WO2008047558A1 - Ceramic honeycomb structure and process for producing ceramic honeycomb structure - Google Patents
Ceramic honeycomb structure and process for producing ceramic honeycomb structure Download PDFInfo
- Publication number
- WO2008047558A1 WO2008047558A1 PCT/JP2007/068874 JP2007068874W WO2008047558A1 WO 2008047558 A1 WO2008047558 A1 WO 2008047558A1 JP 2007068874 W JP2007068874 W JP 2007068874W WO 2008047558 A1 WO2008047558 A1 WO 2008047558A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- honeycomb structure
- ceramic honeycomb
- average
- partition wall
- porosity
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/24—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
- B01D46/2403—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
- B01D46/2418—Honeycomb filters
- B01D46/2425—Honeycomb filters characterized by parameters related to the physical properties of the honeycomb structure material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/24—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
- B01D46/2403—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
- B01D46/2418—Honeycomb filters
- B01D46/2425—Honeycomb filters characterized by parameters related to the physical properties of the honeycomb structure material
- B01D46/2429—Honeycomb filters characterized by parameters related to the physical properties of the honeycomb structure material of the honeycomb walls or cells
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/24—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
- B01D46/2403—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
- B01D46/2418—Honeycomb filters
- B01D46/2425—Honeycomb filters characterized by parameters related to the physical properties of the honeycomb structure material
- B01D46/24491—Porosity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/24—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
- B01D46/2403—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
- B01D46/2418—Honeycomb filters
- B01D46/2425—Honeycomb filters characterized by parameters related to the physical properties of the honeycomb structure material
- B01D46/24492—Pore diameter
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/24—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
- B01D46/2403—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
- B01D46/2418—Honeycomb filters
- B01D46/2425—Honeycomb filters characterized by parameters related to the physical properties of the honeycomb structure material
- B01D46/24494—Thermal expansion coefficient, heat capacity or thermal conductivity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/24—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
- B01D46/2403—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
- B01D46/2418—Honeycomb filters
- B01D46/2451—Honeycomb filters characterized by the geometrical structure, shape, pattern or configuration or parameters related to the geometry of the structure
- B01D46/2455—Honeycomb filters characterized by the geometrical structure, shape, pattern or configuration or parameters related to the geometry of the structure of the whole honeycomb or segments
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/24—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
- B01D46/2403—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
- B01D46/2418—Honeycomb filters
- B01D46/2451—Honeycomb filters characterized by the geometrical structure, shape, pattern or configuration or parameters related to the geometry of the structure
- B01D46/2482—Thickness, height, width, length or diameter
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/24—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
- B01D46/2403—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
- B01D46/2418—Honeycomb filters
- B01D46/2451—Honeycomb filters characterized by the geometrical structure, shape, pattern or configuration or parameters related to the geometry of the structure
- B01D46/2484—Cell density, area or aspect ratio
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/24—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
- B01D46/2403—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
- B01D46/2418—Honeycomb filters
- B01D46/2498—The honeycomb filter being defined by mathematical relationships
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/16—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
- C04B35/18—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay rich in aluminium oxide
- C04B35/195—Alkaline earth aluminosilicates, e.g. cordierite or anorthite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/0006—Honeycomb structures
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
- F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
- F01N3/022—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous
- F01N3/0222—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters characterised by specially adapted filtering structure, e.g. honeycomb, mesh or fibrous the structure being monolithic, e.g. honeycombs
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
- C04B2235/3218—Aluminium (oxy)hydroxides, e.g. boehmite, gibbsite, alumina sol
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/349—Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/52—Constituents or additives characterised by their shapes
- C04B2235/5296—Constituents or additives characterised by their shapes with a defined aspect ratio, e.g. indicating sphericity
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/54—Particle size related information
- C04B2235/5409—Particle size related information expressed by specific surface values
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/54—Particle size related information
- C04B2235/5418—Particle size related information expressed by the size of the particles or aggregates thereof
- C04B2235/5436—Particle size related information expressed by the size of the particles or aggregates thereof micrometer sized, i.e. from 1 to 100 micron
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
- C04B2235/9607—Thermal properties, e.g. thermal expansion coefficient
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2330/00—Structure of catalyst support or particle filter
- F01N2330/06—Ceramic, e.g. monoliths
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2330/00—Structure of catalyst support or particle filter
- F01N2330/30—Honeycomb supports characterised by their structural details
- F01N2330/38—Honeycomb supports characterised by their structural details flow channels with means to enhance flow mixing,(e.g. protrusions or projections)
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24149—Honeycomb-like
Definitions
- the present invention mainly relates to a ceramic honeycomb structure that can be suitably used as a ceramic honeycomb filter that collects and purifies particulate matter in exhaust gas discharged from a diesel engine, and a method for manufacturing the same.
- Diesel engine exhaust gas contains particulates (particulate matter), which are mainly composed of carbon (eg, soot) and high-boiling hydrocarbons. May cause adverse effects. For this reason, it has been the conventional practice to install a ceramic honeycomb filter (hereinafter referred to as “no, two-cam filter”) to remove particulates and purify exhaust gas in the middle of the exhaust pipe of a diesel engine. /! As shown in FIGS. 1 (a) and 1 (b), the honeycomb filter 20 includes a ceramic honeycomb structure 10 (hereinafter referred to as ⁇ the honeycomb honeycomb structure 10 '' composed of a porous partition wall 2 and a peripheral wall 1 forming a large number of flow paths 3 and 4.
- ⁇ the honeycomb honeycomb structure 10
- the honeycomb filter can be regenerated by burning the accumulated particulates with a burner or heater. Alternatively, the particulate matter is blown off by backwash air and then burned to regenerate the honeycomb filter.
- a method of burning the material continuously or a method of injecting and burning unburned fuel into the exhaust gas on the upstream side of the honeycomb filter and burning the collected particulate matter has come to be adopted. It was.
