WO2010114282A4 - Method for manufacturing abrasion-resistant vapor-permeable waterproof fabric having excellent dryness and design, vapor-permeable waterproof fabric and waterproof garments manufactured by same, and method for manufacturing a seam-sealing tape for garment sewing - Google Patents

Method for manufacturing abrasion-resistant vapor-permeable waterproof fabric having excellent dryness and design, vapor-permeable waterproof fabric and waterproof garments manufactured by same, and method for manufacturing a seam-sealing tape for garment sewing Download PDF

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Publication number
WO2010114282A4
WO2010114282A4 PCT/KR2010/001934 KR2010001934W WO2010114282A4 WO 2010114282 A4 WO2010114282 A4 WO 2010114282A4 KR 2010001934 W KR2010001934 W KR 2010001934W WO 2010114282 A4 WO2010114282 A4 WO 2010114282A4
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Prior art keywords
fabric
weight
parts
resistant
waterproof
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PCT/KR2010/001934
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French (fr)
Korean (ko)
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WO2010114282A2 (en
WO2010114282A3 (en
Inventor
박민숙
박명수
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Park Min Suk
Park Myung Soo
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Publication of WO2010114282A2 publication Critical patent/WO2010114282A2/en
Publication of WO2010114282A3 publication Critical patent/WO2010114282A3/en
Publication of WO2010114282A4 publication Critical patent/WO2010114282A4/en

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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0095—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by inversion technique; by transfer processes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B1/00—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating
    • D06B1/10—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating by contact with a member carrying the treating material
    • D06B1/14—Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating by contact with a member carrying the treating material with a roller
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/345—Nitriles
    • D06M13/348—Nitriles unsaturated, e.g. acrylonitrile
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0092—Non-continuous polymer coating on the fibrous substrate, e.g. plastic dots on fabrics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/12—Hydrophobic properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/10—Properties of the materials having mechanical properties
    • D06N2209/105—Resistant to abrasion, scratch
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/12—Permeability or impermeability properties
    • D06N2209/121—Permeability to gases, adsorption
    • D06N2209/123—Breathable
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/12—Permeability or impermeability properties
    • D06N2209/126—Permeability to liquids, absorption
    • D06N2209/128—Non-permeable
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00—Specially adapted uses
    • D06N2211/10—Clothing

Definitions

  • the present invention relates to a method for producing a wear resistant breathable waterproof fabric excellent in dry feeling and design, a moisture permeable waterproof fabric, a waterproof garment, and a method for manufacturing a ventricular ring tape for sewing clothing,
  • the surface treatment agent resin composition is coated on the moisture permeable waterproof coating surface or the laminating film surface by the synchronous grained cylinder up-loading method to maximize the dry feeling, the pleasant feeling and the cold feeling by direct contact with the skin,
  • the pattern effectively and firmly on the coated surface of the fabric it is possible to omit the lining due to the designing, and thus the breathable and waterproof fabric with improved lightness and packability, the waterproof clothing and the garment sewing
  • a method for manufacturing a ventricular ring tape for a heart is a method for producing a wear resistant breathable waterproof fabric excellent in dry feeling and design, a moisture permeable waterproof fabric, a waterproof garment, and a method for manufacturing a ventricular ring tape for sewing clothing.
  • the breathable waterproof coating fabric is widely used for various active sportswear and casual wear such as skiing, golf wear, hiking, climbing, jogging suit, etc.
  • the surface cloth is mainly made by applying moistureproof waterproof coating to the non-thick synthetic fiber fabric It is common.
  • the water-permeable and waterproof fabric is usually subjected to water-repellent processing so as to exclude moisture from the outside, which is applied to starting water (before moisture-permeable water-resistant coating) or late water (after moisture-permeable water-resistant coating).
  • the conventional breathable and waterproof fabric has a three-layer structure composed of a two-layer structure composed of a fiber layer and a coating layer, a fiber layer (outer layer), a coating layer and a fiber layer (lining). , And finally, it becomes a three-layered fabric. Therefore, there has been a disadvantage that the touch feeling becomes dull, the volume and the weight become large, and the manufacturing cost rises because of the eye detection part.
  • the anti-abrasion property and the scratch resistance are weak, so that the durability of washing is insufficient and the antibacterial and deodorizing performance of the coated surface is poor.
  • Korean Patent Laid-Open Publication No. 2004-0004301 a method of foaming a surface treatment agent with a foaming agent is used in order to impart a roughness.
  • a foaming cell is formed on the surface, abrasion resistance is poor, I have a problem to leave.
  • stone powder, silicate, calcium carbonate, etc. which are used as shrinkage additives, are difficult to impart slipperiness to the surface after processing and have a disadvantage that they are not robust against washing or dry cleaning.
  • the present invention has been made to solve the problems of the prior art as described above, and it is an object of the present invention to provide a cosmetic composition which is excellent in dry feeling and abrasion resistance and is not only good in wearing feeling but also light in weight and small in volume when folded, And a method of manufacturing a moisture-permeable and waterproof fabric which is not required to be provided with design by pattern.
  • Another object of the present invention is to provide a moisture-permeable and waterproof fabric having excellent dryness and abrasion resistance and high durability in washing, which is produced by the above method.
  • Another object of the present invention is to provide a method for manufacturing a waterproof garment and a ventricular ring tape for garment sewing sewn by employing the breathable waterproof fabric.
  • the present invention relates to a method for fabricating a knitted fabric, comprising the steps of: performing a breathable and waterproof coating process on a fabric after weaving or knitting; Or heat-resistant, solvent-resistant high molecular weight spherical particles selected from crosslinked polymethyl methacrylate polymer fine particles or crosslinked polyurethane high molecular particles; and a step of transfer coating the surface treating agent resin composition by a synchronous grained cylinder up- And drying the coated fabric.
  • the present invention also provides a method of manufacturing a wear resistant waterproof breathable fabric provided with a dry feeling and a design.
  • the manufacturing method of the present invention may further include a step of water-repellent processing before or after the moisture-permeable waterproof coating.
  • the depth of the pattern of the synchronous grabbed cylinder is preferably 40 to 300 mu m.
  • preferred embodiments of the surface treating agent resin composition include 30 to 300 parts by weight of a mixed organic solvent, 30 to 300 parts by weight of a glass pearl, 100 to 300 parts by weight of a pigment pigment 3 to 6 parts by weight, an antiblocking agent in an amount of 1.5 to 15 parts by weight, and a coupling agent comprising an organic-inorganic hybrid compound in an amount of 0.5 to 2.0 parts by weight.
  • the surface treatment agent resin composition As another preferred embodiment of the surface treatment agent resin composition, 30 to 300 parts by weight of a mixed organic solvent, 100 to 300 parts by weight of a crosslinked polymethylmethacrylate polymer fine particle or a crosslinked polyurethane polymer fine particle is added to 100 parts by weight of a polyurethane resin (solid basis) 30 to 300 parts by weight of heat-resistant, solvent-resistant high molecular weight spherical particles, 3 to 6 parts by weight of pigment pigment and 1.5 to 15 parts by weight of an anti-blocking agent.
  • a mixed organic solvent 100 to 300 parts by weight of a crosslinked polymethylmethacrylate polymer fine particle or a crosslinked polyurethane polymer fine particle is added to 100 parts by weight of a polyurethane resin (solid basis) 30 to 300 parts by weight of heat-resistant, solvent-resistant high molecular weight spherical particles, 3 to 6 parts by weight of pigment pigment and 1.5 to 15 parts by weight of an anti-blocking agent.
  • the surface treating agent composition further contains an inorganic antibacterial agent or a bioceramics deodorant in an amount of 30 parts by weight or less, and the inorganic antibacterial agent is preferably an inorganic ceramic material zeolite-based.
  • the mixed organic solvent is at least two selected from the group consisting of toluene, methyl ethyl ketone, dimethyl formamide, isopropyl alcohol, xylene, perchlorethylene, acetone and ethyl acetate.
  • the viscosity of the surface treating agent resin composition of the present invention is preferably 2,000 to 50,000 cps, and the total solid content of the surface treating agent resin composition is preferably 20 to 50%.
  • the present invention provides an abrasion resistant waterproof fabric which is manufactured by the above-described method and has a pattern depth of 40 to 300 ⁇ m transferred to a breathable and waterproof coated face of a cloth and a synchro-graved cylinder of 40 to 300 ⁇ m to impart dry feeling and designability.
  • the present invention provides a waterproof garment to which the wear resistant breathable waterproof fabric is applied to impart a dried feeling of dryness and designability.
  • the present invention relates to a method for manufacturing a ventilating ring tape fabric, which comprises sequentially laminating a release paper, a hot-melt adhesive layer and a heat-resistant resin film layer made of a polyurethane resin,
  • the surface treatment agent resin composition of the present invention is transferred and coated on the heat-resistant resin film layer of the fabric by a synchro-grained cylinder up-loading method to knit a pattern, and then slit or cut to cut a ventricle ring tape Of the present invention.
  • an inorganic antibacterial agent or a bioceramics deodorant may be further contained in the surface treatment composition in an amount of 30 parts by weight or less.
  • the ventricular ring tape for garment sewing of the present invention satisfies a residual strain of 35% or less.
  • the present invention can provide a method of manufacturing an abrasion resistant breathable waterproof fabric which effectively and firmly transfers a resin composition of a specific component of a surface treatment agent on a breathable and waterproof fabric coated surface by a synchronous grained cylinder up-loading method.
  • the present invention provides a method of manufacturing a wear resistant breathable waterproof fabric by maximizing the dryness, comfort, and cold feeling upon direct contact with the skin, and effectively and firmly transferring the pattern from the synchronized graved cylinder
  • the present invention can provide a breathable and waterproof fabric having improved lightness and packability, a waterproof clothing using the same, and a method of manufacturing a ventricular ring tape for sewing clothes.
  • Example 2 shows the results of the 100-time abrasion test of the breathable and waterproof fabric prepared in Example 1 of the present invention
  • FIG. 3 shows the results of the 100-time abrasion test of the moisture-permeable and waterproof fabric prepared in Example 4 of the present invention
  • the present invention relates to a method for producing a water-proof, water-repellent, water-repellent or water-repellent fabric, comprising the steps of: Or heat-resistant, solvent-containing polymeric spherical particles selected from crosslinked polymethylmethacrylate polymer fine particles or crosslinked polyurethane polymer fine particles; A second step of transcribing the surface treating agent resin composition containing a single or mixed form thereof by a synchronous grained cylinder up-loading method, and a third step of drying the transcription coated raw material, And a method of manufacturing the wear resistant breathable waterproof fabric.
  • the moisture-permeable and waterproof fabric may be fabricated by weaving or knitting the fabric, dyeing and water-repellent processing, coating with a synthetic resin coating solution by direct or transfer coating method, Or may be supplied to the transfer coating process in a rolled state after water-repellent processing (late water) after coating with a synthetic resin coating liquid, omitting water-repellent processing after weaving or knitting dyeing.
  • the manufacturing method of the present invention can further perform the water-repellent processing step before or after the moisture-permeable, water-repellent coating.
  • the moisture-permeable water-repellent coating and the water-repellent processing can be performed before and after the water- If water-repellent processing is performed before, water-repellent water-repellent treatment is applied after coating with a synthetic resin coating liquid.
  • the surface treatment agent resin composition is supplied on the surface of a synchronized gravelled cylinder (engraved roll) to cover both sides, And then scraped the surface of the roll (cylinder) uniformly with a scrapper to remove the resin composition in areas other than the engraved surface, and then transfer coating is performed on the coated surface of the waterproof fabric with a predetermined thickness and pattern .
  • the coating method is a method of uniformly and effectively transferring a resin composition having a high viscosity (about 2,000 to 50,000 cps) by supplying and treating the surface treating agent resin composition in an up-dipping manner on a moisture permeable waterproof coating surface or a laminating film surface on a synchronously grained cylinder So that it can be fixed.
  • the principle of transfer adhesion of the surface treatment agent is a principle of transferring the surface treatment resin composition stuck to the synchronously grafted cylinder to the adherend by passing the adherend while passing the adherend between the synchro-grafted cylinder and the cushion roll, Both of the case where the roll is positioned at the lower end and the case where the roll is positioned at the upper end are possible, but it is more preferable to place the cushion roll at the lower end in terms of the stability of the transfer.
  • the reason for this transfer coating method is to give a roughness to the coating surface of the waterproof fabric.
  • it is required to increase the solid content of the resin composition of the surface treatment agent as much as possible and, as the solid content increases, It will be readily understood by those skilled in the art that the viscosity also increases.
  • the amount of evaporation during the drying heat treatment can be minimized, and further, the resin composition to be transferred from the synchronized grabbed cylinder can be transferred and fixed to a certain thickness.
  • the depth of pattern of the synchronized grabbed cylinder is preferably 40 to 300 mu m. If the depth of the synchro-grained cylinder is shallower than 40 ⁇ , the development of depressions and depressions becomes insufficient, and when the plate is formed deeply in excess of 300 ⁇ , uniform transfer of the resin composition becomes difficult or the transfer pattern becomes distorted Lt; / RTI > That is, when the depth is too deep compared with the pattern size, the transfer rate may become poor.
  • the resin composition of the surface treatment agent used in the transcription coating step of the present invention should have no change in physical properties at a temperature of about 200 ° C and may be any one of toluene, methyl ethyl ketone, dimethyl formamide, isopropyl alcohol, xylene, perchlorethylene, acetone, It is preferable to use sphere-shaped particles of heat-resistant solvent which satisfy insolubility in the organic solvent of Preferably a glass bead or a crosslinked poly (methyl methacrylate) polymer fine particle or a crosslinked polyurethane polymer fine particle, and the mixed form thereof may also be applied.
  • preferred embodiments of the surface treating agent resin composition include 30 to 300 parts by weight of a mixed organic solvent, 30 to 300 parts by weight of a glass bead, 3 to 6 parts by weight of a pigment pigment, 1.5 to 15 parts by weight of an antiblocking agent, and 0.5 to 2.0 parts by weight of a coupling agent comprising an organic-inorganic hybrid compound.
  • glass pearl is used as a preparation for a combined functionality such as dryness, abrasion resistance, irregularity and slipperiness, and the shape of the glass pearl is preferably bead.
  • the slip property due to friction is excellent, and when touching the skin, a feeling of stickiness can not be felt, and a dry and pleasant feeling can be given.
  • waterproof clothing having excellent packability is frequently worn in the spring and summer season, so that it is possible to impart a cool feeling effect to the skin when it comes into contact with the skin due to the nature of inorganic grass pearl in terms of comfort.
  • the glass pearls preferably have a spherical shape with a diameter of 5 to 100 mu m, more preferably 8 to 40 mu m. If the diameter of the glass pearl is less than 5 mu m, the effect of the multi-functional property is insufficient. If the diameter is more than 100 mu m, the surface touch is coarse and the wearing feeling is poor.
