WO2000022348A1 - Dispositif d'evacuation des dechets - Google Patents
Dispositif d'evacuation des dechets Download PDFInfo
- Publication number
- WO2000022348A1 WO2000022348A1 PCT/JP1999/002967 JP9902967W WO0022348A1 WO 2000022348 A1 WO2000022348 A1 WO 2000022348A1 JP 9902967 W JP9902967 W JP 9902967W WO 0022348 A1 WO0022348 A1 WO 0022348A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- ash
- waste
- exhaust gas
- furnace
- incinerator
- Prior art date
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
- F23L9/00—Passages or apertures for delivering secondary air for completing combustion of fuel
- F23L9/02—Passages or apertures for delivering secondary air for completing combustion of fuel by discharging the air above the fire
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/08—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating
- F23G5/14—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating including secondary combustion
- F23G5/16—Incineration of waste; Incinerator constructions; Details, accessories or control therefor having supplementary heating including secondary combustion in a separate combustion chamber
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES
- F23J1/00—Removing ash, clinker, or slag from combustion chambers
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2202/00—Combustion
- F23G2202/10—Combustion in two or more stages
- F23G2202/104—Combustion in two or more stages with ash melting stage
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2900/00—Special features of, or arrangements for incinerators
- F23G2900/00001—Exhaust gas recirculation
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2900/00—Special features of, or arrangements for incinerators
- F23G2900/50204—Waste pre-treatment by pyrolysis, gasification or cracking
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
- F23L2900/00—Special arrangements for supplying or treating air or oxidant for combustion; Injecting inert gas, water or steam into the combustion chamber
- F23L2900/07001—Injecting synthetic air, i.e. a combustion supporting mixture made of pure oxygen and an inert gas, e.g. nitrogen or recycled fumes
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
- F23L2900/00—Special arrangements for supplying or treating air or oxidant for combustion; Injecting inert gas, water or steam into the combustion chamber
- F23L2900/15042—Preheating combustion air by auxiliary combustion, e.g. in a turbine
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/32—Direct CO2 mitigation
Definitions
- the present invention relates to a waste disposal device.
- it relates to a waste incineration melting furnace and a waste incineration heat treatment furnace.
- a rotary kiln type ash melting furnace with a dam is provided at the outlet side of the incinerator, and a heating parner is installed at the outlet side of the ash melting furnace.
- Prior art 3 hereinafter referred to as “prior art 3”)
- FIG. 15 shows a schematic diagram of a typical example (prior art 2).
- 4 1 is a hopper
- 4 2 is a grate
- 4 3 is an ash assembler
- 4 4 is a melting chamber
- 4 5 is a molten slag
- 4 6 is a slag discharge chute
- 4 7 is air preheating. It is a vessel.
- the municipal solid waste put into the hopper 41 is sent to the grate 42 in the incinerator via the dust collector, and moves on the grate 42 due to the air from below and the radiant heat in the furnace. It ignites and burns.
- the ash remaining after the combustion is sent to the melting chamber 44 via the ash hopper 43.
- the ash is melted by the heat of combustion of the unburned matter in the melting wrench or ash and the radiant heat in the furnace, forming molten slag 45, via the slag discharge chute 45. It is discharged outside the furnace. Exhaust gas generated in the ash melting furnace is returned to the incinerator via the air preheater 47.
- preheated air is supplied into the ash melting furnace.
- the flue gas generated in the incinerator is released to the atmosphere via a waste heat boiler, a cooling tower, a bag filter, a smoke exhaust system, and the like.
- the exhaust gas circulating equipment in the incinerator As the exhaust gas circulating equipment in the incinerator, the exhaust gas is conveyed by a circulating blower and blown into the furnace, and as described in Japanese Patent No. 2716141, an ejector using cold air is used. It is known to use the action to transport exhaust gas and blow it into the furnace.
- a circulating blower As the exhaust gas circulating equipment in the incinerator, the exhaust gas is conveyed by a circulating blower and blown into the furnace, and as described in Japanese Patent No. 2716141, an ejector using cold air is used. It is known to use the action to transport exhaust gas and blow it into the furnace.
- a local high-temperature portion may be formed due to the flame of the Pana and the inner wall may be burned out (Prior Art 2, 3).
- the conventional exhaust gas circulation system has the following problems. That is, in the exhaust gas circulation system using a circulation blower,
- High running costs such as electricity costs for blowers and maintenance costs.
- a first waste treatment apparatus comprising:
- Waste incinerator for incineration of waste and generation of ash and flammable gas; Ash incinerator directly connected to the waste incinerator for melting and processing ash; High temperature for generating high-temperature air Air generator; and
- part of the combustible gas (combustion exhaust gas containing unburned components) generated in the waste incinerator and high-temperature air are blown into the ash melting furnace and A swirling flame or a tubular flame having a substantially symmetrical shape is formed. Therefore, the inner wall of the furnace is almost uniformly heated by the radiation or direct heat transfer from these flames. Therefore, the problem of partial solidification of dust / slag or burning due to overheating of the inner wall is suppressed.
- incineration ash and dust in the air current are collected by the slag coating layer on the inner wall surface, so that a high slag conversion rate can be achieved.
- the direction in which the swirling flame or the tubular flame is formed in the ash melting furnace is preferably a direction along the furnace wall of the melting furnace in a direction perpendicular to the flow of the exhaust gas and the incineration ash.
- the high-temperature air generator of the first waste treatment device is preferably a device that generates high-temperature air by heating the air by burning fuel.
- the flue gas of the fuel can be used as a gas for stirring the inside of the incinerator.
- the present invention provides a second waste treatment device comprising:
- Waste incinerator to incinerate waste and produce ash, flammable gas and exhaust gas
- An ash melting furnace directly connected to the waste incinerator for melting ash; and a portion of the combustible gas generated in the waste incinerator to form a swirling flame or a tubular flame; A device that blows the oxidizing agent whose concentration has been adjusted into the ash melting furnace.
- swirling flames or tubular flames having a substantially symmetric shape with respect to the furnace axis are formed in the ash melting furnace, and the inner wall of the furnace is made substantially uniform by radiation from these flames. Heated. Therefore, burning due to partial solidification of dust / slag or overheating of the inner wall is suppressed.
- incineration ash and dust in the air current are collected by the slag coating layer on the inner wall surface, so that a high slag conversion rate can be achieved.
- the oxygen concentration in the oxidizing agent when the oxygen concentration in the oxidizing agent is set to a high value, the absolute flow rate of the oxidizing agent is reduced, so that the residence time of the airflow in the ash melting furnace is prolonged. Can be achieved. Also, by setting the oxygen concentration in the oxidizing agent low, low N ⁇ X combustion can be realized in the ash melting furnace.
- the oxidizing agent is preferably a mixed gas of oxygen and a part of exhaust gas generated in the waste incinerator. Since the sensible heat of the incineration exhaust gas and the unreacted oxygen can be effectively used, the combustion reaction in the ash melting furnace is promoted, and the temperature in the melting furnace can be increased with lower cost. Also, since the amount of nitrogen is smaller than when air is used, the gas volume can be reduced, and the exhaust gas treatment system can be downsized. It is preferable that the first waste treatment device and the second waste treatment device have an adjusting device for adjusting the temperature of the high-temperature air or the oxidizing agent whose oxygen concentration is adjusted.
- the first waste treatment device and the second waste treatment device further include an auxiliary fuel supply device for adjusting the temperature in the ash melting furnace.
- the temperature inside the ash melting furnace can be directly adjusted, so if the furnace condition on the incinerator side suddenly deteriorates, or the spout seems to be clogged for some reason. In the case of, the temperature inside the ash melting furnace can be quickly readjusted without changing the operating conditions on the incinerator side. Therefore, the operation rate of the plant can be maintained at a high level. Also, by supplying fuel into the ash melting furnace, the temperature inside the ash melting furnace can be adjusted independently of the incinerator side, so that the work time for plant startup and shutdown can be shortened.
- the first waste treatment device and the second waste treatment device further include a supply device for supplying a carbon-containing fuel as an auxiliary fuel for adjusting the temperature in the ash melting furnace; It is more preferable to have a stirring means provided for stirring the fuel and the ash.
- a carbon-containing fuel is used as the auxiliary fuel and means for stirring the fuel and the ash are provided in the ash melting furnace, the ash can be melted in a reducing atmosphere. As a result, the volatilization of heavy metals in the ash is promoted, and the decomposition rate of dioxins can be increased. If the carbon-containing fuel has a small particle size, such as fine coke, and is well associated with the airflow in the furnace, it is pressed against the inner wall by the centrifugal effect of the swirling flow in the furnace. It goes without saying that a certain degree of fuel dispersibility can be ensured without a means for stirring.
- the ash melting furnace is such that a downstream side is gradually narrowed toward an outlet. Since the shape of the ash melting furnace gradually narrows toward the outlet, the swirling velocity of the air flow increases toward the downstream side. As a result, the efficiency of collecting ash and dust is improved, and the inner wall can be more effectively heated by the flame. The slag is concentrated in one place, so the gate is difficult to close, and the furnace gas Merits such as low pollution of exhaust gas are realized because mixing is promoted.
