US3409493A - Process for twistless multifilament polyethylene terephthalate yarn - Google Patents

Process for twistless multifilament polyethylene terephthalate yarn Download PDF

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US3409493A
US3409493A US324091A US32409163A US3409493A US 3409493 A US3409493 A US 3409493A US 324091 A US324091 A US 324091A US 32409163 A US32409163 A US 32409163A US 3409493 A US3409493 A US 3409493A
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yarn
filaments
cohered
filament
count
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Mcintyre James Eric
Dempster Hendry Wilson
Kingston Derek
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Imperial Chemical Industries Ltd
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Imperial Chemical Industries Ltd
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/06—Processes in which the treating agent is dispersed in a gas, e.g. aerosols
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/40—Yarns in which fibres are united by adhesives; Impregnated yarns or threads
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02J—FINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
    • D02J1/00—Modifying the structure or properties resulting from a particular structure; Modifying, retaining, or restoring the physical form or cross-sectional shape, e.g. by use of dies or squeeze rollers
    • D02J1/22—Stretching or tensioning, shrinking or relaxing, e.g. by use of overfeed and underfeed apparatus, or preventing stretch
    • D02J1/221—Preliminary treatments
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02J—FINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
    • D02J1/00—Modifying the structure or properties resulting from a particular structure; Modifying, retaining, or restoring the physical form or cross-sectional shape, e.g. by use of dies or squeeze rollers
    • D02J1/22—Stretching or tensioning, shrinking or relaxing, e.g. by use of overfeed and underfeed apparatus, or preventing stretch
    • D02J1/229—Relaxing