  • composition of the glass pearl SiO 2 70 ⁇ 73 wt%, Al 2 O 3 0.8 ⁇ 1.0 wt%, CaO 7 ⁇ 12 wt%, MgO 1.0 ⁇ 4.5% by weight, Na 2 O 3 and K 2 O 13 ⁇ 15% by weight ≪ / RTI > Or SiO 2 52 ⁇ 56 wt%, Al 2 O 3 12 ⁇ 16% by weight, CaO 16 ⁇ 25 wt%, MgO 0 ⁇ 6 wt%, TiO 2 0 ⁇ 0.5% by weight, B 2 O 3 5 ⁇ 13% by weight , Na 2 O 3 and 0 to 0.8 wt% K 2 O; And the composition of the raw material components may be somewhat different. However, in view of economical efficiency, it may be selected from known Grass pearl.
  • a coupling agent composed of an acrylic-based monofunctional or multifunctional monomer and an organic-inorganic hybrid compound comprising phosphorus compound is used, and the coupling agent is an inorganic glass-
  • the effect of increasing the bonding force and dispersibility with the urethane resin can be imparted.
  • the coupling agent is used in an amount of 0.5 to 2.0 parts by weight based on 100 parts by weight of the polyurethane resin (solid basis).
  • the surface treating agent resin composition 30 to 300 parts by weight of a mixed organic solvent, 100 to 200 parts by weight of a crosslinking agent selected from crosslinked polymethyl methacrylate polymer fine particles or crosslinked polyurethane polymer fine particles, based on 100 parts by weight of a polyurethane resin (solid basis) 30 to 300 parts by weight of any one of the heat-resistant solvent-resistant spherical particles, 3 to 6 parts by weight of pigment pigment and 1.5 to 15 parts by weight of an anti-blocking agent.
  • a crosslinking agent selected from crosslinked polymethyl methacrylate polymer fine particles or crosslinked polyurethane polymer fine particles, based on 100 parts by weight of a polyurethane resin (solid basis) 30 to 300 parts by weight of any one of the heat-resistant solvent-resistant spherical particles, 3 to 6 parts by weight of pigment pigment and 1.5 to 15 parts by weight of an anti-blocking agent.
  • the above-mentioned surface treatment agent resin composition it is advantageous in terms of processability because it contains any one of the heat-resistant, solvent-resistant high molecular weight spherical particles selected from crosslinked polymethyl methacrylate polymer fine particles or crosslinked polyurethane polymer fine particles.
  • the surface treating agent resin composition of the present invention is preferably a one-component type polyurethane resin as the main resin binder, since it has favorable metastability in a synchronized grained cylinder and can eliminate surface tackiness after drying.
  • the pigment pigment is used in an aesthetic point of view since it does not use eye detection.
  • silica-based fine powder may be employed as the anti-blocking agent employed for the synergistic effect of drying feeling.
  • the surface treatment agent composition further contains an inorganic antibacterial agent or a bioceramics deodorant in an amount of 30 parts by weight or less.
  • zeolite-based inorganic antibacterial agent in which silver (Ag) and zinc (Zn) are supported in an ionic form is harmless to the human body and has sterilizing power and anti-microbial power for preventing sweat Excellent.
  • a known substance for anion release may be added to the surface treatment agent composition.
  • Examples of the mixed organic solvent used for controlling the dissolution and viscosity of the surface treatment agent resin composition include toluene, methyl ethyl ketone, dimethyl formamide, isopropyl alcohol, xylene, perchlorethylene, acetone, Ethyl acetate or the like, or two or more mixed solvents, and it is preferable to adjust the solvent in consideration of the solubility of the resin such as resin.
  • the viscosity of the resin composition for surface treatment of the present invention is preferably 2,000 cps or more, and more preferably 2,000 to 50,000 cps. If the viscosity of the surface treating agent resin composition is less than 2,000 cps, there is a problem of sedimentation due to the weight of the spherical glass pearl. In this way, when spherical glass pearls are precipitated, the properties of the multi- The viscosity of the resin composition is preferably 2,000 cps or more.
  • another effective method of giving a roughness to the coated surface is to design the solid content of the finally compounded resin composition to a high level within a range that does not hinder workability. Specifically, Is 20% or more, and more preferably 30 to 50%.
  • the effect of the effect can be expected to be increased by the depth of the sculpture in roll forming.
  • the roll patterning method can be divided into a film corroded plate and a carved plate.
  • the film corroded plate is corroded at a depth of about 5 to 20 ⁇ m by applying a photosensitive liquid to a copper-plated cylinder and then developing the film It is a method of expressing the engraved pattern, and it is possible to form the pattern with low depth in general.
  • the engraving pattern is expressed on a roll cylinder using a mill, and the depth of the film can be expressed in a range of usually 40 to 500 mu m, so that it is easy to maximize the application amount of the surface treatment agent resin composition.
  • the depth of the equator according to the size of the pattern, i. E. The number of eyes.
  • the drying process of the third step includes a drying process of the resin composition of the surface treating agent after the transfer coating by the synchro-grained cylinder up-loading method, which is performed in the chamber to which the hot air is supplied.
  • the step of surface-treating the above-mentioned surface treatment agent resin composition by a synchronous grained cylinder up-loading method, and then passing through a heat treatment chamber to evaporate the used solvent and harden the resin binder to fix it on the fabric The chamber may also be indirectly heated or directly radiated.
  • the direct heat radiation method requires special attention from the viewpoint of fire and the like.
  • the use of a substance that lowers the surface tension of the treated fabric such as a water repellent agent, a softener, a wax or the like not only lowers the transfer rate of the resin composition, It is better to avoid this.
  • the present invention relates to a method for producing a wear resistant breathable fabric according to the present invention, wherein a depth of a pattern of a synchronized grained cylinder is transferred to a moisture permeable coating surface of a fabric in a range of 40 to 300 ⁇ m, Provide waterproof fabric.
  • the moisture-permeable and waterproof fabric of the present invention showed almost no change in weight before and after abrasion as a result of 100 times abrasion resistance test, and excellent abrasion resistance without change in appearance due to abrasion damage can be confirmed ( Figs. 2 to 4 ).
  • the present invention provides a waterproof garment to which the wear resistant breathable waterproof fabric is applied to impart a dried feeling of dryness and designability.
  • the waterproof clothing of the present invention can be obtained by coating a surface treatment resin composition having a specific composition on the moisture permeable waterproof coating surface or the laminating film surface by a synchro engraved cylinder up-loading coating method (FIG. 1) , It is possible to maximize the feeling of dryness, comfort, and cold feeling upon direct contact with the skin. In addition, by transferring the pattern from the synchro-engined cylinder to the far-end coating surface effectively and firmly, designability can be imparted and the lining can be omitted. Accordingly, it is possible to provide a waterproof garment imparted with light weight, dry feeling, and designability.
  • the present invention can be applied to the case where a surface-treated coated fabric for an inner detection is sewn, especially in the case of a waterproof or breathable waterproof fabric, It is natural.
  • the present invention relates to a process for producing a ventral ring tape fabric material in which a release paper, a hot-melt adhesive layer and a heat-resistant resin film layer made of a polyurethane resin are successively laminated,
  • the present invention also provides a method of manufacturing a ventricular ring tape for garment sewing, which comprises slicing or cutting a pattern after transferring the pattern by transcription using a synchronized in-cylinder cylinder up-loading method.
  • the surface treating agent resin composition and the grafted cylinder up-loading method are the same as those described above in detail.
  • an inorganic antibacterial agent or an inorganic antibacterial agent is added to 100 parts by weight of a polyurethane resin It will be appreciated that the bioceramics deodorant may be further contained in an amount of 30 parts by weight or less.
  • the ventricular ring tape according to the present invention is used for sealing a sewing line of a waterproof fabric.
  • an eco-friendly hot-melt adhesive layer is formed on the release paper by an extrusion method to a thickness of 30 to 80 m.
  • the heat-resistant resin film layer is formed into a thickness of 20 to 70 ⁇ by a casting method or an extrusion method, laminated by heat-joining with the hot-melt adhesive layer, and then laminated on the heat-resistant resin film layer with a phosphorus- Transfer coating by graved cylinder up-loading method.
  • the ventricular ring tape of the present invention satisfies a residual strain of 35% or less.
  • Inorganic microparticulate compound coupling agent 0.5 kg (manufactured by Microfellow Co., Ltd.), 100 kg of a liquid polyurethane resin containing 30% of a resin solid content, 40 kg of a glass pearl, 20 kg of a pigment pigment toner (2% of pigment solid content), 5 kg of a zeolite inorganic antibacterial agent, -502 product] and 2 kg of silica powder were mixed in 25 kg of a mixed organic solvent (mixed organic solvent in which dimethylformamide: toluene: methyl ethyl ketone was mixed at a weight ratio of 1: 5: 2) and stirred until the powders were completely mixed , And filtered by a screen mesh of 100 mesh. At this time, Grass pearls having a spherical particle diameter distribution of 8 to 30 mu m were used.
  • Denier Nylon yarn was woven and dyed with a lips-top fabric, and a waterproof fabric coated with moisture-permeable and water-resistant polyurethane resin was subjected to one-side water-repellent processing on the face face of the raw fabric and then wound on a riveting machine roll.
  • Rolled coating was carried out by a negative roll of an electronic engraving plate (depth of 80 ⁇ , prime 30, lattice quadrangle).
  • the waterproof fabric unwound from Unwinderer roll was passed through the coating head of the synchronized grabbed cylinder to allow the surface treatment resin composition prepared in step 1 to be transferred onto the surface of the waterproof fabric coated with moisture permeable and waterproof polyurethane resin.
  • the surface treated waterproof fabric was passed through a drying chamber by hot air to dry the surface treating agent.
  • the temperature of the hot air in the chamber was 120 ⁇ , and the flow rate through the chamber was 10 m / min. .
  • Example 2 The same procedure as in Example 1 was carried out except that in Example 1, a transcription coating operation was carried out with a synchronous grained cylinder having a depth of 30 mu m by a film corroded plate instead of an engraved grained cylinder, And processed.
  • Transfer coating was carried out in the same manner as in Example 1 except that 10 kg of aluminosilicate-based deodorant was added to the surface treating agent resin composition of Example 1.
  • Example 1 The surface coating agent of Example 1 was coated with a waterproof cloth in the same manner as in Example 1, except that calcium carbonate was used instead of the glass powder contained in the resin composition.
  • Transparent coating of the waterproof fabric was performed in the same manner as in Example 1, except that the glass beads were not contained in the resin composition of the surface treating agent of Example 1.
  • Example 4 The same procedure as in Example 4 was carried out except that the particle diameter distribution of the heat-resistant solvent-resistant polymer fine particles composed of polymethyl methacrylate as a main component was 50 to 100 ⁇ ⁇ in the surface treatment resin composition of Example 4, Transcription coating was performed.
  • Example 5 Ventricular ring tape preparation 1
  • a low melting point polyurethane hot melt adhesive having a flow starting point of 95 ⁇ ⁇ was extruded into a 50 ⁇ ⁇ thick and 54 inch wide cross-linked release paper to prepare an adhesive layer.
  • the fabric sheet with the fabricated releasing paper laminated thereon was subjected to a transfer coating process of the resin composition of the surface treating agent by the synchronous grained cylinder of step 2 of Example 1 to grind the quadrangular lattice pattern connected with square dots, And rolled up into a roll, and cut into a width of 20 mm in a roll cutter to produce a ventricular ring tape.
  • a ventricular ring tape was produced in the same manner as in Example 5, except that the one-pack type skin resin for heat resistant layer in Example 5 was used as a non-solvent extruded thermoplastic polyurethane film instead of the R / P casting method .
  • MIN / MIN of a solution type hot melt type polyurethane adhesive (SPU-10710 made by SAMHO CHEMICAL CO., LTD., Solid content 30%) with a comma coating on a heat resistant R / P was prepared with 25 parts by weight of methyl ethyl ketone.
  • a one-pack type skin resin containing 30% solid content
  • a solution type polyurethane UCECOAT-775, manufactured by CYTEC Co., Ltd.
  • polyester polyol and diisocyanate as main components
  • 20 parts by weight of methyl ethyl ketone And 5 parts by weight of silica powder DKUSA OK-412 were coated with a heat-resistant skin layer, followed by drying at 80 ° C. and heat treatment at 120 ° C. to prepare a seat fabric for a ventricular ring tape.
  • DAKUSA OK-412 silica powder
  • the result of the transcription coating using the resin composition of the present invention showed better results than that of the fabric prepared without the spherulite particles or the heat-resistant solvent-resistant spherical particles.
  • the physical properties of irregularity, slipperiness, dry feeling and cold feeling were optimized, and in the plate making process, (Example 1) exhibited a better tactile sensation than Example 2 (Example 2) in which transfer coating was carried out using a grained cylinder of a film corrosion-resistant plate.
  • the breathable and waterproof fabric was mounted on a 10 cm diameter disc and subjected to a standard abrasion test method of TABER Industries (USA). CS-10 for 100 times to visually observe the weight loss before and after the test and the appearance of the wear and tear.
  • test piece was evaluated as? When there was almost no abrasion damage to the naked eye,? When the specimen wear was slightly damaged, and X when the specimen wear was remarkable.
  • FIGS. 2 to 4 show photographs of the test piece using the breathable and waterproof fabric prepared in Examples 1 and 4 and Comparative Example 1 after 100 times of abrasion test.
  • Staphylococcus aureus ATCC 6538 and pneumoniae Klebsiella pneumoniae ATCC 4352 were inoculated on 0.05% nonionic surfactant (Snogen) at 37 °C for 24 hours
  • the cultured bacteria were used as an inoculum.
  • the standard cell was KS K 0905 cotton material for dyeing fastness, and the results of the antimicrobial activity test are shown in Table 4 below.
  • the moisture-permeable and waterproof fabric prepared in Examples 1 to 4 and Comparative Examples 1 and 2 was exposed in a container containing ammonia gas, and the amount of the water absorbed and remained was measured over time, and was performed under the following conditions.
  • Test piece 10 ⁇ 10 cm 2
  • Deodorization ratio% (C b - C s ) / C b ) ⁇ 100
  • the ventricular ring tape of the present invention can be surface-treated in the same pattern as the fabric by directly transfer-coating the breathable and waterproof fabric coated surface with the synchro-grained cylinder up-loading method of the present invention.
  • the ventricular ring tape of the present invention exhibits excellent overall residual strain, tensile strength and physical properties relating to elongation, and is thus suitable for use in sewing moisture-permeable and waterproof fabrics for use as an inner detection.
  • the surface treatment agent resin composition of a specific component is effectively and firmly transferred to the moisture permeable waterproof fabric coated surface by the synchronous grained cylinder up-loading method, It has an effect of maximizing the property and abrasion resistance.
  • the moisture-permeable and waterproof fabric produced by the manufacturing method of the present invention is light and small in volume, and thus can be very usefully employed in general casual wear, sports wear, and waterproof clothing for waterproof windshields.
  • the garment product sewn with the breathable and waterproof cloth of the present invention does not require a separate liner cloth, so that the weight of the clothing product is reduced, the volume of the garment is reduced, and the folded cloth is packable.
  • the waterproof garment having excellent packability of the present invention has a strong durability on the coated surface, so that it has a good scratch resistance at the time of dressing clothes or in contact with the skin, and is excellent in drying feeling and cold feeling, There is an effect that even a cool feeling is given.