- the first waste treatment device and the second waste treatment device further include:
- a hazardous waste supply device for injecting gaseous, liquid or particulate hazardous waste into or upstream of the ash melting furnace
- An exhaust gas treatment device provided downstream of the ash melting furnace is preferred.
- harmful substances such as CFCs, waste oil, and PCBs can be treated in the ash melting furnace, so that energy saving and multi-functionality can be realized as a waste treatment device.
- the first waste treatment device and the second waste treatment device are further provided with an unsuitable material disposed on the upstream side of the ash melting furnace for detecting and removing unsuitable molten material in the incinerated ash. It is desirable to have a removal device.
- the ash melting furnace is a rotary kiln type ash melting furnace.
- the present invention provides a third waste disposal apparatus comprising:
- Waste incinerator to incinerate waste and produce ash
- An ash melting furnace directly connected to the waste incinerator through a communication portion for melting ash;
- Dumbers installed in the communication section to control the flow of incineration exhaust gas from the waste incinerator to the ash melting furnace.
- low-temperature incineration exhaust gas can be suppressed from entering the ash melting furnace by adjusting the opening degree of the damper, so that the inside of the ash melting furnace is maintained at a high temperature, stable tapping can be realized, and heating should be performed. Since the absolute amount of gas is reduced, energy saving can be achieved. In addition, since chlorine, which is one of the constituent elements of dioxins, can be suppressed from entering the ash melting furnace together with the incineration exhaust gas, the generation of dioxins downstream from the ash melting furnace can be suppressed.
- Adjustment of the damper opening is performed as follows. That is, the furnace pressures of the waste incinerator and the ash melting furnace are respectively detected, and the damper opening is adjusted so that the furnace pressure of the ash melting furnace becomes slightly higher than the furnace pressure of the waste incinerator. . Even if it is unavoidable that the pressure inside the ash melting furnace must be lower than the pressure inside the waste incinerator, the damper opening should be adjusted so that the differential pressure becomes small. It is preferable that the first, second and third waste treatment apparatuses have an ejector for transporting exhaust gas from the waste incinerator using high-temperature air as a driving flow and injecting the waste gas into the waste incinerator. .
- the waste gas from the waste incinerator (often the secondary combustion exhaust gas at the outlet of the waste heat boiler) is transported and injected into the waste incinerator by a single ejector using hot air as the driving flow. Therefore, the exhaust gas can be blown into the furnace at high speed by utilizing the high viscosity and kinetic energy of the high-temperature air. Also, the action of this jet makes it possible to directly control the furnace flame. Furthermore, since the temperature of the mixture of high-temperature air and exhaust gas is high, the mixture becomes highly viscous and is stirred in the furnace. Can be performed more effectively.
- the required power for exhaust gas circulation is smaller than that of a blower or the like, so that energy can be saved.
- stable transportation of high-temperature dust-containing gas is possible, so that high-temperature exhaust gas containing flammable gas can be recirculated, improving heat efficiency and leading to energy savings.
- the ejector 1 may be provided in the exhaust gas circulation path, or may be provided in the blowing port into the furnace.
- the first, second and third waste treatment equipment have ejectors to transport flammable gas generated in the waste incinerator using hot air as a driving flow and to blow it into the ash melting furnace. Is preferred.
- An ejector that uses high-temperature air as the driving flow transports exhaust gas containing flammable gas in the waste incinerator (primary combustion exhaust gas generated in the waste incinerator) and blows it into the ash melting furnace.
- the exhaust gas can be blown into the furnace at high speed by utilizing the high viscosity and kinetic energy of high-temperature air.
- the action of this jet makes it possible to directly control the furnace flame. As a result, the flame in the furnace is stabilized, leading to lower pollution and higher operating rates.
- the temperature of the air-fuel mixture of the high-temperature air and the exhaust gas is high, the air-fuel mixture becomes highly viscous, and the furnace can be stirred more effectively. Therefore, low air ratio combustion becomes possible, and the amount of exhaust gas is reduced, leading to energy saving.
- the required power for exhaust gas circulation is less than that of a blower or the like, so that energy can be saved.
- stable transportation of high-temperature dust-containing gas is possible, so that high-temperature exhaust gas can be recirculated, improving thermal efficiency and conserving energy.
- the ejector 1 may be provided in the exhaust gas circulation passage, or may be provided in a blow port into the furnace. However, in the former case, a flame is formed just downstream of the ejector, so it is necessary to implement fireproof construction downstream of the ejector.
- the first, second and third waste treatment equipment transport the waste gas from the waste incinerator using the exhaust gas downstream of the induction fan installed in the exhaust gas emission system as a driving flow, and place it in the waste incinerator.
- An ejector for injecting, or an ejector for transporting flammable gas generated in a waste incinerator using the exhaust gas downstream of an induction fan installed in an exhaust gas diffusion system and injecting it into the ash melting furnace It is preferred to have the device.
- the present invention provides a fourth waste disposal apparatus comprising:
- Waste incinerator to incinerate waste and produce ash
- the waste incinerator is an exhaust gas recirculation incinerator having an exhaust gas circulation blower for circulating exhaust gas discharged from the incinerator;
- An ash melting furnace directly connected to the waste incinerator for melting ash; means for sucking exhaust gas from the ash melting furnace using the exhaust gas circulation pipe and circulating the exhaust gas into the waste incinerator;
- An exhaust gas recirculation incinerator is a type of incinerator in which part of the exhaust gas discharged from the incinerator is blown back into the incinerator and used for combustion.
- the unburned gas in the upstream area of the incinerator can be drawn into the ash melting furnace via the bypass by sucking the ash melting furnace exhaust gas using the incinerator exhaust gas circulation program.
- the exhaust gas from the ash melting furnace is returned to the incinerator through the circulation blower of the incinerator, which improves thermal efficiency and eliminates the need for the ash melting furnace to be equipped with an exhaust gas treatment device by itself. It also reduces. Furthermore, when combined with a damper to suppress inflow of incineration exhaust gas from the waste incinerator to the ash melting furnace, the damper prevents excessive invasion of the incineration exhaust gas from the inlet of the ash melting furnace. be able to.
- the waste incinerator is a double-flow grate incinerator comprising a main combustion chamber having an intermediate ceiling.
- the intermediate ceiling in the incinerator clearly separates the exhaust gas containing a large amount of unburned gas and the exhaust gas containing a large amount of unreacted oxygen, and the composition of these components is relatively stable.
- the main heat source (flammable gas) of the melting furnace it is possible to more effectively realize long-term stable operation and energy saving of the ash melting furnace.
- Each of the first, second, third and fourth waste treatment apparatuses has an apparatus for adjusting at least one of a fuel and an oxidizing agent so that the inside of the ash melting furnace has a reducing atmosphere. It is desirable to do.
- the fuel or oxidizing agent to be adjusted may be the one charged into a waste incinerator or the one charged into an ash melting furnace. Further, the present invention provides a fifth waste disposal apparatus comprising:
- Waste incinerator for incinerating waste and producing ash and combustible gas
- Ash heat treatment furnace directly connected to the waste incinerator for heat treating ash
- Hot air for generating hot air Generator
- part of the combustible gas (combustion exhaust gas containing unburned components) generated in the waste incinerator and high-temperature air are blown into the ash heat treatment furnace, and A swirling flame or a tubular flame having a substantially symmetrical shape is formed. Therefore, the inner wall of the furnace is almost uniformly heated by the radiation or direct heat transfer from these flames. Therefore, the problem of partial solidification of dust / slag or burning due to overheating of the inner wall is suppressed.
- a radially outward force acts on the incinerated ash and dust in the airflow, and the ash is pressed against the inner wall. Scattering of dust and dust outside the furnace can be suppressed.
- the direction in which the swirling flame or tubular flame is formed in the ash heat treatment furnace is preferably a direction along the furnace wall of the heat treatment furnace in a direction perpendicular to the flow of the exhaust gas and the incineration ash.
- the high-temperature air generator is an apparatus that heats air by burning fuel to generate high-temperature air.
- the combustion exhaust gas of the fuel is used as a gas for stirring the inside of the incinerator.
- the present invention provides a sixth waste disposal apparatus comprising:
- a swirling flame or a tubular flame having a substantially symmetrical shape with respect to the furnace axis is formed, and the inner wall of the furnace is heated substantially uniformly by radiation from these flames. Therefore, it is possible to prevent the solidification of the dust / slag or the trouble of burning due to overheating of the inner wall. Furthermore, the incineration ash and dust in the air current are pressed against the surface of the inner wall by the centrifugal effect of the swirling flow in the ash heat treatment furnace, so that ash scattering can be suppressed.
- the oxygen concentration in the oxidizing agent is set to a high value, so that the absolute flow rate of the oxidizing agent is reduced, so that the residence time of the airflow in the ash melting furnace is prolonged. Can be suppressed. Also, by setting the oxygen concentration in the oxidizer low, low NOX combustion can be realized in the ash heat treatment furnace.
