WO2008047321B1 - Procédé de fabrication d'hydrogene par décomposition directe de gaz naturel et de gaz de petrole liquefié (lpg) - Google Patents

Procédé de fabrication d'hydrogene par décomposition directe de gaz naturel et de gaz de petrole liquefié (lpg)

Info

Publication number
WO2008047321B1
WO2008047321B1 PCT/IB2007/054240 IB2007054240W WO2008047321B1 WO 2008047321 B1 WO2008047321 B1 WO 2008047321B1 IB 2007054240 W IB2007054240 W IB 2007054240W WO 2008047321 B1 WO2008047321 B1 WO 2008047321B1
Authority
WO
WIPO (PCT)
Prior art keywords
nickel
iron
production method
hydrogen production
catalyst
Prior art date
Application number
PCT/IB2007/054240
Other languages
English (en)
Other versions
WO2008047321A1 (fr
Inventor
Rafig Alibeyli
Beycan Ibrahimoglu
Sadig Guliyev
Original Assignee
Vestel Elekt Sanayi Ve Ticaret
Rafig Alibeyli
Beycan Ibrahimoglu
Sadig Guliyev
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Vestel Elekt Sanayi Ve Ticaret, Rafig Alibeyli, Beycan Ibrahimoglu, Sadig Guliyev filed Critical Vestel Elekt Sanayi Ve Ticaret
Priority to EP07826782A priority Critical patent/EP2076332A1/fr
Publication of WO2008047321A1 publication Critical patent/WO2008047321A1/fr
Publication of WO2008047321B1 publication Critical patent/WO2008047321B1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
    • C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
    • C01B3/26—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0266—Processes for making hydrogen or synthesis gas containing a decomposition step
    • C01B2203/0277—Processes for making hydrogen or synthesis gas containing a decomposition step containing a catalytic decomposition step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C01B2203/1058—Nickel catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

L'invention concerne un catalyseur nickel-fer sur un oxyde d'aluminium gamma qui est préparé au moyen d'une approche d'adsorption à multiples étapes dans un procédé de fabrication d'hydrogène par décomposition directe de gaz naturel et de gaz de pétrole liquéfié. Des solutions aqueuses de sels de nitrate de nickel et de fer sont adsorbées ensemble sur la surface d'aluminium gamma dans la préparation du catalyseur utilisé dans ce procédé, le rapport en poids de nickel et de fer sur la surface de catalyseur étant 1 : 1, et leur poids total étant de 20-40 % en poids. La température de ce procédé varie entre 550°C et 650°C.
PCT/IB2007/054240 2006-10-19 2007-10-18 Procédé de fabrication d'hydrogene par décomposition directe de gaz naturel et de gaz de petrole liquefié (lpg) WO2008047321A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP07826782A EP2076332A1 (fr) 2006-10-19 2007-10-18 Procédé de fabrication d'hydrogene par décomposition directe de gaz naturel et de gaz de petrole liquefié (lpg)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
TR2006/05865A TR200605865A2 (tr) 2006-10-19 2006-10-19 Doğal gaz ve lpg'nin direkt ayrışması ile hidrojen üretimi yöntemi
TR2006/05865 2006-10-19

Publications (2)

Publication Number Publication Date
WO2008047321A1 WO2008047321A1 (fr) 2008-04-24
WO2008047321B1 true WO2008047321B1 (fr) 2008-07-24

Family

ID=39099850

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2007/054240 WO2008047321A1 (fr) 2006-10-19 2007-10-18 Procédé de fabrication d'hydrogene par décomposition directe de gaz naturel et de gaz de petrole liquefié (lpg)

Country Status (4)

Country Link
EP (1) EP2076332A1 (fr)
RU (1) RU2446010C2 (fr)
TR (1) TR200605865A2 (fr)
WO (1) WO2008047321A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110721691A (zh) * 2019-11-12 2020-01-24 中南大学 一种cfan催化剂及其制备和在甲烷制氢中的应用

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102010049957B4 (de) * 2010-10-04 2013-11-14 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Abgasreinigungsvorrichtung, Verfahren zur Abgasreinigung sowie Pyrolysereaktor
RU2526040C1 (ru) * 2013-06-20 2014-08-20 Федеральное государственное бюджетное учреждение "Национальный исследовательский центр "Курчатовский институт" Способ получения моторного топлива
RU2559878C1 (ru) * 2014-06-10 2015-08-20 Федеральное государственное бюджетное учреждение науки Институт химии твердого тела Уральского отделения Российской академии наук Никель-алюминиевая шпинель в качестве катализатора парциального окисления метана и способ ее получения
RU2651195C1 (ru) * 2017-03-10 2018-04-18 Федеральное государственное бюджетное образовательное учреждение высшего образования "Тюменский индустриальный университет" (ТИУ) Способ получения синтез-газа
US20210114003A1 (en) 2017-04-14 2021-04-22 King Abdullah University Of Science And Technology Treated iron ore catalysts for production of hydrogen and graphene
US11890596B2 (en) * 2021-09-07 2024-02-06 United Arab Emirates University Coking resistant NiFeAl catalyst for partial oxidation of methane to synthesis gas

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2704774B1 (fr) * 1993-05-06 1995-07-21 Inst Francais Du Petrole Procédé de préparation de catalyseurs applicables à la déshydrogénation.
RU2204434C2 (ru) * 2001-05-08 2003-05-20 Институт катализа им. Г.К. Борескова СО РАН Катализатор и способ получения смеси водорода и оксида углерода
US6875417B1 (en) * 2001-10-24 2005-04-05 University Of Kentucky Research Foundation Catalytic conversion of hydrocarbons to hydrogen and high-value carbon
EP1623957B1 (fr) * 2005-02-10 2008-02-06 Electrovac AG Procédé et dispositif pour la production d'hydrogène

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110721691A (zh) * 2019-11-12 2020-01-24 中南大学 一种cfan催化剂及其制备和在甲烷制氢中的应用
CN110721691B (zh) * 2019-11-12 2020-07-24 中南大学 一种cfan催化剂及其制备和在甲烷制氢中的应用

Also Published As

Publication number Publication date
RU2009118631A (ru) 2010-11-27
WO2008047321A1 (fr) 2008-04-24
EP2076332A1 (fr) 2009-07-08
TR200605865A2 (tr) 2008-05-21
RU2446010C2 (ru) 2012-03-27

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