US3692684A - Detergent - Google Patents

Detergent Download PDF

Info

Publication number: US3692684A
Authority: US; United States
Prior art keywords: acid; detergent; acids; fatty; water
Prior art date: 1969-10-01
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

US20425A

Other languages

English (en)

Inventor

Gerhard Oskar Hentschel

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

VALTER SVEN ERWIN HENTSCHEL

Original Assignee

VALTER SVEN ERWIN HENTSCHEL

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1969-10-01

Filing date

1970-03-17

Publication date

1972-09-19

1970-03-17 Application filed by VALTER SVEN ERWIN HENTSCHEL filed Critical VALTER SVEN ERWIN HENTSCHEL

1972-09-19 Application granted granted Critical

1972-09-19 Publication of US3692684A publication Critical patent/US3692684A/en

1989-09-19 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000003599 detergent Substances 0.000 title abstract description 24
229910019142 PO4 Inorganic materials 0.000 abstract description 10
159000000011 group IA salts Chemical class 0.000 abstract description 7
150000003839 salts Chemical class 0.000 abstract description 6
150000001735 carboxylic acids Chemical class 0.000 abstract description 4
238000012851 eutrophication Methods 0.000 abstract description 3
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract description 3
150000008064 anhydrides Chemical class 0.000 abstract description 2
235000014113 dietary fatty acids Nutrition 0.000 description 16
239000000194 fatty acid Substances 0.000 description 16
229930195729 fatty acid Natural products 0.000 description 16
-1 aromatic carboxylic acids Chemical class 0.000 description 15
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 14
150000004665 fatty acids Chemical class 0.000 description 13
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
239000002253 acid Substances 0.000 description 12
239000000203 mixture Substances 0.000 description 12
150000002191 fatty alcohols Chemical class 0.000 description 9
235000021317 phosphate Nutrition 0.000 description 9
239000004094 surface-active agent Substances 0.000 description 8
238000005406 washing Methods 0.000 description 8
239000003795 chemical substances by application Substances 0.000 description 7
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
150000003013 phosphoric acid derivatives Chemical class 0.000 description 6
229920000151 polyglycol Polymers 0.000 description 6
239000010695 polyglycol Substances 0.000 description 6
150000007513 acids Chemical class 0.000 description 5
150000001408 amides Chemical class 0.000 description 5
125000000129 anionic group Chemical group 0.000 description 5
238000005282 brightening Methods 0.000 description 5
239000002304 perfume Substances 0.000 description 5
RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 5
FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 4
108090000790 Enzymes Proteins 0.000 description 4
102000004190 Enzymes Human genes 0.000 description 4
229930195725 Mannitol Natural products 0.000 description 4
125000001931 aliphatic group Chemical group 0.000 description 4
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 4
239000000460 chlorine Substances 0.000 description 4
230000000694 effects Effects 0.000 description 4
JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
239000000594 mannitol Substances 0.000 description 4
235000010355 mannitol Nutrition 0.000 description 4
YDSWCNNOKPMOTP-UHFFFAOYSA-N mellitic acid Chemical compound OC(=O)C1=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C(C(O)=O)=C1C(O)=O YDSWCNNOKPMOTP-UHFFFAOYSA-N 0.000 description 4
XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 4
125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 4
FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 3
FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 3
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
GCAIEATUVJFSMC-UHFFFAOYSA-N benzene-1,2,3,4-tetracarboxylic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1C(O)=O GCAIEATUVJFSMC-UHFFFAOYSA-N 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
239000007859 condensation product Substances 0.000 description 3
239000000975 dye Substances 0.000 description 3
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 3
239000010452 phosphate Substances 0.000 description 3
239000000600 sorbitol Substances 0.000 description 3
BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 3
239000000080 wetting agent Substances 0.000 description 3
QPHPUQJVKQXISS-UHFFFAOYSA-N 4-oxo-4-sulfanylbutanoic acid Chemical compound OC(=O)CCC(S)=O QPHPUQJVKQXISS-UHFFFAOYSA-N 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
239000005711 Benzoic acid Substances 0.000 description 2
241000196324 Embryophyta Species 0.000 description 2
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
235000011054 acetic acid Nutrition 0.000 description 2
150000001298 alcohols Chemical class 0.000 description 2
JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 2
235000010233 benzoic acid Nutrition 0.000 description 2
239000001273 butane Substances 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
150000001734 carboxylic acid salts Chemical class 0.000 description 2
RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
238000004851 dishwashing Methods 0.000 description 2
150000002148 esters Chemical class 0.000 description 2
239000008187 granular material Substances 0.000 description 2
TZMQHOJDDMFGQX-UHFFFAOYSA-N hexane-1,1,1-triol Chemical compound CCCCCC(O)(O)O TZMQHOJDDMFGQX-UHFFFAOYSA-N 0.000 description 2
239000003112 inhibitor Substances 0.000 description 2
239000004310 lactic acid Substances 0.000 description 2
