WO2002000975A1 - Method for producing cellulose fibres - Google Patents
Method for producing cellulose fibres Download PDFInfo
- Publication number
- WO2002000975A1 WO2002000975A1 PCT/AT2001/000212 AT0100212W WO0200975A1 WO 2002000975 A1 WO2002000975 A1 WO 2002000975A1 AT 0100212 W AT0100212 W AT 0100212W WO 0200975 A1 WO0200975 A1 WO 0200975A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- fibers
- filaments
- air
- cellulose
- temperature
- Prior art date
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
- D01D5/088—Cooling filaments, threads or the like, leaving the spinnerettes
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
Definitions
- the invention relates to a method according to the preamble of patent claim 1.
- “Lyocell” is the generic name given by BISFA (The International Bureau for the Standardization of man made fibers) for cellulose fibers which are produced by dissolving cellulose in an organic solvent without the formation of a derivative and extruding fibers from this solution.
- An organic solvent is understood to mean a mixture of an organic chemical and water.
- Such fibers are also known under the term “solvent-spun fibers”.
- As an organic solvent N-methyl-morpholine-N-oxide is used today on a commercial scale.
- PCT-WO 94/28218 describes a method similar to PCT-WO 93/19230. According to this document, the temperature of the cooling air should be kept below 50 ° C.
- PCT-WO 95/02082 A method is known from PCT-WO 95/02082, according to which the spinning hole diameter, the spinning mass output per hole, the titer of the individual filament, the width of the air gap and the humidity of the air in the air gap are kept in certain ranges by means of a mathematical expression should be.
- the temperature of the cooling air In the examples of PCT-WO 95/02082 there is no information about the temperature of the cooling air. In the Descriptions are generally temperatures between 10 ° C and 60 ° C, preferably between 20 ° C and 40 ° C.
- PCT-WO 96/17118 deals with the moisture content of the cooling air.
- the highest temperature of the cooling air specified in this document is 40 ° C.
- the temperature of the cooling air can be 0 ° C to 40 ° C.
- the temperature of the cooling air is given as -10 ° C to 50 ° C.
- PCT-WO 98/58103 describes that with a large number of extruded filaments, i.e. when using spinnerets with a large number of spinning holes, a very humid climate is established in the air gap. In order to ensure the stability of the spinning process even under these conditions, it is proposed in PCT-WO 98/58103 that the spinning solution should contain a certain proportion of cellulose and / or another polymer with a higher molecular weight immediately before spinning.
- a problem with spinning cellulose solutions in NMMO is that in solutions with a high viscosity the spinning solution has to be spun at elevated temperatures.
- High viscosities of the spinning solution result, for example, when the cellulose concentration in the solution is high, which is of course desirable from an economic point of view.
- the temperature of the spinning solution must also be kept high if fibers with a low titer, e.g. want to spin less than 1 dtex. In the case of such fibers, the filaments in the air gap must be stretched particularly strongly. Without increasing the temperature of the spinning solution, the viscosity of the spinning solution would also be too high for this stretching.
- the temperature of the spinning solution should be 80 ° C to 120 ° C, especially 100 ° C to 120 ° C during spinning. Since solutions of cellulose in NMMO are thermally unstable and tend to exothermic decomposition reactions, it is not desirable to increase the temperature of the cellulose solution.
- the present invention has for its object to provide a method according to the generic term with which cellulose solutions of high viscosity can be better spun and fibers with small titers can be better produced.
- This object is achieved in that the temperature (T) of the cooling air before contact with the filaments is 60 ° C ⁇ T ⁇ 90 ° C.
- fibers which are produced using cooling air at higher temperatures have higher strength values than fibers which are produced at the same temperature of the spinning solution using cooling air at a lower temperature.
- the cooling air preferably has a moisture content of 4 g H 2 O / kg air to 15 g H 2 O / kg air.
- the method according to the invention is particularly suitable for producing fibers with a titer of less than 1 dtex.
- a spinning solution with 15% by weight cellulose (cellulose: Cellunier F, manufacturer Rayonnier), 10% by weight water and 75% by weight NMMO was spun into fibers using cooling air at different temperatures.
- the strength of the spun fibers was determined in a conditioned state.
- a spinning solution with 14.6% by weight cellulose (cellulose Borregaard LVU); 9.5% by weight of water and 75.9% by weight of> NMMO was spun into fibers with a titer of 1.3 dtex in a continuous test installation. At various temperatures of the cooling air used, the spinning mass temperature was measured in order to be able to produce fibers with this titer without problems.
- the table shows that when using cooling air at a temperature of 65 ° C it is possible to produce the fibers at a significantly lower temperature of the spinning solution.
- a spinning solution with 15% by weight cellulose (pulp Alicell VLV; manufacturer Western Pulp) 10% by weight) water and 75% by weight o NMMO was spun into fibers using cooling air at different temperatures.
- the minimum achievable titer of the fibers and the strength of the spun fibers in a conditioned state were determined as described in Example 1:
- the table shows that when cooling air with higher temperatures is used, it is possible to produce fibers with a titer of less than 1 dtex.
