US5605847A - Process for fabricating a TFT by selectively oxidizing or nitriding a light shielding layer - Google Patents

Process for fabricating a TFT by selectively oxidizing or nitriding a light shielding layer Download PDF

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US5605847A
US5605847A US08/459,826 US45982695A US5605847A US 5605847 A US5605847 A US 5605847A US 45982695 A US45982695 A US 45982695A US 5605847 A US5605847 A US 5605847A
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light
shielding layer
semiconductor island
forming
transparent
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Hongyong Zhang
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Semiconductor Energy Laboratory Co Ltd
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Semiconductor Energy Laboratory Co Ltd
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L27/00—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
    • H01L27/02—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers
    • H01L27/12—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body
    • H01L27/1214—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components specially adapted for rectifying, oscillating, amplifying or switching and having potential barriers; including integrated passive circuit elements having potential barriers the substrate being other than a semiconductor body, e.g. an insulating body comprising a plurality of TFTs formed on a non-semiconducting substrate, e.g. driving circuits for AMLCDs
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76—Unipolar devices, e.g. field effect transistors
    • H01L29/772—Field effect transistors
    • H01L29/78—Field effect transistors with field effect produced by an insulated gate
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/136—Liquid crystal cells structurally associated with a semi-conducting layer or substrate, e.g. cells forming part of an integrated circuit
    • G02F1/1362—Active matrix addressed cells
    • G02F1/136209—Light shielding layers, e.g. black matrix, incorporated in the active matrix substrate, e.g. structurally associated with the switching element
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007—Multistep manufacturing processes
    • H01L29/66075—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66227—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
    • H01L29/66409—Unipolar field-effect transistors
    • H01L29/66477—Unipolar field-effect transistors with an insulated gate, i.e. MISFET
    • H01L29/66742—Thin film unipolar transistors
    • H01L29/6675—Amorphous silicon or polysilicon transistors
    • H01L29/66757—Lateral single gate single channel transistors with non-inverted structure, i.e. the channel layer is formed before the gate
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76—Unipolar devices, e.g. field effect transistors
    • H01L29/772—Field effect transistors
    • H01L29/78—Field effect transistors with field effect produced by an insulated gate
    • H01L29/786—Thin film transistors, i.e. transistors with a channel being at least partly a thin film
    • H01L29/78606—Thin film transistors, i.e. transistors with a channel being at least partly a thin film with supplementary region or layer in the thin film or in the insulated bulk substrate supporting it for controlling or increasing the safety of the device
    • H01L29/78633—Thin film transistors, i.e. transistors with a channel being at least partly a thin film with supplementary region or layer in the thin film or in the insulated bulk substrate supporting it for controlling or increasing the safety of the device with a light shield

Definitions

  • the present invention relates to a semiconductor device comprising a thin film transistor (hereinafter referred to simply as a "TFT"), and to a process for fabricating the same.
  • TFT thin film transistor
  • Thin film transistors have been applied heretofore to active-matrix addressed liquid crystal display devices or to image sensors.
  • the active matrix liquid crystal display devices using TFTs as switching elements i.e., those comprising TFTs being formed in each of the pixels, are attracting much attention as liquid crystal display devices capable of operating at high speed.
  • the electric conductivity of the active layer of a TFT increases as light is irradiated thereto, because the active layers are made of a film of amorphous silicon or crystalline silicon which is usually photosensitive.
  • the o increase in conductivity of an active layer then unfavorably impairs the charge retention of a pixel electrode, because the off current, which is an important characteristic of a TFT switching element, is increased by the irradiation of light. Accordingly, it is necessary to establish a special constitution for the TFT, i.e., a constitution in which light is not irradiated to the active layer, and particularly, in which the channel-forming region of the active layer is isolated from light.
  • the primary purpose of the present invention is to provide a structure in which a TFT is protected from light entering from outside in order to reduce an Ioff current of the TFT.
