Classifications

• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
  • C10G35/00—Reforming naphtha
  • C10G35/04—Catalytic reforming
  • C10G35/06—Catalytic reforming characterised by the catalyst used
  • C10G35/095—Catalytic reforming characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
  • C10G35/00—Reforming naphtha
  • C10G35/04—Catalytic reforming
  • C10G35/06—Catalytic reforming characterised by the catalyst used

Definitions

• the invention relates to a process for reforming a naphtha stream using a surface treated zeolite catalyst.
• Naphtha streams emerging from petrochemical refining processes generally comprise a mixture of Cs to C13 hydrocarbons which include about 15 to 40 wt.% of C ⁇ to Cn aromatic compounds and the balance mostly a mixture of cs to Cn aliphatic hydrocarbons, including mixed paraffins and mixed olefins.
• naphtha is passed over an acidic, medium pore zeolite catalyst, such as ZSM-5, which may also contain one or more dehydrogenation metals such as noble metals, under reforming conditions which include a temperature of from 400 to 1000°F (204 to 540°C), pressures of 50-300 psig, weight hourly space velocity of 0.5-25 and in the optional presence of hydrogen (H2 to oil mole ratio of about 0-10).
• the reactions include dehydrogenation, dehydrocyclization, isomerization and hydrocracking.
• the dehydrogenation reactions typically include dehydroisomerization of alkylcyclopentanes to aromatics, the dehydrogenation of paraffins to olefins, the dehydrogenation of cyclohexanes to aromatics and the dehydrocyclization of acyclic paraffins and acyclic olefins to aromatics.
• the aromatization of the n-paraffins to aromatics is generally considered to be the most important because of the high octane rating of the resulting aromatic product.
• the isomerization reactions include isomerization of n-paraffins to isoparaffins, the hydroisomerization of olefins to isoparaffins, and the isomerization of substituted aromatics.
• the hydrocracking reactions include the hydrocracking of paraffins and hydrodesulfurization of sulfur compounds in the feed stock.
• Acidic zeolites of the HZSM-5 type are also well known catalysts for use in toluene disproportionation reactions wherein toluene or mixtures of toluene and methanol are fed over the catalyst under disproportionation/ alkylation conditions.
• the catalyst is first treated with a silicon-containing compound or other material to reduce the surface acidity of the catalyst. This technique has been found to enhance selectivity of the disproportionation process towards the production of the more valuable para-xylene isomers, in contrast with the meta or ortho isomers. Examples of such processes are found in U.S. Patents 4,950,835, 5,321, 183 and 5,367,099.
• U.S. Patent 5,371,312 discloses a process for the conversion of hydrocarbons comprising passing a hydrocarbon stream over a zeolite which has been treated with an amino silane.
• the catalyst may also contain a dehydrogenation metal such as platinum to reduce the amount of ethyl benzene by-product formed in the process.
• U.S. Patent 5,202,513 discloses the use of a galloalumino silicate catalyst of the ZSM-5 type containing gallium as part of the crystal structure which is treated with an alkali hydroxide, used as a reforming catalyst for naphtha-type feeds.
• WO 96/03209 discloses a reforming process wherein a C5-C9 paraffin or olefin feedstock is contacted under reforming conditions with a zeolite catalyst which has been modified with a platinum group component metal and a second metal selected from gallium, zinc, indium, iron, tin and boron.
• the publication indicates that the process leads to an increased yield of para-xylene and that the yield of para-xylene is further enhanced by pre-coking the catalyst prior to use in the reforming process.
• Another object of the invention is to provide a process for reforming a naphtha feed using a modified zeolite catalyst wherein the para-xylene content of the Cs aromatic product present in the reformate is produced in greater than an equilibrium-amount.
• the present invention provides a process for reforming a naphtha hydrocarbon stream containing at least about 25 wt.% of Cs to C ⁇ aliphatic and cycloaliphatic hydrocarbons comprising contacting said stream under reforming conditions with a modified reforming catalyst comprising an intermediate pore size acidic aluminosuicate support impregnated with at least one dehydrogenation metal selected from the group consisting of gallium, zinc, indium, iron, tin and boron, and oxides or sulfides thereof, said catalyst modified by (a) contact of said impregnated aluminosilicate support with a Periodic Table Group HA metal hydroxide or an organosilicon compound in an amount sufficient to neutralize at least a portion of the acid sites present on the surface of said support and (b) calcination of said support, the reformed naphtha product of said process containing less than about 25 wt.% of C ⁇ -C 4 gas.
