US3396778A - Apparatus for cast cladding - Google Patents

Apparatus for cast cladding Download PDF

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US3396778A
US3396778A US393470A US39347064A US3396778A US 3396778 A US3396778 A US 3396778A US 393470 A US393470 A US 393470A US 39347064 A US39347064 A US 39347064A US 3396778 A US3396778 A US 3396778A
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mold
slab
backing plate
metal
molten metal
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US393470A
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Niels H Jensen
Robert A Westman
Edgar L Fogleman
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Lukens Steel Co
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Lukens Steel Co
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C6/00Coating by casting molten material on the substrate

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  • This invention relates to an apparatus for casting clad on a backing plate which is vertically disposed. More particularly, it relates to such process and apparatus wherein the backing plate together with a frame surrounding at least three sides of the backing plate is moved relative to a continuous casting mold in front of and spaced from the backing plate whereby molten metal entering the mold is continuously cast as clad on the backing plate.
  • cladding is a method or process in which a dissimilar metal or alloy layer is metallurgically bonded to base material in order to produce a metallic surface with special properties not obtainable with the base metal alone, as, for example, corrosion resistance.
  • a dissimilar metal or alloy layer is metallurgically bonded to base material in order to produce a metallic surface with special properties not obtainable with the base metal alone, as, for example, corrosion resistance.
  • the cladding is accomplished on a slab or backing plate which is subsequently to be rolled, it is a usual method to prepare what is known in the art as a sandwich or pack wherein the backing plate and the cladding material are held within a hermetically sealed steel envelope which is heated and rolled to effect a metallurgical bond.
  • Another method is to place a backing plate within a mold and to apply the clad in the form of molten metal directly on the face of the backing plate. When the clad metal is solidified the laminated metal slab may then be rolled.
  • cladding techniques require that the clad be metallurgically bonded to the backing metal in such a way as to avoid undesirable alloying at the interfaces of the clad and the backing metal. It is also frequently important that the clad metal has substantially uniform chemical and physical properties throughout. The casting of the clad should be carried out at a reasonable rapid rate for the most economical use of the equipment.
  • the cladding metal may be subjected to degassing or treatment under vacuum conditions just prior to its application to the backing plate.
  • the thickness of the clad may be regulated within relatively close tolerances.
  • the backing plate may be cleaned under vacuum or inert gas conditions to free it from contaminants such as scale, rust or other oxides, oils, grease, or other foreign material which might form on the face of the clad. Heating means for preheating the backing plate can be used within the tank.
  • the system permits considerable versatility in means which may be emplowed to prevent the molten metal from sticking to the moving mold.
  • a pulse vibrator in the latter may be employed to keep the relative movement between the mold and the metal which has just been poured so that they are never travelling at the same speed and thus prevent sticking of the mold to the molten metal.
  • a sonic vibrator may be incorporated in the mold both to prevent the mold from sticking to the molten metal and to contribute to a fine crystalline structure in the clad metal.
  • such vacuum may be controlled as means to introduce metal into the system and also to assist in the discharge of treating materials, cooling substances, and the like.
  • FIGURE 1 is a vertical sectional view of an apparatus embodying the invention
  • FIGURE 2 is a perspective view showing a plurality of apparatus such as shown in FIGURE 1 arranged with a melting furnace and a gantry crane;
  • FIGURE 3 is a horizontal section of the backing plate and frame as received in the apparatus illustrated in FIG- URE 1;
  • FIGURE 4 is a vertical section illustrating the process of continuous casting of the clad
  • FIGURE 5 is similar to FIGURE 4 except that it shows how the process or apparatus of the invention may be utilized to cast a slab
  • FIGURE 6 is a perspective view of a further embodiment of a pressure vessel in accordance with the invention.
  • FIGURE 7 is a side view of the pressure vessel shown in FIGURE 6, partially broken away to expose the apparatus within the vessel;
  • FIGURE 8 is a front view of the pressure vessel shown in FIGURE 6, also partially broken away;
  • FIGURE 9 is a horizontal sectional view of the pressure vessel illustrated in FIGURE 6;
  • FIGURE 10 shows a vibrating motor such as is used on the pressure vessel illustrated in FIGURE 6;
  • FIGURE 11 is a vertical sectional view of the mold showing the cooling jacket and the vibrating cam mem ber;
  • FIGURE 12 is a front elevational view of the mold shown in FIGURE 11;
  • FIGURE 13 shows a further modification wherein the pressure vessel is connected directly to the melting furnace
  • FIGURE 14 is a perspective view showing a frame member as used in the invention carrying a backing plate
  • FIGURE is a sectional view taken on lines 15-15 of FIGURE 14;
  • FIGURE 16 is similar to FIGURE 15 except that it shows a modification wherein the surface of the backing plate to be clad is scored;
  • FIGURE 17 is a perspective view of a frame similar to FIGURE 14 except that it has a plurality of spaces for the receipt of the molten metal in the casting process in accordance with the invention.