Definitions

  • This invention relates to coherent multi-filament yarn made from hydrophobic synthetic thermoplastic polymers. During the processing of multi-filament yarns including various winding operations, and in use when making fabrics e.g. by weaving or knitting, it is desirable that the yarn should exhibit a certain amount of cohesion in order to prevent individual filaments becoming separated from the others and thereby causing snagging and breakage.
  • multi-filament yarns are usually provided with a degree of cohesion by twisting or sizing processes or by a combination of such processes. Twisting provides a physical restraint to separation of single filaments, whereas sizing provides a polymeric binding agent or adhesive to hold the filaments together. Such processes tend to be slow and expensive. Moreover sizing processes as at present known are less satisfactory for hydrophobic yarns, such as polyester yarns and yarns from polymerised olefines, than for more hydrophilic yarns such as those derived from the natural fibres, regenerated cellulose fibres, and wholly synthetic fibres, such as the commercially available polyamides, which are relatively hydrophilic due to the presence of hydrogen bonding units in the chemical structure.
  • Another method of providing a degree of cohesion which has been suggested consists in passing the filaments through a tube in a high velocity air stream whereby an electrostatic charge is generated and physical cohesion is obtained by intermingling or interlacing of the single filaments.
  • Yet another method which has been suggested 'for obtaining cohesion for yarns of thermoplastic synthetic linear polymers consists in wetting the multifilaments with water and. then heating them above 100 C. while applying external mechanical force.
  • the multi-filament yarn should exhibit a very high degree of cohesion, sometimes even to the extent that complete inter-filament cohesion is required.
  • the degree of cohesion should be such as to prevent separation of individual filaments during processing but later, that a physical or chemical treatment of the final product, such as rapid flexing or scouring, should reduce the degree of cohesion or even disjoin the individual filaments.
  • the colored multifilament yarns becomes stiffer than the untreated uncohered yarn.
  • thermoplastic substantially twistless multifilament yarn made from -a hydrophobic synthetic thermoplastic polymer possessing in the form of oriented fibres a water absorbency of less than 1% at 70 F. and 65% relative humidity, wherein each filament adheres to adjacent filaments by 3,409,493 Patented Nov.
  • the degree of cohesion at any point along the length of the yarn is substantially the same, although the individual filaments cohered may not be the same.
  • We also provide a process for the production of a coherent multi-filament yarn from a hydrophobic synthetic thermoplastic polymer comprising wetting the surface of the filaments of a multi-filament yarn with a liquid which contains a compound which is a solvent for the oriented filaments at an elevated'temperature, then passing the filaments under a controlled tension through a heating zone at a temperature and for a time such that the individual filaments cohere to one another and the solvent is evaporated from the surface of the yarn until the polymer forms a continuous phase from at least one filament through any cohered portion to -another adjoining filament.
  • the solvent should be applied when the yarn is under controlled tension which is maintained whilst the solvent is evaporated preferably by heating ⁇ and before windup.
  • the process is remarkably versatile and widely differing degrees of cohesion such as may be required for different end-uses can be obtained by altering the temperature, or the amount of concentration of the solvent applied, or the solvent used.
  • the temperature to which it is necessary to heat the wetted multifilament yarn in order to obtain cohesion depends on the degree of orientation or crystallinity of the yarn; thus a poly (ethylene terephthalate) yarn drawn over a snu-bbing pin at about C. has a lower degree of orientation and crystallinity than a yarn which has 'been Idrawn over the snubbing pin ⁇ and then over a hot plate at C.
  • the latter yarn usually requires to be heated at a temperature about 10 C. higher than the former to provide a similar degree of cohesion, under otherwise identical conditions and using the same solvent.
  • the cohered yfilament count as used in this specification is determined by cutting the cohered yarns whereby the coherence between the filaments is destroyed to an extent depending on the degree of coherence of the filaments in the yarn, that is to say a yarn of a low degree of cohesion and therefore a high filament count is more easily broken into single filaments, whereas bundles of filaments remain, on cutting a yarn having a high degree of cohesion.
  • a suit-able instrument is commercially available in the Manra yarn filament counter developed by the British Rayon Research Association and made by Newmark Instruments Ltd. Its method and apparatus is designed for counting the number of filaments in a multifilament yarn. The instrument is described in B.P.
  • the number of filaments indicated by the Maura counter although not necessarily exactly the same as the number of filaments or groups of filaments indicated by other methods of measurements, provides a measure of the degree of cohesion in the original sample of multifilament yarn.
  • the number of filaments indicated by the Manra counter we-have termed the cohered filament count or filament count. It will be appreciated that a low filament count signifies a high degree of cohesion, and vice versa. It will be appreciated that a number of measurements are required to -give a statistically significant cohered filament count from a given length of yarn.
