WO2012104639A3 - Composite adsorbent material containing a porous carbon matrix - Google Patents

Composite adsorbent material containing a porous carbon matrix Download PDF

Info

Publication number
WO2012104639A3
WO2012104639A3 PCT/GB2012/050218 GB2012050218W WO2012104639A3 WO 2012104639 A3 WO2012104639 A3 WO 2012104639A3 GB 2012050218 W GB2012050218 W GB 2012050218W WO 2012104639 A3 WO2012104639 A3 WO 2012104639A3
Authority
WO
WIPO (PCT)
Prior art keywords
porous carbon
adsorbent
adsorbent material
material containing
composite adsorbent
Prior art date
Application number
PCT/GB2012/050218
Other languages
French (fr)
Other versions
WO2012104639A2 (en
Inventor
Franciscus Antonius Anna Maria De Leij
James Stratford
Helen SNEATH
Tony HUTCHINGS
Original Assignee
The University Of Surrey
The Forestry Commission
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The University Of Surrey, The Forestry Commission filed Critical The University Of Surrey
Priority to AU2012213202A priority Critical patent/AU2012213202B2/en
Priority to CN201280016411.9A priority patent/CN103608104B/en
Priority to EP12704528.4A priority patent/EP2670526A2/en
Priority to AP2013007094A priority patent/AP3701A/en
Priority to CA2826078A priority patent/CA2826078C/en
Priority to NZ613762A priority patent/NZ613762B2/en
Publication of WO2012104639A2 publication Critical patent/WO2012104639A2/en
Publication of WO2012104639A3 publication Critical patent/WO2012104639A3/en
Priority to US13/955,978 priority patent/US9878356B2/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09C—RECLAMATION OF CONTAMINATED SOIL
    • B09C1/00—Reclamation of contaminated soil
    • B09C1/08—Reclamation of contaminated soil chemically
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0248—Compounds of B, Al, Ga, In, Tl
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0274—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04 characterised by the type of anion
    • B01J20/0277—Carbonates of compounds other than those provided for in B01J20/043
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0274—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04 characterised by the type of anion
    • B01J20/0285—Sulfides of compounds other than those provided for in B01J20/045
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0274—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04 characterised by the type of anion
    • B01J20/0292—Phosphates of compounds other than those provided for in B01J20/048
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/041—Oxides or hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/043—Carbonates or bicarbonates, e.g. limestone, dolomite, aragonite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/045—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium containing sulfur, e.g. sulfates, thiosulfates, gypsum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/24—Naturally occurring macromolecular compounds, e.g. humic acids or their derivatives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28042—Shaped bodies; Monolithic structures
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28069—Pore volume, e.g. total pore volume, mesopore volume, micropore volume
    • B01J20/28073—Pore volume, e.g. total pore volume, mesopore volume, micropore volume being in the range 0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28078—Pore diameter
    • B01J20/28085—Pore diameter being more than 50 nm, i.e. macropores
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28095—Shape or type of pores, voids, channels, ducts
    • B01J20/28097—Shape or type of pores, voids, channels, ducts being coated, filled or plugged with specific compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
    • B01J20/3204—Inorganic carriers, supports or substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3234—Inorganic material layers
    • B01J20/3236—Inorganic material layers containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/288—Treatment of water, waste water, or sewage by sorption using composite sorbents, e.g. coated, impregnated, multi-layered
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/48—Treatment of water, waste water, or sewage with magnetic or electric fields
    • C02F1/488—Treatment of water, waste water, or sewage with magnetic or electric fields for separation of magnetic materials, e.g. magnetic flocculation
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C02F2101/103—Arsenic compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C02F2101/20—Heavy metals or heavy metal compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/06—Contaminated groundwater or leachate
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00—Controlling or monitoring parameters in water treatment
    • C02F2209/06—Controlling or monitoring parameters in water treatment pH
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00—Specific treatment goals
    • C02F2303/16—Regeneration of sorbents, filters