  • FIGURE 18 is a vertical sectional view of an apparatus similar to that shown in FIGURE 1 including means for preheating the slab or backing plate.
  • a pressure vessel comprising a cylindrical tank 20 has an exhaust outlet 21 which leads to a vacuum source such as vacuum pumps (not shown).
  • a loading door 22 Disposed on top of the tank 20 is a loading door 22 which is positioned directly over a hydraulic support means 24.
  • the latter includes a plunger 25 which is received in a hydraulic cylinder 26 by a piston member 27.
  • a bushing 30 around the plunger 25 guides the plunger and assists in maintaining same in a vertical position. It will be appreciated that by the introduction of a hydraulic fluid and varying the pressure in the hydraulic cylinder 26 under the piston member 27, the plunger 25 may be reciprocated.
  • the hydraulic support means 24 provides support for a frame member designated generally 31.
  • the frame member 31 contains a backing plate or slab 32 which has vertical graphite frame parts 34, one on each vertical side edge thereof. There are further graphite frame parts 33 and on the upper and lower edges, respectively, of the backing plate 32, whereby such backing plate is surrounded on its lower and vertical sides :by the graphite frame parts 35 and 34. It will be understood that the leading edges of the graphite frame parts 34 and 35 are coplanar.
  • the frame member 31 together with backing plate 32 are carried by a guide jig 36 which incorporates on its sides guide rails 37.
  • the rails 37 are received between t-wo lines of guide rollers 40* carried by the tank 20.
  • the frame member 31 may be reciprocated by the hydraulic support means 24 along a vertical coplanar path.
  • Molten metal 41 contained in a ladle 42 enters the tank 20 through a aluminum disc inlet 44.
  • a copper airlock 45 seals the burned down aluminum disc inlet 44.
  • the molten metal 41 drops through a degassing area 46 into a tundish 47.
  • the metal pours out of the tundish through the production outlets 50 and is received in a channel means or runner 51 which is carried immediately by a spring-loaded copper mold 52 having a graphite face 54.
  • the mold 52 together with the runner 51 are supported by a framework 55 which is firmly attached to the tank 20.
  • the mold 52 is spring-loaded by means of a compression spring 56 which urges the mold 52 away from the framework 55'.
  • a spill ladle 57 is disposed under the excess outlets 60 of the tundish 47.
  • the tundish 47 is carried by a pivot means 61 which may be manually controlled outside of the tank 20 by any suitable means known to the art.
  • pivot means 61 can be tilted in vertical plane in order to compensate for unequal molten metal from one side or the other of runner 51 by any number of means which would occur to one skilled in the art. Accordingly, when desired, molten metal in the tundish 47 may be spilled into the spill ladle 57.
  • a door 62 in the tank 20 is disposed adjacent to the spill ladle 57 whereby when such door is opened, the spill ladle 57 may be rolled out from the tank 20 on tracks 64.
  • An induction heater 65 is provided to compensate for bending and warping due to the heat of the molten metal on one side of the backing plate 32.
  • a frame member 31 containing a preheated backing plate 32 is carried from an assembly area 66 by an overhead crane 67 and deposited through an open loading door 22 onto the hydraulic support means 24 within a tank 20.
  • the loading door 22 is then secured and a vacuum is pulled within the tank through the exhaust outlet 21.
  • the crane 67 deposits a ladle 42 with molten metal 41, recently poured therein from a melting furnace 70, onto supports 71 carried on a platform 72 above the tanks 20 except for the protruding loading doors 22 and inlets with discs 44.
  • a stopper rod valve 74 in the ladle 42 is pulled and molten stainless steel or other cladding metal 41 is poured from the ladle 42, piercing the aluminum disc inlet 44, through the degassing area 46 and into the tundish 47.
  • the pouring within a vacuum accomplishes a degassing operation.
