WO2003091724A1 - Procede de mesure de la concentration en formaldehyde d'un gaz et instrument de mesure - Google Patents
Procede de mesure de la concentration en formaldehyde d'un gaz et instrument de mesure Download PDFInfo
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- WO2003091724A1 WO2003091724A1 PCT/JP2003/003735 JP0303735W WO03091724A1 WO 2003091724 A1 WO2003091724 A1 WO 2003091724A1 JP 0303735 W JP0303735 W JP 0303735W WO 03091724 A1 WO03091724 A1 WO 03091724A1
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- WIPO (PCT)
- Prior art keywords
- filter
- color
- reagent
- test gas
- formaldehyde
- Prior art date
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Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N31/00—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods
- G01N31/22—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods using chemical indicators
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/27—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands using photo-electric detection ; circuits for computing concentration
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/75—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated
- G01N21/77—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/75—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated
- G01N21/77—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator
- G01N21/78—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator producing a change of colour
- G01N21/783—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator producing a change of colour for analysing gases
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N31/00—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N31/00—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods
- G01N31/22—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods using chemical indicators
- G01N31/223—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods using chemical indicators for investigating presence of specific gases or aerosols
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/20—Oxygen containing
- Y10T436/200833—Carbonyl, ether, aldehyde or ketone containing
- Y10T436/202499—Formaldehyde or acetone
Definitions
- the present invention relates to a method for measuring the concentration of formaldehyde in an atmosphere. More specifically, the present invention relates to a formaldehyde using 4_amino-3-hydrazino-5-mercapto-1,2,4-triazole (AHM T) as a coloring reagent. The present invention relates to a method for measuring a metal concentration and a formaldehyde concentration measuring device used for the method.
- AHM T 4_amino-3-hydrazino-5-mercapto-1,2,4-triazole
- the current living environment especially the high airtightness of buildings, such as houses and buildings using building materials and interior materials containing chemical substances, has caused occupants and occupants to be exposed to various chemical substances emitted from the building materials and interior materials into the atmosphere.
- Various poor physical conditions are caused to the user and the like. These symptoms are diverse and the cause of their onset is largely unresolved, and various complex factors can be considered, so they are usually called sick house syndrome.
- formaldehyde which is contained in building adhesives such as plywood adhesives and glue for clothes, is one of the causative substances.WHO indoor environmental standards are strictly below 0.08 ppm. Regulated.
- Formaldehyde detector tube utilizing the discoloration of the indicator that is colored by the free acid generated by the
- a test gas containing formaldehyde is brought into contact with a detection tub carried on a test paper containing silica gel mixed with hydroxylamine hydrochloride and the pH indicator, and a similar reaction between formaldehyde and hydroxylamine sulfate is carried out.
- Play Method and apparatus for measuring the discoloration of the test paper surface due to acid desorption using a light emitting element (LED) and light receiving element (PIN type photodiode) Multi Gas Finder FP-85, Formaldehyde Monitor FP-250F1W: RIKEN KEIKI
- Formaldehyde was collected through the test gas collecting liquid (0. 5% H 3 B0 3 solution), 4-amino-3-arsenide Dorajino 5-mercapto one 1, 2, added 4_ Toriazonore (AH MT) The reaction is carried out under alkaline conditions, and a potassium periodate (KIO 4 ) solution is further added to form a color, and the color tone is measured using a colorimeter or a spectrophotometer.
- a method and apparatus (Silset: Shimadzu Corporation)
- formaldehyde is adsorbed on or absorbed by the adsorbent and analyzed using advanced analytical equipment such as gas chromatography (GC) and high-performance liquid chromatography (HPLC).
- GC gas chromatography
- HPLC high-performance liquid chromatography
- Formaldehyde is oxidized on the electrode
- Electrochemical analysis such as potentiostatic electrolysis, which measures the oxidation potential, and the emission of orange light generated when formaldehyde is oxidized in the presence of hydrogen peroxide and gallic acid in an alkaline aqueous solution
- a chemiluminescence method for measuring light intensity and the like are known.