  • the wear resistant breathable waterproof fabric of the present invention When the method of manufacturing the wear resistant breathable waterproof fabric of the present invention is applied to the ventricular ring tape to sew the surface treated coated fabric for the inner perception detection,
  • the surface can be treated with the same pattern.

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Abstract

The present invention relates to a method for manufacturing abrasion-resistant vapor-permeable waterproof fabric having excellent dryness and design, to a vapor-permeable waterproof fabric and waterproof garments manufactured by the method, and to a method for manufacturing a seam-sealing tape for garment sewing. The method for manufacturing abrasion-resistant vapor-permeable waterproof fabric having excellent dryness and design according to the present invention comprises: applying a vapor-permeable waterproof coating onto a woven or knitted and subsequently dyed fabric; transfer-coating the vapor-permeable waterproof coated fabric, which is supplied in roll form, with glass pearl, heat-resistant solvent-resistant spherical polymer particles selected from cross-linked poly(methyl methacrylate) polymer particles and cross-linked polyurethane polymer particles, or a surface treatment agent resin composition or a mixture thereof, in a synchro-engraved cylinder uploading manner; and drying the transfer-coated fabric. Accordingly, the surface treatment agent resin composition may be effectively and firmly transferred to the coating surface of the fabric from the synchro-engraved cylinder (intaglio roll), thereby maximizing unevenness, dryness, and abrasion-resistance of the coated surface. Vapor-permeable waterproof fabric manufactured by the method according to the present invention is light and has a low volume since it does not require a lining, and is therefore suitable for general casual wear, sportswear, and waterproof and windproof packable clothing.

Description

건조감 및 의장성이 우수한 내마모 투습방수원단의 제조방법, 그에 의해 제조된 투습방수원단, 방수의류 및 의류봉제용 심실링 테이프의 제조방법A method for manufacturing a wear-resistant waterproof fabric having excellent dryness and designability, a breathable waterproof fabric, a method for manufacturing a waterproof garment, and a ventricular ring tape for sewing clothing
본 발명은 건조감 및 의장성이 우수한 내마모 투습방수원단의 제조방법, 그에 의해 제조된 투습방수원단, 방수의류 및 의류봉제용 심실링 테이프의 제조방법에 관한 것으로, 보다 상세하게는, 특정 조성의 표면처리제 수지조성물을 싱크로 인그레이브드 실린더 업로우딩 방식에 의해 투습방수 코팅면 또는 라미네이팅 필름면에 코팅함으로써, 피부에의 직접 접촉시 건조감, 쾌적감 및 냉감을 극대화시키고, 싱크로 인그레이브드 실린더로부터 원단 코팅면에 효과적이고 견고하게 패턴을 전사시킴으로써, 의장성이 부여되어 안감을 생략할 수 있으며, 이에 따라, 경량성과 패커블성이 개선된 투습방수원단, 그를 이용한 패커블성이 우수한 방수의류 및 의류봉제용 심실링 테이프의 제조방법에 관한 것이다. The present invention relates to a method for producing a wear resistant breathable waterproof fabric excellent in dry feeling and design, a moisture permeable waterproof fabric, a waterproof garment, and a method for manufacturing a ventricular ring tape for sewing clothing, The surface treatment agent resin composition is coated on the moisture permeable waterproof coating surface or the laminating film surface by the synchronous grained cylinder up-loading method to maximize the dry feeling, the pleasant feeling and the cold feeling by direct contact with the skin, By applying the pattern effectively and firmly on the coated surface of the fabric, it is possible to omit the lining due to the designing, and thus the breathable and waterproof fabric with improved lightness and packability, the waterproof clothing and the garment sewing To a method for manufacturing a ventricular ring tape for a heart.
투습방수 코팅원단은 스키, 골프웨어, 하이킹, 등산, 죠깅복 등 각종 액티브 스포츠웨어 및 캐쥬얼웨어에 널리 사용되고 있는 소재로서 겉감지 섬유 원단은 주로 두껍지 않은 합성섬유원단에 투습방수코팅을 하여 제조되는 것이 일반적이다. 또한, 상기 투습방수원단은 외부로부터의 수분을 배척하기 위해 통상적으로 발수가공이 적용되는데 선발수(투습방수 코팅전에 실시) 또는 후발수(투습방수코팅 후 실시)가 적용된다.The breathable waterproof coating fabric is widely used for various active sportswear and casual wear such as skiing, golf wear, hiking, climbing, jogging suit, etc. The surface cloth is mainly made by applying moistureproof waterproof coating to the non-thick synthetic fiber fabric It is common. In addition, the water-permeable and waterproof fabric is usually subjected to water-repellent processing so as to exclude moisture from the outside, which is applied to starting water (before moisture-permeable water-resistant coating) or late water (after moisture-permeable water-resistant coating).
일반적으로 종래의 투습방수원단은 섬유층과 코팅층으로 구성된 2층 구조와 섬유층(겉감), 코팅층 및 섬유층(안감)으로 구성된 3층 구조로 되어 있는데, 2층 구조의 원단은 봉제시 별도로 안감지를 사용함으로써, 결국 3층 구조의 원단으로 되게 마련이다. 따라서, 안감지 부가로 인하여 그만큼 촉감이 둔탁해지고, 부피 및 중량이 커지게 되며, 제조원가도 올라가는 단점이 있어 왔다.Generally, the conventional breathable and waterproof fabric has a three-layer structure composed of a two-layer structure composed of a fiber layer and a coating layer, a fiber layer (outer layer), a coating layer and a fiber layer (lining). , And finally, it becomes a three-layered fabric. Therefore, there has been a disadvantage that the touch feeling becomes dull, the volume and the weight become large, and the manufacturing cost rises because of the eye detection part.
또한, 방수 방풍용으로 간헐적인 사용을 위한 휴대를 위해 접어서 패킹할 때 부피 및 중량이 커지게 되어 매우 불편하게 되는 문제점이 있어 왔다.In addition, there has been a problem that when the battery pack is folded and folded for carrying it for intermittent use due to a waterproof windshield, its volume and weight become large, which is very inconvenient.
종래에 상술한 바와 같은 목적을 위해 패커블(packable)용으로 2층 구조의 코팅원단에 그라비아 방식으로 인쇄를 하거나 음각무늬 표면처리를 한 제품들이 고안되기는 하였었으나, 이것들은 요철감이 없거나 내마모성, 내스크래치성이 약하고, 특유의 매끄럽고 건조한 감이 부족하여 목적에 충분히 부합하지 못하였다.Conventionally, for the purpose of the above-mentioned purpose, there has been devised products which are printed on a two-layered coating fabric for packable by gravure printing or subjected to engraved pattern surface treatment. However, these products have no irregularity, The scratch resistance is poor, and the specific smoothness and dryness are insufficient, which is not satisfactory for the purpose.
또한, 요철감을 준 것이라 하더라도 내마모성이나 내스크래치성이 약하여 세탁내구성이 미흡하고, 코팅면의 항균방취 성능 등이 열악하여 운동 시, 땀 등에 의한 악취의 발생을 예방하지 못하는 단점들이 있어왔다.In addition, even if the unevenness has been imparted, the anti-abrasion property and the scratch resistance are weak, so that the durability of washing is insufficient and the antibacterial and deodorizing performance of the coated surface is poor.
예를 들어, 대한민국 공개특허공보 제2004-0004301호에서는 요철감을 부여키 위해 표면처리 약제를 발포제로 발포시키는 방법을 사용하였으나, 표면에 발포셀이 형성됨으로 인하여 내마모성이 열악하게 되고, 스크래치시 자국을 남기게 되는 문제점을 안고 있다. 또한 요철부제로 사용하는 돌가루, 규소토, 탄산칼슘 등은 가공후 표면의 슬립성을 부여하기 곤란하며, 세탁이나 드라이크리닝에 대해서 견뢰하지 못한 단점을 지니고 있다.For example, in Korean Patent Laid-Open Publication No. 2004-0004301, a method of foaming a surface treatment agent with a foaming agent is used in order to impart a roughness. However, since a foaming cell is formed on the surface, abrasion resistance is poor, I have a problem to leave. In addition, stone powder, silicate, calcium carbonate, etc., which are used as shrinkage additives, are difficult to impart slipperiness to the surface after processing and have a disadvantage that they are not robust against washing or dry cleaning.
제판롤러의 설계에 의한 요철감 발현 측면에서도 상기 특허에서와 같이 필름부식방법에 의해 7∼12㎛ 정도의 심도로 설계를 할 경우 표면처리제 배합물 내 고체물질의 입도 분포상 셀의 심도보다 큰 물질이 존재하기 때문에 정상적인 전사코팅이 이루어지지 않으며, 또한 통상적으로 그라비아 롤상에서 원단으로의 전이율이 70%이상을 넘기기가 현실적으로 곤란하여 표면처리 가공후 실제 코팅원단의 표면으로부터의 부착 높이는 제판상 심도의 30% 이하 수준 정도로 매우 미흡하다.In the aspect of the relief depression due to the design of the plate-making roller, when the film is designed to have a depth of about 7 to 12 μm by the film corrosion method as in the above patent, there is a substance larger than the depth of the cell in the particle size distribution of the solid material in the surface- It is difficult to realize a normal transfer coating. In addition, it is practically difficult to transfer the transfer ratio to the fabric on the gravure roll more than 70%, so that the adhesion height from the surface of the actual coated fabric after the surface treatment is 30% The level is very low.
본 발명은 상술한 바와 같은 종래기술의 문제점을 해결하고자 안출된 것으로서, 본 발명의 목적은 건조감 및 내마모성이 우수하여 착용감이 좋을 뿐만 아니라 경량이고 접었을 때 부피가 작아 패커블성이 우수하여 봉제시 안감지를 필요로 하지 않으며 무늬에 의한 의장성을 함께 부여한 투습방수원단의 제조방법을 제공함에 있다.The present invention has been made to solve the problems of the prior art as described above, and it is an object of the present invention to provide a cosmetic composition which is excellent in dry feeling and abrasion resistance and is not only good in wearing feeling but also light in weight and small in volume when folded, And a method of manufacturing a moisture-permeable and waterproof fabric which is not required to be provided with design by pattern.
본 발명의 다른 목적은 상기 방법에 의해 제조되는 건조감 및 내마모성이 우수하고 세탁 내구성이 강한 투습방수원단을 제공함에 있다.Another object of the present invention is to provide a moisture-permeable and waterproof fabric having excellent dryness and abrasion resistance and high durability in washing, which is produced by the above method.
본 발명의 또 다른 목적은 상기 투습방수원단을 채용하여 봉제된 방수의류 및 의류봉제용 심실링 테이프의 제조방법을 제공함에 있다.Another object of the present invention is to provide a method for manufacturing a waterproof garment and a ventricular ring tape for garment sewing sewn by employing the breathable waterproof fabric.
본 발명은 제직 또는 편직 후 염색 가공된 원단에 투습방수 코팅가공을 수행하는 단계, 상기 투습방수 코팅가공되어 롤상으로 공급되어 온 원단 상에, 그라스 펄; 또는 가교 폴리메틸메타크릴레이트 고분자 미립자 또는 가교 폴리우레탄 고분자 미립자에서 선택되는 내열내용제성 고분자 구상입자;가 함유된 표면처리제 수지조성물을 싱크로 인그레이브드 실린더 업로우딩 방식으로 전사코팅하는 단계 및 상기 전사코팅된 원단을 건조하는 단계를 포함하는 건조감 및 의장성이 부여된 내마모 투습방수원단의 제조방법을 제공한다. The present invention relates to a method for fabricating a knitted fabric, comprising the steps of: performing a breathable and waterproof coating process on a fabric after weaving or knitting; Or heat-resistant, solvent-resistant high molecular weight spherical particles selected from crosslinked polymethyl methacrylate polymer fine particles or crosslinked polyurethane high molecular particles; and a step of transfer coating the surface treating agent resin composition by a synchronous grained cylinder up- And drying the coated fabric. The present invention also provides a method of manufacturing a wear resistant waterproof breathable fabric provided with a dry feeling and a design.
본 발명의 제조방법은 상기 투습방수 코팅가공 전 또는 후에, 발수가공 단계를 더 수행할 수 있다. The manufacturing method of the present invention may further include a step of water-repellent processing before or after the moisture-permeable waterproof coating.
본 발명에 있어서, 상기 싱크로 인그레이브드 실린더의 무늬심도는 40 내지 300㎛인 것이 바람직하다.In the present invention, the depth of the pattern of the synchronous grabbed cylinder is preferably 40 to 300 mu m.
또한, 본 발명에 있어서, 표면처리제 수지조성물의 바람직한 실시형태로는 폴리우레탄수지(고형분 기준) 100 중량부에 대하여, 혼합유기용제 30 내지 300 중량부, 그라스 펄 30 내지 300 중량부, 안료피그먼트 3 내지 6 중량부, 블록킹 방지제 1.5 내지 15중량부 및 유ㆍ무기복합화합물로 이루어진 커플링제 0.5 내지 2.0 중량부인 것이 바람직하다.In the present invention, preferred embodiments of the surface treating agent resin composition include 30 to 300 parts by weight of a mixed organic solvent, 30 to 300 parts by weight of a glass pearl, 100 to 300 parts by weight of a pigment pigment 3 to 6 parts by weight, an antiblocking agent in an amount of 1.5 to 15 parts by weight, and a coupling agent comprising an organic-inorganic hybrid compound in an amount of 0.5 to 2.0 parts by weight.
상기 표면처리제 수지조성물의 바람직한 다른 실시형태로는 폴리우레탄수지(고형분 기준) 100 중량부에 대하여, 혼합유기용제 30 내지 300 중량부, 가교 폴리메틸메타크릴레이트 고분자 미립자 또는 가교 폴리우레탄 고분자 미립자에서 선택되는 내열내용제성 고분자 구상입자 30 내지 300 중량부, 안료피그먼트 3 내지 6 중량부 및 블록킹 방지제 1.5 내지 15중량부로 이루어진 표면처리제 수지조성물을 사용하는 것이다.As another preferred embodiment of the surface treatment agent resin composition, 30 to 300 parts by weight of a mixed organic solvent, 100 to 300 parts by weight of a crosslinked polymethylmethacrylate polymer fine particle or a crosslinked polyurethane polymer fine particle is added to 100 parts by weight of a polyurethane resin (solid basis) 30 to 300 parts by weight of heat-resistant, solvent-resistant high molecular weight spherical particles, 3 to 6 parts by weight of pigment pigment and 1.5 to 15 parts by weight of an anti-blocking agent.
상기 표면처리제 조성물에는 무기항균제 또는 바이오세라믹계 소취제가 30 중량부 이하로 더 함유되는 것이 바람직하며, 상기 무기항균제는 무기계 세라믹물질 제올라이트계인 것이 바람직하다.Preferably, the surface treating agent composition further contains an inorganic antibacterial agent or a bioceramics deodorant in an amount of 30 parts by weight or less, and the inorganic antibacterial agent is preferably an inorganic ceramic material zeolite-based.
