US3692684A - Detergent - Google Patents

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US3692684A
US3692684A US20425A US3692684DA US3692684A US 3692684 A US3692684 A US 3692684A US 20425 A US20425 A US 20425A US 3692684D A US3692684D A US 3692684DA US 3692684 A US3692684 A US 3692684A
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acid
detergent
acids
fatty
water
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US20425A
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Gerhard Oskar Hentschel
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VALTER SVEN ERWIN HENTSCHEL
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VALTER SVEN ERWIN HENTSCHEL
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2065—Polyhydric alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/221—Mono, di- or trisaccharides or derivatives thereof

Definitions

  • the present invention relates to a washing dish-washing and cleaning detergent in the shape of powders, granules or pastes or liquids, the phosphates previously used in such a detergent being completely or partly replaced by chemicals which are more suitable from the eutrophic point of view.
  • the purpose of the phosphates in detergent compositions is to soften the water and to keep thehardening agents in the water in solution. Further, the phosphates have a certain dispersion effect on the dirt particles and improves the effects of the tensides in certain respects.
  • carboxylic acids which are not dangerous from toxicologic point of view may be used.
  • One condition is of course that they could be accepted from water care'point of view. They must also give a satisfactory washing result.
  • COOH-groups give the best results in surface Washing and at the same time many of these acids are toxicologically and allergologically undangerous and do not endanger water care. Several of these carboxylic acids occur in nature and form so to say a natural component of the plants and animals.
  • anionic, double-ionic or nonionic tensides which may be present in the detergents according to the inventhem water soluble, this group being of anionic or nonionie character.
  • anionic active detergent soaps sulphonates and glp hates are of importance.
  • phosphate tion phosphate tion
  • NTA increases the algae growth why this solution of the eutrophication problem still is unsolved. Further, one does not know anything about the reactions between trace elements in natural watercourses and NTA.
  • the present invention relates to detergent compositions which contain alkaline salts of aliphatic and aromatic car boxylic acids and/or their anhydrides having as a maximum eight carbon atoms in the hydrophobic part or having one or several carboxylic groups or the free acids in a mixture with the alkaline salts of inorganic acids, e.g. carbonates and silicates.
  • alkaline salts of aliphatic and aromatic car boxylic acids and/or their anhydrides having as a maximum eight carbon atoms in the hydrophobic part or having one or several carboxylic groups or the free acids in a mixture with the alkaline salts of inorganic acids, e.g. carbonates and silicates.
  • inorganic acids e.g. carbonates and silicates.
  • Said acids are used because they contain only tensides cou be used.
  • the sulphonates may comprise alkylaryl sulphonates, alkyl sulphonates, alkene sulphonates and oxyalkane sulphonates. Also sulphonated esters may be used.
  • the sulphates may comprise e.g. alkylene sulphate, fatty alcohol ether sulphate, sulphated amides of fatty acids, sulphated monoglycerides, sulphating products of ethoxylated and/or propoxylated fatty alcohols, alkyl phenols, fatty acid amines, etc.
  • Sulphonates of fatty acid esters of oxethane sulphonic acid and dioxypropane sulphonic acid, fatty alcoholic esters of lower aliphatic and aromatic thiomonoand dicarboxylic acids as well as condensation products of fatty acids with aminoethane sulphonic acids may be used.
  • Synthetic capillary active carboxylates and condensation products of fatty acids with aminocarboxylic acids or with protein hydrolysates as well as phosphate esters of fatty alcohols and fatty acids may be used.
  • nonionic tensides one may use e.g. alkylic phenol, fatty alcohol, alkyl amino, fatty acid, fatty acid alkylol amide fatty amide polyglycolethers, phosphate esters of ethoxylated fatty alcohols, block polymerisates of ethylene oxide and propylene oxide etc.
  • amphoteric tensides may be used such as imidazoline derivatives of fatty acids, carboxybetaines, compounds with the phosphoric acid groups in the acid test or with sulphonic or sulphuric acid groups.
  • Foam stabilizers or foam inhibitors as well as corrosion inhibitors may be included and so may dirt carrying sub- It has turned out in practice that acids with several enzymes, dyes and water. Also different types of bleaching agents containing oxygen or chlorine and activators and stabilizers belonging thereto.
  • a multivalent higher alcohol in an amount up to 25%, preferably 0.58% as calculated on the quantity of said salts.
  • the multivalent alcohols are selected from the group consisting of sorbitol, mannitol, pentaerythritol, trimethylol propane, trirnethanol ethane, hexanetriol and butane triol.
  • EXAMPLE 3 Detergent for ordinary washing, sprayed I Parts Na-dodecyl benzene sulphonate .Q 10 Fatty alcohol polyglycol ether 5 Xylene sulphonate 7 SEHITJ'I'WBW 2 Phosphate ester of ethoxylated fatty alcohol 2 Na-perborate 15 Na-citrate 30 Mannitol 5 Na-silicate 10 EDTA or NTA 3 Na-salt of benzene tetracarboxylic acid 2 CMC, opt. brightening agent, Mg-silicate 9 EXAMPLE 4 Small-washing detergent, gran.
  • EXAMPLE 7 Dish-washing machine detergent Parts Polypropylene-ethylene oxide-addition product 3 Sodium alkylic polyglycol etherphosphate 3 Na-acetate 25 Na-sulphate 25 Na-citrate 30 Perfumes, dyes, bactericides, water l4
  • EXAMPLE 8 Washing and cleansing paste Parts Fatty acid imidazoline derivate, 50% 10 Succinic acid-Z-ethyl hexylic monoester 3 Undecylene acid monoethanol amide 3
  • Fatty acid condensation product with methyl taurine l6 Glycol derivate 7 Na-citrate 11 1,4-butane dicarboxylic acid 2 CMC 3 Water 45 What I claim is: 1.
  • a detergent composition consisting essentially of: a water-soluble surface active agent have 8 to 30 6 carbon atoms in the hydrophobic group thereof, 3.
  • surface active agent is an anionic wetting agent.