- the detection tube and a method of Ru with hydroxylamine sulfate ⁇ Min test paper device is a portable, has the advantage of obtaining know the measurement result by the measurement site, the co gas NO x, etc. If there is acid gas, acetoaldehyde, acetone, ammonia, etc., it may not be possible to obtain an accurate formaldehyde concentration due to the influence of such gases. Also, to detect the WHO indoor environmental standard of 0.08 ppm, a ventilation time of approximately 30 minutes is required.
- the method of using AHMT as a color reagent is based on the following reaction between formaldehyde and AHMT.
- An object of the present invention is to provide a method for measuring the concentration of formaldehyde in a test gas with high sensitivity and in a short time without being affected by a coexisting gas.
- the present inventors have conducted intensive studies to achieve the above object, and as a result, a test gas containing formaldehyde was introduced into and brought into contact with a filter moistened with a color developing solution composed of a KOH aqueous solution of AHMT. However, they have found that the color develops without an oxidizing agent, and that the degree of color develops is almost proportional in the region where the concentration of formaldehyde in the test gas is lppm or less, and the present invention has been completed.
- the present invention relates to a method for producing a test solution comprising a color reagent solution comprising an aqueous alkali solution of 4-amino-3-hydrazino-5-mercapto-1,2,4-triazole (AHMT) and a test gas; Contact with a filter or a filter that does not give background color due to wetness of the test solution, and determine the formaldehyde concentration in the test gas based on the color tone or degree of color of the filter formed by the formaldehyde in the test gas. This is a method for measuring the concentration of formaldehyde in gas.
- AHMT 4-amino-3-hydrazino-5-mercapto-1,2,4-triazole
- the filter is selected from the group consisting of glass filter paper, silica fiber filter paper, and quartz filter paper.
- a gas flow path formed between a test gas inlet and a test gas outlet connected to a suction pump, and a gas flow path disposed at a predetermined position in the gas flow path and detachably mounted.
- a color reagent containing an alkaline aqueous solution of 4-amino-3-hydrazino-5-mercapto-1,2,4-triazole (AHMT) on the detection tab.
- AHMT 4-amino-3-hydrazino-5-mercapto-1,2,4-triazole
- a filter that does not give background color due to wetting is attached, and the color reagent solution is brought into contact with the test gas so that the formaldehyde in the test gas causes the filter moistened with the color reagent solution to develop a color.
- It is a device for measuring the concentration of formaldehyde in gas, which is characterized by being constituted.
- the detection tab is composed of a filter, a frame, and a filter holder, and the filter is selected from the group consisting of glass filter paper, silica fiber filter paper, and quartz filter paper, and is spread without any gap in the frame to form the filter. It is fixed by the work clamp.
- the above-mentioned detection tab is tabular and is arranged in a predetermined position in a gas channel by inserting into a slit provided in a main part.
- the flat detection tab is housed in a cassette, and the cassette is mounted at a slit position provided in a main body, whereby the detection tab is arranged at a predetermined position in a gas flow path. Is done.
- At least one surface of the filter is irradiated with light.
- Still another embodiment of the measuring device of the present invention comprises a plurality of reagent supply tubes and a reagent mixing tube, wherein the reagent supply tube is a transparent tube portion with a scale and a flexible tube which can be deformed by pressing from outside.
- the reagent mixing tube is detachably attached to the top of the reagent mixing tube, and the reagent mixing tube has a flexible tube portion partially deformable by external pressure.
- the apparatus further includes a color reagent dropping device for dropping a predetermined amount of the color reagent onto the filter.
- FIG. 1 shows the absorbance (550 nm) with respect to various aldehyde concentrations obtained in Reference Example 1 (AHMT solution method).
- FIG. 2 shows the coloring degree (response value%) with respect to the sampling time obtained in Example 1 (the method of the present invention).
- FIG. 3 shows the degree of color development (response value%) with respect to the concentration of formaldehyde (in the range of 0 to 1 ppm) obtained in Example 1 (the method of the present invention).
- FIG. 4 shows the degree of color development (response value%) with respect to the formaldehyde concentration (in the range of 0 to 4 ppm) obtained in Example 1 (the method of the present invention).
- FIG. 5 shows the degree of color development (response value%) of background color development with respect to the sampling time obtained in Example 2.
