WO2009035119A1 - 粉末冶金用鉄基粉末 - Google Patents
粉末冶金用鉄基粉末 Download PDFInfo
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- WO2009035119A1 WO2009035119A1 PCT/JP2008/066615 JP2008066615W WO2009035119A1 WO 2009035119 A1 WO2009035119 A1 WO 2009035119A1 JP 2008066615 W JP2008066615 W JP 2008066615W WO 2009035119 A1 WO2009035119 A1 WO 2009035119A1
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- powder
- iron
- binder
- fluidity
- metallurgy according
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Classifications
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C33/00—Making ferrous alloys
- C22C33/02—Making ferrous alloys by powder metallurgy
- C22C33/0207—Using a mixture of prealloyed powders or a master alloy
- C22C33/0228—Using a mixture of prealloyed powders or a master alloy comprising other non-metallic compounds or more than 5% of graphite
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/10—Metallic powder containing lubricating or binding agents; Metallic powder containing organic material
- B22F1/108—Mixtures obtained by warm mixing
Definitions
- the present invention relates to an iron-based powder suitable for use in powder metallurgy.
- Powder metallurgy technology can produce machine parts with complex shapes with extremely high dimensional accuracy, and can greatly reduce the manufacturing costs of these machine parts. Therefore, various machine parts manufactured by applying powder metallurgy technology are used in many fields. Furthermore, recently, there is an increasing demand for miniaturization or weight reduction of machine parts, and various powders for powder metallurgy for producing machine parts with small size, light weight and sufficient strength are being studied.
- Lubricant for example, zinc stearate, aluminum stearate, etc.
- the resulting mixed powder also called iron-based powder in a broad sense
- iron-based powder has a broad meaning.
- iron-based powders “narrow meaning), secondary powders, and lubricants have different properties (ie, shape, particle size, etc.), so the flowability of the mixed powder is not uniform. Therefore,
- Iron and iron powder (narrow meaning), secondary raw material powder, lubricant, etc. are locally unevenly distributed under the influence of vibration and dropping that occur during the transportation of the mixed powder to the storage hopper. To do. Such a bias due to the difference in fluidity cannot be completely prevented by the segregation prevention treatment.
- Patent Document 5 discloses an iron-based powder mainly composed of iron powder having a particle size in a predetermined range.
- iron powder that falls outside the specified range cannot be used, so not only the yield of iron powder is reduced, but also the iron-base powder is uniformly and sufficiently filled in the thin cavity such as the gear edge. It is difficult to make it.
- JP 2002-515542 A discloses that a small amount of inorganic particulate oxide having a particle diameter of less than 500 nm (nanometer) (eg, Si O 2 having a particle diameter of less than 40 nm is 0.005 to 2 mass).
- Patent Document 7 includes iron powder or iron-based metal powder, lubricant and Z or binder, and carbon black as a fluidity increasing agent.
- a powder metallurgy composition is disclosed in which the amount of the carbon black is 0.001 to 0.2% by weight. This technology is said not to deteriorate the properties of sintered parts.
- iron powder or alloy steel powder which is a material of the iron-based powder, atomizing I's iron powder ⁇ atomized iron powder) according to the method, where 0 is replaced ⁇ powder ⁇ reduced iron powder) or the like
- pure Although iron powder is sometimes called iron powder, iron powder is used in a broad sense, including alloy steel powder, in the above classification according to the manufacturing method.
- iron powder means iron powder in this broad sense.
- Alloy steel powder shall include partially alloyed steel powder and hybrid alloyed steel powder except for pre-alloys. Disclosure of the invention [Problems to be Solved by the Invention]
- An object of the present invention is to solve the above problems. In other words, it is excellent in fluidity, can be filled uniformly in a thin-walled cavity, and has a low ejection force of the compacted body. Furthermore, the sintered body is also used in the subsequent sintering. The object is to provide an iron-based powder for powder metallurgy that can maintain a sufficient strength of (sintered body).
- the present invention is as follows.
