WO2005061156A1 - Fertigungslinie und verfahren zum im kontinuierlichen durchlauf erfolgenden herstellen von gussteilen aus einer metallischen schmelze, insbesondere einer leichtmetallschmelze - Google Patents
Fertigungslinie und verfahren zum im kontinuierlichen durchlauf erfolgenden herstellen von gussteilen aus einer metallischen schmelze, insbesondere einer leichtmetallschmelze Download PDFInfo
- Publication number
- WO2005061156A1 WO2005061156A1 PCT/EP2004/014388 EP2004014388W WO2005061156A1 WO 2005061156 A1 WO2005061156 A1 WO 2005061156A1 EP 2004014388 W EP2004014388 W EP 2004014388W WO 2005061156 A1 WO2005061156 A1 WO 2005061156A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- casting
- unit
- mold
- production line
- core
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D47/00—Casting plants
- B22D47/02—Casting plants for both moulding and casting
Definitions
- the invention relates to a production line for taking place in the continuous flow production of cast parts from a metal melt, in particular 'of a light metal melt, having a plurality of
- Functional units including a core shooting and curing unit for manufacturing cores, a mold mounting unit for mounting molds formed as core packs, a pouring unit for pouring the molten metal into the molds, a cooling unit for solidifying the molten metal contained in the mold, a cooling unit for quenching in terms of heat treatment and demoulding unit for early destructive removal of the mold from the casting.
- the invention likewise relates to a method for continuously casting castings from a molten metal, in which casting cores are first produced and then a casting mold designed as a core package is built from the casting cores. In this mold, the molten metal is poured. Subsequently, the melt contained in the mold is cooled controlled at least until the casting is solidified to a sufficient dimensional stability. Thereupon can start demolding the casting, which destroys the mold. The heat treatment of the casting is done directly from the casting heat by quenching.
- Production lines and methods of the type mentioned above are usually used in large-scale series production of castings.
- the applicant operates a production line with which motor blocks are cast in large quantities in the manner described in an automated process.
- a number of core shooting machines are linearly linked with each other. The number of core shooting machines necessary for this corresponds to the respectively available tool set for a complete core package of a specific type of engine block.
- the shot and completely hardened cores are removed via removal pallets and successively mounted on a parallel to the core shooter assembly line to a core package.
- cycle times of less than 60 seconds must be maintained with a corresponding level of automation.
- molding material for the production of the cores a molding material mixed from a known organic binder and a likewise conventional molding sand is used in the known production line.
- This molding material is solidified in the so-called "cold-box process", in which by gassing with a reaction gas, the curing of the organic binder is effected finished cores are mounted to the molds, stored in a storage facility for outgassing and then mechanically clamped together in the casting unit and poured.
- the respective casting mold After pouring the molten metal, the respective casting mold is brought into a solidification position, starting from which, depending on the casting, it passes through a cooling section for a time greater than 15 minutes in the clamped state. After solidification, the molds are loaded on pallets and driven into a heat treatment furnace. In this furnace, the castings (engine blocks) are thermally sanded and solution annealed in a process lasting several hours.
- the organic binder of the casting molds is decomposed at temperatures in the casting just below the solidus temperature of the alloy used, so that the sand mold breaks up into coarse fragments.
- mechanical conveyor and screens and the use of elaborate sand coolers and bunkers Kernmacherei is then fed back to fine-grained recycled sand. Due to the lengthy, thermal process, large quantities of sand and long transport routes are necessary.
- the above-mentioned object has been achieved by a method for producing molded parts from a molten metal, in particular a light metal melt, in which the following work steps are carried out in a continuous production sequence:
- the time at which the finished castings are dispensed is determined by the rate at which the cores are shot,
- the invention provides a modular process chain in which the processing stations Kernmacherei, Kernwovenmontage, foundry, solidification, Entkernung and quenching for the respective casting are passed through in a continuous process.
- the individual workstations are completed directly consecutively.
- the term "direct” in this context does not mean the shortest spatial distance, but rather it is essential according to the invention that the individual functional units are passed through one after the other without interruption instead, in which the individual work steps are directly interlinked. Molds and castings are conveyed in a continuous flow through the production line.
- Interim storage or other storage are not present in a production line according to the invention.