  • a copper airlock 45 is brought into place to seal the burned out aluminum disc inlet 44.
  • the tundish 47 is pivoted along its axis so as to pour molten metal 41 from the production outlets 50. After the production operation is complete, the tundish 47 is tilted in the opposite direction and the excess metal flows into the spill ladle 57.
  • the production operation consists of a continuous casting process where the frame member 31 together with the backing plate 32 continually move downwardly between the series of guide rollers 40, the backing plate 32 being positioned so that the face of the clad is facing the tundish 47.
  • the hydraulic support means 24 lowers the framed backing plate 32 downwardly opposite the runner 51 together with the mold 52 and the downward motion is correlated with the rate of flow of molten metal from the ladle 42 through the tundish 47 and out of the production outlets 50 onto the face of the moving hacking plate 32.
  • the mold 52 is held into contact with the graphite frame parts 34 by means of the compression spring 56.
  • the front of the mold 52 is a graphite face 54.
  • the back portion is a water-cooled copper girder.
  • the upper frame part 33 blocks further flow of metal from runner 51, the valve 74 is moved downward to stop the flow of molten metal 41 from the ladle 42, and the tundish 47 is pivoted in the opposite direction to discharge excess metal into the spill ladle 57.
  • the vacuum within the tank 20 is 'broken by any appropriate means and the hydraulic support means 24 moves upwardly to bring the backing plate 32 together with the frame member 31 in the vicinity of the loading door 22 which is opened.
  • the crane 67 removes the frame member 31 together with the backing plate 32 and, if desired and if further metal is available, places a further frame member and backing plate onto the hydraulic support means 24.
  • FIGURE 4 illustrates the solidification of the cladding during the pouring process.
  • FIGURE 5 illustrates a modification wherein a thin backing plate 32a is employed with a thick layer of dividing compound 84 applied thereto.
  • the molded section 85 is a slab. Such slabmay, while still hot, .be placed in a further frame member 31 and cladded.
  • a pulse means 86 which consists of :a piston 87 which is reciprocated within a cylinder 90 having a fluid connection with the cylinder 26.
  • the reciprocating piston 87 will communicate hydraulic pressure pulses tothe piston means 27 whereby the piston 27 is vibrated vertically simultaneously with its being lowered, which vibrations are transmitted through the plunger 25 to the backing plate 32 within the frame member 31a to prevent sticking between the mold 52 and the solidified metal which has just been poured adjacent thereto.
  • a second vibrating means comprises a series of mag netostrictive transducer heads 59 attached to the mold 52.
  • Such heads transmit vibrations in the 1 to 50 kilocycle frequency range or higher and the term sonic vibration as used herein is intended to describe that acoustic energy which has a frequency above 1 kilocycle per second and may range from such frequency to many megacycles per second.
  • the magnetostrictive transducer heads 59 have the effect of preventing stickage of the mold to the solidifying metal in the vicinity thereof during operation of the apparatus and, in addition, tend to homogenize the clad metal and cause a finer grain structure therein.
  • Vibration in the mold 52 may also be produced (FIGS. 11-12) by a rotating cam member 94 received within a bore 95 in the mold member 52.
  • the cam 94 acts upon a segment 96- disposed at the top of the bore 95, whereby with each revolution the mold 52 is raised slightly, following which it lowers slightly.
  • the cam is designed and its r.p.m. controlled so that the mold 52 and the adjacent clad never travel at the same speed whereby sticking is prevented.
  • the cam member 94 within the bore 95 also acts to support the mold 52.
  • the mold 52 may be brought flush with the graphite frame parts 34.
  • the mold 52 has a graphite face 54 and is cooled by the circulation of water in jacket 53.
  • more rapid cooling means comprising water nozzles 101a and 1011) are disposed below the mold 52 (FIG. 7) and to either side of the hacking plate and clad metal as it is lowered .by plunger 25.
  • Steam produced by water sprayed on the hot recently solidified metal has the effect of tending to break the vacuum within the tank which is generally a desirable condition at this point. With the breaking of such vacuum the loading door 22 may be opened and the air from the atmosphere is then swept into such door while steam is evacuated through the exhaust outlet 21.
  • the nozzles 101a can also carry fluid and other substances to clean the surface of the backing plate 32 which is to be clad. Since such cleansing takes place in a vacuum, metal once clean tends to stay clean, a circumstance which enhances the metallurgical bond between the cladding metal and the backing plate.
