WO2008047321A1 - Procédé de fabrication d'hydrogene par décomposition directe de gaz naturel et de gaz de petrole liquefié (lpg) - Google Patents

Procédé de fabrication d'hydrogene par décomposition directe de gaz naturel et de gaz de petrole liquefié (lpg) Download PDF

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Publication number
WO2008047321A1
WO2008047321A1 PCT/IB2007/054240 IB2007054240W WO2008047321A1 WO 2008047321 A1 WO2008047321 A1 WO 2008047321A1 IB 2007054240 W IB2007054240 W IB 2007054240W WO 2008047321 A1 WO2008047321 A1 WO 2008047321A1
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WO
WIPO (PCT)
Prior art keywords
catalyst
natural gas
lpg
hydrogen production
direct decomposition
Prior art date
Application number
PCT/IB2007/054240
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English (en)
Other versions
WO2008047321B1 (fr
Inventor
Rafig Alibeyli
Beycan Ibrahimoglu
Sadig Guliyev
Original Assignee
Vestel Elektronik Sanayi Ve Ticaret A.S.
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Publication date
Application filed by Vestel Elektronik Sanayi Ve Ticaret A.S. filed Critical Vestel Elektronik Sanayi Ve Ticaret A.S.
Priority to EP07826782A priority Critical patent/EP2076332A1/fr
Publication of WO2008047321A1 publication Critical patent/WO2008047321A1/fr
Publication of WO2008047321B1 publication Critical patent/WO2008047321B1/fr

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
    • C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
    • C01B3/26—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0266—Processes for making hydrogen or synthesis gas containing a decomposition step
    • C01B2203/0277—Processes for making hydrogen or synthesis gas containing a decomposition step containing a catalytic decomposition step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C01B2203/1058—Nickel catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane

Definitions

  • the present invention relates to producing hydrogen in the petrochemistry field, particularly from natural gas or LPG (Liquefied Petroleum Gas) or from other gas mixtures containing the C 1 -C 4 hydrocarbons.
  • the hydrogen production approach according to the present invention is achieved by making use of Ni-Fe/ ⁇ -AI 2 O 3 type catalysts with a higher activity and a special preparation method.
  • Both of such methods are conducted at temperatures ranging from 750 0 C to 800 0 C and under low pressure levels. Both such methods bring about the following significant drawbacks: conducting the process at high temperatures; formation of CO besides H 2 in the process; provision of a special catalytic conversion system to completely convert CO to CO 2 .
  • the approach of the background art closest to the present invention is the process whereby methane is catalytically decomposed directly to hydrogen and carbon.
  • the basic drawback of this process is the high temperature (700-750 0 C) requirement to provide a high CH 4 conversion yield, whereas the others may be listed as following: - higher energy costs; material selection difficulty for the reactor; an increase in the amount of coke that forms and a decrease in the fixed working period without oxidative regeneration of the catalysts; shortening of the general working life of catalysts.
  • the present invention provides a high-yield hydrogen production approach at relatively lower temperatures by means of direct decomposition of natural gas, LPG, or other gas mixtures having a C r C 4 -hydrocarbon content.
  • This approach is achieved by making use of Ni-Fe/ ⁇ - AI 2 O 3 type catalysts with a higher activity and a special preparation method.
  • the subject process is as following.
  • the catalyst for the direct decomposition of methane is prepared according to the subject process.
  • industrial-type Y-AI 2 O 3 is used as the catalyst carrier, and Ni and Fe are employed as active metals.
  • concentrations of Ni and Fe each vary between 5% and 20% on the catalyst's surface.
  • the catalysts are prepared by adsorbing on the carrier surface the aqueous solutions of metal salts (typically the nitrate salts) in a multi-step method.
  • the adsorption phase is conducted at the room temperature.
  • the carrier is subjected to adsorption, the solution is evaporated and the catalyst dried under air.
  • the calcination of catalyst is carried out in an oven under air.
  • Ni-Fe/ ⁇ -AI 2 O 3 catalyst used in this invention has the following advantages as compared to known catalysts used for the direct decomposition of natural gas (or methane): the aqueous solutions of Ni and Fe salts are adsorbed in a multi-step manner on the carrier in order to have a more homogeneous distribution of such active metals on the carrier surface;
  • Ni and Fe salts are adsorbed together onto the carrier surface; and the catalyst is subjected to calcination after each interim adsorption step conducted on the carrier surface.
  • Any such prepared catalysts are used in the direct decomposition process of natural gas or LPG according to the present invention.
  • the process is conducted under atmosphere pressure and at 550-650 0 C temperature.
  • the volumetric flow rate of natural gas or LPG used as raw materials in this process varies between 720 hour “1 and 4320 hour “1 .
  • the conversion rate of methane in the natural gas to hydrogen varies between 66 to 91% according to the conditions of this process.
  • the contents of the natural gas and LPG used as inputs in the process, and the gaseous products as the output of the process are analyzed by means of Gas Chromatography.
  • the amount and character of the coke formed on the catalyst surface as a result of directly decomposing CH 4 according to this process are studied by the Differential Thermal-Gravimetric Analysis method.
  • Ni + 5% Fe/ ⁇ -AI 2 O 3 catalyst is prepared for use in the subject process. For this reason, 3.12 g Ni(NO 3 ) 2 .6H 2 O and 4.56 g Fe(NO 3 ) 3 .9H 2 O salts are dissolved in 10 ml distilled water and the resulting solution is adsorbed in two steps under mixing for 12 hours on the surface of Y-AI 2 O 3 (10 g), which is previously dried under 150 0 C for 4 hours.
  • the solution is evaporated and the catalyst is dried under air at 150 0 C for 6 hours and subjected to calcination at 500°C for 4 hours, then in the second step following adsorption, the solution is evaporated again and the catalyst dried under air at 15O 0 C. Then, the catalyst is subjected to the final calcination step under air at 75O 0 C for 4 hours. In the calcination steps, the temperature is raised by 150°C/hour "1 starting from 150°C.
  • a 2.5 g aliquot is taken from the prepared catalyst and used for directly decomposing the natural gas.
  • the content of the natural gas used as raw material in this process is as following (% by volume): H 2 - 0.14, CH 4 - 87.84, C 2 H 6 - 4.16, C 3 - 1.19, C 4 -C 5 - 0.03, N 2 - 5.6, O 2 - 0.51 , CO 2 - 0.43.
  • the process is conducted in a continuous experiment system with a fixed bed quarts reactor under atmosphere pressure at 65O 0 C and 30 ml/min gas flow rate (720 hour "1 ).
  • the reactor's inner diameter and length are 2.2 cm and 20 cm, respectively. After the gaseous products are put out of the reactor, they are cooled in a water cooler and analyzed by means of GC. The result is as following:
  • Ni + 10% Fe/ ⁇ -AI 2 O 3 catalyst is prepared for use in this process. Respectively 6.24 g and 9.12 g of Ni(NO 3 ) 2 .6H 2 O and Fe(NO 3 ) 3 .9H 2 O salts are used in the catalyst's synthesis. The adsorption of aqueous solutions of metal salts on the catalyst surface is conducted at three steps.
  • Ni + 20% Fe/ ⁇ -AI 2 O 3 catalyst is prepared for use in this process. Respectively 12.48 g and 18.24 g of Ni(NO 3 ) 2 .6H 2 O and Fe(NO 3 ) 3 .9H 2 O salts are used in the catalyst's synthesis. The adsorption of aqueous solutions of metal salts on the catalyst surface is conducted at four steps in the preparation of the catalyst.
  • 20% Ni + 20% Fe/ ⁇ -Al 2 O 3 catalyst is prepared for use in this process.
  • the preparation of the catalyst is conducted by means of a 4-step adsorption method.
  • the direct decomposition process is conducted at 550°C temperature.
  • 20% Ni + 20% Fe/ ⁇ -AI 2 O 3 catalyst is prepared for use in the subject process.
  • LPG with the following content (% by volume) is used as the raw material in this process: H 2 - 0.2, CH 4 - 0.6, C 2 H 6 - 15.99, C 3 - 50.98, C 4 - 29.15, C 5 - 0.19, N 2 - 1.78, O 2 - 1.11.
  • the temperature of the direct decomposition process is 650 0 C and the flow rate of the natural gas is 30 ml/min (720 hour "1 ).

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

L'invention concerne un catalyseur nickel-fer sur un oxyde d'aluminium gamma qui est préparé au moyen d'une approche d'adsorption à multiples étapes dans un procédé de fabrication d'hydrogène par décomposition directe de gaz naturel et de gaz de pétrole liquéfié. Des solutions aqueuses de sels de nitrate de nickel et de fer sont adsorbées ensemble sur la surface d'aluminium gamma dans la préparation du catalyseur utilisé dans ce procédé, le rapport en poids de nickel et de fer sur la surface de catalyseur étant 1 : 1, et leur poids total étant de 20-40 % en poids. La température de ce procédé varie entre 550°C et 650°C.
PCT/IB2007/054240 2006-10-19 2007-10-18 Procédé de fabrication d'hydrogene par décomposition directe de gaz naturel et de gaz de petrole liquefié (lpg) WO2008047321A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP07826782A EP2076332A1 (fr) 2006-10-19 2007-10-18 Procédé de fabrication d'hydrogene par décomposition directe de gaz naturel et de gaz de petrole liquefié (lpg)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
TR2006/05865A TR200605865A2 (tr) 2006-10-19 2006-10-19 Doğal gaz ve lpg'nin direkt ayrışması ile hidrojen üretimi yöntemi
TR2006/05865 2006-10-19