- the oxidizing agent is a mixed gas of a part of the combustible gas generated in the waste incinerator and oxygen. Sensible heat of incineration exhaust gas ⁇ Since unreacted oxygen can be used effectively, the combustion reaction in the ash heat treatment furnace is promoted, and higher temperatures in the ash heat treatment furnace can be realized at lower cost.
- the fifth and sixth waste treatment apparatuses have an adjusting apparatus for adjusting the temperature of the high-temperature air or the oxidizing agent whose oxygen concentration is adjusted. Waste Even when the furnace conditions on the incinerator side change and the properties of incineration exhaust gas and incineration ash fluctuate, the temperature of the high-temperature air or the oxidizing agent whose oxygen concentration is adjusted is adjusted, and the ash heat treatment furnace is always Temperature is maintained within an appropriate range, and stable operation can be realized for a long time.
- the fifth and sixth waste treatment apparatuses preferably have a supplementary fuel supply apparatus for adjusting the temperature in the ash heat treatment furnace. Since the temperature inside the ash heat treatment furnace can be directly adjusted, the operating conditions on the incinerator side should be changed when the furnace condition on the incinerator side suddenly deteriorates or when the gate becomes slightly clogged for some reason. The temperature inside the ash heat treatment furnace can be readjusted quickly without the need for reheating. Therefore, the operation rate of the plant can be maintained at a high level.
- the fifth waste treatment device and the sixth waste treatment device further include a supply device that supplies a carbon-containing fuel as an auxiliary fuel for adjusting the temperature in the ash heat treatment furnace; It is more preferable to have a stirring means provided in the heat treatment furnace for stirring the fuel and the ash.
- a carbon-containing fuel is used as the auxiliary fuel and means for stirring the fuel and the ash are provided in the ash heat treatment furnace, the ash can be heat-treated in a reducing atmosphere. As a result, the decomposition rate of dioxins in the ash can be increased. If the carbon-containing fuel has a small particle size, such as fine coke, and has good entrainment with the airflow in the furnace, it is pressed against the inner wall by the centrifugal effect of the swirling flow in the furnace. Therefore, it is needless to say that a certain degree of fuel dispersibility can be ensured even if there is no means for stirring.
- the ash heat treatment furnace is such that a downstream side is gradually narrowed toward an outlet. Since the shape of the ash heat treatment furnace gradually narrows toward the outlet, the swirling velocity of the air flow increases toward the downstream side. As a result, the collection efficiency of ash and dust is increased, and the inner wall can be more effectively heated by the flame.
- the outlet is blocked because the ash and dust are concentrated in one place under the influence of gravity. It also has the added advantage that it becomes more difficult and that the mixing of the furnace gas is promoted, thereby reducing the pollution of exhaust gas.
- a hazardous waste supply device for injecting gaseous, liquid, or particulate hazardous waste into or upstream of the ash heat treatment furnace
- the fifth waste treatment apparatus and the sixth waste treatment apparatus have an unsuitable material removing device for detecting and removing unsuitable heat treatment in incinerated ash on the upstream side of the ash heat treatment furnace. Unsuitable heat treatment is detected and removed upstream of the ash heat treatment furnace, eliminating incineration ash shelves near the entrance of the ash heat treatment furnace and obstruction of the outlet, and stable heat for a long time Processing can be realized.
- the average temperature in the furnace can be set lower, so that energy saving and lower exhaust gas emissions can be achieved.
- the ash heat treatment furnace is a rotary kiln type ash heat treatment furnace. Because the ash heat treatment furnace is inclined downward and rotates downstream, even if unsuitable heat treatment is present, the incinerated ash is forcibly transported to the downstream without accumulating in the furnace. can do.
- the present invention provides a seventh waste disposal apparatus comprising:
- Waste incinerator to incinerate waste and produce ash
- An ash heat treatment furnace directly connected to the waste incinerator through a communication portion for heat-treating ash;
- a damper installed in the communication section to control the flow of incineration exhaust gas from the waste incinerator to the ash heat treatment furnace.
- Adjustment of the damper opening is performed as follows. That is, the pressures in the waste incinerator and the ash heat treatment furnace are detected separately, and the damper opening is adjusted so that the pressure in the ash heat treatment furnace is slightly higher than the pressure in the waste incinerator. . Even if it is unavoidable that the pressure inside the ash heat treatment furnace must be lower than the pressure inside the waste incinerator, the damper opening should be adjusted so that the pressure difference becomes small.
- the fifth, sixth, and seventh waste treatment equipment should have an ejector for conveying the exhaust gas from the waste incinerator using hot air as a driving flow and blowing it into the waste incinerator. preferable.
- the waste gas from the waste incinerator (often the secondary combustion exhaust gas at the outlet of the waste heat boiler) is transported and injected into the waste incinerator by a single ejector using hot air as the driving flow. Therefore, the exhaust gas can be blown into the furnace at high speed by utilizing the high viscosity and kinetic energy of the high-temperature air. Also, the action of this jet makes it possible to directly control the furnace flame. Further, since the temperature of the air-fuel mixture of the high-temperature air and the exhaust gas is high, the air-fuel mixture becomes highly viscous, and the stirring in the furnace can be performed more effectively.
- the required power for exhaust gas circulation is less than that of a blower or the like, so that energy can be saved.
- stable transportation of high-temperature dust-containing gas is possible, so that high-temperature exhaust gas containing flammable gas can be recirculated, improving heat efficiency and leading to energy savings.
- the ejector 1 may be provided in the exhaust gas circulation path, or may be provided in the blowing port into the furnace.
- the fifth, sixth and seventh waste treatment equipment transports the flammable gas generated in the waste incinerator using high-temperature air as a driving flow and blows it into the ash heat treatment furnace. It is preferred to have a device.
- the exhaust gas in the waste incinerator (primary combustion exhaust gas generated in the waste incinerator) is transported by an ejector device that uses high-temperature air as the driving flow, it is blown into the ash heat treatment furnace.
- exhaust gas can be blown into the furnace at high speed.
- the action of this jet makes it possible to directly control the furnace flame. Therefore, the flame in the furnace is stabilized, which leads to lower pollution and higher operating rate.
- the temperature of the air-fuel mixture of the high-temperature air and the exhaust gas is high, the air-fuel mixture becomes highly viscous, and the furnace can be stirred more effectively.
- the ejector 1 may be provided in the exhaust gas circulation passage, or may be provided in a blow port into the furnace. However, in the former case, since a flame is formed immediately downstream of the ejector, it is necessary to implement refractory work downstream of the ejector.
- the fifth, sixth, and seventh waste treatment equipment transport waste gas from the waste incinerator using the exhaust gas downstream of the induction fan installed in the exhaust gas emission system as a driving flow, and place it in the waste incinerator.
- An ejector for injecting, or an ejector for transporting the combustible gas generated in the waste incinerator using the exhaust gas downstream of the induction fan installed in the exhaust gas diffusion system and injecting it into the ash heat treatment furnace It is preferred to have the device.
- the present invention provides an eighth waste disposal apparatus comprising:
- Waste incinerator to incinerate waste and produce ash
- the waste incinerator is an exhaust gas recirculation incinerator having an exhaust gas circulation blower for circulating exhaust gas discharged from the incinerator;
- An ash heat treatment furnace that is directly connected to the waste incinerator and heat-treats the ash; means for sucking exhaust gas from the ash heat treatment furnace using the exhaust gas circulation blower and circulating the exhaust gas into the waste incinerator;
- An exhaust gas recirculation incinerator is a type of incinerator in which part of the exhaust gas discharged from the incinerator is blown back into the incinerator and used for combustion.
- the exhaust gas from the ash heat treatment furnace is sucked using an incinerator exhaust gas circulation
- Unburned gas in the upstream area of the incinerator can be drawn into the ash heat treatment furnace via a bypass, eliminating the need for installing a special blower for blowing combustion exhaust gas into the ash heat treatment furnace and realizing energy savings.
- the exhaust gas from the ash heat treatment furnace is returned to the incinerator via the circulating blower of the incinerator, improving thermal efficiency and eliminating the need for an ash heat treatment furnace to be equipped with an exhaust gas treatment device alone, reducing equipment costs. It also becomes. Furthermore, when combined with a damper to suppress the inflow of incineration exhaust gas from the waste incinerator to the ash heat treatment furnace, the damper prevents excessive invasion of the incineration exhaust gas from the inlet of the ash heat treatment furnace. Can be.
- the waste incinerator is a double-flow grate incinerator comprising a main combustion chamber having an intermediate ceiling.
- the intermediate ceiling in the incinerator clearly separates the exhaust gas containing a large amount of unburned gas and the exhaust gas containing a large amount of unreacted oxygen, and the composition of these components is relatively stable.
- the apparatus has a temperature control device for controlling the temperature in the ash heat treatment furnace to 800 ° C. or more and the ash melting temperature or less. preferable.
- an apparatus for adjusting at least one of a fuel and an oxidant so that the inside of the ash heat treatment furnace has a reducing atmosphere is provided. Is preferred.
- the fuel or oxidizing agent to be adjusted may be the one charged into a waste incinerator or the one charged into an ash heat treatment furnace.
- FIG. 1 is a diagram showing an example of an embodiment of the present invention.