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Emergency Medicine (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Molecular Biology (AREA)
  • Detergent Compositions (AREA)

Abstract

A DETERGENT CONTAINING ALKALINE SALTS OF ORGANIC, ALIPHATIC AND/OR AROMATIC CARBOXYLIC ACIDS AND/OR ANHYDRIDES OF THE SAME WITH ONE OR SEVERAL CARBOXYLIC GROUPS. THESE SALTS REPLACE IN THE DETERGENT PREVIOUSLY USED PHOSPHATES WHICH CAUSED A EUTROPHICATION AND ENDANGERED THE ECOLOGY.

Description

United States Patent 3,692,684 DETERGENT Gerhard Oskar Hentschel, Goteborg, Sweden, assignor to Valter Sven Erwin Hentschel, Goteborg, Sweden No Drawing. Filed Mar. 17, 1970, Ser. No. 20,425 Claims priority, application Switzerland, Oct. 1, 1969, 13,492/ 69 Int. Cl. Clld 3/20 US. Cl. 252-89 3 Claims ABSTRACT OF THE DISCLOSURE A detergent containing alkaline salts of organic, aliphatic and/or aromatic carboxylic acids and/or anhy, drides of the same with one or several carboxylic groups. These salts replace in the detergent previously used phosphates which caused a eutrophication and endangered the ecology.
BACKGROUND OF THE INVENTION The present invention relates to a washing dish-washing and cleaning detergent in the shape of powders, granules or pastes or liquids, the phosphates previously used in such a detergent being completely or partly replaced by chemicals which are more suitable from the eutrophic point of view.
The purpose of the phosphates in detergent compositions is to soften the water and to keep thehardening agents in the water in solution. Further, the phosphates have a certain dispersion effect on the dirt particles and improves the effects of the tensides in certain respects.
The phosphates form nutrient salts for the watercourses and when waste water is discharged into such watercourses, this results in overnutrition with an increased propagation of algae and a filling as a result (eutrophica- 3,692,684 Patented Sept. 19, 1972 DETAILED DESCRIPTION OF THE INVENTION The carboxylic acids which should preferably be used according to the invention are the following aliphatic acidsz. lactic acid, acetic acid, tartaric acid and citric acid, and the following aromatic acids: benzoic acid, phthalic acid and tri-, tetra-, pentaand hexa-carboxylic acids and their alkaline salts. However, the invention is not restricted to the acids enumerated in the aforegoing but also other.
carboxylic acids which are not dangerous from toxicologic point of view may be used. One condition is of course that they could be accepted from water care'point of view. They must also give a satisfactory washing result.
COOH-groups give the best results in surface Washing and at the same time many of these acids are toxicologically and allergologically undangerous and do not endanger water care. Several of these carboxylic acids occur in nature and form so to say a natural component of the plants and animals.
The anionic, double-ionic or nonionic tensides which may be present in the detergents according to the inventhem water soluble, this group being of anionic or nonionie character. As anionic active detergent soaps, sulphonates and glp hates are of importance. Also phosphate tion). For this reason it is important to keep the phosphate contents as low as possible or to replace the phosphates completely in detergent compositions. In the detergent industry one has tried to accomplish this by introducing nitrilotriacetates (NTA) and replacing large parts of the phosphates therewith. As the decomposition of NTA in recipients and purifying plants is not completely known and the watercourses thereby are fed with nitrogen and nitrogen compounds, also NTA increases the algae growth why this solution of the eutrophication problem still is unsolved. Further, one does not know anything about the reactions between trace elements in natural watercourses and NTA.
