WO2005088657A3 - Procede de fabrication d’electrode, electrode ainsi obtenue et supercondensateur la comprenant - Google Patents
Procede de fabrication d’electrode, electrode ainsi obtenue et supercondensateur la comprenant Download PDFInfo
- Publication number
- WO2005088657A3 WO2005088657A3 PCT/FR2005/000525 FR2005000525W WO2005088657A3 WO 2005088657 A3 WO2005088657 A3 WO 2005088657A3 FR 2005000525 W FR2005000525 W FR 2005000525W WO 2005088657 A3 WO2005088657 A3 WO 2005088657A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- electrode
- making
- including same
- resulting
- supercapacitor including
- Prior art date
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 3
- 239000002041 carbon nanotube Substances 0.000 abstract 1
- 229910021393 carbon nanotube Inorganic materials 0.000 abstract 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/26—Electrodes characterised by their structure, e.g. multi-layered, porosity or surface features
- H01G11/28—Electrodes characterised by their structure, e.g. multi-layered, porosity or surface features arranged or disposed on a current collector; Layers or phases between electrodes and current collectors, e.g. adhesives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y10/00—Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/32—Carbon-based
- H01G11/36—Nanostructures, e.g. nanofibres, nanotubes or fullerenes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/32—Carbon-based
- H01G11/38—Carbon pastes or blends; Binders or additives therein
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/84—Processes for the manufacture of hybrid or EDL capacitors, or components thereof
- H01G11/86—Processes for the manufacture of hybrid or EDL capacitors, or components thereof specially adapted for electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1393—Processes of manufacture of electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Materials Engineering (AREA)
- Nanotechnology (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Mathematical Physics (AREA)
- Theoretical Computer Science (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Carbon And Carbon Compounds (AREA)
Abstract
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA002558511A CA2558511A1 (fr) | 2004-03-09 | 2005-03-04 | Procede de fabrication d'electrode, electrode ainsi obtenue et supercondensateur la comprenant |
CN2005800077604A CN1934665B (zh) | 2004-03-09 | 2005-03-04 | 电极的制造方法、所得到的电极和包括该电极的超电容器 |
JP2007502367A JP4754553B2 (ja) | 2004-03-09 | 2005-03-04 | 電極の製造方法と、得られた電極と、この電極を含むスーパーコンデンサ |
EP05736960A EP1726023A2 (fr) | 2004-03-09 | 2005-03-04 | PROCEDE DE FABRICATION D’ELECTRODE, ELECTRODE AINSI OBTENUE ET SUPERCONDENSATEUR LA COMPRENANT |
US10/590,298 US7532454B2 (en) | 2004-03-09 | 2005-03-04 | Method for making an electrode, resulting electrode and supercapacitor including same |
KR1020067017983A KR101046895B1 (ko) | 2004-03-09 | 2005-03-04 | 전극 제조 방법, 그 방법으로 제조한 전극 및 그 전극을포함하는 수퍼커패시터 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0402437 | 2004-03-09 | ||
FR0402437A FR2867600B1 (fr) | 2004-03-09 | 2004-03-09 | Procede de fabrication d'electrode, electrode ainsi obtenue et supercondensateur la comprenant |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2005088657A2 WO2005088657A2 (fr) | 2005-09-22 |
WO2005088657A3 true WO2005088657A3 (fr) | 2006-02-02 |
Family
ID=34896400
