WO2010091805A2 - Verfahren zum abtrennen von stickstoff - Google Patents
Verfahren zum abtrennen von stickstoff Download PDFInfo
- Publication number
- WO2010091805A2 WO2010091805A2 PCT/EP2010/000615 EP2010000615W WO2010091805A2 WO 2010091805 A2 WO2010091805 A2 WO 2010091805A2 EP 2010000615 W EP2010000615 W EP 2010000615W WO 2010091805 A2 WO2010091805 A2 WO 2010091805A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- nitrogen
- fraction
- feed
- rich
- heat exchanger
- Prior art date
Links
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/0204—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the feed stream
- F25J3/0209—Natural gas or substitute natural gas
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/0228—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
- F25J3/0233—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of CnHm with 1 carbon atom or more
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/0228—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
- F25J3/0257—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of nitrogen
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2200/00—Processes or apparatus using separation by rectification
- F25J2200/04—Processes or apparatus using separation by rectification in a dual pressure main column system
- F25J2200/06—Processes or apparatus using separation by rectification in a dual pressure main column system in a classical double column flow-sheet, i.e. with thermal coupling by a main reboiler-condenser in the bottom of low pressure respectively top of high pressure column
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2200/00—Processes or apparatus using separation by rectification
- F25J2200/72—Refluxing the column with at least a part of the totally condensed overhead gas
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2200/00—Processes or apparatus using separation by rectification
- F25J2200/78—Refluxing the column with a liquid stream originating from an upstream or downstream fractionator column
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2210/00—Processes characterised by the type or other details of the feed stream
- F25J2210/42—Nitrogen
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2210/00—Processes characterised by the type or other details of the feed stream
- F25J2210/62—Liquefied natural gas [LNG]; Natural gas liquids [NGL]; Liquefied petroleum gas [LPG]
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2235/00—Processes or apparatus involving steps for increasing the pressure or for conveying of liquid process streams
- F25J2235/60—Processes or apparatus involving steps for increasing the pressure or for conveying of liquid process streams the fluid being (a mixture of) hydrocarbons
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2245/00—Processes or apparatus involving steps for recycling of process streams
- F25J2245/90—Processes or apparatus involving steps for recycling of process streams the recycled stream being boil-off gas from storage
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2270/00—Refrigeration techniques used
- F25J2270/90—External refrigeration, e.g. conventional closed-loop mechanical refrigeration unit using Freon or NH3, unspecified external refrigeration
- F25J2270/904—External refrigeration, e.g. conventional closed-loop mechanical refrigeration unit using Freon or NH3, unspecified external refrigeration by liquid or gaseous cryogen in an open loop
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2280/00—Control of the process or apparatus
- F25J2280/20—Control for stopping, deriming or defrosting after an emergency shut-down of the installation or for back up system
Definitions
- the invention relates to a process for separating a nitrogen-rich fraction from a feed fraction containing essentially nitrogen and hydrocarbons, wherein the feed fraction is partially condensed and rectified into a nitrogen-rich and a methane-rich fraction.
- the feed fraction containing essentially nitrogen and hydrocarbons which originates, for example, from an upstream LNG plant, is introduced. It preferably has a pressure which is greater than 25 bar. It may have been subjected to a pretreatment such as sulfur removal, carbon dioxide removal, drying, etc. In the heat exchanger E1 it is cooled against process streams, which will be discussed in more detail below, and partially condensed. After the valve d, the partially condensed feed fraction is then fed via line 1 'to a high-pressure column T1.
- This high-pressure column T1 together with the low-pressure column T2, forms a double column T1 / T2.
- a hydrocarbon-rich liquid fraction is withdrawn via line 2, subcooled in the heat exchanger E2 against process streams, which will be discussed in more detail below, and then fed via line 2 'and expansion valve a to the low-pressure column T2 in the upper region.
- a liquid nitrogen-rich fraction is withdrawn from the upper region of the pre-separation column T1.
- a partial stream of this fraction is added via line 3 1 as reflux to the pre-separation column T1.