- the conveying path over which the casting cores and then the casting molds are initially conveyed be guided so that an optimal workflow is ensured regardless of whether the respective parts on the shortest route to each next workstation be transported.
- the cycle of the production process according to the invention is determined by the time-critical unit of production, namely core shooting.
- the curing times are distributed to several stations in the core production plant.
- the cores output from the core manufacturing unit are taken over by the mold mounting device and assembled into a core package.
- the respectively present at the transfer cores form a G tellkernsatz, from each of which a core forming the mold can be assembled without special sorting. In this way it is possible to assemble molds fully automatically, without the need for elaborate control devices.
- a particularly preferred embodiment of the invention provides that an inorganic, in particular a water glass-based binder is used as the binder. Binders of this type ensure a high dimensional stability of the cores after curing when exposed to heat. By using an inorganic binder, it is also possible to thin-wall the casting cores, which are exposed to larger specific loads in the core package forming the casting mold. In addition, practical experiments have shown that inorganic bonded molding materials can be easily dissolved in water and have good disintegration properties.
- Core package molds constructed from cores produced using inorganic binders thus not only prove to be robust, but have additional beneficial properties for performing the method of the present invention.
- the resulting in a production line according to the invention core sand volume is reduced, as is cored in a short way after pouring into water and the mold can be formed as a thin-walled core package with the advantages mentioned.
- the parts required for holding and transporting the core package (clamping devices, cooling iron, mold segments, support elements, clamping devices, etc.) can be easily cleaned and reused in circulation.
- the invention is particularly suitable for the production of complex shaped engine blocks of aluminum-based alloys.
- An advantageous embodiment of the invention is characterized in that the core production plant comprises a core shooting station, a plurality of hardening and one conveyor, which then conveys the core tools in the circulation of the shooting station, the hardening stations to the transfer stations to the mold assembly device and back to the shooting station.
- the core production unit has a device for the automated changing of the shot hoods in the shooting station assigned to the individual tools required for the shooting of the cores.
- an automatic tool cleaning is integrated. Core breakage can be automatically removed at a position on the conveyor system.
- the automatic mold assembly in the mold assembly unit can be facilitated by the fact that the finished cores are taken directly to transfer stations on the conveyor system of the core manufacturing plant.
- the mold mounting unit used according to the invention comprises more than one assembly station and a conveying device conveys the mold to be produced in succession to the assembly stations in succession.
- Each of the assembly stations can perform a specific task and optionally has intermediate storage, core adhesive stations, LinerZu Entry, screwing devices, etc.
- the production line comprises a heating device for heating these zuzugitenden in the casting components. It is favorable for the desired continuity of the production process, if the
- Heating device is integrated into the casting unit and the heating takes place in the plant cycle.
- the temperature of the components to be infused can be adjusted specifically with little expenditure of energy and can be coordinated with the mold filling and solidification process of the entire casting.
- the incorporation of the casting unit into the working cycle predetermined by the core manufacturing unit can be realized by the casting unit comprising a turntable which takes over the casting mold conveyed from the mold assembly unit to the casting unit at a transfer station from the conveying device connecting the die assembly unit to the casting unit promotes a pivoting movement to a casting station and the mold after the done in the casting station controlled mold filling process with melt further promotes to a transfer station at which it passes the respective mold to the cooling unit leading to conveyor.
- the controlled mold filling can be done by coupling the molds to a known low-pressure casting furnace, gas-pressure-controlled melt transport into the mold cavity, closing the pouring opening and subsequent 180 ° rotation in solidification position (roll-over).
- the rotational movement can be used to control the mold filling process.
- a special advantage of core packages made of inorganic binders are hardly any gases when in contact with the melt, since the binder does not burn.
- local cooling molds can be used to remove heat from the area of holes, storage chairs, accumulations of material, etc. in a targeted manner.
- the solution annealing which can only be carried out with great difficulty in the prior art, can be avoided by quenching the cast pieces starting from a specific temperature.
- the cooling unit has a quenching station for quenching the casting from the casting heat out.
- the gutting of the solidified casting can be done in a conventional manner by liquid jets.
- the demolding unit preferably has a liquid jet device for destroying the casting mold. With such a liquid jet device, the casting cores sitting in the casting can be flushed out.
- the demolding unit can also comprise a liquid-fillable basin into which the casting mold can be inserted.