  • Removal means 104 is provided at the bottom of tank 20 for the removal of spent material, debris, liquid, and the like. It will be understood by those skilled in the art that the removed material and liquid can frequently be separated for subsequent re-use.
  • a gas inlet 105 is provided in the vicinity of the degassing area. Such gas inlet 105 may selectively provide a jet of gas to intercept the stream of molten metal,
  • such gas generally being an inert gas.
  • an inert gas is employed, a turbulence may be produced wherein the degassing effect is enhanced.
  • a bank of radiant heating cells 106 perform essentially the same function as the induction heater 65 of the first embodiment.
  • a further exhaust outlet 107 is placed in the proximity of the inlet 44 to insure the exhaust of gases which may enter with the poured metals.
  • an airlock such as airlock 45 in the first embodiment or other appropriate covering means may be placed over the inlet 44 in order to maintain a pressure-tight condition within the tank 20.
  • the frame member 31a may be first lowered through the loading door 22 onto hydraulic support means 24, following which such door is closed and atmosphere is exhausted from the tank 20.
  • Plungers 25 lower the frame member 31a whereby the face of the backing slab 32 to be clad may be thoroughly cleaned by action of the treating nozzle 102 or the water nozzle 101a or a combination of both.
  • Plunger 25 is then raised to the position shown in FIGURE 7, mold 52 is brought flush with frame member 31a, and, as previously described, molten metal from the ladle 42 is received in the tundish 47.
  • a stream of argon gas 110 intersects the stream of molten metal to assist the degassing process in the area 46.
  • the metal is then poured into the runner 51 and at the same time valve 91 is opened and pulse means 86 is started whereby the plunger 25 is lowered and at the same time vibrated through impulses imparted by pulse means 86.
  • vibrations may be augmented by the rotation of the cam 94 by means of the motor 98 in the mold 52 and by actuation of the transducer heads 59.
  • the heating elements 106 are turned on in order to keep the backing plate 32 from warping or bending due to the heat generated by the poured unetal.
  • the exhaust pumps may then be again started to evacuate the steam from the tank 20 and the plunger 25 is raised by closing the valve 91 and starting the pump 1-11.
  • Pulse means 86 is secured when the backing plate 32 together with the poured metal which is now cladded onto such plate no longer contacts mold 52.
  • the surface of the slab can be further treated by shot peening, plating by peening, or the like.
  • FIGURE 13 shows a melting furnace 114 connected to a modified tank 20a by means of a conduit 115.
  • the conduit 115 is made of refractory material or other suitable substances for the conveyance of molten metal, such as steel.
  • the outlet 116 of conduit 115 is higher than the level of the metal 117 in the melting furnace 114. Consequently, by controlling the degree of vacuum in the tank 20a--and hence the pressure differential between the two units-the rate of flow of molten metal 117 through conduit 115 to the inlet 116 may be controlled.
  • the modified frame means 31a is shown in FIGURE 14.
  • the guide rails 3711 are incorporated in the frame member 31a and an inwardly extending flange 33a is provided in the after portion of the frame means 31a.
  • the graphite frame parts 34a and the backing plate 32a can be readily assembled in such a frame member.
  • FIGURE 16 discloses a frame member 31a which has a backing plate 32b similar to the backing plate 32a except that its surface 381) has been scored to provide an additional surface interlock between the molten metal and the surface 381).
  • FIGURE 17 shows a frame member 31c which in all respects is similar to frame member 31a except that a plurality of vertical division plates 39c create a plurality of spaces to receive backing plates in the form of billets for cladding, or, alternatively, by the use of dividing compound as shown in FIGURE 5, billets may be formed, per se.
  • the dividing plates 390 will be composed of graphite.
  • FIGURE 18 illustrates a further refinement wherein the slab 32 is preheated on both or either side, as desired, before and during the casting step when the piston lowers the frame member.
  • the same reference numbers as those seen in the FIGURE 1 device are used insofar as applicable.
  • heating elements 202 which are located between insulating screens 201 and the front and back of slab 32.
  • the preferred heating elements are longitudinally arranged so that substantially the entire front and back surfaces of the slab can be preheated at the same time.
  • Suitable heating elements are silicon carbide rods although alternative arrangements will occur to one skilled in the art.
  • Induction heater 65 can be eliminated but except for this change and the modification of the tank top, the apparatus and process described in connection with FIG- URE 1 are the same.
