WO1996021423A1 - Formulations tensioactives aqueuses exemptes de sel electrolytique - Google Patents
Formulations tensioactives aqueuses exemptes de sel electrolytique Download PDFInfo
- Publication number
- WO1996021423A1 WO1996021423A1 PCT/EP1995/005140 EP9505140W WO9621423A1 WO 1996021423 A1 WO1996021423 A1 WO 1996021423A1 EP 9505140 W EP9505140 W EP 9505140W WO 9621423 A1 WO9621423 A1 WO 9621423A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- carbon atoms
- alkyl
- acid
- alcohol
- radical
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 40
- 238000009472 formulation Methods 0.000 title claims abstract description 21
- -1 fatty alcohol ether sulphates Chemical class 0.000 claims abstract description 60
- 239000004094 surface-active agent Substances 0.000 claims abstract description 30
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 26
- 235000000346 sugar Nutrition 0.000 claims abstract description 17
- 229920005862 polyol Polymers 0.000 claims abstract description 15
- 125000000217 alkyl group Chemical group 0.000 claims description 30
- 125000004432 carbon atom Chemical group C* 0.000 claims description 21
- 239000003792 electrolyte Substances 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 11
- 125000003342 alkenyl group Chemical group 0.000 claims description 9
- 239000007787 solid Substances 0.000 claims description 6
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- 239000013543 active substance Substances 0.000 claims description 4
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 4
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- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 2
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- 125000005456 glyceride group Chemical group 0.000 claims description 2
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- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 241000384110 Tylos Species 0.000 description 1
- 235000010419 agar Nutrition 0.000 description 1
- 150000001323 aldoses Chemical class 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 229920003090 carboxymethyl hydroxyethyl cellulose Polymers 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
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- 230000015556 catabolic process Effects 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000000973 cosmetic coloring agent Substances 0.000 description 1
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- 238000006471 dimerization reaction Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 1
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 235000019387 fatty acid methyl ester Nutrition 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000004872 foam stabilizing agent Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000008098 formaldehyde solution Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- LQJBNNIYVWPHFW-QXMHVHEDSA-N gadoleic acid Chemical compound CCCCCCCCCC\C=C/CCCCCCCC(O)=O LQJBNNIYVWPHFW-QXMHVHEDSA-N 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 229930182478 glucoside Natural products 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 150000002337 glycosamines Chemical class 0.000 description 1
- 229920002674 hyaluronan Polymers 0.000 description 1
- 229960003160 hyaluronic acid Drugs 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002584 ketoses Chemical class 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000002101 lytic effect Effects 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- UWJJYHHHVWZFEP-UHFFFAOYSA-N pentane-1,1-diol Chemical compound CCCCC(O)O UWJJYHHHVWZFEP-UHFFFAOYSA-N 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000223 polyglycerol Polymers 0.000 description 1
- 235000010958 polyglycerol polyricinoleate Nutrition 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000004334 sorbic acid Substances 0.000 description 1
- 229940075582 sorbic acid Drugs 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 229940035044 sorbitan monolaurate Drugs 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000005846 sugar alcohols Chemical class 0.000 description 1
- 230000019635 sulfation Effects 0.000 description 1
- 238000005670 sulfation reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- AQWHMKSIVLSRNY-UHFFFAOYSA-N trans-Octadec-5-ensaeure Natural products CCCCCCCCCCCCC=CCCCC(O)=O AQWHMKSIVLSRNY-UHFFFAOYSA-N 0.000 description 1
- 150000005691 triesters Chemical class 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/56—Glucosides; Mucilage; Saponins
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
- A61K8/604—Alkylpolyglycosides; Derivatives thereof, e.g. esters
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/02—Alkyl sulfonates or sulfuric acid ester salts derived from monohydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/525—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
Definitions
- the invention relates to electrolyte salt-free surfactant formulations containing sugar surfactants, fatty alcohol ether sulfates and polyol esters, a process for their preparation and the use of polyol esters as viscosity regulators.
