US6906227B2 - Bisphenol phenol adducts - Google Patents
Bisphenol phenol adducts Download PDFInfo
- Publication number
- US6906227B2 US6906227B2 US10/149,905 US14990502A US6906227B2 US 6906227 B2 US6906227 B2 US 6906227B2 US 14990502 A US14990502 A US 14990502A US 6906227 B2 US6906227 B2 US 6906227B2
- Authority
- US
- United States
- Prior art keywords
- filter
- zone
- phenol
- cake
- filter cake
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- -1 Bisphenol phenol adducts Chemical class 0.000 title claims abstract description 9
- 229930185605 Bisphenol Natural products 0.000 title description 2
- 238000000034 method Methods 0.000 claims abstract description 17
- 238000006555 catalytic reaction Methods 0.000 claims abstract description 8
- 150000001335 aliphatic alkanes Chemical class 0.000 claims abstract description 6
- 150000002576 ketones Chemical class 0.000 claims abstract description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 32
- 239000012065 filter cake Substances 0.000 claims description 30
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 28
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 26
- 239000013078 crystal Substances 0.000 claims description 26
- 238000005406 washing Methods 0.000 claims description 20
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 16
- 239000004744 fabric Substances 0.000 claims description 13
- 229910052757 nitrogen Inorganic materials 0.000 claims description 13
- 238000004519 manufacturing process Methods 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 7
- 239000000725 suspension Substances 0.000 claims description 7
- 239000012452 mother liquor Substances 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 238000002425 crystallisation Methods 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 4
- 238000005273 aeration Methods 0.000 claims description 3
- 239000000155 melt Substances 0.000 claims description 3
- 230000035699 permeability Effects 0.000 claims description 3
- 230000008025 crystallization Effects 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
- 239000001301 oxygen Substances 0.000 description 7
- 229910052760 oxygen Inorganic materials 0.000 description 7
- 238000000746 purification Methods 0.000 description 6
- 238000000926 separation method Methods 0.000 description 6
- 239000007787 solid Substances 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000003377 acid catalyst Substances 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 238000003490 calendering Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- YQDJQYVIHZYJSE-UHFFFAOYSA-N 1-phenyl-2,3-dihydroindene-1,2-diol Chemical class OC1CC2=CC=CC=C2C1(O)C1=CC=CC=C1 YQDJQYVIHZYJSE-UHFFFAOYSA-N 0.000 description 1
- MLCQXUZZAXKTSG-UHFFFAOYSA-N 2-[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound C=1C=CC=C(O)C=1C(C)(C)C1=CC=C(O)C=C1 MLCQXUZZAXKTSG-UHFFFAOYSA-N 0.000 description 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001728 carbonyl compounds Chemical class 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical class O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 125000004464 hydroxyphenyl group Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 125000003454 indenyl group Chemical class C1(C=CC2=CC=CC=C12)* 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- XDTRNDKYILNOAP-UHFFFAOYSA-N phenol;propan-2-one Chemical compound CC(C)=O.OC1=CC=CC=C1 XDTRNDKYILNOAP-UHFFFAOYSA-N 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920001230 polyarylate Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001601 polyetherimide Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 150000003732 xanthenes Chemical class 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/68—Purification; separation; Use of additives, e.g. for stabilisation
- C07C37/70—Purification; separation; Use of additives, e.g. for stabilisation by physical treatment
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/68—Purification; separation; Use of additives, e.g. for stabilisation
- C07C37/70—Purification; separation; Use of additives, e.g. for stabilisation by physical treatment
- C07C37/82—Purification; separation; Use of additives, e.g. for stabilisation by physical treatment by solid-liquid treatment; by chemisorption
Definitions
- the present application relates to a process for producing high-purity bis(4-hydroxyaryl)alkanes from adducts of bis(4-hydroxyaryl)alkanes and aromatic hydroxy compounds, which are obtained by acid-catalysed reaction of the aromatic hydroxy compounds with ketones.
- Bisphenols as condensation products of phenols and carbonyl compounds, constitute starting materials or intermediate products for the production of a wide range of commercial products.
- condensation product from the reaction between phenol and acetone, 2,2-bis(4-hydroxyphenyl)propane (BPA).
- BPA serves as the starting material for the production of various polymeric materials such as, for example, polyarylates, polyetherimides, polysulfones and modified phenol-formaldehyde resins. It is preferably used in the production of epoxy resins and polycarbonates.