235000014655 lactic acid Nutrition 0.000 description 2
239000007788 liquid Substances 0.000 description 2
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
150000003014 phosphoric acid esters Chemical class 0.000 description 2
239000000843 powder Substances 0.000 description 2
239000000047 product Substances 0.000 description 2
239000000344 soap Substances 0.000 description 2
239000011734 sodium Substances 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
150000005846 sugar alcohols Polymers 0.000 description 2
229910021653 sulphate ion Inorganic materials 0.000 description 2
SDHMGKANHNMOSS-UHFFFAOYSA-N 1-aminoethanesulfonic acid Chemical class CC(N)S(O)(=O)=O SDHMGKANHNMOSS-UHFFFAOYSA-N 0.000 description 1
CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 description 1
KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
235000013162 Cocos nucifera Nutrition 0.000 description 1
244000060011 Cocos nucifera Species 0.000 description 1
241000195493 Cryptophyta Species 0.000 description 1
FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
241001465754 Metazoa Species 0.000 description 1
SUZRRICLUFMAQD-UHFFFAOYSA-N N-Methyltaurine Chemical compound CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
201000002451 Overnutrition Diseases 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
108010009736 Protein Hydrolysates Proteins 0.000 description 1
239000004115 Sodium Silicate Substances 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical group OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
GTTSNKDQDACYLV-UHFFFAOYSA-N Trihydroxybutane Chemical compound CCCC(O)(O)O GTTSNKDQDACYLV-UHFFFAOYSA-N 0.000 description 1
239000012190 activator Substances 0.000 description 1
239000013543 active substance Substances 0.000 description 1
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 1
235000011037 adipic acid Nutrition 0.000 description 1
229960000250 adipic acid Drugs 0.000 description 1
230000001476 alcoholic effect Effects 0.000 description 1
230000005791 algae growth Effects 0.000 description 1
150000001335 aliphatic alkanes Chemical class 0.000 description 1
125000003282 alkyl amino group Chemical group 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
230000000844 anti-bacterial effect Effects 0.000 description 1
159000000032 aromatic acids Chemical class 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
239000003899 bactericide agent Substances 0.000 description 1
OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical class CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 description 1
239000007844 bleaching agent Substances 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
150000007942 carboxylates Chemical class 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
235000015165 citric acid Nutrition 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
239000012459 cleaning agent Substances 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
150000001991 dicarboxylic acids Chemical class 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
239000006260 foam Substances 0.000 description 1
239000004872 foam stabilizing agent Substances 0.000 description 1
150000002395 hexacarboxylic acids Chemical class 0.000 description 1
230000002209 hydrophobic effect Effects 0.000 description 1
125000001165 hydrophobic group Chemical group 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
150000002462 imidazolines Chemical class 0.000 description 1
150000007522 mineralic acids Chemical class 0.000 description 1
MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical class OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
229910017464 nitrogen compound Inorganic materials 0.000 description 1
150000002830 nitrogen compounds Chemical class 0.000 description 1
235000015097 nutrients Nutrition 0.000 description 1
235000020823 overnutrition Nutrition 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000002245 particle Substances 0.000 description 1
239000006072 paste Substances 0.000 description 1
229940083254 peripheral vasodilators imidazoline derivative Drugs 0.000 description 1
125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
239000010665 pine oil Substances 0.000 description 1
229920001522 polyglycol ester Polymers 0.000 description 1
IWZKICVEHNUQTL-UHFFFAOYSA-M potassium hydrogen phthalate Chemical compound [K+].OC(=O)C1=CC=CC=C1C([O-])=O IWZKICVEHNUQTL-UHFFFAOYSA-M 0.000 description 1
239000003531 protein hydrolysate Substances 0.000 description 1
229940071207 sesquicarbonate Drugs 0.000 description 1
150000004760 silicates Chemical class 0.000 description 1
235000017557 sodium bicarbonate Nutrition 0.000 description 1
229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
239000001540 sodium lactate Substances 0.000 description 1
235000011088 sodium lactate Nutrition 0.000 description 1
229940005581 sodium lactate Drugs 0.000 description 1
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
229910052911 sodium silicate Inorganic materials 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
239000003760 tallow Substances 0.000 description 1
239000011975 tartaric acid Substances 0.000 description 1
235000002906 tartaric acid Nutrition 0.000 description 1
229940095064 tartrate Drugs 0.000 description 1
230000002110 toxicologic effect Effects 0.000 description 1
231100000027 toxicology Toxicity 0.000 description 1
235000013619 trace mineral Nutrition 0.000 description 1
239000011573 trace mineral Substances 0.000 description 1
QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
239000002351 wastewater Substances 0.000 description 1
239000008096 xylene Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/221—Mono, di- or trisaccharides or derivatives thereof