상기 표면처리제 조성물에 있어서, 상기 혼합유기용제는 톨루엔, 메틸에틸케톤, 디메틸포름아마이드, 이소프로필알콜, 크실렌, 퍼클로로에틸렌, 아세톤 및 에틸아세테이트로 이루어지는 군에서 선택되는 둘 이상인 것이다.In the surface treatment agent composition, the mixed organic solvent is at least two selected from the group consisting of toluene, methyl ethyl ketone, dimethyl formamide, isopropyl alcohol, xylene, perchlorethylene, acetone and ethyl acetate.
또한, 본 발명의 표면처리제 수지조성물의 점도가 2,000∼50,000 cps가 바람직하고, 표면처리제 수지조성물의 전체 고형분은 20∼50%인 것이 바람직하다.The viscosity of the surface treating agent resin composition of the present invention is preferably 2,000 to 50,000 cps, and the total solid content of the surface treating agent resin composition is preferably 20 to 50%.
본 발명은 상기 제조방법에 의해 제조되되, 원단의 투습방수 코팅면에 싱크로 인그레이브드 실린더의 무늬심도가 40 내지 300㎛로 전사되어 건조감 및 의장성이 부여된 내마모 투습방수원단을 제공한다.The present invention provides an abrasion resistant waterproof fabric which is manufactured by the above-described method and has a pattern depth of 40 to 300 μm transferred to a breathable and waterproof coated face of a cloth and a synchro-graved cylinder of 40 to 300 μm to impart dry feeling and designability.
또한, 상기 내마모 투습방수원단이 채용되어 봉제된 건조감 및 의장성이 부여된 방수의류를 제공한다.Further, the present invention provides a waterproof garment to which the wear resistant breathable waterproof fabric is applied to impart a dried feeling of dryness and designability.
나아가, 본 발명은 이형지, 핫멜트 접착제층 및 폴리우레탄 수지로 제조된 내열성수지 필름층이 순차 합지된 심실링테이프 제작용 원단을 제조하고, Further, the present invention relates to a method for manufacturing a ventilating ring tape fabric, which comprises sequentially laminating a release paper, a hot-melt adhesive layer and a heat-resistant resin film layer made of a polyurethane resin,
상기 원단 중 내열성수지 필름층 상에, 본 발명의 표면처리제 수지조성물을 싱크로 인그레이브드 실린더 업로우딩 방식으로 전사코팅하여 패턴을 인각한 후, 슬리팅 또는 커팅하여 재단하는 의류봉제용 심실링 테이프의 제조방법을 제공한다.The surface treatment agent resin composition of the present invention is transferred and coated on the heat-resistant resin film layer of the fabric by a synchro-grained cylinder up-loading method to knit a pattern, and then slit or cut to cut a ventricle ring tape Of the present invention.
이때, 상기 표면처리제 조성물에 무기항균제 또는 바이오세라믹계 소취제가 30 중량부 이하로 더 함유될 수 있다.At this time, an inorganic antibacterial agent or a bioceramics deodorant may be further contained in the surface treatment composition in an amount of 30 parts by weight or less.
또한, 본 발명의 의류봉제용 심실링 테이프는 잔류변형율이 35%이하를 충족한다.Further, the ventricular ring tape for garment sewing of the present invention satisfies a residual strain of 35% or less.
본 발명은 투습방수원단 코팅면에 특정 성분의 표면처리제 수지조성물을 싱크로 인그레이브드 실린더 업로우딩 방식에 의해 효과적으로 견고하게 전사시키는 내마모 투습방수원단의 제조방법을 제공할 수 있다.The present invention can provide a method of manufacturing an abrasion resistant breathable waterproof fabric which effectively and firmly transfers a resin composition of a specific component of a surface treatment agent on a breathable and waterproof fabric coated surface by a synchronous grained cylinder up-loading method.
이에, 본 발명은 상기 내마모 투습방수원단의 제조방법에 의하여, 피부에의 직접 접촉시 건조감, 쾌적감 및 냉감을 극대화시키고, 싱크로 인그레이브드 실린더로부터 원단 코팅면에 효과적이고 견고하게 패턴을 전사시킴으로써, 의장성이 부여되어 안감을 생략할 수 있으며, 이에 따라, 경량성과 패커블성이 개선된 투습방수원단, 그를 이용한 방수의류 및 의류봉제용 심실링 테이프의 제조방법을 제공할 수 있다. Accordingly, the present invention provides a method of manufacturing a wear resistant breathable waterproof fabric by maximizing the dryness, comfort, and cold feeling upon direct contact with the skin, and effectively and firmly transferring the pattern from the synchronized graved cylinder The present invention can provide a breathable and waterproof fabric having improved lightness and packability, a waterproof clothing using the same, and a method of manufacturing a ventricular ring tape for sewing clothes.
도 1은 본 발명의 제조방법 중, 전사코팅 공정에 사용되는 싱크로 인그레이브드 실린더 업로우딩 방식의 모식도이고, 1silver Among the manufacturing methods of the present invention, a schematic view of a synchronous grained cylinder up-loading method used in a transfer coating process,
도 2는 본 발명의 실시예 1에서 제조된 투습방수원단의 100회 마모시험 후 결과이고, 2 shows the results of the 100-time abrasion test of the breathable and waterproof fabric prepared in Example 1 of the present invention,
도 3은 본 발명의 실시예 4에서 제조된 투습방수원단의 100회 마모시험 후 결과이고, FIG. 3 shows the results of the 100-time abrasion test of the moisture-permeable and waterproof fabric prepared in Example 4 of the present invention,
도 4는 본 발명의 비교예 1에서 제조된 투습방수원단의 100회 마모시험 후 결과이다. 4 shows the results of the 100-time abrasion test of the breathable and waterproof fabric prepared in Comparative Example 1 of the present invention.
이하, 본 발명을 상세히 설명하고자 한다.Hereinafter, the present invention will be described in detail.
본 발명은 제직 또는 편직 후 염색 가공된 원단에 투습방수 코팅가공을 수행하는 제1단계, 상기 투습방수 코팅가공되어 롤상으로 공급되어 온 원단 상에, 그라스 펄; 또는 가교 폴리메틸메타크릴레이트 고분자 미립자 또는 가교 폴리우레탄 고분자 미립자에서 선택되는 내열내용제성 고분자 구상 입자; 단독 또는 그 혼합형태가 함유된 표면처리제 수지조성물을 싱크로 인그레이브드 실린더 업로우딩 방식으로 전사코팅하는 제2단계 및 상기 전사코팅된 원단을 건조하는 제3단계를 포함하는 건조감 및 의장성이 부여된 내마모 투습방수원단의 제조방법을 제공한다. The present invention relates to a method for producing a water-proof, water-repellent, water-repellent or water-repellent fabric, comprising the steps of: Or heat-resistant, solvent-containing polymeric spherical particles selected from crosslinked polymethylmethacrylate polymer fine particles or crosslinked polyurethane polymer fine particles; A second step of transcribing the surface treating agent resin composition containing a single or mixed form thereof by a synchronous grained cylinder up-loading method, and a third step of drying the transcription coated raw material, And a method of manufacturing the wear resistant breathable waterproof fabric.
이하, 단계별로 상세히 설명하면, 상기 제1단계에서 투습방수원단은 원단을 직조 또는 편직하고 염색 및 발수 가공처리 한 후, 합성수지 코팅액으로 다이렉트 또는 트랜스퍼 코팅 방법으로 코팅처리한 다음, 롤링된 상태로 공급되거나, 원단 직조 또는 편직 염색 후에 발수가공을 생략하고, 합성수지 코팅액으로 코팅처리하여 발수가공 처리한 후(후발수) 역시 롤링된 상태로 전사코팅공정에 공급될 수 있다.In the first step, the moisture-permeable and waterproof fabric may be fabricated by weaving or knitting the fabric, dyeing and water-repellent processing, coating with a synthetic resin coating solution by direct or transfer coating method, Or may be supplied to the transfer coating process in a rolled state after water-repellent processing (late water) after coating with a synthetic resin coating liquid, omitting water-repellent processing after weaving or knitting dyeing.
본 발명의 제조방법은 상기 투습방수 코팅가공 전공정 또는 후공정으로 발수가공 단계를 더 수행할 수 있는데, 상기 투습방수 코팅과 발수가공은 전후를 바꾸어 수행할 수 있으며, 방수원단에서 합성수지 코팅액으로 코팅 하기전에 발수가공하면 선발수, 발수가공을 합성수지 코팅액으로 코팅을 한 후에 실시하면 후발수 가공이라 한다. The manufacturing method of the present invention can further perform the water-repellent processing step before or after the moisture-permeable, water-repellent coating. The moisture-permeable water-repellent coating and the water-repellent processing can be performed before and after the water- If water-repellent processing is performed before, water-repellent water-repellent treatment is applied after coating with a synthetic resin coating liquid.
본 발명에 있어서, 상기 전사코팅하는 제2단계는 도 1에 도시된 바와 같이, 싱크로 인그레이브드 실린더(음각롤)의 표면상에 상기 표면처리제 수지조성물을 공급하여 양변부를 막아 수지조성물의 변부 이탈을 막고, 스크랩퍼로 롤(실린더)표면을 균일하게 스크랩핑하여 음각이외의 부위에 있는 수지조성물을 제거한 후 방수원단의 코팅면에 소정의 두께 및 무늬로 전사코팅이 이루어지도록 수행되는 것이 바람직하다.In the second step of the transfer coating according to the present invention, as shown in FIG . 1 , the surface treatment agent resin composition is supplied on the surface of a synchronized gravelled cylinder (engraved roll) to cover both sides, And then scraped the surface of the roll (cylinder) uniformly with a scrapper to remove the resin composition in areas other than the engraved surface, and then transfer coating is performed on the coated surface of the waterproof fabric with a predetermined thickness and pattern .
상기 코팅 방식은 투습방수 코팅면 또는 라미네이팅 필름면에 싱크로 인그레이브드 실린더 상에 업로우딩 방식으로 표면처리제 수지조성물을 공급하여 처리함으로써 고점도(약 2,000∼50,000 cps)의 수지조성물을 균일하게 효과적으로 전사 고착시킬 수 있게 된다.The coating method is a method of uniformly and effectively transferring a resin composition having a high viscosity (about 2,000 to 50,000 cps) by supplying and treating the surface treating agent resin composition in an up-dipping manner on a moisture permeable waterproof coating surface or a laminating film surface on a synchronously grained cylinder So that it can be fixed.
표면처리제의 전사 고착 원리는 싱크로 인그레이브드 실린더와 쿳션롤 사이에 피착체를 통과시키면서 압착을 해줌으로써, 싱크로 인그레이브드 실린더에 묻어있던 표면처리제 수지조성물을 피착체 쪽으로 전사시키는 원리인데, 통상 쿳션롤을 하단부에 위치시키는 경우와 상단부에 위치시키는 경우 모두 가능한 방법이지만 전사의 안정성 측면에서 쿳션롤을 하단부에 위치시키는 것이 더욱 바람직하다.The principle of transfer adhesion of the surface treatment agent is a principle of transferring the surface treatment resin composition stuck to the synchronously grafted cylinder to the adherend by passing the adherend while passing the adherend between the synchro-grafted cylinder and the cushion roll, Both of the case where the roll is positioned at the lower end and the case where the roll is positioned at the upper end are possible, but it is more preferable to place the cushion roll at the lower end in terms of the stability of the transfer.
이러한 전사코팅 방법으로 해야 하는 이유는 방수 원단의 코팅 표면에 요철감을 부여키 위한 것이며, 이를 위해 표면 처리제 수지조성물의 고형분을 최대한 높이는 것이 요구되고, 수지특성상 고형분의 증가에 따라 자연스럽게 표면처리제 수지조성물의 점도도 높아지게 됨은 당업자에게 있어서 용이하게 이해되어질 수 있을 것이다.The reason for this transfer coating method is to give a roughness to the coating surface of the waterproof fabric. For this purpose, it is required to increase the solid content of the resin composition of the surface treatment agent as much as possible and, as the solid content increases, It will be readily understood by those skilled in the art that the viscosity also increases.
이와 같이 고점도로 하는 경우에 건조 열처리 과정에서 증발되는 양을 최소화할 수 있게 되고, 나아가 싱크로 인그레이브드 실린더에서 전사되는 수지조성물을 일정 두께로 전사 고착시킬 수 있게 되는 것이다.In this case, the amount of evaporation during the drying heat treatment can be minimized, and further, the resin composition to be transferred from the synchronized grabbed cylinder can be transferred and fixed to a certain thickness.
본 발명에 있어서, 싱크로 인그레이브드 실린더의 무늬심도는 40 내지 300㎛인 것이 바람직하다. 상기 싱크로 인그레이브드 실린더의 심도가 40㎛보다 얕으면, 요철감 발현이 미흡하게 되고, 300㎛을 초과하여 깊게 제판할 경우는 수지조성물의 균일한 전사가 어렵게 되거나 전사무늬형태가 일그러지는 문제가 발생할 수 있다. 즉, 무늬 크기에 비해 지나치게 심도가 깊을 경우 전이율이 불량해질 우려가 있다.In the present invention, the depth of pattern of the synchronized grabbed cylinder is preferably 40 to 300 mu m. If the depth of the synchro-grained cylinder is shallower than 40 탆, the development of depressions and depressions becomes insufficient, and when the plate is formed deeply in excess of 300 탆, uniform transfer of the resin composition becomes difficult or the transfer pattern becomes distorted Lt; / RTI > That is, when the depth is too deep compared with the pattern size, the transfer rate may become poor.
본 발명의 전사 코팅단계에서 사용되는 표면처리제 수지조성물은 약 200℃ 온도에서 물성 변화가 없어야 하고, 톨루엔, 메틸에틸케톤, 디메틸포름아마이드, 이소프로필알콜, 크실렌, 퍼클로로에틸렌, 아세톤, 에틸아세테이트 등의 유기용제에 불용성을 충족하는 내열내용제성의 구상입자를 사용하는 것이 바람직하다. 바람직하게는 그라스 펄(glass bead) 또는 가교 폴리메틸메타크릴레이트 고분자 미립자 또는 가교 폴리우레탄 고분자 미립자에서 선택되는 내열내용제성 고분자 구상입자를 함유하는 것이며, 그 혼합형태 역시 적용될 수 있다.The resin composition of the surface treatment agent used in the transcription coating step of the present invention should have no change in physical properties at a temperature of about 200 ° C and may be any one of toluene, methyl ethyl ketone, dimethyl formamide, isopropyl alcohol, xylene, perchlorethylene, acetone, It is preferable to use sphere-shaped particles of heat-resistant solvent which satisfy insolubility in the organic solvent of Preferably a glass bead or a crosslinked poly (methyl methacrylate) polymer fine particle or a crosslinked polyurethane polymer fine particle, and the mixed form thereof may also be applied.