  • the Manta yarn filament counter uses a razor type cutter which cuts through a pretensioned lament yarn which is clamped between two clamps with the razor cutting between the clamps. Before cutting proceeds the clistance between the clamps is gradually automatically increased by the movement of the clamps.
  • the cutter of the instrument works through a dashpot mechanism allowing the cutter to bear steadily down on the yarn which is held under tension transverse to the cutter and the yarn is in Contact with a sensing arm of a crystal transducer. As the yarn is cut the individual filaments or cohered filaments together separate from the rest of the yarn and there is a change in the force exerted on the sensing arm which produces a pulse which operates an electronic counter.
  • the arrangement is such that the yarn is held under approximately the same tension for each test by having the yarn initially just taut in the yarn clamps and then moving the clamps apart by a finite amount. This operation and the bearing down of the cutter is done automatically when the switch operating the instrument is thrown.
  • a multifilament yarn having 24 filaments but which has not been treated according to our invention produces 23 or 24 pulses and the instrument registers a count of 23 or 24.
  • the instrument registers a count of 23 or 24.
  • the cohered filament count should be in the region of 5-60% off the number of filaments in the untreated yarn.
  • a yarn containing 24 filaments should give a cohered filament count of from 2 to 14.
  • a yarn containing l2 filaments should Agive a count of from 2 ot 7.
  • a yar-n containing 36 filaments should give a count of from 2 to 21.
  • a yarn containing 72 filaments would require a count of from 4 to 42.
  • a cohered filamentl count of l0- preferably l0-70% of the number of filaments in the untreated yarn is particularly useful. If the cohered filament count is above 80%, for example, in; a 24 filal ment yarn if the filament count is above 20, the weaving performance is affected unless the yarn is also sized.
  • the cohered yarns are delustred. This is caused by the solvents used for the cohering process and this can have definite advantages, for example when it is not possible or expedient to produce a sufficiently delustred yarn for use in a particular fabric construction.
  • a variety of lnovel and desirable fabric effects can beob'tained by a suitable combination of the cohered yarns with other yarns vor with yarns having -a different degree of coherence and therefore a different appearance in fabric form; thus a lawn-like structure can be obtained by using a combination of cohered warp and fiat weft yarn or by using a warp with a higher degree of cohesion than in the weft.
  • a fabric can be woven with a combination of 2 or more yarns of different degrees of cohesion which can be treated in such a way so that the yarns having a low degree of cohesion can be broken down into individual filaments.
  • the techniques suitable ffor separatingy the filaments in a cohered yarn include scouring, pressing, calendering, treatment with swelling agents or treatment in strongly alkaline solutions for example in sodium hydroxide.
  • Cohesion of the filaments is preferably carried out by the synthetic filament yarn manufacturer and may be carried out before, during or after drawing. Since it is necessary to provide heat to cohere the yarn and to remove surplus solvent by evaporation we provide a process in which this heating is integrated with an existing heating process necessary during the manufacture of the yarn thus:
  • the solvent may be applied to an undrawn yarn immediately before drawing. The yarn is then drawn using heat and the yarn is cohered during heat setting.
  • the solvent may be applied to drawn yarn which has not been heat set and the yarn is subsequently cohered during the heat setting stage as in (l) above.
  • the solvent may be applied to drawn, heat set yarn and the required degree of cohesion may be obtained in a separate heating step, and before windup, which is preferred.
  • Suitable means for heating include hot air or vapour, contact withI a hot plate or a heated roller, or radiant heating including infra-red and high frequency heating.
  • the multifilament yarn should be maintained under controlled tension during the heating stage. It is however an advantage of the process that the properties of the cohered yarn may be modified according to the amount of tension applied. If the tension is controlled at a relatively low level slight shrinkage occurs whereas if the tension is ⁇ controlled at a relatively high level slight stretching occurs; in the latter case a substantial increase in tenacity can be obtained.
  • An important feature of the process of this invention is that little or no distortion of the shape of individual filaments or of the multifilament yarn need occur during the process; i.e. the force applied to hold the individual filaments together is insuicient to cause distortion. However it-is possible, if desired, to apply additional forces during the heating-process in order to distort the shape of the resulting cohered multifilament or of the individual yarns and thus to obtain, for example, ribbon-like structures.
  • Suitable solvents may have a boiling point either below or above the temperature of treatment.
  • the former are readily removed from the yarn by evaporation, and it isr frequently desirable to use them in undiluted form.
  • Solvents, particularly those which have a boiling point above thetemperature of treatment may be retained in the yarn to a small extent even though completely evaporated from the surface, and this may result in slight plasticisation of the yarn and particularly of the bonds between filaments. This can result in gradual changes in the strength of the bonds during the passage of time, such that it becomes easier to separate individual filaments from each other, and can be an advantage where it is desirable to separate the ⁇ filaments in the finished product, in other words when a temporary bonding is required.