• a modified reforming catalyst comprising an intermediate
• the process of the invention provides a reformate product which on the one hand, contains a reduced content of low value Ci to C 4 gases which are primarily the by-product of cracked C 4 + aliphatic and cycloaliphatic compounds while, on the other hand, maintaining a high yield of more valuable C ⁇ to C_ aromatics in the reformate, and greater than equilibrium-amount yields of para-xylene in the Cs aromatic component of the reformate.
• Zeolites which may be used as molecular sieve support material for the catalyst of the present invention include intermediate pore size zeolites having an average pore size in the range of about 5 to about 7 Angstroms and a Si ⁇ 2 Al 2 ⁇ 3 ratio of at least 10. These include zeolites having a MFI, MEL, TON, MTT or FER crystalline structure. Preferred such zeolites include ZSM-5, silicalite (a high silica to alumina ratio form of ZSM-5), ZSM-11, ZSM-12, ZSM-21, ZSM-22, ZSM-23, ZSM-35 and ZSM-38, with ZSM-5 being most preferred.
• the zeolite is preferably used in its highly acidic form, e.g. HZSM-5.
• the zeolite as synthesized, contains alkali or alkaline earth metal cations, these can be exchanged with ammonium cations, followed by calcination in air at 600°F (315°C) to 1000°F (540°C) by techniques well known in the art to produce the acid form of the zeolite.
• the dehydrogenation metals may be incorporated into the zeolite structure by any suitable method such as impregnation (incipient wetness method) or by ion exchange.
• the zeolite is impregnated with the metal by well known methods such as by contacting a solution of a metal salt dissolved in an aqueous or alcoholic medium with the zeolite particles for a period of time sufficient to allow the cations to penetrate the zeolite pore structure.
• Suitable salts include the chlorides and nitrates. After drying the resulting zeolite precursor, it is preferably calcined at temperatures of from 300°C to 600°C for a period of 1 to 6 hours.
• the metal will be present in the zeolite structure in the form of the oxide.
• hydrogen sulfide may form under reforming conditions which may, in turn, react with the metal oxide to form at least some metal sulfide.
• the metal may be in the form of the oxide, the sulfide or mixtures of these during the reforming process.
• the preferred metal loading may range from about 0.1 to 10 wt.%, most preferably from about 0.5 to 5 wt.%.
• the dehydrogenation metal present in the zeolite consists essentially of one or a mixture of gallium, zinc, indium, iron, tin or boron metal compounds, and does not contain a noble metal such as platinum, platinum/rhenium or platinum/iridium which tend to be more sensitive to deactivation by sulfur poisoning and/or coke build-up under reforming conditions.
• a noble metal such as platinum, platinum/rhenium or platinum/iridium which tend to be more sensitive to deactivation by sulfur poisoning and/or coke build-up under reforming conditions.
• the aluminosuicate support impregnated with the dehydrogenation metal is then modified by contact of the support with a hydroxide of a Group II A metal or an organosilicon compound in an amount sufficient to neutralize at least a portion of the acid sites present on the surface of the support, after which the catalyst is dried and calcined in air to provide the modified catalyst of this invention.
• neutralized as used herein is intended to mean not only chemical neutralization of the support such as displacement of H + cations by alkaline earth metal ions, but also blocking of surface H + cations by silicon compounds deposited on the surface of the support and within the channels of the support.
• the aluminosilicate support may be modified by dispersing the aluminosuicate in an about 0.1 to 2 normal aqueous solution of the hydroxide for a period of from about 0.2 to 1 hour.
• the dispersion is heated at 25°C up to reflux temperature for a period of about 1/2 to one hour.
• the modified aluminosilicate is separated from the solution, dried and calcined in air at a temperature of up to 1000°C, preferably from about 300°C to 600°C for a period of 1 to 24 hours.
