WO2011051530A2 - Glass-recycling machine for obtaining cullet - Google Patents

Glass-recycling machine for obtaining cullet Download PDF

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Publication number
WO2011051530A2
WO2011051530A2 PCT/ES2010/070696 ES2010070696W WO2011051530A2 WO 2011051530 A2 WO2011051530 A2 WO 2011051530A2 ES 2010070696 W ES2010070696 W ES 2010070696W WO 2011051530 A2 WO2011051530 A2 WO 2011051530A2
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WO
WIPO (PCT)
Prior art keywords
glass
recycling machine
machine according
color
rollers
Prior art date
Application number
PCT/ES2010/070696
Other languages
Spanish (es)
French (fr)
Other versions
WO2011051530A3 (en
Inventor
Samuel Felipe Fernandez
Original Assignee
Ecoinnova Investigación Y Medio Ambiente, S.L.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ecoinnova Investigación Y Medio Ambiente, S.L. filed Critical Ecoinnova Investigación Y Medio Ambiente, S.L.
Publication of WO2011051530A2 publication Critical patent/WO2011051530A2/en
Publication of WO2011051530A3 publication Critical patent/WO2011051530A3/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C19/00Other disintegrating devices or methods
    • B02C19/0056Other disintegrating devices or methods specially adapted for specific materials not otherwise provided for
    • B02C19/0081Other disintegrating devices or methods specially adapted for specific materials not otherwise provided for specially adapted for breaking-up bottles
    • B02C19/0087Other disintegrating devices or methods specially adapted for specific materials not otherwise provided for specially adapted for breaking-up bottles for glass bottles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B02CRUSHING, PULVERISING, OR DISINTEGRATING; PREPARATORY TREATMENT OF GRAIN FOR MILLING
    • B02CCRUSHING, PULVERISING, OR DISINTEGRATING IN GENERAL; MILLING GRAIN
    • B02C23/00Auxiliary methods or auxiliary devices or accessories specially adapted for crushing or disintegrating not provided for in preceding groups or not specially adapted to apparatus covered by a single preceding group
    • B02C23/08Separating or sorting of material, associated with crushing or disintegrating
    • B02C23/10Separating or sorting of material, associated with crushing or disintegrating with separator arranged in discharge path of crushing or disintegrating zone
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B07SEPARATING SOLIDS FROM SOLIDS; SORTING
    • B07CPOSTAL SORTING; SORTING INDIVIDUAL ARTICLES, OR BULK MATERIAL FIT TO BE SORTED PIECE-MEAL, e.g. BY PICKING
    • B07C5/00Sorting according to a characteristic or feature of the articles or material being sorted, e.g. by control effected by devices which detect or measure such characteristic or feature; Sorting by manually actuated devices, e.g. switches
    • B07C5/34Sorting according to other particular properties
    • B07C5/342Sorting according to other particular properties according to optical properties, e.g. colour
    • B07C5/3425Sorting according to other particular properties according to optical properties, e.g. colour of granular material, e.g. ore particles, grain
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65FGATHERING OR REMOVAL OF DOMESTIC OR LIKE REFUSE
    • B65F1/00Refuse receptacles; Accessories therefor
    • B65F1/0033Refuse receptacles; Accessories therefor specially adapted for segregated refuse collecting, e.g. receptacles with several compartments; Combination of receptacles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65FGATHERING OR REMOVAL OF DOMESTIC OR LIKE REFUSE
    • B65F1/00Refuse receptacles; Accessories therefor
    • B65F1/14Other constructional features; Accessories
    • B65F1/1405Compressing means incorporated in, or specially adapted for, refuse receptacles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65FGATHERING OR REMOVAL OF DOMESTIC OR LIKE REFUSE
    • B65F1/00Refuse receptacles; Accessories therefor
    • B65F1/0033Refuse receptacles; Accessories therefor specially adapted for segregated refuse collecting, e.g. receptacles with several compartments; Combination of receptacles
    • B65F2001/008Means for automatically selecting the receptacle in which refuse should be placed
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65FGATHERING OR REMOVAL OF DOMESTIC OR LIKE REFUSE
    • B65F2210/00Equipment of refuse receptacles
    • B65F2210/12Crushing means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65FGATHERING OR REMOVAL OF DOMESTIC OR LIKE REFUSE
    • B65F2240/00Types of refuse collected
    • B65F2240/112Bottles
    • B65F2240/1123Glass
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/10Waste collection, transportation, transfer or storage, e.g. segregated refuse collecting, electric or hybrid propulsion
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/60Glass recycling

Definitions

  • the purpose of the glass recycling device intended for domestic use by consumers of glass, both business and private, whose objective is to perform at origin, that is, at the same point of disposal of glass containers, a large part of the industrial process of recycling glass by grinding it, color separation and elimination of contaminating residues, all in a completely automated and safe way, so that the final product obtained is the calcine or basic raw material used to The manufacture of new glass.
  • the collected glass is, for the most part, of domestic origin, and is conducted in special transports to the treatment plants, where, properly selected, it is processed for recycling.
  • the glass to be treated contains a large number of impurities, such as plastic and metal plugs, corks, stones, papers, plastics, etc. Under these conditions, it would be practically impossible to manufacture new containers, since these foreign bodies would create defects in the new glass, so that during a phase of the process, the glass melts at high temperatures to eliminate these residues that remain on the surface forming a layer called "cream" and that is removed. In turn, and so that the glass can be reused in the manufacture of new containers, the most important requirement is that it be separated by colors, distinguishing mainly three of these colors: green, transparent and opaque or amber.
  • the glass, once treated and selected by size, color and type, is deposited in the silos and subsequently supplied to the glass manufacturers who, with this raw material called "calcine", manufacture the glass products.
  • the glass is 100% recycled and can be recycled again and again for life, being the main destination of the recovered glass the manufacture of new containers that have exactly the same quality characteristics as the original ones.
  • recycled glass is also used in the manufacture of other products, such as kitchen countertops, tiles or reflective paints. It is necessary to continue favoring the recycling of glass as this brings important advantages, such as energy savings, the contribution to environmental conservation, savings in raw materials and other additional advantages.