- FIG. 2 is a diagram showing a system of exhaust gas, steam, etc. in a waste incineration melting furnace which is an example of an embodiment of the present invention.
- FIG. 3 is a diagram showing details of an example of an ash melting furnace which is an example of an embodiment of the present invention.
- FIG. 4 is a diagram showing details of a tapered flue, a connecting portion between a melting unsuitable object detection / removal unit and an ash melting furnace in one example of the embodiment of the present invention.
- FIG. 5 is a diagram showing the details of an unsuitable molten object detection / removal unit according to an example of an embodiment of the present invention.
- FIG. 6 is a diagram showing an example of an embodiment of the present invention in which the ash melting furnace is a low-melt kiln type.
- FIG. 7 is a schematic diagram showing a circulation system of combustion gas and combustion exhaust gas in a furnace using an ejector device according to an example of an embodiment of the present invention.
- FIG. 8 is a diagram showing an example of an embodiment of the present invention.
- FIG. 9 is a diagram showing a system of exhaust gas, steam, and the like in a waste incineration / ash heat treatment furnace which is an example of an embodiment of the present invention.
- FIG. 10 is a diagram showing details of an example of an ash heat treatment furnace which is an example of an embodiment of the present invention.
- FIG. 11 is a diagram showing details of a tapered flue, a connecting portion between a heat treatment unsuitable object detection / removal unit and an ash heat treatment furnace in one example of an embodiment of the present invention.
- FIG. 12 is a diagram showing details of a heat treatment inappropriate object detection / removal unit in one example of the embodiment of the present invention.
- FIG. 13 is a diagram showing an example of an embodiment of the present invention in which the ash heat treatment furnace is a rotary kiln type.
- FIG. 14 is a schematic diagram showing a circulation system of combustion gas and combustion exhaust gas in a furnace using an ejector device according to an example of an embodiment of the present invention.
- FIG. 15 is a diagram showing an example of a conventional waste incineration melting furnace. BEST MODE FOR CARRYING OUT THE INVENTION An embodiment of the present invention will be described with reference to the drawings.
- FIG. 1 is a diagram showing an example of an embodiment of the present invention. In Fig.
- 1, 1 is a scallop
- 2 is garbage
- 3 is a main combustion chamber
- 4 is an incineration ash
- 5 is a tapered flue
- 6 is a part for detecting and removing unsuitable molten material
- 7 is a grid
- 8 is an ash melting furnace
- 9 is molten slag
- 10 is a slag conveyor
- 1 1 is a slag reservoir
- 1 2 is an adjustment damper
- 13 is a dust remover
- 14 is a heat exchanger
- 15 is an exhaust gas circulation blower
- 16 is an intermediate ceiling
- 1 Reference numeral 8 denotes a waste heat poirer
- 19 denotes an outlet for stirring gas in the furnace
- 20 denotes a gas outlet.
- the refuse 2 charged in the hopper 1 is ignited and burned by hot air from below the grate in the main combustion chamber 3 or by a combustion assist wrench (not shown) installed in the main combustion chamber 3.
- the incineration ash 4 generated by the combustion passes through the tapered flue 5 and enters the unsuitable molten material detection / removal unit 6.
- the unsuitable molten material detection / removal unit 6 is provided with a detector of unsuitable molten material and a device for discharging the detected unsuitable molten material to the outside of the furnace.
- the incinerated ash 4 from which unsuitable molten materials have been removed falls through the grid 7 and is melted in the ash melting furnace 8 to become molten slag 9, which falls on the slag conveyor 10 and is stored in the slag reservoir 11
- molten slag 9 which falls on the slag conveyor 10 and is stored in the slag reservoir 11
- the molten slag can be dropped into water to form granulated slag.
- An adjustment damper 12 is provided between the ash melting furnace 8 and the unsuitable melting detection / removal unit 6 to control the amount of exhaust gas entering the ash melting furnace 8 from the waste incinerator. Exhaust gas is prevented from flowing. It should be noted that, without providing the adjustment damper 12, the operation may be performed such that the incineration ash 4 is always filled upstream of the ash melting furnace 8 to form a material seal.
- a gas outlet 20 is provided in the ash melting furnace 8, and as shown in the A-A 'cross-sectional view, the gas outlet 20 allows the gas to be discharged into the waste incinerator.
- a mixture of generated combustible gas (unburned gas in the incinerator) and high-temperature air is blown into the furnace at high speed.
- the blowing direction of the high-temperature gas mixture is tangential to the inner wall of the ash-melting furnace 8 as seen in the A-A 'cross-sectional view. Turning flame as shown in Produces a tubular flame.
- the inner wall of the furnace is almost uniformly heated by the radiation or direct heat transfer from these flames. Therefore, it is possible to suppress partial solidification of dust and slag or burnout trouble due to overheating of the inner wall.
- incineration ash and dust in the air current are collected by the slag coating layer on the inner wall surface, so that a high slag conversion rate can be achieved.
- Exhaust gas generated by burning the unburned gas in the incinerator in the ash melting furnace 8 is introduced into the exhaust gas circulation system of the waste incinerator, dust is removed by the dust remover 13, and cooled by the heat exchanger 14. After that, it is mixed with oxygen through the exhaust gas circulation blower 15 and blown into the waste incinerator again.
- an independent blower may be installed, and the exhaust gas passing through the ash melting furnace 8 may be pressurized and used as a stirring gas in the secondary combustion chamber 17 described later.
- An intermediate ceiling 16 is provided in the main combustion chamber 3 so that the flow of exhaust gas is divided into two as shown by arrows in the figure.
- the exhaust gas passing through the upper part of the intermediate ceiling 16 contains a large amount of unburned gas, and the exhaust gas passing through the lower part of the intermediate ceiling 16 contains a large amount of unreacted oxygen. I have.
- a part of the exhaust gas passing through the upper part of the intermediate ceiling 16 that is, the exhaust gas containing a large amount of unburned gas is taken out and blown into the ash melting furnace 8 as unburned gas in the incinerator, and the ash melting is performed.
- the exhaust gas passing through the lower part of the intermediate ceiling 16 contains a small amount of unburned components, so if it is put into the ash melting furnace 8, it does not serve as fuel, but rather the ash melting furnace 8 It is harmful to lower the temperature.
- the above-described adjustment damper 12 is provided to prevent the exhaust gas from flowing into the ash melting furnace 8. Specifically, the pressure in the furnace near the boundary between the main combustion chamber 3 and the tapered flue 5 and the pressure in the ash melting furnace 8 are detected, and the damper 1 is maintained so that the latter pressure is slightly higher than the former pressure. Adjust the opening of 2. Depending on the furnace design conditions, the latter pressure may have to be lower than the former pressure (for example, in the embodiment shown in Fig.
- the exhaust gas circulation blower 15 Since the unburned gas is drawn into the ash melting furnace 8, the pressure of the latter is lower than the pressure of the former.) Even in this case, the pressure difference between the two is kept small and exhaust gas is reduced as much as possible. The opening so that it does not flow into the ash melting furnace through the furnace.
- a gas obtained by mixing exhaust gas passing through an exhaust gas circulation blower 15 with oxygen is blown into the main combustion chamber 3 from the lower part of the grate.
- the grate may be corroded. In such a case, it is preferable to blow air from under the grate, and to blow a mixed gas of oxygen and exhaust gas directly into the main combustion chamber.
- the high-temperature air blown into the ash melting furnace 8 is produced by heating the air by a high-temperature air generator not shown. Generally, fuel is burned and the heat heats the air. If the combustion exhaust gas at this time is used as the stirring gas blown out from the outlet 19 of the stirring gas in the furnace, the inside of the furnace can be stirred without changing the excess air ratio, and the combustion in the furnace is promoted. At the same time, it is also effective in reducing exhaust gas NOx. Also, the sensible heat of the combustion exhaust gas of the high-temperature air generator can be recovered by the waste heat boiler 18.
- the ash melting furnace 8 is blown with a mixture of natural gas and high-temperature air in the incinerator, but an oxidizing agent whose oxygen concentration is adjusted may be used instead of the high-temperature air.
- the oxidizing agent can be produced, for example, by mixing oxygen and exhaust gas from a waste incinerator.
- the oxygen concentration in the oxidizing agent is set to a high value, the absolute flow rate of the oxidizing agent decreases, so that the residence time of the airflow in the ash melting furnace increases. Therefore, a higher slag conversion rate can be achieved.
- the oxygen concentration in the oxidizer low, low NOX combustion can be realized in the ash melting furnace.
- the temperature in the ash melting furnace 8 it is preferable to detect the temperature in the ash melting furnace 8 and adjust the temperature of the high-temperature air or the oxidizing agent whose oxygen concentration is adjusted so as to keep this temperature constant.
- the temperature in the ash melting furnace 8 it is preferable to detect the temperature in the ash melting furnace 8 and adjust the temperature of the high-temperature air or the oxidizing agent whose oxygen concentration is adjusted so as to keep this temperature constant.
- an auxiliary fuel supply device may be provided to blow the auxiliary fuel into the ash melting furnace 8 and adjust the amount of the auxiliary fuel to adjust the temperature in the ash melting furnace 8.