  • the heating elements are arranged so that the temperature of at least the front and back surfaces of slab 32 or either of them may quickly be brought to a temperature in the order of 2200 F. or above. Although much lower temperatures down to about 800 F. have some effect in the avoidance of premature freezing of the poured metal, it has been postulated that in the instance of pouring 18-8 stainless steel on a carbon steel backing plate, superior wetting and, accordingly, better welding occurs when the surface temperature of the slab is 2200 F. or more with the temperature of the stainless steel melt being above 2650 F. to about 3000 F.
  • Commercially available heating elements of silicon carbide can be heated to about 3100 F. and are capable of heating the slab surfaces to the desired temperatures in a relatively short time. Other ways of raising the temperature of the slab surfaces such as induction heating within or without the tank 20 can also be employed, but if preheating is done it is preferable to carry it out completely within the tank using resistance heating elements.
  • the plunger can be moved upwardly until the clad backing plate is again in preheat position.
  • the cladded plate can then be heated to annealing temperatures before being removed from the top of the tank.
  • Apparatus for cast cladding which comprises a pressure chamber (20), an evacuation means (21) operatively connected to said chamber, opening means (22) in the upper part of said chamber for admitting a vertically disposed rectangular metallic slab (32), reciprocating means (24) disposed .under said opening within said chamber for moving said slab up and down in a vertical plane, horizontally disposed mold means (52) carried in said chamber positioned to be proximate and including a planar surface substantially parallel to the surface of said slab .carried by said reciprocating means, said slab being movable past said mold means while maintaining molten metal retaining relationship with said mold means, a molten metal inlet (44) in the upper portion of said chamber and a molten metal receiving and distributing means (47) within said chamber disposed to receive molten metal from said inlet and distribute same to said mold means, said mold means being limited to the region for casting metal on said slab, whereby when said molten metal is so distributed to said mold means and said slab is moved downward by said reciprocating means, a cla
  • sonic vibrations means (59) are incorporated in said mold means, said sonic vibration means adapted to vibrate said mold relative to metal adjacent thereto to promote stripping of said metal from said mold.
  • heating means (202) is positioned in the upper part of said chamber for preheating said slab while positioned on said reciprocating means.
  • said reciprocating means includes a hydraulic cylinder (26) and piston (27), the fiuid in said cylinder under pressure from the weight of said slab, pump means (111) and discharge means (91) to introduce and discharge fluid from said cylinder for reciprocating said slab, and pulse means (86) interconnected with the fluid in said cylinder whereby the downward speed of said reciprocating means is varied by pressure pulsations introduced on said fluid by said pulse means within said cylinder.
  • a heating means (65) is included within said chamber positioned on the side of said slab opposite said mold means whereby the back of said slab receiving said molten metal may be heated to prevent warping of said slab.
  • cooling means (101a, 101b) are incorporated in said chamber positioned below said mold means to cool and promote solidification of said clad as it moves past said mold means.
  • cooling means are positioned to direct fluid on both sides of said slab following the casting of a clad thereon.
  • cleansing means (102) are positioned within said chamber to direct cleansing material against said slab for removing oxides and other impurities therefrom.
  • said cleansing means directs a treating material at a high velocity to impinge upon said slab and a recovery means (104) operatively associated with said chamber to recover therefrom said spent treating material and debris removed from said slab.
  • An apparatus in accordance with claim 1 in combination with a melting furnace (114) containing molten metal (117), conduit means (115) connecting the lower portion of said furnace and said molten metal inlet, the latter having a height above the level of metal in said furnace whereby molten metal is received from said furnace in said chamber only when vacuum is applied in said chamber.
  • a mold for cladding a rectangular vertically disposed slab (32) on one face thereof which comprises a graphite frame (31) receiving said slab and embracing the edges thereof, said frame extending continuously forward of the face of said slab to form the ends of a space extending in front of said face, said space having a horizontally disposed rectangular cross section, a horizontal forming element (52) disposed across said frame opposite said face and in slidable molten metal retaining engagement with two parallel edges thereof, said forming element movable contiguous with said space and including a planar surface forming a partial fourth side surface of said rectangular space, and means to move relatively said forming element vertically upward along said space while maintaining said molten metal retaining engagement whereby molten metal introduced into said space between said slab and said forming element forms a clad of a uniform thickness and having the cross-sectional dimensions of said rectangular space on said slab said forming element being limited only to the essential region for casting metal on said slab.