Abstract

The invention relates to composite adsorbent materials, and in particular, to highly porous carbon-based composite materials for the adsorption and stabilisation of inorganic substances. The composite adsorbent material comprises a porous carbon carrier matrix and an adsorbent species, wherein the adsorbent species is precipitated within the pores of the carrier matrix. The invention extends to various uses of such adsorbent materials, for example in water purification, recovery of metals from waste streams and remediation applications, and where the adsorbent material is amended into soil, waste etc. for the purpose of breaking pollutant-receptor linkages.
PCT/GB2012/050218 2011-02-03 2012-02-02 Composite adsorbent material WO2012104639A2 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
AU2012213202A AU2012213202B2 (en) 2011-02-03 2012-02-02 Composite adsorbent material containing a porous carbon matrix
CN201280016411.9A CN103608104B (en) 2011-02-03 2012-02-02 Composite adsorbing material containing porous carbon substrate
EP12704528.4A EP2670526A2 (en) 2011-02-03 2012-02-02 Composite adsorbent material
AP2013007094A AP3701A (en) 2011-02-03 2012-02-02 Composite adsorbent material
CA2826078A CA2826078C (en) 2011-02-03 2012-02-02 Composite adsorbent material
NZ613762A NZ613762B2 (en) 2011-02-03 2012-02-02 Composite adsorbent material containing a porous carbon matrix
US13/955,978 US9878356B2 (en) 2011-02-03 2013-07-31 Composite adsorbent material

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB1101864.5A GB2487760B (en) 2011-02-03 2011-02-03 Composite adsorbent material
GB1101864.5 2011-02-03

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US13/955,978 Continuation US9878356B2 (en) 2011-02-03 2013-07-31 Composite adsorbent material

Publications (2)

Publication Number Publication Date
WO2012104639A2 WO2012104639A2 (en) 2012-08-09
WO2012104639A3 true WO2012104639A3 (en) 2013-01-03

Family

ID=43836147

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2012/050218 WO2012104639A2 (en) 2011-02-03 2012-02-02 Composite adsorbent material

Country Status (8)

Country Link
US (1) US9878356B2 (en)
EP (1) EP2670526A2 (en)
CN (1) CN103608104B (en)
AP (1) AP3701A (en)
AU (1) AU2012213202B2 (en)
CA (1) CA2826078C (en)
GB (1) GB2487760B (en)
WO (1) WO2012104639A2 (en)