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FR2005/000525 WO2005088657A2 (fr) | 2004-03-09 | 2005-03-04 | Procede de fabrication d’electrode, electrode ainsi obtenue et supercondensateur la comprenant |
Country Status (8)
Country | Link |
---|---|
US (1) | US7532454B2 (fr) |
EP (1) | EP1726023A2 (fr) |
JP (1) | JP4754553B2 (fr) |
KR (1) | KR101046895B1 (fr) |
CN (1) | CN1934665B (fr) |
CA (1) | CA2558511A1 (fr) |
FR (1) | FR2867600B1 (fr) |
WO (1) | WO2005088657A2 (fr) |
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US7972697B2 (en) * | 2005-01-26 | 2011-07-05 | Honda Motor Co., Ltd. | Electrochemical activation of capacitor material |
FR2901156B1 (fr) * | 2006-05-16 | 2009-01-23 | Arkema Sa | Composite catalytique a base de charbon actif catalytique et nanotubes de carbone, procede de fabrication, electrode et supercondensateur comprenant le composite catalytique |
JP4706975B2 (ja) * | 2006-07-10 | 2011-06-22 | 清水建設株式会社 | 電気二重層キャパシタ用炭素電極及び電気二重層キャパシタ用炭素電極の製造方法 |
US8284539B2 (en) * | 2006-08-02 | 2012-10-09 | Ada Technologies, Inc. | High performance ultracapacitors with carbon nanomaterials and ionic liquids |
JP2010503214A (ja) * | 2006-09-01 | 2010-01-28 | バッテル メモリアル インスティテュート | カーボンナノチューブのナノコンポジット、カーボンナノチューブのナノコンポジットを作製する方法、およびナノコンポジットを含むデバイス |
KR100915968B1 (ko) * | 2007-01-29 | 2009-09-10 | (주)썬텔 | 탄소재료-탄소나노섬유 복합 소재를 전극 재료로 사용한전기이중층 캐패시터 |
FR2912554A1 (fr) * | 2007-02-12 | 2008-08-15 | Arkema France | Electrode comprenant au moins un nitroxyde et des nanotubes de carbone |
DE602007006152D1 (de) * | 2007-02-16 | 2010-06-10 | Centre Nat Rech Scient | Verbundstoff mit karbonisierten Biopolymeren und Kohlenstoffnanoröhren |
WO2009120872A2 (fr) * | 2008-03-26 | 2009-10-01 | Ada Technologies, Inc. | Batteries de haute performance avec nanomatériaux de carbone et liquides ioniques |
GB2472554B (en) * | 2008-05-05 | 2012-12-05 | Ada Technologies Inc | High performance carbon nanocomposites for ultracapacitors |
CN102187413B (zh) | 2008-08-15 | 2013-03-20 | 加利福尼亚大学董事会 | 电化学储能用分级结构纳米线复合物 |
CN101685710B (zh) * | 2008-09-26 | 2012-07-04 | 通用电气公司 | 制备组合物、包含组合物的薄片及包含薄片的电极的方法 |
CA2758568A1 (fr) | 2009-04-24 | 2010-10-28 | Applied Nanostructured Solutions, Llc | Composite et revetement de blindage contre les emi a base de cnt |
US9111658B2 (en) | 2009-04-24 | 2015-08-18 | Applied Nanostructured Solutions, Llc | CNS-shielded wires |
JP5744008B2 (ja) | 2009-04-27 | 2015-07-01 | アプライド ナノストラクチャード ソリューションズ リミテッド ライアビリティー カンパニーApplied Nanostructuredsolutions, Llc | 複合材料構造体を除氷するためのcntベース抵抗加熱 |
KR101046098B1 (ko) * | 2009-07-17 | 2011-07-01 | 삼성전기주식회사 | 커패시터용 분극성 전극 및 이를 포함하는 전기 이중층 커패시터 |
US9469554B2 (en) * | 2009-07-29 | 2016-10-18 | General Electric Company | Bipolar electrode and supercapacitor desalination device, and methods of manufacture |
US9167736B2 (en) | 2010-01-15 | 2015-10-20 | Applied Nanostructured Solutions, Llc | CNT-infused fiber as a self shielding wire for enhanced power transmission line |
EP2543099A4 (fr) | 2010-03-02 | 2018-03-28 | Applied NanoStructured Solutions, LLC | Dispositifs électriques enroulés en spirale contenant des matériaux d'électrode imprégnés de nanotubes de carbone et procédés et appareils pour la fabrication de ceux-ci |
EP2543052B1 (fr) | 2010-03-02 | 2019-11-27 | Applied NanoStructured Solutions, LLC | Dispositifs électriques contenant des fibres infusées aux nanotubes de carbone et procédés de production associés |
RU2419907C1 (ru) * | 2010-04-23 | 2011-05-27 | ЮГ Инвестмент Лтд. | Многоэлементный электрохимический конденсатор и способ его изготовления |