Definitions

the present invention relates to a washing dish-washing and cleaning detergent in the shape of powders, granules or pastes or liquids, the phosphates previously used in such a detergent being completely or partly replaced by chemicals which are more suitable from the eutrophic point of view.
the purpose of the phosphates in detergent compositions is to soften the water and to keep thehardening agents in the water in solution. Further, the phosphates have a certain dispersion effect on the dirt particles and improves the effects of the tensides in certain respects.
carboxylic acids which are not dangerous from toxicologic point of view may be used.
One condition is of course that they could be accepted from water care'point of view. They must also give a satisfactory washing result.
COOH-groups give the best results in surface Washing and at the same time many of these acids are toxicologically and allergologically undangerous and do not endanger water care. Several of these carboxylic acids occur in nature and form so to say a natural component of the plants and animals.
anionic, double-ionic or nonionic tensides which may be present in the detergents according to the inventhem water soluble, this group being of anionic or nonionie character.
anionic active detergent soaps sulphonates and glp hates are of importance.
phosphate tion phosphate tion
NTA increases the algae growth why this solution of the eutrophication problem still is unsolved. Further, one does not know anything about the reactions between trace elements in natural watercourses and NTA.
the present invention relates to detergent compositions which contain alkaline salts of aliphatic and aromatic car boxylic acids and/or their anhydrides having as a maximum eight carbon atoms in the hydrophobic part or having one or several carboxylic groups or the free acids in a mixture with the alkaline salts of inorganic acids, e.g. carbonates and silicates.
alkaline salts of aliphatic and aromatic car boxylic acids and/or their anhydrides having as a maximum eight carbon atoms in the hydrophobic part or having one or several carboxylic groups or the free acids in a mixture with the alkaline salts of inorganic acids, e.g. carbonates and silicates.
inorganic acids e.g. carbonates and silicates.
Said acids are used because they contain only tensides cou be used.
the sulphonates may comprise alkylaryl sulphonates, alkyl sulphonates, alkene sulphonates and oxyalkane sulphonates. Also sulphonated esters may be used.
the sulphates may comprise e.g. alkylene sulphate, fatty alcohol ether sulphate, sulphated amides of fatty acids, sulphated monoglycerides, sulphating products of ethoxylated and/or propoxylated fatty alcohols, alkyl phenols, fatty acid amines, etc.
Sulphonates of fatty acid esters of oxethane sulphonic acid and dioxypropane sulphonic acid, fatty alcoholic esters of lower aliphatic and aromatic thiomonoand dicarboxylic acids as well as condensation products of fatty acids with aminoethane sulphonic acids may be used.