Families Citing this family (48)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL2461928T3 (en) * 2009-08-05 2020-01-31 Höganäs Ab Permeable porous composite
EP2706040A1 (en) * 2012-09-07 2014-03-12 Baden-Württemberg Stiftung gGmbH Particle for recovering an anion from an aqueous solution
WO2014144718A1 (en) 2013-03-15 2014-09-18 Carus Corporation Sustained release reactant blends
CN104772330A (en) * 2014-05-14 2015-07-15 雷志刚 Method for separating harmful heavy metals in paddy field
CN104014199B (en) * 2014-06-24 2016-03-23 潘峰 For removing the filter medium of phenol in drinking water, filter core and preparation method
CN104388094B (en) * 2014-10-13 2017-04-05 广东省生态环境与土壤研究所（广东省土壤科学博物馆） A kind of iron-based biological carbon materials, its preparation technology and its application in remediation contaminated soil
CN104368323B (en) * 2014-11-04 2017-04-19 中国科学院过程工程研究所 Carbon-based catalyst for desulfurization and denitrification as well as preparation method and application of catalyst
CN107614442B (en) * 2015-04-15 2021-07-23 联邦科学和工业研究组织 Water treatment and/or remediation process
CN104841201B (en) * 2015-04-29 2016-09-21 安徽天诚环保机械有限公司 A kind of active carbon air filtering material adding cork composition and preparation method thereof
CN105536801B (en) * 2015-06-29 2019-01-15 大连理工大学 A kind of Ni based composite catalyst and its preparation method and application
CN105127193B (en) * 2015-09-21 2019-04-09 江苏隆昌化工有限公司 A kind of method of hydrated calcium chloroaluminate in-situ immobilization phosphor polluted soil
DE102015221206A1 (en) * 2015-10-29 2017-05-04 Fränkische Rohrwerke Gebr. Kirchner Gmbh & Co. Kg Composition for the immobilization of metal ions
US10099072B2 (en) 2015-12-15 2018-10-16 Vanderbilt University Adsorbent materials and methods of making and use thereof
CN105618472B (en) * 2015-12-22 2019-01-29 湖南森美思环保有限责任公司 A kind of permanent method for removing available heavy metal in heavy-metal contaminated soil
CN105523538B (en) * 2016-01-05 2017-10-17 上海交通大学 A kind of mesoporous carbon plate of sequential 2 D and its preparation method and application
US10501350B1 (en) * 2016-04-20 2019-12-10 Ecosense International, Inc. System, method and bio media for stormwater treatment
WO2018046286A1 (en) 2016-09-06 2018-03-15 Unilever N.V. Adsorbent comprising layered double hydroxide and activated carbon
US11975305B2 (en) 2017-02-10 2024-05-07 Calgon Carbon Corporation Sorbent and method of making
CN107282002A (en) * 2017-07-03 2017-10-24 安徽天顺环保设备股份有限公司 A kind of adsorbent for being used to remove removing heavy metals
CN107855106A (en) * 2017-11-21 2018-03-30 湖南科技大学 Activated carbon supported mesoporous calcium silicates composite and preparation method thereof
CN108118560B (en) * 2017-12-20 2020-09-29 湖南科技大学 Heavy metal ion filter paper and preparation method thereof
JP7109912B2 (en) * 2017-12-20 2022-08-01 株式会社フジタ Phosphorus adsorbent and method for producing phosphorus adsorbent
CN108079965B (en) * 2017-12-20 2020-11-27 湖南科技大学 Cellulose-loaded porous calcium silicate filter material for heavy metal ion filtration and preparation method thereof
CN108178383B (en) * 2018-01-25 2021-06-08 南京维克环保科技有限公司 Purification treatment device for silt-containing sewage
CN108622877B (en) * 2018-04-09 2022-01-28 中国矿业大学 Nitrogen-doped porous carbon material with hierarchical pore structure and preparation method and application thereof