- FIGS. 6A and 6B are diagrams for explaining a mode of contact between a test gas and a filter in the formaldehyde concentration measuring apparatus of the present invention, wherein FIG. 6A shows a filter surface contact type, and FIG. (C) is a filter surface collision type.
- FIG. 7 is a diagram for explaining the detection tab.
- FIG. 8 illustrates a preferred embodiment of the formaldehyde concentration measuring apparatus of the present invention.
- FIG. 9 is a diagram for explaining a mode of the detection tab cassette.
- FIG. 10 is a diagram for explaining one embodiment of a color reagent injection device. BEST MODE FOR CARRYING OUT THE INVENTION
- the method for measuring the formaldehyde concentration of the present invention is based on the following color-forming reaction between an aqueous solution of 4-amino-3-hydrazino-15-mercapto-1,2,4-triazole (AHMT) and formaldehyde under alkaline conditions.
- AHMT 4-amino-3-hydrazino-15-mercapto-1,2,4-triazole
- the present invention is characterized in that an intermediate produced by the reaction between AHMT and formaldehyde under alkaline conditions is colored by air oxidation.
- the above reaction is a substantial solution reaction in the color reagent solution held in the filter moistened with the color reagent, and the color development process proceeds by air oxidation by contact between the solution surface and air. Therefore, it is not necessary to add an oxidizing agent, for example, KIO 4 in the coloring process.
- wet means a state in which the color developing solution is filled between the fibers constituting the filter and held by the filter, and the filter and the color developing solution form a liquid layer.
- the color reagent solution held in the filter and the test gas are brought into continuous contact with each other for a period of time during which measurable color development occurs.
- the contact time between the above-mentioned filter and the test gas is such that the concentration of formaldehyde in the test gas is 0.04. In the range of ⁇ lppm, it is in the range of 180-300 seconds. If the formaldehyde concentration is higher, the measurement can be performed in a shorter time.
- the color reagent solution is an alkaline aqueous solution of AHMT, and is an aqueous solution containing AHMT and a free base of 1 N or more, preferably 2 N or more. Since the alkaline aqueous solution of AHMT is difficult to dissolve AHMT in water, AHMT is once dissolved in an aqueous acid solution to prepare an aqueous AHMT acid solution, and then the acid in the aqueous AHMT acid solution is neutralized. It is prepared by adding and mixing an amount of an aqueous alkali solution that can be made to act.
- the AHMT acid aqueous solution is an aqueous solution containing 0.1 to 1 N free acid, and a non-oxidizing acid, preferably hydrochloric acid, is used as the acid used for its preparation.
- the concentration of AHMT is usually between 0.1 and 0.5 weight. /. Although there is no particular limitation, it can be appropriately selected according to the concentration of formaldehyde to be measured.
- AHMT acid aqueous solution can be stored stably at room temperature in glass containers or plastic containers.
- an aqueous solution containing 2 to 1 ON of a free base is usually prepared, and is used without dilution or further diluted as necessary.
- a strongly basic alkali metal hydroxide for example, KOH or NaOH is preferably used.
- the alkaline aqueous solution can be stored at room temperature in a plastic container.
- the color developing reagent may be prepared by mixing the AHMT acid aqueous solution and the alkaline aqueous solution in a container, or by mixing them on a filter by individually dropping them on a filter. Is also good. Since the color reagent solution in which the AHMT acid aqueous solution and the alkaline aqueous solution are mixed is unstable to light, it is preferable to mix the AHMT acid aqueous solution and the aqueous solution immediately before use or on a filter.
- the amount of the color reagent solution that moistens the filter may be such that the reagent on the filter is present as a solution during the measurement, that is, during the flow of the test gas, and the filter does not dry. It is appropriately selected according to the expected formaldehyde concentration in the test gas. 'one)
- the filter is a filter which, when the filter is wetted with the color reagent, can retain a sufficient amount of the filter in the filter, and does not give background color with them, and an alkaline solution of at least 2 N or more.
- the material and shape are not particularly limited as long as they are stable. When optically measuring the degree of color development using transmitted light, it is required that the light be sufficiently transmitted.
- preferred filters are glass filter paper, silica fiber filter paper, quartz filter paper and the like.