  • approximately 40% of the glass containers consumed are not recycled and go to the landfill.
  • the sectors of the economy that are large consumers of glass, such as hospitality and catering have a serious deficit of glass recycling, in that it is an inconvenience and added costs for the scarce resources of which They have for the most part.
  • the rapid pace of operation of the business the need for a glass storage space, away from the work area, transport to the special container, and the lack of encouragement from the responsible agencies also make these consumers desist from recycling.
  • the glass recycling process that is currently used in all countries is carried out entirely in treatment plants for this purpose, requiring only the consumer to, when discarding the glass containers, separate them from other waste solids such as plastics, metal, cardboard, as well as organic waste to, in this way, facilitate its treatment.
  • the glass recycling device which consists essentially of a completely watertight cube-shaped machine, with the exception of a top opening through which any glass container is introduced, which through the use of optical sensing technology and completely automatically, it is separated according to its color - green, opaque or amber, and transparent - to be crushed and separated from contaminating waste such as metal or plastic and, finally, it is deposited in waterproof bags, already converted into calc ⁇ n, where it is stored with all the guarantees of safe sealing, for its subsequent transport to the manufacturing plants.
  • the device so described basically, a saving in logistics and transport costs is achieved, since the storage capacity of the containers would be significantly increased, reducing the frequency and, therefore, the collection costs in collection vehicles specialized.
  • the costs of the treatment process of glass containers which currently range between € 2 and € 25c per ton, would be significantly reduced. This cost saving, in the same way, allows to increase the glass recycling rate and the cost in terms of environmental protection.
  • underlies the present invention is not so much to substantially alter the collection and transport process, but to make it more efficient, being able to be used both in glass-consuming establishments (restaurants, bars, discos, hotels, etc.) and in the field domestic, or in the glass container itself, properly adapted.
  • FIGi. It shows a perspective view of the glass recycling device for obtaining calcin, object of the present invention.
  • the present invention consists of a glass recycling device for obtaining calcine, wherein said device essentially comprises an inlet or container of glass containers located in the upper part of the device and that offers an opening in its central zone that facilitates the vertical fall of the glass containers; and where, in addition, there is a gate system formed by a trapdoor at the bottom of the opening.
  • the electronic photocell In the lower part of the gate, in an orifice made for this purpose, the electronic photocell is configured to detect the color of the glass, and which activates, depending on the color, the selective pouring hopper (4), which is It is divided into three compartments, for transparent, green and opaque or amber glass. In the same way the motor-reducer (2) is activated for the beginning of the crushing process.
  • This crushing process materializes, firstly, with the press (5) located just below the inlet gate (1) and where, as a result of it, the container can only fall vertically and with the seat of it down.
  • This press (5) is constituted, in its preferred embodiment, by two folded metal plates that form a vertically closed perimeter block in rectangular form.
  • the position between both plates is, in its initial phase, slightly open at the top to allow the glass container to enter, and closed at the bottom.
  • the union between both plates depends on an axis located at the bottom of these.
  • the upper lift is carried out by means of a horizontal axis that runs along the entire length of the plate at its upper edge.
  • the movement of said plates is offered by the motor-reducer (2) fixed to a base plate, which transmits a continuous circular movement to a horizontal axis, which drives two crankshafts and two connecting rods (6) located on each side of the plates which convert the initial circular movement into horizontal movement. Said movement is transmitted to the plates by the connecting rods (6) achieving a separation between them with different measurement states.
  • the crushing process continues after the press (5) with the grinding system (3), which consists of at least two horizontal rollers formed by tubes and metal shafts.
  • the rollers or wheels are responsible for the final crushing of the glass.
  • the fixation of said assembly is formed by a junction box that keeps the rollers permanently stable. The junction box is screwed to the bottom of the press (5).
  • the grinding system rollers (3) rotate on their axes in opposite directions, favoring the falling of the crushed glass between them towards the selective pouring hopper.
  • the transmission of the rollers is obtained by means of a pinion placed at the end of the axis of one of the rollers, which causes the rotation of the other roller in the opposite direction, by pushing.
  • One of the rollers is provided with metal wheels arranged longitudinally on the perimeter surface thereof.
  • the crushed product falls by gravity into the selective pouring hopper (4) located just below the grinding system (3) and fixed thereto. It is constituted by a metal sheet through which the crushed glass is poured into each of the three receiving bags depending on their color. Depending on the color of the glass detected by the photocell, and depending on it, this sheet acting as a gate adopts a certain position, allowing the crushed glass to be deposited only in its corresponding bag according to its color.
  • the hopper (4) has three possible positions, which are commanded according to the color of the glass.
  • the gate In the first position, the gate is kept completely vertical in line with the exit of the rollers of the ground system (3) and allowing the deposit of the calcine (crushed and ground glass) in the central bag.
  • the hopper In positions two and three, the hopper adopts an angle of 45 or -45 or respectively on the vertical, to one side and another respectively, depending on the color and in order to deposit it in the side bags.
  • the hopper (4) also includes means to eliminate unwanted contaminating residues that the containers contain by default, such as plastics, papers, corks, etc.
  • Said means consist of a sieve (8) based on a series of metal rods placed longitudinally in the pouring hopper (4), with a separation between them that allows the crushed glass to pass, retaining most of the contaminating waste, which in the previous process they have been deformed but not crushed, so that their volume is greater than that of glass.
  • These rods have a slight inclination on the horizontal plane to allow the fall of these contaminating residues to a removable metal box (9) from the outside for its emptying, cleaning and replacement.
  • the calcine storage compartments (10) are located in the lower part of the assembly.
  • the whole set is supported by a steel structure (i) or other material capable of withstanding the different elements that make up the machine.

