WO2002016290A3 - Verfahren zur synthese von terminalen olefinen mit enger molgewichtsverteilung - Google Patents

Verfahren zur synthese von terminalen olefinen mit enger molgewichtsverteilung Download PDF

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Publication number
WO2002016290A3
WO2002016290A3 PCT/EP2001/009756 EP0109756W WO0216290A3 WO 2002016290 A3 WO2002016290 A3 WO 2002016290A3 EP 0109756 W EP0109756 W EP 0109756W WO 0216290 A3 WO0216290 A3 WO 0216290A3
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WO
WIPO (PCT)
Prior art keywords
fraction
olefins
carbon count
synthesising
molar mass
Prior art date
Application number
PCT/EP2001/009756
Other languages
English (en)
French (fr)
Other versions
WO2002016290A2 (de
Inventor
Hans Peter Rath
Helmut Mach
Michael Roeper
Juergen Stephan
Joern Karl
Richard Blackborow
Original Assignee
Basf Ag
Hans Peter Rath
Helmut Mach
Michael Roeper
Juergen Stephan
Joern Karl
Richard Blackborow
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag, Hans Peter Rath, Helmut Mach, Michael Roeper, Juergen Stephan, Joern Karl, Richard Blackborow filed Critical Basf Ag
Priority to AU2002214957A priority Critical patent/AU2002214957A1/en
Publication of WO2002016290A2 publication Critical patent/WO2002016290A2/de
Publication of WO2002016290A3 publication Critical patent/WO2002016290A3/de

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/10—Magnesium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/28—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/30—Tungsten
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/32—Manganese, technetium or rhenium
    • C07C2523/36—Rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/755—Nickel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/20—Carbon compounds
    • C07C2527/232—Carbonates

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Die vorliegende Erfindung betrifft ein Verfahren zur Herstellung von linearen α-Olefinen durch eine isomerisierende Metathesereaktion mit nachfolgender Ethenolyse. Das Verfahren umfaßt die Verfahrensschritte: 1) Einführen einer C4-C10-Olefinenfraktion in eine isomerisierende Metathesereaktion, ii) Auftrennen des erhaltenen Gemischs in a) eine C2-C3-Olefinfraktion, b) eine Fraktion, die Olefine mit der gewünschten Kohlenstoffzahl enthält, c) ein leichte Fraktion, die Olefine mit einer Kohlenstoffzahl von C4 bis unterhalb der Kohlenstoffzahl der gewünschten Fraktion b) enthält und, d) eine schwere Fraktion, die Olefine mit einer Kohlenstoffzahl oberhalb der Kohlensotffzahl der gewünschten Fraktion b) enthält iii) Rückführen der leichten Fraktion C)sowie gegebenenfalls der schweren Fraktion d) in die isomerisierende Metathesereaktion i), iv) Einführen der Fraktion b) sowie gegebenenfalls der Fraktion d) in eine Ethenolysereaktion, v) Isolieren der in iv) hergestellten α-Olefinfraktion. Insbesondere lassen sich mit diesem Verfahren lineare C8-C12-α-Olefin darstellen.
PCT/EP2001/009756 2000-08-23 2001-08-23 Verfahren zur synthese von terminalen olefinen mit enger molgewichtsverteilung WO2002016290A2 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2002214957A AU2002214957A1 (en) 2000-08-23 2001-08-23 Method for synthesising terminal olefins having a limited molar mass distribution

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE2000141345 DE10041345A1 (de) 2000-08-23 2000-08-23 Verfahren zur Synthese von terminalen Olefinen mit enger Molgewichtsverteilung
DE10041345.5 2000-08-23

Publications (2)

Publication Number Publication Date
WO2002016290A2 WO2002016290A2 (de) 2002-02-28
WO2002016290A3 true WO2002016290A3 (de) 2002-06-27

Family

ID=7653496

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2001/009756 WO2002016290A2 (de) 2000-08-23 2001-08-23 Verfahren zur synthese von terminalen olefinen mit enger molgewichtsverteilung

Country Status (3)

Country Link
AU (1) AU2002214957A1 (de)
DE (1) DE10041345A1 (de)
WO (1) WO2002016290A2 (de)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102146031B (zh) 2001-03-26 2014-08-06 陶氏环球技术有限责任公司 不饱和脂肪酸酯或不饱和脂肪酸与低级烯烃的置换方法
EP1501784B1 (de) 2002-04-29 2019-03-13 Dow Global Technologies LLC Integriertes chemisches verfahren zur industriellen nutzung von pflanzensamenölen
CN101003459B (zh) * 2002-10-24 2011-08-10 陶氏环球技术有限责任公司 烯烃易位产物混合物的稳定
JP4779121B2 (ja) 2003-10-09 2011-09-28 ダウ グローバル テクノロジーズ エルエルシー 不飽和アルコールの改良合成方法
DE102004033410A1 (de) * 2004-02-14 2005-09-01 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von Olefinen mit 8 bis 12 Kohlenstoffatomen
US8436110B2 (en) 2008-10-31 2013-05-07 Dow Global Technologies Llc Olefin metathesis process employing bimetallic ruthenium complex with bridging hydrido ligands

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3491163A (en) * 1967-07-17 1970-01-20 Phillips Petroleum Co Preparation of long chain linear olefins
EP0475245A2 (de) * 1990-09-11 1992-03-18 Albemarle Corporation Verfahren zur Herstellung von Alpha-Olefin durch Ethenolyse
US5243120A (en) * 1991-10-30 1993-09-07 Shell Oil Company Process for the production of olefins
WO1994008922A1 (en) * 1992-10-19 1994-04-28 Dsm N.V. Process for the conversion of an olefin or a mixture of olefins
WO1997034854A1 (en) * 1996-03-19 1997-09-25 Shell Internationale Research Maatschappij B.V. Process for the preparation of alpha olefins
DE19827323A1 (de) * 1998-06-19 1999-12-23 Basf Ag Verwendung von metallocenkatalysiert hergestellten Oligodecenen als Komponenten in Schmierstoffen

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3491163A (en) * 1967-07-17 1970-01-20 Phillips Petroleum Co Preparation of long chain linear olefins
EP0475245A2 (de) * 1990-09-11 1992-03-18 Albemarle Corporation Verfahren zur Herstellung von Alpha-Olefin durch Ethenolyse
US5243120A (en) * 1991-10-30 1993-09-07 Shell Oil Company Process for the production of olefins
WO1994008922A1 (en) * 1992-10-19 1994-04-28 Dsm N.V. Process for the conversion of an olefin or a mixture of olefins
WO1997034854A1 (en) * 1996-03-19 1997-09-25 Shell Internationale Research Maatschappij B.V. Process for the preparation of alpha olefins
DE19827323A1 (de) * 1998-06-19 1999-12-23 Basf Ag Verwendung von metallocenkatalysiert hergestellten Oligodecenen als Komponenten in Schmierstoffen

Also Published As

Publication number Publication date
DE10041345A1 (de) 2002-03-07
AU2002214957A1 (en) 2002-03-04
WO2002016290A2 (de) 2002-02-28

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