Synthetic capillary active carboxylates and condensation products of fatty acids with aminocarboxylic acids or with protein hydrolysates as well as phosphate esters of fatty alcohols and fatty acids may be used.
nonionic tensides one may use e.g. alkylic phenol, fatty alcohol, alkyl amino, fatty acid, fatty acid alkylol amide fatty amide polyglycolethers, phosphate esters of ethoxylated fatty alcohols, block polymerisates of ethylene oxide and propylene oxide etc.
amphoteric tensides may be used such as imidazoline derivatives of fatty acids, carboxybetaines, compounds with the phosphoric acid groups in the acid test or with sulphonic or sulphuric acid groups.
Foam stabilizers or foam inhibitors as well as corrosion inhibitors may be included and so may dirt carrying sub- It has turned out in practice that acids with several enzymes, dyes and water. Also different types of bleaching agents containing oxygen or chlorine and activators and stabilizers belonging thereto.
a multivalent higher alcohol in an amount up to 25%, preferably 0.58% as calculated on the quantity of said salts.
the multivalent alcohols are selected from the group consisting of sorbitol, mannitol, pentaerythritol, trimethylol propane, trirnethanol ethane, hexanetriol and butane triol.
EXAMPLE 3 Detergent for ordinary washing, sprayed I Parts Na-dodecyl benzene sulphonate .Q 10 Fatty alcohol polyglycol ether 5 Xylene sulphonate 7 SEHITJ'I'WBW 2 Phosphate ester of ethoxylated fatty alcohol 2 Na-perborate 15 Na-citrate 30 Mannitol 5 Na-silicate 10 EDTA or NTA 3 Na-salt of benzene tetracarboxylic acid 2 CMC, opt. brightening agent, Mg-silicate 9 EXAMPLE 4 Small-washing detergent, gran.
EXAMPLE 7 Dish-washing machine detergent Parts Polypropylene-ethylene oxide-addition product 3 Sodium alkylic polyglycol etherphosphate 3 Na-acetate 25 Na-sulphate 25 Na-citrate 30 Perfumes, dyes, bactericides, water l4
EXAMPLE 8 Washing and cleansing paste Parts Fatty acid imidazoline derivate, 50% 10 Succinic acid-Z-ethyl hexylic monoester 3 Undecylene acid monoethanol amide 3
Fatty acid condensation product with methyl taurine l6 Glycol derivate 7 Na-citrate 11 1,4-butane dicarboxylic acid 2 CMC 3 Water 45 What I claim is: 1.
a detergent composition consisting essentially of: a water-soluble surface active agent have 8 to 30 6 carbon atoms in the hydrophobic group thereof, 3.
surface active agent is an anionic wetting agent.

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Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Emergency Medicine (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Molecular Biology (AREA)
Detergent Compositions (AREA)

US20425A 1969-10-01 1970-03-17 Detergent Expired - Lifetime US3692684A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
SE13492/69A SE352652B (nl)	1969-10-01	1969-10-01

Publications (1)

Publication Number	Publication Date
US3692684A true US3692684A (en)	1972-09-19

Family

ID=20297485

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
US20425A Expired - Lifetime US3692684A (en)	1969-10-01	1970-03-17	Detergent

Country Status (12)