• Organosilicon compounds which may be used to modify the catalyst include compounds selected from the group consisting of silanes, silicones, and alkylsilicates.
• Suitable silanes include alkoxy silanes such as tetramethoxy or tetraethyoxy silane.
• Suitable silicones and silicone polymers include compounds having the formula -[R ⁇ R2SiO] wherein Ri and R 2 are the same or different Ci to C _ alkyl groups, phenyl groups, halogen, hydrogen, hydroxy, alkoxy, aralkyl and the like with at least one of Ri or R2 being an organic group, and n ranges from 2 to 1,000.
• silicones examples include dimethylsilicone, copolymers of dimethylsiloxane and a lower alkylene oxide such as ethylene oxide, diethylsilicone, methyl hydrogen silicone and the like.
• Suitable alkyl silicates include Ci to C 4 alkyl silicates such as methyl silicate or ethyl silicate.
• the silicon compound may be deposited on the surface of the aluminosilicate by any suitable method.
• the silicon compound may be used in liquid heat form or may be dissolved or dispersed in a solvent or aqueous medium to form a solution, dispersion or emulsion, mixed with the aluminosuicate to form a paste, dried and calcined. This deposition process can be repeated one or more times to provide a more uniformly coated product.
• the silicon compound may be deposited on the aluminosilicate surface by well known vapor deposition techniques. The deposited silicon compound extensively covers and resides on the external surface of the aluminosilicate molecular sieve and on surfaces within the molecular sieve channels.
• the silicon treated aluminosilicate is then calcined in air at a temperature of up to 1000°C, preferably from 300°C to 600°C, for a period of 1 to 24 hours.
• Neutralization methods as described above should be sufficient to neutralize at least about 50%, more preferably at least about 75%, and most preferably at least about 90% of the acidic sites present on the surface of the catalyst.
• the zeolite may be used in the catalytic process in its crystalline particulate form or it may be combined with 50 to 90 wt.%) of a binder material such a silica, alumina or various clay materials as is known in the art to form molded pellets or extrudates.
• a binder material such as silica, alumina or various clay materials as is known in the art to form molded pellets or extrudates.
• a zeolite-bound ZSM-5- free extrudate can also be used in the process.
• the metal impregnation and/or silicon compound deposition process described above may be carried out before or after the zeolite is composited with the binder, preferably before.
• the content of cracked C ⁇ -C paraffin gases produced in the naphtha reforming process of this invention is significantly lower than that produced in conventional naphtha reforming, generally less than 25 wt.% and often less than 20 wt.% of the reformate product.
• Typical naphtha feeds which may be processed in accordance with this invention are refinery products containing at least abut 25 wt.%, more usually at least about 35 wt.%, and most usually about 50 wt.% of Cs to Co aliphatic and cycloahphatic hydrocarbons such as olefins and paraffins, about 30 to 40 wt.% of C ⁇ to C is aromatics, of which at least 5 wt.%, more usually at least 10 wt.%) constitutes C9+ aromatics and roughly 10 to 20 wt.% of which constitutes Ce-Cs aromatics (BTX).
• These naphtha feeds may also contain 50 to 500 weight ppm sulfur and about 10 to 100 weight ppm of nitrogen compounds.
• sulfur refers to elemental sulfur as well as sulfur compounds such as organosulfides or heterocyclic benzothiophenes.
• Typical examples of aliphatic hydrocarbons present in the naphtha stream include paraffins such as n-hexane, 2-methylpentane, 3- methylpentane, n-heptane, 2-methylhexane, 3-methylhexane, 3- ethylpentane, 2,5-dimethylhexane, n-octane, 2-methylheptane, 3- ethylhexane, n-nonane, 2-methyloctane, 3-methyloctane and n-decane, as well as corresponding Cs to C ⁇ cyclop araffins.
• Typical olefins include 1-hexene, 2-methyl-l-pentene, 1-heptene, 1-octene and 1- nonene.
• Aromatics include benzene, toluene, xylenes as well as C_ to Cn aromatics.
• the naphtha is upgraded by passing it through one or more catalyst beds positioned in a reforming reactor.
