Classifications

• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
  • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
  • C08L25/02—Homopolymers or copolymers of hydrocarbons
  • C08L25/04—Homopolymers or copolymers of styrene
  • C08L25/06—Polystyrene
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
  • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
  • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
  • C08L27/06—Homopolymers or copolymers of vinyl chloride

Definitions

• the invention relates to the polymer industry and can be used in the manufacture of plastic or rubber recreational products for various purposes, including goods and products for household and decorative, hygienic, cultural, agricultural and others.
• Bioplastics belong to the most innovative products that are widely used in all areas of human activity. They are made on the basis of a mixture of inorganic polymers acceptable for use in the food industry, medicine, veterinary medicine, agriculture, with components of natural origin [1, 2] ⁇ Therefore, when used, requirements for the quality and properties of products made from bioplastics increase, especially those with by which a person contacts directly.
• a disadvantage of the known material is the limited functional biological capabilities due to the lack of natural substances in its composition, which deprives the healing effect.
• a large number of source components, the difficulty of obtaining some of them, as well as the great complexity and duration of the manufacture of the final product, due to the complexity of the composition, as a whole lead to the high cost of the finished material and products from it.
• the introduction of synthetic aromatic and bactericidal substances deprives the finished material of the biological energy of plants, significantly reduces the saturation of the aroma in the finished material, which reduces the efficiency of contact of living organisms with such plastic material.
• bioplastics containing a polymer and one or more extracts from plants, and having bactericidal and aromatic properties, as well as some biological (energy) properties [4].
• plant extracts it contains a powder of extracts from plant materials flavored with aromatic essential oil, and as a polymer, high-pressure polyethylene with or without heat stabilizer or polystyrene in the following ratio, wt.%: The above polymer 90-99.9; the above plant extract powder of 0.01-10.
• the disadvantages of the known bioplastics include insufficient biological activity and limited functional biological capabilities due to a narrow number of starting components — use only extracts from medicinal plants and one type of artificial polymer — high pressure polyethylene or polystyrene, which leads to limited use of the material.
• the present invention proposed bioplastics with significantly improved characteristics, increased biological activity in comparison with the prototype, and expanded functional biological capabilities, which leads to a wide range of its use as a multi-purpose healing material.
• the basis of the invention is the task of improving the bioplastics, in which through the use of other starting components in its composition, and the introduction of additional components, which significantly influenced the technical result, the quality of the material is improved while maintaining the healing natural properties of the starting materials, increasing its biological activity, leads to an increase in the effect of a comprehensive healing effect, which lasts throughout the entire long service life, increasing utility ty during use, and the expansion of the healing properties and functionality of the material by expanding a number of source components.
• bioplastics is characterized by the following features: as mummified extracts from plant materials, it contains mummified extracts from any ground or underground parts of plants, trees, or mushrooms; as mummified extracts from any living organisms, it contains various origin mummified extracts from insects, arthropods, amphibians, fish, reptiles, corals, animals, birds, or parts thereof, or from products of their origin; as natural substances of various origin, it contains natural substances of plant, animal origin, birds or amphibians, insects, arthropods, fish, reptiles, corals, including eggs, larvae, vegetable resins, mainly incense, myrrh, mummy, amber, conifers resins, beekeeping products, mainly propolis, bee bread, royal jelly, or essential or any other oils of natural origin; as vitamins or multivitamins as auxiliary components, it contains vitamins, mainly of groups A, B, C, D, E; as auxiliary components, it contains dyes and
• the expansion of a number of starting components while preserving the healing properties of the biologically active substances of the starting natural raw materials enriches the bioplastics and products from it with various biological healing properties, and in comparison with the prototype (having aromatic, bactericidal and energy properties) leads to the appearance of additionally new healing properties (antiseptic , antiparasitic, fungicidal, antistatic, and protection from the negative effects of external energy fields), which improves the quality of