- a movement device for moving the mold immersed in the basin can be assigned to the liquid basin.
- the molded parts caught in the liquid further disintegrate into finely granular molding material and can be easily removed from the liquid tank.
- water is optionally suitable with additives, which may be heated to a certain, the decay of the molding material of the mold additionally supporting temperature.
- a particularly practical embodiment of the invention is characterized in that the cooling unit and the demolding unit are combined to form a combined cooling and demolding unit.
- the problems caused by the use of organic binders in the prior art can be eliminated by using an inorganic binder as the binder of the molding material.
- Such known from the prior art binder system can be cured by heat, without causing the environment or the machine personnel polluting gases.
- the single figure shows schematically a production line 1 for the fully automatic production of engine blocks made of an aluminum alloy in a plan view.
- the production line comprises a core production unit 2 for manufacturing casting cores, a mold mounting unit 3 for mounting core molds G, a casting unit 4 for casting molten aluminum into the casting molds G, a cooling unit 5a for solidifying the molten metal contained in the casting mold G, and a demoulding unit 5b for destructive removal of the respective casting mold G and a quenching unit 5c of the casting M.
- the core production unit 2 has a core shooting station 6 and a conveying device 7 designed as a conveying path.
- the transport device 7 is divided into four sections 7a, 7b, 7c, 7d, which are arranged at right angles to each other such that they form the side line of a rectangle in plan view.
- the Core tool shells WO are conveyed to the section 7d.
- the core shooting station 6 is positioned in a corner region of the transport device 7, on which the sections 7a and 7d of the transport device abut one another. In the core shooting station 6 casting cores are shot in a conventional manner from an inorganic binder and a quartz sand or synthetic sand mixed molding material.
- the core shooting station 6 is a
- Assorted shot changing device 8 which provides the gun used in the core shooting station 6 each shot hood tool specific.
- the tools W are positioned in the curing stations A. In the middle of the section 7b, the tool shells WO are lifted and transferred to the conveying path 7e.
- a first assembly robot 11 is associated with the mold assembly unit 3, which takes over from the curing station A and transported over the section 7b cores from the lower tool part WU.
- Further assembly robots 10 of the mold mounting unit 3 corresponding to the takeover robot 11 are positioned along the portion 7c of the transport device 7 arranged opposite the portion 7a.
- a last assembly robot 9 of the assembly unit 3 is positioned in the conveying direction F at the beginning of the section 7b opposite arranged section 7d.
- the transport device 7 transfer stations are formed in this way, where the finished casting cores are transferred to the mold assembly unit 3.
- the casting molds G are conveyed via a conveying device 12 designed as a conveying path and conveyed along the assembly robots 9-11.
- the conveyor 12 has three linearly extending sections 13,14,15, of which in plan view the first section 13 at right angles to the second section 14 and the third section 15 is again arranged at right angles to the second section 15, so that the sections 13- 15 are arranged in a top view U-shaped.
- the first casting cores 11 of the respective casting mold G are assembled by the first assembly robot 11. Subsequently, the casting molds G, which are partly finished in this state, reach the section 14 of the conveyor 12 and are conveyed along the assembly robots 10, 9, adding the respective further casting cores G to the respective casting mold until the mold has been finished when leaving the mold assembly unit 3 is.
- the casting molds G reach the section 15, which guides them to a turntable 16.
- the turntable 16 takes over the respective casting mold G and transports in a 90 ° rotation to a heating station 17 in the inserts to be cast into the engine block to be manufactured (eg liners etc.) or mold parts (eg brass quills for bore area, etc.) are heated inductively.
- the casting mold G is conveyed to the casting station 18 of the casting unit 4. There, the molten aluminum is conveyed into the respective casting mold G. Subsequently, the turntable 16 again conveys the casting mold G filled with melt to a transfer station, at which the casting mold G is transferred to a further conveying device 19 designed as a conveying path.
- the casting mold G is transported on via a straight-line conveying section 20 of the cooling unit 5a. At the end of the conveyor line 20, the solidification of the molten aluminum in the mold G is completed so far that the casting M formed in it has received a solid shape.