이에, 바람직한 표면처리제 수지조성물의 실시형태로는 폴리우레탄수지(고형분 기준) 100 중량부에 대하여, 혼합유기용제 30 내지 300 중량부, 그라스 펄 30 내지 300 중량부, 안료피그먼트 3 내지 6 중량부, 블록킹 방지제 1.5 내지 15 중량부 및 유ㆍ무기 복합 화합물로 이루어진 커플링제 0.5 내지 2.0 중량부로 이루어진 표면처리제 수지조성물을 사용하는 것이다. Thus, preferred embodiments of the surface treating agent resin composition include 30 to 300 parts by weight of a mixed organic solvent, 30 to 300 parts by weight of a glass bead, 3 to 6 parts by weight of a pigment pigment, 1.5 to 15 parts by weight of an antiblocking agent, and 0.5 to 2.0 parts by weight of a coupling agent comprising an organic-inorganic hybrid compound.
상기 조성 중, 그라스 펄(glass pearl)은 건조감, 내마모성, 요철감 및 슬립성 등 복합 기능성을 위한 조제로 사용되며, 상기 그라스 펄의 형상은 구상(bead)인 것이 바람직한데, 표면의 돌출된 부분이 반구 또는 구상으로 되면 마찰에 의한 슬립성이 우수하게 되고, 피부에 접했을 경우 끈적임 촉감을 느낄수 없고 건조하고 쾌적한 느낌을 부여 할 수 있다. 특히, 패커블성이 우수한 방수의류는 봄여름시즌에 많이 착용하므로 쾌적성 측면에서 무기 그라스 펄의 특성상 피부에 접촉했을 경우 냉감 효과도 부여할 수 있다.Among the above compositions, glass pearl is used as a preparation for a combined functionality such as dryness, abrasion resistance, irregularity and slipperiness, and the shape of the glass pearl is preferably bead, When this hemispherical or spherical shape is formed, the slip property due to friction is excellent, and when touching the skin, a feeling of stickiness can not be felt, and a dry and pleasant feeling can be given. In particular, waterproof clothing having excellent packability is frequently worn in the spring and summer season, so that it is possible to impart a cool feeling effect to the skin when it comes into contact with the skin due to the nature of inorganic grass pearl in terms of comfort.
이때, 그라스 펄은 직경 5 내지 100㎛의 구상형태가 바람직하며, 더욱 바람직하기로는 8 내지 40㎛으로 되는 것이다. 상기 그라스 펄의 직경이 5㎛ 미만이면, 복합기능성의 효과가 미흡하고, 100㎛을 초과하면, 표면터치가 거칠어 착용감이 불량하다.At this time, the glass pearls preferably have a spherical shape with a diameter of 5 to 100 mu m, more preferably 8 to 40 mu m. If the diameter of the glass pearl is less than 5 mu m, the effect of the multi-functional property is insufficient. If the diameter is more than 100 mu m, the surface touch is coarse and the wearing feeling is poor.
그라스 펄의 조성예로서는 SiO2 70∼73중량%, Al2O3 0.8∼1.0중량%, CaO 7∼12중량%, MgO 1.0∼4.5중량%, Na2O3 및 K2O 13∼15중량%로 이루어진 그라스 펄; 또는 SiO2 52∼56중량%, Al2O3 12∼16중량%, CaO 16∼25중량%, MgO 0∼6중량%, TiO2 0∼0.5중량%, B2O3 5∼13중량%, Na2O3 및 K2O 0∼0.8중량%로 이루어진 그라스 펄; 등 제조공법이나 원료성분의 조성이 다소 다를 수 있으나, 경제성을 고려하여 공지된 그라스 펄에서 선택 사용할 수 있다. Examples The composition of the glass pearl SiO 2 70~73 wt%, Al 2 O 3 0.8~1.0 wt%, CaO 7~12 wt%, MgO 1.0~4.5% by weight, Na 2 O 3 and K 2 O 13~15% by weight ≪ / RTI > Or SiO 2 52~56 wt%, Al 2 O 3 12~16% by weight, CaO 16~25 wt%, MgO 0~6 wt%, TiO 2 0~0.5% by weight, B 2 O 3 5~13% by weight , Na 2 O 3 and 0 to 0.8 wt% K 2 O; And the composition of the raw material components may be somewhat different. However, in view of economical efficiency, it may be selected from known Grass pearl.
또한, 표면처리제 수지조성물에 그라스 펄을 함유할 경우, 아크릴계 일관능성 또는 다관능성 단량체와 인계 화합물로 이루어진 유ㆍ무기 복합 화합물로 이루어진 커플링제를 사용하며, 상기 커플링제는 무기 그라스 펄과 유기물인 폴리우레탄수지와의 결합력과 분산성을 높여주는 효과를 부여할 수 있다. 이때, 커플링제는 폴리우레탄수지(고형분 기준) 100 중량부에 대하여, 0.5 내지 2.0 중량부를 사용한다. In the case of containing glass pearl in the surface treating agent resin composition, a coupling agent composed of an acrylic-based monofunctional or multifunctional monomer and an organic-inorganic hybrid compound comprising phosphorus compound is used, and the coupling agent is an inorganic glass- The effect of increasing the bonding force and dispersibility with the urethane resin can be imparted. The coupling agent is used in an amount of 0.5 to 2.0 parts by weight based on 100 parts by weight of the polyurethane resin (solid basis).
바람직한 표면처리제 수지조성물의 다른 실시형태로서, 폴리우레탄수지(고형분 기준) 100 중량부에 대하여, 혼합유기용제 30 내지 300 중량부, 가교 폴리메틸메타크릴레이트 고분자 미립자 또는 가교 폴리우레탄 고분자 미립자에서 선택되는 어느 하나의 내열내용제성 고분자 구상입자 30 내지 300 중량부, 안료피그먼트 3 내지 6 중량부 및 블록킹 방지제 1.5 내지 15 중량부를 함유하는 것이다.As another preferred embodiment of the surface treating agent resin composition, 30 to 300 parts by weight of a mixed organic solvent, 100 to 200 parts by weight of a crosslinking agent selected from crosslinked polymethyl methacrylate polymer fine particles or crosslinked polyurethane polymer fine particles, based on 100 parts by weight of a polyurethane resin (solid basis) 30 to 300 parts by weight of any one of the heat-resistant solvent-resistant spherical particles, 3 to 6 parts by weight of pigment pigment and 1.5 to 15 parts by weight of an anti-blocking agent.
상기 표면처리제 수지조성물의 경우, 가교 폴리메틸메타크릴레이트 고분자 미립자 또는 가교 폴리우레탄 고분자 미립자에서 선택되는 어느 하나의 내열내용제성 고분자 구상입자를 함유함으로써, 가공성 측면에서 유리하다. In the case of the above-mentioned surface treatment agent resin composition, it is advantageous in terms of processability because it contains any one of the heat-resistant, solvent-resistant high molecular weight spherical particles selected from crosslinked polymethyl methacrylate polymer fine particles or crosslinked polyurethane polymer fine particles.
본 발명의 표면처리제 수지조성물은 주제 수지바인더로서, 1-콤포넌트형 폴리우레탄 수지를 사용하는 것이 싱크로 인그레이브드 실린더에서의 전이성이 양호하며 건조후 표면 끈적임 현상도 없앨 수 있어서 바람직하다.The surface treating agent resin composition of the present invention is preferably a one-component type polyurethane resin as the main resin binder, since it has favorable metastability in a synchronized grained cylinder and can eliminate surface tackiness after drying.
상기 안료피그먼트는 안감지 사용을 하지 않는 관계로 심미적 관점에서 사용되는 것이다.The pigment pigment is used in an aesthetic point of view since it does not use eye detection.
상기 표면처리제 수지조성물 중, 건조감의 상승 효과를 위해서 채용되는 블록킹 방지제로는 시판의 실리카계 미분말이 채용될 수 있다.Among the above-mentioned surface treatment agent resin compositions, commercially available silica-based fine powder may be employed as the anti-blocking agent employed for the synergistic effect of drying feeling.
상기 표면처리제 조성물에는 무기항균제 또는 바이오세라믹계 소취제가 30 중량부이하로 더 함유되는 것이 바람직하다.It is preferable that the surface treatment agent composition further contains an inorganic antibacterial agent or a bioceramics deodorant in an amount of 30 parts by weight or less.
상기 무기항균제로는 무기계 세라믹물질인 제올라이트계로 은(Ag)과 아연(Zn)을 이온 형태로 담지시킨 제올라이트계 무기항균제가 인체에 무해하며 인체에서 발생하는 땀 등의 부패를 방지하는 살균력, 항균력이 뛰어나 바람직하다.As the inorganic antibacterial agent, zeolite-based inorganic antibacterial agent in which silver (Ag) and zinc (Zn) are supported in an ionic form is harmless to the human body and has sterilizing power and anti-microbial power for preventing sweat Excellent.
상기 표면처리제 조성물에는 공지의 음이온 방출을 위한 물질이 부가될 수도 있을 것이다. A known substance for anion release may be added to the surface treatment agent composition.
또한, 상기 표면처리제 조성물에 있어서, 상기 표면처리제 수지조성물의 용해 및 점도 조절을 위해 사용하는 혼합유기용제로는 톨루엔, 메틸에틸케톤, 디메틸포름아마이드, 이소프로필알콜, 크실렌, 퍼클로로에틸렌, 아세톤, 에틸아세테이트 등의 단독 또는 2종 이상의 혼합용제로 사용하되, 수지등 부재료의 용해성 등을 감안하여 적의 조정 사용하는 것이 좋다.Examples of the mixed organic solvent used for controlling the dissolution and viscosity of the surface treatment agent resin composition include toluene, methyl ethyl ketone, dimethyl formamide, isopropyl alcohol, xylene, perchlorethylene, acetone, Ethyl acetate or the like, or two or more mixed solvents, and it is preferable to adjust the solvent in consideration of the solubility of the resin such as resin.
본 발명의 표면처리제 수지조성물의 점도는 2000 cps 이상인 것이 바람직하며, 더욱 바람직하게는 2,000∼50,000 cps인 것이다. 이때, 표면처리제 수지조성물의 점도가 2,000 cps 미만이면, 구상 그라스 펄의 자중에 의해 침전하는 문제가 발생하며, 이렇게 되어 구상의 그라스 펄이 침전할 경우 표면처리제 수지조성물의 처리에 의한 복합기능성의 물성이 불균일해질 가능성이 있어서 상기 수지조성물의 점도는 2,000 cps 이상인 것이 바람직하다.The viscosity of the resin composition for surface treatment of the present invention is preferably 2,000 cps or more, and more preferably 2,000 to 50,000 cps. If the viscosity of the surface treating agent resin composition is less than 2,000 cps, there is a problem of sedimentation due to the weight of the spherical glass pearl. In this way, when spherical glass pearls are precipitated, the properties of the multi- The viscosity of the resin composition is preferably 2,000 cps or more.
또한, 본 발명의 제조방법에서, 코팅면에 요철감을 줄 수 있는 또 다른 효과적인 방법은 최종 배합된 수지조성물의 고형분을 작업성을 저해하지 않는 범위 내에서 높게 설계하는 것인데, 구체적으로 표면처리제 수지조성물의 전체 고형분이 20% 이상, 더욱 바람직하게는 30∼50%일 경우, 효과 발현에 유용할 것이다. In addition, in the manufacturing method of the present invention, another effective method of giving a roughness to the coated surface is to design the solid content of the finally compounded resin composition to a high level within a range that does not hinder workability. Specifically, Is 20% or more, and more preferably 30 to 50%.
요철감 부여를 위해 상기 배합약제의 고형분 조정과 더불어 롤제판시 조각의 심도에 의해 그 효과의 상승을 기대할 수 있을 것이다.In addition to the adjustment of the solid content of the compounding agent in order to give a relief feel, the effect of the effect can be expected to be increased by the depth of the sculpture in roll forming.
통상 롤무늬 제판 방법은 필름부식제판과 조각제판으로 구분될 수 있는데, 필름부식제판은 동을 도금한 실린더에 감광액을 도포한 후, 필름을 현상하는 방식으로 약 5∼20㎛ 심도로 부식이 되어 음각 무늬를 표현하는 방식이고 일반적으로 낮은 심도의 무늬형성이 가능하다. In general, the roll patterning method can be divided into a film corroded plate and a carved plate. The film corroded plate is corroded at a depth of about 5 to 20 μm by applying a photosensitive liquid to a copper-plated cylinder and then developing the film It is a method of expressing the engraved pattern, and it is possible to form the pattern with low depth in general.
한편, 조각제판 방식은 밀을 사용하여 음각 무늬를 롤실린더에 표현하며, 통상 40∼500㎛의 심도 표현이 가능하여, 표면처리제 수지조성물의 도포 전이량을 극대화 하기가 용이할 것이다. 물론 무늬의 크기 즉, 목(目)수에 따른 적도의 심도를 조정해야 함은 당업자에게 용이하게 이해될 것이다.On the other hand, in the engraving method, the engraving pattern is expressed on a roll cylinder using a mill, and the depth of the film can be expressed in a range of usually 40 to 500 mu m, so that it is easy to maximize the application amount of the surface treatment agent resin composition. Of course, it will be readily understood by those skilled in the art to adjust the depth of the equator according to the size of the pattern, i. E. The number of eyes.
본 발명에 있어서, 상기 제3단계의 건조 공정은 상기 싱크로 인그레이브드 실린더 업로우딩 방식에 의해 전사 코팅한 후에, 표면처리제 수지조성물의 건조 과정이 포함되는데, 이것은 열풍이 공급되는 챔버안에서 이루어진다. In the present invention, the drying process of the third step includes a drying process of the resin composition of the surface treating agent after the transfer coating by the synchro-grained cylinder up-loading method, which is performed in the chamber to which the hot air is supplied.
상세하게는, 상기 표면처리제 수지조성물을 싱크로 인그레이브드 실린더 업로우딩 방식으로 표면 처리한 후, 반드시 열처리 챔버를 통과시켜 사용한 용제를 증발시키고 수지바인더를 경화시켜 원단에 고착시키는 공정에 있어서, 열처리 챔버는 간접열풍식 또는 직접 복사열 방식으로 해도 무관할 것이다. 그러나 직접 열복사 방식은 화재 등의 관점에서 각별한 주의가 요망되는 바, 바람직하기로는 간접 열풍 방식이 좋다.Specifically, in the step of surface-treating the above-mentioned surface treatment agent resin composition by a synchronous grained cylinder up-loading method, and then passing through a heat treatment chamber to evaporate the used solvent and harden the resin binder to fix it on the fabric, The chamber may also be indirectly heated or directly radiated. However, the direct heat radiation method requires special attention from the viewpoint of fire and the like.
한편, 표면처리제 수지조성물의 처리시 피처리 원단에는 표면장력을 떨어뜨리는 물질, 예를 들면, 발수제, 유연제, 왁스류 등의 사용은 수지조성물의 전이율을 떨어뜨릴 뿐만 아니라 불균일도를 증가시키는 원인이 되므로 피하는 것이 좋다.On the other hand, when the surface treatment agent resin composition is treated, the use of a substance that lowers the surface tension of the treated fabric such as a water repellent agent, a softener, a wax or the like not only lowers the transfer rate of the resin composition, It is better to avoid this.