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WO2008047321A1 true WO2008047321A1 (fr) 2008-04-24
WO2008047321B1 WO2008047321B1 (fr) 2008-07-24

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EP (1) EP2076332A1 (fr)
RU (1) RU2446010C2 (fr)
TR (1) TR200605865A2 (fr)
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012045423A3 (fr) * 2010-10-04 2012-08-30 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Dispositif et procédé de purification de gaz d'échappement, catalyseur et réacteur de pyrolyse
WO2018189723A1 (fr) 2017-04-14 2018-10-18 King Abdullah University Of Science And Technology Catalyseurs de minerai de fer traités pour la production d'hydrogène et de graphène
US20230070707A1 (en) * 2021-09-07 2023-03-09 United Arab Emirates University NOVEL COKING RESISTANT NiFeAl CATALYST FOR PARTIAL OXIDATION OF METHANE TO SYNTHESIS GAS

Families Citing this family (4)

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RU2526040C1 (ru) * 2013-06-20 2014-08-20 Федеральное государственное бюджетное учреждение "Национальный исследовательский центр "Курчатовский институт" Способ получения моторного топлива
RU2559878C1 (ru) * 2014-06-10 2015-08-20 Федеральное государственное бюджетное учреждение науки Институт химии твердого тела Уральского отделения Российской академии наук Никель-алюминиевая шпинель в качестве катализатора парциального окисления метана и способ ее получения
RU2651195C1 (ru) * 2017-03-10 2018-04-18 Федеральное государственное бюджетное образовательное учреждение высшего образования "Тюменский индустриальный университет" (ТИУ) Способ получения синтез-газа
CN110721691B (zh) * 2019-11-12 2020-07-24 中南大学 一种cfan催化剂及其制备和在甲烷制氢中的应用

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EP0623385A1 (fr) * 1993-05-06 1994-11-09 Institut Francais Du Petrole Procédé de préparation de catalyseurs applicables à la déshydrogénation
US6875417B1 (en) * 2001-10-24 2005-04-05 University Of Kentucky Research Foundation Catalytic conversion of hydrocarbons to hydrogen and high-value carbon
EP1623957A1 (fr) * 2005-02-10 2006-02-08 Electrovac, Fabrikation elektrotechnischer Spezialartikel Gesellschaft m.b.H. Procédé et dispositif pour la production d'hydrogène

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RU2204434C2 (ru) * 2001-05-08 2003-05-20 Институт катализа им. Г.К. Борескова СО РАН Катализатор и способ получения смеси водорода и оксида углерода

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EP0623385A1 (fr) * 1993-05-06 1994-11-09 Institut Francais Du Petrole Procédé de préparation de catalyseurs applicables à la déshydrogénation
US6875417B1 (en) * 2001-10-24 2005-04-05 University Of Kentucky Research Foundation Catalytic conversion of hydrocarbons to hydrogen and high-value carbon
EP1623957A1 (fr) * 2005-02-10 2006-02-08 Electrovac, Fabrikation elektrotechnischer Spezialartikel Gesellschaft m.b.H. Procédé et dispositif pour la production d'hydrogène

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RESHETENKO T V ET AL: "Coprecipitated iron-containing catalysts (Fe-Al2O3, Fe-Co-Al2O3, Fe-Ni-Al2O3) for methane decomposition at moderate temperatures - Part II. Evolution of the catalysts in reaction", APPLIED CATALYSIS A: GENERAL, ELSEVIER SCIENCE, AMSTERDAM, NL, vol. 270, no. 1-2, 30 August 2004 (2004-08-30), pages 87 - 99, XP004518321, ISSN: 0926-860X *
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012045423A3 (fr) * 2010-10-04 2012-08-30 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Dispositif et procédé de purification de gaz d'échappement, catalyseur et réacteur de pyrolyse
US9074508B2 (en) 2010-10-04 2015-07-07 Fraunhofer-Gesellschaft Zur Foerderung Der Angewandten Forschung E.V. Exhaust-gas purification device, method for exhaust-gas purification, catalytic converter and pyrolysis reactor
WO2018189723A1 (fr) 2017-04-14 2018-10-18 King Abdullah University Of Science And Technology Catalyseurs de minerai de fer traités pour la production d'hydrogène et de graphène
US20230070707A1 (en) * 2021-09-07 2023-03-09 United Arab Emirates University NOVEL COKING RESISTANT NiFeAl CATALYST FOR PARTIAL OXIDATION OF METHANE TO SYNTHESIS GAS
US11890596B2 (en) * 2021-09-07 2024-02-06 United Arab Emirates University Coking resistant NiFeAl catalyst for partial oxidation of methane to synthesis gas

Also Published As

Publication number Publication date
TR200605865A2 (tr) 2008-05-21
RU2446010C2 (ru) 2012-03-27
RU2009118631A (ru) 2010-11-27
WO2008047321B1 (fr) 2008-07-24
EP2076332A1 (fr) 2009-07-08

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