WO2008133112A1 - リチウム二次電池用非水電解液及びそれを用いたリチウム二次電池 - Google Patents
リチウム二次電池用非水電解液及びそれを用いたリチウム二次電池 Download PDFInfo
- Publication number
- WO2008133112A1 WO2008133112A1 PCT/JP2008/057350 JP2008057350W WO2008133112A1 WO 2008133112 A1 WO2008133112 A1 WO 2008133112A1 JP 2008057350 W JP2008057350 W JP 2008057350W WO 2008133112 A1 WO2008133112 A1 WO 2008133112A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- electrolyte solution
- lithium secondary
- secondary battery
- nonaqueous electrolyte
- nonaqueous
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C317/00—Sulfones; Sulfoxides
- C07C317/02—Sulfones; Sulfoxides having sulfone or sulfoxide groups bound to acyclic carbon atoms
- C07C317/08—Sulfones; Sulfoxides having sulfone or sulfoxide groups bound to acyclic carbon atoms of an acyclic unsaturated carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C317/00—Sulfones; Sulfoxides
- C07C317/16—Sulfones; Sulfoxides having sulfone or sulfoxide groups and singly-bound oxygen atoms bound to the same carbon skeleton
- C07C317/18—Sulfones; Sulfoxides having sulfone or sulfoxide groups and singly-bound oxygen atoms bound to the same carbon skeleton with sulfone or sulfoxide groups bound to acyclic carbon atoms of the carbon skeleton
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0567—Liquid materials characterised by the additives
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0569—Liquid materials characterised by the solvents
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
- H01M10/4235—Safety or regulating additives or arrangements in electrodes, separators or electrolyte
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/60—Other road transportation technologies with climate change mitigation effect
- Y02T10/70—Energy storage systems for electromobility, e.g. batteries
Abstract
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP08740436A EP2138481A4 (en) | 2007-04-20 | 2008-04-15 | NONAQUEOUS ELECTROLYTE SOLUTION FOR LITHIUM SECONDARY BATTERY AND LITHIUM SECONDARY BATTERY USING THE SAME |
JP2009511810A JP5428855B2 (ja) | 2007-04-20 | 2008-04-15 | リチウム二次電池用非水電解液及びそれを用いたリチウム二次電池 |
US12/596,300 US8404390B2 (en) | 2007-04-20 | 2008-04-15 | Nonaqueous electrolyte solution for lithium secondary battery and lithium secondary battery using the same |
CN200880012245.9A CN101657416B (zh) | 2007-04-20 | 2008-04-15 | 锂二次电池用非水电解液及使用其的锂二次电池 |
KR1020097021324A KR101533121B1 (ko) | 2007-04-20 | 2008-04-15 | 리튬 이차전지용 비수 전해액 및 그것을 이용한 리튬 이차전지 |
Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2007-112400 | 2007-04-20 | ||
JP2007112400 | 2007-04-20 | ||