- the filter can have any shape such as a circle or a rectangle according to the measuring device. Also, a preferable result can be obtained by stacking and using several filters in order to retain a sufficient amount of the color reagent solution.
- a method for wetting the filter with the color developing reagent As a method for wetting the filter with the color developing reagent, a method in which an AHMT acidic aqueous solution and an alkaline aqueous solution are directly dropped on the filter using a dispenser such as a Pittman, respectively. A method in which a mixed aqueous solution mixed with an aqueous solution is dropped on a filter using a dispenser or the like can be appropriately adopted.
- the test gas is not particularly limited as long as it is a gas that may contain formaldehyde.
- the indoor gas that is expected to contain low concentrations of formaldehyde, the smoke chamber that contains high concentrations of formaldehyde, or the surrounding air and soil air will be used as the test gas.
- gas collected by publishing air or nitrogen gas into seawater or industrial wastewater in a culture cage that may dissolve formaldehyde, gas generated by heating solid materials such as wall materials, etc. Etc. can also be used as the test gas.
- the test gas and the filter in which the color reagent solution is wetted are mixed. Make contact.
- the contact between the test gas and the filter can be achieved by either flowing the test gas in parallel with the filter surface, colliding the test gas with the filter surface at an angle, or passing the test gas through the filter. May be.
- a method in which the test gas impinges on the filter surface at an angle is preferable.
- the filter surface When formaldehyde is present in the test gas by bringing the test gas into contact with the color reagent retained in the filter in the manner described above, the filter surface has a purple-red color with a maximum absorption wavelength of 550 nm on the filter surface. Spots appear. The color tone of this spot is measured visually or colorimetrically, and collated with a color tone sample or colorimetric calibration curve created by measuring in advance using a standard gas with a known formaldehyde concentration. Determine the formaldehyde concentration in the test gas.
- a method for optically measuring the degree of color development a method of irradiating light toward the spot and measuring the change in the intensity of reflected light from the spot (response value%), that is, the degree of color development can be adopted.
- a light emitting element LED
- a PIN type photodiode can be used as a light receiving element for reflected light.
- FIG. 6 shows a mode of contact between the test gas and the filter moistened with the coloring reagent, which is an essential part of the formaldehyde concentration measuring apparatus of the present invention.
- a test gas flow path 11 is formed between the test gas inlet 12 of the main unit 1 and the test gas outlet 13 for connection to an external suction pump, and the detection tab 2 is attached to the detection tab 2.
- the removed filter 21 is detachably mounted on the main body 1 so as to be exposed in the test gas flow path 11. As a result, the test gas flowing in the test gas flow channel 11 can be brought into contact with the filter 21 moistened with the coloring reagent.
- FIG. 6 shows the mode in which the test gas flows almost parallel to the surface of the filter 21 and comes into contact with the color reagent, and (b) shows the mode in which the test gas contacts the color reagent through the filter 21.
- C shows an embodiment in which the test gas is caused to collide with the surface of the filter 21 to come into contact with the coloring reagent.
- FIG. 6 is an example, and the mode in which the test gas is brought into contact with the filter 21 is not limited to the illustrated mode. May be adopted.
- the detection tab 2 is composed of a filter 22 and a frame 22 on which the finole letter 21 is developed and mounted, and a filter presser 23 fixing the filter 21 to the frame 22.
- the expanded portion of the filter 21 in the frame 22 can have any shape such as a circle (FIG. 7 (a)) or a square (FIG. 7 (b)).
- the detection tab 2 is a flat plate as shown in FIG. 7 (b), that is, a frame 22 having a developed portion of the filter 21 on a part of a rectangular flat plate, whereby Insert the detection tab 21 into the slit 15 provided on the side of the main body 1 and push it into the main body 1 along the rail 16 provided inside the main body 1, so that the filter 21 of the detection tab 2 is in the predetermined position.
- the detection tab 2 is housed in the cassette 25, and the cassette 25 is applied to the slit 15 provided in the main body 1 so that the filter moistened with the color reagent solution is formed. 2
- the detection tab 2 can be attached to the main body 1 without exposing one surface to natural light.