- the surfactant raw materials are usually used as highly concentrated aqueous pastes which are easy to handle and should therefore be as low-viscosity as possible. 2. When diluted with water, the finished surfactant formulations result from the concentrates, which in turn must now have a significantly higher viscosity.
- sugar surfactants - such as alkyl oligoglucosides or fatty acid N-alkyl glucamides - and fatty alcohol ether sulfates, alone or in combination, have proven to be particularly suitable for the production of skin-compatible agents for the care and cleaning of skin and hair. Accordingly, the prior art is extensive, which refers to these surfactants or surfactant mixtures with regard to their use in the field of cosmetics.
- aqueous surfactant mixtures based on alkyl oligoglucosides and fatty alcohol ether sulfates can be thickened by adding electrolyte salts and nonionic polymers.
- DE-A 4121612 (Henkel) describes dilute aqueous anionic surfactant formulations which, through small additions of a ternary combination of alkyl oligoglucosides, electrochemicals, lytic salts and polyol ether esters are thickened.
- DE-A 4139935 discloses liquid personal cleansing agents which can contain alkyl polyglucosides, oil bodies such as monoglycerides and anionic surfactants such as ether sulfates.
- the object of the invention was therefore to provide formulations which have exactly the opposite viscosity and dilution behavior.
- the invention relates to aqueous surfactant formulations which contain no electrolytes and contain
- sugar surfactants are alkyl and alkenyl oligoglycosides, which are known substances which follow the general formula (I)
- R 1 stands for an alkyl and / or alkenyl radical with 4 to 22 carbon atoms
- G for a sugar radical with 5 or 6 carbon atoms and p for numbers from 1 to 10, and which are obtained by the relevant methods of preparative organic chemistry can be.
- the alkyl and / or alkenyl oligoglycosides can be derived from aldoses or ketoses with 5 or 6 carbon atoms, preferably glucose.
- the preferred alkyl and / or alkenyl oligoglycosides are thus alkyl and / or alkenyl oligoglucosides.
- alkyl and / or alkenyl oligoglycosides with a medium oligomer degree of risk p from 1.1 to 3.0 is used. From an application-technical point of view, preference is given to those alkyl and / or alkenyl oligoglycosides whose degree of oligomerization is less than 1.7 and in particular between 1.2 and 1.4.
- the alkyl or alkenyl radical R 1 can be derived from primary alcohols having 4 to 11, preferably 8 to 10, carbon atoms. Typical examples are butanol, capronic alcohol, caprylic alcohol, capric alcohol and decyl alcohol and their technical mixtures, such as are obtained, for example, in the hydrogenation of technical fatty acid methyl esters or in the course of the hydrogenation of aldehydes from Roelen's oxo synthesis.
- the alkyl or alkenyl radical R 1 can also be derived from primary alcohols having 12 to 22, preferably 12 to 14, carbon atoms. Typical examples are lauryl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, arachyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol, and their technical mixtures, which can be obtained as described above. Alkyl oligoglucosides based on hardened c 12/14 ⁇ Ko k osa _U co h ° -L with a DP of 1 to 3 are preferred. Fatty acid N-alkyl polydroxyalkylamides
- Suitable sugar surfactants are fatty acid N-alkyl polyhydroxyalkylamides of the formula (II)
- R ⁇ CO stands for an aliphatic acyl radical with 6 to 22 carbon atoms
- R3 for hydrogen, an alkyl or hydroxyalkyl radical with 1 to 4 carbon atoms
- [Z] for a linear or branched polyhydroxyalkyl radical with 3 to 12 carbon atoms and 3 to 10 hydroxyl groups .
- the fatty acid N-alkyl polyhydroxyalkylamides are known substances which can usually be obtained by reductive amination of a reducing sugar with ammonia, an alkylamine or an alkanolamine and subsequent acylation with a fatty acid, a fatty acid alkyl ester or a fatty acid chloride.
- a reducing sugar with ammonia
- an alkylamine or an alkanolamine and subsequent acylation with a fatty acid, a fatty acid alkyl ester or a fatty acid chloride.