Landscapes

  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Mechanical Engineering (AREA)
  • Processing Of Solid Wastes (AREA)
  • Disintegrating Or Milling (AREA)
  • Glass Compositions (AREA)
  • Glass Melting And Manufacturing (AREA)

Abstract

The invention relates to a glass-recycling machine for obtaining cullet, of the type that comprises: a supporting structure (1), glass supply means, and cullet-storage and -removal means (10) formed by storage compartments that receive cullet from a selective discharge hopper (4). The invention also includes colour-detection means which distinguish between the types of glass, activating the selective discharge hopper (4) in order to position the zone or receptacle corresponding to the colour detected, as well as crushing means (3, 5). According to the invention, once the colour of the glass has been detected and the glass has been pressed and crushed in the crushing means (3, 5), the glass then passes into the selective discharge hopper (4) which is positioned according to the colour of glass detected and which contains screening means (8) for removing unwanted contaminants.

Description

MÁQUINA RECICLADORA DE VIDRIO PARA LA OBTENCIÓN DE CALCÍN  GLASS RECYCLING MACHINE FOR CALCIN OBTAINING
DESCRIPCIÓN  DESCRIPTION
El objeto del dispositivo reciclador de vidrio destinado al uso doméstico por parte de los consumidores de vidrio, tanto de negocios como de particulares, cuyo objetivo es realizar en origen, es decir, en el mismo punto de desecho de los envases de vidrio, una gran parte del proceso industrial de reciclaje del vidrio mediante el triturado del mismo, la separación por colores y la eliminación de residuos contaminantes, todo ello de forma totalmente automatizada y segura, de forma que el producto final obtenido sea el calcín o materia prima básica utilizada para la fabricación de vidrio nuevo. The purpose of the glass recycling device intended for domestic use by consumers of glass, both business and private, whose objective is to perform at origin, that is, at the same point of disposal of glass containers, a large part of the industrial process of recycling glass by grinding it, color separation and elimination of contaminating residues, all in a completely automated and safe way, so that the final product obtained is the calcine or basic raw material used to The manufacture of new glass.
Antecedentes de la invención Background of the invention
La recuperación de vidrio se atribuye inicialmente a Alemania y a Suiza, aunque fueron los daneses los pioneros en este campo, comenzando en 1962. La recogida selectiva de envases de vidrio es la primera que se inició en España en los años 80 (concretamente en 1982 en Barcelona, con un resultado de 836 Tm), por iniciativa de los propios fabricantes de envases con el objeto de reducir conste en su fabricación. Con el tiempo, la recogida selectiva de vidrio se va implantando en la mayoría de los grandes municipios hasta que, con la entrada en vigor de la nueva Ley 11/1997 de envases y residuos, se crea el sistema integrado de gestión (SIG) de ECOVIDRIO para el reciclado del vidrio, con el objetivo de reciclar la máxima cantidad de residuos de vidrio. The recovery of glass is initially attributed to Germany and Switzerland, although the Danes were the pioneers in this field, beginning in 1962. The selective collection of glass containers is the first that began in Spain in the 80s (specifically in 1982 in Barcelona, with a result of 836 Tm), at the initiative of the packaging manufacturers themselves in order to reduce their manufacturing. Over time, the selective collection of glass is being implemented in most large municipalities until, with the entry into force of the new Law 11/1997 on packaging and waste, the integrated management system (GIS) of ECOVIDRIO for the recycling of glass, with the aim of recycling the maximum amount of glass waste.
El vidrio recogido es, en su mayor parte, de procedencia doméstica, y es conducido en transportes especiales a las plantas de tratamiento, en donde, debidamente seleccionado, se procede a su tratamiento para el reciclado. The collected glass is, for the most part, of domestic origin, and is conducted in special transports to the treatment plants, where, properly selected, it is processed for recycling.
Generalmente, el vidrio a tratar contiene un gran número de impurezas, como tapones de plástico y metálicos, corchos, piedras, papeles, plásticos, etc. En estas condiciones, sería prácticamente imposible la fabricación de nuevos envases, ya que estos cuerpos extraños crearía defectos en el vidrio nuevo, por lo que durante una fase del proceso, el vidrio se funde a altas temperaturas para eliminar estos residuos que quedan en la superficie formando una capa denominada "nata" y que es retirada. A su vez, y para que el vidrio pueda ser reutilizado en la fabricación de nuevos envases, el requisito más importante es que esté separado por colores, distinguiendo principalmente tres de estos colores: verde, transparente y opaco o ámbar. El vidrio, una vez tratado y seleccionado por tamaño, color y tipo, es depositado en los silos para posteriormente suministrarlo a los fabricantes de vidrio que, con esta materia prima denominada "calcín", fabrican los productos de vidrio. Generally, the glass to be treated contains a large number of impurities, such as plastic and metal plugs, corks, stones, papers, plastics, etc. Under these conditions, it would be practically impossible to manufacture new containers, since these foreign bodies would create defects in the new glass, so that during a phase of the process, the glass melts at high temperatures to eliminate these residues that remain on the surface forming a layer called "cream" and that is removed. In turn, and so that the glass can be reused in the manufacture of new containers, the most important requirement is that it be separated by colors, distinguishing mainly three of these colors: green, transparent and opaque or amber. The glass, once treated and selected by size, color and type, is deposited in the silos and subsequently supplied to the glass manufacturers who, with this raw material called "calcine", manufacture the glass products.