- the cassette 25 is a box having a front lid 26 that opens up and down on the front, and has two or more rotatable pin rollers 27 on both sides inside the cassette for inserting and removing the detection tab 2.
- the pin roller 27 is inserted into a groove 24 provided on the side surface of the detection tab 2 so that the detection tab 2 can be easily taken in and out of the cassette 25.
- the detection tab 2 has an insertion hole 28 just above the filter 21 for mounting the color reagent injection device 4. Further, a glass plate is provided directly below the filter 21 of the detection tab 2.
- the detection tab 2 may be screwed into the mounting position and mounted with a screw or the like. .
- the material of the main body 1 and its internal structure can be either metal or plastic
- the detection tab 2 may be made of metal or plastic except for the filter 21.
- the inside of the main unit and the parts arranged inside the main unit are painted black except for the filter 21 to prevent reflection of light from other than the surface of the filter 21.
- the apparatus includes an optical measurement system that optically measures the degree of color development on the surface of the filter 21 and displays the result as the absolute concentration of formaldehyde.
- the optical measurement system consists of a light emitting element (LED) 31 for irradiating the filter 21 with light, a light receiving element (PIN type photodiode) 32 for receiving light reflected from the filter 21 and light receiving Includes a liquid crystal display 33 that displays the change in the intensity of the reflected light received by the element 32 (response value%), that is, the chromaticity converted to the formaldehyde concentration value.
- the change in the reflection intensity (response value%) is calculated from the output voltage (V) of the light receiving element before, during, and after the test gas is ventilated by the following formula.
- V represents the output voltage before introducing the test gas, and represents the output voltage during or after introducing the test gas.
- This change in output voltage corresponds to the change in reflection intensity (response value%) on the filter surface, that is, the degree of color development.
- an electronic component room is formed by a partition below the mounting portion of the detection tab 2.
- the electronic component room is required to display the voltage change measured by the light receiving element 32 such as CPU, RAM, ROM, timer, battery, etc. on the display 33 as the formaldehyde concentration. Electronic components are accommodated.
- a set of the color reagent pouring device 4 as shown in FIG. 10 is included.
- the color reagent pouring device 4 comprises at least a set of two graduated reagent supply tubes 4 1 ab and a reagent mixing tube 4 4 .
- the reagent supply tube 4 1 ab is attached to the upper lid portion 4 7 of the reagent mixing tube 4 4. It is attached detachably.
- the reagent supply pipe 41 is composed of a so-called graduated spike composed of a transparent rigid pipe section 42 having a scale and a soft lid section 43 which can be deformed by being pressed from the outside.
- the lid 43 may be a normal soft rubber cap, but is preferably a bellows as shown.
- One of the reagent supply tubes 41 is for an AHMT hydrochloric acid aqueous solution, and the other is for an alkaline aqueous solution.
- a syringe can be used instead of the above-mentioned spid.
- the reagent mixing tube 44 is composed of a hard tube portion 45 and a soft tube portion 46 that can be partially deformed by external pressure, and the lower end portion 48 becomes a thin tube like a spode, and is opened. I have.
- the lower end portion 48 is detachably attached to the insertion hole 28 located just above the filter 21 of the detection tab 2 of the cassette 25. It is preferable that the soft tube portion 46 of the reagent mixing tube 44 is also made of bellows.
- Aldehyde compounds that may coexist in the test gas acetoaldehyde and daltalaldehyde were checked for color development using the AHMT reagent.
- AHMT manufactured by Wako Pure Chemical Industries, Ltd., for aldehyde determination Ca. No.011-08331
- potassium hydroxide manufactured by Wako Pure Chemical Industries, Ltd .: potassium hydroxide pellet first grade Ca. No. 165-03865
- the volume was adjusted to prepare a KOH23% (about 4. IN) solution.
- An oxidizing agent solution was prepared by adding 0.2N KOH (prepared by adding 1 Otnl of the alkaline solution to a volume of 205 ml with distilled water) to 0.75 g of potassium periodate solution 100.
- Figure 1 shows the measurement results.
- Figure 1 shows that the color reaction of AHMT is a reaction unique to formaldehyde, and It shows that the absorbance of light at a wavelength of 550 nm is proportional to the concentration over a wide range of concentration.