- H. Kelkenberg An overview of this topic by H. Kelkenberg can be found in Tens. Surf.Det. J25, 8 (1988).
- the fatty acid N-alkylpolyhydroxyalkylamides are preferably derived from reducing sugars with 5 or 6 carbon atoms, in particular from glucose.
- the preferred fatty acid N-alkyl polyhydroxyalkylamides are therefore fatty acid-N-alkylglucamides as represented by the formula (III):
- the preferred fatty acid N-alkylpolyhydroxyalkylamides used are glucamides of the formula (III) in which R 3 represents hydrogen or an amine group and R 2 C0 represents the acyl radical of caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, Palmoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroseline acid, linoleic acid, linolenic acid, arachidic acid, gadoleic acid, behenic acid or erucic acid or their technical mixtures.
- R 3 represents hydrogen or an amine group
- R 2 C0 represents the acyl radical of caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, Palmoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroseline acid,
- Fatty acid N-alkylglucamides of the formula (III) which are obtained by reductive amination of glucose with methylamine and subsequent acylation with lauric acid or C12 14-coconut fatty acid or a corresponding derivative are particularly preferred.
- the polyhydroxyalkylamides can also be derived from maltose and palatinose.
- fatty acid N-alkylpolyhydroxyalkylamides are also the subject of a large number of publications. Their use as a thickener is known, for example, from European patent application EP-AI 0285768 (Hüls). French published patent application FR-A 1580491 (Henkel) describes aqueous detergent mixtures based on sulfates and / or sulfonates, nonionic surfactants and optionally soaps, which contain fatty acid N-alkylglucamides as foam regulators.
- ether sulfates are known anionic surfactants which are produced on an industrial scale by SO3 or CSA sulfation of fatty alcohol polyglycol ethers and subsequent neutralization.
- R ⁇ for a linear or branched alkyl and / or alkenyl radical having 6 to 22 carbon atoms
- m for numbers of 1 to 10
- X represents an alkali and / or alkaline earth metal, ammonium, alkylammonium, alkanolammonium or glucammonium.
- Typical examples are the sulfates of adducts of an average of 1 to 10 and in particular 2 to 5 moles of ethylene oxide with capron alcohol, caprylic alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, isostearyl alcohol Oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, arachyl alcohol, gadoleyl alcohol, behenyl alcohol and erucyl alcohol and their technical mixtures, in the form of their sodium and / or magnesium salts.
- the ether sulfates can have both a conventional and a narrowed homolog distribution.
- ether sulfates based on adducts of an average of 2 to 3 mol ethylene oxide with technical C 2/14 ⁇ or C 1 ⁇ / ig coconut fatty alcohol fractions in the form of their sodium and / or magnesium salts.
- Components (a) and (b) can be used in a weight ratio of 5: 1 to 1: 5, preferably 2: 1 to 1: 2, based on the active substance content.
- Polyolesters are understood to mean substances which are obtained by reacting polyols having 2 to 12 hydroxyl groups with fatty acids having 6 to 22 carbon atoms.
- suitable polyol components include glycerin; Alkylene glycols such as, for example, ethylene glycol, diethylene glycol, propylene glycol; technical oligoglycerol mixtures with a degree of self-condensation of 1.5 to 10, such as technical diglycerol mixtures with a diglycerol content of 40 to 50% by weight; Methyl compounds, such as in particular trimethylolethane, trimethylolpropane, trimethylolbutane, pentaerythritol and dipentaerythritol; Lower alkyl glucosides, in particular those with 1 to 8 carbons in the alkyl radical, such as, for example, methyl and butyl glucoside; Sugar alcohols with 5 to 12 carbon atoms such as sorbitol or mannitol, sugars
- Suitable fatty acid components are: caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, palmitic acid, palmoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, eladoleinic acid, elaleolachic acid, elaleoleinic acid, elaleolachic acid, elaleolachic acid, elaleolachic acid, elaleolachic acid, elaleolachic acid, elaleolachic acid, elaoleolic acid , Behenic acid and erucic acid and their technical mixtures, for example in the pressure splitting of natural fats and oils, in the reduction of aldehydes from Roelen's
- polyesters are esters of partial glycerides, sorbitan and / or oligoglycerols with saturated fatty acids with 12 to 18 carbon atoms.