JP2007-277364 | 2007-10-25 | ||
JP2007277364 | 2007-10-25 | ||
JP2007-338405 | 2007-12-28 | ||
JP2007338405 | 2007-12-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2008133112A1 true WO2008133112A1 (ja) | 2008-11-06 |
Family
ID=39925570
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2008/057350 WO2008133112A1 (ja) | 2007-04-20 | 2008-04-15 | リチウム二次電池用非水電解液及びそれを用いたリチウム二次電池 |
Country Status (6)
Country | Link |
---|---|
US (1) | US8404390B2 (ja) |
EP (1) | EP2138481A4 (ja) |
JP (2) | JP5428855B2 (ja) |
KR (1) | KR101533121B1 (ja) |
CN (2) | CN102856587B (ja) |
WO (1) | WO2008133112A1 (ja) |
Cited By (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010192165A (ja) * | 2009-02-16 | 2010-09-02 | Sanyo Electric Co Ltd | 非水電解質二次電池 |
CN101924244A (zh) * | 2009-06-11 | 2010-12-22 | 索尼公司 | 电池 |
JPWO2012011586A1 (ja) * | 2010-07-23 | 2013-09-09 | 宇部興産株式会社 | 非水電解液及びそれを用いた電気化学素子 |
WO2013187276A1 (ja) * | 2012-06-11 | 2013-12-19 | 日本電気株式会社 | 二次電池 |
WO2014080871A1 (ja) * | 2012-11-20 | 2014-05-30 | 日本電気株式会社 | リチウムイオン二次電池 |
WO2014080870A1 (ja) * | 2012-11-20 | 2014-05-30 | 日本電気株式会社 | リチウムイオン二次電池 |
WO2015080102A1 (ja) * | 2013-11-28 | 2015-06-04 | 日本電気株式会社 | 二次電池用電解液およびこれを用いた二次電池 |
JP5765226B2 (ja) * | 2009-09-15 | 2015-08-19 | 宇部興産株式会社 | 非水電解液及びそれを用いた電気化学素子 |
US9190695B2 (en) | 2010-08-05 | 2015-11-17 | Wako Pure Chemical Industries, Ltd. | Nonaqueous electrolyte solution, method for producing same, and nonaqueous electrolyte battery using the electrolyte solution |
US9257720B2 (en) | 2010-08-05 | 2016-02-09 | Wako Pure Chemical Industries, Ltd. | Nonaqueous electrolyte solution and nonaqueous electrolyte battery using same |
JP2016051600A (ja) * | 2014-08-29 | 2016-04-11 | 富山薬品工業株式会社 | 蓄電デバイス用非水電解液 |
JPWO2014030684A1 (ja) * | 2012-08-24 | 2016-07-28 | 宇部興産株式会社 | 非水電解液及びそれを用いた蓄電デバイス |
KR20160113598A (ko) | 2014-01-24 | 2016-09-30 | 산요가세이고교 가부시키가이샤 | 2 차 전지용 첨가제, 그것을 사용한 전극 및 전해액, 리튬 이온 전지 그리고 리튬 이온 캐패시터 |
EP2485316A4 (en) * | 2009-09-29 | 2017-01-11 | Mitsubishi Chemical Corporation | Nonaqueous electrolyte battery and nonaqueous electrolyte solution |
WO2017004885A1 (zh) * | 2015-07-08 | 2017-01-12 | 深圳新宙邦科技股份有限公司 | 一种锂离子电池非水电解液及锂离子电池 |
JP2017168347A (ja) * | 2016-03-17 | 2017-09-21 | 富山薬品工業株式会社 | 蓄電デバイス用非水電解液 |
US9905887B2 (en) | 2012-06-05 | 2018-02-27 | Nec Corporation | Lithium secondary battery |
WO2018211896A1 (ja) * | 2017-05-15 | 2018-11-22 | コニカミノルタ株式会社 | ビニルスルホン化合物、リチウムイオン電池用電解液及びリチウムイオン電池 |
US10243234B2 (en) | 2014-10-24 | 2019-03-26 | Nec Corporation | Secondary battery |
WO2019180946A1 (ja) * | 2018-03-23 | 2019-09-26 | 富山薬品工業株式会社 | 蓄電デバイス用非水電解液 |
Families Citing this family (23)
