WO2009028192A1 - 吸着剤 - Google Patents

吸着剤 Download PDF

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Publication number
WO2009028192A1
WO2009028192A1 PCT/JP2008/002342 JP2008002342W WO2009028192A1 WO 2009028192 A1 WO2009028192 A1 WO 2009028192A1 JP 2008002342 W JP2008002342 W JP 2008002342W WO 2009028192 A1 WO2009028192 A1 WO 2009028192A1
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WO
WIPO (PCT)
Prior art keywords
ion
water
adsorbent agent
iron oxide
organic polymer
Prior art date
Application number
PCT/JP2008/002342
Other languages
English (en)
French (fr)
Inventor
Toshiki Matsui
Shin Bito
Toshiyuki Hakata
Original Assignee
Toda Kogyo Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toda Kogyo Corporation filed Critical Toda Kogyo Corporation
Publication of WO2009028192A1 publication Critical patent/WO2009028192A1/ja

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/288—Treatment of water, waste water, or sewage by sorption using composite sorbents, e.g. coated, impregnated, multi-layered
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0225—Compounds of Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt
    • B01J20/0229—Compounds of Fe
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/26—Synthetic macromolecular compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28026—Particles within, immobilised, dispersed, entrapped in or on a matrix, e.g. a resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/46—Materials comprising a mixture of inorganic and organic materials
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/285—Treatment of water, waste water, or sewage by sorption using synthetic organic sorbents
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C02F2101/103—Arsenic compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C02F2101/105—Phosphorus compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C02F2101/12—Halogens or halogen-containing compounds
    • C02F2101/14—Fluorine or fluorine-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C02F2101/20—Heavy metals or heavy metal compounds
    • C02F2101/22—Chromium or chromium compounds, e.g. chromates
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00—Specific treatment goals
    • C02F2303/16—Regeneration of sorbents, filters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Engineering & Computer Science (AREA)
  • Hydrology & Water Resources (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Water Treatment By Sorption (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

　本発明は、溶液中のフッ素やリン、ヒ素、セレン、クロムを含有するイオンを吸着除去するものであり、水中での形状維持性が高いため、カラムなどに充填して使用でき、さらに、脱離・再生によって繰り返し使用できる吸着剤を提供する。 　Ｚｒ、Ｃｅ、Ｈｆ、Ｌａ、Ｙから選ばれる１種以上を含有する含水酸化鉄粒子と、エチレンビニルアルコール共重合樹脂又はポリビニルアセタール樹脂の一種以上から選ばれる有機高分子樹脂との複合造粒物からなる吸着剤であって、該吸着剤の平均粒径が０．３～３．０ｍｍであって、細孔容積が０．１～０．５ｃｍ３／ｇであって、圧縮強度が３～２０Ｎであり、前記含水酸化鉄粒子の平均一次粒子径が０．０１～０．５μｍであってＺｒ、Ｃｅ、Ｈｆ、Ｌａ、Ｙの含有量が３．０～３０ｗｔ％であり、前記有機高分子樹脂の含有量が３．０～１０ｗｔ％である水中の有害イオンを吸着する吸着剤である。
PCT/JP2008/002342 2007-08-29 2008-08-28 吸着剤 WO2009028192A1 (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-223181 2007-08-29
JP2007223181 2007-08-29

Publications (1)

Publication Number Publication Date
WO2009028192A1 true WO2009028192A1 (ja) 2009-03-05

Family

ID=40386931

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/002342 WO2009028192A1 (ja) 2007-08-29 2008-08-28 吸着剤

Country Status (2)

Country Link
JP (1) JP5482979B2 (ja)
WO (1) WO2009028192A1 (ja)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102745764A (zh) * 2012-07-20 2012-10-24 陕西科技大学 一种利用铝钛复合鞣制废弃物去除铬鞣废水中三价铬的方法
CN104084177A (zh) * 2014-07-15 2014-10-08 京东方科技集团股份有限公司 一种磁性壳聚糖纳米纤维铜离子吸附剂及其制备方法、用途
CN106492753A (zh) * 2016-02-16 2017-03-15 朱小平 一种砷吸附材料的制备方法
WO2018129772A1 (zh) * 2017-01-10 2018-07-19 苏州大学张家港工业技术研究院 一种处理含硒酸根废水的方法
CN111909502A (zh) * 2020-06-30 2020-11-10 会通新材料股份有限公司 一种PPO-sPS组合物及其制备方法
CN113149356A (zh) * 2021-04-25 2021-07-23 华设设计集团环境科技有限公司 一种高效除磷复合填料及其制备方法
CN113694899A (zh) * 2021-09-02 2021-11-26 南京大学 一种镧锆双金属树脂基纳米复合材料及其制备方法与应用
CN114906956A (zh) * 2022-04-27 2022-08-16 江苏启创环境科技股份有限公司 微电解耦合纳米复合材料吸附的有机磷废水深度除磷方法