본 발명은 상기 내마모 투습방수원단의 제조방법에 의해 제조되되, 원단의 투습방수 코팅면에 싱크로 인그레이브드 실린더의 무늬 심도가 40 내지 300㎛로 전사되어 건조감 및 의장성이 부여된 내마모 투습방수원단을 제공한다.The present invention relates to a method for producing a wear resistant breathable fabric according to the present invention, wherein a depth of a pattern of a synchronized grained cylinder is transferred to a moisture permeable coating surface of a fabric in a range of 40 to 300 μm, Provide waterproof fabric.
특히, 본 발명의 투습방수원단은 100회 내마모성 실험 결과, 마모전후의 중량변화가 거의 없었으며, 마모손상에 따른 외관변화없는 우수한 내마모성을 확인할 수 있다[도 2 내지 도 4].Particularly, the moisture-permeable and waterproof fabric of the present invention showed almost no change in weight before and after abrasion as a result of 100 times abrasion resistance test, and excellent abrasion resistance without change in appearance due to abrasion damage can be confirmed ( Figs. 2 to 4 ).
또한, 상기 내마모 투습방수원단이 채용되어 봉제된 건조감 및 의장성이 부여된 방수의류를 제공한다.Further, the present invention provides a waterproof garment to which the wear resistant breathable waterproof fabric is applied to impart a dried feeling of dryness and designability.
본 발명의 방수의류는 투습방수 코팅면 또는 라미네이팅 필름면에 특정 조성의 표면처리제 수지조성물이 싱크로 인그레이브드 실린더 업로우딩 방식(synchro engraved cylinder up-loading coating method)에 의해 코팅함으로써[도 1], 피부에의 직접 접촉시 건조감, 쾌적감 및 냉감을 극대화시킬 수 있다. 또한, 싱크로 인그레이브드 실린더로부터 원단 코팅면에 효과적이고 견고하게 패턴을 전사시킴으로써, 의장성이 부여되어 안감을 생략할 수 있다. 이에, 경량성, 건조감 및 의장성이 부여된 방수의류를 제공할 수 있다.The waterproof clothing of the present invention can be obtained by coating a surface treatment resin composition having a specific composition on the moisture permeable waterproof coating surface or the laminating film surface by a synchro engraved cylinder up-loading coating method (FIG. 1) , It is possible to maximize the feeling of dryness, comfort, and cold feeling upon direct contact with the skin. In addition, by transferring the pattern from the synchro-engined cylinder to the far-end coating surface effectively and firmly, designability can be imparted and the lining can be omitted. Accordingly, it is possible to provide a waterproof garment imparted with light weight, dry feeling, and designability.
나아가, 본 발명은 안감지 대용의 표면처리된 코팅원단을 봉제할 경우, 특히 방수 또는 투습방수 원단의 경우 심미적 관점에서 심실링 테이프에도 본 원단과 같은 무늬로 표면처리 해주거나 특정 로고 등을 표현해 주어야 함은 당연하다.Furthermore, the present invention can be applied to the case where a surface-treated coated fabric for an inner detection is sewn, especially in the case of a waterproof or breathable waterproof fabric, It is natural.
구체적으로, 본 발명은 이형지, 핫멜트 접착제층 및 폴리우레탄 수지로 제조된 내열성수지 필름층이 순차 합지된 심실링테이프 제작용 원단을 제조하고, 상기 원단 중 내열성수지 필름층 상에, 표면처리제 수지조성물을 싱크로 인그레이브드 실린더 업로우딩 방식으로 전사코팅하여 패턴을 인각한 후, 슬리팅 또는 커팅하여 재단하는 의류봉제용 심실링 테이프의 제조방법을 제공한다.Specifically, the present invention relates to a process for producing a ventral ring tape fabric material in which a release paper, a hot-melt adhesive layer and a heat-resistant resin film layer made of a polyurethane resin are successively laminated, The present invention also provides a method of manufacturing a ventricular ring tape for garment sewing, which comprises slicing or cutting a pattern after transferring the pattern by transcription using a synchronized in-cylinder cylinder up-loading method.
이때, 상기 표면처리제 수지조성물 및 인그레이브드 실린더 업로우딩 방식은 상기에서 구체적으로 설명한 바와 동일하며, 본 발명의 표면처리제 조성물에서, 폴리우레탄수지(고형분 기준) 100 중량부에 대하여, 무기항균제 또는 바이오세라믹계 소취제가 30 중량부 이하로 더 함유될 수 있음도 당연히 이해될 것이다.In this case, the surface treating agent resin composition and the grafted cylinder up-loading method are the same as those described above in detail. In the surface treating agent composition of the present invention, an inorganic antibacterial agent or an inorganic antibacterial agent is added to 100 parts by weight of a polyurethane resin It will be appreciated that the bioceramics deodorant may be further contained in an amount of 30 parts by weight or less.
본 발명의 심실링 테이프는 방수가공원단의 봉제선 실링에 사용하는 것으로서, 먼저 이형지상에 친환경성 핫멜트 접착층을 압출방식으로 30∼80㎛ 두께로 성형한다. 내열성수지 필름층은 캐스팅방식 또는 압출방식으로 20∼70㎛ 두께로 성형하고, 상기 핫멜트 접착층과 열합지하여 라미네이션시킨 후, 내열성수지 필름층 상에 본 발명에 의한 특정 조성의 표면처리제 조성물을 이용한 인그레이브드 실린더 업로우딩 방식으로 전사코팅한다. 이후, 이형지를 박리하고, 요구되는 폭으로 슬리팅 또는 컷팅하여 신축 회복특성, 요철감, 의장성 및 건조감이 우수한 심실링테이프를 얻을 수 있다[표 7]. 또한, 본 발명의 심실링 테이프는 잔류변형율이 35% 이하를 충족한다.The ventricular ring tape according to the present invention is used for sealing a sewing line of a waterproof fabric. First, an eco-friendly hot-melt adhesive layer is formed on the release paper by an extrusion method to a thickness of 30 to 80 m. The heat-resistant resin film layer is formed into a thickness of 20 to 70 탆 by a casting method or an extrusion method, laminated by heat-joining with the hot-melt adhesive layer, and then laminated on the heat-resistant resin film layer with a phosphorus- Transfer coating by graved cylinder up-loading method. Then, peeling off the release paper, and by slitting or cutting to the required width stretch recovery properties, it is possible to obtain a sense of unevenness, design property and the excellent dry feeling ventricular ring tape TABLE 7. In addition, the ventricular ring tape of the present invention satisfies a residual strain of 35% or less.
이하, 실시예를 통하여 본 발명을 보다 상세히 설명하고자 한다. Hereinafter, the present invention will be described in more detail with reference to Examples.
본 실시예는 본 발명을 보다 구체적으로 설명하기 위한 것이며, 본 발명의 범위가 이들 실시예에 한정되는 것은 아니다. The present invention is intended to more specifically illustrate the present invention, and the scope of the present invention is not limited to these embodiments.
<실시예 1> 투습방수원단 제조 1<Example 1> Production of moisture-permeable waterproof fabric 1
1. 표면처리제 수지조성물 제조1. Preparation of resin composition for surface treatment agent
수지 고형분 30% 함유 액상 폴리우레탄수지 100kg, 그라스 펄 40kg, 안료피그먼트 토너(안료고형분 2%) 20kg, 제올라이트계 무기항균제 5kg, 유ㆍ무기 복합화합물 커플링제 0.5kg [(주)마이크로폴사의 MC-502 제품] 및 실리카 분말 2kg을 25kg의 혼합유기용제(디메틸포름아마이드:톨루엔:메틸에틸케톤=1:5:2 중량비로 혼합한 혼합유기용제)에 넣고, 분말이 완전히 혼합될 때까지 교반하고, 100 메쉬의 거름망으로 필터링하여 준비하였다. 이때, 그라스 펄은 구상의 입경분포가 8∼30㎛인 것을 사용하였다.Inorganic microparticulate compound coupling agent 0.5 kg (manufactured by Microfellow Co., Ltd.), 100 kg of a liquid polyurethane resin containing 30% of a resin solid content, 40 kg of a glass pearl, 20 kg of a pigment pigment toner (2% of pigment solid content), 5 kg of a zeolite inorganic antibacterial agent, -502 product] and 2 kg of silica powder were mixed in 25 kg of a mixed organic solvent (mixed organic solvent in which dimethylformamide: toluene: methyl ethyl ketone was mixed at a weight ratio of 1: 5: 2) and stirred until the powders were completely mixed , And filtered by a screen mesh of 100 mesh. At this time, Grass pearls having a spherical particle diameter distribution of 8 to 30 mu m were used.
2. 싱크로 인그레이브드 실린더에 의한 표면처리제 수지조성물의 전사코팅2. Transcription coating of resin composition for surface treatment agent by synchro-engraved cylinder
70 데니어 나이론 원사를 립스탑 조직으로 제직 및 염색후, 투습방수 기능성 폴리우레탄수지로 코팅처리된 방수원단을 원단 페이스면에 편면 발수 가공한 후, 벳칭기 롤에 감긴 상태로 준비하였으며, 이것을 싱크로 인그레이브드 실린더 롤코팅기에 걸고, 전자조각 제판(심도80㎛, 선수30, 격자형 4각 무늬)의 음각롤에 의한 전사코팅 작업을 수행하였다.70 Denier Nylon yarn was woven and dyed with a lips-top fabric, and a waterproof fabric coated with moisture-permeable and water-resistant polyurethane resin was subjected to one-side water-repellent processing on the face face of the raw fabric and then wound on a riveting machine roll. Rolled coating was carried out by a negative roll of an electronic engraving plate (depth of 80 탆, prime 30, lattice quadrangle).
언와인더롤에서 풀린 방수원단이 싱크로 인그레이브드 실린더의 코팅헤드부를 통과하면서 방수원단의 투습방수 기능성 폴리우레탄수지가 코팅된 필름면에 상기 단계 1에서 제조된 표면처리제 수지조성물이 전사되도록 하였다. The waterproof fabric unwound from Unwinderer roll was passed through the coating head of the synchronized grabbed cylinder to allow the surface treatment resin composition prepared in step 1 to be transferred onto the surface of the waterproof fabric coated with moisture permeable and waterproof polyurethane resin.
이후, 표면처리된 방수원단을 열풍에 의한 건조챔버를 통과시켜 표면처리제를 건조시켰다. 챔버의 열풍 온도는 120℃로 하였고, 챔버를 통과하는 속도는 10m/min. 이었다.Thereafter, the surface treated waterproof fabric was passed through a drying chamber by hot air to dry the surface treating agent. The temperature of the hot air in the chamber was 120 캜, and the flow rate through the chamber was 10 m / min. .
<실시예 2> 투습방수원단 제조 2 <Example 2> Production of moisture-permeable waterproof fabric 2
실시예 1에서 전자조각제판 싱크로 인그레이브드 실린더 대신 필름부식제판에 의한 심도 30㎛의 싱크로 인그레이브드 실린더로 전사코팅 작업을 수행하는 것을 제외하고는, 실시예 1과 동일한 방법으로 방수원단의 표면처리 작업을 하였다.The same procedure as in Example 1 was carried out except that in Example 1, a transcription coating operation was carried out with a synchronous grained cylinder having a depth of 30 mu m by a film corroded plate instead of an engraved grained cylinder, And processed.
<실시예 3> 투습방수원단 제조 3 <Example 3> Production of moisture-permeable waterproof fabric 3
실시예 1의 표면처리제 수지조성물에, 알루미노실리케이트계 소취제 10kg을 추가하는 것을 제외하고는, 상기 실시예 1과 동일한 방법으로 전사코팅을 수행하였다.Transfer coating was carried out in the same manner as in Example 1 except that 10 kg of aluminosilicate-based deodorant was added to the surface treating agent resin composition of Example 1.
<실시예 4> 투습방수원단 제조 4<Example 4> Production of moisture-permeable waterproof fabric 4
수지 고형분 30% 함유 액상 폴리우레탄수지 100kg, 주성분이 폴리메틸메타크릴레이트로 구성된 내열내용제성 고분자미립자 30kg, 안료피그먼트 토너(안료고형분 2%) 20kg, 제올라이트계 무기항균제 5kg 및 실리카 분말 2kg을 25kg의 혼합유기용제(디메틸포름아마이드:톨루엔:메틸에틸케톤=1:5:2 중량비로 혼합한 혼합유기용제)에 넣고 분말이 완전히 혼합될 때까지 교반하고, 100메쉬의 거름망으로 필터링하여 준비하였다. 이때, 폴리메틸메타크릴레이트를 주성분으로 구성된 내열내용제성 고분자미립자는 구상의 입경분포가 8∼30㎛인 것을 사용하였다.100 kg of a liquid polyurethane resin containing 30% of a resin solid content, 30 kg of heat-resistant solvent-resistant polymer fine particles composed mainly of polymethyl methacrylate, 20 kg of a pigment pigment toner (pigment solid content 2%), 5 kg of a zeolite inorganic antibacterial agent and 2 kg of a silica powder Was mixed with a mixed organic solvent (dimethylformamide: toluene: methyl ethyl ketone = 1: 5: 2 by weight in a mixed organic solvent), stirred until the powders were completely mixed, and filtered through a 100-mesh sieve. At this time, the heat-resistant solvent-resistant polymer fine particles composed of polymethylmethacrylate as a main component had a spherical particle size distribution of 8 to 30 탆.
<비교예 1>&Lt; Comparative Example 1 &
실시예 1의 표면처리제 수지조성물에 함유된 그라스 펄 대신에 탄산칼슘을 넣는 것을 제외하고는, 실시예 1과 동일한 방법으로 방수원단의 전사코팅 작업을 수행하였다. The surface coating agent of Example 1 was coated with a waterproof cloth in the same manner as in Example 1, except that calcium carbonate was used instead of the glass powder contained in the resin composition.
<비교예 2>&Lt; Comparative Example 2 &
실시예 1의 표면처리제 수지조성물에 그라스 펄이 함유되지 않은 것을 제외하고는, 상기 실시예1 과 동일한 방법으로 방수원단의 전사코팅 작업을 수행하였다.Transparent coating of the waterproof fabric was performed in the same manner as in Example 1, except that the glass beads were not contained in the resin composition of the surface treating agent of Example 1.
<비교예 3>&Lt; Comparative Example 3 &
상기 실시예 4의 표면처리제 수지조성물에서, 폴리메틸메타크릴레이트를 주성분으로 구성된 내열내용제성 고분자미립자의 입경분포가 50∼100㎛인 것을 제외하고는, 상기 실시예 4와 동일한 방법으로 방수원단의 전사코팅 작업을 수행하였다.The same procedure as in Example 4 was carried out except that the particle diameter distribution of the heat-resistant solvent-resistant polymer fine particles composed of polymethyl methacrylate as a main component was 50 to 100 占 퐉 in the surface treatment resin composition of Example 4, Transcription coating was performed.
<실시예 5> 심실링 테이프 제조 1Example 5: Ventricular ring tape preparation 1
유동개시점이 95℃인 저융점 폴리우레탄 핫멜트 접착제를 크라프트 이형지에 두께50㎛, 폭 54 인치로 압출 성형시켜 접착제층을 제조하였다. A low melting point polyurethane hot melt adhesive having a flow starting point of 95 占 폚 was extruded into a 50 占 퐉 thick and 54 inch wide cross-linked release paper to prepare an adhesive layer.