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JP5520906B2 (ja) * | 2011-09-20 | 2014-06-11 | 株式会社日立製作所 | リチウムイオン二次電池用正極、リチウムイオン二次電池及び電池モジュール |
DE102011084009A1 (de) * | 2011-10-05 | 2013-04-11 | Varta Microbattery Gmbh | Lithium-Ionen-Zellen mit verbesserten Eigenschaften |
WO2013054511A1 (ja) * | 2011-10-11 | 2013-04-18 | 株式会社Gsユアサ | 非水電解質二次電池および非水電解質二次電池の製造方法 |
TW201330350A (zh) * | 2011-11-01 | 2013-07-16 | Hitachi Maxell Energy Ltd | 鋰蓄電池 |
KR101542317B1 (ko) | 2013-01-10 | 2015-08-05 | 주식회사 엘지화학 | 리튬 인산철 나노분말 제조방법 |
KR101561377B1 (ko) * | 2013-01-10 | 2015-10-20 | 주식회사 엘지화학 | 리튬 인산철 나노분말 제조방법 |
KR101586556B1 (ko) | 2013-01-10 | 2016-01-20 | 주식회사 엘지화학 | 탄소 코팅 리튬 인산철 나노분말 제조방법 |
US20160204432A1 (en) * | 2013-09-05 | 2016-07-14 | Ishihara Sangyo Kaisha, Ltd. | Non-aqueous electrolyte secondary battery and method for manufacturing the same |
JP6380409B2 (ja) | 2013-12-19 | 2018-08-29 | 宇部興産株式会社 | 非水電解液、それを用いた蓄電デバイス、及びそれに用いられるカルボン酸エステル化合物 |
US10109885B2 (en) * | 2014-05-07 | 2018-10-23 | Sila Nanotechnologies, Inc. | Complex electrolytes and other compositions for metal-ion batteries |
DE102014108254A1 (de) * | 2014-06-12 | 2015-12-17 | Karlsruher Institut für Technologie Innovationsmanagement | Elektrolyt, Zelle und Batterie umfassend den Elektrolyt und dessen Verwendung |
JP6187829B2 (ja) * | 2015-03-31 | 2017-08-30 | トヨタ自動車株式会社 | リチウム二次電池および該電池の製造方法 |
KR102103898B1 (ko) * | 2017-01-23 | 2020-04-24 | 주식회사 엘지화학 | 비수전해액용 첨가제, 이를 포함하는 리튬 이차전지용 비수전해액 및 리튬 이차전지 |
CN109037776A (zh) * | 2017-06-09 | 2018-12-18 | 宁德时代新能源科技股份有限公司 | 电解液以及包括该电解液的电池 |
WO2019016903A1 (ja) * | 2017-07-19 | 2019-01-24 | 宇部興産株式会社 | 非水電解液及びそれを用いた蓄電デバイス |
CN108258314A (zh) * | 2018-02-01 | 2018-07-06 | 广州赛益迪新能源科技有限公司 | 一种适配高压镍钴锰三元正极材料的电解液 |
CN110707359A (zh) * | 2018-07-09 | 2020-01-17 | 中国科学院福建物质结构研究所 | 一种高电压型锂离子电池用电解液 |
CN110416607A (zh) * | 2019-05-30 | 2019-11-05 | 安徽兴锂新能源有限公司 | 一种锂离子电池电解液 |
CN110867612B (zh) * | 2019-10-15 | 2022-03-08 | 湖南法恩莱特新能源科技有限公司 | 一种锂离子电池低温充放电解液 |
CN112701350B (zh) * | 2019-10-23 | 2023-06-16 | 宁德国泰华荣新材料有限公司 | 一种电解液、锂离子电池及化成方法 |
WO2021128002A1 (zh) * | 2019-12-24 | 2021-07-01 | 宁德时代新能源科技股份有限公司 | 二次电池及含有该二次电池的装置 |
CN112349961B (zh) * | 2020-11-12 | 2021-09-24 | 宁德新能源科技有限公司 | 电解液及包含其的电化学装置和电子设备 |
CN114267877A (zh) * | 2021-11-30 | 2022-04-01 | 合肥国轩高科动力能源有限公司 | 一种锂离子电池电解液及锂离子电池 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0696770A (ja) * | 1992-09-10 | 1994-04-08 | Fuji Photo Film Co Ltd | 化学電池 |
JP2000021446A (ja) * | 1998-07-03 | 2000-01-21 | Fuji Photo Film Co Ltd | 非水二次電池 |
JP2005108440A (ja) | 2003-03-24 | 2005-04-21 | Samsung Sdi Co Ltd | リチウム二次電池用電解質及びこれを含むリチウム二次電池 |