Country	Link
US (1)	US3692684A (nl)
JP (1)	JPS507610B1 (nl)
BE (1)	BE750676A (nl)
CH (1)	CH540973A (nl)
DE (1)	DE2026739C3 (nl)
FR (1)	FR2065800A5 (nl)
GB (1)	GB1309814A (nl)
LU (1)	LU60901A1 (nl)
NL (1)	NL7007168A (nl)
SE (1)	SE352652B (nl)
SU (1)	SU479299A3 (nl)
ZA (1)	ZA706253B (nl)

Cited By (29)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3844982A (en) *	1969-11-24	1974-10-29	Procter & Gamble	Built detergent composition
US3852220A (en) *	1972-01-12	1974-12-03	Marathon Oil Co	Isocyanurate-based polyelectrolyte detergent composition
US3859224A (en) *	1971-09-24	1975-01-07	Hoechst Ag	Detergent composition containing, as a builder, the sodium salt of glycerol tricitrate
US3872020A (en) *	1971-09-14	1975-03-18	Dai Ichi Kogyo Seiyaku Co Ltd	Detergent compositions
US3896040A (en) *	1971-01-04	1975-07-22	Andre Danesh	Detergent composition
US3915879A (en) *	1973-04-10	1975-10-28	Lever Brothers Ltd	Detergent compositions
US3920569A (en) *	1972-02-14	1975-11-18	Lever Brothers Ltd	Detergent composition having substituted phthalic acid salt builder
US3951877A (en) *	1972-07-17	1976-04-20	Lion Fat & Oil Co., Ltd.	Heavy-duty granular detergent composition with sodium citrate builder
US3953352A (en) *	1973-06-04	1976-04-27	Kao Soap Co., Ltd.	Acidic cleaning composition
US3962149A (en) *	1973-10-12	1976-06-08	Colgate-Palmolive Company	Non-phosphate spray dried detergents containing dicarboxylic acid salts
US3971728A (en) *	1972-03-07	1976-07-27	Ethyl Corporation	Sequestering agent
US4009114A (en) *	1974-09-23	1977-02-22	Colgate-Palmolive Company	Non-phosphate detergent composition
US4013579A (en) *	1973-06-06	1977-03-22	Kao Soap Co., Ltd.	Acidic cleaning composition
US4040972A (en) *	1975-03-12	1977-08-09	Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler	Ion-exchanging aluminum silicate with hydrophilic surfaces
US4088593A (en) *	1975-03-12	1978-05-09	Henkel Kommanditgesellschaft Auf Aktien (Henkel Kgaa)	Ion-exchanging aluminum silicate with hydrophilic surfaces
US4102799A (en) *	1974-08-29	1978-07-25	Colgate-Palmolive Company	Automatic dishwasher detergent with improved effects on overglaze
US4123375A (en) *	1975-11-22	1978-10-31	Henkel Kommanditgesellschaft Auf Aktien	Dishwasher detergent with clear rinsing effect and method of machine washing dishes
US4210550A (en) *	1978-07-14	1980-07-01	Akzo N.V.	Detergent composition containing an alkali carbonate
US4239552A (en) *	1978-08-03	1980-12-16	Basf Aktiengesellschaft	Machine dishwashing, using polyhydric alcohols, carboxylic acids and or esters of these as rinsing agents
US4239641A (en) *	1978-08-03	1980-12-16	Basf Aktiengesellschaft	Use of polyhydric alcohols, carboxylic acids, hydroxy-carboxylic acids and/or their esters with polyhydric alcohols as viscosity regulators
US4252663A (en) *	1971-01-15	1981-02-24	Ab Helios, Kemisk-Tekniska Fabriker	Detergent compositions
US4395365A (en) *	1980-09-08	1983-07-26	Nissan Motor Co., Ltd.	Metal cleaning composition containing a fatty acid succrose ester and other detergent components
US4594175A (en) *	1984-08-29	1986-06-10	Economics Laboratory, Inc.	Mechanical dishwashing rinse composition having a low foaming sulfonic acid rinsing agent, a hydrotrope and a source of active halogen
US4612137A (en) *	1984-09-03	1986-09-16	Kao Corporation	Anti-yellowing detergent composition containing citrate and isocitrate
US4613448A (en) *	1973-09-24	1986-09-23	The Colgate-Palmolive Co.	Detergent compositions
US4902439A (en) *	1987-04-15	1990-02-20	Ciba-Geigy Corporation	Detergent composition for washing off dyeings obtained with fibre-reactive dyes, process for the preparation thereof and use thereof
US4935158A (en) *	1986-10-30	1990-06-19	Aszman Harry W	Solid detergent cleaning composition, reusable cleaning pad containing same and method of manufacture
US4983315A (en) *	1989-08-10	1991-01-08	The Procter & Gamble Company	N,N'-(1-oxo-1,2-ethanediyl)-bis(aspartic acid), salts and use in detergent compositions
US5427707A (en) *	1985-06-14	1995-06-27	Colgate Palmolive Co.	Thixotropic aqueous compositions containing adipic or azelaic acid stabilizer