SUMMARY OF THE INVENTION The present invention relates to detergent compositions which contain alkaline salts of aliphatic and aromatic car boxylic acids and/or their anhydrides having as a maximum eight carbon atoms in the hydrophobic part or having one or several carboxylic groups or the free acids in a mixture with the alkaline salts of inorganic acids, e.g. carbonates and silicates. In order to improve the effect of said carboxylic acid salts it has turned out to be suitable to add multivalent higher alcohols up to an amount of 25%, preferably 0.58% as calculated on the quantity of said salts. Said acids are used because they contain only tensides cou be used. The sulphonates may comprise alkylaryl sulphonates, alkyl sulphonates, alkene sulphonates and oxyalkane sulphonates. Also sulphonated esters may be used. The sulphates may comprise e.g. alkylene sulphate, fatty alcohol ether sulphate, sulphated amides of fatty acids, sulphated monoglycerides, sulphating products of ethoxylated and/or propoxylated fatty alcohols, alkyl phenols, fatty acid amines, etc. Sulphonates of fatty acid esters of oxethane sulphonic acid and dioxypropane sulphonic acid, fatty alcoholic esters of lower aliphatic and aromatic thiomonoand dicarboxylic acids as well as condensation products of fatty acids with aminoethane sulphonic acids may be used. Synthetic capillary active carboxylates and condensation products of fatty acids with aminocarboxylic acids or with protein hydrolysates as well as phosphate esters of fatty alcohols and fatty acids may be used.
As nonionic tensides one may use e.g. alkylic phenol, fatty alcohol, alkyl amino, fatty acid, fatty acid alkylol amide fatty amide polyglycolethers, phosphate esters of ethoxylated fatty alcohols, block polymerisates of ethylene oxide and propylene oxide etc.
Also amphoteric tensides may be used such as imidazoline derivatives of fatty acids, carboxybetaines, compounds with the phosphoric acid groups in the acid test or with sulphonic or sulphuric acid groups.
Foam stabilizers or foam inhibitors as well as corrosion inhibitors may be included and so may dirt carrying sub- It has turned out in practice that acids with several enzymes, dyes and water. Also different types of bleaching agents containing oxygen or chlorine and activators and stabilizers belonging thereto.
In order to improve the effect of the carboxylic acid salts there is added a multivalent higher alcohol in an amount up to 25%, preferably 0.58% as calculated on the quantity of said salts. The multivalent alcohols are selected from the group consisting of sorbitol, mannitol, pentaerythritol, trimethylol propane, trirnethanol ethane, hexanetriol and butane triol.
As a conclusion it could be said that all tensides and aids used in connection with detergents and cleaning agents may be combined with the principle of the present invention and that the above enumeration .is. not to be considered as any restriction whatsoever.
The following examples are intended to illustrate the invention:
Sodium silicate, cryst. CMC, perfume, opt. brightening agent, enzymes,
and water l1 EXAMPLE 2 Large-scale detergent, granules Parts Fatty alcohol polyglycol ether having 30 mols EO (ethylene oxide) 12 Tallow fatty alcohol i 2 Cumol sulphonate ,3 Na-adipate 3 Na-K-tartrate 7 Na-acetate 10 Calcined soda 2O Na-bicarbonate .4 10 Na-percarbonate l5 Na-silicate '10 CMC, perfume, opt. brightening agent, Mg-silicate,
enzymes, and water Q. 8
EXAMPLE 3 Detergent for ordinary washing, sprayed I Parts Na-dodecyl benzene sulphonate .Q 10 Fatty alcohol polyglycol ether 5 Xylene sulphonate 7 SEHITJ'I'WBW 2 Phosphate ester of ethoxylated fatty alcohol 2 Na-perborate 15 Na-citrate 30 Mannitol 5 Na-silicate 10 EDTA or NTA 3 Na-salt of benzene tetracarboxylic acid 2 CMC, opt. brightening agent, Mg-silicate 9 EXAMPLE 4 Small-washing detergent, gran.
Parts Alkylbenzene sulphonate, 50% 12 Fatty alcohol polyglycol ether 6 Thiosuccinic acid semiester of fatty acid polyglycol ether, Na-salt Coconut fatty acid monoethanol amide or fatty acid amide polyglycol ether 2 Na-silicate 6 Mannitol 2.5 Na-citrate 21 Benzene hexacarboxylic acid 3.5 Gran. soda l0 Sesquicarbonate 14 Sodium sulphate calc. 13 CMC, opt. brightening agent, perfume, water 7 EXAMPLE 5 Pre-washing detergent, powder, gran.