- Iron-base powder for powder metallurgy characterized by adhering flowability-improving particles containing 50 to 100% by mass of carbon black to the surface of iron powder particles via a binder .
- the iron powder here is iron powder in the above-mentioned broad sense including alloy copper powder.
- the binder may adhere at least a part of the auxiliary raw material powder (particularly the powder for alloy) to the iron powder.
- the binder is attached to a part of the surface of the iron powder particles, and the fluidity improving particles are attached to at least a part of the surface of the binder.
- the binder after the surface of the iron powder is coated with the binder, it is preferable to adhere the fluidity improving particles to the surface of the binder, and the binder coats the entire iron powder particles. Rather, it is preferable to coat a part.
- the coverage of the iron powder with the binder is more preferably 30% or more and 50% or less.
- the coverage in (2) and (3) above means the ratio of the area covered with the binder to the area of the iron powder particle surface.
- the coverage of the fluidity improving particles attached to the surface of the binder means the ratio of the area covered with the fluidity improving particles to the area of the particle surface covered with the binder.
- the penetration is preferably 0.05 to 1 mm.
- the binder includes zinc stearate, lithium stearate, calcium stearate, stearate monoamide and ethylene bis-stear mouth amide.
- the iron-based powder for powder metallurgy according to any one of (1) to (6) above, which is one or more of (ethylenbis (stearamide)).
- iron-based powder contains one or more selected from Cu, C, Ni and Mo as an alloy component Iron-based powder for powder metallurgy according to the above.
- the iron powder preferably contains one or more selected from Cu, C, Ni and to as an alloy component.
- the iron powder is one or more selected from atomized iron powder, reduced iron powder, and iron powder obtained by partially diffusing and adhering alloy components.
- the iron-base powder for powder metallurgy according to any one of the above.
- alloy component those listed in the invention of (8) are preferable.
- the second iron powder that has not been subjected to segregation prevention treatment after the first iron powder has been subjected to segregation prevention treatment.
- the second iron powder corresponds to “iron powder without binder”.
- the coverage of the iron powder with the above-mentioned binder is the average coverage including the iron powder without the binder.
- the fluidity-improving particles contain PMMA powder and Z or PE powder in addition to the carbon black, and the average particle size of the fluidity-improving particles is in the range of 5 to 500 nm.
- FIG. 1 is an explanatory view schematically showing a state in which a binder, graphite, and bonbon black adhere to iron powder and are partially covered.
- FIG. 2 is an explanatory view showing, in an enlarged manner, the coated portion in FIG.
- FIG. 3 is a perspective view schematically showing the main part of the filling tester.
- the iron powder and the alloy component are mixed while being heated together with the binder using a mixing device (a kind of segregation preventing treatment).
- the fluidity improving particles containing 50 to 100% by mass of carbon black are added after the segregation preventing treatment and mixed in a dry state by a mixing apparatus.
- various property improving agents such as a machinability improving agent may be added together with the alloy components, and heated and mixed together with the binder.
- Alloy components and property improvers are generally powders of about 1 to 20 m.
- Typical alloy components are graphite powder, Cu powder, Ni powder, and Cr powder, W powder, Mo powder, Co powder, etc. are often used.
- Typical examples of the machinability improver are Mn S powder and Ca F 2 powder, and phosphate powder and BN powder are also used.
- a lubricant having a melting point higher than the heating temperature may be added at the same time as the alloy component.
- a powder lubricant after the segregation preventing treatment to ensure moldability referred to as a free lubricant.
- a free lubricant can also be appropriately selected from known ones.
- Other property improvers include slidability improvers.
- a high-speed mixer which is a kind of mechanical stirring type mixing device is preferable from the viewpoint of stirring power.
- the mixing device should be selected appropriately according to the production amount of iron-based powder and the required fluidity.
- a predetermined amount of iron powder is charged into a high-speed mixer, and alloy components such as graphite powder and Cu powder and a binder are added thereto. After adding these raw materials, start heating and mixing.