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
ZA72142B (en) *	1971-01-25	1973-09-26	Colgate Palmolive Co	Heavy duty liquid detergent
CA966751A (en) *	1971-03-18	1975-04-29	Charles R. Ries	Phosphorus-free detergent composition
BE787682A (fr) *	1971-08-17	1973-02-19	Unilever Nv	Compositions detergentes
US4013577A (en) *	1972-04-14	1977-03-22	Colgate-Palmolive Company	Heavy duty dry biodegradable detergent composition
GB1432137A (en) *	1972-06-13	1976-04-14	Chem Y	Detergent compositions
DE2230453A1 (de) *	1972-06-22	1974-01-17	Benckiser Gmbh Joh A	Grundstoffansatz fuer wasch- und reinigungsmittel
IT1002614B (it) *	1973-01-15	1976-05-20	Colgate Palmolive Co	Detersivo anionico privo di fosfati
NL7407851A (nl) *	1973-06-15	1974-12-17
US3971815A (en) *	1974-11-13	1976-07-27	The Procter & Gamble Company	Acid mix process
CH639416A5 (de) *	1977-06-27	1983-11-15	Akzo Nv	Detergentienzusammensetzung enthaltend alkalicarbonat.
IT1124027B (it) *	1979-03-23	1986-05-07	Mira Lanza Spa	Composizione detersiva a basso o nullo tenore di fosforo
GB8522621D0 (en) *	1985-09-12	1985-10-16	Unilever Plc	Detergent powder
GB2330588B (en) *	1997-10-24	1999-08-18	Cheng Wen Lin	Multipurpose cleaning agent
DE19851662A1 (de) *	1998-11-10	2000-05-18	Menno Chemie Vertriebsges M B	Mittel zur Beseitigung der Klebefähigkeit von Helmintheneiern
RU2530883C2 (ru) *	2012-08-29	2014-10-20	Общество с ограниченной ответственностью Пермская производственная фирма "Фантом"	Моющая композиция для очистки поверхностей различных твердых тел

1969
- 1969-10-01 SE SE13492/69A patent/SE352652B/xx unknown
1970
- 1970-03-17 US US20425A patent/US3692684A/en not_active Expired - Lifetime
- 1970-05-06 CH CH680070A patent/CH540973A/de not_active IP Right Cessation
- 1970-05-07 GB GB2196070A patent/GB1309814A/en not_active Expired
- 1970-05-12 LU LU60901D patent/LU60901A1/xx unknown
- 1970-05-14 JP JP45040551A patent/JPS507610B1/ja active Pending
- 1970-05-16 NL NL7007168A patent/NL7007168A/xx unknown
- 1970-05-19 FR FR7017212A patent/FR2065800A5/fr not_active Expired
- 1970-05-20 BE BE750676D patent/BE750676A/xx unknown
- 1970-06-01 DE DE2026739A patent/DE2026739C3/de not_active Expired
- 1970-09-08 SU SU1474363A patent/SU479299A3/ru active
- 1970-09-14 ZA ZA706253A patent/ZA706253B/xx unknown