- the honeycomb filter 20 has a high particulate collection efficiency and a long collection time.
- the pressure loss is required to be low, and in particular, the collection time (the time during which particulate matter can be collected at a certain pressure loss or less) is preferably as long as possible. If the collection time is short, the collected particulate matter must be frequently burned and removed by heating with an electric heater or burner, or by fuel injection. The fuel efficiency of the engine will deteriorate.
- Japanese Patent Laid-Open No. 7-163823 the cell walls have a porosity of 45 to 60% toward the force from the surface to the interior, connexion openings and the specific surface area of the total pore penetrating M (m 2 / g ) And the surface roughness of the filter surface ⁇ ⁇ ) is disclosed as a porous ceramic honeycomb filter with 1000M + 85N ⁇ 530, and by having such a shape, the collection time is long. It states that the number of playbacks can be reduced.
- JP-A-7-163823 by using a combination of fine talc and coarse silica, coarse silica located on the surface increases the surface roughness (N), and fine!
- Japanese Patent Application Laid-Open No. 8-931 has a porosity of 40 to 55% and an average pore diameter of 5 to 50 m, and has a surface valley level (surface pores in a portion lower than the average surface by surface roughness measurement).
- a honeycomb filter with an area ratio value of 20% or less is disclosed. This filter has good releasability of fine particles collected on the surface, so it can be used for a long time with good regenerative efficiency by backwash air. However, there is little increase in pressure loss.
- the portion lower than the average surface by surface roughness measurement where fine particles are preferentially collected becomes smaller.
- particulate matter in exhaust gas has been reduced in size and made uniform by improving diesel engines (high-pressure fuel injection). Loss increases are more likely to occur and during collection It was not enough to solve the problem of short intervals.
- WO01 / 15877 describes a particulate removal filter composed of a cordierite honeycomb structure having a partition wall thickness of 0.3 mm and a cell density of 200 cpsi, by increasing the porosity to reduce the Valley Level from 15% to 30%.
- the collection rate was improved by about 5% in the case of a normal flat wall honeycomb structure and about 10% in the case of a wave wall honeycomb structure.
- the Valley Level of about 30% is still insufficient for the problem of increasing the collection time, and further increasing the porosity causes a decrease in the strength of the honeycomb structure. It is difficult to obtain a honeycomb filter having a high strength and a low pressure loss while making it long.
- an object of the present invention is to reduce the increase in pressure loss of the honeycomb filter when the particulate matter is collected, thereby making it possible to reliably increase the collection time and to have a high strength.
- a ceramic honeycomb structure suitable for a filter and a method for producing the same are provided.
- the present inventors have determined that the porosity, average pore diameter, and surface shape of the partition walls of the ceramic honeycomb structure are in a specific range.
- the present inventors have found that the increase in pressure loss can be reduced and the collection time can be increased, and the present invention has been conceived.
- the ceramic honeycomb structure of the present invention is a ceramic honeycomb structure having a large number of channels surrounded by porous partition walls, the partition walls having a porosity of 55 to 70% and 10 to 40 m.
- the ratio of the recess area ratio CR ratio of the projected area on the average surface of the recessed portion rather than the average surface obtained from the unevenness of the partition wall surface by the least square method] is 0.32 to 0.6
- the average depth of the recess H H-concave average value of the depth of the concave with respect to the average surface] is 0 ⁇ 02 to 0 ⁇ 1 mm.
- the CR is preferably 0 ⁇ 4 to 0 ⁇ 5. It is preferable that the recess is in the range of 0 ⁇ 03 to 0 ⁇ 06 mm.
- the partition wall preferably has a permeability of 1 ⁇ 8 X 10- 12 m 2.
- the partition preferably has a porosity of 60 to 70% and an average pore diameter of 15 to 30 m.
- Thermal expansion coefficient between 40 to 800 ° C of the flow path Direction of the partition wall is preferably 4 ⁇ 15 X 10- 7 / ° C.
- the method of the present invention for manufacturing a ceramic honeycomb structure includes a ceramic honeycomb in which a pore former is mixed and kneaded with a cordierite forming raw material powder to obtain a clay, and the clay is molded, dried and fired.
- a method of manufacturing a structure the cordierite raw material powder BET specific surface area 1 to 3 m 2 / g, the silica powder is the aspect ratio of 1 ⁇ 2-5 contain 5 to 20 wt%, said granulation
- the pore material is a foamed foamed resin having an average particle size of 40 to 80 m, and 6 to 15 parts by mass of the foamed foamed resin is added to 100 parts by mass of the cordierite-forming raw material powder.
- the ceramic honeycomb structure of the present invention has irregularities formed on the partition wall surface, and the ratio of the concave parts and the depth of the concave parts are in an appropriate range, the particulate matter is collected.
- the increase in pressure loss of the honeycomb filter can be reduced, so that the collection time of the honeycomb filter can be extended and the strength of the honeycomb filter is improved.
- FIG. 1 (a) is a schematic cross-sectional view showing an example of a ceramic honeycomb filter of the present invention perpendicular to a flow path.
- FIG. 1 (b) is a schematic cross-sectional view showing an example of the ceramic honeycomb filter of the present invention parallel to the flow path.
- Fig. 2 is a view showing the results of measuring the unevenness of the surface of the ceramic honeycomb structure of Example 3.
- FIG. 3 is a schematic view showing a cross section of pores formed in partition walls of a conventional ceramic honeycomb structure.
- FIG. 4 is a schematic view showing a cross section of pores formed in the partition walls of the ceramic honeycomb structure of the present invention.
- Ceramic honeycomb structure is a ceramic honeycomb structure having a large number of flow paths surrounded by porous partition walls, wherein the partition walls have a porosity of 55 to 70% and an average fineness of 10 to 40 11 m.