• the material also enhances biological activity, and expands the functional biological capabilities, which leads to an increase in the effect of the complex healing effect with constant or temporary contact with living organisms.
• the claimed bioplastics has the ability to protect against the negative effects of radiation from external energy fields, which are harmful factors (harmful environmental factors that lead to poor health, reduced ability to work, illness and even death as a result of the disease are called harmful factors).
• harmful factors harmful environmental factors that lead to poor health, reduced ability to work, illness and even death as a result of the disease are called harmful factors.
• organic compounds of natural origin plants, beekeeping products, mummies, amber and others
• the proposed bioplastics becomes healthier With increased biological activity, which has inherent healing properties, with maximally expanded functional capabilities, which makes it possible to effectively carry out the overall complex healing effect.
• the distinguishing features of the claimed bioplastics are essential and necessary to achieve a new technical result. However, it should be borne in mind that this invention is not limited to them.
• a technical result consisting in improving the quality of the material while preserving the healing natural properties of the starting materials, increasing its biological activity, which leads to an increase in the effect of a comprehensive healing effect that persists throughout the entire long service life, an increase in usefulness when used, and an expansion of the healing properties and functionality of the material by expanding a number of initial components.
• inventive bioplastics are multi-purpose and can be used in the composition of the material for the manufacture of products or their elements for any purpose, which are in constant or temporary contact with living organisms (examples of its purpose for use are indicated in paragraphs 9-24 of the formula), with the expected healing effect .
• Bioplastics contains a mixture of material based on high molecular weight compounds with organic compounds of natural origin, which are active substances. According to the claimed claims, as a material based on macromolecular compounds, it contains any polymer or rubber, or any composition based on them in the form of cast or woven material, which is acceptable for use in food and feed industry, medicine, veterinary medicine, rural the farm. Plastics - materials based on macromolecular compounds - polymers. Polyethylene can be well processed into products by various methods of plastic deformation: injection molding, compressor and injection molding, blowing, extrusion, vacuum molding, plasma spraying.
• thermoplastic polymers can be used - polyethylene (including high-pressure polyethylene), or polyvinyl chloride, or polypropylene, or polystyrene.
• active substances of natural origin it contains one or more mummified extract from plant materials or from any living organisms, and / or any natural substances of various origins, or their complex mixture, which are a vitamin-containing organometallic natural complex with preservation of biologically active substances of natural raw materials.
• as mummified extracts from plant materials it may contain mummified extracts from any ground or underground parts of plants, trees, or fungi.
• any living organisms of various origins it may contain mummified extracts from insects, arthropods, amphibians, fish, reptiles, corals, animals, birds, or parts thereof, or from products of their origin.
• natural substances of various origins it contains natural substances of plant, animal origin, birds or amphibians, insects, arthropods, fish, reptiles, corals, including eggs, larvae, plant resins, mainly incense, myrrh, mummy, amber, coniferous resins, beekeeping products, mainly propolis, bee bread, royal jelly, or essential or any other oils of natural origin.
• Mummified extracts from plant materials can be used in the form of powders (for example, well-known prepared powders of mummified extracts of Econika), aromatic essential oils or in the form of fatty oils (vegetable, animal). Powders of mummified extracts from plant materials in most cases are obtained in a known manner by aqueous or alcoholic extraction of plant mass with concentration and drying [5]. The technology for producing powders recreates the natural process of mummification of plant materials and allows the original product to be converted into thermoliotropic state (like a mummy). Additionally, bioplastics contains micro- and / or macroelements, which are presented individually or in the form of any of their compounds, or substances of the organic form.