El vidrio se recicla al 100% y puede ser reciclado una y otra vez de por vida, siendo el principal destino del vidrio recuperado la fabricación de nuevos envases que tienen exactamente las mismas características de calidad que los originales. Además, el vidrio reciclado se emplea también en la fabricación de otros productos, como encimeras de cocina, azulejos o pinturas reflectantes. Resulta necesario continuar favoreciendo el reciclaje del vidrio ya que esto aporta importantes ventajas, como el ahorro energético, la contribución a la conservación del medio ambiente, el ahorro en materias primas y otras ventajas adicionales. No obstante, y pese a las innegables ventajas del reciclado del vidrio, aproximadamente el 40% de los envases de vidrio consumidos no se reciclan y van a parar al vertedero. Particularmente, los sectores de la economía que son grandes consumidores de vidrio, como el de la hostelería y la restauración, tienen un grave déficit de reciclado de vidrio, en cuanto a que les supone un inconveniente y costes añadidos para los escasos recursos de los que disponen en su mayor parte. Además, el rápido ritmo de funcionamiento del negocio, la necesidad de un espacio de almacenamiento del vidrio, alejado de la zona de trabajo, el transporte hacia el contenedor especial, y la falta de estímulo de los organismos responsables hacen además que dichos consumidores desistan del reciclado. The glass is 100% recycled and can be recycled again and again for life, being the main destination of the recovered glass the manufacture of new containers that have exactly the same quality characteristics as the original ones. In addition, recycled glass is also used in the manufacture of other products, such as kitchen countertops, tiles or reflective paints. It is necessary to continue favoring the recycling of glass as this brings important advantages, such as energy savings, the contribution to environmental conservation, savings in raw materials and other additional advantages. However, and despite the undeniable advantages of glass recycling, approximately 40% of the glass containers consumed are not recycled and go to the landfill. Particularly, the sectors of the economy that are large consumers of glass, such as hospitality and catering, have a serious deficit of glass recycling, in that it is an inconvenience and added costs for the scarce resources of which They have for the most part. In addition, the rapid pace of operation of the business, the need for a glass storage space, away from the work area, transport to the special container, and the lack of encouragement from the responsible agencies also make these consumers desist from recycling.
Es por ello importante que parte del proceso de transformación del vidrio para su reciclaje se traslade inicialmente al consumidor, de forma que lo que llegue a las plantas de tratamiento no sean residuos de envase de vidrio mezclados y con elementos contaminantes como hasta ahora, sino algo mucho más parecido al calcín necesario para la fabricación de vidrio nuevo, desconociendo los inventores, expertos en la materia, de la existencia de una máquina como la descrita en la presente invención. Descripción de la invención It is therefore important that part of the glass transformation process for recycling is initially transferred to the consumer, so that what arrives at the treatment plants are not mixed glass container waste and with contaminant elements as until now, but something much more similar to the calcine necessary for the manufacture of new glass, ignoring the inventors, experts in the field, of the existence of a machine as described in the present invention. Description of the invention
Como ha sido descrito, el proceso de reciclado de vidrio que se utiliza en la actualidad en todos los países se realiza íntegramente en plantas de tratamiento a tal efecto, exigiendo únicamente al consumidor que, al desechar los envases de vidrio, los separen de otros residuos sólidos como plásticos, metal, cartón, así como de los residuos orgánicos para, de este modo, facilitar su tratamiento. Esto supone que gran parte del proceso de tratamiento del vidrio (y por ende, de sus costes) esté dedicado a limpiar dicho vidrio, eliminando los elementos contaminantes denominados "infusibles", como el plástico, corcho, metal, porcelana y piedras, y separarlo por colores, para finalmente obtener una materia prima pura con la que se puede fabricar vidrio nuevo: el calcín. As has been described, the glass recycling process that is currently used in all countries is carried out entirely in treatment plants for this purpose, requiring only the consumer to, when discarding the glass containers, separate them from other waste solids such as plastics, metal, cardboard, as well as organic waste to, in this way, facilitate its treatment. This means that a large part of the glass treatment process (and therefore, of its costs) is dedicated to cleaning said glass, eliminating the so-called "infusible" contaminating elements, such as plastic, cork, metal, porcelain and stones, and separating it. by colors, to finally obtain a pure raw material with which new glass can be manufactured: calcine.
La solución a este problema técnico radica en la inclusión de parte del procedimiento de tratamiento en origen, para que en vez de llegar el vidrio en crudo a las plantas de reciclado, lo que llegase fuese el calcín, triturado y separado por colores y con la mayor parte de los residuos contaminantes eliminados. The solution to this technical problem lies in the inclusion of part of the treatment process at source, so that instead of reaching the raw glass to the recycling plants, what came to be the calcine, crushed and separated by colors and with the most of the contaminant waste removed.
Es por esto que se presenta el dispositivo reciclador de vidrio que consiste esencialmente en una máquina en forma de cubo completamente estanca, a excepción hecha de una abertura superior por la que se introduce cualquier envase de vidrio, que mediante el uso de tecnología de sensorización óptica y de forma completamente automática, es separado en función de su color - verde, opaco o ámbar, y transparente - para ser triturado y separado de los residuos contaminantes como metal o plástico y que, finalmente, es depositado en bolsas estancas, ya convertido en calcín, donde se va almacenando con todas las garantías de sellado seguro, para su posterior transporte a las plantas de fabricación. This is why the glass recycling device is presented, which consists essentially of a completely watertight cube-shaped machine, with the exception of a top opening through which any glass container is introduced, which through the use of optical sensing technology and completely automatically, it is separated according to its color - green, opaque or amber, and transparent - to be crushed and separated from contaminating waste such as metal or plastic and, finally, it is deposited in waterproof bags, already converted into calcín, where it is stored with all the guarantees of safe sealing, for its subsequent transport to the manufacturing plants.
Gracias al dispositivo así descrito, se consigue, básicamente, un ahorro de costos de logística y transporte, ya que se aumentaría notablemente la capacidad de almacenamiento de los contenedores, reduciéndose la frecuencia y, por lo tanto, los costes de la recogida en vehículos recolectores especializados. Actualmente, entre el 3% y el 5% de lo que los consumidores depositan en los contenedores no es vidrio, lo que supone un coste añadido muy importante, ya que se transporta basura en lugar de vidrio, lo que redunda en un mayor coste del proceso de tratamiento. Evidentemente, aunque es necesario el tratamiento del vidrio en plantas industriales especializadas, se reducirían notablemente los costes del proceso de tratamiento de los envases de vidrio, que actualmente oscilan entre los 2o€ y los 25c por tonelada. Este ahorro de costes, del mismo modo, permite aumentar la tasa de reciclado de vidrio y el coste en cuanto a protección medioambiental. Thanks to the device so described, basically, a saving in logistics and transport costs is achieved, since the storage capacity of the containers would be significantly increased, reducing the frequency and, therefore, the collection costs in collection vehicles specialized. Currently, between 3% and 5% of what consumers deposit in containers is not glass, which is a very important added cost, since trash is transported instead of glass, which results in a higher cost of treatment process Obviously, although the treatment of glass in specialized industrial plants is necessary, the costs of the treatment process of glass containers, which currently range between € 2 and € 25c per ton, would be significantly reduced. This cost saving, in the same way, allows to increase the glass recycling rate and the cost in terms of environmental protection.