- the withdrawn via line 3 Nitrogen-rich fraction is supercooled in the heat exchanger E2 and fed via line 3 "and expansion valve b of the low pressure column T2 above the feed point of the above-described methane-rich fraction.
- a methane-rich liquid fraction which in addition to methane includes the higher hydrocarbons contained in the feed fraction withdrawn. Their nitrogen content is typically less than 5 mole%.
- the methane-rich fraction is pumped by the pump P to the highest possible pressure - this is usually between 5 and 15 bar - pumped.
- the methane-rich liquid fraction is heated and optionally partially evaporated. Via line 5 1 , it is then fed to the heat exchanger E1 and completely evaporated in this against the feed fraction to be cooled and superheated.
- the methane-rich fraction is then compressed to the desired discharge pressure, which is usually more than 25 bar, and withdrawn from the process via line 5 ".
- NRUs Nelculation Unit
- Nitrogen separation from nitrogen / hydrocarbon mixtures is always carried out when an increased nitrogen content prevents the intended use of the nitrogen / hydrocarbon mixture. For example, one exceeds
- NRUs Nitrogen content of more than 5 mol% Typical specifications of natural gas pipelines in which the nitrogen / hydrocarbon mixture is transported. Even gas turbines can only be operated up to a certain nitrogen content in the fuel gas.
- Such NRUs are typically constructed similarly to an air fractionator with a double column, such as described with reference to FIG 1, as Monef process unit and arranged as a rule in a so-called. CoId box.
- NRU feed gas nitrogen and hydrocarbons-containing feed fraction
- U. may last longer than a week. This long warm start-up startup time is lost as production time and can therefore lead to significant financial losses. This is particularly the case when the NRU is integrated with other installations whose production depends on the functioning of the NRU; LNG plants with a fuel gas treatment for gas turbines by the NRU are mentioned as examples.
- the object of the present invention is to provide a generic method for separating a nitrogen-rich fraction from a feed fraction containing essentially nitrogen and hydrocarbons, which avoids the disadvantages described above.
- a generic method for separating a nitrogen-rich fraction from a feed fraction containing essentially nitrogen and hydrocarbons is proposed, which is characterized in that the (n) separation column (n) used for the rectification separation during an interruption of the feed fraction ( n) and the heat exchangers used for the partial condensation of the feed fraction and the cooling and heating of resulting in the rectificational separation process streams heat exchanger are maintained by means of one or more different cooling media at temperature levels substantially the temperature levels during normal operation of the separation column (s) and correspond to the heat exchanger.
- a temperature level is to be understood that differs by no more than 20 K from the temperature level prevailing during normal operation and which ensures that none Disadvantages associated with the heating of the separation column (s) and / or the heat exchanger occur.
- the cooling medium is a hydrocarbon-rich fraction, preferably liquefied natural gas (LNG), boil-off gas, liquid and / or gaseous nitrogen is used.
- the NRU is now kept cold during an interruption of the supply of the feed fraction by the separation column (s), lines, pumps, heat exchangers, etc. of the NRU are cooled during the interruption period by supplying one or more different cooling media.
- Embodiments discussed only the differences from the procedure shown in the figure 1.
- the double separation column T1 / T2 is closed during the interruption of the feed fraction - the valves c and d in the line 1 or 1 'are closed during this period - via the lines 6 to 6 a cooling medium, preferably liquefied natural gas (LNG), suitable for the cooling of the columns T1 and T2 is fed in.
- a cooling medium preferably liquefied natural gas (LNG)
- LNG liquefied natural gas
- the supply of liquefied natural gas via the lines 6 and 6 'in the low-pressure column T2 is of particular importance, since in the case of heating of this column, the liquid evaporated in it to the atmosphere or in a torch system must be delivered. If it comes to a warming of the high-pressure column T1 and an associated evaporation of the liquid contained in it, the resulting gas would condense again due to the capacitor E3. However, this recondensation only works as long as there is a sufficiently large and cold amount of liquid in the bottom of the separation column T2. Nevertheless, in the case of a longer interruption also a supply of cooling medium via the lines 6 "and 6 '" in the column T1 is required, but at least useful. In particular, leaks at the valves a and b lead to prolonged downtime to fluid losses in the high-pressure column T1.