- the rotational speed of a rotating impeller in a high-speed mixer varies depending on the size of the mixing tank and the shape of the rotating blade. Generally, the rotational speed at the tip of the rotating blade is about 1 to 10 mZs ec. It is preferable to set the degree.
- the free lubricant used here is a lubricant added in order to improve the pullability during molding.
- the free lubricant can be appropriately selected from known ones, but it is preferable to use metal lic soap, amide wax, polyamide, polyethylene, polyethylene oxide or the like.
- the particle size of the free lubricant is preferably about 1 to 150 ⁇ m.
- the flowability improving particles mainly composed of carbon black are added at the same time as the free lubricant is added. At this time, the binder is completely solidified, but the flowability improving particles are extremely fine (that is, the particle diameter is 5 to 500 nm), and therefore, van der Waalska adheres to the iron powder particles by electrostatic force. The fluidity improving particles will be described later.
- the iron-based powder of the present invention is produced by the above method.
- the binder may be appropriately selected from known ones, and any kind of binder that melts by heating or solidifies by heating can be used. Among them, those having lubricity after solidification are preferable. The reason is that this type reduces the frictional force between the powder particles, improves the fluidity of the powder, and promotes the rearrangement of the particles at the early stage of molding. Specifically, metal exploration, amide wax, polyamide, polyethylene, polyethylene oxide, etc. are used. In particular, zinc stearate, lithium stearate, calcium stearate, stearic acid monoamide, and ethylene bisstearamide are preferred. These binders may be used alone or in combination of two or more.
- the adhesion between the binder and the binder is greater than the adhesion between the iron powder and the iron powder and the adhesion of the iron powder and the binder. Therefore, when the entire surface of the iron powder is coated with a binder, its fluidity is significantly degraded. In consideration of fluidity, it is preferable that the binder is unevenly distributed on the surface of the iron powder. Therefore, in the present invention, it is preferable and necessary to attach the binder only to a part of the surface of the iron powder.
- the suitable coverage of the surface of the iron powder with the binder is preferably 50% or less, more preferably 10% or more and 50% or less, although it varies depending on the addition rate of the binder and graphite.
- the coverage exceeds 50%, the adhesion between the iron powder particles increases and the fluidity deteriorates.
- the graphite powder or the like may not be sufficiently adhered to the surface of the iron powder, although it varies depending on the addition rate of graphite and the like. In this case, the fluidity deteriorates by increasing the number of fine particles.
- the coverage is more preferably 30% or more and 50% or less.
- the control of these coverages can be easily adjusted by the amount of binder added. It can also be adjusted by controlling mixing conditions such as mixing temperature and stirring speed.
- the binder is preferably added in an amount within the range of about 0.05 to 0.8 parts by mass with respect to 100 parts by mass of iron powder according to the desired coverage.
- the coverage with the binder is expressed by the ratio (%) of the total area of the part coated with the binder to the total area of the iron powder particle surface within the observation range. That is, for example, when one iron powder particle using graphite as an alloy element and carbon black particles as a fluidity improving particle is observed by SEM, the iron powder particle 1 as shown in FIG.
- the coverage of the iron powder particles 1 is the area ratio (%) of the part 2.
- the present inventors have found that the difference between the iron powder and the binder becomes very clear by a shape-enhanced image with an acceleration voltage of 5 kV or less, more preferably 3 kV or less. Heading.
- the acceleration voltage for determining the ratio of the binder adhering to the iron powder surface must be 0.1 to 5 kV, and more preferably in the range of 1 to 3 kV.
- a clear contrast is obtained to distinguish between powder and binder.
- the detector used at this time may be a secondary electron detector that obtains a shape-enhanced image or an Inlens detector that obtains a substance-enhanced image, but it is more preferable to use a secondary electron detector.
- Images taken under these optimized measurement conditions are captured as digital data on a personal computer. After binarizing this using image analysis software, the area ratio (%) of the binder adhering to the iron powder surface is obtained, and this is taken as the coverage of the binder adhering to the iron powder surface. In addition, in the SEM observation when calculating the above coverage, it is preferable to observe about 10 fields of view at about 300 times and obtain the average value.