- Typical examples are technical lauric acid, palmitic acid, stearic acid re, coconut fatty acid mono / diglycerides and the sorbitan mono-, sesqui-, di- and / or triesters of the fatty acids mentioned. These substances are known commercial products.
- the viscosity regulators are usually used in amounts of 5 to 15, preferably 8 to 12,% by weight, based on the sum of the solids contents of components (a) and (b).
- the concentrated formulations can have a solids content of 25 to 50, preferably 30 to 40% by weight and the dilute solutions a solids content of 10 to 25, preferably 15 to 20% by weight.
- polyol esters preferably partial glyceride fatty acid esters and / or sorbitan fatty acid esters
- concentration aqueous systems containing sugar surfactants and ether sulfates results in an advantageously low viscosity. If these solutions are diluted with water, on the other hand, a desired increase in viscosity takes place, especially in the absence of electrolyte salts.
- Another object of the invention therefore relates to the use of polyol esters as viscosity regulators for electrolyte salt-free aqueous surfactant formulations based on sugar surfactants and fatty alcohol ether sulfates.
- the mixtures according to the invention are suitable for the production of foaming cleaning agents, preferably in Area of hair and body care.
- the formulations can be present in these compositions in amounts of 1 to 50, preferably 4 to 35% by weight, based on the composition.
- the hair and body cleansing agents can contain auxiliaries and additives. These include, in particular, other surfactants that are compatible with the other ingredients. Typical examples are monoglyceride sulfates, mono- and / or dialkyl sulfosuccinates, fatty acid isethionates, fatty acid sarcosinates, fatty acid tauides, ether carboxylic acids, alkyl amido betaines or protein fatty acid condensates.
- Emulsifiers, superfatting agents, further thickening agents, biogenic active substances, film formers, preservatives, colorants and fragrances may also be present as auxiliaries and additives.
- W / O and O / W emulsifiers such as, for example, hardened and ethoxylated castor oil, polyglycerol fatty acid esters or polyglycerol poly- ricinoleates are suitable as emulsifiers.
- Substances such as, for example, polyethoxylated lanolin derivatives, lecithin derivatives, polyol fatty acid esters, monoglycerides and fatty acid alkanolamides can be used as superfatting agents, the latter simultaneously serving as foam stabilizers.
- Suitable thickeners are, for example, polysaccharides, in particular xanthan gum, guar guar, agar agar, alginates and tyloses, carboxymethyl cellulose and hydroxyethyl cellulose, and also higher molecular weight polyethylene glycol mono- and diesters of fatty acids, polyacrylates, polyvinyl alcohol and polyvinylpyrrolidone, surfactants such as, for example, fatty alcohol ethoxylates with a narrow homolog distribution or alkyl oligoglucosides and electrolytes such as sodium chloride and ammonium chloride.
- Biogenic active substances are understood to mean, for example, plant extracts and vitamin complexes.
- Common film formers are, for example, chitosan, microcrystalline chitosan, quaternized chitosan, polyvinyl pyrrolidone, vinyl pyrrolidone-vinyl acetate copolymers, polymers of the acrylic acid series, quaternary cellulose derivatives, collagen, hyaluronic acid or its salts and similar compounds.
- Suitable preservatives are, for example, phenoxyethanol, formaldehyde solution, parabens, pentanediol or sorbic acid.
- Suitable pearlizing agents are, for example, glycol distearic acid esters such as ethylene glycol distearate, but also fatty acid monoglycol esters.
- Dyes which can be used are the substances which are suitable and approved for cosmetic purposes, as described, for example, in the publication "Cosmetic Colorants” by Farbstoffk ⁇ mmission of the German Research Foundation, published by Verlag Chemie, Weinheim, 1984, pp. 81-106. These dyes are usually used in concentrations of 0.001 to 0.1% by weight, based on the mixture as a whole.