CN109110862A (en) * 2018-09-20 2019-01-01 北京师范大学 A kind of denitrogenation dephosphorizing material and preparation method thereof
US11420186B2 (en) 2019-03-25 2022-08-23 King Fahd University Of Petroleum And Minerals Ca-Y-carbonate nanosheets, their use, and synthesis
JP7330772B2 (en) * 2019-06-19 2023-08-22 株式会社フジタ fertilizer
CN110180500B (en) * 2019-06-24 2022-05-24 吕梁学院 Preparation method of walnut shell biomass carbon photocatalytic degradation-adsorbent and application of walnut shell biomass carbon photocatalytic degradation-adsorbent in removal of rhodamine B in dye wastewater
US11623884B1 (en) * 2019-08-02 2023-04-11 Wm Intellectual Property Holdings, L.L.C. System and method for removal of PFAS from waste streams
CN110975815A (en) * 2019-12-25 2020-04-10 南宁师范大学 Preparation method of nitric acid oxidation modified high-temperature carbonized active bamboo charcoal
CN111233196A (en) * 2020-02-03 2020-06-05 安徽冠臻环保科技有限公司 Garbage percolation concentrated solution adsorption fermentation dehydration solidification process
CN111252844B (en) * 2020-02-18 2022-01-04 四川大学 Application of eggshell particles in bismuth-containing sewage treatment and use method thereof
CN111389367A (en) * 2020-04-22 2020-07-10 徐州工程学院 Metal sludge-based biochar, preparation method and application in removing nitrogen and phosphorus in water body
JP2021171692A (en) * 2020-04-23 2021-11-01 株式会社フジタ Adsorbent
CN111676023B (en) * 2020-05-27 2021-05-25 永清环保股份有限公司 Semi-wrapping stabilizing material and preparation method and use method thereof
CN111545206A (en) * 2020-06-01 2020-08-18 山东祥桓环境科技有限公司 Method for preparing advanced iron oxide carbon catalyst from biomass in one step and application
CN112337433B (en) * 2020-11-09 2023-04-07 江西理工大学 Preparation method and application of renewable cadmium removal agent and regeneration method
CN112756392B (en) * 2020-12-18 2022-03-01 广东工业大学 Remediation agent and remediation method for organic contaminated soil
CN112694894A (en) * 2020-12-31 2021-04-23 河南川萍环保科技有限公司 Remediation agent for antimony-polluted soil and application method thereof
JP2022138511A (en) * 2021-03-10 2022-09-26 株式会社フジタ Adsorbent and manufacturing method thereof
IT202100014195A1 (en) * 2021-05-31 2022-12-01 Univ Bologna Alma Mater Studiorum METHOD FOR THE MANUFACTURING OF A COMPOSITE MATERIAL FOR THE RECOVERY OF NUTRIENTS AND/OR POLLUTANTS FROM WASTE WATER, COMPOSITE MATERIAL OBTAINED AND RELATED USE
CN113426828B (en) * 2021-07-30 2022-11-11 西南科技大学 Method for restoring strontium-polluted soil
CN113632614B (en) * 2021-08-13 2022-08-16 金华生物质产业科技研究院 Preparation and application methods of compound heavy metal contaminated soil remediation material
CN114436408A (en) * 2022-01-21 2022-05-06 河北科技师范学院 Magnetic mushroom bran biochar and preparation method and application thereof
CN114433024A (en) * 2022-04-12 2022-05-06 农业农村部环境保护科研监测所 Modified biochar and preparation method and application thereof
CN114749141B (en) * 2022-05-16 2023-06-20 南开大学 Environment heavy metal pollution repairing agent and preparation method and application thereof
CN115672269A (en) * 2022-09-30 2023-02-03 南华大学 Calcium carbonate modified biochar, preparation method thereof and application thereof in treating beryllium-containing wastewater