  • Apparatus in accordance with claim 12 including a pressure chamber (2), an opening (22) in the upper part of said chamber for admitting said frame, and reciprocating means (24) disposed under said opening within said chamber for receiving said frame and comprising the means for relatively moving said forming element along said space.

Description

13, 1968 N. H. JENSEN ETAL 3,396,778
APPARATUS FOR CAST CLADDING Filed Aug. 24, 1964 6 Sheets-Sheet 1 INVENTORS N. H. JENSEN R. A. WEST/WAN E: L. FOGLEMAN Aug. 13, 1968 N, H, ENSEN EQ'IAL 3,396,778
APPARATUS FOR CAST CLADDING 6 Sheets-Sheet 2 N H JENSEN R. A. WESTMAN E: L. FOGLEMAN TTORNEYS Aug. 13, 1968 N.'H.JENSEN ETAL 3, 6,778
APPARATUS FOR CAST CLADDING Filed Aug. 24, 1964 e Sheets-Sheet 3 as i 9/ :1 SUMP 9o F 15.5
INVENTORS N. H JENSEN R. A. WES TMAN E L. F OGLEMAN ORNEYS Aug. 13, 1968 N.H.JENSEN E L APPARATUS FOR CAST CLADDING 6 Sheets-Sheet 5 Filed Aug. 24, 1964 INVENTORS M H JENSEN R. A. WESTMAN E L. FOG]. E MAN BY Mr); 4/07! ATTORNEYS United States Patent 3,396,778 APPARATUS FOR CAST CLADDING Niels H. Jensen, Glenmoore, Robert A. Westman, Coatesville, and Edgar L. Fogleman, Downingtown, Pa., assignors to Lukcns Steel Company, Coatesville, Pa., a corporation of Pennsylvania Continuation-impart of application Ser. No. 349,288,
Mar. 4, 1964. This application Aug. 24, 1964, Ser.
13 Claims. (Cl. 164275) ABSTRACT OF THE DISCLOSURE Cladding apparatus wherein a slab held in a graphite frame is lowered within a vacuum chamber past a horizontal mold which bears against the graphite frame and molten cladding metal is continuously poured between the slab and the mold, solidifying as it moves past the mold to form a cladding surface on the slab. The slab is preheated to promote a bond betwen the slab and the metal and prevent warping. The mold is vibrated to eliminate sticking. Alternatively, the frame with the slab is vibrated by pulsing its hydraulic lift for the same purpose.
Cross reference to related applications This application is a continuation-in-part of application Serial No. 349,288, filed Mar. 4, 1964, now abandoned.
Summary and objects 0 the invention This invention relates to an apparatus for casting clad on a backing plate which is vertically disposed. More particularly, it relates to such process and apparatus wherein the backing plate together with a frame surrounding at least three sides of the backing plate is moved relative to a continuous casting mold in front of and spaced from the backing plate whereby molten metal entering the mold is continuously cast as clad on the backing plate.
Broadly speaking, cladding is a method or process in which a dissimilar metal or alloy layer is metallurgically bonded to base material in order to produce a metallic surface with special properties not obtainable with the base metal alone, as, for example, corrosion resistance. When the cladding is accomplished on a slab or backing plate which is subsequently to be rolled, it is a usual method to prepare what is known in the art as a sandwich or pack wherein the backing plate and the cladding material are held within a hermetically sealed steel envelope which is heated and rolled to effect a metallurgical bond. Another method is to place a backing plate within a mold and to apply the clad in the form of molten metal directly on the face of the backing plate. When the clad metal is solidified the laminated metal slab may then be rolled.
Practical cladding techniques require that the clad be metallurgically bonded to the backing metal in such a way as to avoid undesirable alloying at the interfaces of the clad and the backing metal. It is also frequently important that the clad metal has substantially uniform chemical and physical properties throughout. The casting of the clad should be carried out at a reasonable rapid rate for the most economical use of the equipment.
Accordingly, it is an object of this invention to provide process or apparatus for cast cladding which is inexpensive, permits rapid cladding techniques, has considerable flexibility in the type and thickness of clad produced, and
is adaptable to the casting of slabs, billets, or blooms 3,396,778 Patented Aug. 13, 1968 vantages. For example, the cladding metal may be subjected to degassing or treatment under vacuum conditions just prior to its application to the backing plate. The thickness of the clad may be regulated Within relatively close tolerances. The backing plate may be cleaned under vacuum or inert gas conditions to free it from contaminants such as scale, rust or other oxides, oils, grease, or other foreign material which might form on the face of the clad. Heating means for preheating the backing plate can be used within the tank.
