシ樹脂成形材料を上記条件で直径50mm×厚さ3mmの円板に成形し、成形後直ちにショアD型硬度計(株式会社上島製作所製HD-1120(タイプD))を用いて測定した。
封止用エポキシ樹脂成形材料を上記条件で10mm×70mm×3mmに成形、後硬化して試験片を作製した。得られた試験片を株式会社エー・アンド・デイ製テンシロンを用い、JIS-K-6911に準拠した3点支持型曲げ試験を260℃の恒温槽内で行い、260℃での曲げ弾性率(MPa)を求めた。
上記(2)で成形した円板を上記条件で後硬化した。得られた円板を85℃、60%RHの条件下で168時間放置し、放置前後の質量変化を測定して、吸水率(質量%)=(放置後の円板質量-放置前の円板質量)/放置前の円板質量×100で評価した。
8mm×10mm×0.4mmのシリコンチップを搭載した外形寸法20mm×14mm×2mmの80ピンフラットパッケージ(QFP)(リードフレーム材質:銅合金、ダイパッド部上面およびリード先端銀メッキ処理品)を、封止用エポキシ樹脂成形材料を用いて上記条件で成形、後硬化して作製した。得られたパッケージを85℃、85%RHの条件で168時間加湿した後、所定温度(235℃、245℃、255℃)、10秒の条件でリフロー処理をそれぞれ行い、パッケージ外部のクラックの有無を目視で、パッケージ内部の剥離発生の有無を超音波探傷装置(日立建機株式会社製HYE-FOCUS)でそれぞれ観察し、試験パッケージ数(10)に対する、クラック及び剥離のいずれかが発生したパッケージ数の総和で評価した。
厚さ1/16インチ(約1.6mm)の試験片を成形する金型を用いて、封止用エポキシ樹脂成形材料を上記条件で成形して後硬化を行って作製した。得られた試験片をUL-94試験法に従って難燃性を評価した。
Claims (6)
- (A)エポキシ樹脂と、(B)硬化剤と、(C)硬化促進剤と、(D)無機充てん剤と、(E1)アリールアミノ基含有アルコキシシラン化合物と、(E2)エポキシ基含有アルコキシシラン化合物と、を含有する封止用エポキシ樹脂成形材料。
- 封止用エポキシ樹脂成形材料中の前記(E1)アリールアミノ基含有アルコキシシラン化合物の合計量が、封止用エポキシ樹脂成形材料中の前記(E1)アリールアミノ基含有アルコキシシラン化合物及び前記(E2)エポキシ基含有アルコキシシラン化合物の合計量に対して、10質量%以上80質量%以下である請求項1~請求項3のいずれか1項に記載の封止用エポキシ樹脂成形材料。
- 封止用エポキシ樹脂成形材料中の前記(E1)アリールアミノ基含有アルコキシシラン化合物及び前記(E2)エポキシ基含有アルコキシシラン化合物の合計量が、封止用エポキシ樹脂成形材料中の前記(A)エポキシ樹脂の合計量に対して2質量%以上15質量%以下である請求項1~請求項4のいずれか1項に記載の封止用エポキシ樹脂成形材料。
- 請求項1~請求項5のいずれか1項に記載の封止用エポキシ樹脂成形材料により封止された素子を備える電子部品装置。
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KR1020187025941A KR20180104168A (ko) | 2011-05-13 | 2012-05-10 | 밀봉용 에폭시 수지 성형 재료 및 전자 부품 장치 |
KR1020137032049A KR101899186B1 (ko) | 2011-05-13 | 2012-05-10 | 밀봉용 에폭시 수지 성형 재료 및 전자 부품 장치 |
CN201280023016.3A CN103517948A (zh) | 2011-05-13 | 2012-05-10 | 密封用环氧树脂成形材料及电子部件装置 |
JP2013515110A JPWO2012157529A1 (ja) | 2011-05-13 | 2012-05-10 | 封止用エポキシ樹脂成形材料及び電子部品装置 |
US14/116,979 US20140128505A1 (en) | 2011-05-13 | 2012-05-10 | Epoxy resin molding material for sealing and electronic component device |
US15/404,224 US10662315B2 (en) | 2011-05-13 | 2017-01-12 | Epoxy resin molding material for sealing and electronic component device |
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US14/116,979 A-371-Of-International US20140128505A1 (en) | 2011-05-13 | 2012-05-10 | Epoxy resin molding material for sealing and electronic component device |
US15/404,224 Continuation US10662315B2 (en) | 2011-05-13 | 2017-01-12 | Epoxy resin molding material for sealing and electronic component device |
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JP (4) | JPWO2012157529A1 (ja) |
KR (2) | KR101899186B1 (ja) |
CN (3) | CN109971122A (ja) |
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JP2018024857A (ja) * | 2016-07-29 | 2018-02-15 | 日本化薬株式会社 | (メタ)アリルエーテル樹脂、エポキシ樹脂、硬化性樹脂組成物及びその硬化物 |
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Also Published As
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KR20180104168A (ko) | 2018-09-19 |
JP6478953B2 (ja) | 2019-03-06 |
JP2016084480A (ja) | 2016-05-19 |
JP2016199769A (ja) | 2016-12-01 |
TW201938680A (zh) | 2019-10-01 |
TWI670319B (zh) | 2019-09-01 |
JP6753378B2 (ja) | 2020-09-09 |
TWI647275B (zh) | 2019-01-11 |
CN103517948A (zh) | 2014-01-15 |
CN105440582A (zh) | 2016-03-30 |
JPWO2012157529A1 (ja) | 2014-07-31 |
US10662315B2 (en) | 2020-05-26 |
JP2017222881A (ja) | 2017-12-21 |
TW201712069A (zh) | 2017-04-01 |
CN109971122A (zh) | 2019-07-05 |
US20140128505A1 (en) | 2014-05-08 |
US20170121505A1 (en) | 2017-05-04 |
JP6304271B2 (ja) | 2018-04-04 |
KR20140034804A (ko) | 2014-03-20 |
TW201302906A (zh) | 2013-01-16 |
KR101899186B1 (ko) | 2018-09-14 |
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