- the binder used has a penetration (hardness) I of 0.05 or more and 2 or less, preferably 0.05 or more and 1 or less.
- the penetration is a method of measuring the hardness of the wax paste and is shown in JIS K-2207, and is usually measured at a room temperature of 25 ° C.
- heat treatment equivalent to the segregation prevention treatment is necessary for the binder alone.
- measure as bulk (pellet) is necessary for the binder alone.
- the penetration of the binder is 2 mm or less, preferably 1 or less.
- the above-mentioned binders also act as lubricants during molding, so if the lubricant has a higher hardness than necessary, that is, if the penetration is too low, the lubricity is reduced.
- the penetration of the binder is preferably 0.05 or more. In order to obtain particularly excellent lubricity, it is preferable that the penetration is 0.3 mm or more.
- the alloy component with the binder there are a method of attaching by melting the binder by heating, and a method of attaching by dissolving the binder in a solvent and mixing it, and then evaporating the solvent.
- the former method is preferable in order to make the binder unevenly distributed on the surface of the iron powder.
- the coverage with binder should be the average coverage including iron powder without binder.
- the iron-based powder may contain Cu, C, Ni, Mo, etc. as alloy components. Methods for adding these alloy components to the iron-based powder include making the iron powder an alloy, making the particles different from the iron powder, and attaching the alloy component to the iron powder.
- the iron powder may be atomized iron powder, reduced iron powder, iron powder with alloy components attached, or the like. Details are described below.
- iron powders there are various types of iron powders depending on the production method, but hydrogenated iron powder and Z or reduced iron powder may be used in consideration of the moldability, characteristics of the molded body, and characteristics of the sintered body. I like it. These iron powders have irregularities on the particle surface, and when compacted, they become entangled, and the strength of the molded body and sintered body is increased.
- the iron powder is within the scope of the above definition, that is, pure iron powder or alloy copper powder (including partially alloyed steel powder, iron, hybrid alloyed steel powder), and is not particularly limited. Pure iron powder is iron: 98% or more and the balance is impurities.
- Alloy steel powder contains a total of about 10% by mass or less of alloy components such as Mn, Cu, Mo, Cr, W, Ni, P, S, V, and Si. Also, prealloying is to add alloy composition to molten steel in advance, and pre-alloying to pre-alloying and pre-alloying by combining particles containing alloy components to the iron powder surface by diffusion reaction. Doing both is called hybrid alloying.
- the particle size of iron powder is generally in the range of 60 to 100 / i.m in terms of average particle size (value based on the sieve distribution method stipulated in Japan Powder Metallurgy Industry Association Standard J P MA P02—1992).
- the binder tends to remain locally on the irregularities.
- a wettability improving process for improving the wettability between the iron powder surface and the binder. In the present invention, it is not desirable to excessively eliminate the uneven distribution of the binder, but it does not prohibit the application of wettability treatment to adjust the coverage and distribution of the binder.
- wetting improvers include silane coupling agents, acetylene glycol series Surface active agents, polyhydric alcohol surfactants, etc.
- the fluidity improving particles used in the present invention are fine powders having an effect of improving the fluidity of iron powder, and contain 50 to 100% by mass of carbon black.
- Carbon black is used in toners and coatings, and its particle size is preferably in the range of 5 to 100 nm. Since carbon black is mainly composed of carbon, there is no concern that it will remain as a harmful impurity after sintering. Moreover, since it is an amorphous material, diffusion is faster than that of graphite powder, and it is expected that it can be easily dissolved even at low temperature and short time sintering.
- the coverage of the fluidity improving particles adhering to the surface of the binder is preferably 50% or more. By setting the coverage to 50% or more, the adhesion force between the binder and the binder can be reliably reduced.
- the upper limit of the coverage is not particularly limited, and even if it is 100%, there is no problem. However, from the viewpoint of avoiding the concern of increased output during molding, limit it to 90% or less.