- BPA production methods are known and are based on the acid-catalysed reaction of phenol and acetone, wherein a phenol-acetone ratio preferably greater than 5:1 is established in the reaction.
- the acid catalysts used may comprise both homogeneous and heterogeneous Br ⁇ nsted or Lewis acids, such as for example strong mineral acids such as hydrochloric or sulfuric acid.
- Gel-form or macroporous sulfonated cross-linked polystyrene resins (acidic ion exchangers) are preferably used.
- a product mixture arises which primarily contains BPA and water, in addition to unreacted phenol and optionally acetone.
- typical condensation reaction by-products arise in small quantities, such as for example 2-(4-hydroxyphenyl)-2-(2-hydroxyphenyl)propane (o,p-BPA), substituted indenes, hydroxyphenyl indanols, hydroxyphenyl chromans, substituted xanthenes and more highly condensed compounds having three or more phenyl rings in the molecular framework.
- One method of working up and purifying BPA entails the separation of BPA from the reaction mixture in the form of an approximately equimolar crystalline adduct with phenol by cooling of the reaction mixture, with the BPA/phenol adduct being crystallised as a crystal suspension.
- the BPA/phenol adduct crystals are then separated from the liquid phase by a suitable apparatus for solid/liquid separation, such as a rotary filter or centrifuge, and fed to a further purification stage.
- the crystal mash leaving the crystallisers is passed to the rotary filters, for example, and is fed to the trough of the rotary filter, the rotary filter drum dipping into the crystal mash present therein.
- the rotary filter drum is subdivided into different segments by means of a control head.
- the cake-forming zone located in the area of the rotary filter trough, is adjoined by a washing zone, in which the filter cake is washed by spraying with phenol via rows of nozzles, followed by a drying zone, in which residual phenol contained in the filter cake is drawn off as far as possible.
- the cake-forming zone, washing zone and drying zone are each connected with the associated vacuum units.
- pressure equalisation is performed between suction chamber and rotary filter housing by means of a depressurisation zone in the control head, to allow problem-free detachment of the filter cake when it reaches the doctor blade.
- the filter cloth is washed with phenol via a row of nozzles before entry into the rotary filter trough.
- the object is to provide a process for optimum separation of the BPA/phenol adduct crystals from the mother liquor and purification of the crystals.
- the invention provides a process for separating and purifying adducts of bis(4-hydroxyaryl)alkanes and aromatic hydroxy compounds obtained during production by acid-catalysed reaction of aromatic hydroxy compounds with ketones, which process is characterised in that the adduct crystals formed in the process are separated from the mother liquor after crystallisation out of the suspension by continuous filtration in a revolving vacuum drum filter containing a plurality of filter cells and then washed, and the washing liquid is drawn off.
- the invention preferably relates to the separation and purification of the 2,2-bis(4-hydroxyphenyl)propane/phenol adduct crystals (BPA/phenol adduct crystals) arising during production by acid-catalysed reaction of phenol and acetone.
- BPA/phenol adduct crystals 2,2-bis(4-hydroxyphenyl)propane/phenol adduct crystals
- Vacuum drum filters are known (e.g. Krauss Maffei drum filter TSF; FIG. 1 ).
- the drum filters preferably contain as filter cells a cake-forming zone ( 12 ), a washing zone ( 13 ), a drying suction zone ( 14 ), an aeration zone ( 15 ) and optionally a cake removal zone ( 10 ) and a cloth rinsing zone.
- the BPA/phenol adduct crystal suspension arising during crystallisation passes into the vacuum drum filter via a feed stream.
- the solids content in the feed stream is preferably 5-35%, in particular 20-30%.
- the feed stream preferably exhibits a temperature of from 40 to 70° C., in particular from 40 to 45° C., preferably around 41° C.
- the quantity of adduct crystals separated from the suspension liquid as filter cake per unit time and per m 2 filter surface area is preferably 100 to 800 kg/h, in particular 300 to 700 kg/h.
- a vacuum of from 5 to 500 mbar is preferably applied in the cake-forming zone.
- a vacuum of from 5 to 300 mbar is preferably applied in the washing zone.
- a vacuum of from 5 to 500 mbar is preferably applied in the drying suction zone.
- Rinsing of the filter cake in the washing zone is performed with pure phenol at temperatures of preferably 45 to 70° C., in particular 50 to 60° C.
- Filter cake cleaning is preferably performed using a rinsing agent quantity of 50-150% relative to the quantity of filter cake.