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3876451A (en) * 1971-08-24 1975-04-08 David M Zall Activated carbon and the method of making it
EP0121339A2 (en) * 1983-03-03 1984-10-10 Takeda Chemical Industries, Ltd. Method for removal of poisonous gases
US4877920A (en) * 1988-06-08 1989-10-31 Sun Refining And Marketing Company Process for removing arsine impurities in process streams
US6277780B1 (en) * 1994-08-09 2001-08-21 Westvaco Corporation Preparation of phosphorus-treated activated carbon composition
WO2002069351A1 (en) * 2001-02-26 2002-09-06 University Of Utah Research Foundation Magnetic activated carbon particles for adsorption of solutes from solution
US20040089608A1 (en) * 2001-08-27 2004-05-13 Vo Toan Phan Adsorbents for removing heavy metals and methods for producing and using the same
US20070080115A1 (en) * 2005-10-11 2007-04-12 Paul Sylvester Sorbent for removal of contaminants from fluids
US20080293565A1 (en) * 2007-05-24 2008-11-27 Calgon Carbon Corporation Metal impregnated activated carbons and method of making same
WO2011016038A1 (en) * 2009-08-05 2011-02-10 Technion Research And Development Foundation Ltd Method for removal of selenium contaminants from aqueous fluids

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US790145A (en) 1905-02-13 1905-05-16 Harry L Makely Corn-planter.
US1519470A (en) * 1921-01-22 1924-12-16 Robert E Wilson Impregnated carbon and process of making same
GB247241A (en) * 1924-08-13 1926-02-15 Johan Nicolaas Adolf Sauer Improvements in the manufacture and use of active carbons
JPS5654206A (en) * 1979-10-03 1981-05-14 Xerox Corp High porous catalyst supporting body for ozone removing device
US4701219A (en) 1982-02-08 1987-10-20 Ashland Oil, Inc. Inhibiting leaching of metals from catalysts and sorbents and compositions and methods therefor
GB8612861D0 (en) * 1986-05-27 1986-07-02 Cambridge Life Sciences Immobilised enzyme biosensors
JPH0252040A (en) * 1988-08-11 1990-02-21 Sumitomo Heavy Ind Ltd Ethylene adsorbent and method for keeping freshness of plant
JPH1076004A (en) * 1996-09-05 1998-03-24 Kanegafuchi Chem Ind Co Ltd Adsorbing material for humor treatment and adsorber for humor treatment
US6787034B2 (en) * 2002-07-12 2004-09-07 Remediation Products, Inc. Compositions for removing hydrocarbons and halogenated hydrocarbons from contaminated environments
US7425521B2 (en) * 2003-06-20 2008-09-16 Honeywell International Inc. Structured adsorbent media for purifying contaminated air
WO2005058482A1 (en) * 2003-12-16 2005-06-30 Calgon Carbon Corporation Adsorbents for removing heavy metals and methods for producing and using the same
KR101375467B1 (en) * 2005-09-08 2014-03-18 리서치 파운데이션 오브 더 시티 유니버시티 오브 뉴욕 Catalytic adsorbents obtained from municipal sludges, industrial sludges, compost and tobacco waste and process for their production
US7767007B2 (en) * 2006-12-08 2010-08-03 Praxair Technology, Inc. Mercury adsorbents compatible as cement additives
JP2008189946A (en) * 2007-01-31 2008-08-21 Iwate Univ Carbide carrying triazine thiol, method for manufacturing carbide carrying triazine thiol, method for adsorbing metal ion, and method for recovering metal
DE102007023953B4 (en) * 2007-05-23 2016-02-04 Zf Friedrichshafen Ag Planetary gear with a multi-plate clutch or a multi-disc brake
US20090209418A1 (en) * 2008-02-18 2009-08-20 Nagoya Electrical Educational Foundation Adsorbent and method for manufacturing the same
KR101592620B1 (en) * 2008-10-08 2016-02-05 도쿠리츠교세이호진 노교간쿄기쥬츠겐큐쇼 Formed object adsorbing hazardous substance
JP5236569B2 (en) * 2009-04-28 2013-07-17 高知県 Method for producing oxyacid ion sorbent, oxyacid ion sorbent and ion sorption treatment method

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3876451A (en) * 1971-08-24 1975-04-08 David M Zall Activated carbon and the method of making it
EP0121339A2 (en) * 1983-03-03 1984-10-10 Takeda Chemical Industries, Ltd. Method for removal of poisonous gases
US4877920A (en) * 1988-06-08 1989-10-31 Sun Refining And Marketing Company Process for removing arsine impurities in process streams
US6277780B1 (en) * 1994-08-09 2001-08-21 Westvaco Corporation Preparation of phosphorus-treated activated carbon composition
WO2002069351A1 (en) * 2001-02-26 2002-09-06 University Of Utah Research Foundation Magnetic activated carbon particles for adsorption of solutes from solution
US20040089608A1 (en) * 2001-08-27 2004-05-13 Vo Toan Phan Adsorbents for removing heavy metals and methods for producing and using the same
US20070080115A1 (en) * 2005-10-11 2007-04-12 Paul Sylvester Sorbent for removal of contaminants from fluids
US20080293565A1 (en) * 2007-05-24 2008-11-27 Calgon Carbon Corporation Metal impregnated activated carbons and method of making same
WO2011016038A1 (en) * 2009-08-05 2011-02-10 Technion Research And Development Foundation Ltd Method for removal of selenium contaminants from aqueous fluids