- the temperature in the ash melting furnace 8 can be accurately controlled, so that if the furnace condition on the incinerator side suddenly deteriorates, or if the gate becomes slightly blocked for some reason, the incinerator The temperature in the ash melting furnace can be readjusted quickly without changing the operating conditions on the side. Therefore, the operation rate of the plant can be maintained at a high level.
- the temperature inside the ash melting furnace can be adjusted independently of the incinerator, the time required for plant startup and shutdown can be shortened.
- a fuel containing carbon for example, a powdered fuel.
- the injected carbon-containing fuel is pressed against the inner wall by centrifugal force in the same manner as the ash, and the carbon-containing fuel is burned at this location. This further promotes the volatilization of heavy metals from the ash. Further, since the vicinity of the inner wall is also in a reducing atmosphere, burning of the inner wall is suppressed. As a result, the operating rate of the equipment is increased, and there is an effect of reducing repair costs such as replacement of furnace materials.
- FIG. 2 shows a system of exhaust gas, steam, and the like in a waste incineration melting furnace which is an example of an embodiment of the present invention.
- the oxygen separated from the air by the oxygen production device is mixed with the exhaust gas from the exhaust gas circulation system in a mixer, and is blown into an incinerator to burn refuse.
- Most of the exhaust gas from the incinerator flows into an exhaust gas circulation system consisting of a dust remover, a heat exchanger, and a blower, is mixed with oxygen in a mixer, and is blown into the incinerator again. In this case, air is blown from below the grate, and the exhaust gas mixed with oxygen in the mixer is blown directly into the combustion chamber.
- Part of the exhaust gas that does not flow to the exhaust gas circulation system flows into the ash melting furnace 8 as described above, and another part flows into the exhaust gas treatment equipment.
- Exhaust gas that has been burned in the ash melting furnace to heat the incinerated ash is guided to the dust remover and enters the exhaust gas circulation system as described above.
- the exhaust gas that has flowed into the exhaust gas treatment facility is released to the atmosphere from the chimney after removing moisture. If a CO 2 fixation device is provided, the CO 2 in the exhaust gas will be fixed and will not be released to the atmosphere.
- the water removed in the exhaust gas treatment facility is released after being treated in the wastewater treatment facility.
- the sensible heat of exhaust gas from incinerators is used to generate steam in an exhaust gas boiler, and the generated steam is used for power generation plans.
- the heat exchanger is used to heat the water supply to the waste heat boiler.
- FIG. 3 shows details of an example of an ash melting furnace according to an embodiment of the present invention.
- 21 is a gas inlet in the incinerator
- 22 is a high-temperature air inlet
- 23 is an outlet.
- the ash melting furnace 8 is a furnace having a substantially circular cross section, and the downstream side thereof becomes gradually narrower as approaching the outlet 23.
- a gas outlet 20 is provided at a part of the side wall on the upstream side, and is connected to the gas inlet 21 and the high-temperature air inlet 22 in the incinerator. Exhaust gas blown from the gas inlet 21 in the incinerator furnace and high-temperature air blown from the high-temperature air inlet 22 are mixed at the gas outlet 20 and the ash melting furnace has a substantially circular cross-section. Is blown in the tangential direction, that is, along the circumference. As a result, a swirling flame or a tubular flame substantially symmetrical with respect to the furnace axis is formed.
- the inner wall of the furnace is almost uniformly heated by the radiation or direct heat transfer from these flames. Therefore, burning due to partial solidification of dust / slag or overheating of the inner wall is suppressed. Furthermore, due to the centrifugal effect of the swirling flow in the ash melting furnace, Since incineration ash and dust in the airflow are collected by the slag coating layer on the inner wall surface, a high slag conversion rate can be achieved. Further, since the waste incinerator and the ash melting furnace 8 are directly connected, the high-temperature ash is guided into the ash melting furnace 8 without being cooled, so that the thermal efficiency is increased.
- downstream side of the ash melting furnace 8 is narrower as it approaches the outlet 23. Therefore, the swirling flow velocity of the flame becomes higher toward the downstream side. Therefore, the efficiency of collecting ash and dust increases. Further, the inner wall can be more effectively heated by the flame. In addition, the slag is concentrated at one location and the hot water is not easily blocked. In addition, since the mixing of the furnace gas is promoted, low pollution of exhaust gas is realized.
- FIG. 4 is a diagram showing details of a tapered flue, a connecting portion between a melting unsuitable object detection / removal unit and an ash melting furnace in one example of the embodiment of the present invention.
- reference numeral 24 denotes a high-temperature air generator
- reference numeral 25 denotes a toxic substance supply device.
- Hazardous substances such as PCBs are charged from the harmful substance supply device 25 to the detection / removal section of unsuitable molten substances 6 .Gas and liquid harmful substances such as CFCs and waste oil are blown into the incinerator by unburned gas. It is blown into the melting furnace 8 from the port 21 together with the unburned gas in the incinerator.
- An adjustment damper 12 is provided at the boundary between the removal unit 6 and the ash melting furnace 8 .
- the hydraulic damper is used to raise and lower the damper, and as described above, from the waste incinerator to the ash melting furnace Suppress the amount of exhaust gas flowing into 8. In the actual operation, the opening degree of the dambar is almost equal to the surface of the incineration ash 4.
- FIG. 5 is a diagram showing the details of an unsuitable molten object detection / removal unit according to an example of an embodiment of the present invention.
- 26 is a TV camera
- 27 is a pusher
- 28 is a cooling air inlet
- 29 is a shielding plate
- 30 is a cover
- 31 is a vibration device.
- Unsuitable for melting is a material such as steel that does not burn and does not melt in an ash melting furnace. If such a substance enters the ash melting furnace, it may damage the equipment, cause incineration ash to be suspended near the entrance, or block the gate.
- a grid 7 is provided on the exit side of the unsuitable molten material detection / removal unit 6 so that these unsuitable molten objects are prevented from dropping by the lattice and do not enter the ash melting furnace.
- the grid 7 is hollow and is cooled by air supplied from a cooling air inlet 27.
- the unsuitable molten material remaining on the grid 7 is monitored by a TV camera 26 and discharged out of the furnace by operating a pusher 27. At this time, the shielding plate 29 is raised to create a space through which the unsuitable molten material passes.
- the cover 30 is hung from the upper structure by a hinge, and is rotated by being pushed by the unsuitable molten material, whereby the unsuitable molten material passes through the force bar 30 and is discharged out of the furnace. Thereafter, the pusher 27 is returned to the original position, and the shielding plate 29 is lowered to seal the inside of the furnace.
- the vibrating device 31 is provided on the lattice 7 to vibrate the lattice 7. Thereby, the incineration ash on the grid 7 falls without remaining on the grid 7 and is guided into the ash melting furnace.
- FIG. 6 is a diagram showing an example of an embodiment of the present invention in which the ash melting furnace is a rotary kiln type.
- reference numeral 8 ' denotes a smelting furnace, a kiln, 32, a roller, and 33, a blowing port for a mixed gas of combustible gas and high-temperature air.
- the rotation of the rollers 32 rotates the flat kiln 8 ′.
- the rotary kiln 8 ' is inclined downward toward the downstream side, and the downstream side is tapered.
- the flammable gas and the high-temperature air are mixed just before the injection port 33 and are blown into the roaster kiln 8 '.
- the blowing direction does not pass through the central axis of the rotary kiln 8 ', but is oblique to the direction of travel toward the wall surface. Therefore, a swirling flame or a tubular flame is generated in the roastery kiln 8 '.
- the ash melting furnace is a rotary kiln type, it inclines and rotates downward toward the downstream side, so even if unsuitable melting substances are interposed, the incinerated ash is forcibly retained without remaining in the furnace. Can be transported downstream. Also, dust adhering to the inner wall of the ash melting furnace, when it reaches a certain size, separates by its own weight and is transported downstream, so that cleaning inside the ash melting furnace is not required and labor can be saved.
- FIG. 7 shows a furnace using an ejector device according to an embodiment of the present invention. It is a figure which shows the schematic of the circulation system of internal combustion gas and combustion exhaust gas.
- 34 and 35 are ejectors.
- a portion of the combustion exhaust gas (ERG) after performing the secondary combustion near the inlet of the exhaust heat boiler 18 is led to the ejector 134 through the exhaust gas circulation pipe.
- High-temperature air (above the ignition temperature of the combustion exhaust gas) is blown into the ejector 134 as a driving flow, and ERG is sucked into the ejector 134, mixed with the high-temperature air, and blown into the main combustion chamber 3. It is.
- part of the primary combustion exhaust gas (unburned gas in the furnace) generated in the main combustion chamber 3 is taken out by a pipe and guided to the ejector 135.
- High-temperature air (above the ignition temperature of the unburned gas in the furnace) is blown into the ejector 135 as a driving flow, and the primary combustion exhaust gas is sucked into the ejector 135 and mixed with the high-temperature air. It is blown into the ash melting furnace 8.
- the ejector unit has a simple structure, and the dust in the exhaust gas is unlikely to adhere.
- a high-temperature air pipe is inserted in the exhaust gas pipe, the primary combustion gas pipe, and the primary combustion in the exhaust gas pipe.