La idea que subyace en la presente invención no es tanto alterar sustancialmente el proceso de recogida y transporte, sino hacerlo más eficiente, pudiendo utilizarse tanto en los establecimientos consumidores de vidrio (restaurantes, bares, discotecas, hoteles, etc.) como en el ámbito doméstico, o bien en el propio contenedor de vidrio, debidamente adaptado. The idea that underlies the present invention is not so much to substantially alter the collection and transport process, but to make it more efficient, being able to be used both in glass-consuming establishments (restaurants, bars, discos, hotels, etc.) and in the field domestic, or in the glass container itself, properly adapted.
Breve descripción de las figuras A continuación se pasa a describir de manera muy breve una serie de dibujos que ayudan a comprender mejor la invención y que se relacionan expresamente con una realización de dicha invención que se presenta como un ejemplo no limitativo de ésta. BRIEF DESCRIPTION OF THE FIGURES A series of drawings that help to better understand the invention and that expressly relate to an embodiment of said invention that is presented as a non-limiting example thereof is described very briefly below.
FIGi. Muestra una vista en perspectiva del dispositivo reciclador de vidrio para la obtención de calcín, objeto de la presente invención. FIGi. It shows a perspective view of the glass recycling device for obtaining calcin, object of the present invention.
Realización preferente de la invención Preferred Embodiment of the Invention
La presente invención, tal y como se puede observar en las figura adjunta, consiste en un dispositivo reciclador de vidrio para la obtención de calcín, en donde dicho dispositivo comprende, esencialmente, una entrada o depósito de envases de vidrio situada en la parte superior del dispositivo y que ofrece una apertura en su zona central que facilita la caída vertical de los envases de vidrio; y en donde, además, hay un sistema de compuertas formado por una trampilla en la parte inferior de la apertura. The present invention, as can be seen in the attached figure, consists of a glass recycling device for obtaining calcine, wherein said device essentially comprises an inlet or container of glass containers located in the upper part of the device and that offers an opening in its central zone that facilitates the vertical fall of the glass containers; and where, in addition, there is a gate system formed by a trapdoor at the bottom of the opening.
En la parte baja de la compuerta, en un orificio practicado a tal efecto, se sitúa la fotocélula electrónica configurada para detectar el color del vidrio, y que activa, en función del color, la tolva de vertido selectivo (4), la cual se halla dividida en tres compartimentos, para vidrio transparente, verde y opaco o ámbar. De igual modo se activa el motor-reductor (2) para el comienzo del proceso de triturado. Este proceso de triturado se materializa, en primer lugar, con la prensa (5) situada justo debajo de la compuerta de entrada (1) y en donde, por efecto de la misma, el envase sólo puede caer de forma vertical y con el asiento de la misma hacia abajo. Esta prensa (5) está constituida, en su realización preferida, por dos placas metálicas plegadas que conforman un bloque perimetral cerrado verticalmente en forma rectangular. La posición entre ambas placas es, en su fase inicial, ligeramente abierta en la parte superior para permitir la entrada del envase de vidrio, y cerrada en la parte inferior. La unión entre ambas placas depende de un eje situado en la parte inferior de estas. La sustentación superior se realiza mediante un eje horizontal que discurre a lo largo de toda la longitud de la placa en su borde superior. In the lower part of the gate, in an orifice made for this purpose, the electronic photocell is configured to detect the color of the glass, and which activates, depending on the color, the selective pouring hopper (4), which is It is divided into three compartments, for transparent, green and opaque or amber glass. In the same way the motor-reducer (2) is activated for the beginning of the crushing process. This crushing process materializes, firstly, with the press (5) located just below the inlet gate (1) and where, as a result of it, the container can only fall vertically and with the seat of it down. This press (5) is constituted, in its preferred embodiment, by two folded metal plates that form a vertically closed perimeter block in rectangular form. The position between both plates is, in its initial phase, slightly open at the top to allow the glass container to enter, and closed at the bottom. The union between both plates depends on an axis located at the bottom of these. The upper lift is carried out by means of a horizontal axis that runs along the entire length of the plate at its upper edge.
El movimiento de dichas placas es ofrecido por el motor-reductor (2) fijado a una placa base, que transmite un movimiento circular continuo a un eje horizontal, el cual acciona dos cigüeñales y dos bielas (6) situadas a cada lado de las placas que convierten el movimiento circular inicial en movimiento horizontal. Dicho movimiento es transmitido a las placas mediante las bielas (6) consiguiendo una separación entre ellas con diferentes estados de medida. The movement of said plates is offered by the motor-reducer (2) fixed to a base plate, which transmits a continuous circular movement to a horizontal axis, which drives two crankshafts and two connecting rods (6) located on each side of the plates which convert the initial circular movement into horizontal movement. Said movement is transmitted to the plates by the connecting rods (6) achieving a separation between them with different measurement states.
Como consecuencia de esto, en la parte superior de las placas se consigue una mayor separación que en la parte inferior, siendo por ello que la primera rotura del vidrio se efectúa en la parte más alta de la prensa. En la parte inferior la separación obtenida es menor y, por tanto, la fragmentación del envase es mayor, consiguiendo unos fragmentos de tamaño muy reducido. El proceso de triturado continua tras la prensa (5) con el sistema de molido (3), el cual está constituido por al menos dos rodillos horizontales formados por tubos y ejes metálicos. Los rodillos o muelas son los encargados del triturado final del vidrio. La fijación de dicho conjunto la conforma una caja de unión que mantiene los rodillos a una separación estable de forma permanente. La caja de unión va atornillada a la parte inferior de la prensa (5). As a consequence of this, in the upper part of the plates a greater separation is achieved than in the lower part, for which reason the first breakage of the glass is carried out in the highest part of the press. In the lower part the separation obtained is smaller and, therefore, the fragmentation of the package is greater, obtaining fragments of very small size. The crushing process continues after the press (5) with the grinding system (3), which consists of at least two horizontal rollers formed by tubes and metal shafts. The rollers or wheels are responsible for the final crushing of the glass. The fixation of said assembly is formed by a junction box that keeps the rollers permanently stable. The junction box is screwed to the bottom of the press (5).