Cited By (29)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3844982A (en) *	1969-11-24	1974-10-29	Procter & Gamble	Built detergent composition
US3896040A (en) *	1971-01-04	1975-07-22	Andre Danesh	Detergent composition
US4252663A (en) *	1971-01-15	1981-02-24	Ab Helios, Kemisk-Tekniska Fabriker	Detergent compositions
US3872020A (en) *	1971-09-14	1975-03-18	Dai Ichi Kogyo Seiyaku Co Ltd	Detergent compositions
US3859224A (en) *	1971-09-24	1975-01-07	Hoechst Ag	Detergent composition containing, as a builder, the sodium salt of glycerol tricitrate
US3852220A (en) *	1972-01-12	1974-12-03	Marathon Oil Co	Isocyanurate-based polyelectrolyte detergent composition
US3920569A (en) *	1972-02-14	1975-11-18	Lever Brothers Ltd	Detergent composition having substituted phthalic acid salt builder
US3971728A (en) *	1972-03-07	1976-07-27	Ethyl Corporation	Sequestering agent
US3951877A (en) *	1972-07-17	1976-04-20	Lion Fat & Oil Co., Ltd.	Heavy-duty granular detergent composition with sodium citrate builder
US3915879A (en) *	1973-04-10	1975-10-28	Lever Brothers Ltd	Detergent compositions
US3953352A (en) *	1973-06-04	1976-04-27	Kao Soap Co., Ltd.	Acidic cleaning composition
US4013579A (en) *	1973-06-06	1977-03-22	Kao Soap Co., Ltd.	Acidic cleaning composition
US4613448A (en) *	1973-09-24	1986-09-23	The Colgate-Palmolive Co.	Detergent compositions
US3962149A (en) *	1973-10-12	1976-06-08	Colgate-Palmolive Company	Non-phosphate spray dried detergents containing dicarboxylic acid salts
US4102799A (en) *	1974-08-29	1978-07-25	Colgate-Palmolive Company	Automatic dishwasher detergent with improved effects on overglaze
US4009114A (en) *	1974-09-23	1977-02-22	Colgate-Palmolive Company	Non-phosphate detergent composition
US4088593A (en) *	1975-03-12	1978-05-09	Henkel Kommanditgesellschaft Auf Aktien (Henkel Kgaa)	Ion-exchanging aluminum silicate with hydrophilic surfaces
US4040972A (en) *	1975-03-12	1977-08-09	Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler	Ion-exchanging aluminum silicate with hydrophilic surfaces
US4123375A (en) *	1975-11-22	1978-10-31	Henkel Kommanditgesellschaft Auf Aktien	Dishwasher detergent with clear rinsing effect and method of machine washing dishes
US4210550A (en) *	1978-07-14	1980-07-01	Akzo N.V.	Detergent composition containing an alkali carbonate
US4239552A (en) *	1978-08-03	1980-12-16	Basf Aktiengesellschaft	Machine dishwashing, using polyhydric alcohols, carboxylic acids and or esters of these as rinsing agents
US4239641A (en) *	1978-08-03	1980-12-16	Basf Aktiengesellschaft	Use of polyhydric alcohols, carboxylic acids, hydroxy-carboxylic acids and/or their esters with polyhydric alcohols as viscosity regulators
US4395365A (en) *	1980-09-08	1983-07-26	Nissan Motor Co., Ltd.	Metal cleaning composition containing a fatty acid succrose ester and other detergent components
US4594175A (en) *	1984-08-29	1986-06-10	Economics Laboratory, Inc.	Mechanical dishwashing rinse composition having a low foaming sulfonic acid rinsing agent, a hydrotrope and a source of active halogen
US4612137A (en) *	1984-09-03	1986-09-16	Kao Corporation	Anti-yellowing detergent composition containing citrate and isocitrate
US5427707A (en) *	1985-06-14	1995-06-27	Colgate Palmolive Co.	Thixotropic aqueous compositions containing adipic or azelaic acid stabilizer
US4935158A (en) *	1986-10-30	1990-06-19	Aszman Harry W	Solid detergent cleaning composition, reusable cleaning pad containing same and method of manufacture
US4902439A (en) *	1987-04-15	1990-02-20	Ciba-Geigy Corporation	Detergent composition for washing off dyeings obtained with fibre-reactive dyes, process for the preparation thereof and use thereof
US4983315A (en) *	1989-08-10	1991-01-08	The Procter & Gamble Company	N,N'-(1-oxo-1,2-ethanediyl)-bis(aspartic acid), salts and use in detergent compositions