- the coverage of the fluidity-improving particles is the total area where the fluidity-improving particles are present on the surface with respect to the total area of the area coated with the binder, which is within the observation range when observed with SEM. It shall be expressed in area ratio (%). That is, as shown in Fig. 2, the part 2 previously coated with the binder adhering to the surface of the iron powder (same as Fig. 1) has a fluidity improving particle (carbon in this example). It has a part where black 3) exists.
- the coverage of the fluidity improving particles with respect to the binder-coated portion 2 is the ratio (%) of the area of the portion 3 to the portion 2. For simplicity, graphite is not shown in FIG.
- the present inventors set the acceleration voltage to 0.1 to 2 kV when determining the ratio of carbon black covering the surface of the binder adhering to the iron powder surface. And that the contrast for distinguishing iron powder, binder, and bonbon black is most clearly obtained, particularly in the range of 0.1 to 1 kV.
- the detector used at this time is preferably an Inlens detector capable of obtaining a substance-enhanced image rather than a secondary electron detector capable of obtaining a shape-enhanced image.
- Images taken under these optimized measurement conditions are captured as digital data on a personal computer. After this value was reduced using image analysis software, the area ratio (%) of carbon black covering the surface of the binder was determined, and this was calculated as the coverage ratio of carbon black covering the surface of the binder. And In SEM observation when calculating the above coverage, about 3000 times It is preferable to observe about 20 fields of view and find the average value.
- the coverage of the entire fluidity-improving particles may be estimated based on the carbon black coverage obtained by the above observation and the ratio of carbon black in the fluidity-improving particles.
- the components added to the fluidity improving particles are:
- PMMA polymethylmethacrylate
- PE polyethylene
- metal oxides inhibit the bonding between iron powder particles during sintering, leading to a decrease in strength of the sintered body. Therefore, the amount of metal oxide (for example, A1 2 0 3 -MgO 2 Si O z ⁇ H 2 0, Si0 2 , Ti0 2 , Fe 2 0 3, etc.) should be reduced as much as possible for fluidity improving particles. Is preferred. Moreover, since organic substances (for example, PMMA, PE, etc.) are expensive, it is preferable to reduce the amount of organic substances added as much as possible. For this reason, the carbon black content should be in the range of 50-100% by mass.
- the average particle size of these fluidity-improving particles is less than 5 nm, the iron powder surface irregularities or the iron powder surface may be buried in the lubricant. In addition, these fine particles are present in an aggregated state. However, if the fine particles are too weak, the aggregates adhere to the iron powder surface, which is not preferable. In general, the production cost of fine particles increases as the finer. On the other hand, if it exceeds 500 nm, it becomes the same as the curvature of the irregularities present on the iron powder surface from the beginning, and the meaning of adhering these particles is lost. In particular, the fluidity improving particles (A) are present in the sintered body as they are without being decomposed during the sintering.
- the average particle size of the fluidity improving particles is preferably in the range of 5 to 500 nm. More preferably, it is 100 nm or less.
- the particle size of the fluidity-improving particles is the value obtained by arithmetic mean by observation with an electron microscope for carbon black, the value obtained by measuring the particle shape as a sphere by BET specific surface area measurement for the above (A), and For (B) above, the value measured by the microtrack method using ethanol as the dispersion medium shall be used.
- the addition amount of the fluidity improving particles is preferably in the range of 0.01 to 3 parts by mass with respect to 100 parts by mass of the iron powder. More preferably, it is 0.05 parts by mass or more. More preferably, it is 0.2 parts by mass or less.
- the effect of adding fluidity-improving particles is to provide fine irregularities on the iron powder surface, reducing the contact area between the particles and lowering the adhesion. In addition, it has the effect of preventing the bonding between the binders on the iron powder surface.
- iron powder without a binder is considered to have excellent fluidity.
- Another form of the present invention is an iron-based powder containing iron powder without a binder. This is based on the above viewpoint, and less than 50% by mass of iron powder is iron powder without a binder. If the iron powder with no binder on the surface is 50% by mass or more, the punching power becomes high during molding, and there is a possibility that mold squeezing may occur or the molded body may be damaged. . More preferably, the iron powder without binder is 20% by mass or less. Further, it is preferable to add 5% by mass or more from the viewpoint of obtaining a remarkable effect, and more preferably 10% by mass or more.