- a cooling medium is passed through the heat exchanger E1.
- This cooling medium must have a temperature which is similar to the temperature which the feed fraction fed to the heat exchanger E1 in the normal operation via the line 1 has.
- gaseous nitrogen is advantageously used. After passing through the heat exchanger E1, the nitrogen is released via line T to the atmosphere.
- a cooling medium is passed through the heat exchangers E 2 and E 1 via the line sections 8, 4 1 and 4 "This cooling medium, which is advantageously cold, gaseous nitrogen, has a temperature which is similar to the temperature of the The nitrogen-rich stream withdrawn in normal operation via line 4.
- the supply of the cooling medium (s) to the heat exchangers E1 and E2 must in practice be designed in such a way that the lines between the heat exchangers and the columns are cooled as completely as possible.
- the temperature profiles of the columns T1 / T2 and the heat exchanger E1 / E2 can be maintained during the interruption period, so that after completion of the
- FIG. 4 A further advantageous embodiment of the method according to the invention is shown in FIG.
- warm, gaseous nitrogen and liquefied natural gas are mixed via the lines 10 and 11 and fed via line 12 to the line section 4 and led through the line sections 4 1 and 4 "through the heat exchangers E 2 and E 1.
- the supply of a further cooling medium via line 9 Optionally, it can be implemented as described above
- the embodiment of the method according to the invention shown in FIG. 4 has the advantage that the often expensive provision of cold nitrogen can be dispensed with.
- Separation process or the NRU in a LNG or NGL plant can also be used accumulating boil-off gas as a cooling medium.
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- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Separation By Low-Temperature Treatments (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
RU2011137412/06A RU2524312C2 (ru) | 2009-02-10 | 2010-02-02 | Способ удаления азота |
MX2011007887A MX2011007887A (es) | 2009-02-10 | 2010-02-02 | Metodo para separar nitrogeno. |
AU2010213189A AU2010213189B2 (en) | 2009-02-10 | 2010-02-02 | Method for removing nitrogen |
US13/148,484 US8435403B2 (en) | 2009-02-10 | 2010-02-02 | Process for removing nitrogen |
NO20111226A NO20111226A1 (no) | 2009-02-10 | 2011-09-09 | Fremgangsmate for utskillelse av nitrogen |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102009008229.8 | 2009-02-10 | ||
DE102009008229A DE102009008229A1 (de) | 2009-02-10 | 2009-02-10 | Verfahren zum Abtrennen von Stickstoff |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2010091805A2 true WO2010091805A2 (de) | 2010-08-19 |
WO2010091805A3 WO2010091805A3 (de) | 2013-04-18 |
Family
ID=42317491
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2010/000615 WO2010091805A2 (de) | 2009-02-10 | 2010-02-02 | Verfahren zum abtrennen von stickstoff |
Country Status (7)
Country | Link |
---|---|
US (1) | US8435403B2 (de) |
AU (1) | AU2010213189B2 (de) |
DE (1) | DE102009008229A1 (de) |
MX (1) | MX2011007887A (de) |
NO (1) | NO20111226A1 (de) |
RU (1) | RU2524312C2 (de) |
WO (1) | WO2010091805A2 (de) |
Families Citing this family (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102009036366A1 (de) | 2009-08-06 | 2011-02-10 | Linde Aktiengesellschaft | Verfahren zum Abtrennen von Stickstoff |