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5637708B2 (ja) * 2010-03-19 2014-12-10 戸田工業株式会社 フッ素吸着剤によるフッ素イオン含有排水の処理方法
JP5502678B2 (ja) * 2010-09-27 2014-05-28 株式会社クラレ 組成物、金属イオン吸着材、及び金属回収方法
JP5250140B1 (ja) * 2011-07-12 2013-07-31 三菱製紙株式会社 磁性吸着剤粒子
JP5864284B2 (ja) * 2012-01-26 2016-02-17 太平洋セメント株式会社 塩素バイパスダスト水洗排水からのセレン除去方法
JP5957276B2 (ja) * 2012-04-26 2016-07-27 大日精化工業株式会社 ポリビニルブチラール樹脂及びフェロシアン化金属化合物を含有するセシウム除去材及びセシウム除去材用ペレットの製造方法
US20150315054A1 (en) * 2012-11-30 2015-11-05 Organo Corporation System for treating coal gasification wastewater, and method for treating coal gasification wastewater
JP6377130B2 (ja) * 2014-03-03 2018-08-22 株式会社マエダマテリアル 水処理用吸着剤、その製造方法、水処理装置、水処理装置用カートリッジ及び水処理方法
EP4183761A1 (en) * 2021-11-18 2023-05-24 Kuraray Europe GmbH Use of compacted polyvinyl acetals as binder in ceramic green sheets

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10296077A (ja) * 1996-08-14 1998-11-10 Takeda Chem Ind Ltd イオン吸着剤
JP2006305551A (ja) * 2005-03-29 2006-11-09 Toda Kogyo Corp 吸着剤
JP2007014826A (ja) * 2005-06-10 2007-01-25 Asahi Kasei Chemicals Corp 多孔性成形体およびその製造方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4810792B2 (ja) * 2004-01-26 2011-11-09 栗田工業株式会社 吸着材及び水処理方法
JP5062976B2 (ja) * 2005-06-15 2012-10-31 旭化成ケミカルズ株式会社 排水処理装置および排水処理方法
JP4854999B2 (ja) * 2005-07-20 2012-01-18 株式会社日本海水 フッ素吸着剤及びその製法
JP4609660B2 (ja) * 2006-01-27 2011-01-12 戸田工業株式会社 吸着剤

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10296077A (ja) * 1996-08-14 1998-11-10 Takeda Chem Ind Ltd イオン吸着剤
JP2006305551A (ja) * 2005-03-29 2006-11-09 Toda Kogyo Corp 吸着剤
JP2007014826A (ja) * 2005-06-10 2007-01-25 Asahi Kasei Chemicals Corp 多孔性成形体およびその製造方法

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102745764A (zh) * 2012-07-20 2012-10-24 陕西科技大学 一种利用铝钛复合鞣制废弃物去除铬鞣废水中三价铬的方法
CN104084177A (zh) * 2014-07-15 2014-10-08 京东方科技集团股份有限公司 一种磁性壳聚糖纳米纤维铜离子吸附剂及其制备方法、用途
CN104084177B (zh) * 2014-07-15 2017-02-01 京东方科技集团股份有限公司 一种磁性壳聚糖纳米纤维铜离子吸附剂及其制备方法、用途
CN106492753A (zh) * 2016-02-16 2017-03-15 朱小平 一种砷吸附材料的制备方法
WO2018129772A1 (zh) * 2017-01-10 2018-07-19 苏州大学张家港工业技术研究院 一种处理含硒酸根废水的方法
CN111909502A (zh) * 2020-06-30 2020-11-10 会通新材料股份有限公司 一种PPO-sPS组合物及其制备方法
CN111909502B (zh) * 2020-06-30 2022-05-17 会通新材料股份有限公司 一种PPO-sPS组合物及其制备方法
CN113149356A (zh) * 2021-04-25 2021-07-23 华设设计集团环境科技有限公司 一种高效除磷复合填料及其制备方法
CN113694899A (zh) * 2021-09-02 2021-11-26 南京大学 一种镧锆双金属树脂基纳米复合材料及其制备方法与应用
CN113694899B (zh) * 2021-09-02 2022-07-12 南京大学 一种镧锆双金属树脂基纳米复合材料及其制备方法与应用
CN114906956A (zh) * 2022-04-27 2022-08-16 江苏启创环境科技股份有限公司 微电解耦合纳米复合材料吸附的有机磷废水深度除磷方法
CN114906956B (zh) * 2022-04-27 2023-06-20 江苏启创环境科技股份有限公司 微电解耦合纳米复合材料吸附的有机磷废水深度除磷方法

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Publication number Publication date
JP2009072773A (ja) 2009-04-09
JP5482979B2 (ja) 2014-05-07

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