  • polyester filaments derived from terephthalic acid such as poly (ethylene terephthalate)
  • suitable solvents include tetrachloroethane, chloral, 'y-butyrolactone, anisaldehyde, m-cresol, benzophenone and Z-phenoxyethanol, benzyl alcohol, acetophenone, salicylaldehyde, methyl cyclohexanone, acetophenone and a mixture of nitrowith chlorobenzene.
  • suitable solvents include xylenes and a number of other known solvents fo ⁇ r polypropylene. ⁇ It will be appreciated that the temperature required to cause inter-filament cohesion depends on the polymer ,from which the filaments are made and on the solvent used to produce cohesion.
  • the multifilament yarn may be brought into a particular configuration before, during or after the application of the liquid containing the solvent. This may be done, for example,by passing the filaments through a tube in a high velocity air stream and thereby generating an electric charge and causing inter-mingling and interlacing ofthe filaments, or by applying twist or false twist to the multifilament yarn or by using a crimped yarn e.g. twist crimped yarn.
  • the bond between any two filaments consists solely of the polymer of which the filaments are composed in a crystalline or partly crystalline form. This crystallinity may be detected by examining the material of which the bond is composed by X-rays, when it is found to give an X-ray pattern typical of the polymer in a crystalline form.
  • the material of which the bon-d is composed is not, in general, as highly oriented as the material within the filaments, but may exhibit some degree ,of orientation. Chemically the material of which the bond is composed is the same as the polymer from which the filaments have been made and the material forms therefore a chemically continuous phase.
  • FIGURE l is a diagrammatic view of a longitudinal section of a cohered multifilament yarn on a greatly enlarged scale.
  • FIGURE 2 is a view of a yarn as in FIGURE 1 when some of the bonds between the filaments have been partly broken down.
  • FIGURE 3 is a diagrammatic view of a yarn being cut on a filament yarn counter.
  • FIGURE 4 is an enlarged view of the cutter of FIG- URE 3.
  • FIGURE 5 is a diagrammatic view of the apparatus for drawing and applying solvent to the yarn.
  • FIGURE 1 a number of cohered filaments 1, 1a, 1b, 1c, 1d, 1e, 1f are shown in longitudinal section and it will be noticed that there is a gap of an uncohered portion 2 between filaments 1c and 1d.
  • an after treatment such as calendering in fabric form or treatment with caustic sodium hydroxide
  • partial separation of the cohered filaments occurs to form gaps 3, 4, 5, 6 and 7 between the filaments, as' shown in FIGURE 2.
  • FIGURE 3 shows diagrammatically the testing of a cohered yarn 8 as it is being cut by a cutter 9 whilst being clamped between clamps 10 and 11 which are moved farther apart before cutting to provide tension so that the uncohered filaments separate on cutting into individual fibre ends shown at 12.
  • a sensing arm 13 of a crystal transducer is in contact with the pretensioned yarn as it is being cut and pulses which are produced by cutting the yarn operate an electronic counter (not shown).
  • FIGURE 4 is an enlarged view of the cutter 9 shown in FIGURE 3 and shows separation of small bundles of filaments 14 and 15 as the yarn is being cut.
  • FIGURE 5 shows an undrawn yarn at 8a being drawn between feed roll 16 with associated idler roll 17 and draw roll 18 with associated idler roll 19. After looping the yarn four turns on the feed and draw roll it is passed over a spaced idler roll 20 back to the draw roll 18 with asso- 7 ciated idler roll 19. Between the idler roll 20 and the draw roll is a driven solvent applicator roll 21 rotating in a trough of solvent 22. The yarn bearing the solvent, after making another set of four turns over the draw roll, where cohension and drying occur, is passed through a cooling zone before being wound up. c
  • The. following examples illustrate but do not limit our lnvention.
  • EXAMPLE 1 A 52 denier 24 filament delustred poly(ethylene terephthalate) multifilament yarn of tenacity 5.1 g.p.d. and extensibility 35% was passed through a bath of tetra- Chloroethane then round a feed roll, over a hot plate and round a draw roll at 100 ft./ min. and was finally wound up n a bobbin. The yarn obtained at different hot-plate temperatures were tested by extension to break on an Instron testing machine. Yarns treated at 160-200 C. were completely cohered, so that they broke as a single unit (giving a cohered filament count of 3-4); yarns treated at 14S-150 C.
  • EXAMPLE 2 A poly(ethylene terephthalate) multifilament yarn of denier 125.7, containing 24 filaments, was treated as in Example 1 with the hot plate at 180 C.
  • the yarn was allowed to run under only slight tension shrinkage occurred and the final denier was 129.7; there was a decrease in tenacity from 6.7 g.p.d. to 6.4 g.p.d., and an increase in extensibility from 15% to 23%.
  • On the Instron tester a single break was recorded. The yarns when tested with the Maura counter gave a cohered filament count of 2-5.
  • EXAMPLE 3 A number of solvents were tested with yarns of Example l and Example 2 at a plate temperature of 180 C. Cohesion to a filament count of 3-15 -was obtained with 'y-butyrolactone, methyl cyclohexanone, acetophenone, salicylaldehyde, benzyl alcohol, methyl salicylate, nitrobenzene, ⁇ a 1:1 mixture by volume of nitrobenzene and chlorobenzene, and an aqueous emulsion of tetrachloroethane, but not with chlorobenzene, anisole, dimethyl formamide, ethylene glycol, ethylene diacetate, dimethyl maleate, bromobenzene, or o-dichlorobenzene. Cohension was obtained with o-dichlorobenzene, however, when the plate temperature was raised to 205 C. or above.