• Suitable reforming conditions are as follows:
• the catalyst modified in accordance with Examples 2 and 3 was prepared by impregnating 40.33 grams of calcined H+ZSM-5 powder with a solution of 2.76 grams of Zn(NOs)2 and 37.97 grams of water. After drying at 120°C for 2 hours, the catalyst precursor was calcined at 500°C for 4 hours to give a ZnO/HZSM-5 catalyst (ZnZSM-5).
• a mixture of 20.46g of the ZnZSM-5 catalyst prepared in Example 1, 0.59g of barium hydroxide and 200 ml. of water were heated under reflux for 0.5 hour. After centrifuging, the wet solid was dried in a vacuum at 50°C for 5 hours and at 120°C for 3 hours. The dried product was pelletized to 16/45 mesh and calcined in air at 500°C for 2.5 hours to yield a barium neutralized ZnZSM-5 catalyst [BaJZnZSM- 5.
• the catalytic test was conducted in a fixed bed at reactor 890°F, 100 psig, 2 WHSV, 2 H 2 /feed and using a Cs-221°F CAT naphtha as the feed.
• the CAT naphtha feed contained 460 ppm sulfur, 76 ppm nitrogen, 38.1 wt.% paraffins, 11.4 wt.% cyclop araffins, 16.1 wt.% olefins and 34.4 wt.% aromatics.
• the experimental results of these tests are as shown in Table 1.
• coating or neutralizing the ZnZSM-5 reduced the gas make to 9.9 or 19.6 wt.%, respectively, down from 42.9 wt.% achieved using the non-modified catalyst, while maintaining a 45 to 47 wt.% aromatics yield.
• the ZnZSM-5 catalyst from Example 1 (25.93 g) was mixed with a dimethylsiloxane-ethylene oxide copolymer (30.64 g) in neat, liquid form at room temperature for 1 hr and dried in vacuum at 60°C for 4 hr and then calcined at 530°C for 8 hr to give a one time silica coated ZnZSM-5 catalyst [i.e.(Si)ZnZSM-5]. The above procedure was repeated 3 more times to give a 4x(Si)ZnZSM-5 catalyst.
• Example 7 The CAT naphtha used in Examples 4-6 was reformed over the non- silica containing catalyst prepared in Example 1 and the silica- containing catalyst as prepared in Example 7 under the following conditions: 50 psig, 500°C, 2 WHSV and 4 H2/molar feed ratio. Results are shown in Table 2.
• Examples 8 and 9 were repeated except that the naphtha stream used was a fight virgin C5-C12 naphtha containing 81 wt.% paraffins and 19 wt.% of aromatics. Reforming was conducted under the following low pressure conditions: 10 psig, 527°C, 2 WHSV and 4 N2/molar feed ratio. Results are shown in Table 3.
• Another advantage associated with the use of the catalysts of this invention as naphtha reforming catalysts is that the catalyst is more highly selective towards the production of the para-xylene component of the mixed Cs aromatics product produced of the four main Cs products, para-xylene is considerably more valuable as a chemical intermediate than ethyl benzene or the meta and ortho-xylene isomers.
• Para-xylene occurs in approximately equilibrium amounts, about 20 to 25 wt.%, depending on the temperature, in the Cs aromatics fraction of a typical reformate stream produced using conventional noble metal- containing catalysts or using ZSM-5 catalysts modified with a dehydrogenation metal such as zinc. Reformate produced using the neutralized catalysts of this invention contains a Cs aromatic fraction which can have a content of para-xylene considerably higher than the equilibrium amount, as illustrated in Example 12 below.

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• 1998
  • 1998-02-11 DE DE69819305T patent/DE69819305D1/de not_active Expired - Lifetime
  • 1998-02-11 AU AU66542/98A patent/AU6654298A/en not_active Abandoned
  • 1998-02-11 WO PCT/US1998/002747 patent/WO1998036037A1/en not_active Application Discontinuation
  • 1998-02-11 KR KR1019997007443A patent/KR20000071153A/ko not_active Application Discontinuation
  • 1998-02-11 CA CA002281563A patent/CA2281563A1/en not_active Abandoned
  • 1998-02-11 CN CN98803606A patent/CN1251123A/zh active Pending
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