폴리에스터폴리올 및 디이소시아네이트가 주성분인 용액형 폴리우레탄(CYTEC사제UCECOAT-775) 1액형 스킨 수지(고형분 30% 함유) 100 중량부에 대하여, 메틸에틸케톤 20 중량부, 실리카 파우더(DAEGUSA제 OK-412) 5 중량부를 처방하여, 두께 40㎛, 폭 57인치로 RP(Release Paper) 상에 콤마 코팅하여 80℃에서 건조 및 120℃에서 20m/min의 속도로 열처리하는 연속공정으로 두께 40㎛, 폭 57인치로 캐스팅 필름을 제조하고, 박리하여 110℃의 열실린더에서 상기 준비한 핫멜트 접착제층과 열합지하여 심실링테이프 제작용 원단 시트를 제조하였다. 20 parts by weight of methyl ethyl ketone, 20 parts by weight of silica powder (manufactured by DAEGUSA OK-775, manufactured by DAI-US KK), 100 parts by weight of a solution type polyurethane mainly containing polyester polyol and diisocyanate (UCECOAT- 412), followed by comma coating on RP (Release Paper) at a thickness of 40 占 퐉 and a width of 57 inches, followed by drying at 80 占 폚 and heat treatment at 120 占 폚 at a rate of 20 m / min. A casting film was prepared at 57 inches, peeled, and heat-laminated with the prepared hot-melt adhesive layer in a heat cylinder at 110 캜 to prepare a fabric sheet for manufacturing a ventricular ring tape.
상기 제작된 이형지가 합지된 원단 시트를 실시예 1의 단계 2의 싱크로 인그레이브드 실린더에 의한 표면처리제 수지조성물의 전사코팅 공정을 수행하여 사각도트로 연결된 사각격자 패턴 무늬를 인각시킨 후, 크라프트 이형지를 제거하고 롤 상으로 권취한 후, 롤 컷팅기에서 20mm 폭으로 재단하여 심실링테이프를 제조하였다.The fabric sheet with the fabricated releasing paper laminated thereon was subjected to a transfer coating process of the resin composition of the surface treating agent by the synchronous grained cylinder of step 2 of Example 1 to grind the quadrangular lattice pattern connected with square dots, And rolled up into a roll, and cut into a width of 20 mm in a roll cutter to produce a ventricular ring tape.
<실시예 6>&Lt; Example 6 >
상기 실시예 5에서 내열층용 1액형 스킨수지를 R/P 캐스팅 공법이 아닌 무용제형 압출 열가소성 폴리우레탄 필름을 사용하는 것을 제외하고는, 상기 실시예 5와 동일하게 수행하여, 심실링 테이프를 제조하였다.A ventricular ring tape was produced in the same manner as in Example 5, except that the one-pack type skin resin for heat resistant layer in Example 5 was used as a non-solvent extruded thermoplastic polyurethane film instead of the R / P casting method .
<비교예 4>&Lt; Comparative Example 4 &
내열 R/P상에 콤마 코팅으로 용액형 핫멜트형 폴리우레탄 접착제(SAMHO CHEMICAL CO., LTD 제 SPU-10710,고형분30%) 100 중량부에 대하여, 메틸에틸케톤 25 중량부의 처방으로 5M/MIN.의 속도로 코팅하고, 연속하여 폴리에스터폴리올 및 디이소시아네이트가 주성분인 용액형 폴리우레탄(CYTEC사제 UCECOAT-775) 1액형 스킨 수지(고형분 30% 함유) 100 중량부에 대하여, 메틸에틸케톤 20 중량부, 실리카 파우더(DAEGUSA제 OK-412) 5 중량부로 내열 스킨층을 코팅하여 80℃ 건조 및 120℃ 열처리를 수행하여 심실링테이프용 시트원단을 제조하는 것을 제외하고는, 상기 실시예5와 동일한 방법으로 수행하여 심실링 테이프를 제조하였다.MIN / MIN of a solution type hot melt type polyurethane adhesive (SPU-10710 made by SAMHO CHEMICAL CO., LTD., Solid content 30%) with a comma coating on a heat resistant R / P was prepared with 25 parts by weight of methyl ethyl ketone. And 100 parts by weight of a one-pack type skin resin (containing 30% solid content) of a solution type polyurethane (UCECOAT-775, manufactured by CYTEC Co., Ltd.) containing polyester polyol and diisocyanate as main components, 20 parts by weight of methyl ethyl ketone And 5 parts by weight of silica powder (DAKUSA OK-412) were coated with a heat-resistant skin layer, followed by drying at 80 ° C. and heat treatment at 120 ° C. to prepare a seat fabric for a ventricular ring tape. To produce a ventricular ring tape.
<실험예 1><Experimental Example 1>
상기 실시예 1∼4 및 비교예 1∼3에서 제조된 투습방수원단에 대하여, 촉감, 내마모성, 착용감, 항균방취 성능 및 소취성능의 물성을 시험하여 하기 표 1 내지 표 5에 나타내었다.The breathable and waterproof fabrics prepared in Examples 1 to 4 and Comparative Examples 1 to 3 were tested for tactile, abrasion resistance, wearing comfort, antibacterial performance and deodorization performance, as shown in Tables 1 to 5 below.
1. 촉감 : 손에 의한 촉감 테스트(hand feel test)1. Touch: hand feel test
상기 실시예 1∼4 및 비교예 1∼2에서 제조된 투습방수원단에 대하여, 30명의 섬유 기술분야 당업자 및 30명의 일반 소비자가 참여하여, 손에 의한 촉감 중, 원단의 요철감, 슬립성, 건조감 및 냉감에 대한 관능검사를 수행하고, 그 결과를 하기 표 1에 기재하였다.30 persons skilled in the field of textile technology and 30 ordinary consumers participated in the breathable and waterproof fabrics produced in Examples 1 to 4 and Comparative Examples 1 and 2 so that the feeling of roughness, slipperiness, The sensory evaluation on the feeling of dryness and coldness was carried out, and the results are shown in Table 1 below.
이때, 상기 촉감이 요철감이 매우 두드러지고, 표면처리된 원단면끼리 마주보고 비빌 경우 슬립이 매우 잘 이루어지고, 손등으로 문질렀을 경우 건조감이 매우 우수하고, 손등으로 만졌을 경우, 차가운 감이 매우 느껴질 경우를 매우 우수(◎),At this time, when the touch feeling is very conspicuous, when the surface treated circular cross sections are facing each other, the slip is very well performed, and when it is rubbed with the back of the hand, the dry feeling is excellent, and when it is touched with the hand touch, If the case is very good (◎),
상기 촉감이 요철감이 두드러지고, 표면처리된 원단면끼리 마주보고 비빌 경우 슬립이 잘 이루어지고, 손등으로 문질렀을 경우 건조감이 우수하고, 손등으로 만졌을경우 차가운 감이 우수한 경우, 우수(○), When the touch is conspicuous, the surface of the circular cross section is visually opposed to each other, the slip is well performed. When the touch is rubbed with the back of the hand, the dry feeling is excellent. When the hand touch is excellent,
상기 촉감이 요철감이 다소 있고, 표면처리된 원단면끼리 마주보고 비빌 경우 다소슬립이 이루어지며, 손등으로 문질렀을 경우 건조감이 약하게 느껴지며, 손등으로 만졌을 경우 차가운 감이 약간 느껴지는 경우 보통(△) 및 (△) When the touch feeling is slight, there is a slight feeling of irregularity. When the surface treated circular cross sections are opposite to each other, a little slip occurs. When the rubbing with the back of the hand feels a little dry feeling, And
상기 촉감이 요철감이 전혀없고, 표면처리된 원단면끼리 마주보고 비빌 경우 슬립이 잘 이루어지지 않고, 손등으로 문질렀을 경우 건조감이 매우 약하며, 손등으로 만졌을 경우 차가운 감이 느껴지지 않는 경우, 불량(×)으로 판정하였다. If the feel is not irregular, the surface is not visibly slippery when facing each other, and if it is rubbed with the back of the hand, the feeling of dryness is very weak. If the touch is not felt cold, ×).
Figure PCTKR2010001934-appb-I000001
Figure PCTKR2010001934-appb-I000001
상기 손에 의한 촉감 테스트 결과, 본 발명의 표면처리제 수지조성물을 이용하여 전사코팅한 경우, 그라스 펄 또는 내열내용제성 고분자 구상입자를 함유하지 않고 제조된 원단보다 우수한 결과를 보였다. 특히, 그라스 펄을 함유한 표면처리제 수지조성물을 이용하여 전사코팅하여 제조된 원단의 경우, 요철감, 슬립성, 건조감 및 냉감에 대한 물성을 최적화시켰으며, 제판공정 시, 전자조각제판 싱크로 인그레이브드 실린더를 이용한 경우(실시예 1), 필름부식제판 싱크로 인그레이브드 실린더로 전사코팅한 경우(실시예 2)보다 우수한 촉감을 나타내었다.As a result of the hand-tactile test, the result of the transcription coating using the resin composition of the present invention showed better results than that of the fabric prepared without the spherulite particles or the heat-resistant solvent-resistant spherical particles. Particularly, in the case of a fabric prepared by transcription coating using a surface treatment agent resin composition containing grass pearl, the physical properties of irregularity, slipperiness, dry feeling and cold feeling were optimized, and in the plate making process, (Example 1) exhibited a better tactile sensation than Example 2 (Example 2) in which transfer coating was carried out using a grained cylinder of a film corrosion-resistant plate.
2. 내마모성 시험2. Abrasion resistance test
상기 실시예 1, 4 및 비교예 1에서 제조된 투습방수원단에 대하여, 마모측정기(TABER Abrasion Tester)를 이용하여, 마모정도를 비교 평가하였다.In the Examples 1 and 4 and Comparative Example 1, The moisture permeable and waterproof fabric was subjected to comparative evaluation using abrasion tester (TABER Abrasion Tester).
*직경 10cm 원판에 상기 투습방수원단을 장착하고, 미국(TABER Industries)의 표준마모시험법 NO. CS-10으로 100 회 실시하여, 시험 전후의 중량감소 및 마모외관 상태를 육안 관찰하였다.* The breathable and waterproof fabric was mounted on a 10 cm diameter disc and subjected to a standard abrasion test method of TABER Industries (USA). CS-10 for 100 times to visually observe the weight loss before and after the test and the appearance of the wear and tear.
이때, 시험편이 마모손상이 육안으로 거의 없을 경우 ◎, 시험편 마모손상이 약간 보일 경우 ○ 및 시험편 마모손상이 현저할 경우를 ×로 판정하였다.At this time, the test piece was evaluated as? When there was almost no abrasion damage to the naked eye,? When the specimen wear was slightly damaged, and X when the specimen wear was remarkable.
또한, 도 2 내지 도 4는 상기 실시예 1, 4 및 비교예 1에서 제조된 투습방수원단을 이용한 시험편을 100회 마모시험 후 사진결과를 나타낸다.FIGS. 2 to 4 show photographs of the test piece using the breathable and waterproof fabric prepared in Examples 1 and 4 and Comparative Example 1 after 100 times of abrasion test.
Figure PCTKR2010001934-appb-I000002
Figure PCTKR2010001934-appb-I000002
상기 내마모성 실험 결과, 그라스 펄 또는 내열내용제성 고분자 구상입자를 함유한 표면처리제 수지조성물을 이용하여 전사코팅한 경우(실시예 1 및 4), 100회 마모조건 하에서도 마모전후의 중량감소가 현저히 감소하였으며, 특히, 그라스 펄을 함유한 경우, 마모손상 정도의 외관변화가 거의 없을 정도로 우수한 내마모성을 보였다. As a result of the above abrasion resistance test, it was found that when the surface coating agent resin composition containing glass pearls or heat resistant solvent-resistant polymer spherical particles was used for transfer coating (Examples 1 and 4), the weight loss before and after abrasion was remarkably reduced In particular, when the glass pearl was contained, the abrasion resistance was excellent enough that there was almost no change in appearance of the abrasion damage degree.
3. 착용감3. Wearing comfort
상기 실시예 1∼4 및 비교예 1∼2에서 제조된 투습방수원단으로 의류를 제작한 후, 착용감을 비교 시험하였다. 이때, 상기 투습방수원단에 별도의 안감지를 대지 않고 제작하였다. After the clothes were produced with the breathable and waterproof fabrics prepared in Examples 1 to 4 and Comparative Examples 1 and 2, the feeling of comfort was comparatively tested. At this time, the breathable and waterproof fabric was produced without a separate liner.
착용감은 착용자가 피부에 닿는 면을 중심으로 관능검사를 실시하였으며, 쾌적(○), 보통(△) 및 불쾌감(×)으로 분류하였다.Sensory evaluation was performed on the surface of the wearer touching the skin and classified as pleasant (◯), normal (△) and discomfort (×).
Figure PCTKR2010001934-appb-I000003
Figure PCTKR2010001934-appb-I000003
4. 항균 방취 성능4. Antibacterial performance
상기 실시예 1∼4 및 비교예 1∼2에서 제조된 투습방수원단에 대한 항균 방취시험을 하기 조건 하에서 수행하였다. The antibacterial and deodorant tests on the breathable and waterproof fabrics prepared in Examples 1 to 4 and Comparative Examples 1 and 2 were carried out under the following conditions.
사용한 균주로는 식중독의 주원인균인 황색포도상 구균(Staphylcoccus aureus ATCC 6538) 및 폐렴균인 폐렴막대균(Klebsiella pneumoniae ATCC 4352)을 0.05% 비이온계 계면활성제(Snogen) 상에 접종하여 37℃에서 24시간 배양한 균을 접종원으로 사용하였다. 표준포는 KS K 0905 염색견뢰도용 면소재 백포를 사용하였으며, 상기 항균성 실험 결과를 하기 표 4에 기재하였다. Staphylococcus aureus ATCC 6538 and pneumoniae Klebsiella pneumoniae ATCC 4352 were inoculated on 0.05% nonionic surfactant (Snogen) at 37 ℃ for 24 hours The cultured bacteria were used as an inoculum. The standard cell was KS K 0905 cotton material for dyeing fastness, and the results of the antimicrobial activity test are shown in Table 4 below.
Figure PCTKR2010001934-appb-I000004
Figure PCTKR2010001934-appb-I000004
5. 탈취 성능5. Deodorizing performance
상기 실시예 1∼4 및 비교예 1∼2에서 제조된 투습방수원단을 암모니아가스가 들어있는 용기 내에 노출시켜 흡수되고 남은 양을 시간의 경과에 따라 측정하였으며, 하기 조건 하에서 수행하였다. The moisture-permeable and waterproof fabric prepared in Examples 1 to 4 and Comparative Examples 1 and 2 was exposed in a container containing ammonia gas, and the amount of the water absorbed and remained was measured over time, and was performed under the following conditions.