  • a light-blocking (light shielding) film is interposed between a TFT and a light transparent substrate. More specifically, the light-blocking film comprises such a material which is capable of being changed to a light-transparent film upon oxidation or nitridation. Therefore, the unnecessary portion of the light-blocking film which is not located under the TFT but is selectively converted to light transparent without using a complicated photolithography process for pattering the light-blocking film.
  • the light blocking film prevents the TFT from being undesirably irradiated with light entering from a transparent substrate while the other portions of the light blocking film are changed to be transparent so that the device can operate as an electro-optical display device.
  • the present invention is applicable not only to an active matrix liquid crystal device in which TFTs are provided on a pixel area of a transparent substrate or an image sensor, but also to an integrated circuit which employs TFTs formed on a transparent substrate.
  • the light-blocking layer in the present invention comprises a material selected from the group consisting of silicon and aluminum, for example. These materials are light-shielding but can be made transparent upon oxidation or nitridation. Further, it is preferable to dope the silicon with an appropriate impurity, for example, phosphorous, arsenic, boron, aluminum or other IIIb or Vb group elements.
  • a semiconductor island which forms source, drain and channel regions therein has its peripheral portion nitrided or oxidized.
  • FIGS. 1A-1G are schematic cross-sectional views showing a manufacturing process of a TFT in accordance with a first embodiment of the invention.
  • FIG. 2 shows a plane view showing a TFT obtained in accordance with a first embodiment of the invention
  • FIGS. 3A-3D are schematic cross-sectional views showing a manufacturing process of a TFT in accordance with a second embodiment of the invention.
  • FIG. 4 shows a cross-sectional view of a liquid crystal device utilizing TFTs as a switching element of a pixel.
  • an amorphous silicon film 12 doped with phosphorous is formed under the lower side of an active layer comprising source/drain regions 22 and 24 and a channel region 23, and light is irradiated from the substrate side.
  • the amorphous silicon film 12 functions as a light shield to shut off the light irradiated from the substrate side.
  • the shaded region other than the active area is nitrided or oxidized to impart light transmitting properties thereto.
  • the active region is surrounded by a nitrided or an oxidized portion 28, and the light shielding layer also extends thereunder, the active layer is completely shielded from light.
  • the TFT can be completely shielded from incident light irradiated from the substrate side;
  • the channel forming region can be fixed at the ground level because the phosphorous doped silicon film is electrically conductive;
  • metal elements such as nickel can be gettered.
  • FIG. 3D Another typical example of the present invention is described below referring to FIG. 3D.
  • light is irradiated from the substrate side (the lower side of the figure).
  • an aluminum film 32 is provided to the lower portion of the active layer in which source/drain regions 40 and 42, and a channel forming region 41 is formed.
  • the aluminum film shields the active layer from light passing through the substrate. Nitrogen or oxygen atoms are implanted into the regions other than the region corresponding to the active layer in order to render those regions transparent by forming aluminum nitride or aluminum oxide. Since the aluminum film 32 is extended to the peripheral portion (as indicated with reference numeral 48) around the active layer, light path to the active layer from the glass substrate 31 is cut off completely.
  • the TFT can be completely shielded from incident light irradiated from the substrate side;
  • the film functions as a heat sink to stabilize the operation of a TFT.
  • the present example provides a process for fabricating an N-channel TFT according to an embodiment of the present invention.
  • a P-channel TFT can be fabricated in the same manner by modifying the source/drain regions into P-type conductive source/drain regions.
  • a P-channel TFT and an N-channel TFT can be formed in a complementary configuration to provide a CMOS circuit.
  • the TFT according to the present example can be used in an active-matrix type liquid crystal display device or in an image sensor. Furthermore, it can be used in an integrated circuit formed on a light-transmitting substrate.
  • an amorphous silicon film 12 doped with phosphorous is formed at a thickness of on a glass substrate 11.
  • the silicon film absorbs light and functions mainly as a light shield.
  • the concentration of phosphorous contained in the amorphous silicon is 1 ⁇ 10 19 atoms/cm 3 -5 ⁇ 10 21 atoms/cm 3 , preferably, 1-5 ⁇ 10 20 atoms/cm 3 .