Los rodillos del sistema de molido (3) giran sobre sus ejes en sentidos opuestos, favoreciendo la caída del vidrio triturado entre ambos hacia la tolva de vertido selectivo. La transmisión de los rodillos se obtiene mediante un piñón colocado en el extremo del eje de uno de los rodillos, el cual provoca el giro del otro rodillo en sentido opuesto, por empuje. Uno de los rodillos va provisto de muelas metálicas dispuestas longitudinalmente en la superficie perimetral del mismo. The grinding system rollers (3) rotate on their axes in opposite directions, favoring the falling of the crushed glass between them towards the selective pouring hopper. The transmission of the rollers is obtained by means of a pinion placed at the end of the axis of one of the rollers, which causes the rotation of the other roller in the opposite direction, by pushing. One of the rollers is provided with metal wheels arranged longitudinally on the perimeter surface thereof.
El producto triturado cae por gravedad a la tolva de vertido selectivo (4) situada justo debajo del sistema de molido (3) y fijada a los mismos. Está constituida por una chapa metálica a través de la que se vierte el vidrio triturado a cada una de las tres bolsas receptoras en función de su color. Según el color del vidrio detectado por la fotocélula, y en función del mismo, esta chapa que actúa a modo de compuerta adopta una posición determinada, permitiendo que el vidrio triturado se deposite únicamente en su bolsa correspondiente según su color. The crushed product falls by gravity into the selective pouring hopper (4) located just below the grinding system (3) and fixed thereto. It is constituted by a metal sheet through which the crushed glass is poured into each of the three receiving bags depending on their color. Depending on the color of the glass detected by the photocell, and depending on it, this sheet acting as a gate adopts a certain position, allowing the crushed glass to be deposited only in its corresponding bag according to its color.
La tolva (4) tiene tres posiciones posibles, que son comandadas en función del color del vidrio. En la primera posición, la compuerta se mantiene totalmente vertical en línea con la salida de los rodillos del sistema de molido (3) y permitiendo el depósito del calcín (vidrio triturado y molido) en la bolsa central. En las posiciones dos y tres, la tolva adopta un ángulo de 45 o y -45 o respectivamente sobre la vertical, hacia un lado y otro respectivamente, en función del color y con el objeto de depositarlo en las bolsas laterales. The hopper (4) has three possible positions, which are commanded according to the color of the glass. In the first position, the gate is kept completely vertical in line with the exit of the rollers of the ground system (3) and allowing the deposit of the calcine (crushed and ground glass) in the central bag. In positions two and three, the hopper adopts an angle of 45 or -45 or respectively on the vertical, to one side and another respectively, depending on the color and in order to deposit it in the side bags.
La tolva (4) comprende, igualmente, medios para eliminar los residuos contaminantes no deseados que los envases contienen por defecto, como plásticos, papeles, corchos, etc. Dichos medios consisten en una criba (8) basada en una serie de varillas metálicas colocadas longitudinalmente en la tolva de vertido (4), con una separación entre ellas que permite el paso del vidrio triturado, reteniendo la mayor parte de los residuos contaminantes, que en el proceso anterior se han deformado pero no triturado, por lo que su volumen es mayor que el del vidrio. Estas varillas tienen una ligera inclinación sobre el plano horizontal para permitir la caída de estos residuos contaminantes hasta un cajetín metálico extraíble (9) desde el exterior para su vaciado, limpieza y reposición. Finalmente, los compartimentos de almacenamiento de calcín (10) están situados en la parte más baja del conjunto. Permiten la instalación diferenciada de tres unidades de bolsas para el almacenamiento del calcín, las cuales son totalmente ignífugas y estancas. El tamaño de dichas bolsas dependerá del tamaño de la máquina, lógicamente. El acceso de los usuarios a los compartimentos (10) se realiza a través de la frontal de la máquina, y por medio de una portezuela rectangular situada en la parte inferior que forma parte del cerramiento exterior de la máquina y que cuenta con cierre de seguridad que impide el funcionamiento de la máquina si está abierta. The hopper (4) also includes means to eliminate unwanted contaminating residues that the containers contain by default, such as plastics, papers, corks, etc. Said means consist of a sieve (8) based on a series of metal rods placed longitudinally in the pouring hopper (4), with a separation between them that allows the crushed glass to pass, retaining most of the contaminating waste, which in the previous process they have been deformed but not crushed, so that their volume is greater than that of glass. These rods have a slight inclination on the horizontal plane to allow the fall of these contaminating residues to a removable metal box (9) from the outside for its emptying, cleaning and replacement. Finally, the calcine storage compartments (10) are located in the lower part of the assembly. They allow the differentiated installation of three units of bags for the storage of the calcín, which are totally fireproof and watertight. The size of these bags will depend on the size of the machine, logically. The users access to the compartments (10) is done through the front of the machine, and by means of a rectangular door located at the bottom that is part of the outer enclosure of the machine and that has a closure safety that prevents the machine from working if it is open.
Todo el conjunto queda soportado por una estructura de acero (i) u otro material capaz de aguantar los distintos elementos que conforman la máquina. The whole set is supported by a steel structure (i) or other material capable of withstanding the different elements that make up the machine.