• micro and macro elements it contains selected mainly from a number of sodium, and / or potassium, and / or magnesium, and / or iron, and / or zinc, and / or copper, and / or manganese, and / or nickel and / or boron and / or cobalt and / or molybdenum and / or vanadium and / or fluorine and / or selenium and / or iodine and / or tin and / or calcium and / or cadmium, and / or phosphorus, and / or chromium, and / or silver, acceptable for use in the food and feed industry.
• Sources of microelements and vitamins may be plant materials or raw materials of another organic form or extracts thereof, or mineral or table water, or table salt or sea salt, or a natural mineral, or chalk, or eggshell, or bone or grass meal, or flour of various cereals, or bran, or cake, or yeast, or algae, or coral, or shells of crustaceans or reptiles, or mollusks or their shells.
• bioplastics may contain vitamins or multivitamins, both water-soluble and oil, mainly groups A, B, C, D, E; and / or dyes and / or pigments of natural origin.
• the above components of the inventive bioplastics are contained in the following ratio, wt.%: Polymer or rubber, or a composition based on them from 79.99 to 99.997; mummified extracts from plant materials or from any living organisms, and / or any natural substances of various origin, or their complex mixture 10.0 - 0.001; micro and / or macronutrients 10.0-0.001; auxiliary components - the rest.
• the use in the inventive plastic is more than 10.0 wt.% Organic compounds of natural origin (mummified extracts) practically does not lead to an increase in the effect, but it increases costs and can affect the physicomechanical properties of plastics, since a large number of them increases the amount of fillers in the polymer composition, which is not always desirable.
• the claimed composition of the components of the bioplastics is optimal to achieve the expected technical result.
• the invention is industrially applicable and can be repeatedly obtained known in the industry, including the number of polymer, methods using known means and equipment.
• certain polymers are used in the form of powder or granules.
• high pressure polyethylene grade 17504-006 GOST 16337-77
• the powder or granules of a given polymer is heated until they melt.
• the introduction, for example, mummified extracts into the bioplastics is carried out in a known manner in the manufacture of plastic products.
• the specified mummified extracts from plant materials or their mixtures, and / or any natural substances of various origins, micro and / or macrocells, or auxiliary components are added in the required amount.
• mummified extracts from plant materials or mixtures thereof are introduced into plastic in the form of ready-made powders of mummified extracts (for example, Econika powders obtained according to the known method [5].
• aromatization of powders of mummified extracts to them add 1-1, 5 wt.% essential oils of the amount of powder, according to the methods of aromatherapy, or sprayed onto polymer granules (powdered with a powder of plant extract) before melting.
• essential oils are introduced in pure form, either their alcohol solutions (mainly in ethanol), or mixed with transport fatty oil (for example, walnut oil, corn oil, etc.). Mix everything until a homogeneous mass and, if necessary, form the desired product.
• transport fatty oil for example, walnut oil, corn oil, etc.
• the result is a uniformly stable healing healing material - bioplastics - a mixture of artificial material and mummified extracts of natural raw materials, where all biological active properties are preserved.
• certain organic compounds of natural origin, micro and / or macro elements, auxiliary components and a specific type of material based on high molecular weight compounds with predetermined properties are used in its production, which allows to expand the functional biological capabilities and the scope of use.
• bioplastics acquires the corresponding well-known healing properties [6].
• bioplastics acquires the corresponding well-known healing properties [6].
• Example 1 with the following ratio of components, wt.%: Polyethylene - 90.0, propolis - 7, magnesium - 1, iron - 1.5, cobalt - 0.5.
• This composition of bioplastics has antiseptic and bactericidal properties and helps to improve cardiovascular activity (products: insoles, applicators, pendants, bracelets, etc.).
• Example 2 in the following ratio of components, wt.%: Polyvinyl chloride - 85.0, frankincense - 10, iodine - 1, calcium - 2, nickel - 0.5, tin - 0.5, sodium - 0.5, vitamins or multivitamins - 0.5.
• This bioplastics composition helps to improve the thyroid gland (products: insoles, applicators, etc.).
• Example 3 with the following ratio of components, wt.%: Polyethylene - 95.0, essential oil of wormwood lemon - 3, chromium - 0.02, vanadium - 0.03, selenium - 0.05, calcium - 1, 9.
• This bioplastics composition has antiparasitic properties and helps to improve the activity of the gastrointestinal tract (products: insoles, applicators, bracelets, etc.).
• Example 4 in the following ratio of components, wt.%: Polyethylene - 95.0, sea salt - 2.0, mummified wormwood extract - 3.0.
• This composition of bioplastics has antiparasitic properties with respect to moths, bugs (products: bags, bags for clothes, for products, food packaging and ⁇ . ⁇ .)