- Such iron-based powder can be obtained by mixing iron powder that has not been subjected to segregation treatment with iron powder that has undergone segregation treatment.
- the range of the average particle size of the iron powder suitable for addition is the same as that in the case of the general iron powder.
- fluidity-improving particles can be mixed with iron powder without a binder first, and then mixed with iron powder after segregation prevention treatment to further improve fluidity. The reason for this has not been clarified, but due to the anti-agglomeration effect that bare iron powder crushes aggregates of fluidity improving powder, One possible reason is that the flowability improving particles are spread more on the surface of the binder. Although it is expected that the same effect can be obtained by replacing the iron powder without a binder with other raw material powder without a binder, iron powder is most preferable.
- the content of the composition other than iron is 10 parts by mass or less with respect to 100 parts by mass of iron powder. It is preferable that When applying the iron-based powder of the present invention to powder metallurgy, before filling the mold and compression molding, add additional raw material powders (alloy powder, machinability improving powder, etc.) and mix and fire. It is free to adjust the composition and the like of the bonded body.
- the coverage of the binder surface by the fluidity improving particles was obtained by (the coverage ratio of the binder surface by carbon black) / (ratio of the number of carbon black particles occupied by the fluidity improving particles).
- the particle number ratio was obtained by correcting the weight ratio by the number of particles per weight estimated from the average particle diameter and the specific gravity of the material.
- the substance represented by Al 2 0 3 'MgO 2 SiO z -x H 2 0, Si 0 2 is called magnesium aluminate silicate, and X is any number that indicates the stability of the composite compound. Usually, it is said to be about 1-2.
- Iron-based powders were obtained in the same manner as above except that the binders and free lubricants were those described in Table 1.
- the filling properties of the iron-based powder thus obtained were evaluated using a filling tester shown in FIG. The evaluation was performed by filling iron-based powder in a cavity 6 provided in the container 7 having a length of 20 mm, a depth of 40 concealment, and a width of 0.5 mm.
- Powder box 4 filled with iron-based powder 5 moved in the direction of the arrow in Fig. 3 (moving direction 8), the moving speed was 200mm / sec, and the holding time of powder box 4 on the cavity was 0.5 sec.
- filling rate Filling density after filling (filling weight cavity volume) as a percentage of apparent density before filling is designated as filling rate (filling rate 100% means complete filling), and the same test is repeated 10 times. Filling variation is expressed by standard deviation of filling rate.
- the iron-based powders of these inventive examples were filled in a mold and pressed (molding pressure 686 MPa) to form a 5 mm-thick tensile test piece and a 10-thick Charpy test piece, and further fired in an RX gas atmosphere. Sintering (sintering temperature 1130, sintering time 20 minutes) was performed to prepare tensile test pieces and Charpy test pieces. Table 3 shows the results of the tensile test and Charpy test. Invention Examples 1 to 9 and 12 all showed good filling variation. In addition, the strength and toughness of the sintered body was good, showing almost the same value as that of the powder to which no fluidity improving particles were added (Comparative Example 1 described later).
- the addition amount of the fluidity improving particles is as low as 0.01%, and the coverage of the binder surface by the fluidity improving particles obtained under the above production conditions is too small. Greater than the invention example.
- Inventive Examples 17 and 18 have a binder coverage of 50. This is an example that exceeds / ⁇ . In these cases, the filling variation is larger than in the other invention examples.
- Invention Examples 19 and 20 are examples in which the penetration of the binder is outside the optimum range (0.05 to 1 mm) or the preferred range (0.05 to 2 mm). In these cases, the filling variation is larger than that of the other invention examples.
- Inventive Examples 10 to 15 (excluding 12) all showed good filling properties, but the coverage with the binder was 10% or more, which was superior in filling properties.
- the properties of the obtained sintered body were good, but the properties of the sintered body were excellent when the coverage with the binder was 30% or more.