- the total proportion of auxiliaries and additives can be 1 to 50, preferably 5 to 40% by weight, based on the composition.
- A Ci2 / i6- ⁇ ° fcosalkyloligoglucosid (Plantaren ( R) APG 1200)
- B Ci2 / i4- okosfettalkohol + 2EO ether sulfate Na / Mg salt
- the examples and comparative examples show that concentrated mixtures of alkyl oligoglucosides and alkyl ether sulfates are low-viscosity due to the addition of polyol esters, while the same dilute solutions have an advantageously high viscosity.
- the addition of electrolyte salts as a thickener surprisingly causes a breakdown in the viscosity.
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Abstract
L'invention concerne de nouvelles formulations tensioactives aqueuses exemptes de sel électrolytique, qui contiennent (a) des tensioactifs sacchariques, (b) des sulfates d'ether d'alcool gras et (c) des esters de polyol. Ces formulations sont de faible viscosité lorsqu'elles sont très concentrées, mais très visqueuses lorsqu'elles sont diluées.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19500799.9 | 1995-01-13 | ||
DE19500799A DE19500799A1 (de) | 1995-01-13 | 1995-01-13 | Elektrolytsalzfreie wäßrige Tensidformulierungen |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1996021423A1 true WO1996021423A1 (fr) | 1996-07-18 |
Family
ID=7751395
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP1995/005140 WO1996021423A1 (fr) | 1995-01-13 | 1995-12-27 | Formulations tensioactives aqueuses exemptes de sel electrolytique |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE19500799A1 (fr) |
WO (1) | WO1996021423A1 (fr) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19829646A1 (de) * | 1998-07-02 | 2000-01-05 | Wella Ag | Verfahren zur Herstellung von wäßrigen Lösungen von Alkylethersulfaten |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0070074A2 (fr) * | 1981-07-13 | 1983-01-19 | THE PROCTER & GAMBLE COMPANY | Compositions moussantes contenant des agents tensio-actifs |
EP0490041A1 (fr) * | 1990-12-08 | 1992-06-17 | Hüls Aktiengesellschaft | Composition cosmétique |
DE4121612A1 (de) * | 1991-06-29 | 1993-01-07 | Henkel Kgaa | Waessrige tensidzubereitungen |
WO1993008250A1 (fr) * | 1991-10-15 | 1993-04-29 | Henkel Kommanditgesellschaft Auf Aktien | Preparations tensioactives visqueuses aqueuses |
DE4139935A1 (de) * | 1991-12-04 | 1993-06-09 | Kao Corporation Gmbh, 4000 Duesseldorf, De | Fluessiges koerperreinigungsmittel |
WO1994010975A1 (fr) * | 1992-11-09 | 1994-05-26 | Unilever Plc | Composition de lavage |
-
1995
- 1995-01-13 DE DE19500799A patent/DE19500799A1/de not_active Withdrawn
- 1995-12-27 WO PCT/EP1995/005140 patent/WO1996021423A1/fr active Application Filing
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0070074A2 (fr) * | 1981-07-13 | 1983-01-19 | THE PROCTER & GAMBLE COMPANY | Compositions moussantes contenant des agents tensio-actifs |
EP0490041A1 (fr) * | 1990-12-08 | 1992-06-17 | Hüls Aktiengesellschaft | Composition cosmétique |
DE4121612A1 (de) * | 1991-06-29 | 1993-01-07 | Henkel Kgaa | Waessrige tensidzubereitungen |
WO1993008250A1 (fr) * | 1991-10-15 | 1993-04-29 | Henkel Kommanditgesellschaft Auf Aktien | Preparations tensioactives visqueuses aqueuses |
DE4139935A1 (de) * | 1991-12-04 | 1993-06-09 | Kao Corporation Gmbh, 4000 Duesseldorf, De | Fluessiges koerperreinigungsmittel |
WO1994010975A1 (fr) * | 1992-11-09 | 1994-05-26 | Unilever Plc | Composition de lavage |
Also Published As
Publication number | Publication date |
---|---|
DE19500799A1 (de) | 1996-07-18 |
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