- the washing or rinsing liquid is introduced via washing nozzles, preferably 10 to 30 washing nozzles.
- the nozzles are generally preferably so arranged that their spray cones overlap on the filter cake.
- Cloth rinsing is preferably performed at temperatures of from 70 to 85° C., preferably 78 to 82° C., with pure phenol or with phenol recovered from the process by distillation.
- Cloth rinsing is preferably performed using a rinsing agent quantity of from 20 to 100% relative to the amount of filter cake.
- the filter cloth comprises a phenol- and heat-resistant filter cloth, preferably calendered once or twice, with air permeability of preferably 300 to 1500 l/dm 2 /min, in particular 500 to 900 l/dm 2 /min.
- the rotary filter housing is preferably rendered inert with nitrogen under a slight excess pressure of 20 mbar, preferably 10 mbar. Nitrogen is preferably also passed through the washed filter cake.
- the nitrogen used preferably has an oxygen content of less than 1 ppm and is preferably recirculated, wherein approximately 3-10% of the recirculated quantity is preferably continuously discharged and replaced by pure nitrogen.
- the recirculated nitrogen is preferably washed with completely deionised water.
- the drum rotation speed, filter cake thickness, recirculated nitrogen quantity and the suction openings in the control disk are set such that the residual moisture in the filter cake is below 30%, preferably 20%, in particular below 15%, relative to the mixed crystal quantity.
- Drum roundness and scraper knife orientation are so set that the scraper knife is at a maximum distance from the drum of preferably 4-6 mm over the entire filter surface.
- the BPA/phenol adduct crystals obtained in this way and separated and purified according to the invention are melted on a heating coil and, to keep the contact time between the adduct crystals and the hot stainless steel surface (1.4571) to a minimum, allowed to flow directly as a melt into a receiving tank.
- the surface temperature of the heating coil is preferably 130 to 230° C., preferably 150 to 170° C. Melting is preferably performed under inert conditions, in particular with the exclusion of oxygen (oxygen content ⁇ 1 ppm).
- the BPA/phenol adduct crystals arising during the acid-catalysed reaction of phenol and acetone with subsequent suspension crystallisation are separated off from the liquid phase by a rotary filter and fed to further cleaning.
- a solids content in the feed stream of 25%, a feed temperature of 41° C. and a quantity of separated-off mixed crystals (filter cake) of 500 kg/h per m 2 of filter surface area are established.
- Filtration is performed on a phenol- and heat-resistant filter cake (twice calendered) with air permeability of 700 l/dm 2 /min.
- the vacuum in the cake-forming zone is 100 mbar
- the vacuum in the washing zone is 80 mbar
- the vacuum in the drying suction zone is 100 mbar.
- the rotary filter housing is rendered inert with nitrogen ( ⁇ 1 ppm oxygen) under a slight excess pressure of 10 mbar.
- Drum rotation speed, filter cake thickness, recirculated nitrogen quantity (oxygen content ⁇ 1 ppm) and the suction openings in the control disk are set such that the residual moisture in the filter cake is ⁇ 15%, relative to the mixed crystal quantity.
- drum roundness and scraper knife orientation are so set that the scraper knife is at a maximum distance from the drum of approximately 5 mm over the entire filter surface.
- Pure phenol at a temperature of 55° C. is used for rinsing the filter cake in the washing zone, wherein the rinsing agent quantity for filter cake purification is 100% relative to the filter cake quantity.
- 20 washing nozzles are used, wherein the nozzles are so arranged that their spray cones overlap on the filter cake.
- Nitrogen oxygen content ⁇ 1 ppm
- Nitrogen is passed through the washed filter cake, which nitrogen is recirculated, wherein approximately 7% of the recirculated quantity is continuously discharged and replaced by pure nitrogen and the recirculated nitrogen is washed with completely deionised water.
- the mixed crystals are melted on a heating coil under inert conditions (oxygen content ⁇ 1 ppm), the melt flowing immediately to a receiving tank, to keep the contact time between the crystals and the hot stainless steel surface (1.4571) to a minimum.
- the surface temperature of the heating coil is approximately 160° C.
- Phenol at a temperature of 80° C. is used for cloth rinsing, wherein the rinsing agent quantity for cloth rinsing is 80% relative to the quantity of filter cake.