Parts Alkylsulphate, Na-salt 4 Laurie acid monoethanol amide thiosuccinic semiester, Na-salt 2 Fatty acid polyglycol ester 4 Soda gran. 20 Sodium bicarbonate 2O Na-disilicate 15 Na-acetate 20 Potassium biphthalate 5 Pentaerythrite 4 CMS, opt. brightening agent, enzymes, water 6 EXAMPLE 6 Liquid washing and cleansing agent Parts Mixture of alkane and alkene sulphonates 7 Dialkyl phenolpolyglycol ether 3 Undecylene acid monoethanol amide thiosuccinic acid semiester, Na-salt 3 Fatty acid aminoxide 2 Pine-oil 3 Ethyldiglycol 3 Sodium lactate 10 Sorbitol 2 Water, perfume, dyes, ammonia etc. 67
EXAMPLE 7 Dish-washing machine detergent Parts Polypropylene-ethylene oxide-addition product 3 Sodium alkylic polyglycol etherphosphate 3 Na-acetate 25 Na-sulphate 25 Na-citrate 30 Perfumes, dyes, bactericides, water l4 EXAMPLE 8 Washing and cleansing paste Parts Fatty acid imidazoline derivate, 50% 10 Succinic acid-Z-ethyl hexylic monoester 3 Undecylene acid monoethanol amide 3 Fatty acid condensation product with methyl taurine l6 Glycol derivate 7 Na-citrate 11 1,4-butane dicarboxylic acid 2 CMC 3 Water 45 What I claim is: 1. A detergent composition consisting essentially of: a water-soluble surface active agent have 8 to 30 6 carbon atoms in the hydrophobic group thereof, 3. The detergent composition of claim 2 wherein said selected from the group consisting of an anionic wetsurface active agent is a sodium soap. ting agent, a nonionic wetting agent, an amphoteric wetting agent and mixtures thereof in an amount of References Cited from about 10 to about 32 parts per 100 parts of 5 UNITED STATES PATENTS composition; an alkaline salt of a carboxylic acid selected from the 2264103 11/1941 TPcker I 252' 89 2,740,727 4/1956 Littleton et al 252-8.6 group consisting of lactic acid, acetic acid, tartaric 2,838,455 6/1958 Tompkins 2528.6 acld, citric and, butane dicarboxylrc acid, adipic 2,311 008 2/1943 T k H 252 89 acid, benzoic acid, phthalic acid, benzene tricar- 10 3'308O67 3/1967 25289 boxylic acid, benzene tetracarboxylic, benzene pen- 3459670 8/1969 C 252-89 tacarboxylic, benzene hexacarboxylic acid and mix at er tures thereof, said alkaline salt being present in an amount of from about 10 to about 30 parts per 100 OTHER REFERENCES parts of i i 15 Chemmumque, vol. 10, No. 1, February 1962, Atlas a polyhydric alcohol selected from the group consisting Publ- PP- of sorbitol, mannitol, pentaerythritol, trimethylol propane, trimethylol ethane, hexanetriol and butane MAYER WEINBLATF Pnmary Exammer triol, said polyhydric alcohol being present in said W, E, SCHULZ, A i t t E i composition in an amount of 0.5% to 25% by 20 weight of the salt of said carboxylic acid thereof. US. Cl. X.R.
2. The detergent composition of claim 1 wherein said 21058; 252-8.6
surface active agent is an anionic wetting agent.
UNITED STATES PATENT OFFICE CERTIFICATE OF CORRECTION Patent No. 3,692 ,684 Dated September 19, 1972 Inventor(s) Gerhard Oskar Hentschel It is certified that error appears in the above-identified patent and that said Letters Patent are hereby corrected as shown below:
In Column 1, line 6, after the word "application" delete "Switzerland" and insert "Sweden" In Column 4, line 32 "CMS" should be CMC In Column 4, line 75, "have" should be having Signed and sealed this 6th day of February 1973.
(SEAL) Attest:
ROBERT GOTTSCHALK EDWARD M.PLETCHER,JR.
Commissioner of Patents Attesting Officer FORM po'wso H0459) USCOMM-DC 60376-P69 [1.5, GOVERNMENT PRINTING OFFICE: 959 0-365-334
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BE (1) BE750676A (en)
CH (1) CH540973A (en)
DE (1) DE2026739C3 (en)
FR (1) FR2065800A5 (en)
GB (1) GB1309814A (en)
LU (1) LU60901A1 (en)
NL (1) NL7007168A (en)
SE (1) SE352652B (en)
SU (1) SU479299A3 (en)
ZA (1) ZA706253B (en)