Abstract
Description
Claims
Priority Applications (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU6712701A AU6712701A (en) | 2000-06-29 | 2001-06-28 | Method for producing cellulose fibres |
JP2002506280A JP2004501296A (en) | 2000-06-29 | 2001-06-28 | Method for producing cellulosic fiber |
AU2001267127A AU2001267127B2 (en) | 2000-06-29 | 2001-06-28 | Method for producing cellulose fibres |
BR0112036-0A BR0112036A (en) | 2000-06-29 | 2001-06-28 | Process for the production of cellulosic fibers |
CA002413706A CA2413706A1 (en) | 2000-06-29 | 2001-06-28 | Process for the production of cellulosic fibres |
DE50102613T DE50102613D1 (en) | 2000-06-29 | 2001-06-28 | METHOD FOR PRODUCING CELLULOSIC FIBERS |
EP01944725A EP1299583B1 (en) | 2000-06-29 | 2001-06-28 | Method for producing cellulose fibres |
AT01944725T ATE269434T1 (en) | 2000-06-29 | 2001-06-28 | METHOD FOR PRODUCING CELLULOSIC FIBERS |
NO20026186A NO20026186D0 (en) | 2000-06-29 | 2002-12-23 | Process for producing cellulose fibers |
US10/330,779 US20030173700A1 (en) | 2000-06-29 | 2002-12-27 | Method for producing cellulose fibres |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT0112100A AT408355B (en) | 2000-06-29 | 2000-06-29 | Process for producing cellulosic fibres |
ATA1121/2000 | 2000-06-29 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/330,779 Continuation US20030173700A1 (en) | 2000-06-29 | 2002-12-27 | Method for producing cellulose fibres |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2002000975A1 true WO2002000975A1 (en) | 2002-01-03 |
Family
ID=3685802
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/AT2001/000212 WO2002000975A1 (en) | 2000-06-29 | 2001-06-28 | Method for producing cellulose fibres |
Country Status (13)
Country | Link |
---|---|
US (1) | US20030173700A1 (en) |
EP (1) | EP1299583B1 (en) |
JP (1) | JP2004501296A (en) |
CN (1) | CN1180142C (en) |
AT (1) | AT408355B (en) |
AU (2) | AU2001267127B2 (en) |
BR (1) | BR0112036A (en) |
CA (1) | CA2413706A1 (en) |
DE (1) | DE50102613D1 (en) |
NO (1) | NO20026186D0 (en) |
TR (1) | TR200401926T4 (en) |
TW (1) | TW534932B (en) |
WO (1) | WO2002000975A1 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT506268B1 (en) * | 2008-01-11 | 2014-08-15 | Chemiefaser Lenzing Ag | MICROFIBRE |
US10920274B2 (en) | 2017-02-21 | 2021-02-16 | Apdn (B.V.I.) Inc. | Nucleic acid coated submicron particles for authentication |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1996017118A1 (en) * | 1994-12-02 | 1996-06-06 | Akzo Nobel N.V. | Method of producing shaped cellulose bodies, and yarn made of cellulose filaments |
WO1999047733A1 (en) * | 1998-03-16 | 1999-09-23 | Weyerhaeuser Company | Lyocell fibers, and compositions for making the same |
WO1999063136A1 (en) * | 1998-06-04 | 1999-12-09 | Lenzing Aktiengesellschaft | Method for producing cellulosic shaped bodies |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ATA53792A (en) * | 1992-03-17 | 1995-02-15 | Chemiefaser Lenzing Ag | METHOD FOR PRODUCING CELLULOSIC MOLDED BODIES, DEVICE FOR IMPLEMENTING THE METHOD AND USE OF A SPINNING DEVICE |
US6221487B1 (en) * | 1996-08-23 | 2001-04-24 | The Weyerhauser Company | Lyocell fibers having enhanced CV properties |
AT405531B (en) * | 1997-06-17 | 1999-09-27 | Chemiefaser Lenzing Ag | METHOD FOR PRODUCING CELLULOSIC FIBERS |
-
2000
- 2000-06-29 AT AT0112100A patent/AT408355B/en not_active IP Right Cessation
-
2001
- 2001-06-28 AU AU2001267127A patent/AU2001267127B2/en not_active Ceased
- 2001-06-28 WO PCT/AT2001/000212 patent/WO2002000975A1/en active IP Right Grant
- 2001-06-28 JP JP2002506280A patent/JP2004501296A/en not_active Abandoned
- 2001-06-28 AU AU6712701A patent/AU6712701A/en active Pending
- 2001-06-28 CN CNB018118291A patent/CN1180142C/en not_active Expired - Fee Related
- 2001-06-28 TW TW090115807A patent/TW534932B/en not_active IP Right Cessation
- 2001-06-28 CA CA002413706A patent/CA2413706A1/en not_active Abandoned
- 2001-06-28 EP EP01944725A patent/EP1299583B1/en not_active Expired - Lifetime
- 2001-06-28 TR TR2004/01926T patent/TR200401926T4/en unknown
- 2001-06-28 BR BR0112036-0A patent/BR0112036A/en not_active IP Right Cessation
- 2001-06-28 DE DE50102613T patent/DE50102613D1/en not_active Expired - Fee Related
-
2002
- 2002-12-23 NO NO20026186A patent/NO20026186D0/en not_active Application Discontinuation
- 2002-12-27 US US10/330,779 patent/US20030173700A1/en not_active Abandoned
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1996017118A1 (en) * | 1994-12-02 | 1996-06-06 | Akzo Nobel N.V. | Method of producing shaped cellulose bodies, and yarn made of cellulose filaments |