- a BPA/phenol adduct with high purity levels (>99% without phenol content) is obtained by this type of filtration.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19961521A DE19961521A1 (de) | 1999-12-20 | 1999-12-20 | Bisphenol-Phenol-Addukte |
DE19961521.7 | 1999-12-20 | ||
PCT/EP2000/012323 WO2001046105A1 (fr) | 1999-12-20 | 2000-12-07 | Adduits bisphenol-phenol |
Publications (2)
Publication Number | Publication Date |
---|---|
US20030038094A1 US20030038094A1 (en) | 2003-02-27 |
US6906227B2 true US6906227B2 (en) | 2005-06-14 |
Family
ID=7933457
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/149,905 Expired - Lifetime US6906227B2 (en) | 1999-12-20 | 2000-12-07 | Bisphenol phenol adducts |
Country Status (13)
Country | Link |
---|---|
US (1) | US6906227B2 (fr) |
EP (1) | EP1242350B1 (fr) |
JP (1) | JP4969007B2 (fr) |
KR (1) | KR100695860B1 (fr) |
CN (1) | CN1202059C (fr) |
AU (1) | AU3007401A (fr) |
BR (1) | BR0016505A (fr) |
DE (2) | DE19961521A1 (fr) |
ES (1) | ES2218277T3 (fr) |
HK (1) | HK1054920A1 (fr) |
MX (1) | MXPA02006089A (fr) |
TW (1) | TW568901B (fr) |
WO (1) | WO2001046105A1 (fr) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20040099613A1 (en) * | 2000-10-06 | 2004-05-27 | Franke Gijsbert Theodorus | Washing and dewatering of suspensions |
US20050145580A1 (en) * | 2001-10-02 | 2005-07-07 | Rotometrics | Method and apparatus to clean particulate matter from a toxic fluid |
US20070004941A1 (en) * | 2005-06-04 | 2007-01-04 | Ulrich Blaschke | Process for the preparation of high-purity bisphenol A |
US20160236121A1 (en) * | 2013-10-03 | 2016-08-18 | Bastenhof Consultancy B.V. | Filtration system and method for filtering a liquid |
US20170036143A1 (en) * | 2014-04-15 | 2017-02-09 | Bart Van Den Berg | Drum Filter for Water Filtration and Method Therefor |
US20200164290A1 (en) * | 2017-06-07 | 2020-05-28 | Sabic Global Technologies B.V. | Rotary vacuum filter, method, and use |
US10705588B2 (en) | 2011-10-27 | 2020-07-07 | Intel Corporation | Enabling a non-core domain to control memory bandwidth in a processor |
US20210252436A1 (en) * | 2018-06-21 | 2021-08-19 | Valmet Ab | Vacuum filter |
US11358077B2 (en) * | 2017-03-31 | 2022-06-14 | Krones Ag | Bottle-processing machine and method for cleaning the pump/nozzle protector of the bottle-processing machine |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19961521A1 (de) * | 1999-12-20 | 2001-06-21 | Bayer Ag | Bisphenol-Phenol-Addukte |
AU2003252295A1 (en) * | 2002-08-28 | 2004-03-19 | Idemitsu Kosan Co., Ltd. | Process for producing bisphenol a |
KR101131653B1 (ko) * | 2003-02-21 | 2012-03-28 | 다우 도이치란트 게엠베하 운트 코. 오하게 | 비스(4-히드록시아릴)알칸과 페놀계 화합물의 부가생성물의회수 방법 |
DE102004005723A1 (de) * | 2004-02-05 | 2005-08-25 | Bayer Materialscience Ag | Herstellung von Bisphenol A mit verringertem Schwefelgehalt |
JP2005232134A (ja) * | 2004-02-23 | 2005-09-02 | Mitsubishi Chemicals Corp | ビスフェノールaの製造方法 |
JP4876601B2 (ja) * | 2006-02-01 | 2012-02-15 | 三菱化学株式会社 | スラリーの取り扱い方法 |
JP5184751B2 (ja) * | 2006-03-16 | 2013-04-17 | 出光興産株式会社 | ビスフェノールaの製造方法 |
JP5210705B2 (ja) * | 2008-05-08 | 2013-06-12 | 三菱レイヨン株式会社 | アクリロニトリル系ポリマーの製造方法 |
EP2404650A1 (fr) | 2010-07-09 | 2012-01-11 | Bayer MaterialScience AG | Dispositif et procédé de séparation solide-liquide de suspensions solide-liquide |
CN101983750B (zh) * | 2010-12-23 | 2014-08-06 | 中信重工机械股份有限公司 | 一种用于立盘过滤机的高液位喷淋进料装置 |