- the casting mold G which still has its original shape, is formed into a conveying device 21 which is likewise designed as a conveying path and is arranged at right angles to the conveying path 20 of the cooling unit 5a
- the casting mold G In the water basin 23 filled with tempered water, the casting mold G is moved in order to accelerate its decomposition. In addition, by means of non-illustrated water jet devices, the casting mold G can be acceleratedly destroyed and cores lying inside the solidified casting M can be rinsed out. The fragments of the mold G are caught in the water basin 23 and disintegrate, since the inorganic binder dissolves in the water basin 23. This results in fine-grained molding material. The molding material is mixed with new inorganic binder again to new molding material and fed back to the core production unit 2.
- the inorganic binder is partially dissolved in the water of the water basin 23.
- the water contained in the binder is also fed to a treatment and returned to the production cycle.
- the casting (engine block) M After removal from the mold, the casting (engine block) M, which is now free from casting core residues, is fed via a conveyor line 25 to a post-processing unit 26 in which it is deburred, sawn and, if necessary, subjected to further finishing operations.
- the tact with which the castings M are ejected from the production line 1 is determined by the tact with which the core production unit 2 supplies the casting cores produced by it to the mold mounting unit 3.
- their treatment in the individual functional units 2-6 of the production line 1 only a small number of casting manipulators (robots) is required due to the direct linking of these units 2-6, the rapid cooling and the desanding combined directly with the cooling ,
- the production line according to the invention can produce high quality castings in relatively small quantities in a particularly economical manner with little effort on machines and costs.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Molds, Cores, And Manufacturing Methods Thereof (AREA)
- Casting Devices For Molds (AREA)
- Treatment Of Steel In Its Molten State (AREA)
- Continuous Casting (AREA)
Abstract
Description
Claims
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/562,959 US7588070B2 (en) | 2003-12-19 | 2004-12-17 | Production line and method for the production of cast parts, from a metallic melt, in particular a light molten metal, which takes place in a continuous cycle |
AU2004305239A AU2004305239A1 (en) | 2003-12-19 | 2004-12-17 | Production line and method for the continuous production of cast parts from a molten metal, in particular a molten light alloy |
DE502004000896T DE502004000896D1 (de) | 2003-12-19 | 2004-12-17 | Fertigungslinie und verfahren zum im kontinuierlichen durchlauf erfolgenden herstellen von gussteilen aus einer metallischen schmelze, insbesondere einer leichtmetallschmelze |
JP2006544351A JP2007514549A (ja) | 2003-12-19 | 2004-12-17 | 金属溶湯、特に軽金属溶湯から鋳物を連続的流れの中で製造する生産ライン及び方法 |
MXPA06000096A MXPA06000096A (es) | 2003-12-19 | 2004-12-17 | Linea de produccion y metodo para la produccion continua de partes colocadas de un metal fundido, en particular una aleacion ligera fundida. |
EP04820597A EP1626830B1 (de) | 2003-12-19 | 2004-12-17 | Fertigungslinie und verfahren zum im kontinuierlichen durchlauf erfolgenden herstellen von gussteilen aus einer metallischen schmelze, insbesondere einer leichtmetallschmelze |