  • the doped amorphous silicon film is electrically conductive, and hence, it maintains the potential of the region in which the channel is formed later at a ground level.
  • an insulating film such as a silicon oxide film 13 is deposited by sputtering to a thickness of 500 ⁇ (generally in the range of from 300 to 600 ⁇ ).
  • An amorphous silicon film 14 is then deposited to a thickness of 1,000 ⁇ (generally in the range of from 500 to 1,500 ⁇ ) by plasma CVD.
  • the amorphous silicon film 14 functions as an active layer of the TFT. If necessary, the amorphous silicon film may be crystallized to provide a crystalline silicon film 14.
  • the crystalline silicon film 14 can be obtained by thermally annealing the amorphous silicon film, by irradiating a laser beam to the amorphous silicon film, or by initially forming a crystalline silicon film.
  • a silicon oxide film 15 is then further deposited by sputtering at a thickness of 500 ⁇ (generally in the range of from 200 to 1,000 ⁇ ).
  • a 2,000 ⁇ thick (generally from 2,000 to 3,000 ⁇ thick) aluminum film 16 is formed thereafter by vapor deposition.
  • a mask is further formed thereon using a resist 17 to obtain a structure as shown in FIG. 1A.
  • the aluminum film 16, the silicon oxide film 15, and the silicon film 14 are etched by using the resist 17 as the mask to obtain an island-like laminate.
  • the aluminum film 16 is side-etched thereafter as shown in FIG. 1B by means of isotropic dry etching. The side etching is effected to leave a light shielding layer in a marginal portion 48 in the final product shown in FIG. 1G.
  • the resist 17 is removed thereafter to introduce nitrogen by ion implantation.
  • the aluminum film 16 functions as a mask for introducing nitrogen inside the hatched portion 18.
  • Annealing is effected thereafter to impart light-transmitting properties to the nitrogen-implanted region by nitridation.
  • the annealing step is preferably effected by irradiating an intense light (infrared radiation).
  • An infrared radiation is selectively absorbed by silicon and not by the glass. Accordingly, the temperature of silicon can be selectively elevated to a value as high as 1,000° C. or even higher so that an effect well comparable to that of thermal annealing at 1,000° C. can be obtained.
  • the portion of the phosphorous doped silicon film 12 in which the nitrogen is implanted becomes transparent. That is, the hatched portion shown in FIG. 1(C) is subjected to nitriding to provide a light-transmitting region. The silicon oxide film 15 and the aluminum film 16 are removed thereafter to obtain a structure as shown in FIG. 1D. Thus, a light-shielded active region surrounded by a nitride portion can be established while rendering the other region light-transmittable.
  • another silicon oxide film 19 is formed thereafter at a thickness of 1,000 ⁇ by sputtering.
  • the silicon oxide film thus obtained functions as a gate insulation film.
  • An aluminum film containing 1 to 2% silicon is formed thereafter at a thickness of 6,000 ⁇ and patterned to obtain a gate electrode 20.
  • An anodic oxide layer 21 is formed around this aluminum gate electrode to a thickness of 2,000 ⁇ . This step of anodic oxidation is effected in an ethylene glycol solution containing from 1 to 5% tartaric acid.
  • the anodic oxide layer 21 functions as a mask in forming an offset gate region in the later step of implanting phosphorus ion.
  • FIG. 1E thus is obtained a structure illustrated in FIG. 1E.
  • the gate electrode may be of a known type containing silicon as the principal component, a laminate of silicon and a metal, or may be a silicide.
  • Phosphorus ions are selectively introduced into the semiconductor layer by ion implantation thereafter as shown in FIG. 1F.
  • source/drain regions 22 and 24, which were rendered N-type, and a channel forming region 23 are formed in a self-aligning manner.
  • a laser beam or an intense light is irradiated to the resulting structure to activate the implanted phosphorus and to effect annealing.
  • an intense light an infrared light having a wavelength in the range of from 0.5 to 5 ⁇ m is desirable.
  • the heat annealing by the intense light is carried out in a short time, preferably within a few minutes.