Cited By (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3844982A (en) * 1969-11-24 1974-10-29 Procter & Gamble Built detergent composition
US3852220A (en) * 1972-01-12 1974-12-03 Marathon Oil Co Isocyanurate-based polyelectrolyte detergent composition
US3859224A (en) * 1971-09-24 1975-01-07 Hoechst Ag Detergent composition containing, as a builder, the sodium salt of glycerol tricitrate
US3872020A (en) * 1971-09-14 1975-03-18 Dai Ichi Kogyo Seiyaku Co Ltd Detergent compositions
US3896040A (en) * 1971-01-04 1975-07-22 Andre Danesh Detergent composition
US3915879A (en) * 1973-04-10 1975-10-28 Lever Brothers Ltd Detergent compositions
US3920569A (en) * 1972-02-14 1975-11-18 Lever Brothers Ltd Detergent composition having substituted phthalic acid salt builder
US3951877A (en) * 1972-07-17 1976-04-20 Lion Fat & Oil Co., Ltd. Heavy-duty granular detergent composition with sodium citrate builder
US3953352A (en) * 1973-06-04 1976-04-27 Kao Soap Co., Ltd. Acidic cleaning composition
US3962149A (en) * 1973-10-12 1976-06-08 Colgate-Palmolive Company Non-phosphate spray dried detergents containing dicarboxylic acid salts
US3971728A (en) * 1972-03-07 1976-07-27 Ethyl Corporation Sequestering agent
US4009114A (en) * 1974-09-23 1977-02-22 Colgate-Palmolive Company Non-phosphate detergent composition
US4013579A (en) * 1973-06-06 1977-03-22 Kao Soap Co., Ltd. Acidic cleaning composition
US4040972A (en) * 1975-03-12 1977-08-09 Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler Ion-exchanging aluminum silicate with hydrophilic surfaces
US4088593A (en) * 1975-03-12 1978-05-09 Henkel Kommanditgesellschaft Auf Aktien (Henkel Kgaa) Ion-exchanging aluminum silicate with hydrophilic surfaces
US4102799A (en) * 1974-08-29 1978-07-25 Colgate-Palmolive Company Automatic dishwasher detergent with improved effects on overglaze
US4123375A (en) * 1975-11-22 1978-10-31 Henkel Kommanditgesellschaft Auf Aktien Dishwasher detergent with clear rinsing effect and method of machine washing dishes
US4210550A (en) * 1978-07-14 1980-07-01 Akzo N.V. Detergent composition containing an alkali carbonate
US4239552A (en) * 1978-08-03 1980-12-16 Basf Aktiengesellschaft Machine dishwashing, using polyhydric alcohols, carboxylic acids and or esters of these as rinsing agents
US4239641A (en) * 1978-08-03 1980-12-16 Basf Aktiengesellschaft Use of polyhydric alcohols, carboxylic acids, hydroxy-carboxylic acids and/or their esters with polyhydric alcohols as viscosity regulators
US4252663A (en) * 1971-01-15 1981-02-24 Ab Helios, Kemisk-Tekniska Fabriker Detergent compositions
US4395365A (en) * 1980-09-08 1983-07-26 Nissan Motor Co., Ltd. Metal cleaning composition containing a fatty acid succrose ester and other detergent components
US4594175A (en) * 1984-08-29 1986-06-10 Economics Laboratory, Inc. Mechanical dishwashing rinse composition having a low foaming sulfonic acid rinsing agent, a hydrotrope and a source of active halogen
US4612137A (en) * 1984-09-03 1986-09-16 Kao Corporation Anti-yellowing detergent composition containing citrate and isocitrate
US4613448A (en) * 1973-09-24 1986-09-23 The Colgate-Palmolive Co. Detergent compositions
US4902439A (en) * 1987-04-15 1990-02-20 Ciba-Geigy Corporation Detergent composition for washing off dyeings obtained with fibre-reactive dyes, process for the preparation thereof and use thereof
US4935158A (en) * 1986-10-30 1990-06-19 Aszman Harry W Solid detergent cleaning composition, reusable cleaning pad containing same and method of manufacture
US4983315A (en) * 1989-08-10 1991-01-08 The Procter & Gamble Company N,N'-(1-oxo-1,2-ethanediyl)-bis(aspartic acid), salts and use in detergent compositions
US5427707A (en) * 1985-06-14 1995-06-27 Colgate Palmolive Co. Thixotropic aqueous compositions containing adipic or azelaic acid stabilizer