BRPI0414936-0A BRPI0414936A (pt) | 2003-12-19 | 2004-12-17 | linha de produção e método para a produção de peças fundidas, a partir de um fundido metálico, em particular um metal fundido leve, que ocorre em um ciclo contìnuo |
PL04820597T PL1626830T3 (pl) | 2003-12-19 | 2004-12-17 | Linia produkcyjna i sposób wytwarzania w ruchu ciągłym odlewów z ciekłego metalu, zwłaszcza z ciekłego metalu lekkiego |
CA002528474A CA2528474A1 (en) | 2003-12-19 | 2004-12-17 | Production line and method for the continuous production of cast parts from a molten metal, in particular a molten light alloy |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10360694.7 | 2003-12-19 | ||
DE10360694A DE10360694B3 (de) | 2003-12-19 | 2003-12-19 | Fertigungslinie und Verfahren zum im kontinuierlichen Durchlauf erfolgenden Herstellen von Gussteilen aus einer metallischen Schmelze, insbesondere einer Leichtmetallschmelze |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2005061156A1 true WO2005061156A1 (de) | 2005-07-07 |
WO2005061156A8 WO2005061156A8 (de) | 2005-09-22 |
Family
ID=34625693
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2004/014388 WO2005061156A1 (de) | 2003-12-19 | 2004-12-17 | Fertigungslinie und verfahren zum im kontinuierlichen durchlauf erfolgenden herstellen von gussteilen aus einer metallischen schmelze, insbesondere einer leichtmetallschmelze |
Country Status (15)
Country | Link |
---|---|
US (1) | US7588070B2 (de) |
EP (1) | EP1626830B1 (de) |
JP (1) | JP2007514549A (de) |
CN (1) | CN1822912A (de) |
AT (1) | ATE331582T1 (de) |
AU (1) | AU2004305239A1 (de) |
BR (1) | BRPI0414936A (de) |
CA (1) | CA2528474A1 (de) |
DE (3) | DE20320923U1 (de) |
ES (1) | ES2268667T3 (de) |
MX (1) | MXPA06000096A (de) |
PL (1) | PL1626830T3 (de) |
RU (1) | RU2006104714A (de) |
WO (1) | WO2005061156A1 (de) |
ZA (1) | ZA200510103B (de) |
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DE102005019961A1 (de) * | 2005-04-29 | 2006-11-02 | Audi Ag | Verfahren zur Herstellung eines Gussteiles im Verbundguss |
CN1326647C (zh) * | 2005-11-11 | 2007-07-18 | 贵阳铝镁设计研究院 | 铸造车间分区配置方式 |
JP4700737B2 (ja) * | 2006-09-25 | 2011-06-15 | アイシン高丘株式会社 | 鋳造品生産ライン装置 |
DE102006057660B4 (de) * | 2006-12-07 | 2019-08-22 | Bayerische Motoren Werke Aktiengesellschaft | Verfahren zum Druckgießen von Bauteilen und Verwendung einer Sprühvorrichtung einer Druckgießvorrichtung |
FR2911522B1 (fr) * | 2007-01-22 | 2009-02-27 | Cinetic Linking Sa | Chaine de production automatisee de pieces metalliques et procede de moulage. |
DE102007008149A1 (de) | 2007-02-19 | 2008-08-21 | Ashland-Südchemie-Kernfest GmbH | Thermische Regenerierung von Gießereisand |
CN101683687B (zh) * | 2008-09-24 | 2012-07-11 | 上海乾通汽车附件有限公司 | 采用普通压铸机对发动机缸体进行全自动压铸的方法 |
CA2740562A1 (en) * | 2008-10-23 | 2010-04-29 | Tenedora Nemak, S.A. De C.V. | Automated system for improved cooling of aluminum castings in sand molds |
JP4939668B2 (ja) * | 2009-05-01 | 2012-05-30 | アイテックエフエム株式会社 | 鋳物製品の製造方法及び製造工場 |
WO2011030618A1 (ja) * | 2009-09-10 | 2011-03-17 | 新東工業株式会社 | 注湯機制御システム、注湯設備及び注湯方法 |
DE102010028489A1 (de) * | 2010-05-03 | 2011-11-03 | Dürr Ecoclean GmbH | Anlage und Verfahren zum Reinigen und/oder Entgraten von Werkstücken |
US8220523B2 (en) | 2010-09-16 | 2012-07-17 | Anderson & Associates | Method and apparatus for manipulating investment casting mold handlers |
DE102011100415A1 (de) | 2011-05-04 | 2011-12-22 | Daimler Ag | Fertigungsanlage und Verfahren zum Herstellen von Sandkernen |
CN102284683B (zh) * | 2011-08-24 | 2013-03-27 | 机械工业第三设计研究院 | 全自动精密组芯造型生产线、铸造生产线及其生产方法 |