US8780526B2 (en) | 2010-06-15 | 2014-07-15 | Applied Nanostructured Solutions, Llc | Electrical devices containing carbon nanotube-infused fibers and methods for production thereof |
BR112012017246A2 (pt) | 2010-09-23 | 2016-03-22 | Applied Nanostructured Solutins Llc | fibra infundida por cnt como um fio autoblindado para linha de transmissão de energia aprimorada |
JP5789391B2 (ja) * | 2011-03-30 | 2015-10-07 | 日信工業株式会社 | カーボンナノファイバーを用いた電極用多孔質体、電極、電池、キャパシタ、水処理装置、油田装置用の耐熱筐体、油田装置及び電極用多孔質体の製造方法 |
TWI460238B (zh) | 2011-12-15 | 2014-11-11 | Ind Tech Res Inst | 自組塗裝塗料、散熱板及其製造方法 |
TWI466153B (zh) | 2011-12-15 | 2014-12-21 | Ind Tech Res Inst | 電容器及其製造方法 |
US9085464B2 (en) | 2012-03-07 | 2015-07-21 | Applied Nanostructured Solutions, Llc | Resistance measurement system and method of using the same |
JP6161328B2 (ja) * | 2012-05-18 | 2017-07-12 | Jsr株式会社 | 電極活物質、電極及び蓄電デバイス |
JP6161272B2 (ja) * | 2012-12-04 | 2017-07-12 | Jmエナジー株式会社 | 蓄電デバイス |
US9627691B2 (en) | 2013-02-07 | 2017-04-18 | Ada Technologies, Inc. | Metalized, three-dimensional structured oxygen cathode materials for lithium/air batteries and method for making and using the same |
US9613760B2 (en) * | 2014-06-12 | 2017-04-04 | Corning Incorporated | Energy storage device and methods for making and use |
FR3038610B1 (fr) * | 2015-07-07 | 2017-09-01 | Dreem | Composition polymerique et electrode pour un dispositif de mesure non-invasive de signaux electriques biologiques |
CN105304347A (zh) * | 2015-09-24 | 2016-02-03 | 山东润昇电源科技有限公司 | 一种柔性超级电容器电极及其制作方法 |
EP3249669A1 (fr) | 2016-05-25 | 2017-11-29 | Universiteit van Amsterdam | Supercondensateur et matériau carboné poreux dopé à l'azote |
RU2646531C1 (ru) * | 2016-09-23 | 2018-03-05 | Общество с ограниченной ответственностью "Фотоника РВ" | Суперконденсаторная ячейка |
KR102660440B1 (ko) * | 2016-12-02 | 2024-04-25 | 패스트캡 시스템즈 코포레이션 | 복합 전극 |
KR101998648B1 (ko) | 2017-11-03 | 2019-07-11 | 한국에너지기술연구원 | 슈퍼커패시터용 금속-실리사이드 나노선 기반 전극, 이 전극의 제조 방법, 이 전극을 사용한 슈퍼커패시터 및 이 슈퍼커패시터의 제조 방법 |
CN109786128B (zh) * | 2019-03-18 | 2021-04-30 | 新奥石墨烯技术有限公司 | 多孔碳/碳纳米管复合材料及其制备方法、电极和超级电容器 |
FR3098003B1 (fr) | 2019-06-26 | 2022-07-15 | Solvionic | Procédé et dispositif de fabrication d'électrodes pour un supercondensateur à base de liquide ionique et procédé de fabrication d'un tel supercondensateur |
US11557765B2 (en) | 2019-07-05 | 2023-01-17 | Fastcap Systems Corporation | Electrodes for energy storage devices |
US10981794B1 (en) * | 2020-03-24 | 2021-04-20 | Yazaki Corporation | Stable aqueous dispersion of carbon |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000124079A (ja) * | 1998-10-15 | 2000-04-28 | Tokin Corp | 電気二重層キャパシタ |
EP1146527A2 (fr) * | 2000-04-12 | 2001-10-17 | Iljin Nanotech Co., Ltd. | Electrode pour supercondensateur et sa méthode de fabrication |
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IL109497A (en) * | 1993-05-05 | 1998-02-22 | Hyperion Catalysis Int | Three-dimensional macroscopic clusters of randomly arranged charcoal fibrils and products containing these |
US5358801A (en) * | 1993-09-03 | 1994-10-25 | Valence Technology, Inc. | Solid electochemical cell of improved capacity and cycling capability having surfactant in vanadium oxide cathode mixture |
AU721291C (en) * | 1996-05-15 | 2003-02-27 | Hyperion Catalysis International, Inc. | Graphitic nanofibers in electrochemical capacitors |
EP0927778B1 (fr) * | 1997-12-04 | 2003-07-02 | Kashima Oil Co., Ltd. | Fibres de carbone activées et leurs utilisation dans des capaciteurs à double couches |