- the exhaust gas piping be bent as little as possible to prevent dust in the exhaust gas from adhering to these pipings.
- a pulse burner to the exhaust gas pipe to generate a pulsating flow in the exhaust gas in the exhaust gas pipe to suppress the adhesion of dust.
- the exhaust gas downstream of the induction fan can be used instead of the hot air.
- the induction fan is provided downstream of the exhaust gas treatment equipment
- the exhaust gas downstream of the induction fan is removed in the exhaust gas treatment equipment and has pressure, so the driving flow of the ejector It is suitable for use as. This eliminates the need for a dedicated blower for exhaust gas circulation, which reduces equipment costs and power consumption.
- the sensible heat of the exhaust gas used as the driving flow can be recovered, the thermal efficiency can be increased, and energy can be saved.
- atmosphere 0 2 meter in ash melting furnace 8 C_ ⁇ meter detects more C_ ⁇ 2 meter or the like, as the furnace atmosphere is kept reducing, the main combustion chamber 3 Fuel from a combustion burner (not shown) installed in the furnace, oxidizing agent such as hot air blown into the main combustion chamber 3, or combustion gas or blow-off gas blown into the ash melting furnace 8 from the gas outlet 20
- An atmosphere adjusting device in the ash melting furnace for adjusting any of the oxidizing agents such as high-temperature air may be provided.
- the waste incinerator and the incineration ash melting furnace are directly connected, and react with a part of the unburned gas generated in the incinerator like high-temperature air or oxygen-enriched air.
- the swirling flow velocity increases remarkably downstream, so that ash is trapped on the slag coating layer on the inner wall. This improves the collection efficiency and promotes complete combustion in the furnace.
- the exhaust gas circulation blower for the incinerator is connected to the downstream end of the ash melting furnace as a means to draw high-temperature unburned exhaust gas from the incinerator into the ash melting furnace. By doing so, long-term stable operation can be realized without applying a special high-temperature blower.
- the high-temperature exhaust gas discharged from the high-temperature air generator is used to improve the mixing properties in the incinerator, thereby reducing the incineration exhaust gas pollution and reducing the exhaust gas emission.
- Energy saving can be realized by effective use of sensible heat (heat recovery in the boiler downstream of the incinerator).
- the vicinity of the inner wall can be selectively heated, and the ash is heat-treated in a reducing atmosphere, so that the decomposition efficiency of dioxins in the ash increases, The durability of the material is further improved.
- the waste gas from the waste incinerator is transported and blown into the waste incinerator, and the combustible gas generated in the waste incinerator is removed.
- low air ratio combustion is possible, reducing the amount of exhaust gas and leading to energy savings.
- the flame inside the furnace is stable, low pollution can be achieved.
- energy can be saved, and high-temperature dust-containing gas can be stably conveyed, improving thermal efficiency and realizing energy saving in this aspect as well.
- FIG. 8 is a diagram showing an example of an embodiment of the present invention.
- 101 is hot pot
- 102 is refuse
- 103 is main combustion chamber
- 104 is incineration ash
- 105 is tapered flue
- 106 is detection and removal of unsuitable heat treatment.
- 107 is a grid
- 108 is an ash heat treatment furnace
- 109 is a slag
- 110 is a slag conveyor
- 1 1 is a slag reservoir
- 1 1 2 is an adjustment damper
- 1 1 3 is a dust remover
- 1 14 is a heat exchanger
- 1 15 is an exhaust gas circulation blower
- 1 16 is an intermediate ceiling
- 1 18 is a waste heat boiler
- 1 19 is an outlet for stirring gas in the furnace
- 1 20 is a gas outlet Mouth.
- the refuse 102 charged in the hopper 1 is ignited and burned by hot air from below the grate in the main combustion chamber 103 or by a combustion support wrench (not shown) installed in the main combustion chamber 103. .
- the incineration ash 104 generated by the combustion passes through the tapered flue 105 and enters the heat treatment unsuitable object detection / removal unit 106.
- the unsuitable heat treatment detection / removal unit 106 is provided with a detector for unsuitable heat treatment and a device for discharging the detected unsuitable heat treatment to the outside of the furnace.
- the incinerated ash 104 from which heat-treatment unsuitable materials have been removed falls through the lattice 100 mm, is heat-treated in the ash heat treatment furnace 108, becomes slag 109, and falls onto the slag conveyor 110.
- Slag reservoir 1 1 1 Without providing the slag conveyor 110 and the slag reservoir 1 11, the slag can be dropped into the water to be used as crushed slag.
- an adjustment damper 112 that suppresses the amount of exhaust gas entering the ash heat treatment furnace 108 from the waste incinerator.
- the flue gas is prevented from flowing into the ash heat treatment furnace 108 side. It is to be noted that the operation may be performed such that the incineration ash 104 is always filled upstream of the ash heat treatment furnace 108 without using the adjustment damper 111, so that a material seal may be formed.
- a gas outlet 120 is provided in the ash heat treatment furnace 108, and as shown in the A-A ′ cross-sectional view, a waste gas is discharged from the gas outlet 120.
- a mixture of flammable gas (unburned gas in the incinerator) and high-temperature air generated in the incinerator is being blown into the furnace at high speed.
- the blowing direction of the high-temperature gas mixture is tangential to the inner wall of the ash heat treatment furnace 108 as seen in the A-A 'cross-sectional view.
- a swirling or tubular flame is generated as shown in FIG. Therefore, the inner wall of the furnace is almost uniformly heated by the radiation or direct heat transfer from these flames.
- Exhaust gas generated by burning the unburned gas in the incinerator in the ash heat treatment furnace 108 is introduced into the exhaust gas circulation system of the waste incinerator, dust is removed by the dust remover 113, and the heat exchanger 111 After being cooled in 4, it is mixed with oxygen through the exhaust gas circulation blower 115, and is blown into the waste incinerator again.
- an independent blower can be installed to increase the pressure of the exhaust gas that has passed through the ash heat treatment furnace 108 and use it as a stirring gas in the secondary combustion chamber 117 described later. .
- An intermediate ceiling 1 16 is provided in the main combustion chamber 103, whereby the flow of exhaust gas is divided into two as shown by arrows in the figure.
- the exhaust gas passing above the middle ceiling 116 contains a large amount of unburned gas, and the exhaust gas passing below the middle ceiling 116 contains a large amount of unreacted oxygen. stable.
- a part of the exhaust gas passing through the upper part of the intermediate ceiling 116 that is, a part of the exhaust gas containing a large amount of unburned gas is extracted and converted into unburned gas in the incinerator.
- the ash heat treatment furnace 108 is used as the main heat source. That is, a part of the exhaust gas passing through the upper part of the intermediate ceiling 1 16 is drawn into the ash heat treatment furnace 108 through the gas outlet 120 by the negative pressure generated by the exhaust gas circulation blower 115. Will be. Therefore, a special blower for blowing the unburned gas in the incinerator into the ash heat treatment furnace 8 is not required.
- the exhaust gas that passes through the lower part of the intermediate ceiling 1 16 contains little unburned components, so if it is put into the ash heat treatment furnace 108, it will not serve as fuel, but rather ash. It is not preferable because the temperature in the heat treatment furnace 108 is lowered, and dioxins contained in the exhaust gas and chlorine as a starting material thereof enter the ash heat treatment furnace.
- the above-mentioned adjustment damper 112 is provided to prevent the exhaust gas from flowing into the ash heat treatment furnace 108.
- the pressure in the furnace near the boundary between the main combustion chamber 103 and the tapered flue 105 and the pressure in the ash heat treatment furnace 108 Is detected, and the opening of the damper 112 is adjusted so that the latter pressure is maintained slightly higher than the former pressure.
- the latter pressure may have to be lower than the former pressure (for example, in the embodiment shown in Fig. 8, the exhaust gas circulation blower 115 Since the unburned gas is drawn into the ash heat treatment furnace 108, the pressure of the latter is lower than the pressure of the former.) Even in this case, the pressure difference between the two is kept small and the exhaust gas is tapered as much as possible. Adjust the opening so that it does not flow into the ash heat treatment furnace through the flue 105.
- the gas obtained by mixing the exhaust gas having passed through the exhaust gas circulation blower 115 with oxygen is blown into the main combustion chamber 103 from the lower part of the grate.
- Grate may be corroded if it contains HC1 etc. In such a case, it is preferable to blow air from under the grate, and to blow a mixture of oxygen and exhaust gas directly into the main combustion chamber.
- the high-temperature air blown into the ash heat treatment furnace 108 is produced by heating the air by a high-temperature air generator (not shown). Generally, fuel is burned and the heat heats the air. If the flue gas at this time is used as a stirring gas blown out from the outlet 1 19 of the stirring gas in the furnace, the inside of the furnace can be stirred without changing the excess air ratio, and the combustion in the furnace is promoted. It is also effective in reducing exhaust gas NOx. In addition, the sensible heat of the flue gas from the high-temperature air generator can be recovered by the waste heat boiler 118.
- the ash heat treatment furnace 108 is blown with a mixed gas of natural gas and high-temperature air in the incinerator, but uses an oxidizing agent whose oxygen concentration is adjusted instead of high-temperature air. May be.