- Recess area ratio CR ratio of projected area of average surface area of recess to average surface obtained by least square method from unevenness on partition wall surface
- average recess depth H-concave the average value of the depth of the concave with respect to the average surface
- an increase in pressure loss when particulate matter is collected can be reduced, and a high-strength honeycomb structure can be obtained.
- the method for measuring the recess area ratio and the average recess depth will be described below.
- a 3D surface roughness measuring instrument scan a stylus with a tip of R2 m and a tip angle of 60 ° over an arbitrary 0.8 mm x 0.8 mm area on the partition wall surface, totaling every 2 ⁇ in both x and y directions. Measure surface roughness data at 160,000 locations. Obtaining an average surface from these data by a least square method, the recess area ratio CR (Con Cave value obtained by dividing by the total measured area of the projected area of the average surface of the concave portion than the mean plane (0.8 2 mm 2) Ratio).
- CR Con Cave value obtained by dividing by the total measured area of the projected area of the average surface of the concave portion than the mean plane (0.8 2 mm 2) Ratio).
- CR [ratio of the projected area of the concave portion to the average surface rather than the average surface obtained by the least square method from the unevenness of the partition wall surface].
- CR of 0.3 corresponds to approximately 30% of the Valley Level described in JP-A-8-931 and WO01 / 15877.
- the average concave portion depth H is the average value of the depth of the concave portion from the average plane within the measurement area (0.8 mm ⁇ 0.8 mm).
- CR is less than 0.32 (the area ratio of the recesses from the average surface is small), the particulate matter is likely to be clogged when the particulate matter is collected, thereby reducing the increase in pressure loss. Effect is not obtained.
- CR exceeds 0.6 (the area ratio of the recesses from the average surface increases), the opening size of the recesses increases, so that the strength of the honeycomb structure decreases and the honeycomb filter cannot be practically used.
- a more preferable range of CR is 0 ⁇ 35 to 0.5, and most preferably 0 ⁇ 4 to 0.5.
- the large CR means that the area ratio of the partition wall surface due to the pores is simply large.
- Different. 3 and 4 schematically show the cross-sectional shape of the pores.
- the average surface 23 is a surface that minimizes the sum of squares of the measurement points of the convex portion 21 and the concave portion 22.
- CR is the area ratio (al, & 2 ⁇ ) occupied by the recess 22 projected onto the average surface.
- the opening area ratio of the partition wall surface is the area ratio of the opening portion on the surface 24 (the sum of bl and b2 ′ ′ ′). For example, as shown in Fig.
- the ceramic honeycomb structure of the present invention has an effect of reducing the increase in pressure loss because the CR is increased as shown in FIG.
- the most characteristic feature of the present invention is that a partition wall having a high porosity of about 80% has conventionally been required in order to achieve a CR of 0.3 or more, but a relatively low level of 70% or less is required. In spite of the partition wall having porosity, CR of 0.3 or more was obtained. As a result, the increase in pressure loss can be reduced without reducing the strength of the ceramic honeycomb structure.
- BET specific surface area force Sl-3 m is used as a ceramic raw material that melts at a relatively low temperature during the firing process (for example, silica powder in the case of cordierite). This can be achieved by selecting a foam with an average particle size of 40 to 80 am as the pore former and selecting one with a large aspect ratio of 1.2 to 5 as large as 2 / g.
- the concave force is less than S0.02 mm, the concave portion is too shallow, so that the effect of reducing the increase in pressure loss when the particulate matter is collected cannot be obtained. If the H-concave exceeds 0.1 mm, the recess on the surface of the partition wall is too deep and the strength decreases starting from the tip of the recess. The more preferable range of the H-concave (from 0 ⁇ 03 to 0 ⁇ 06 mm.
- the average height H of the protrusions [average value of the height of the protrusions relative to the average surface] is, from the viewpoint of suppressing the resistance when the exhaust gas enters the flow path is low It is preferably 0.1 mm or less.
- the ceramic honeycomb structure according to the present invention has a partition wall having a porosity of 55 to 70% and an average pore diameter of 10 to 40 m, so that the Hayuka in an initial state before collecting particulate matter is obtained.
- the pressure loss of the filter can be reduced.
- the porosity of the partition walls is less than 55%, the pressure loss of the honeycomb filter in the initial state increases, and when it exceeds 70%, the strength of the honeycomb structure decreases.
- a more preferable porosity range is 60 to 70%. If the average pore diameter is less than 10 m, the pressure loss of the honeycomb filter in the initial state increases, and if it exceeds 40 ⁇ 01, the strength of the ceramic honeycomb structure decreases. More preferred! /,
- the average pore size range is 15-3001.
- the partition walls preferably have air permeability of 1 ⁇ 8 X 10- 12 m 2.
- the partition wall has an air permeability in this range, the pressure loss of the honeycomb filter in the initial state can be further reduced, and the increase in the pressure loss when the particulate matter is collected can be reduced.
- the air permeability is 3 ⁇ 7 X 10- 12 m 2.
- the air permeability is a value obtained based on the equation (1).
- k is the air permeability (m 2 )
- n is the viscosity of air at room temperature (MPa second)
- T is the sample thickness (m)
- Q is the air flow rate through the sample (m 3 )
- A is the sample area (m 2 ) and ⁇ ⁇ are the pressure difference (MPa) in the thickness direction of the sample.
- the air permeability k is determined by the force S obtained by setting the partition wall sample cut out from the ceramic honeycomb filter in one holder, adding a difference in air pressure between both sides of the sample, and measuring the flow rate of air passing through the partition wall.
- Netsu ⁇ expansion coefficient between 40 to 800 ° C in the flow path direction of the partition wall is preferably 4 ⁇ 15 X 10- 7 / ° C.