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* Cited by examiner, † Cited by third party
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ZA72142B (en) * 1971-01-25 1973-09-26 Colgate Palmolive Co Heavy duty liquid detergent
CA966751A (en) * 1971-03-18 1975-04-29 Charles R. Ries Phosphorus-free detergent composition
BE787682A (en) * 1971-08-17 1973-02-19 Unilever Nv DETERGENT COMPOSITIONS
US4013577A (en) * 1972-04-14 1977-03-22 Colgate-Palmolive Company Heavy duty dry biodegradable detergent composition
GB1432137A (en) * 1972-06-13 1976-04-14 Chem Y Detergent compositions
DE2230453A1 (en) * 1972-06-22 1974-01-17 Benckiser Gmbh Joh A BASIC MATERIAL APPROACH FOR DETERGENTS AND DETERGENTS
IT1002614B (en) * 1973-01-15 1976-05-20 Colgate Palmolive Co ANIONIC DETERGENT WITHOUT PHOSPHATES
NL7407851A (en) * 1973-06-15 1974-12-17
US3971815A (en) * 1974-11-13 1976-07-27 The Procter & Gamble Company Acid mix process
CH639416A5 (en) * 1977-06-27 1983-11-15 Akzo Nv DETERGENT COMPOSITION CONTAINING ALKALICARBONATE.
IT1124027B (en) * 1979-03-23 1986-05-07 Mira Lanza Spa DETERGENT COMPOSITION WITH LOW OR NO PHOSPHORUS CONTENT
GB8522621D0 (en) * 1985-09-12 1985-10-16 Unilever Plc Detergent powder
GB2330588B (en) * 1997-10-24 1999-08-18 Cheng Wen Lin Multipurpose cleaning agent
DE19851662A1 (en) * 1998-11-10 2000-05-18 Menno Chemie Vertriebsges M B Means for removing the adhesiveness of helminth eggs
RU2530883C2 (en) * 2012-08-29 2014-10-20 Общество с ограниченной ответственностью Пермская производственная фирма "Фантом" Washing composition for purification of surfaces of various solid bodies