- Oxidizing agents include, for example, oxygen and waste gas from waste incinerators. It can be manufactured by mixing.
- the oxygen concentration in the oxidizing agent is set to a high value, the absolute flow rate of the oxidizing agent is reduced, so that the residence time of the airflow in the ash heat treatment furnace is prolonged. The dust collection efficiency can be improved.
- low NOX combustion can be realized in the ash heat treatment furnace.
- the temperature in the ash heat treatment furnace 108 it is preferable to detect the temperature in the ash heat treatment furnace 108 and adjust the temperature of the high-temperature air or the oxidizing agent whose oxygen concentration is adjusted so as to keep this temperature constant.
- the temperature in the ash heat treatment furnace 108 it is preferable to detect the temperature in the ash heat treatment furnace 108 and adjust the temperature of the high-temperature air or the oxidizing agent whose oxygen concentration is adjusted so as to keep this temperature constant.
- the temperature in the ash heat treatment furnace 8 is preferably controlled to 800 ° C. or more. This makes it possible to simultaneously reduce dioxins and heavy metals in the ash. Therefore, the ash after the heat treatment can be effectively used. Further, since the inside of the furnace exceeds the melting point of the main heavy metals, it is possible to suppress solidification of these in the furnace. Further, it is preferable that the temperature in the ash heat treatment furnace 108 be controlled to be equal to or lower than the melting temperature of the ash.
- the types, melting points, and boiling points (or sublimation points) of heavy metals that are particularly problematic in the ash treatment field are as follows. table 1
- Arsenic (As) 871 (Sublimation point: 61 6)
- the temperature in the ash heat treatment furnace 108 may be adjusted by providing an auxiliary fuel supply device and blowing the auxiliary fuel into the ash heat treatment furnace 108 and adjusting the amount of the auxiliary fuel.
- the temperature in the ash heat treatment furnace 108 can be accurately controlled, so that when the furnace condition on the incinerator side suddenly deteriorates, or the outlet of the ash heat treatment furnace 108 tends to be blocked for some reason.
- the temperature inside the ash heat treatment furnace can be quickly readjusted without changing the operating conditions on the incinerator side. For this reason, the plant operation rate can be maintained at a high level.
- the temperature inside the ash heat treatment furnace can be adjusted independently of the incinerator, the work time for starting up and shutting down the plant can be shortened.
- a fuel containing carbon for example, a powdered fuel.
- the injected carbon-containing fuel is pressed against the inner wall by centrifugal force in the same manner as the ash, and the carbon-containing fuel is burned at this location. This further promotes the volatilization of heavy metals from the ash. Further, since the vicinity of the inner wall is also in a reducing atmosphere, burning of the inner wall is suppressed. As a result, the operating rate of the equipment is increased, and there is an effect of reducing repair costs such as replacement of furnace materials.
- FIG. 9 shows a system of exhaust gas, steam, and the like in a waste incineration heat treatment furnace which is an example of the embodiment of the present invention.
- the oxygen separated from the air by the oxygen generator is mixed with the exhaust gas from the exhaust gas circulation system in the mixer, and is blown into the incinerator to burn the waste.
- Most of the exhaust gas from the incinerator flows into an exhaust gas circulation system consisting of a dust remover, a heat exchanger, and a blower, is mixed with oxygen in a mixer, and is injected into the incinerator again. It is. In this case, air is blown from below the grate, and the exhaust gas mixed with oxygen in the mixer is blown directly into the combustion chamber.
- the ratio of the mixed exhaust gas and oxygen By changing the ratio of the mixed exhaust gas and oxygen, it is possible to control the combustion state of the refuse in the incinerator and, unlike air blowing, no extra nitrogen is blown into the furnace.
- the exhaust gas volume can be reduced, and the exhaust gas treatment equipment can be downsized.
- Part of the exhaust gas that does not flow to the exhaust gas circulation system flows into the ash heat treatment furnace 108 as described above, and another part flows into the exhaust gas treatment facility.
- the flue gas that has been burned in the ash heat treatment furnace to heat the incinerated ash is guided to the dust remover and enters the flue gas circulation system as described above.
- the exhaust gas that has flowed into the exhaust gas treatment facility is released to the atmosphere from the chimney after removing water. If a CO 2 fixation device is provided, C ⁇ 2 in the exhaust gas will be fixed and will not be released to the atmosphere.
- the water removed in the exhaust gas treatment facility is released after being treated in the wastewater treatment facility.
- the sensible heat of flue gas from incinerators is used to generate steam in flue gas boilers, and the generated steam is used in power plants.
- the heat exchanger is used to heat the water supply to the waste heat boiler.
- FIG. 10 shows details of an example of an ash heat treatment furnace according to an embodiment of the present invention.
- reference numeral 121 denotes a gas inlet in the incinerator
- 122 denotes a high-temperature air inlet
- 123 denotes an outlet.
- the ash heat treatment furnace 108 is a furnace having a substantially circular cross section, and the downstream side thereof becomes gradually narrower as approaching the outlet 123.
- a gas outlet 120 is provided in a part of the side wall on the upstream side, which is connected to the gas inlet 121 and the high-temperature air inlet 122 in the incinerator. .
- Exhaust gas blown from the gas inlet 1 2 1 in the incinerator furnace and high-temperature air blown from the high-temperature air inlet 1 2 2 are mixed at the gas outlet 1 20, and the ash has a substantially circular cross section.
- the heat treatment furnace 8 is blown in the tangential direction of the section 8, that is, along the circumference. As a result, a swirling flame or a tubular flame having a substantially symmetric shape with respect to the furnace axis is formed.
- the inner wall of the furnace becomes almost uniform due to radiation from these flames or direct heat transfer. Heated. Therefore, burning due to partial solidification of dust / slag or overheating of the inner wall is suppressed.
- incineration ash and dust in the airflow are collected at the surface of the inner wall, so that a high slag conversion rate can be achieved.
- the waste incinerator and the ash heat treatment furnace 108 are directly connected, the high-temperature ash is guided into the ash heat treatment furnace 108 without being cooled, so that the thermal efficiency is increased.
- the downstream side of the ash heat treatment furnace 108 becomes narrower as approaching the outlet 123, so that the flame turning speed becomes higher toward the downstream side. Therefore, the efficiency of collecting ash and dust is increased. Further, the inner wall can be more effectively heated by the flame. Furthermore, for example, when the ash is melted, the slag is concentrated in one place and the tap water is hardly clogged. In addition, since the mixing of the furnace gas is promoted, the pollution of exhaust gas can be reduced.
- FIG. 11 is a diagram showing details of a tapered flue, a connecting portion between a heat treatment unsuitable object detection / removal unit and an ash heat treatment furnace in one example of an embodiment of the present invention.
- reference numeral 124 denotes a high-temperature air generator
- reference numeral 125 denotes a harmful substance supply device.
- Hazardous substances such as PCBs are loaded into the heat treatment unsuitable substance detection / removal unit 106 from the harmful substance supply device 125, and gas and liquid harmful substances such as fly ash and waste oil are incinerated.
- the unburned gas is blown into the heat treatment furnace 108 together with the unburned gas in the incinerator from the unburned gas inlet 1 2 1.
- These substances are decomposed in a high-temperature ash heat treatment furnace 108 and finally absorbed by an exhaust gas treatment device shown in FIG.
- Hazardous substances in powder are not blown from the unburnt gas inlet 1 in the incinerator, and the heat treatment unsuitable substances detection and removal section 106 is charged with high-temperature air. When blown in from the mouth 22, it may be scattered in the ash heat treatment furnace 108, and may not be sufficiently decomposed and may be discharged untreated from the outlet of the ash heat treatment furnace 108. This is to prevent it. Therefore, it is charged into the heat treatment unsuitable object detection / removal unit 106 and put into the ash heat treatment furnace 108 together with the incineration ash 104 to promote decomposition.
- FIG. 12 is a diagram showing details of a heat treatment inappropriate object detection / removal unit in one example of the embodiment of the present invention.
- 1 26 is a TV camera
- 1 27 is a pusher
- 1 2 8 is a cooling air inlet
- 1 2 9 is a shielding plate
- 1 3 0 is a cover
- 1 3 1 is a vibration device. is there.
- Unsuitable materials for heat treatment are incombustible substances consisting of large chunks such as steel and do not contain harmful substances such as dioxin. There is a risk of incineration ash hanging from the shelves and blocking the gate. Therefore, a lattice 107 is provided on the exit side of the heat treatment unsuitable object detection / removal section 106, so that these heat treatment unsuitable objects do not drop because of the lattice and do not enter the ash heat treatment furnace. Has been.
- the lattice 107 is hollow and is cooled by air supplied from a cooling air inlet 127.
- the unsuitable heat treatment remaining on the lattice 107 is monitored by a TV camera 126 and discharged to the outside of the furnace by operating the pusher 127. At this time, raise the shield plate 12 9 to create a space through which unsuitable heat treatment can pass.
