USRE1450E - Improvement in preparing hides for tanning - Google Patents
Improvement in preparing hides for tanning Download PDFInfo
- Publication number
- USRE1450E USRE1450E US RE1450 E USRE1450 E US RE1450E
- Authority
- US
- United States
- Prior art keywords
- tanning
- hides
- sulphur
- improvement
- water
- Prior art date
Links
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 24
- 239000005864 Sulphur Substances 0.000 description 20
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 16
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 14
- 235000015450 Tilia cordata Nutrition 0.000 description 14
- 235000011941 Tilia x europaea Nutrition 0.000 description 14
- 239000004571 lime Substances 0.000 description 14
- 210000003491 Skin Anatomy 0.000 description 12
- 239000007788 liquid Substances 0.000 description 12
- 235000017550 sodium carbonate Nutrition 0.000 description 12
- 229910000029 sodium carbonate Inorganic materials 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 239000003513 alkali Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000001828 Gelatine Substances 0.000 description 4
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium monoxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 229920000159 gelatin Polymers 0.000 description 4
- 235000019322 gelatine Nutrition 0.000 description 4
- 239000010985 leather Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 235000012255 calcium oxide Nutrition 0.000 description 2
- 239000000292 calcium oxide Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000002349 favourable Effects 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 125000004435 hydrogen atoms Chemical class [H]* 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 239000008234 soft water Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
Definitions
- hides and skins maybe depilated and fitted for tanning, so as to preserve all their good qualities in an unimpaired and natural condition, thereby producing heavier as well as finer, tougher, and softer leather.
- the materials used in this process are 7 substantially as follows: Sulphur, (S,) one part;
- the depilating-liquid is prepared by dissolving fully this compound, made as above, in water. Two pounds of sulphur, two of soda-- ash,and twenty of lime, dissolved in the proper quantity of water, will be enough for one hundred calf-skins. For hides the liquid should be made stronger in due proportion. This liquid can at any time be strengthened by adding more of the compound when a more prompt action is'demanded, and the same liquid can also be strengthened up as the case requires for successive packs until a less favorable action is discovered, when the vat should be cleaned out and a new liquid substituted for the old one.
- the sulphur of commerce is nearly uniform in quality and quite free from impurities; but the quality and alkaline strength of soda-ash vary much, and as the object of this element is to dissolve the sulphur or bring it into a condition that will more readily combine with the lime, so as to change the nature and mode of its action upon the skin, the smallest amount a .of this or any other form of alkali that will accomplish this object is found in practice to be or work the best. I have employed sulphur and lime direct in different proportions; but.
- compositions for purposes similar to mine have been proposed by charging alkalies and lime withsulphureted hydrogen, and also by fusing sulphur with alkalies secure byLetters Patent, is
Description
UNITED STATES AMOS n. LUFKIN, or CLEVELAND, oHIo.
, IMPROVEMENT IN PREPARlN'G moss FOR TANNING.
Specification forming part of Letters Patent No. 29,392, dated July 31, 1850; Reissue No 1,450, dated April 7, 1863. I
hides and skins maybe depilated and fitted for tanning, so as to preserve all their good qualities in an unimpaired and natural condition, thereby producing heavier as well as finer, tougher, and softer leather.
First. The materials used in this process are 7 substantially as follows: Sulphur, (S,) one part;
soda-ash, (N aO,) or its equivalent, one part,
' and quicklime, (OaO,) ten parts, by weight.
Second. These materials are thus used: Put the soda-ash, in fine powder, into a suitable box with the sulphur, adding water enough to make them plastic. Then ,with a common hoe, mix and grind them thoroughly together. To the lime, fully slaked and hot from slaking, add this soda-ash and sulphur prepared as above, and mix the whole mass together till it. becomes perfectly uniform in quality and color,
using water enough to allow the whole to be easily worked; or'the soda-ash may be dissolved with water or steam, and the sulphur added thereto. 'Then proceed as above directed. 7
Third. The depilating-liquid is prepared by dissolving fully this compound, made as above, in water. Two pounds of sulphur, two of soda-- ash,and twenty of lime, dissolved in the proper quantity of water, will be enough for one hundred calf-skins. For hides the liquid should be made stronger in due proportion. This liquid can at any time be strengthened by adding more of the compound when a more prompt action is'demanded, and the same liquid can also be strengthened up as the case requires for successive packs until a less favorable action is discovered, when the vat should be cleaned out and a new liquid substituted for the old one.
\ Vere theelements of .thiscompound as they are obtained for use accurately represented by their chemical symbols, it would be easy to fix definitely the proportions giving for each kind of stock the best results, and so state them; but this is not the fact. Therefore the proportions herein given should not be considered absolute, but may be Varied according to the strength and purity of the ingredients used.
The sulphur of commerce is nearly uniform in quality and quite free from impurities; but the quality and alkaline strength of soda-ash vary much, and as the object of this element is to dissolve the sulphur or bring it into a condition that will more readily combine with the lime, so as to change the nature and mode of its action upon the skin, the smallest amount a .of this or any other form of alkali that will accomplish this object is found in practice to be or work the best. I have employed sulphur and lime direct in different proportions; but.
the action was not as eflicient, and the results, so far as developed, were not satisfactory.
Skins and hides, having been fully prepared, should be treated in the unhairing-liquid from two to six days. The longer time seems to prepare the gelatine better for the tann'in. If soft and pliable stock is to be produced, the lime, if best quality, may be slightly reduced below the proportion herein given; if heavy stockas sole-leather, where firmnessand so lidity are the essential qualities-the lime element may be somewhat increased. when the hair has been removed from the skins or hides, they can be made ready for the tan-vat by simply soaking them in soft water between each working upon the beam. "Water slightly warm facilitates the operation. When convenient, milling" them for a short time with a thorough washing in clean water has been found suificient. If the water for this use is hard, a little bate may be advantageous.
This compound, as an agent for the prepa rationof hides and skins for the bark, will become completely under the control of the operator. that even under protracted treatment it does not injure or diminish the gelatine of the skin 5 but while acquiring aknowledge of the nature i and qualities of the compound the care and Rightly made, experience has shown skill of the operator should be in constant use i to detect and correct any apparently wrong trary, is" exceedingly simple and certain in its operations.
I am aware that compositions for purposes similar to mine have been proposed by charging alkalies and lime withsulphureted hydrogen, and also by fusing sulphur with alkalies secure byLetters Patent, is
The process of treating hides by the use of and preparing them to be tanned, substantially sulphur for the purpose of removing the'hairv action incident to this as to every new process. l What I claim as my invention, and desireito andalkaline earths. These processes are objectionable both on account of the diflicult operations required in'carrying them into prac- \Vitnesses: tice, and also on account of want of uniform EDM. F. BROWN, results in their use, Whereas mine, on the con- I MosEs KELLY.
ashereindes'cribed. I
' A. D. LUFKIN.
Family
ID=
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