Cited By (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3844982A (en) * 1969-11-24 1974-10-29 Procter & Gamble Built detergent composition
US3896040A (en) * 1971-01-04 1975-07-22 Andre Danesh Detergent composition
US4252663A (en) * 1971-01-15 1981-02-24 Ab Helios, Kemisk-Tekniska Fabriker Detergent compositions
US3872020A (en) * 1971-09-14 1975-03-18 Dai Ichi Kogyo Seiyaku Co Ltd Detergent compositions
US3859224A (en) * 1971-09-24 1975-01-07 Hoechst Ag Detergent composition containing, as a builder, the sodium salt of glycerol tricitrate
US3852220A (en) * 1972-01-12 1974-12-03 Marathon Oil Co Isocyanurate-based polyelectrolyte detergent composition
US3920569A (en) * 1972-02-14 1975-11-18 Lever Brothers Ltd Detergent composition having substituted phthalic acid salt builder
US3971728A (en) * 1972-03-07 1976-07-27 Ethyl Corporation Sequestering agent
US3951877A (en) * 1972-07-17 1976-04-20 Lion Fat & Oil Co., Ltd. Heavy-duty granular detergent composition with sodium citrate builder
US3915879A (en) * 1973-04-10 1975-10-28 Lever Brothers Ltd Detergent compositions
US3953352A (en) * 1973-06-04 1976-04-27 Kao Soap Co., Ltd. Acidic cleaning composition
US4013579A (en) * 1973-06-06 1977-03-22 Kao Soap Co., Ltd. Acidic cleaning composition
US4613448A (en) * 1973-09-24 1986-09-23 The Colgate-Palmolive Co. Detergent compositions
US3962149A (en) * 1973-10-12 1976-06-08 Colgate-Palmolive Company Non-phosphate spray dried detergents containing dicarboxylic acid salts
US4102799A (en) * 1974-08-29 1978-07-25 Colgate-Palmolive Company Automatic dishwasher detergent with improved effects on overglaze
US4009114A (en) * 1974-09-23 1977-02-22 Colgate-Palmolive Company Non-phosphate detergent composition
US4088593A (en) * 1975-03-12 1978-05-09 Henkel Kommanditgesellschaft Auf Aktien (Henkel Kgaa) Ion-exchanging aluminum silicate with hydrophilic surfaces
US4040972A (en) * 1975-03-12 1977-08-09 Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler Ion-exchanging aluminum silicate with hydrophilic surfaces
US4123375A (en) * 1975-11-22 1978-10-31 Henkel Kommanditgesellschaft Auf Aktien Dishwasher detergent with clear rinsing effect and method of machine washing dishes
US4210550A (en) * 1978-07-14 1980-07-01 Akzo N.V. Detergent composition containing an alkali carbonate
US4239552A (en) * 1978-08-03 1980-12-16 Basf Aktiengesellschaft Machine dishwashing, using polyhydric alcohols, carboxylic acids and or esters of these as rinsing agents
US4239641A (en) * 1978-08-03 1980-12-16 Basf Aktiengesellschaft Use of polyhydric alcohols, carboxylic acids, hydroxy-carboxylic acids and/or their esters with polyhydric alcohols as viscosity regulators
US4395365A (en) * 1980-09-08 1983-07-26 Nissan Motor Co., Ltd. Metal cleaning composition containing a fatty acid succrose ester and other detergent components
US4594175A (en) * 1984-08-29 1986-06-10 Economics Laboratory, Inc. Mechanical dishwashing rinse composition having a low foaming sulfonic acid rinsing agent, a hydrotrope and a source of active halogen
US4612137A (en) * 1984-09-03 1986-09-16 Kao Corporation Anti-yellowing detergent composition containing citrate and isocitrate
US5427707A (en) * 1985-06-14 1995-06-27 Colgate Palmolive Co. Thixotropic aqueous compositions containing adipic or azelaic acid stabilizer
US4935158A (en) * 1986-10-30 1990-06-19 Aszman Harry W Solid detergent cleaning composition, reusable cleaning pad containing same and method of manufacture
US4902439A (en) * 1987-04-15 1990-02-20 Ciba-Geigy Corporation Detergent composition for washing off dyeings obtained with fibre-reactive dyes, process for the preparation thereof and use thereof
US4983315A (en) * 1989-08-10 1991-01-08 The Procter & Gamble Company N,N'-(1-oxo-1,2-ethanediyl)-bis(aspartic acid), salts and use in detergent compositions

Also Published As

Publication number Publication date
CH540973A (en) 1973-08-31
LU60901A1 (en) 1970-07-16
SU479299A3 (en) 1975-07-30
JPS507610B1 (en) 1975-03-27
FR2065800A5 (en) 1971-08-06
SE352652B (en) 1973-01-08
DE2026739B2 (en) 1978-04-27
DE2026739A1 (en) 1971-04-22
NL7007168A (en) 1971-04-05
BE750676A (en) 1970-11-03
DE2026739C3 (en) 1979-01-18
GB1309814A (en) 1973-03-14
ZA706253B (en) 1971-05-27

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