FR2971331B1 (fr) | 2011-02-09 | 2017-12-22 | L'air Liquide Sa Pour L'etude Et L'exploitation Des Procedes Georges Claude | Procede et appareil de separation cryogenique d'un debit riche en methane |
US9487458B2 (en) | 2014-02-28 | 2016-11-08 | Fluor Corporation | Configurations and methods for nitrogen rejection, LNG and NGL production from high nitrogen feed gases |
DE102015004120A1 (de) * | 2015-03-31 | 2016-10-06 | Linde Aktiengesellschaft | Verfahren zum Abtrennen von Stickstoff aus einer Kohlenwasserstoff-reichen Fraktion |
TWI603044B (zh) | 2015-07-10 | 2017-10-21 | 艾克頌美孚上游研究公司 | 使用液化天然氣製造液化氮氣之系統與方法 |
TWI606221B (zh) | 2015-07-15 | 2017-11-21 | 艾克頌美孚上游研究公司 | 一倂移除溫室氣體之液化天然氣的生產系統和方法 |
TWI608206B (zh) | 2015-07-15 | 2017-12-11 | 艾克頌美孚上游研究公司 | 藉由預冷卻天然氣供給流以增加效率的液化天然氣(lng)生產系統 |
KR102137939B1 (ko) * | 2015-12-14 | 2020-07-27 | 엑손모빌 업스트림 리서치 캄파니 | 액체 질소로 보강된, 팽창기-기반 lng 생산 방법 |
SG11201803521SA (en) | 2015-12-14 | 2018-06-28 | Exxonmobil Upstream Res Co | Method of natural gas liquefaction on lng carriers storing liquid nitrogen |
KR102137940B1 (ko) | 2015-12-14 | 2020-07-27 | 엑손모빌 업스트림 리서치 캄파니 | 액화 질소를 사용하여 액화 천연 가스로부터 질소를 분리하기 위한 방법 및 시스템 |
SG11201906786YA (en) | 2017-02-24 | 2019-09-27 | Exxonmobil Upstream Res Co | Method of purging a dual purpose lng/lin storage tank |
US11536510B2 (en) | 2018-06-07 | 2022-12-27 | Exxonmobil Upstream Research Company | Pretreatment and pre-cooling of natural gas by high pressure compression and expansion |
WO2020036711A1 (en) | 2018-08-14 | 2020-02-20 | Exxonmobil Upstream Research Company | Conserving mixed refrigerant in natural gas liquefaction facilities |
JP7179155B2 (ja) | 2018-08-22 | 2022-11-28 | エクソンモービル アップストリーム リサーチ カンパニー | 高圧エキスパンダプロセスのための一次ループ始動方法 |
JP7179157B2 (ja) | 2018-08-22 | 2022-11-28 | エクソンモービル アップストリーム リサーチ カンパニー | 高圧エキスパンダプロセスのための熱交換器構成及びそれを用いた天然ガス液化方法 |
CA3109918C (en) | 2018-08-22 | 2023-05-16 | Exxonmobil Upstream Research Company | Managing make-up gas composition variation for a high pressure expander process |
WO2020106397A1 (en) | 2018-11-20 | 2020-05-28 | Exxonmobil Upstream Research Company | Methods and apparatus for improving multi-plate scraped heat exchangers |
WO2020106394A1 (en) | 2018-11-20 | 2020-05-28 | Exxonmobil Upstream Research Company | Poly refrigerated integrated cycle operation using solid-tolerant heat exchangers |
WO2020159671A1 (en) | 2019-01-30 | 2020-08-06 | Exxonmobil Upstream Research Company | Methods for removal of moisture from lng refrigerant |
US11668524B2 (en) | 2019-01-30 | 2023-06-06 | Exxonmobil Upstream Research Company | Methods for removal of moisture from LNG refrigerant |
US11686528B2 (en) | 2019-04-23 | 2023-06-27 | Chart Energy & Chemicals, Inc. | Single column nitrogen rejection unit with side draw heat pump reflux system and method |
US11465093B2 (en) | 2019-08-19 | 2022-10-11 | Exxonmobil Upstream Research Company | Compliant composite heat exchangers |
US20210063083A1 (en) | 2019-08-29 | 2021-03-04 | Exxonmobil Upstream Research Company | Liquefaction of Production Gas |
WO2021055020A1 (en) | 2019-09-19 | 2021-03-25 | Exxonmobil Upstream Research Company | Pretreatment and pre-cooling of natural gas by high pressure compression and expansion |