JP2006294519A (ja) | 2005-04-13 | 2006-10-26 | Sony Corp | 電解液および電池 |
JP2007173147A (ja) | 2005-12-26 | 2007-07-05 | Gs Yuasa Corporation:Kk | 非水電解質二次電池 |
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US6406817B2 (en) * | 1998-07-01 | 2002-06-18 | Ube Industries, Ltd. | Crosslinked polymer, electrolyte using the polymer, and nonaqueous secondary battery using the electrolyte |
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-
2008
- 2008-04-15 CN CN201210279083.3A patent/CN102856587B/zh not_active Expired - Fee Related
- 2008-04-15 JP JP2009511810A patent/JP5428855B2/ja not_active Expired - Fee Related
- 2008-04-15 CN CN200880012245.9A patent/CN101657416B/zh not_active Expired - Fee Related
- 2008-04-15 US US12/596,300 patent/US8404390B2/en active Active
- 2008-04-15 WO PCT/JP2008/057350 patent/WO2008133112A1/ja active Application Filing
- 2008-04-15 KR KR1020097021324A patent/KR101533121B1/ko not_active IP Right Cessation
- 2008-04-15 EP EP08740436A patent/EP2138481A4/en not_active Withdrawn
-
2013
- 2013-06-24 JP JP2013131402A patent/JP5704193B2/ja not_active Expired - Fee Related
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JP2006294519A (ja) | 2005-04-13 | 2006-10-26 | Sony Corp | 電解液および電池 |
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Title |
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SKATTEBOEL L. ET AL.: "Thiopyran 1,1-dioxide derivatives from addition of amines to propargyl sulfone", JOURNAL OF ORGANIC CHEMISTRY, vol. 33, no. 2, 1968, pages 548 - 552, XP008118657 * |
Cited By (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010192165A (ja) * | 2009-02-16 | 2010-09-02 | Sanyo Electric Co Ltd | 非水電解質二次電池 |
CN101924244A (zh) * | 2009-06-11 | 2010-12-22 | 索尼公司 | 电池 |
US9130244B2 (en) | 2009-09-15 | 2015-09-08 | Ube Industries, Ltd. | Nonaqueous electrolyte solution and electrochemical element using same |
JP5765226B2 (ja) * | 2009-09-15 | 2015-08-19 | 宇部興産株式会社 | 非水電解液及びそれを用いた電気化学素子 |
EP2485316A4 (en) * | 2009-09-29 | 2017-01-11 | Mitsubishi Chemical Corporation | Nonaqueous electrolyte battery and nonaqueous electrolyte solution |
JPWO2012011586A1 (ja) * | 2010-07-23 | 2013-09-09 | 宇部興産株式会社 | 非水電解液及びそれを用いた電気化学素子 |
US9190695B2 (en) | 2010-08-05 | 2015-11-17 | Wako Pure Chemical Industries, Ltd. | Nonaqueous electrolyte solution, method for producing same, and nonaqueous electrolyte battery using the electrolyte solution |
KR20180103187A (ko) | 2010-08-05 | 2018-09-18 | 후지필름 와코 준야꾸 가부시키가이샤 | 비수계 전해액 및 그를 사용한 비수계 전해액 전지 |
US9257720B2 (en) | 2010-08-05 | 2016-02-09 | Wako Pure Chemical Industries, Ltd. | Nonaqueous electrolyte solution and nonaqueous electrolyte battery using same |