WO1999047733A1 (en) * | 1998-03-16 | 1999-09-23 | Weyerhaeuser Company | Lyocell fibers, and compositions for making the same |
WO1999063136A1 (en) * | 1998-06-04 | 1999-12-09 | Lenzing Aktiengesellschaft | Method for producing cellulosic shaped bodies |
Also Published As
Publication number | Publication date |
---|---|
CN1180142C (en) | 2004-12-15 |
AU2001267127B2 (en) | 2005-03-24 |
EP1299583A1 (en) | 2003-04-09 |
JP2004501296A (en) | 2004-01-15 |
EP1299583B1 (en) | 2004-06-16 |
CN1439065A (en) | 2003-08-27 |
NO20026186L (en) | 2002-12-23 |
DE50102613D1 (en) | 2004-07-22 |
US20030173700A1 (en) | 2003-09-18 |
AT408355B (en) | 2001-11-26 |
TR200401926T4 (en) | 2004-09-21 |
AU6712701A (en) | 2002-01-08 |
BR0112036A (en) | 2003-05-13 |
NO20026186D0 (en) | 2002-12-23 |
CA2413706A1 (en) | 2002-12-24 |
ATA11212000A (en) | 2001-03-15 |
TW534932B (en) | 2003-06-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0494852B1 (en) | Process for the production of cellulosic articles | |
EP1763596B1 (en) | Method for the production of molded cellulose bodies | |
DE69723582T2 (en) | REGENERATED CELLULOSE FIBERS AND METHOD FOR THEIR PRODUCTION | |
EP0574870B1 (en) | Process for producing cellulose moulded articles | |
EP2981640B1 (en) | Polysaccharide fibres and method for the production thereof | |
EP2268857B1 (en) | Cellulosic mouldings | |
EP0659219B1 (en) | Cellulose fibres | |
EP2524980A1 (en) | Method for producing precursor fibres and carbon fibres containing lignine | |
DE19537726C2 (en) | Process for the production of mechanically stable polyfilen filament bundles from cellulose with a very high proportion of additives | |
DE4219658C2 (en) | Process for the production of cellulose fiber filaments and foils by the dry-wet extrusion process | |
DE202013011959U1 (en) | Direct-spun cellulose fibers, their preparation and use | |
DE202014105007U1 (en) | regenerated cellulose fibers | |
DE4302055C1 (en) | Cellulose acetate filaments prepd. by spinning from an acetone soln. - are useful for the prodn. of cigarette filter tow | |
EP0918894B1 (en) | Method for producing cellulose fibres | |
AT402739B (en) | METHOD FOR PRODUCING A CELLULOSIC MOLDED BODY | |
EP0918798B1 (en) | Method for the production of cellulosic shaped bodies | |
WO2009012916A2 (en) | Spinning method | |
EP0726974A1 (en) | Process for manufacturing cellulose moulded bodies | |
EP1299583B1 (en) | Method for producing cellulose fibres | |
EP0283831B1 (en) | Process for producing yarns by melt-spinning polyethylene terephthalate | |
EP0918893B1 (en) | Cellulose microfibre | |
DE876290C (en) | Dry spinning process for viscose | |
DD299235A7 (en) | METHOD FOR PRODUCING FIBERS FROM REGENERATED CELLULOSE | |
DE102012016714A1 (en) | Regenerated cellulose fibers which are present as non-fibrillating cellulose filaments present in form of micro- or super-micro-filaments having less titre, useful e.g. as carbon fiber precursors for producing carbon fibers | |
EP2664697A2 (en) | Flame retardant cellulose regenerated fibers and process for their preparation |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): AE AG AL AM AU AZ BA BB BG BR BY BZ CA CH CN CR CU CZ DE DK DM DZ EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT TZ UA UG US UZ VN YU ZA ZW |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR BF BJ CF CG CI CM GA GN GW ML MR NE SN TD TG |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
REG | Reference to national code |
Ref country code: DE Ref legal event code: 8642 |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2001944725 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2001267127 Country of ref document: AU |
|
ENP | Entry into the national phase |
Ref country code: JP Ref document number: 2002 506280 Kind code of ref document: A Format of ref document f/p: F |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2413706 Country of ref document: CA |
|
WWE | Wipo information: entry into national phase |
Ref document number: 018118291 Country of ref document: CN |
|
WWE | Wipo information: entry into national phase |
Ref document number: 10330779 Country of ref document: US |
|
WWP | Wipo information: published in national office |
Ref document number: 2001944725 Country of ref document: EP |
|
WWG | Wipo information: grant in national office |
Ref document number: 2001944725 Country of ref document: EP |
|
WWG | Wipo information: grant in national office |
Ref document number: 2001267127 Country of ref document: AU |