US11815308B2 (en) | 2019-09-19 | 2023-11-14 | ExxonMobil Technology and Engineering Company | Pretreatment and pre-cooling of natural gas by high pressure compression and expansion |
US11083994B2 (en) | 2019-09-20 | 2021-08-10 | Exxonmobil Upstream Research Company | Removal of acid gases from a gas stream, with O2 enrichment for acid gas capture and sequestration |
KR20220062653A (ko) | 2019-09-24 | 2022-05-17 | 엑손모빌 업스트림 리서치 캄파니 | 선박의 이중 목적 극저온 탱크 또는 lng 및 액화 질소용 부유식 저장 유닛용 화물 스트리핑 기능 |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5125934A (en) * | 1990-09-28 | 1992-06-30 | The Boc Group, Inc. | Argon recovery from argon-oxygen-decarburization process waste gases |
US5220797A (en) * | 1990-09-28 | 1993-06-22 | The Boc Group, Inc. | Argon recovery from argon-oxygen-decarburization process waste gases |
US5233839A (en) * | 1991-03-13 | 1993-08-10 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Process for operating a heat exchanger |
FR2682964B1 (fr) * | 1991-10-23 | 1994-08-05 | Elf Aquitaine | Procede de deazotation d'un melange liquefie d'hydrocarbures consistant principalement en methane. |
DE4135302A1 (de) * | 1991-10-25 | 1993-04-29 | Linde Ag | Anlage zur tieftemperaturzerlegung von luft |
JP3373013B2 (ja) * | 1993-11-16 | 2003-02-04 | 日本エア・リキード株式会社 | 窒素ガス製造装置 |
DE19919932A1 (de) * | 1999-04-30 | 2000-11-02 | Linde Ag | Verfahren zum Gewinnen einer Reinmethanfraktion |
FR2825119B1 (fr) * | 2001-05-23 | 2003-07-25 | Air Liquide | Procede et installation d'alimentation d'une unite de separation d'air au moyen d'une turbine a gaz |
GB0116977D0 (en) * | 2001-07-11 | 2001-09-05 | Boc Group Plc | Nitrogen rejection method and apparatus |
GB0220791D0 (en) * | 2002-09-06 | 2002-10-16 | Boc Group Plc | Nitrogen rejection method and apparatus |
GB0226983D0 (en) * | 2002-11-19 | 2002-12-24 | Boc Group Plc | Nitrogen rejection method and apparatus |
RU2265778C1 (ru) * | 2004-04-30 | 2005-12-10 | Савинов Михаил Юрьевич | Способ очистки и разделения смеси ректификацией |
KR101188502B1 (ko) * | 2004-07-01 | 2012-10-08 | 바스프 에스이 | 프로판으로부터 아크롤레인, 아크릴산, 또는 이들의혼합물의 제조 방법 |
US7552599B2 (en) * | 2006-04-05 | 2009-06-30 | Air Products And Chemicals, Inc. | Air separation process utilizing refrigeration extracted from LNG for production of liquid oxygen |
DE102010020282A1 (de) * | 2010-05-12 | 2011-11-17 | Linde Aktiengesellschaft | Stickstoff-Abtrennung aus Erdgas |
-
2009
- 2009-02-10 DE DE102009008229A patent/DE102009008229A1/de not_active Withdrawn
-
2010
- 2010-02-02 MX MX2011007887A patent/MX2011007887A/es active IP Right Grant
- 2010-02-02 WO PCT/EP2010/000615 patent/WO2010091805A2/de active Application Filing
- 2010-02-02 RU RU2011137412/06A patent/RU2524312C2/ru active
- 2010-02-02 US US13/148,484 patent/US8435403B2/en active Active
- 2010-02-02 AU AU2010213189A patent/AU2010213189B2/en active Active
-
2011
- 2011-09-09 NO NO20111226A patent/NO20111226A1/no not_active Application Discontinuation
Non-Patent Citations (1)
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NO20111226A1 (no) | 2011-09-09 |
DE102009008229A1 (de) | 2010-08-12 |
RU2524312C2 (ru) | 2014-07-27 |
AU2010213189B2 (en) | 2016-01-14 |
MX2011007887A (es) | 2011-08-15 |
WO2010091805A3 (de) | 2013-04-18 |
RU2011137412A (ru) | 2013-03-20 |
US20120041248A1 (en) | 2012-02-16 |
AU2010213189A1 (en) | 2011-08-18 |
US8435403B2 (en) | 2013-05-07 |
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