Claims

REIVINDICACIONES
1. - Máquina recicladora de vidrio para la obtención de calcín del tipo que comprende una estructura portante (i) que contiene unos medios de entrada de vidrio y unos medios de almacenamiento y retirada del calcín (10) conformados por unos compartimentos de almacenamiento que reciben el calcín de una tolva de vertido selectivo (4) caracterizada porque 1. - Glass recycling machine for obtaining calcin of the type comprising a supporting structure (i) containing glass entry means and means for storing and removing the calcine (10) formed by storage compartments that receive the calcine of a selective pouring hopper (4) characterized in that
los medios de detección de color discriminan el tipo de vidrio, activando la tolva de vertido selectivo (4) para situar la zona o depósito adecuado para el color detectado, así como unos medios de triturado, que a su vez comprenden, al menos, una prensa (5) y un sistema de molido (3);  the color detection means discriminate the type of glass, activating the selective pouring hopper (4) to locate the area or deposit suitable for the detected color, as well as crushing means, which in turn comprise at least one press (5) and a grinding system (3);
y en donde, el vidrio, una vez detectado el color, prensado y molido en los medios de triturado (3,5), pasa a la tolva de vertido selectivo (4), colocada según el color del vidrio detectado, y en donde se sitúan unos medios de cribado (8) de los elementos contaminantes no deseados, de tal forma que los compartimentos de almacenamiento reciban el calcín constituido por el vidrio triturado y cribado.  and where, the glass, once the color has been detected, pressed and ground in the crushing media (3,5), passes to the selective pouring hopper (4), placed according to the color of the detected glass, and where they place screening means (8) of the unwanted contaminating elements, such that the storage compartments receive the calcine constituted by the crushed and screened glass.
2. - Máquina recicladora de acuerdo con la reivindicación 1 caracterizada porque los medios de entrada de envases de vidrio están situados en la parte superior del dispositivo y ofrecen una apertura en su zona central que facilita la caída vertical de los envases de vidrio y con el asiento de la misma hacia abajo;  2. - Recycling machine according to claim 1 characterized in that the glass container inlet means are located in the upper part of the device and offer an opening in its central area that facilitates the vertical fall of the glass containers and with the seat it down;
y en donde, además, hay un sistema de compuertas formado por una trampilla n en la parte inferior de la apertura.  and where, in addition, there is a gate system formed by a trapdoor n at the bottom of the opening.
3. - Máquina recicladora de acuerdo con la reivindicación 2 caracterizada porque en la parte baja de la compuerta o trampilla, en un orificio practicado a tal efecto, se sitúa la fotocélula electrónica configurada para detectar el color del vidrio, y que activa, en función del color, la tolva de vertido selectivo (4).  3. - Recycling machine according to claim 2 characterized in that in the lower part of the hatch or trapdoor, in an orifice made for this purpose, the electronic photocell configured to detect the color of the glass is located, and which activates, depending on of color, the selective pouring hopper (4).
4. - Máquina recicladora de acuerdo con la reivindicación 1 caracterizada porque la tolva de vertido selectivo se halla dividida en tres compartimentos, para vidrio transparente, verde y opaco o ámbar.  4. - Recycling machine according to claim 1 characterized in that the selective pouring hopper is divided into three compartments, for transparent, green and opaque or amber glass.
5. - Máquina recicladora de acuerdo con la reivindicación 1 caracterizada porque los medios de triturado (3,5) comprenden una prensa (5) situada justo debajo de la compuerta de entrada y en donde, por efecto de la misma, el envase sólo puede caer de forma vertical y con el asiento de la misma hacia abajo;  5. - Recycling machine according to claim 1, characterized in that the grinding means (3.5) comprise a press (5) located just below the inlet gate and where, by effect thereof, the package can only fall vertically and with its seat down;
y en donde esta prensa (5) está constituida por dos placas metálicas plegadas que conforman un bloque perimetral cerrado verticalmente en forma rectangular, siendo la posición entre ambas placas (51,52), en su fase inicial, ligeramente abierta en la parte superior para permitir la entrada del envase de vidrio, y cerrada en la parte inferior. and where this press (5) is constituted by two folded metal plates that form a vertically closed perimeter block in rectangular form, the position between the two plates (51.52) being, in its initial phase, slightly open at the top to allow the glass container to enter, and closed at the bottom.
6. - Máquina recicladora de acuerdo con la reivindicación 5 caracterizada porque la unión entre las placas de la prensa (5) depende de un eje situado en la parte inferior de estas, mientras que la sustentación superior se realiza mediante un eje horizontal que discurre a lo largo de toda la longitud de la placa en su borde superior.  6. - Recycling machine according to claim 5 characterized in that the union between the plates of the press (5) depends on an axis located at the bottom of these, while the upper lift is carried out by means of a horizontal axis that runs at along the entire length of the plate at its upper edge.
7. - Máquina recicladora de acuerdo con la reivindicación 6 caracterizada porque el movimiento de las placas de la prensa es ofrecido por un motor-reductor (2) fijado a una placa base, que transmite un movimiento circular continuo a un eje horizontal, el cual acciona dos cigüeñales y dos bielas (6) situadas a cada lado de las placas que convierten el movimiento circular inicial en movimiento horizontal, siendo dicho movimiento transmitido a las placas mediante las bielas (6) consiguiendo una separación entre ellas con diferentes estados de medida.  7. - Recycling machine according to claim 6 characterized in that the movement of the press plates is offered by a motor-reducer (2) fixed to a base plate, which transmits a continuous circular movement to a horizontal axis, which it drives two crankshafts and two connecting rods (6) located on each side of the plates that convert the initial circular movement into horizontal movement, said movement being transmitted to the plates by means of the connecting rods (6) achieving a separation between them with different measurement states.
8.- Máquina recicladora de acuerdo con la reivindicación 7 caracterizada porque en la parte superior de las placas se consigue una mayor separación que en la parte inferior, siendo por ello que la primera rotura del vidrio se efectúa en la parte más alta de la prensa, y donde en la parte inferior la separación obtenida es menor y, por tanto, la fragmentación del envase es mayor, consiguiendo unos fragmentos de tamaño muy reducido.  8. Recycling machine according to claim 7, characterized in that a greater separation is achieved in the upper part of the plates than in the lower part, for which reason the first breakage of the glass is carried out in the highest part of the press , and where in the inferior part the obtained separation is smaller and, therefore, the fragmentation of the container is greater, obtaining fragments of very small size.