- a ceramic honeycomb structure having such a coefficient of thermal expansion exhibits extremely excellent thermal shock resistance, and there is almost no risk of breakage even when sudden temperature changes occur.
- Further preferred thermal expansion coefficient definitive between 40 to 800 ° C in the flow path direction of the partition wall is 5 ⁇ 12 X 10- 7 / ° C.
- the partition wall thickness of the ceramic honeycomb structure is preferably from 0.1 to 0.5 mm.
- the strength of the honeycomb structure decreases because the partition wall is a porous body having a porosity of 55 to 70%.
- the partition wall thickness exceeds 0.5 mm, the porosity of the partition wall is 55-70. Even if the porosity is high, the pressure resistance of the honeycomb filter increases because the ventilation resistance of the partition wall against the exhaust gas increases.
- a more preferable partition wall thickness is 0.2-0.4 mm.
- the pitch of the partition walls is preferably 1 to 3 mm.
- the partition pitch is less than 1 mm, the opening area of the inlet of the honeycomb structure is reduced, so that the pressure loss at the honeycomb filter inlet increases, and when it exceeds 3 mm, the area of the filter is reduced and the particles are reduced. The amount of collected substances decreases.
- the shape of the flow path partitioned by the partition walls of the ceramic honeycomb structure is not particularly limited, but from the viewpoint of production, any one of a triangle, a quadrangle, a hexagon, and a circle is preferable. From the viewpoint of the strength of the honeycomb structure and the filter area, a rectangular channel is preferred. Since the flow path resistance when the exhaust gas passes through the flow path is increased when the partition wall is curved, the partition wall is preferably flat. In the cross section perpendicular to the flow path, the maximum value (maximum amplitude) of the difference between the line connecting the points where the multiple bulkheads constituting one flow path intersect with a straight line and the centerline of the formed bulkhead is It is preferably less than 100% with respect to the partition wall thickness. More preferably, the maximum amplitude is less than 50%, more preferably less than 30% with respect to the partition wall thickness.
- a material having excellent heat resistance is used because the present invention is mainly used for the purpose of removing the particulate matter in the exhaust gas of the diesel engine.
- a ceramic material whose main crystal is at least one selected from the group consisting of cordierite, alumina, mullite, silicon nitride, sialon, silicon carbide, aluminum titanate, aluminum nitride, and LAS is used. That power S is preferable.
- Cordierite or aluminum titanate is the most preferred material because it is inexpensive, has excellent heat resistance and corrosion resistance, and has low thermal expansion.
- the material constituting the partition wall and the sealing portion may be different! /, But it is preferable that they are the same in order to reduce the stress generated by the difference in thermal expansion coefficient between the partition wall and the sealing portion.
- a clay that becomes a material such as cordierite, alumina, mullite, silicon nitride, sialon, silicon carbide, aluminum titanate, anodized nitride, and LAS is produced by firing.
- This clay is formed, for example, by adding water, a binder and a pore former to a cordierite forming raw material powder and the like.
- the obtained clay is extruded using a known honeycomb structure forming die and then dried to produce a dried honeycomb structured body.
- the outer peripheral portion of the honeycomb structure has a concave groove that opens to the outside and extends substantially in the axial direction.
- the plugging material slurry is filled into desired flow paths at both ends of the ceramic honeycomb structure and fired to integrate the plugging portions and the partition walls.
- the partition walls and the plugging portions may be fired simultaneously.
- the outer peripheral wall portion is formed by filling and applying the outer peripheral wall coating material made of, for example, ceramic aggregate and the inorganic binder, which is the same material as the partition walls, into the concave groove on the outer peripheral portion of the ceramic honeycomb structure.
- a ceramic honeycomb finisher is obtained by performing a firing operation in accordance with the above and integrating the partition walls and the outer peripheral wall portion.
- the processing and removal of the peripheral portion can also be performed using a cylindrical grinder after the dried honeycomb structured body is fired.
- a cylindrical grinder After processing and removing the peripheral edge that is likely to be deformed during extrusion, an outer peripheral wall made of ceramic aggregate and an inorganic binder is formed to obtain a ceramic honeycomb filter having high strength, which is mounted on a diesel engine. Even if it is done, high resistance and durability can be secured.
- the ceramic honeycomb structure having partition walls is a ceramic raw material powder having a specific shape, for example, when the nonicum structure is cordierite, and a silica powder having a specific shape and an average particle size of 40 as a pore former. It can be obtained by using a foamed resin of ⁇ 80 m. Since silica powder melts in a relatively low temperature region during firing, pores corresponding to the shape of the powder are formed.
- Silica particles having a shape with a BE T specific surface area force Sl of ⁇ 3 m 2 / g and an aspect ratio of 1 By adding 5 to 20% by weight with respect to the raw material powder of single light, a concave portion effective for collecting particulate matter is formed on the partition wall surface. Quartz, cristobalite, fused silica, etc. can be used as the silica powder, but fused silica is preferred from the viewpoint of effectively forming the recesses.
- the foamed resin having an average particle diameter of 40 to 80 m is added in an amount of 6 to 15 parts by mass with respect to 100 parts by mass of the ceramic raw material.
- the ceramic honeycomb structure has cordierite as the main crystal, silica having an average particle diameter of 5 to 25 m, talc having an average particle diameter of 8 to 15 m, and 4 to 20 m It is preferable to use alumina having an average particle diameter.
- the alumina powder preferably has at least one peak (maximum value) of the particle size distribution (volume basis) in the particle size range of 0.5 to 101 and the particle size range of 10 to 80 m. .