• Example 5 in the following ratio of components, wt.%: Polypropylene - 95.0, frankincense - 1, 0, mummy - 2.0, mummified extract of oak leaves - 2.0.
• This bioplastics composition has antistatic properties (household products).
• Example 6 in the following ratio of components, wt.%: Polyethylene - 96.0, frankincense - 1.0, mummified alfalfa extract - 3.0.
• This bioplastics composition has antiseptic and bactericidal properties (products: lids for various dishes - glass jars, bottles, packaging film, food containers).
• Example 7 in the following ratio of components, wt.%: polystyrene - 95.0, mummified celandine extract - 0.5, mummified alfalfa extract - 3.0, mummified extract of Japanese Sophora - 0.5, cobalt - 0.5, zinc - 0.05.
• This composition of bioplastics has antiseptic and bactericidal properties, protects against the harmful effects of high-frequency fields (products: telephone, television, computer, microwave oven, electric ovens, etc., radio and electrical products).
• Example 8 with the following ratio of components, wt.%: Rubber - 94.0, chamomile - 3.0, series - 3.0.
• This bioplastics composition has antiseptic and bactericidal, and anti-allergenic properties.
• the claimed invention allows to obtain bioplastics of various spectrum of action, with good biocompatibility and increased activity of health-improving action.
• the proposed bioplastics can be used in the composition of the material for the production of any health products or their elements that have healing properties, such as antiparasitic and antiviral, antiseptic, bactericidal, fungicidal and aromatic properties, as well as antistatic and the ability to protect against the negative effects of external energy fields.
• any consumer goods or their elements including household, medical, hygienic, cultural, everyday-decorative and agricultural purposes, or their elements ; in the composition of the material that is acceptable for use in the food and feed industry, for the manufacture of any products or their elements for food or feed, including containers, containers or packaging articles in the form of bags, bags, films, or as lids for glass containers; as part of a material that is acceptable for use in the food industry for the production of chewing gum; as part of the material in the production of woven materials for any household and industrial purposes; as part of the material as the basis for the manufacture of various types of dressings, cosmetic masks and compresses; in the composition of the material in the manufacture of any rubber products for various purposes or their elements; as a soil additive for growing plants in the agricultural industry; as a part of material for the production of products or their elements in the field of medical equipment and machinery; as a part of material for the production of products or their elements of industrial production in the field
• Products from the proposed bioplastics may be made in the form of any shape, including simple or complex geometric or curved shapes.
• One of the common methods for manufacturing products from thermoplastic polymers is extrusion. First, the appropriate composition of the bioplastics or rubber material with the specified components is made, and then a product of a certain shape is formed in a molding form from a heated elastic mass followed by cooling (for a molded product).
• Bioactive health properties of the claimed bioplastics are stored for a long time during the entire service life, products from it can be washed with detergents without reducing their activity.
• the material is not biodegradable, non-toxic.
• finished products from the proposed plastic have a healthy bioenergy of natural substances.
• prototypes were made in the form of various products with different compositions - the proposed starting materials and in a different ratio of bioplastics components (as shown in the examples above), which passed the test, confirming the receipt of the expected technical result and positive effect.
• the proposed bioplastics is multi-purpose and can find application in various fields of industry and in human activities: food, medical, in the field of medical technology and equipment, agricultural, electrical, electronics, automotive, shipbuilding, construction and others. Information sources.
• Patent UA JYQ 48617 pending. 10/25/2001, publ. 05/17/2004, bull. ⁇ 5/2004 C08L 23/00, 25/00, 27/00, ⁇ 08 ⁇ 5/00 (prototype).

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• Chemical & Material Sciences (AREA)
• Health & Medical Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Medicinal Chemistry (AREA)
• Polymers & Plastics (AREA)
• Organic Chemistry (AREA)
• Agricultural Chemicals And Associated Chemicals (AREA)
• Compositions Of Macromolecular Compounds (AREA)

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Citations (5)

• 2010
  • 2010-10-18 UA UAA201012321A patent/UA96236C2/uk unknown
• 2011
  • 2011-05-26 WO PCT/UA2011/000041 patent/WO2012054003A1/ru active Application Filing

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