DE102014108275A1 (de) * | 2014-06-12 | 2015-12-17 | Basf Se | Vorrichtung und Verfahren zur Abtrennung eines Zielprodukts aus einer das Zielprodukt enthaltenden flüssigen Phase |
DE102014016453B4 (de) | 2014-11-06 | 2018-08-23 | Lemmermeyer Gmbh & Co. Kg | Filtersystem, seine Verwendung sowie ein Verfahren zur Filtration von einer Lauge |
CN109513256A (zh) * | 2018-11-13 | 2019-03-26 | 湖南黄金洞矿业有限责任公司 | 一种高效分离矿浆和颗粒介质的过筛分离*** |
FR3095962B1 (fr) * | 2019-05-15 | 2021-10-15 | S N F Sa | Nouveau procédé de filtration de l’acide 2-acrylamido-2-méthylpropane sulfonique |
CN110075592A (zh) * | 2019-05-31 | 2019-08-02 | 威海沁和实业有限公司 | 螺旋过滤洗涤机 |
CN115487531B (zh) * | 2022-10-08 | 2024-04-16 | 常州工学院 | 一种对氨基苯酚中和结晶及连续甩干的综合处理装置 |
CN116440533B (zh) * | 2023-06-19 | 2023-08-29 | 东莞市瑞辉新材料技术有限公司 | 一种附带循环控温功能的双酚芴重结晶分离装置 |
Citations (4)
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US3972950A (en) * | 1974-08-14 | 1976-08-03 | Shell Oil Company | Process for the purification of bisphenol A |
US4212997A (en) * | 1978-06-27 | 1980-07-15 | General Electric Company | Process for recovering 2,2-bis(4-hydroxyphenyl)propane from an adduct of 2,2-bis(4-hydroxyphenyl)propane and phenol |
WO1994019302A1 (fr) | 1993-02-17 | 1994-09-01 | China Petro-Chemical Corporation | Nouveau procede de production de bisphenol a de grande purete et ultrapur |
US20030038094A1 (en) * | 1999-12-20 | 2003-02-27 | Rainer Neumann | Bisphenol phenol adducts |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
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GB2189403B (en) * | 1986-04-21 | 1989-11-29 | Steetley Refractories Ltd | Method of and apparatus for filtering a slurry |
JP3348737B2 (ja) * | 1993-04-21 | 2002-11-20 | 月島機械株式会社 | ビスフェノールaのフェノール付加物の遠心濾過分離方法 |
JPH0725798A (ja) * | 1993-07-08 | 1995-01-27 | Idemitsu Petrochem Co Ltd | 高純度ビスフェノールaの製造方法 |
DE4408008A1 (de) * | 1994-03-10 | 1995-09-14 | Bayer Ag | Verfahren zur kontinuierlichen Herstellung von hochreinem Bisphenol-A |
JPH0985016A (ja) * | 1995-09-26 | 1997-03-31 | Sumitomo Metal Mining Co Ltd | フィルターケーク剥ぎ取り装置 |
DE19727894A1 (de) * | 1997-07-01 | 1999-05-06 | Clariant Gmbh | Synthetisches Magnesiumsilikat |
JP3946845B2 (ja) * | 1997-12-24 | 2007-07-18 | 日本ジーイープラスチックス株式会社 | ビスフェノール類の製造方法およびポリカーボネートの製造方法 |
-
1999
- 1999-12-20 DE DE19961521A patent/DE19961521A1/de not_active Withdrawn
-
2000
- 2000-12-07 US US10/149,905 patent/US6906227B2/en not_active Expired - Lifetime
- 2000-12-07 EP EP00990667A patent/EP1242350B1/fr not_active Expired - Lifetime
- 2000-12-07 DE DE50005938T patent/DE50005938D1/de not_active Expired - Lifetime
- 2000-12-07 BR BR0016505-0A patent/BR0016505A/pt not_active Application Discontinuation
- 2000-12-07 AU AU30074/01A patent/AU3007401A/en not_active Abandoned
- 2000-12-07 ES ES00990667T patent/ES2218277T3/es not_active Expired - Lifetime
- 2000-12-07 KR KR1020027007870A patent/KR100695860B1/ko not_active IP Right Cessation
- 2000-12-07 WO PCT/EP2000/012323 patent/WO2001046105A1/fr active IP Right Grant
- 2000-12-07 CN CNB008174326A patent/CN1202059C/zh not_active Expired - Lifetime
- 2000-12-07 MX MXPA02006089A patent/MXPA02006089A/es unknown
- 2000-12-07 JP JP2001546619A patent/JP4969007B2/ja not_active Expired - Fee Related
- 2000-12-19 TW TW089127150A patent/TW568901B/zh not_active IP Right Cessation
-
2003