  • EXAMPLE 4 A 50 denier tow composed of 24 drawn and oriented filaments of polyethylene terephthalate was wetted with 25% of its weight of benzyl alcohol and passed over a 12 hot plate maintained at 270-275 C. at a yarn speed of 1500 ft./min. and under a tension of 20 g. The yarn was then wound onto a package. A full arc of contact was maintained on the hot plate. The resulting cohered yarn had a filament count of 15.
  • EXAMPLE 6 Benzyl alcohol, 35% by weight of fibre, was applied to a 50 denier tow consisting of 24 filaments of drawn and oriented polyethylene terephthalate. The wet tow was passed down a tube 17 long and approximately 11/2" diameter, through which hot air at a temperature rof 330- 350 C. was circulated at a rate of 1 to 2 litres/min. The wind-up speed was maintained at 500 ft./min. to give a cohered yarn having a filament count of 3.
  • EXAMPLE 7 A denier tow comprised of 24 undrawn and oriented filaments of polyethylene terephthalate was drawn on a system comprising two heated rolls 0f the same diameter of 41/2"; the feed roll, maintained at 90 C. and rotating at approximately 1/s of the speed of the second, the draw roll, which was maintained at C. Each roll had an associated separator roll so that the yarn could make more than one complete turn round the heated rolls, and in this case four turns were taken round each roll.
  • the drawn yarn, after leaving the hot draw roll, now of about 50 denier was taken round a further separator roll situated some 2 ft. from the draw roll and 25%, by weight of the fibre, of benzyl alcohol was applied to the yarn. The wet yarn was then fed back to the draw roll and four complete turns were taken round the roll.
  • the cohered yarn was wound onto a package at 1,000 ft./min.
  • the filament count was 8.
  • EXAMPLE 8 A tow comprised of 48 undrawn and oriented filaments of polyethylene terephthalate of total denier 1090 was drawn between two rolls of the same diameter but revolving at different speeds such that a draw ratio of 4.38 was applied. In addition the rolls were heated, the slower roll to a surface temperature of 90 C. and the faster draw roll to a temperature of 140 C. 'Ille drawn yarn was taken from the draw roll over a free running separator roll after which 35%, by weight of fibre, of benzyl alcohol was applied and the yarn was passed through a lagged metal tube 16" long and 1A" internal diameter, into the centre of which steam at 450 C. was passed. The yarn was wound on to a package at 400 ft./min. The yarn had a cohered filament count of 14.
  • EXAMPLE 9 A tow consisting of 24 undrawn filaments of poly(ethyl ene terephthalate) of total denier 545 was treated as in Example 7, except that the draw ratio was 4.38, the faster draw roll was operated at a temperature of 215 C., a 50% emulsion of benzyl alcohol in water was applied to give 7% of benzyl alcohol on the drawn yarn, and the wetted yarn was taken eight times round the draw roll before cooling and winding up at 700 feet per minute. The filament count was 4.
  • EXAMPLE 10 A tow consisting of 24 undrawn filaments of poly(ethyl ene terephthalate) of total denier 161 was treated as in Example 9, except that the faster draw roll was operated at a temperature of C., and the amount of benzyl alcohol applied to the fibre was 4% (equal to 8% of a 50% emulsion in water). The filament count was 6.
  • EXAMPLE 11 A tow consisting of 24 undrawn filaments of poly(ethyl ene terephthalate) of total denier 545 was treated as in Example 9, except that only 2% of benzyl alcohol was applied (4% of a 50% emulsion). The filament count was 15.
  • EXAMPLE 12 To illustrate the iniluence of temperature Example 4 is repeated except that: the temperature of the hot plate is maintained at 278-285 C., the yarn has a cohered iilament count of 8-12.
  • Example 4 is respected except that the temperature of the hot plate is maintained at 287-295 C. A yarn of cohered lament count 4-6 is obtained.
  • EXAMPLE 14 To illustrate the influence of yarn speed Example 4 is repeated except that the yarn speed is decreased to 1200 ft./ min. A yarn of cohered filament count 7-9 is obtained.
  • EXAMPLE 15 To illustrate the influence of solvent pickup Example 4 is repeated except that the solvent level is increased to 30%: A yarn of iilament count 10-12 is obtained: For comparison if the solvent level is decreased to 15% a yarn of filament count is obtained.
  • Example 4 To illustrate the influence of tow denier, Example 4 is repeated except that the tow denier is increased to 125.
  • the yarn in this comparative example is uncohered and has a filament count of 24, and a yarn of 75 denier gives a filament count of approximately 20.
  • EXAMPLE 17 10 cone fluid.
  • Polydimethyl siloxane is the preferred silicone fluid having a viscosity at 25 C. of 5,000 centistokes.
  • a process for the production of a coherent multifilament yarn having an average cohered yarn count of 5-80% of the total number of filaments from a polyethylene terephthalate having a water absorbency of less than 1% at 70 F. and 65% relative humidity comprising wetting the surfaces of the individual filaments of a yarn containing 5 to 2,000 lilaments with 1-80% by weight of the filaments of a liquid, passing the filaments under tension through a heating zone where it is heated by heat transfer from a solid metal surface, a gas or a vapor maintained for a time in said zone and at an elevated temperature of 14C-600 C. in which the product of the temperature, in degrees centigrade, of the heating zone, and the time in seconds, spent in the heating zone, is in the range 0.5-200,
  • said liquid containing a compound which is a solvent for the oriented laments at said elevated temperature
  • a process according to claim 1 including the step of coating the cohered yarn with a silicone fluid having a viscosity at 25 C. between 1,000 and 10,000 centistokes.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Chemical Treatment Of Fibers During Manufacturing Processes (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Artificial Filaments (AREA)
US324091A 1962-11-16 1963-11-15 Process for twistless multifilament polyethylene terephthalate yarn Expired - Lifetime US3409493A (en)

