WO2007060089A3 - Alpha-(beta-ketocarbonyl)-funktionelle organosiliciumverbindungen und deren herstellung - Google Patents

Alpha-(beta-ketocarbonyl)-funktionelle organosiliciumverbindungen und deren herstellung Download PDF

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Publication number
WO2007060089A3
WO2007060089A3 PCT/EP2006/068162 EP2006068162W WO2007060089A3 WO 2007060089 A3 WO2007060089 A3 WO 2007060089A3 EP 2006068162 W EP2006068162 W EP 2006068162W WO 2007060089 A3 WO2007060089 A3 WO 2007060089A3
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WO
WIPO (PCT)
Prior art keywords
radical
compounds
ketocarbonyl
production
contain
Prior art date
Application number
PCT/EP2006/068162
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English (en)
French (fr)
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WO2007060089A2 (de
Inventor
Christian Herzig
Original Assignee
Wacker Chemie Ag
Christian Herzig
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Wacker Chemie Ag, Christian Herzig filed Critical Wacker Chemie Ag
Publication of WO2007060089A2 publication Critical patent/WO2007060089A2/de
Publication of WO2007060089A3 publication Critical patent/WO2007060089A3/de

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/38—Polysiloxanes modified by chemical after-treatment
    • C08G77/382—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon
    • C08G77/388—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0834—Compounds having one or more O-Si linkage
    • C07F7/0838—Compounds with one or more Si-O-Si sequences
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/38—Polysiloxanes modified by chemical after-treatment

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Silicon Polymers (AREA)

Abstract

Beschrieben werden neue -(-Ketocarbonyl)-funktionelle Organosiliciumverbindungen, die mindestens einen Si-gebundenen Rest B ausgewählt aus der Gruppe der allgemeinen Formeln -CR12-Y-C(=O)-CHR3-C(=O)-CH2R3 (I) und -CR12-Y-C(=O)-CR3=C(-OH)-CH2R3 (II) enthalten, wobei ein Sauerstoffatom oder ein Rest der Formel -NR2- ist, Y R1 ein Wasserstoffatom oder einen Alkyl-, Cycloalkyl-, Aryl- oder Aralkylrest mit 1 bis 30 Kohlenstoffatomen bedeutet, R2 ein Rest R1 ist oder einen organischen Rest, der ein oder mehrere Heteroatome ausgewählt aus der Gruppe von B, N, O, P, S, Si, Ti, F, Cl, Br und J enthalten kann, bedeutet, 3 ein Rest R1 ist, und R ein Verfahren zu deren Herstellung , bei dem Diketene (1) der allgemeinen Formel R3-CH=C-CHR3-C=O (III), O oder deren Derivate, mit Organosiliciumverbindungen (2), die mindestens einen Si- -CR12-YH gebundenen Rest A der allgemeinen Formel (IV) je Molekül enthalten, wobei Y, R1 und R3 die oben dafür angegebene Bedeutung haben, gegebenenfalls in Gegenwart einer oder mehrerer organischen Verbindungen (3), die die Reaktion des Restes A in (2) mit - Ketocarbonylverbindungen verzögern oder verhindern, umgesetzt werden.
PCT/EP2006/068162 2005-11-24 2006-11-07 Alpha-(beta-ketocarbonyl)-funktionelle organosiliciumverbindungen und deren herstellung WO2007060089A2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102005056050A DE102005056050A1 (de) 2005-11-24 2005-11-24 Alpha-(beta-Ketocarbonyl)-funktionelle Organosiliciumverbindungen und deren Herstellung
DE102005056050.4 2005-11-24

Publications (2)

Publication Number Publication Date
WO2007060089A2 WO2007060089A2 (de) 2007-05-31
WO2007060089A3 true WO2007060089A3 (de) 2007-08-02

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PCT/EP2006/068162 WO2007060089A2 (de) 2005-11-24 2006-11-07 Alpha-(beta-ketocarbonyl)-funktionelle organosiliciumverbindungen und deren herstellung

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DE (1) DE102005056050A1 (de)
WO (1) WO2007060089A2 (de)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102006020815A1 (de) * 2006-05-04 2007-11-08 Wacker Chemie Ag Verfahren zur Herstellung von beta-Ketocarbonyl-funktionellen Organosiliciumverbindungen
DE102006020816A1 (de) * 2006-05-04 2007-11-08 Wacker Chemie Ag Organosiliciumverbindungen, die beta-Ketoamidgruppen und über Enamin-Bindungen gebundene organische Polymere enthalten, und Verfahren zu ihrer Herstellung
DE102006038062A1 (de) * 2006-08-16 2008-02-21 Wacker Chemie Ag Chelatpolymerisation
KR102296683B1 (ko) 2016-11-16 2021-09-01 와커 헤미 아게 Ｂ-케토카르보닐-작용성 오르가노실리콘 화합물의 분산액
CN111094526B (zh) * 2017-12-06 2021-08-06 瓦克化学股份公司 β-酮羰基官能化的有机硅化合物的乳液

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU555104A1 (ru) * 1975-07-21 1977-04-25 Способ получени -кремнийзамещенных амидов оксикислот
EP0010130A1 (de) * 1978-08-28 1980-04-30 Bayer Ag Sila-substituierte 1,4-Dihydropyridinderivate, Verfahren zu ihrer Herstellung, Arzneimittel und Verfahren zu deren Herstellung

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU555104A1 (ru) * 1975-07-21 1977-04-25 Способ получени -кремнийзамещенных амидов оксикислот
EP0010130A1 (de) * 1978-08-28 1980-04-30 Bayer Ag Sila-substituierte 1,4-Dihydropyridinderivate, Verfahren zu ihrer Herstellung, Arzneimittel und Verfahren zu deren Herstellung

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
DATABASE BEILSTEIN [online] BEILSTEIN INSTITUTE FOR ORGANIC CHEMISTRY, FRANKFURT-MAIN, DE; XP002432299, retrieved from XFIRE Database accession no. Reaction ID 1517264 *
DATABASE BEILSTEIN [online] BEILSTEIN INSTITUTE FOR ORGANIC CHEMISTRY, FRANKFURT-MAIN, DE; XP002432300, retrieved from XFIRE Database accession no. BRN 2414120 *
MIRONOV, V.F. ET AL., J. GEN. CHEM. USSR, vol. 37, 1967, pages 1821 - 1823 *
TACKE R. ET AL.: "Sila-Analoga", ZEITSCHRIFT FÜR NATURFORSCHUNG B ANORG. CHEM., vol. 35, no. 4, 1980, pages 494 - 501, XP009083303 *
WEE A G H ET AL: "The rhodium(II)-catalyzed reaction of N-bis(trimethylsilylmethyl)diazoamides: steric, electronic and conformational effects", TETRAHEDRON LETTERS, ELSEVIER, AMSTERDAM, NL, vol. 43, no. 35, 26 August 2002 (2002-08-26), pages 6173 - 6176, XP004373267, ISSN: 0040-4039 *
WEE, A. ET AL.: "The Bis(trimethylsilyl)methyl Group as an Effective N-Protecting Group and Site-Selective Control Element in Rhodium(II)-Catalyzed Reaction of Diazoamides", J. ORG. CHEM., vol. 70, no. 21, 14 October 2005 (2005-10-14), pages 8372 - 8380, XP002432277 *

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Publication number Publication date
WO2007060089A2 (de) 2007-05-31
DE102005056050A1 (de) 2007-05-31

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