KR100459340B1 (ko) * | 1998-09-28 | 2004-12-04 | 하이페리온 커탤리시스 인터내셔널 인코포레이티드 | 전기화학적 축전기용 피브릴 합성전극 |
US6733925B2 (en) * | 2000-02-08 | 2004-05-11 | Shin-Kobe Electric Machinery Co., Ltd. | Non-aqueous electrolytic solution secondary battery with electrodes having a specific thickness and porosity |
EP1168389B1 (fr) * | 2000-06-27 | 2005-09-07 | Asahi Glass Co., Ltd. | Matériau de carbone activé, sa méthode de fabrication et condensateur électrique à double couche l'utilisant |
FR2817387B1 (fr) | 2000-11-27 | 2003-03-21 | Ceca Sa | Cellules de stockage d'energie a double couche electrochimique a haute densite d'energie et forte densite de puissance |
JP2002175837A (ja) * | 2000-12-06 | 2002-06-21 | Nisshinbo Ind Inc | 高分子ゲル電解質及び二次電池並びに電気二重層キャパシタ |
JP4294246B2 (ja) * | 2001-05-31 | 2009-07-08 | 新日本石油精製株式会社 | 電気二重層キャパシタ電極用炭素材料及びその製造方法並びに電気二重層キャパシタ及びその製造方法 |
JP3561780B2 (ja) * | 2002-01-29 | 2004-09-02 | 潤二 伊藤 | 分極性電極用電極合剤及びその製造方法並びに当該電極合剤を用いた分極性電極 |
US7061749B2 (en) * | 2002-07-01 | 2006-06-13 | Georgia Tech Research Corporation | Supercapacitor having electrode material comprising single-wall carbon nanotubes and process for making the same |
CN1315139C (zh) | 2002-07-12 | 2007-05-09 | 四川工业学院 | 碳纳米管复合电极超大容量电容器及其制造方法 |
JP3793751B2 (ja) * | 2002-11-29 | 2006-07-05 | 大同メタル工業株式会社 | 電気二重層コンデンサ用分極性電極の製造方法 |
-
2004
- 2004-03-09 FR FR0402437A patent/FR2867600B1/fr not_active Expired - Fee Related
-
2005
- 2005-03-04 US US10/590,298 patent/US7532454B2/en not_active Expired - Fee Related
- 2005-03-04 KR KR1020067017983A patent/KR101046895B1/ko not_active IP Right Cessation
- 2005-03-04 WO PCT/FR2005/000525 patent/WO2005088657A2/fr active Application Filing
- 2005-03-04 JP JP2007502367A patent/JP4754553B2/ja not_active Expired - Fee Related
- 2005-03-04 CN CN2005800077604A patent/CN1934665B/zh not_active Expired - Fee Related
- 2005-03-04 EP EP05736960A patent/EP1726023A2/fr not_active Withdrawn
- 2005-03-04 CA CA002558511A patent/CA2558511A1/fr not_active Abandoned
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000124079A (ja) * | 1998-10-15 | 2000-04-28 | Tokin Corp | 電気二重層キャパシタ |
EP1146527A2 (fr) * | 2000-04-12 | 2001-10-17 | Iljin Nanotech Co., Ltd. | Electrode pour supercondensateur et sa méthode de fabrication |
Non-Patent Citations (3)
Title |
---|
EMMENEGGER C ET AL: "Investigation of electrochemical double-layer (ECDL) capacitors electrodes based on carbon nanotubes and activated carbon materials", JOURNAL OF POWER SOURCES, ELSEVIER SEQUOIA S.A. LAUSANNE, CH, vol. 124, no. 1, 1 October 2003 (2003-10-01), pages 321 - 329, XP004454632, ISSN: 0378-7753 * |
FRACKOWIAK E ET AL: "Electrochemical storage of energy in carbon nanotubes and nanostructured carbons", CARBON, XX, XX, vol. 40, no. 10, August 2002 (2002-08-01), pages 1775 - 1787, XP004371677, ISSN: 0008-6223 * |
PATENT ABSTRACTS OF JAPAN vol. 2000, no. 07 29 September 2000 (2000-09-29) * |
Also Published As
Publication number | Publication date |
---|---|
KR20070005611A (ko) | 2007-01-10 |
FR2867600A1 (fr) | 2005-09-16 |
CN1934665B (zh) | 2011-11-23 |
CN1934665A (zh) | 2007-03-21 |
US7532454B2 (en) | 2009-05-12 |
US20070201184A1 (en) | 2007-08-30 |
CA2558511A1 (fr) | 2005-09-22 |
WO2005088657A2 (fr) | 2005-09-22 |
KR101046895B1 (ko) | 2011-07-06 |
JP2007528596A (ja) | 2007-10-11 |
EP1726023A2 (fr) | 2006-11-29 |
JP4754553B2 (ja) | 2011-08-24 |
FR2867600B1 (fr) | 2006-06-23 |
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