- VOCs volatile organic compounds
- Table 1 shows the measurement results of the absorbance.
- Table 1 shows that none of the VOCs, even at very high concentrations of 100 Oppm, developed color with AHTM.
- hydroxide hydroxide (Wako Pure Chemical Co., Ltd .: hydroxide pellet, first grade Ca. No. 165-03865) is added and dissolved in distilled water, and the volume is adjusted with distilled water until the final volume is 10 Oml. Then, a 23% (4.1 N) solution was prepared.
- a formaldehyde solution (manufactured by Wako Pure Chemical Industries, special grade, 37%) was diluted with nitrogen gas using a calibration gas preparation device (manufactured by Gastech: permeator: PD-1B). Test gases containing various concentrations of formaldehyde were prepared.
- a commercially available device manufactured by Riken Keiki Co., Ltd .: Multigas Finder FP-85 was modified and used. This device is located inside the main unit so that the light emitting element (LED) and the light receiving element (PIN type photodiode) can detect the color spot of the filter on the power detection tab.
- LED light emitting element
- PIN type photodiode PIN type photodiode
- Figure 2 shows the response value (%) to the sampling time (the contact time between the test gas and the filter), and Figure 3 shows the response value (%) to the formaldehyde concentration (0 lppm).
- Figure 4 shows the response value (%) to Figure 2 shows that the degree of color development due to formaldehyde increases almost in proportion to the flow time of the test gas, and that the increase in the degree of color development depends on the concentration of formaldehyde in the test gas. Is shown.
- Figure 3 shows a significant correlation in the range of 0.041 ppm when the test gas flows for 180 300 seconds. This result indicates that a concentration of less than 0.08 ppm, which is the WHO environmental standard, can be measured with a measurement time of 180 to 300 seconds.
- Figure 4 shows that under the above measurement conditions, there is no change in chromaticity above a concentration of about 1 ppm.
- the background color development of filters made of various materials moistened with the color reagent solution was evaluated.
- the following filters were cut to a size of 5 ⁇ in diameter and attached to the same detection tab as the detection tab used in Example 1, and the AHMT hydrochloric acid solution and KOH solution prepared in Example 1 were separated separately.
- the filter was wetted and attached to a predetermined position of the measuring device, and gas not containing formaldehyde was sucked into the measuring device and brought into contact with one surface of the filter.
- Figure 5 shows the degree of color development (response value%) with respect to the sampling time in the background (formaldehyde concentration Oppm) when using a cellulose filter and a glass filter.
- Table 2 shows the evaluation results of other filters. Table 2
- Figure 5 shows that the background color (formaldehyde concentration is Oppm) increases with time for the cellulose filter.
- the color hardly develops even after 10 minutes. Therefore, even at a low concentration of formaldehyde SO.0 8 ppm, the color develops sufficiently significantly in a short time.
- the method for measuring the formaldehyde concentration of the present invention uses AHMT as a coloring reagent, as shown in the above-mentioned Reference Example, for an aldehyde compound or a volatile organic compound (VOC) present as a coexisting substance in a test gas. Highly selective for formaldehyde.
- the detection sensitivity is extremely high, as shown in Example 1, in the range of 0.04 to lppm, and the measurement time is 180 to 300 seconds, which is much shorter than the conventional method.
- the above method can be performed extremely easily.
- the present invention provides a method for measuring formaldehyde concentration, which is highly effective for environmental analysis, has a very high formaldehyde selectivity, is highly sensitive and can measure formaldehyde concentration in a very short time, and a measuring apparatus used therefor. Therefore, its significance in the environmental field is extremely large.