Also Published As

Publication number	Publication date
CH540973A (de)	1973-08-31
LU60901A1 (nl)	1970-07-16
SU479299A3 (ru)	1975-07-30
JPS507610B1 (nl)	1975-03-27
FR2065800A5 (nl)	1971-08-06
SE352652B (nl)	1973-01-08
DE2026739B2 (de)	1978-04-27
DE2026739A1 (de)	1971-04-22
NL7007168A (nl)	1971-04-05
BE750676A (fr)	1970-11-03
DE2026739C3 (de)	1979-01-18
GB1309814A (en)	1973-03-14
ZA706253B (en)	1971-05-27

Publication	Publication Date	Title
US3692684A (en)	1972-09-19	Detergent
ES2586461B1 (es)	2017-12-01	Composición detergente en forma de pastilla efervescente
US3676340A (en)	1972-07-11	Combinations of detergents with controlled foaming properties and washing agents containing them
US4199482A (en)	1980-04-22	Laundry pre-spotter composition and method of using same
US3741911A (en)	1973-06-26	Phosphate-free detergent composition
FI57610C (fi)	1980-09-10	Flytande syntetiska tvaettmedelkompositioner utan stoedsubstanser
US3583924A (en)	1971-06-08	Cleaning composition with improved bleaching effect
US3707503A (en)	1972-12-26	Stabilized liquid detergent composition
GB1439000A (en)	1976-06-09	Washing compositions and washing assistants for textiles
US3951879A (en)	1976-04-20	Detergent that reduces electrostatic cling of synthetic fabrics
JPH01104883A (ja)	1989-04-21	布地を柔軟にするための組成物
US3816318A (en)	1974-06-11	Detergent
US20160348042A1 (en)	2016-12-01	Concentrated laundry detergents
JPH08502095A (ja)	1996-03-05	改良型汎用洗浄組成物
US4009114A (en)	1977-02-22	Non-phosphate detergent composition
US4248729A (en)	1981-02-03	Detergency booster
TW201311881A (zh)	2013-03-16	液體洗淨劑組合物
CA1044983A (en)	1978-12-26	Liquid detergent compositions
US20120015859A1 (en)	2012-01-19	Fluid bleaching agent composition
GB1459033A (en)	1976-12-22	Pulverulent foam-regulated washing compositions
GB1298236A (en)	1972-11-29	Improvements in or relating to the treatment of textiles
JP5250714B2 (ja)	2013-07-31	衣料用粉末洗剤組成物
AU598489B2 (en)	1990-06-28	Detergent composition of improved oily soil removing capability
RU2230104C1 (ru)	2004-06-10	Синтетическое моющее средство для стирки детского белья
JP5876023B2 (ja)	2016-03-02	衣料用粉末洗剤組成物

US3692684A - Detergent - Google Patents

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Applications Claiming Priority (1)

Publications (1)

Family

ID=20297485

Family Applications (1)

Country Status (12)

Cited By (29)

Families Citing this family (15)

Cited By (29)

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