US8555950B2 (en) * | 2011-10-25 | 2013-10-15 | Ford Global Technologies, Llc | Organic-like casting process for water jackets |
CN102397984A (zh) * | 2011-11-28 | 2012-04-04 | 芜湖火龙铸造有限公司 | 一种自动加料成型装置 |
AT515345A1 (de) | 2014-01-03 | 2015-08-15 | Fill Gmbh | Verfahren zum Gießen eines Gussteils |
US10933467B2 (en) | 2014-03-28 | 2021-03-02 | Inductotherm Corp. | Clean cell environment roll-over electric induction casting furnace system |
CN104707989B (zh) * | 2015-02-12 | 2017-01-25 | 温岭市申弘电器配件厂 | 电机壳自动化流水线 |
US11065677B2 (en) | 2016-05-20 | 2021-07-20 | Nemak, S.A.B. De C.V. | Automated assembly cell and assembly line for producing sand molds for foundries |
CN106623869B (zh) * | 2017-01-18 | 2018-07-03 | 包头市拓又达新能源科技有限公司 | 一种稀土冶炼六轴机器人的智能浇模脱模设备及方法 |
CN107321964B (zh) * | 2017-06-16 | 2019-01-18 | 徐扬 | 一种铸铁件后清洗流水线及其清洗方法 |
CN107199333B (zh) * | 2017-07-10 | 2023-04-21 | 苏州明志科技股份有限公司 | 一种桁架浇铸*** |
DE102018221750A1 (de) * | 2018-12-14 | 2020-06-18 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verfahren und Gussform zum Herstellen von Metallgusswerkstücken |
DE102019134739B3 (de) * | 2019-12-17 | 2021-04-01 | Meissner Ag Modell- Und Werkzeugfabrik | Kernschießverfahren und Kernschießvorrichtung für die Herstellung von Kernen mit gleichzeitigem Härtungsverfahren |
CN113118431B (zh) * | 2021-04-26 | 2022-07-19 | 机械工业第六设计研究院有限公司 | 较大铸件的自动化造型工艺 |
CN113828762B (zh) * | 2021-08-10 | 2023-07-18 | 洛阳托普热能技术有限公司 | 一种全自动铝水连续生产及输送线 |
CN115138834A (zh) * | 2022-07-28 | 2022-10-04 | 共享智能铸造产业创新中心有限公司 | 智能铸造工厂 |
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-
2003
- 2003-12-19 DE DE20320923U patent/DE20320923U1/de not_active Expired - Lifetime
- 2003-12-19 DE DE10360694A patent/DE10360694B3/de not_active Withdrawn - After Issue
-
2004
- 2004-12-17 MX MXPA06000096A patent/MXPA06000096A/es active IP Right Grant
- 2004-12-17 AU AU2004305239A patent/AU2004305239A1/en not_active Abandoned
- 2004-12-17 AT AT04820597T patent/ATE331582T1/de active
- 2004-12-17 EP EP04820597A patent/EP1626830B1/de active Active
- 2004-12-17 US US10/562,959 patent/US7588070B2/en not_active Expired - Fee Related
- 2004-12-17 PL PL04820597T patent/PL1626830T3/pl unknown
- 2004-12-17 CA CA002528474A patent/CA2528474A1/en not_active Abandoned
- 2004-12-17 BR BRPI0414936-0A patent/BRPI0414936A/pt not_active Application Discontinuation
- 2004-12-17 ES ES04820597T patent/ES2268667T3/es active Active
- 2004-12-17 DE DE502004000896T patent/DE502004000896D1/de active Active
- 2004-12-17 CN CNA2004800199043A patent/CN1822912A/zh active Pending
- 2004-12-17 WO PCT/EP2004/014388 patent/WO2005061156A1/de active Application Filing
- 2004-12-17 JP JP2006544351A patent/JP2007514549A/ja active Pending
- 2004-12-17 RU RU2006104714/02A patent/RU2006104714A/ru not_active Application Discontinuation
-
2005
- 2005-12-12 ZA ZA200510103A patent/ZA200510103B/en unknown
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DE502004000896D1 (de) | 2006-08-10 |
CA2528474A1 (en) | 2005-07-07 |
AU2004305239A1 (en) | 2005-07-07 |
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US7588070B2 (en) | 2009-09-15 |
RU2006104714A (ru) | 2007-09-10 |
BRPI0414936A (pt) | 2006-11-07 |
EP1626830B1 (de) | 2006-06-28 |
PL1626830T3 (pl) | 2006-11-30 |
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CN1822912A (zh) | 2006-08-23 |
MXPA06000096A (es) | 2006-04-07 |
EP1626830A1 (de) | 2006-02-22 |
US20070169912A1 (en) | 2007-07-26 |
ZA200510103B (en) | 2006-12-27 |
WO2005061156A8 (de) | 2005-09-22 |
ES2268667T3 (es) | 2007-03-16 |
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