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Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP03715426A EP1500930A4 (en) | 2002-04-24 | 2003-03-26 | METHOD FOR MEASURING THE FORMALDEHYDE CONCENTRATION OF GAS AND MEASUREMENT INSTRUMENT |
AU2003227215A AU2003227215A1 (en) | 2002-04-24 | 2003-03-26 | Method of measuring formaldehyde concentration of gas and measuring instrument |
KR10-2004-7016896A KR20040104579A (ko) | 2002-04-24 | 2003-03-26 | 가스 중의 포름알데히드 농도의 측정방법 및 측정장치 |
US10/512,431 US20060018793A1 (en) | 2002-04-24 | 2003-03-26 | Method of measuring formaldehyde concentration of gas and measuring instrument |
CA002487741A CA2487741A1 (en) | 2002-04-24 | 2003-03-26 | Method of measuring formaldehyde concentration of gas and measuring instrument |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2002-122612 | 2002-04-24 | ||
JP2002122612A JP3889989B2 (ja) | 2001-12-17 | 2002-04-24 | ガス中のホルムアルデヒド濃度の測定方法および測定装置 |
Publications (1)
Publication Number | Publication Date |
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WO2003091724A1 true WO2003091724A1 (fr) | 2003-11-06 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/JP2003/003735 WO2003091724A1 (fr) | 2002-04-24 | 2003-03-26 | Procede de mesure de la concentration en formaldehyde d'un gaz et instrument de mesure |
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US (1) | US20060018793A1 (ja) |
EP (1) | EP1500930A4 (ja) |
KR (1) | KR20040104579A (ja) |
AU (1) | AU2003227215A1 (ja) |
CA (1) | CA2487741A1 (ja) |
WO (1) | WO2003091724A1 (ja) |
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CN106872540A (zh) * | 2017-04-21 | 2017-06-20 | 马刚 | 一种甲醛、氨检测装置及其检测方法 |
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DE102005039539B3 (de) * | 2005-08-20 | 2007-01-04 | Albert-Ludwigs-Universität Freiburg | Messvorrichtung zur optischen Bestimmung einer Schadgaskonzentration in Transmission sowie ein Detektionsmittel als auch ein Verfahren hierfür |
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KR100823516B1 (ko) * | 2006-11-21 | 2008-04-21 | 포항공과대학교 산학협력단 | 압저항 캔틸리버를 이용한 포름알데히드 센서 |
US8613214B2 (en) | 2008-01-09 | 2013-12-24 | Orono Spectral Solutions, Inc. | Apparatus and method for determining analyte content in a fluid |
US8393198B2 (en) * | 2008-01-09 | 2013-03-12 | OronoSpectral Solutions, Inc. | Apparatus and method for determining analyte content in a fluid |
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CN102262088A (zh) * | 2011-04-28 | 2011-11-30 | 吉林大学 | 甲醛快速检测装置及其制作方法 |
RU2488092C1 (ru) * | 2012-02-22 | 2013-07-20 | Ильдар Зафирович Денисламов | Способ определения концентрации газа в жидкости |
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CN115494164A (zh) * | 2021-06-18 | 2022-12-20 | 中国科学院大连化学物理研究所 | 一种气固多相催化反应过程中甲醛的检测方法 |
CN113984743B (zh) * | 2021-09-30 | 2022-08-16 | 华南理工大学 | 一种基于纳米复合纤维的甲醛检测试纸及其制备方法和应用 |
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- 2003-03-26 KR KR10-2004-7016896A patent/KR20040104579A/ko active IP Right Grant
- 2003-03-26 EP EP03715426A patent/EP1500930A4/en not_active Withdrawn
- 2003-03-26 CA CA002487741A patent/CA2487741A1/en not_active Abandoned
- 2003-03-26 AU AU2003227215A patent/AU2003227215A1/en not_active Abandoned
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106872540A (zh) * | 2017-04-21 | 2017-06-20 | 马刚 | 一种甲醛、氨检测装置及其检测方法 |
CN117761045A (zh) * | 2023-12-26 | 2024-03-26 | 杭州智泓达科技有限公司 | 一种甲醛显色试纸、其制备方法与应用 |
CN117761045B (zh) * | 2023-12-26 | 2024-05-24 | 杭州智泓达科技有限公司 | 一种甲醛显色试纸、其制备方法与应用 |
Also Published As
Publication number | Publication date |
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EP1500930A1 (en) | 2005-01-26 |
AU2003227215A1 (en) | 2003-11-10 |
CA2487741A1 (en) | 2003-11-06 |
KR20040104579A (ko) | 2004-12-10 |
EP1500930A4 (en) | 2009-05-20 |
US20060018793A1 (en) | 2006-01-26 |
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