- the green density of the molded body was 6.9 to 7.lMg / m 3 at the time of 686 MPa molding, and the output power at that time was 10 to 15 MPa, both of which were in the range where there was no problem. It was.
- Comparative examples 1 in Tables 1 to 3 are examples. In Comparative Example 1, the properties of the sintered body are good, but the fillability is extremely poor.
- an iron-based powder was obtained by the same production method as in Invention Examples 1 to 9 except that Si 2 O containing 25% by mass of carbon black was added and mixed as fluidity improving particles.
- the comparative example 2 in Tables 1 to 3 is an example.
- Table 4 shows the physical properties of the fluidity improving particles used in combination with carbon black. In Comparative Example 2, the filling variation is good, but the strength of the sintered body is significantly reduced.
- Comparative Example 1 had large filling variations, and Comparative Example 2 had low tensile strength and Charpy impact value. '.
- the types of iron powder reduced iron powder, alloy copper powder, etc.
- auxiliary material powder alloy powder, machinability improving powder, etc.
- lubricants other than those listed in Table 1 (eg Ni powder, In the case of using MnS powder, CaF 2 powder, lithium stearate, etc.), the same tendency as in Example 1 was observed, and the effect of the present invention was confirmed.
- an iron-based powder having excellent fluidity using iron powder as a raw material and suitable for use in powder metallurgy can be produced.
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Abstract
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Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
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EP08830583.4A EP2210691B2 (en) | 2007-09-14 | 2008-09-09 | Iron-based powder for powder metallurgy |
CA2699033A CA2699033C (en) | 2007-09-14 | 2008-09-09 | Iron-based powder for powder metallurgy |
US12/733,560 US7867314B2 (en) | 2007-09-14 | 2008-09-09 | Iron-based powder for powder metallurgy |
CN2008801072245A CN101801566B (zh) | 2007-09-14 | 2008-09-09 | 粉末冶金用铁基粉末 |
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JP2007239570 | 2007-09-14 | ||
JP2007-239570 | 2007-09-14 | ||
JP2008124277 | 2008-05-12 | ||
JP2008-124277 | 2008-05-12 | ||
JP2008198306 | 2008-07-31 | ||
JP2008-198306 | 2008-07-31 |
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WO2009035119A1 true WO2009035119A1 (ja) | 2009-03-19 |
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US (1) | US7867314B2 (ja) |
EP (1) | EP2210691B2 (ja) |
JP (2) | JP4379535B1 (ja) |
CN (1) | CN101801566B (ja) |
CA (1) | CA2699033C (ja) |
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Cited By (3)
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JP2010245460A (ja) * | 2009-04-09 | 2010-10-28 | Tamura Seisakusho Co Ltd | 圧粉磁心及びその製造方法 |
WO2014103287A1 (ja) * | 2012-12-28 | 2014-07-03 | Jfeスチール株式会社 | 粉末冶金用鉄基粉末 |
WO2020217618A1 (ja) * | 2019-04-23 | 2020-10-29 | Jfeスチール株式会社 | 粉末冶金用混合粉 |
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Publication number | Priority date | Publication date | Assignee | Title |
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US8747516B2 (en) * | 2007-12-13 | 2014-06-10 | Jfe Steel Corporation | Iron-based powder for powder metallurgy |
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CN101801566A (zh) | 2010-08-11 |
EP2210691A1 (en) | 2010-07-28 |
JP4379535B1 (ja) | 2009-12-09 |
CN101801566B (zh) | 2012-02-15 |
JP2010053440A (ja) | 2010-03-11 |
JP2010053437A (ja) | 2010-03-11 |
US7867314B2 (en) | 2011-01-11 |
EP2210691B1 (en) | 2015-08-05 |
CA2699033C (en) | 2013-05-28 |
US20100224025A1 (en) | 2010-09-09 |
CA2699033A1 (en) | 2009-03-19 |
EP2210691B2 (en) | 2018-04-11 |
EP2210691A4 (en) | 2011-05-11 |
JP5381262B2 (ja) | 2014-01-08 |
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