  • An interlayer insulating film 25 is then formed with silicon oxide or polyimide and further electrodes 26 and 27 are formed as shown in FIG. 1G. Thus, a TFT is completed.
  • the active layer comprising source/drain regions 22, 24 and a channel forming region 23 is surrounded by a peripheral portion 28 into which nitrogen is implanted and nitrided.
  • FIG. 2 a planar view as seen from the upper side of the TFT of FIG. 1G is illustrated. It can be seen that a channel forming region 23 is formed under the gate electrode 20.
  • the thickness of the gate insulating layer is not enough at the side edges of the semiconductor layer because of a stepped configuration, and therefore, there is a problem that a leak current or short circuit occurs there between the gate electrode 20 and channel region 23.
  • the nitride 28 formed around the edges of the active layer prevents problems such as the concentration of electric field from occurring.
  • the light shielding film 12 extends not only just below the active layer of the TFT but also extends to a peripheral portion around the active layer as shown by the margin 48. This constitution prevents the TFT from being irradiated by the light incident to the TFT from the substrate 31 side.
  • the distance indicated with the numeral 48 corresponds to the thickness of the nitride 28 shown in FIG. 2.
  • the phosphorous doped silicon film 12 not only functions as a light shield but also functions as a gettering means with respect to impurities.
  • the regions other than the active layer is rendered light-transmittable by nitriding. Accordingly, the TFT can be maintained isolated from light while transmitting the light through the other regions.
  • the implanted portion of the silicon film becomes a transparent PSG. Also, in the case of using a mixture of oxygen and nitrogen, the implanted portion becomes transparent nitrided silicon oxide. (SiON)
  • An aluminum film 32 is formed on a glass substrate 31 by sputtering to a thickness of 500 ⁇ (generally in the range of from 200 to 1,000 ⁇ ), and a silicon oxide film 33 is formed further thereon by sputtering to a thickness of 500 ⁇ (generally in the range of from 200 to 800 ⁇ ).
  • An amorphous silicon film 34 is formed thereon by plasma CVD to a thickness of 1,000 ⁇ , and is crystallized thereafter by subjecting it to thermal annealing at 600° C. for a duration of 24 hours.
  • a silicon oxide film 35 is formed further thereon by sputtering to a thickness of 500 ⁇ , and an aluminum film 36 is formed thereon to a thickness of 1,000 ⁇ also by sputtering to form a resist 30.
  • the aluminum film 36 and the silicon oxide film 35 are patterned using this resist 30 to obtain a structure as shown in FIG. 3A.
  • nitrogen or oxygen ions for example, nitrogen ions (N+) in this case, are implanted into the shaded region 37.
  • the region 37 is nitrided and the amorphous silicon film 34 is partly converted into a light-transmitting silicon nitride film.
  • the silicon oxide film 33 is also converted into a silicon oxynitride film and rendered light-transmittable.
  • the aluminum film 32 also turns into a light-transmitting aluminum nitride (AlN) film.
  • AlN aluminum nitride
  • all the regions subjected to the ion implantation turn into light-transmitting regions.
  • the same effects result by implanting oxygen ions in place of nitrogen ions because an aluminum oxide (e.g. Al 2 O 3 ) film is obtained from an aluminum film.
  • a mixture of oxygen and nitrogen may be used to form aluminum oxynitride. (AlON)
  • a silicon oxide film 46 is formed to a thickness of 1,000 ⁇ by sputtering to provide a gate insulating film.
  • a 6,000 ⁇ thick aluminum film containing 1% silicon is formed and patterned to provide an aluminum gate electrode 38.
  • An oxide film 39 is then formed by anodic oxidation to a thickness of 2,000 ⁇ around the aluminum electrode 38 to obtain a structure as shown in FIG. 3C.
  • source/drain regions 40 and 42, and a channel forming region 41 are formed in a self-aligned manner by implanting phosphorus ions by ion implantation.
  • annealing is effected by irradiating a laser beam or an intense light.