- the cover 130 is hung from the upper structure by a hinge, and is rotated by being pushed by an unheated object, so that the unheated object passes through the cover 130 and exits the furnace. Is discharged. After that, return the pusher 127 to the original position, lower the shielding plate 127, and seal the inside of the furnace.
- the lattice 107 is provided with a vibrating device 1331 and vibrates the lattice 107. As a result, the incinerated ash on the grid 107 falls without remaining on the grid 107 and is guided into the ash heat treatment furnace.
- FIG. 13 is a diagram showing an example of an embodiment of the present invention in which the ash heat treatment furnace is a rotary kiln type.
- reference numeral 108 ′ designates a roasting kiln as an ash heat treatment furnace
- reference numeral 132 designates a roller
- reference numeral 133 designates an inlet for a mixed gas of combustible gas and high-temperature air.
- the rotation of the rollers 13 2 causes the one-piece kiln 10 8 ′ to rotate.
- the rotary kiln 108 ' is inclined downward toward the downstream side, and the downstream side is tapered.
- the combustible gas and the high-temperature air are mixed just before the blowing port 133 and blown into the rotary kiln 108 '.
- the blowing direction is oblique to the direction of travel toward the wall without passing through the central axis of the mouth-to-mouth kiln 108 '. Therefore, a swirling flame or a tubular flame is generated in the mouthless kiln 108 '.
- the ash heat treatment furnace is a rotary kiln type, it inclines downward and rotates toward the downstream side, so even if unsuitable heat treatments are interposed, they are incinerated without staying in the furnace. Ash can be forcibly transported downstream.
- dust adhering to the inner wall of the ash heat treatment furnace when it reaches a certain size, separates by its own weight and is transported to the downstream side, cleaning inside the ash heat treatment furnace becomes unnecessary, and labor can be saved.
- FIG. 14 shows a schematic diagram of a circulation system of combustion gas and combustion exhaust gas in a furnace using an ejector device according to an example of an embodiment of the present invention.
- 1 34 and 1 35 are ejectors.
- a portion of the flue gas (ERG) after the secondary combustion has been performed near the inlet of the exhaust heat poirer 118 is led to the ejector 134 through the exhaust gas circulation pipe.
- High-temperature air (above the ignition temperature of the combustion exhaust gas) is blown into the ejector 134 as a driving flow, and the ERG is sucked into the ejector 134 and mixed with the high-temperature air to form the main combustion. It is blown into room 3.
- part of the primary combustion exhaust gas (unburned gas in the furnace) generated in the main combustion chamber 103 is taken out by a pipe and guided to the ejector 135.
- High-temperature air (above the ignition temperature of the unburned gas in the furnace) is blown into the ejector 135 as a driving flow, and the primary combustion exhaust gas is sucked into the ejector 135 and mixed with the high-temperature air.
- the ejector unit has a simple structure, and the dust in the exhaust gas is unlikely to adhere to it.
- a high-temperature air pipe is inserted in the exhaust gas pipe, the primary combustion gas pipe, and the primary combustion gas
- the exhaust gas piping be bent as little as possible to prevent dust in the exhaust gas from adhering to these pipings.
- the exhaust gas downstream of the induction fan can be used instead of the hot air.
- the induction fan If the exhaust gas is installed downstream of the air-conditioning equipment, the exhaust gas downstream of the induction fan is removed in the exhaust gas treatment equipment and has a pressure, so it is suitable for use as a drive flow for the ejector. . This eliminates the need for a dedicated blower for exhaust gas circulation, which reduces equipment costs and power consumption.
- the sensible heat of the exhaust gas used as the driving flow can be recovered, the thermal efficiency can be increased, and energy can be saved.
- the residual ⁇ 2 in the exhaust gas can be utilized as combustion ⁇ 2 in the incinerator, it is possible to reduce the supply air amount, can you to also reduce the amount of exhaust gas. Thus, energy saving, C_ ⁇ 2 measures can be realized.
- An atmosphere adjusting device in the ash heat treatment furnace may be provided for adjusting either the oxidizing agent such as a combustion assisting gas or high-temperature air.
- the waste incinerator and the ash heat treatment furnace are directly connected to each other and react with a part of the unburned gas generated in the incinerator like high-temperature air or oxygen-enriched air.
- the problem caused by the melting and solidification of the ash does not occur. -Can decompose and volatilize harmful heavy metals.
- the flammable gas generated in the incinerator is ash-heat treated without a circulation blower by using the eject effect of the high-temperature air at the entrance of the ash heat treatment furnace. Can be pulled into the furnace.
- the high-temperature exhaust gas discharged from the high-temperature air generator to improve the mixing property in the incinerator, the pollution of the incineration exhaust gas is reduced, and the sensible heat of the exhaust gas is effectively used (in the boiler downstream of the incinerator). Energy recovery by heat recovery) can be realized.
- the vicinity of the inner wall can be selectively heated, and the ash is heat-treated in a reducing atmosphere, so that the decomposition efficiency of dioxins in the ash increases, The durability of the material is further improved.
- the waste gas from the waste incinerator is transported and blown into the waste incinerator, and the combustible gas generated in the waste incinerator is removed.
- low air ratio combustion is possible, reducing the amount of exhaust gas and leading to energy savings.
- the flame inside the furnace is stable, low pollution can be achieved.
- a place for exhaust gas circulation Since less power is required, energy can be saved, and high-temperature dust-containing gas can be transported stably, improving thermal efficiency and realizing energy saving in this aspect as well.
- the reducing atmosphere is provided near the inner wall of the ash heat treatment furnace, burning of the inner wall can be suppressed.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Gasification And Melting Of Waste (AREA)
- Incineration Of Waste (AREA)
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020007004836A KR100348746B1 (ko) | 1998-10-12 | 1999-06-03 | 폐기물처리장치 |
EP99923884A EP1039221A4 (en) | 1998-10-12 | 1999-06-03 | WASTE DISPOSAL DEVICE |
Applications Claiming Priority (10)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10/289858 | 1998-10-12 | ||
JP28985898 | 1998-10-12 | ||
JP10/309330 | 1998-10-30 | ||
JP30933198 | 1998-10-30 | ||
JP30933098 | 1998-10-30 | ||
JP10/309331 | 1998-10-30 | ||
JP11/3608 | 1999-01-11 | ||
JP00360999A JP3460605B2 (ja) | 1998-10-12 | 1999-01-11 | 廃棄物焼却・熱処理炉 |
JP11/3609 | 1999-01-11 | ||
JP00360899A JP3460604B2 (ja) | 1998-04-08 | 1999-01-11 | 廃棄物焼却溶融炉 |
Publications (1)
Publication Number | Publication Date |
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WO2000022348A1 true WO2000022348A1 (fr) | 2000-04-20 |
Family
ID=27518380
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/JP1999/002967 WO2000022348A1 (fr) | 1998-10-12 | 1999-06-03 | Dispositif d'evacuation des dechets |
Country Status (4)
Country | Link |
---|---|
EP (2) | EP1039221A4 (ja) |
KR (1) | KR100348746B1 (ja) |
TW (1) | TW473605B (ja) |
WO (1) | WO2000022348A1 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110966871A (zh) * | 2020-01-06 | 2020-04-07 | 洛阳明远石化技术有限公司 | 一种低热值燃料气加热炉节能装置及节能方法 |
CN113917079A (zh) * | 2021-09-30 | 2022-01-11 | 北京中科润宇环保科技股份有限公司 | 一种用于生活垃圾焚烧厂焚烧炉的烟气量精确测量方法 |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT508648B1 (de) * | 2009-08-26 | 2012-12-15 | Siemens Vai Metals Tech Gmbh | Aufgabeschurre für sintermaterial |
KR101238800B1 (ko) | 2011-09-19 | 2013-03-04 | 한국수력원자력 주식회사 | 비대칭 경사형 바닥을 갖는 유도가열식 용융로 |
US9539581B2 (en) | 2011-10-11 | 2017-01-10 | Materials Recovery Company | Method for recycling ash |
EP2778523B1 (de) * | 2013-03-14 | 2019-06-19 | Hitachi Zosen Inova AG | Schlackeaufbereitungsvorrichtung |
CN106225241B (zh) * | 2016-08-30 | 2021-10-22 | 浙江特富发展股份有限公司 | 双炉膛导热油锅炉防结焦结构 |
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- 1999-06-03 EP EP02008240A patent/EP1227278A3/en not_active Withdrawn
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CN110966871A (zh) * | 2020-01-06 | 2020-04-07 | 洛阳明远石化技术有限公司 | 一种低热值燃料气加热炉节能装置及节能方法 |
CN113917079A (zh) * | 2021-09-30 | 2022-01-11 | 北京中科润宇环保科技股份有限公司 | 一种用于生活垃圾焚烧厂焚烧炉的烟气量精确测量方法 |
Also Published As
Publication number | Publication date |
---|---|
EP1227278A2 (en) | 2002-07-31 |
EP1039221A4 (en) | 2002-12-04 |
KR20010031770A (ko) | 2001-04-16 |
TW473605B (en) | 2002-01-21 |
EP1039221A1 (en) | 2000-09-27 |
KR100348746B1 (ko) | 2002-08-14 |
EP1227278A3 (en) | 2002-08-07 |
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