- cordierite forming raw material powder As cordierite forming raw material powder, kaolin, talc, silica A (fused silica), alumina and aluminum hydroxide powder shown in Table 1 and Table 2 were weighed according to Formulation A shown in Table 3. To 100 parts by mass of these cordierite-forming raw material powders, 6 parts by mass of a foamed foamed resin having an average particle diameter of 60 m is added as a pore former, and methylcellulose and hydroxypropylmethylcellulose are added as binders. After thoroughly mixing in a dry process, water was added and kneaded to produce a plasticized ceramic clay. Here, the specific surface area of the powder was measured by the BET method, and the average particle size was measured by the laser diffraction method.
- the aspect ratio was calculated as an average value of major axis / minor axis by measuring the major axis and minor axis of 10 arbitrary powders from SEM photographs.
- This kneaded material was extruded, cut and dried to obtain a dried body having a honeycomb structure.
- the ceramic honeycomb structure is fired at 1400 ° C. in a batch furnace. Obtained.
- This ceramic The two-cam structure had a concave groove that opened to the outside and extended almost in the axial direction.
- the outer diameter was 265 mm
- the overall length was 304 mm
- the partition wall thickness was 0.3 mm
- the partition wall pitch was 1.5 mm.
- Peak positions in the particle size distribution were 5 m and 20 m.
- Formulation A Formulation B Formulation C Formulation D Formulation E Kaolin 7.6 18.9 10.4 7.6 7.6 Talc 41.0 40.8 41.0 41.0 41.0 Alumina 22.8 19.2 22.0 22.8 22.8 Aluminum hydroxide 11.1 9.3 10.6 11.1 11.1 Siri force A 17.5 11.8 16 ⁇ ⁇ Silica B ⁇ ⁇ ⁇ 17.5 ⁇ Silica C ⁇ ⁇ ⁇ ⁇ 17.5 [0043]
- the desired flow path at both ends of the obtained ceramic honeycomb structure was filled with a plugging material slurry made of a cordierite forming raw material, and the plugged portion was fired at 1400 ° C. The plugging part and the partition were integrated.
- the outer peripheral wall portion is formed by filling and applying the outer peripheral wall coating material composed of cordierite aggregate having an average particle size of 15 m and colloidal silica in the concave groove formed in the outer peripheral portion of the ceramic honeycomb structure. After the formation, it was dried and the partition wall and the outer peripheral wall were integrated to obtain a ceramic honeycomb filter having an outer diameter of 267 mm and a total length of 304 mm (filter volume: 17 L).
- Examples 2, 3 and 4 were the same as Example 1 except that 8 parts by mass, 10 parts by mass, 12 parts by mass and 14 parts by mass of foamed foamed resin having an average particle diameter of 60 m were used as pore formers, respectively. And 5 ceramic honeycomb filters were obtained.
- Ceramic honeycomb filters of Examples 6 and 7 were obtained in the same manner as Example 3 except that the mixing ratio of the ceramic raw material powder was changed to the mixing B and mixing C shown in Table 3.
- Ceramic honeycomb filters of Comparative Examples 1 and 2 were obtained in the same manner as in Example 1 except that 5 parts by mass and 16 parts by mass of foamed foamed resin having an average particle diameter of 60 ⁇ m were used as the pore former.
- Ceramic honeycomb filters of Comparative Examples 3 and 4 were obtained in the same manner as in Example 2 except that silica B powder and silica C powder were used in place of the silica A powder.
- Comparative Example 5 is 40 parts by weight of graphite powder with an average particle size of 20 m
- Comparative Example 6 is 8 masses of foamed foamed resin with an average particle size of 86 m.
- a ceramic honeycomb filter was obtained in the same manner as in Example 2 except that a part of the filter was used.
- Example 13 By simulating Example 13 described in JP-A-8-931, a cordierite composition of 42 to 56% by weight of SiO, 30 to 45% by weight of A10 and 12 to 16% by weight of MgO is obtained. And an average particle size of 10 mm m talc, silica with an average particle size of 40 m, kaolin with an average particle size of 3 m, alumina with an average particle size of 1.8 01, and other cordierite raw materials, and 20% by weight of graphite is added to this mixture Further, methylcellulose, a surfactant, and water were added, mixed and kneaded, extruded and then dried to obtain a dried honeycomb structure.
- Example 7 Thereafter, in the same manner as in Example 1, the peripheral part of the dried body was processed and removed, fired at 1400 ° C, and then plugged and outer peripheral wall parts were formed, the outer diameter was 267 mm, and the total length was A ceramic honeycomb filter of Comparative Example 7 having a thickness of 304 mm (filter volume: 17 L), a partition wall thickness of 0.3 mm, and a partition wall pitch of 1.5 mm was obtained.
- Pressure loss was evaluated for the ceramic honeycomb filters of Examples 1 to 7 and Comparative Examples 1 to 7. Pressure loss was evaluated based on the following criteria by measuring the pressure difference between the inflow side and the outflow side using a pressure test stand.
- carbon powder having a particle size of 0.042 ⁇ m was introduced at a rate of 3 g / h at an air flow rate of 10 Nm 3 / min, and 17 g (lg of carbon powder per liter of filter volume) before carbon powder was charged.
- the rate of increase in pressure loss after injection was calculated using the following formula.
- Pressure loss rise rate (%) 100 X ⁇ (pressure loss after carbon lg / L injection)-(pressure loss before carbon injection) ⁇ / (pressure loss before carbon injection)
- the collection pressure loss was evaluated according to the following criteria based on the pressure loss increase rate.
- a test piece was cut out from the ceramic honeycomb filter, and the porosity, average pore diameter, and recess area ratio CR [the ratio of the projected area to the average surface of the recess rather than the average surface obtained from the unevenness of the partition wall surface by the least square method] ], Concave average depth H concave [average value of concave depth with respect to the average surface], convex average height H convex [average value of convex height with respect to the average surface], partition air permeability, separation The coefficient of thermal expansion and A-axis compressive strength were measured between 40 and 800 ° C in the direction of the wall flow path.