시험편 : 10 × 10 ㎠Test piece: 10 × 10 cm 2
가스백 : 5LGas bag: 5L
가스백 내 가스량 : 3LGas volume in gas bag: 3L
측정시간 : 2시간 경과 후Measurement time: After 2 hours
초기농도 :암모니아(100 ppm)Initial concentration: Ammonia (100 ppm)
탈취율 % = (Cb - Cs)/ Cb)×100Deodorization ratio% = (C b - C s ) / C b ) × 100
(상기에서, Cb; blank, 2시간 경과 후 시험용기 안에 남아있는 시험가스의 농도이고, Cs; sample, 2시간 경과 후 시험용기 안에 남아있는 시험가스의 농도이다.)(Cb; blank, the concentration of the test gas remaining in the test vessel after 2 hours, Cs; sample, the concentration of the test gas remaining in the test vessel after 2 hours).
Figure PCTKR2010001934-appb-I000005
Figure PCTKR2010001934-appb-I000005
6. 내세탁성6. Washability
상기 실시예 1, 4 및 비교예 1에서 제조된 투습방수원단을 10회 세탁시험한 후, 그라스 펄 또는 내열내용제성 고분자 구상입자의 탈락에 의한 표면촉감 변화를 분석 평가하였다.In the Examples 1 and 4 and Comparative Example 1, Waterproof breathable fabric After 10 times of the washing test, changes in surface tactile sensation due to dropping of spherical pearl or heat resistant water-resistant polymer spherical particles were analyzed and evaluated.
◎; 요철감, 건조감, 냉감, 슬립감 등 감성 지수가 매우 훌륭함.◎; Feeling of irregularity, feeling of dryness, cold feeling, slip sensation are very good.
○; 요철감, 건조감, 냉감, 슬립감 등 감성 지수가 다소 좋은 편임.○; The feeling of irregularity, feeling of dryness, cold feeling, slip feeling and the feeling index are somewhat good.
△; 요철감, 건조감, 냉감, 슬립감 등 감성 지수가 그다지 좋지 못함.?; Feeling of irregularity, feeling of dryness, cold feeling, slipperiness, etc. are not so good.
Figure PCTKR2010001934-appb-I000006
Figure PCTKR2010001934-appb-I000006
상기 결과로부터, 실시예 1 및 4에서 제조된 투습방수원단의 경우, 10회 세탁이후에도 그라스 펄 또는 내열내용제성 고분자 구상입자의 탈락없이 우수한 촉감을 유지하였다. From the above results, in the case of the moisture-permeable and waterproof fabrics prepared in Examples 1 and 4, even after 10 times of washing, excellent tactile feeling was maintained without dropping of Grass pearl or heat-resistant solvent-resistant polymer spherical particles.
<실험예 2> 심실링 테이프의 물성측정<Experimental Example 2> Measurement of physical properties of ventricular ring tape
실시예 5∼6 및 비교예 4에서 제조된 심실링 테이프에 대하여, 인장실험 이후, 인장이전의 상태로 회복되기까지의 변형정도를 나타내는 잔류변형율, 인장강도 및 신도에 관한 물성을 측정하여 하기 표 7에 나타내었다. Tensile strength and elongation of the ventricular ring tape prepared in Examples 5 to 6 and Comparative Example 4 were measured after tensile test to determine the extent of deformation until recovery to the state before tensile was measured, 7.
Figure PCTKR2010001934-appb-I000007
Figure PCTKR2010001934-appb-I000007
그 결과, 본 발명의 심실링 테이프는 본 발명의 제조방법인 싱크로 인그레이브드 실린더 업로우딩 방식으로 투습방수원단 코팅면에 직접 전사코팅함으로써, 원단과 같은 패턴 무늬로 표면처리할 수 있다. As a result, the ventricular ring tape of the present invention can be surface-treated in the same pattern as the fabric by directly transfer-coating the breathable and waterproof fabric coated surface with the synchro-grained cylinder up-loading method of the present invention.
또한, 본 발명의 심실링 테이프는 우수한 잔류변형율, 인장강도 및 신도에 관한 물성전반을 보임으로써, 안감지 대용의 투습방수원단의 봉제용도에 적합하다.Further, the ventricular ring tape of the present invention exhibits excellent overall residual strain, tensile strength and physical properties relating to elongation, and is thus suitable for use in sewing moisture-permeable and waterproof fabrics for use as an inner detection.
본 발명의 내마모 투습방수원단의 제조방법에 따라, 특정 성분의 표면처리제 수지조성물을 싱크로 인그레이브드 실린더 업로우딩 방식에 의해 투습방수원단 코팅면에 효과적으로 견고하게 전사시킴으로써 요철감, 건조감, 의장성 및 내마모성을 극대화시키는 효과가 있다.According to the method of manufacturing the moisture resistant breathable waterproof fabric of the present invention, the surface treatment agent resin composition of a specific component is effectively and firmly transferred to the moisture permeable waterproof fabric coated surface by the synchronous grained cylinder up-loading method, It has an effect of maximizing the property and abrasion resistance.
또한, 본 발명의 제조방법에 의해 제조된 투습방수원단은 가볍고, 부피가 작아 일반 캐주얼, 스포츠용, 방수 방풍용의 방수의류에 매우 유용하게 채용될 수 있다.Further, the moisture-permeable and waterproof fabric produced by the manufacturing method of the present invention is light and small in volume, and thus can be very usefully employed in general casual wear, sports wear, and waterproof clothing for waterproof windshields.
또한, 본 발명의 투습방수원단을 채용하여 봉제된 의류제품은 별도의 안감지가 필요하지 않게 되어 의류제품이 경량화되고 부피감이 작아지며, 잘 접어지므로 패커블(Packable)하게 되는 효과가 있다. 또한, 본 발명의 패커블성이 우수한 방수의류는 코팅면의 내구성이 강하여 의복의 착의 탈의시 또는 피부와 접촉시 내스크래치성이 좋고, 건조감, 냉감이 우수하여 쾌적한 착용감을 부여하는 효과가 있어서 더운 날씨에도 시원한 감이 부여되는 효과가 있다.In addition, the garment product sewn with the breathable and waterproof cloth of the present invention does not require a separate liner cloth, so that the weight of the clothing product is reduced, the volume of the garment is reduced, and the folded cloth is packable. In addition, the waterproof garment having excellent packability of the present invention has a strong durability on the coated surface, so that it has a good scratch resistance at the time of dressing clothes or in contact with the skin, and is excellent in drying feeling and cold feeling, There is an effect that even a cool feeling is given.
본 발명의 내마모 투습방수원단의 제조방법을 심실링 테이프에 적용하여, 안감지 대용의 표면처리된 코팅원단을 봉제할 경우, 특히 방수 또는 투습방수원단의 심미적 관점에서 심실링 테이프에도 본 원단과 같은 무늬로 표면처리할 수 있다.When the method of manufacturing the wear resistant breathable waterproof fabric of the present invention is applied to the ventricular ring tape to sew the surface treated coated fabric for the inner perception detection, The surface can be treated with the same pattern.
이상에서 본 발명은 기재된 구체예에 대해서만 상세히 설명되었지만 본 발명의 기술사상 범위 내에서 다양한 변형 및 수정이 가능함은 당업자에게 있어서 명백한 것이며, 이러한 변형 및 수정이 첨부된 특허청구범위에 속함은 당연한 것이다. While the invention has been shown and described with reference to certain exemplary embodiments thereof, it will be understood by those skilled in the art that various changes and modifications may be made without departing from the spirit and scope of the invention as defined by the appended claims.

Claims (12)

  1. 제직 또는 편직 후 염색 가공된 원단에 투습방수 코팅가공을 수행하는 단계; Performing a breathable and waterproof coating process on the fabric dyed and processed after weaving or knitting;
    상기 투습방수 코팅가공되어 롤상으로 공급되어 온 원단 상에 그라스 펄 또는 가교 폴리메틸메타크릴레이트 고분자 미립자 또는 가교 폴리우레탄 고분자 미립자에서 선택되는 내열내용제성 고분자 구상입자 단독 또는 혼합형태가 함유된 표면처리제 수지조성물을 싱크로 인그레이브드 실린더 업로우딩 방식으로 전사코팅하는 단계; 및 A surface treatment agent resin containing a heat resistant solvent-resistant high molecular weight spherical particle alone or mixed form selected from graphelin or crosslinked polymethylmethacrylate polymer fine particles or crosslinked polyurethane polymer fine particles on the fabric which has been subjected to the moisture- Transfer coating the composition in a synchronous grained cylinder up-loading manner; And
    상기 전사코팅된 원단을 건조하는 단계를 포함하는 건조감 및 의장성이 부여된 내마모 투습방수원단의 제조방법.And drying the transcriptionally coated fabric. The method of claim 1,
  2. 제1항에 있어서, 상기 싱크로 인그레이브드 실린더의 심도는 40 내지 300㎛인 것을 특징으로 하는 상기 내마모 투습방수원단의 제조방법.The method of claim 1, wherein the depth of the synchro-grabbed cylinder is 40 to 300 占 퐉.
  3. 제1항에 있어서, 상기 표면처리제 수지조성물이 폴리우레탄수지(고형분 기준) 100 중량부에 대하여, 혼합유기용제 30 내지 300 중량부, 그라스 펄 30 내지 300 중량부, 안료피그먼트 3 내지 6 중량부, 블록킹 방지제 1.5 내지 15중량부 및 유ㆍ무기복합화합물로 이루어진 커플링제 0.5 내지 2.0 중량부로 이루어진 것을 특징으로 하는 상기 내마모 투습방수원단의 제조방법.The surface treatment agent composition according to claim 1, wherein the surface treating agent resin composition comprises 30 to 300 parts by weight of a mixed organic solvent, 30 to 300 parts by weight of a glass bead, 3 to 6 parts by weight of a pigment pigment (based on 100 parts by weight of a polyurethane resin 1.5 to 15 parts by weight of an antiblocking agent, and 0.5 to 2.0 parts by weight of a coupling agent comprising an organic-inorganic hybrid compound.
  4. 제1항에 있어서, 상기 표면처리제 수지조성물이 폴리우레탄수지(고형분 기준) 100 중량부에 대하여, 혼합유기용제 30 내지 300 중량부, 가교 폴리메틸메타크릴레이트 고분자 미립자 또는 가교 폴리우레탄 고분자 미립자에서 선택되는 내열내용제성 고분자 구상입자 30 내지 300 중량부, 안료피그먼트 3 내지 6 중량부 및 블록킹 방지제 1.5 내지 15중량부로 이루어진 것을 특징으로 하는 상기 내마모 투습방수원단의 제조방법.The surface treatment agent composition according to claim 1, wherein the surface treating agent resin composition is selected from the group consisting of 30 to 300 parts by weight of a mixed organic solvent, 100 parts by weight of a crosslinked polymethylmethacrylate polymer fine particle or crosslinked polyurethane polymer fine particles based on 100 parts by weight of a polyurethane resin (solid basis) , 30 to 300 parts by weight of heat-resistant solvent-resistant spherical polymer particles, 3 to 6 parts by weight of pigment pigment and 1.5 to 15 parts by weight of an anti-blocking agent.
  5. 제3항 또는 제4항에 있어서, 상기 표면처리제 조성물에 The surface treatment agent composition according to claim 3 or 4,
    폴리우레탄수지(고형분 기준) 100 중량부에 대하여, 무기항균제 또는 바이오세라믹계 소취제가 30 중량부 이하로 더 함유되는 것을 특징으로 하는 상기 내마모 투습방수원단의 제조방법.Wherein the inorganic antibacterial agent or the bioceramics based deodorant is further contained in an amount of 30 parts by weight or less based on 100 parts by weight of the polyurethane resin (on a solid basis).
  6. 제5항에 있어서, 상기 무기항균제가 무기계 세라믹물질 제올라이트계인 것을 특징으로 하는 상기 내마모 투습방수원단의 제조방법.[6] The method according to claim 5, wherein the inorganic antibacterial agent is an inorganic ceramic material zeolite.
  7. 제3항 또는 제4항에 있어서, 상기 혼합유기용제가 톨루엔, 메틸에틸케톤, 디메틸포름아마이드, 이소프로필알콜, 크실렌, 퍼클로로에틸렌, 아세톤 및 에틸아세테이트로 이루어지는 군에서 선택되는 둘 이상의 혼합물인 것을 특징으로 하는 상기 내마모 투습방수원단의 제조방법.5. The method according to claim 3 or 4, wherein the mixed organic solvent is a mixture of two or more selected from the group consisting of toluene, methyl ethyl ketone, dimethyl formamide, isopropyl alcohol, xylene, perchlorethylene, acetone and ethyl acetate Wherein said waterproof breathable fabric is produced by a method comprising the steps of:
  8. 제1항 내지 제7항의 제조방법에 의해 제조되되, 8. A process for producing a compound according to any one of claims 1 to 7,
    투습방수원단 상에 싱크로 인그레이브드 실린더의 무늬심도가 40 내지 300㎛로 전사되어 건조감 및 의장성이 부여된 내마모 투습방수원단.Breathable breathable waterproof fabric with a patterned depth of 40 to 300 ㎛ of a synchronized grained cylinder on the breathable waterproof fabric, giving dry feeling and designability.
  9. 제8항의 내마모 투습방수원단이 채용되어 봉제된 건조감 및 의장성이 부여된 방수의류.The waterproof clothing with the dry feeling and the design is sewn by adopting the abrasion breathable waterproof fabric of paragraph 8.
  10. 이형지상에 핫멜트 접착제층 및 폴리우레탄 수지로 제조된 내열성수지 필름층이 순차 합지된 심실링테이프 제작용 원단을 제조하고, A fabric for producing a ventricular ring tape in which a hot-melt adhesive layer and a heat-resistant resin film layer made of a polyurethane resin are successively laminated on a release sheet,
    상기 원단 중 내열성수지 필름층 상에, 제3항 또는 제4항의 표면처리제 수지조성물을 싱크로 인그레이브드 실린더 업로우딩 방식으로 전사코팅하여 패턴을 인각한 후 슬리팅 또는 커팅하여 재단하는 의류봉제용 심실링 테이프의 제조방법.The resin composition of the surface treatment agent of claim 3 or 4 is transferred and coated on the heat-resistant resin film layer of the fabric by a synchronous grained cylinder up-loading method to cut the pattern and then cut by slitting or cutting. Method of manufacturing a ventricular ring tape.
  11. 제10항에 있어서, 상기 표면처리제 조성물에 무기항균제 또는 바이오세라믹계 소취제가 30 중량부 이하로 더 함유된 것을 특징으로 하는 상기 의류봉제용 심실링 테이프의 제조방법.The method according to claim 10, wherein the surface treatment composition further contains an inorganic antibacterial agent or a bioceramics deodorant in an amount of 30 parts by weight or less.
  12. 제10항에 있어서, 잔류변형율이 35%이하인 것을 특징으로 하는 상기 의류봉제용 심실링 테이프의 제조방법.The method according to claim 10, wherein the residual strain is 35% or less.
PCT/KR2010/001934 2009-04-03 2010-03-30 Method for manufacturing abrasion-resistant vapor-permeable waterproof fabric having excellent dryness and design, vapor-permeable waterproof fabric and waterproof garments manufactured by same, and method for manufacturing a seam-sealing tape for garment sewing WO2010114282A2 (en)

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