US9905887B2 (en) | 2012-06-05 | 2018-02-27 | Nec Corporation | Lithium secondary battery |
JPWO2013187276A1 (ja) * | 2012-06-11 | 2016-02-04 | 日本電気株式会社 | 二次電池 |
WO2013187276A1 (ja) * | 2012-06-11 | 2013-12-19 | 日本電気株式会社 | 二次電池 |
JPWO2014030684A1 (ja) * | 2012-08-24 | 2016-07-28 | 宇部興産株式会社 | 非水電解液及びそれを用いた蓄電デバイス |
JPWO2014080871A1 (ja) * | 2012-11-20 | 2017-01-05 | 日本電気株式会社 | リチウムイオン二次電池 |
US10177413B2 (en) | 2012-11-20 | 2019-01-08 | Nec Corporation | Lithium ion secondary battery |
JPWO2014080870A1 (ja) * | 2012-11-20 | 2017-01-05 | 日本電気株式会社 | リチウムイオン二次電池 |
WO2014080870A1 (ja) * | 2012-11-20 | 2014-05-30 | 日本電気株式会社 | リチウムイオン二次電池 |
WO2014080871A1 (ja) * | 2012-11-20 | 2014-05-30 | 日本電気株式会社 | リチウムイオン二次電池 |
WO2015080102A1 (ja) * | 2013-11-28 | 2015-06-04 | 日本電気株式会社 | 二次電池用電解液およびこれを用いた二次電池 |
JPWO2015080102A1 (ja) * | 2013-11-28 | 2017-03-16 | 日本電気株式会社 | 二次電池用電解液およびこれを用いた二次電池 |
US10587008B2 (en) | 2013-11-28 | 2020-03-10 | Nec Corporation | Electrolyte solution for secondary battery and secondary battery using same |
KR20160113598A (ko) | 2014-01-24 | 2016-09-30 | 산요가세이고교 가부시키가이샤 | 2 차 전지용 첨가제, 그것을 사용한 전극 및 전해액, 리튬 이온 전지 그리고 리튬 이온 캐패시터 |
JP2016051600A (ja) * | 2014-08-29 | 2016-04-11 | 富山薬品工業株式会社 | 蓄電デバイス用非水電解液 |
US10243234B2 (en) | 2014-10-24 | 2019-03-26 | Nec Corporation | Secondary battery |
WO2017004885A1 (zh) * | 2015-07-08 | 2017-01-12 | 深圳新宙邦科技股份有限公司 | 一种锂离子电池非水电解液及锂离子电池 |
JP2017168347A (ja) * | 2016-03-17 | 2017-09-21 | 富山薬品工業株式会社 | 蓄電デバイス用非水電解液 |
WO2018211896A1 (ja) * | 2017-05-15 | 2018-11-22 | コニカミノルタ株式会社 | ビニルスルホン化合物、リチウムイオン電池用電解液及びリチウムイオン電池 |
JPWO2018211896A1 (ja) * | 2017-05-15 | 2020-03-19 | コニカミノルタ株式会社 | ビニルスルホン化合物、リチウムイオン電池用電解液及びリチウムイオン電池 |
JP7074131B2 (ja) | 2017-05-15 | 2022-05-24 | コニカミノルタ株式会社 | ビニルスルホン化合物、リチウムイオン電池用電解液及びリチウムイオン電池 |
WO2019180946A1 (ja) * | 2018-03-23 | 2019-09-26 | 富山薬品工業株式会社 | 蓄電デバイス用非水電解液 |
CN111971841A (zh) * | 2018-03-23 | 2020-11-20 | 富山药品工业株式会社 | 蓄电设备用非水电解液 |
CN111971841B (zh) * | 2018-03-23 | 2023-09-19 | 富山药品工业株式会社 | 蓄电设备用非水电解液 |
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EP2138481A1 (en) | 2009-12-30 |
EP2138481A4 (en) | 2011-11-30 |
JP5704193B2 (ja) | 2015-04-22 |
KR101533121B1 (ko) | 2015-07-01 |
KR20100015530A (ko) | 2010-02-12 |
CN102856587B (zh) | 2015-06-17 |
JP2013239443A (ja) | 2013-11-28 |
CN101657416A (zh) | 2010-02-24 |
US20100092872A1 (en) | 2010-04-15 |
CN102856587A (zh) | 2013-01-02 |
JP5428855B2 (ja) | 2014-02-26 |
CN101657416B (zh) | 2014-03-12 |
US8404390B2 (en) | 2013-03-26 |
JPWO2008133112A1 (ja) | 2010-07-22 |
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