9. - Máquina recicladora de acuerdo con la reivindicación 1 caracterizada porque los medios de triturado (3,5) comprenden un sistema de molido (3), el cual está constituido por al menos dos rodillos horizontales formados por tubos y ejes metálicos, configurados para el triturado final del vidrio, y en donde la fijación de dicho conjunto la conforma una caja de unión que mantiene los rodillos a una separación estable de forma permanente, estando dicha caja de unión atornillada a la parte inferior de la prensa (5).  9. - Recycling machine according to claim 1 characterized in that the grinding means (3.5) comprise a grinding system (3), which is constituted by at least two horizontal rollers formed by tubes and metal shafts, configured to the final crushing of the glass, and where the fixing of said assembly is formed by a junction box that keeps the rollers permanently stable, said junction box being screwed to the bottom of the press (5).
10. - Máquina recicladora de acuerdo con la reivindicación 9 caracterizada porque los rodillos giran sobre sus ejes en sentidos opuestos, favoreciendo la caída del vidrio triturado entre ambos hacia la tolva de vertido selectivo (4), y en donde la transmisión de los rodillos se obtiene mediante un piñón colocado en el extremo del eje de uno de los rodillos, el cual provoca el giro del otro rodillo en sentido opuesto, por empuje; y donde además uno de los rodillos va provisto de muelas metálicas dispuestas longitudinalmente en la superficie perimetral del mismo.  10. - Recycling machine according to claim 9 characterized in that the rollers rotate on their axes in opposite directions, favoring the falling of the crushed glass between them towards the selective pouring hopper (4), and where the transmission of the rollers is obtained by means of a pinion placed at the end of the axis of one of the rollers, which causes the rotation of the other roller in the opposite direction, by pushing; and where in addition one of the rollers is provided with metal wheels arranged longitudinally on the perimeter surface thereof.
11.- Máquina recicladora de acuerdo con la reivindicación 1 caracterizada porque el producto triturado en los medios de triturado (3,5) cae por gravedad a la tolva de vertido selectivo (4) situada justo debajo del sistema de molido (3) y fijada a los mismos, estando dicha tolva (4) constituida por una chapa metálica a través de la que se vierte el vidrio triturado a cada una de las tres bolsas receptoras en función de su color. 11. Recycling machine according to claim 1 characterized in that the crushed product in the crushing means (3,5) falls by gravity to the selective pouring hopper (4) located just below the grinding system (3) and fixed thereto, said hopper (4) being constituted by a metal sheet through which the crushed glass is poured to each of the three receiving bags depending on their color.
12.- Máquina recicladora de acuerdo con la reivindicación 11 caracterizada porque la tolva (4) tiene tres posiciones posibles, que son comandadas en función del color del vidrio, donde en la primera posición, la compuerta se mantiene totalmente vertical en línea con la salida de los rodillos del sistema de molido (3) y permitiendo el depósito del calcín en la bolsa central, mientras que en las posiciones dos y tres, la tolva (4) adopta un ángulo de 45 o y -45 o respectivamente sobre la vertical, hacia un lado y otro respectivamente, en función del color y con el objeto de depositarlo en las bolsas laterales. 12. Recycling machine according to claim 11, characterized in that the hopper (4) has three possible positions, which are controlled according to the color of the glass, where in the first position, the gate is kept completely vertical in line with the outlet of the rollers of the grinding system (3) and allowing the deposition of the calcine in the central bag, while in positions two and three, the hopper (4) adopts an angle of 45 or y -45 or respectively on the vertical, towards one side and another respectively, depending on the color and in order to deposit it in the side bags.
13. - Máquina recicladora de acuerdo con la reivindicación 1 caracterizada porque los medios de cribado (8) consisten, esencialmente, en una criba basada en una serie de varillas metálicas colocadas longitudinalmente en la tolva de vertido selectivo (4), con una separación entre ellas que permite el paso del vidrio triturado, reteniendo la mayor parte de los residuos contaminantes, y donde estas varillas tienen una ligera inclinación sobre el plano horizontal para permitir la caída de estos residuos contaminantes hasta un cajetín metálico extraíble (9) desde el exterior para su vaciado, limpieza y reposición.  13. - Recycling machine according to claim 1 characterized in that the screening means (8) consist essentially of a screen based on a series of metal rods placed longitudinally in the selective pouring hopper (4), with a separation between they that allow the passage of the crushed glass, retaining most of the contaminating residues, and where these rods have a slight inclination on the horizontal plane to allow the fall of these contaminating residues to a removable metal box (9) from the outside to its emptying, cleaning and replacement.
14. - Máquina recicladora de acuerdo con la reivindicación 1 caracterizada porque los compartimentos de almacenamiento de calcín (10) están situados en la parte más baja del conjunto y están configurados para la instalación diferenciada de tres unidades de bolsas para el almacenamiento del calcín, las cuales son ignífugas y estancas.  14. - Recycling machine according to claim 1 characterized in that the calcine storage compartments (10) are located in the lower part of the assembly and are configured for the differentiated installation of three units of bags for the storage of the calcine, which are fireproof and waterproof.
PCT/ES2010/070696 2009-10-28 2010-10-27 Glass-recycling machine for obtaining cullet WO2011051530A2 (en)

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CN111356533A (en) * 2017-10-16 2020-06-30 格雷赛尔有限责任公司 Apparatus for treating and separating inorganic solid waste
CN110304367A (en) * 2019-07-15 2019-10-08 泰山学院 A kind of residential quarters garbage classification system
IT201900016367A1 (en) 2019-09-16 2021-03-16 Eco Sistem San Felice S R L SYSTEM FOR ON SITE DISPOSAL OF GLASS ARTICLES
WO2021053478A1 (en) 2019-09-16 2021-03-25 Y.E.S. S.R.L. Young Ecology Society System for the in situ disposal of glass articles

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WO2011051530A3 (en) 2011-07-07
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