- the concave area ratio CR, the average concave depth H, and the average convex height H were measured by the following method. Using a Mitutoyo 3D surface roughness measuring instrument, scan a stylus with a tip of R211 m and a tip angle of 60 ° into an arbitrary 0.8 mm x 0.8 mm area on the partition wall surface with a stylus load of 85 mgre in the x and y directions. In both cases, surface roughness data of a total of 160,000 locations were measured every 2 ⁇ .
- the average surface was obtained from this unevenness data by the least square method, and the value obtained by dividing the projected area onto the average surface of the concave portion from this average surface by the measurement area (0.8 mm x 0.8 mm) was taken as CR (ConcaveRatio).
- H concave is the average value of the depth of the concave from the average surface within the measurement area (0.8 mm X 0.8 mm region), and H convex is the measurement area (0.8 mm X 0.8 mm region) It is the average value of the height of the convex part from the said average surface in the inside.
- FIG. 2 shows the convex portion 21 and the concave portion 22 when cut by the average surface of the partition wall surface obtained in Example 3.
- the air permeability of the partition walls was measured using a palm porometer manufactured by Porous Materials.
- the air permeability k was obtained by setting a partition wall sample cut out from the ceramic honeycomb filter in a holder, adding an air pressure difference between both surfaces of the sample, and measuring the air flow rate passing through the partition wall.
- the thermal expansion coefficient was measured by placing a test piece having a size of 4.8 mm ⁇ 4.8 mm ⁇ 50 mm and a longitudinal direction along the flow path of the ceramic honeycomb structure in a thermomechanical analyzer. The coefficient of thermal expansion was determined as an average value between 40 ° C and 800 ° C.
- the A-axis compressive strength was measured in accordance with the standard M505-87 "Testing method for ceramic monolithic carrier for automobile exhaust gas purification catalyst" established by the Japan Automobile Engineering Association.
- the pore specific surface area M (m 2 / g) was determined together with the porosity and the average pore diameter by the above Autopore III manufactured by Micromeritics.
- the surface roughness on the surface of one partition was obtained with a surface roughness meter.
- the maximum partition wall amplitude is the maximum difference between the line connecting the points where a plurality of partition walls constituting one flow path intersect with a straight line and the center line of the formed partition wall The value (maximum amplitude) was measured at 4 locations x 5 channels per channel, and a total of 20 measured data were averaged.
- Comparative Example 7 3 XX 4.7 3 As shown in Table 4, the ceramic honeycomb filters of Examples 1 to 7 formed from the ceramic honeycomb structure of the present invention had a partition wall porosity of 55 to 70% and an average pore diameter. When collecting particulate matter with a low carbon collection pressure loss, the force is 10 to 40 mm, the recess area ratio CR is 0 ⁇ 32 to 0 ⁇ 6, and the depression is 0.02 to 0.1 mm. As a result, the A-axis compressive strength of 3 MPa or more was obtained.
- the ceramic honeycomb filter of Comparative Example 1 has a porosity of less than 55%, so the evaluation result of pressure loss is rejected (X), and the ceramic honeycomb filter of Comparative Example 2 has a porosity exceeding 70%. Therefore, the A-axis compressive strength was low. Since the ceramic honeycomb filters of Comparative Examples 3 and 7 had a CR of less than 0.32, the carbon collection pressure loss was high, and the pressure loss increased when particulate matter was collected. Since the ceramic honeycomb filter of Comparative Example 4 has a CR exceeding 0.6, the A-axis pressure The shrinkage strength was low.
- the ceramic honeycomb filter of Comparative Example 5 has a CR in the range of 0.32 to 0.6, and the H-concave is 0.02 mm or less, the carbon collection pressure loss is high and the increase in pressure loss when collecting particulate matter is large. It was. Although the ceramic honeycomb filter of Comparative Example 6 had a CR in the range of 0.32 to 0.6, the H-concave was 0.1 mm or more, so the A-axis compressive strength was low.
- the ceramic honeycomb filter described in Japanese Patent Application Laid-Open No. 8-931 has a high collection pressure loss and a large increase in pressure loss when collecting particulate matter.
