WO2011040787A3 - 고흡장성 혼합금속산화물 촉매를 통한 희박 질소산화물 분해처리 방법 - Google Patents

고흡장성 혼합금속산화물 촉매를 통한 희박 질소산화물 분해처리 방법 Download PDF

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WO2011040787A3
WO2011040787A3 PCT/KR2010/006714 KR2010006714W WO2011040787A3 WO 2011040787 A3 WO2011040787 A3 WO 2011040787A3 KR 2010006714 W KR2010006714 W KR 2010006714W WO 2011040787 A3 WO2011040787 A3 WO 2011040787A3
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mixed metal
metal oxide
nitrogen oxides
oxide catalyst
exhaust gas
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PCT/KR2010/006714
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English (en)
French (fr)
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WO2011040787A2 (ko
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장길상
팽소산
박서영
양기선
한아름
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상명대학교 산학협력단
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Publication of WO2011040787A2 publication Critical patent/WO2011040787A2/ko
Publication of WO2011040787A3 publication Critical patent/WO2011040787A3/ko

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9413—Processes characterised by a specific catalyst
    • B01D53/9422—Processes characterised by a specific catalyst for removing nitrogen oxides by NOx storage or reduction by cyclic switching between lean and rich exhaust gases (LNT, NSC, NSR)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/54—Nitrogen compounds
    • B01D53/56—Nitrogen oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B01D2255/102—Platinum group metals
    • B01D2255/1023—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20746—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20753—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/209—Other metals
    • B01D2255/2092—Aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/90—Physical characteristics of catalysts
    • B01D2255/91—NOx-storage component incorporated in the catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/40—Nitrogen compounds
    • B01D2257/402—Dinitrogen oxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/40—Nitrogen compounds
    • B01D2257/404—Nitrogen oxides other than dinitrogen oxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/502—Carbon monoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/702—Hydrocarbons
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/10—Capture or disposal of greenhouse gases of nitrous oxide (N2O)

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Catalysts (AREA)

Abstract

본 발명은 혼합금속산화물 촉매를 이용한 질소산화물의 분해처리 방법에 관한 것으로, 보다 상세하게는 흡장 성능이 뛰어난 하이드로탈사이트형 전구체로부터 제조된 혼합 금속 산화물 촉매를 사용하여 엔진 연소시의 배기가스에서 희박 질소산화물을 분해 처리하는 방법을 제공함으로써, 이에 의하여 희박 NOx 및 N2O를 산소와 분리 흡착한 후 별도의 환원제 없이 엔진의 리치(Rich) 가동시 배기가스의 CO 및 HC를 환원제로 사용하여 흡장된 질소산화물을 분해 탈착함으로써 배기가스에서 질소산화물을 효율적으로 제거할 수 있는 장점이 있다.
PCT/KR2010/006714 2009-09-30 2010-09-30 고흡장성 혼합금속산화물 촉매를 통한 희박 질소산화물 분해처리 방법 WO2011040787A2 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2009-0093424 2009-09-30
KR1020090093424A KR101029642B1 (ko) 2009-09-30 2009-09-30 고흡장성 혼합금속산화물 촉매를 통한 희박 질소산화물 분해처리 방법

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WO2011040787A2 WO2011040787A2 (ko) 2011-04-07
WO2011040787A3 true WO2011040787A3 (ko) 2011-09-09

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PCT/KR2010/006714 WO2011040787A2 (ko) 2009-09-30 2010-09-30 고흡장성 혼합금속산화물 촉매를 통한 희박 질소산화물 분해처리 방법

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KR (1) KR101029642B1 (ko)
WO (1) WO2011040787A2 (ko)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018114245A1 (en) * 2016-12-19 2018-06-28 Scg Chemicals Co., Ltd. NOx STORAGE AND REDUCTION CATALYST AND METHOD FOR PREPARING THE SAME
CN109012688A (zh) * 2018-08-17 2018-12-18 太原理工大学 一种类水滑石基NiMnFe低温脱硝催化剂的制备方法及应用
CN108993530B (zh) * 2018-08-17 2021-05-18 太原理工大学 一种水滑石基NiMnTi催化剂的制备方法和应用
CN109499568B (zh) * 2018-12-31 2022-02-08 天津大学 基于铁改性水滑石衍生氧化物的柴油车尾气净化催化剂及其制备方法
KR102618881B1 (ko) * 2020-11-18 2023-12-29 고려대학교 산학협력단 반복 흡착 성능이 증진된 저온 질소산화물 흡착제 및 이의 제조 방법
CN114558580B (zh) * 2022-01-25 2023-10-27 晋中学院 水滑石基CoNiV复合氧化物催化剂的制备方法及逃逸氨脱除应用

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07163870A (ja) * 1993-08-27 1995-06-27 Engelhard Corp Ｎ２ｏのｎ２ｏ含有気体混合物からの除去法
JP2866928B2 (ja) * 1996-09-06 1999-03-08 工業技術院長 亜酸化窒素分解用触媒及び亜酸化窒素の除去方法
KR100287050B1 (ko) * 1995-11-09 2001-05-02 와다 아끼히로 엔진의 배기가스를 정화하기 위한 방법 및 장치
KR100654885B1 (ko) * 2005-06-01 2006-12-06 장길상 일산화탄소를 이용한 질소산화물의 분해방법

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100569084B1 (ko) * 2004-08-26 2006-04-07 한국화학연구원 이중촉매층을 이용한 질소산화물의 정화방법
KR100836907B1 (ko) 2006-06-23 2008-06-12 희성촉매 주식회사 디젤엔진 배기가스 중 질소산화물의 흡장-환원 제거용전이금속 치환 하이드로탈사이트 촉매

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07163870A (ja) * 1993-08-27 1995-06-27 Engelhard Corp Ｎ２ｏのｎ２ｏ含有気体混合物からの除去法
KR100287050B1 (ko) * 1995-11-09 2001-05-02 와다 아끼히로 엔진의 배기가스를 정화하기 위한 방법 및 장치
JP2866928B2 (ja) * 1996-09-06 1999-03-08 工業技術院長 亜酸化窒素分解用触媒及び亜酸化窒素の除去方法
KR100654885B1 (ko) * 2005-06-01 2006-12-06 장길상 일산화탄소를 이용한 질소산화물의 분해방법

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KR20110035621A (ko) 2011-04-06
KR101029642B1 (ko) 2011-04-15

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