  • the annealing can be effected most effectively by irradiating an infrared light at a wavelength region of from 0.5 to 5 ⁇ m, preferably about 1.3 ⁇ m.
  • the dangling bonds and defects in the silicon film can be removed efficiently by irradiating an infrared radiation, because infrared radiation can be selectively absorbed by the silicon film without considerably elevating the temperature of the glass substrate.
  • An inter layer insulator 43 is formed thereafter, and after perforating the holes therethrough, electrodes as source/drain electrodes 44 and 46 are formed to obtain a complete TFT as shown in FIG. 3D.
  • a phosphorus-doped silicon film or an aluminum film was used as the light shield layer in the examples above.
  • a titanium film may be used as a titanium oxide film or a titanium nitride film by implanting therein nitrogen or oxygen ions. Titanium oxide is light transmitting, but titanium nitride is opaque and cannot be use in the pixel portions.
  • metals or metal silicides or a laminate of metal and silicon can be used as the light-shielding layer.
  • Mo, Ta and Wo may be used as such a metal. It is also possible to add silicon into the metal at 0.1-30 atomic %.
  • a highly reliable TFT can be obtained by using a phosphorous doped silicon film or an aluminum film as the light shield layer and further imparting light-transmitting properties to the light-transmitting portions of the film by implanting nitrogen or oxygen ions therein.
  • FIG. 4 shows a cross-sectional view of a liquid crystal device utilizing TFTs as a switching element of a pixel, employing the present invention.
  • thin film transistors are provided on a transparent substrate 51 in accordance with the present invention.
  • Reference numeral 52 indicates a thin film transistor generally.
  • Each transistor is connected with a pixel electrode 53 comprising a transparent conductive film such as indium tin oxide.
  • the liquid crystal device includes a number of pixel electrodes 53 in the form a matrix.
  • a phosphorous doped amorphous silicon film 54 is formed on the transparent substrate 51 and under the transistors.
  • the portion of the silicon film which locates under the pixel electrodes has been changed to a transparent silicon oxide or silicon nitride film 55 upon oxidation or nitridation.
  • a silicon oxide film 56 between the transistors and the underlying silicon film as shown in the figure.
  • Reference numeral 61 denotes a driver circuit which is directly or indirectly formed on the substrate 51.
  • a known liquid crystal layer 60 such as a TN, STN or ferroelectric liquid crystal layer is interposed between the transparent substrate 51 and a counter substrate 57 having a counter electrode 58 and an orientation control film 59 formed thereon.
  • a light source is located on the side of the substrate 51 having the thin film transistors 52.
  • the light enters from the substrate 51 and is modified by the liquid crystal layer 60.
  • the modified light is seen from the side of the substrate 57.
  • the phosphorous doped silicon 54 prevents the light from entering into the active semiconductor layer of thin film transistors.
  • the liquid crystal device employing the present invention has a high reliability with respect to incident light.
  • the liquid crystal device can be used as a display which is directly seen by a user or as a projector in which the light modified by the liquid crystal is projected onto a screen.
  • polarizing plates are located on the path of the light appropriately.
  • the semiconductor device in accordance with the present invention should not be limited to the particular type of the TFT disclosed in the embodiments of the invention. Rather, any other type of thin film transistors such as an inverted coplaner type, a staggered type and an inverted staggered type may be used. Also, thin film diodes may be used instead of thin film transistors.

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US08/459,826 1993-06-24 1995-06-02 Process for fabricating a TFT by selectively oxidizing or nitriding a light shielding layer Expired - Lifetime US5605847A (en)

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US20050037554A1 (en) * 1995-08-02 2005-02-17 Semiconductor Energy Laboratory Co.,Ltd., A Japan Corporation Method for manufacturing semiconductor device
US20050110132A1 (en) * 2003-09-30 2005-05-26 Sanyo Electric Co., Ltd. Semiconductor device
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US20020063261A1 (en) 2002-05-30
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US6573589B2 (en) 2003-06-03
US5886364A (en) 1999-03-23
US6335540B1 (en) 2002-01-01
KR100294026B1 (ko) 2001-09-17

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