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Geometry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Materials Engineering (AREA)
- Thermal Sciences (AREA)
- Manufacturing & Machinery (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Combustion & Propulsion (AREA)
- Filtering Materials (AREA)
- Porous Artificial Stone Or Porous Ceramic Products (AREA)
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP07828620.0A EP2070576B1 (en) | 2006-09-28 | 2007-09-27 | Ceramic honeycomb structure and process for producing ceramic honeycomb structure |
JP2008539719A JP5315997B2 (ja) | 2006-09-28 | 2007-09-27 | セラミックハニカム構造体及びセラミックハニカム構造体の製造方法 |
US12/303,466 US7833606B2 (en) | 2006-09-28 | 2007-09-27 | Ceramic honeycomb structure and method for producing ceramic honeycomb structure |
CN2007800207842A CN101460230B (zh) | 2006-09-28 | 2007-09-27 | 蜂窝陶瓷结构体及蜂窝陶瓷结构体的制造方法 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2006265107 | 2006-09-28 | ||
JP2006-265107 | 2006-09-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2008047558A1 true WO2008047558A1 (en) | 2008-04-24 |
Family
ID=39313805
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2007/068874 WO2008047558A1 (en) | 2006-09-28 | 2007-09-27 | Ceramic honeycomb structure and process for producing ceramic honeycomb structure |
Country Status (5)
Country | Link |
---|---|
US (1) | US7833606B2 (ja) |
EP (1) | EP2070576B1 (ja) |
JP (1) | JP5315997B2 (ja) |
CN (1) | CN101460230B (ja) |
WO (1) | WO2008047558A1 (ja) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2012528784A (ja) * | 2009-06-05 | 2012-11-15 | コーニング インコーポレイテッド | コージライト形成バッチ材料及びその使用方法 |
JP5344930B2 (ja) * | 2007-01-30 | 2013-11-20 | 京セラ株式会社 | ハニカム構造体および浄化装置 |
CN107207370A (zh) * | 2015-02-05 | 2017-09-26 | 日本碍子株式会社 | 蜂窝结构体 |
WO2018207497A1 (ja) * | 2017-05-11 | 2018-11-15 | 株式会社キャタラー | 排ガス浄化触媒装置 |
JPWO2020194681A1 (ja) * | 2019-03-28 | 2020-10-01 | ||
JP2021159867A (ja) * | 2020-03-31 | 2021-10-11 | 日本碍子株式会社 | セラミックス製のフィルタ |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8187353B2 (en) * | 2009-01-21 | 2012-05-29 | Corning Incorporated | Filtration structures for improved particulate filter performance |
DE112013002164T5 (de) * | 2012-04-23 | 2015-01-29 | Dow Global Technologies Llc | Axial geschnittene keramische Wabeneinheiten |
CN102850084A (zh) * | 2012-09-17 | 2013-01-02 | 李少荣 | 一种以有机树脂发泡微球为造孔剂的多孔陶瓷的制备方法 |
US9499442B1 (en) * | 2013-03-15 | 2016-11-22 | Ibiden Co., Ltd. | Method for manufacturing aluminum-titanate-based ceramic honeycomb structure |
US9028741B1 (en) * | 2013-03-15 | 2015-05-12 | Ibiden Co., Ltd. | Method for manufacturing aluminum-titanate-based ceramic honeycomb structure |
WO2016152727A1 (ja) * | 2015-03-24 | 2016-09-29 | 日立金属株式会社 | セラミックハニカム構造体 |
JP6559597B2 (ja) * | 2016-02-29 | 2019-08-14 | 日本碍子株式会社 | ハニカム構造体の製造方法 |
JP6803275B2 (ja) * | 2017-03-17 | 2020-12-23 | 日本碍子株式会社 | ハニカム構造体 |
JP6853166B2 (ja) * | 2017-12-08 | 2021-03-31 | 日本碍子株式会社 | フィルタ |
JP7038585B2 (ja) * | 2018-03-30 | 2022-03-18 | 日本碍子株式会社 | セラミックス多孔体及び集塵用フィルタ |
JP2020158351A (ja) * | 2019-03-27 | 2020-10-01 | 日本碍子株式会社 | ハニカム構造体、および、ハニカム構造体の製造方法 |
JP6940787B2 (ja) * | 2019-07-31 | 2021-09-29 | 株式会社デンソー | 排ガス浄化フィルタ |
JP6940786B2 (ja) * | 2019-07-31 | 2021-09-29 | 株式会社デンソー | 排ガス浄化フィルタ |
CN113731062A (zh) * | 2021-09-16 | 2021-12-03 | 上海洁昊环保股份有限公司 | 一种透壁式滤芯及除尘装置 |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07163823A (ja) | 1993-12-15 | 1995-06-27 | Ngk Insulators Ltd | 多孔質セラミックハニカムフィルタ |
JPH08931A (ja) | 1994-06-21 | 1996-01-09 | Ngk Insulators Ltd | 排ガスフィルタおよびそれを使用した排ガス処理装置 |
JPH0977573A (ja) * | 1995-07-12 | 1997-03-25 | Denso Corp | ハニカム構造体及びその製造方法 |
JP2000279729A (ja) * | 1999-03-30 | 2000-10-10 | Ibiden Co Ltd | セラミックフィルタユニット及びその製造方法、セラミックフィルタ |
WO2001015877A1 (fr) | 1999-08-30 | 2001-03-08 | Ngk Insulators, Ltd. | Structure en nid d'abeille de paroi ondulee et procede de production de celle-ci |
JP2001340718A (ja) * | 2000-06-02 | 2001-12-11 | Ngk Insulators Ltd | ハニカムフィルタ用基材及びその製造方法 |
JP2002119871A (ja) * | 2000-10-17 | 2002-04-23 | Kanegafuchi Chem Ind Co Ltd | 新規な固定化触媒及びその製造方法 |
JP2002326879A (ja) * | 2001-03-01 | 2002-11-12 | Ngk Insulators Ltd | セラミックス構造体の製造方法 |
JP2003040687A (ja) * | 2000-06-30 | 2003-02-13 | Ngk Insulators Ltd | ハニカムセラミックス構造体とその製造方法 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004000901A (ja) * | 2002-03-29 | 2004-01-08 | Ngk Insulators Ltd | 多孔質ハニカム構造体 |
JP3855267B2 (ja) | 2002-06-17 | 2006-12-06 | トヨタ自動車株式会社 | 排ガス浄化用触媒及びその製造方法 |
JP2005095884A (ja) * | 2003-08-29 | 2005-04-14 | Hitachi Metals Ltd | セラミックハニカム構造体及びセラミックハニカム構造体押出成形用坏土 |
JP5185616B2 (ja) * | 2005-03-10 | 2013-04-17 | 日本碍子株式会社 | ハニカム構造体 |