The system permits considerable versatility in means which may be emplowed to prevent the molten metal from sticking to the moving mold. For example, when the backing plate is lowered relative to the mold in a hydraulic lift, a pulse vibrator in the latter may be employed to keep the relative movement between the mold and the metal which has just been poured so that they are never travelling at the same speed and thus prevent sticking of the mold to the molten metal. Or a sonic vibrator may be incorporated in the mold both to prevent the mold from sticking to the molten metal and to contribute to a fine crystalline structure in the clad metal.
By the utilization of a pressure vessel in the system in which a vacuum can be created, such vacuum may be controlled as means to introduce metal into the system and also to assist in the discharge of treating materials, cooling substances, and the like.
The foregoing advantages are objects of this invention and other objects, adaptabilities, and capabilities will appear as the description progresses, reference being had to the accompanying drawings, in which:
Brief description of the invention FIGURE 1 is a vertical sectional view of an apparatus embodying the invention;
FIGURE 2 is a perspective view showing a plurality of apparatus such as shown in FIGURE 1 arranged with a melting furnace and a gantry crane;
FIGURE 3 is a horizontal section of the backing plate and frame as received in the apparatus illustrated in FIG- URE 1;
FIGURE 4 is a vertical section illustrating the process of continuous casting of the clad;
FIGURE 5 is similar to FIGURE 4 except that it shows how the process or apparatus of the invention may be utilized to cast a slab;
FIGURE 6 is a perspective view of a further embodiment of a pressure vessel in accordance with the invention;
FIGURE 7 is a side view of the pressure vessel shown in FIGURE 6, partially broken away to expose the apparatus within the vessel;
FIGURE 8 is a front view of the pressure vessel shown in FIGURE 6, also partially broken away;
FIGURE 9 is a horizontal sectional view of the pressure vessel illustrated in FIGURE 6;
FIGURE 10 shows a vibrating motor such as is used on the pressure vessel illustrated in FIGURE 6;
FIGURE 11 is a vertical sectional view of the mold showing the cooling jacket and the vibrating cam mem ber;
FIGURE 12 is a front elevational view of the mold shown in FIGURE 11;
FIGURE 13 shows a further modification wherein the pressure vessel is connected directly to the melting furnace;
FIGURE 14 is a perspective view showing a frame member as used in the invention carrying a backing plate;
FIGURE is a sectional view taken on lines 15-15 of FIGURE 14;
FIGURE 16 is similar to FIGURE 15 except that it shows a modification wherein the surface of the backing plate to be clad is scored; and
FIGURE 17 is a perspective view of a frame similar to FIGURE 14 except that it has a plurality of spaces for the receipt of the molten metal in the casting process in accordance with the invention.
FIGURE 18 is a vertical sectional view of an apparatus similar to that shown in FIGURE 1 including means for preheating the slab or backing plate.
Description of the preferred embodiments Referring now to FIGURE 1, a pressure vessel comprising a cylindrical tank 20 has an exhaust outlet 21 which leads to a vacuum source such as vacuum pumps (not shown). Disposed on top of the tank 20 is a loading door 22 which is positioned directly over a hydraulic support means 24. The latter includes a plunger 25 which is received in a hydraulic cylinder 26 by a piston member 27. A bushing 30 around the plunger 25 guides the plunger and assists in maintaining same in a vertical position. It will be appreciated that by the introduction of a hydraulic fluid and varying the pressure in the hydraulic cylinder 26 under the piston member 27, the plunger 25 may be reciprocated.
The hydraulic support means 24 provides support for a frame member designated generally 31. In the embodiment shown in FIGURE 3, the frame member 31 contains a backing plate or slab 32 which has vertical graphite frame parts 34, one on each vertical side edge thereof. There are further graphite frame parts 33 and on the upper and lower edges, respectively, of the backing plate 32, whereby such backing plate is surrounded on its lower and vertical sides :by the graphite frame parts 35 and 34. It will be understood that the leading edges of the graphite frame parts 34 and 35 are coplanar. The frame member 31 together with backing plate 32 are carried by a guide jig 36 which incorporates on its sides guide rails 37. The rails 37 are received between t-wo lines of guide rollers 40* carried by the tank 20. By such means or other appropriate apparatus as will occur to one skilled in the art, the frame member 31 may be reciprocated by the hydraulic support means 24 along a vertical coplanar path.