Also Published As

Publication number Publication date
AU2012213202A1 (en) 2013-08-15
NZ613762A (en) 2015-01-30
GB2487760A (en) 2012-08-08
US9878356B2 (en) 2018-01-30
CA2826078A1 (en) 2012-08-09
AP2013007094A0 (en) 2013-08-31
US20130316898A1 (en) 2013-11-28
WO2012104639A2 (en) 2012-08-09
CA2826078C (en) 2020-09-15
AP3701A (en) 2016-05-31
GB201101864D0 (en) 2011-03-23
AU2012213202B2 (en) 2017-01-19
CN103608104B (en) 2017-07-14
CN103608104A (en) 2014-02-26
GB2487760B (en) 2015-11-18
EP2670526A2 (en) 2013-12-11

Similar Documents

Publication Publication Date Title
WO2012104639A3 (en) Composite adsorbent material containing a porous carbon matrix
Truong et al. Polyethyleneimine modification of activated fly ash and biochar for enhanced removal of natural organic matter from water via adsorption
EP2060535A4 (en) Porous carbon materials and production process thereof,and adsorbents, masks, adsorbing sheets and carriers
WO2008143831A3 (en) Sorbent bodies comprising activated carbon, processes for making them, and their use
WO2011068830A3 (en) Porous geopolymer materials
WO2008001354A3 (en) Method for adsorption of fluid contaminants and regeneration of the adsorbent
NZ599127A (en) Remediation composition comprising alum sludge
IN2014DN09726A (en)
WO2013162968A3 (en) Carbon nanocomposite sorbent and methods of using the same for separation of one or more materials from a gas stream
Pham et al. Adsorptive removal and recovery of organic pollutants from wastewater using waste paper-derived carbon-based aerogel
MX2009010357A (en) Materials for removing contaminants from fluids using supports with biologically-derived functionalized groups and methods of forming and using the same.
MX336364B (en) Biotechnological process for hydrocarbon recovery in low permeability porous media.
WO2012024752A8 (en) Absorbent composition designed for removing contaminants, mainly sulphur compounds, contained in liquid and gaseous streams, method for obtaining a designed absorbent composition, method for removing impurities, mainly sulphur compounds, including hydrogen sulphide, contained in liquid or gaseous streams, and use of an absorbent composition
MY163255A (en) A buoyant multifunctional composite material for effective removal of organic compounds in water and wastewater
WO2011053034A3 (en) Water purification system and water purification method employing biological activated carbon and granular activated carbon
Yang et al. Surface-nanoengineered bacteria for efficient local enrichment and biodegradation of aqueous organic wastes: using phenol as a model compound
GB201319623D0 (en) Thermal treatment of a contaminated volume of material
WO2011129976A3 (en) Apparatus and methods for removing mercury from formation effluents
FR2958655B1 (en) PROCESS FOR PURIFYING AROMATIC EXTRACTS CONTAINING AROMATIC POLYCYCLIC COMPOUNDS
EP4324543A3 (en) Compositions, articles, and methods for abatement of hydrocarbon, metals, and organic pollutants
MY145639A (en) Use of an adsorbent for the removal of liquid, gaseous and/or dissolved contituents from a process stream
WO2012157955A3 (en) Oil purification method and apparatus with porous membrane
WO2012050437A3 (en) Production of sodium bicarbonate from a basic process stream
WO2010083323A3 (en) Reactor unit for pollutant removal
Ehrampoush et al. Benzene Removal from Aqueous Solution by Surface Modified Carbon NanotubesUsing Calcium Hypochlorite

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 12704528

Country of ref document: EP

Kind code of ref document: A2

ENP Entry into the national phase

Ref document number: 2826078

Country of ref document: CA

NENP Non-entry into the national phase

Ref country code: DE

ENP Entry into the national phase

Ref document number: 2012213202

Country of ref document: AU

Date of ref document: 20120202

Kind code of ref document: A

WWE Wipo information: entry into national phase

Ref document number: 2012704528

Country of ref document: EP