-
2007
- 2007-09-27 EP EP07828620.0A patent/EP2070576B1/en active Active
- 2007-09-27 US US12/303,466 patent/US7833606B2/en active Active
- 2007-09-27 WO PCT/JP2007/068874 patent/WO2008047558A1/ja active Application Filing
- 2007-09-27 JP JP2008539719A patent/JP5315997B2/ja active Active
- 2007-09-27 CN CN2007800207842A patent/CN101460230B/zh active Active
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07163823A (ja) | 1993-12-15 | 1995-06-27 | Ngk Insulators Ltd | 多孔質セラミックハニカムフィルタ |
JPH08931A (ja) | 1994-06-21 | 1996-01-09 | Ngk Insulators Ltd | 排ガスフィルタおよびそれを使用した排ガス処理装置 |
JPH0977573A (ja) * | 1995-07-12 | 1997-03-25 | Denso Corp | ハニカム構造体及びその製造方法 |
JP2000279729A (ja) * | 1999-03-30 | 2000-10-10 | Ibiden Co Ltd | セラミックフィルタユニット及びその製造方法、セラミックフィルタ |
WO2001015877A1 (fr) | 1999-08-30 | 2001-03-08 | Ngk Insulators, Ltd. | Structure en nid d'abeille de paroi ondulee et procede de production de celle-ci |
JP2001340718A (ja) * | 2000-06-02 | 2001-12-11 | Ngk Insulators Ltd | ハニカムフィルタ用基材及びその製造方法 |
JP2003040687A (ja) * | 2000-06-30 | 2003-02-13 | Ngk Insulators Ltd | ハニカムセラミックス構造体とその製造方法 |
JP2002119871A (ja) * | 2000-10-17 | 2002-04-23 | Kanegafuchi Chem Ind Co Ltd | 新規な固定化触媒及びその製造方法 |
JP2002326879A (ja) * | 2001-03-01 | 2002-11-12 | Ngk Insulators Ltd | セラミックス構造体の製造方法 |
Non-Patent Citations (1)
Title |
---|
See also references of EP2070576A4 |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5344930B2 (ja) * | 2007-01-30 | 2013-11-20 | 京セラ株式会社 | ハニカム構造体および浄化装置 |
JP2012528784A (ja) * | 2009-06-05 | 2012-11-15 | コーニング インコーポレイテッド | コージライト形成バッチ材料及びその使用方法 |
CN107207370A (zh) * | 2015-02-05 | 2017-09-26 | 日本碍子株式会社 | 蜂窝结构体 |
WO2018207497A1 (ja) * | 2017-05-11 | 2018-11-15 | 株式会社キャタラー | 排ガス浄化触媒装置 |
JP2018187595A (ja) * | 2017-05-11 | 2018-11-29 | 株式会社キャタラー | 排ガス浄化触媒装置 |
US11149604B2 (en) | 2017-05-11 | 2021-10-19 | Cataler Corporation | Exhaust gas purification catalyst device |
WO2020194681A1 (ja) * | 2019-03-28 | 2020-10-01 | 日本碍子株式会社 | 多孔質複合体 |
JPWO2020194681A1 (ja) * | 2019-03-28 | 2020-10-01 | ||
CN113597334A (zh) * | 2019-03-28 | 2021-11-02 | 日本碍子株式会社 | 多孔质复合体 |
JP7198911B2 (ja) | 2019-03-28 | 2023-01-04 | 日本碍子株式会社 | 多孔質複合体 |
US11883770B2 (en) | 2019-03-28 | 2024-01-30 | Ngk Insulators, Ltd. | Porous composite |
JP2021159867A (ja) * | 2020-03-31 | 2021-10-11 | 日本碍子株式会社 | セラミックス製のフィルタ |
JP7234180B2 (ja) | 2020-03-31 | 2023-03-07 | 日本碍子株式会社 | セラミックス製のフィルタ |
Also Published As
Publication number | Publication date |
---|---|
JPWO2008047558A1 (ja) | 2010-02-25 |
EP2070576A4 (en) | 2012-05-09 |
CN101460230B (zh) | 2012-02-01 |
CN101460230A (zh) | 2009-06-17 |
EP2070576B1 (en) | 2014-03-19 |
US7833606B2 (en) | 2010-11-16 |
US20090142543A1 (en) | 2009-06-04 |
JP5315997B2 (ja) | 2013-10-16 |
EP2070576A1 (en) | 2009-06-17 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO2008047558A1 (en) | Ceramic honeycomb structure and process for producing ceramic honeycomb structure | |
US6984253B2 (en) | Honeycomb filter | |
US7037567B2 (en) | Honeycomb structure | |
US7138003B2 (en) | Honeycomb structure | |
JP4495152B2 (ja) | ハニカム構造体及びその製造方法 | |
JP2011506093A (ja) | 非対称六角形の流路を有するガス濾過構造 | |
US20060168908A1 (en) | Honeycomb structural body and method of manufacturing the same | |
CN101389392B (zh) | 陶瓷蜂窝式过滤器 | |
US7670664B2 (en) | Honeycomb structure body | |
US20060280905A1 (en) | Honeycomb structure | |
JP5344930B2 (ja) | ハニカム構造体および浄化装置 | |
JP2011509816A (ja) | 非対称六角形の流路を有するガス濾過構造 | |
JP6068274B2 (ja) | ハニカム構造体 | |
JP7505657B2 (ja) | 金型 | |
JP2005144250A (ja) | ハニカム構造体 | |
US20090246457A1 (en) | Honeycomb structure | |
JP5877740B2 (ja) | 接合型ハニカムフィルタ | |
JP2011509817A (ja) | 凹面又は凸面の六角形の流路を有するガス濾過構造 | |
JP3935159B2 (ja) | セラミックハニカムフィルタ | |
JP5242213B2 (ja) | ハニカム構造体 | |
US20110167806A1 (en) | Particle filter devices | |
JP7002388B2 (ja) | ハニカム構造体 | |
JP6059181B2 (ja) | ハニカム構造体 | |
WO2005079165A2 (ja) | ハニカム構造体及び排気ガス浄化装置 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
WWE | Wipo information: entry into national phase |
Ref document number: 200780020784.2 Country of ref document: CN |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 07828620 Country of ref document: EP Kind code of ref document: A1 |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2008539719 Country of ref document: JP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2007828620 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 12303466 Country of ref document: US |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
ENP | Entry into the national phase |
Ref document number: PI0713751 Country of ref document: BR Kind code of ref document: A2 Effective date: 20081210 |