- 2003-10-09 HK HK03107259A patent/HK1054920A1/xx not_active IP Right Cessation
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US3972950A (en) * | 1974-08-14 | 1976-08-03 | Shell Oil Company | Process for the purification of bisphenol A |
US4212997A (en) * | 1978-06-27 | 1980-07-15 | General Electric Company | Process for recovering 2,2-bis(4-hydroxyphenyl)propane from an adduct of 2,2-bis(4-hydroxyphenyl)propane and phenol |
WO1994019302A1 (fr) | 1993-02-17 | 1994-09-01 | China Petro-Chemical Corporation | Nouveau procede de production de bisphenol a de grande purete et ultrapur |
US20030038094A1 (en) * | 1999-12-20 | 2003-02-27 | Rainer Neumann | Bisphenol phenol adducts |
Cited By (15)
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US20040099613A1 (en) * | 2000-10-06 | 2004-05-27 | Franke Gijsbert Theodorus | Washing and dewatering of suspensions |
US20050145580A1 (en) * | 2001-10-02 | 2005-07-07 | Rotometrics | Method and apparatus to clean particulate matter from a toxic fluid |
US7404904B2 (en) * | 2001-10-02 | 2008-07-29 | Melvin Stanley | Method and apparatus to clean particulate matter from a toxic fluid |
US20070004941A1 (en) * | 2005-06-04 | 2007-01-04 | Ulrich Blaschke | Process for the preparation of high-purity bisphenol A |
US20080108851A1 (en) * | 2005-06-04 | 2008-05-08 | Bayer Materialscience Ag | Process for the Preparation of High-Purity Bisphenol A |
US7427694B2 (en) | 2005-06-04 | 2008-09-23 | Bayer Materialscience Ag | Process for the preparation of high-purity bisphenol A |
US10705588B2 (en) | 2011-10-27 | 2020-07-07 | Intel Corporation | Enabling a non-core domain to control memory bandwidth in a processor |
US20160236121A1 (en) * | 2013-10-03 | 2016-08-18 | Bastenhof Consultancy B.V. | Filtration system and method for filtering a liquid |
US9956510B2 (en) * | 2013-10-03 | 2018-05-01 | Bastenhof Consultancy B.V. | Filtration system and method for filtering a liquid |
US20170036143A1 (en) * | 2014-04-15 | 2017-02-09 | Bart Van Den Berg | Drum Filter for Water Filtration and Method Therefor |
US10792595B2 (en) * | 2014-04-15 | 2020-10-06 | Bart Van Den Berg | Drum filter for water filtration and method therefor |
US11358077B2 (en) * | 2017-03-31 | 2022-06-14 | Krones Ag | Bottle-processing machine and method for cleaning the pump/nozzle protector of the bottle-processing machine |
US20200164290A1 (en) * | 2017-06-07 | 2020-05-28 | Sabic Global Technologies B.V. | Rotary vacuum filter, method, and use |
US20210252436A1 (en) * | 2018-06-21 | 2021-08-19 | Valmet Ab | Vacuum filter |
US11980837B2 (en) * | 2018-06-21 | 2024-05-14 | Valmet Ab | Rotary drum vacuum filter with a throttling valve |
Also Published As
Publication number | Publication date |
---|---|
EP1242350B1 (fr) | 2004-03-31 |
AU3007401A (en) | 2001-07-03 |
DE50005938D1 (de) | 2004-05-06 |
US20030038094A1 (en) | 2003-02-27 |
KR20020062355A (ko) | 2002-07-25 |
TW568901B (en) | 2004-01-01 |
JP4969007B2 (ja) | 2012-07-04 |
ES2218277T3 (es) | 2004-11-16 |
BR0016505A (pt) | 2002-08-27 |
MXPA02006089A (es) | 2003-01-28 |
CN1411430A (zh) | 2003-04-16 |
CN1202059C (zh) | 2005-05-18 |
HK1054920A1 (en) | 2003-12-19 |
EP1242350A1 (fr) | 2002-09-25 |
JP2003518049A (ja) | 2003-06-03 |
WO2001046105A1 (fr) | 2001-06-28 |
KR100695860B1 (ko) | 2007-03-20 |
DE19961521A1 (de) | 2001-06-21 |
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