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US377166A US3409496A (en) 1963-11-15 1964-06-01 Twistless multifilament yarn of polyethylene terephthalate

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GB43399/62A GB1022639A (en) 1962-11-16 1962-11-16 Yarns made from thermoplastic polymers

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US3925134A (en) * 1971-09-30 1975-12-09 Celanese Corp Process for preparing supported ribbons
US4508674A (en) * 1981-03-31 1985-04-02 Asahi Kasei Kogyo Kabushiki Kaisha Process for the production of a polyester fiber dyeable under normal pressure
US4545835A (en) * 1983-06-15 1985-10-08 Badische Corporation Method of forming supported antistatic yarn
US5203939A (en) * 1991-08-05 1993-04-20 Coats Viyella, Plc Process for production of internally bonded sewing threads

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US2323684A (en) * 1942-02-07 1943-07-06 Owens Corning Fiberglass Corp Coated glass fiber strand
US2440226A (en) * 1943-08-19 1948-04-20 Du Pont Method and apparatus for producing and stretching artificial yarn
US2733178A (en) * 1956-01-31 stevenson
US3094374A (en) * 1961-07-11 1963-06-18 Du Pont Dry spinning process for preparing coalesced spandex filaments
US3095343A (en) * 1960-09-15 1963-06-25 United States Filter Corp Method for treating continuous filamentary tows
US3106501A (en) * 1958-09-22 1963-10-08 Eastman Kodak Co Process for manufacturing filters
US3151011A (en) * 1960-12-05 1964-09-29 Celanese Corp Process for making ribbons
US3161706A (en) * 1961-09-28 1964-12-15 Polythane Corp Method and apparatus for wet spinning elastomeric polymers into a fused multifilament fiber
US3164947A (en) * 1963-02-28 1965-01-12 Wall Rope Works Inc Cordage and methods of manufacture thereof
US3190294A (en) * 1958-09-30 1965-06-22 Celanese Corp Cigarette filters

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Publication number Priority date Publication date Assignee Title
US2733178A (en) * 1956-01-31 stevenson
US2063897A (en) * 1929-07-17 1936-12-15 Celanese Corp Production of artificial filaments or threads
US2323684A (en) * 1942-02-07 1943-07-06 Owens Corning Fiberglass Corp Coated glass fiber strand
US2440226A (en) * 1943-08-19 1948-04-20 Du Pont Method and apparatus for producing and stretching artificial yarn
US3106501A (en) * 1958-09-22 1963-10-08 Eastman Kodak Co Process for manufacturing filters
US3190294A (en) * 1958-09-30 1965-06-22 Celanese Corp Cigarette filters
US3095343A (en) * 1960-09-15 1963-06-25 United States Filter Corp Method for treating continuous filamentary tows
US3151011A (en) * 1960-12-05 1964-09-29 Celanese Corp Process for making ribbons
US3094374A (en) * 1961-07-11 1963-06-18 Du Pont Dry spinning process for preparing coalesced spandex filaments
US3161706A (en) * 1961-09-28 1964-12-15 Polythane Corp Method and apparatus for wet spinning elastomeric polymers into a fused multifilament fiber
US3164947A (en) * 1963-02-28 1965-01-12 Wall Rope Works Inc Cordage and methods of manufacture thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3925134A (en) * 1971-09-30 1975-12-09 Celanese Corp Process for preparing supported ribbons
US4508674A (en) * 1981-03-31 1985-04-02 Asahi Kasei Kogyo Kabushiki Kaisha Process for the production of a polyester fiber dyeable under normal pressure
US4545835A (en) * 1983-06-15 1985-10-08 Badische Corporation Method of forming supported antistatic yarn
US5203939A (en) * 1991-08-05 1993-04-20 Coats Viyella, Plc Process for production of internally bonded sewing threads

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NL300565A (xx)
DE1444083C3 (de) 1973-09-20
CH492036A (de) 1970-06-15
BE639967A (xx)
DE1444083A1 (de) 1968-10-10
GB1022639A (en) 1966-03-16
DE1444083B2 (de) 1973-02-08

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