Molten metal 41 contained in a ladle 42 enters the tank 20 through a aluminum disc inlet 44. When molten metal 41 is not flowing, a copper airlock 45 seals the burned down aluminum disc inlet 44. The molten metal 41 drops through a degassing area 46 into a tundish 47.
In the cladding process, the metal pours out of the tundish through the production outlets 50 and is received in a channel means or runner 51 which is carried immediately by a spring-loaded copper mold 52 having a graphite face 54. The mold 52 together with the runner 51 are supported by a framework 55 which is firmly attached to the tank 20. The mold 52 is spring-loaded by means of a compression spring 56 which urges the mold 52 away from the framework 55'. A spill ladle 57 is disposed under the excess outlets 60 of the tundish 47. The tundish 47 is carried by a pivot means 61 which may be manually controlled outside of the tank 20 by any suitable means known to the art. It will be understood that pivot means 61 can be tilted in vertical plane in order to compensate for unequal molten metal from one side or the other of runner 51 by any number of means which would occur to one skilled in the art. Accordingly, when desired, molten metal in the tundish 47 may be spilled into the spill ladle 57. A door 62 in the tank 20 is disposed adjacent to the spill ladle 57 whereby when such door is opened, the spill ladle 57 may be rolled out from the tank 20 on tracks 64.
An induction heater 65 is provided to compensate for bending and warping due to the heat of the molten metal on one side of the backing plate 32.
In operation, a frame member 31 containing a preheated backing plate 32 is carried from an assembly area 66 by an overhead crane 67 and deposited through an open loading door 22 onto the hydraulic support means 24 within a tank 20. The loading door 22 is then secured and a vacuum is pulled within the tank through the exhaust outlet 21. At approximately the same time the crane 67 deposits a ladle 42 with molten metal 41, recently poured therein from a melting furnace 70, onto supports 71 carried on a platform 72 above the tanks 20 except for the protruding loading doors 22 and inlets with discs 44. When sufficient vacuum has formed within the tank 21 a stopper rod valve 74 in the ladle 42 is pulled and molten stainless steel or other cladding metal 41 is poured from the ladle 42, piercing the aluminum disc inlet 44, through the degassing area 46 and into the tundish 47. The pouring within a vacuum accomplishes a degassing operation. After the ladle 42 has been emptied, a copper airlock 45 is brought into place to seal the burned out aluminum disc inlet 44. The tundish 47 is pivoted along its axis so as to pour molten metal 41 from the production outlets 50. After the production operation is complete, the tundish 47 is tilted in the opposite direction and the excess metal flows into the spill ladle 57.
The production operation consists of a continuous casting process where the frame member 31 together with the backing plate 32 continually move downwardly between the series of guide rollers 40, the backing plate 32 being positioned so that the face of the clad is facing the tundish 47. Thus the hydraulic support means 24 lowers the framed backing plate 32 downwardly opposite the runner 51 together with the mold 52 and the downward motion is correlated with the rate of flow of molten metal from the ladle 42 through the tundish 47 and out of the production outlets 50 onto the face of the moving hacking plate 32. The mold 52 is held into contact with the graphite frame parts 34 by means of the compression spring 56. As previously noted, the front of the mold 52 is a graphite face 54. The back portion is a water-cooled copper girder.
When the casting operation is complete, the upper frame part 33 blocks further flow of metal from runner 51, the valve 74 is moved downward to stop the flow of molten metal 41 from the ladle 42, and the tundish 47 is pivoted in the opposite direction to discharge excess metal into the spill ladle 57. The vacuum within the tank 20 is 'broken by any appropriate means and the hydraulic support means 24 moves upwardly to bring the backing plate 32 together with the frame member 31 in the vicinity of the loading door 22 which is opened. The crane 67 removes the frame member 31 together with the backing plate 32 and, if desired and if further metal is available, places a further frame member and backing plate onto the hydraulic support means 24.
FIGURE 4 illustrates the solidification of the cladding during the pouring process. Hence it will be noted that as a stream of metal is poured into the water-cooled copper mold 52 it forms a hard skin 81.
FIGURE 5 illustrates a modification wherein a thin backing plate 32a is employed with a thick layer of dividing compound 84 applied thereto. In this modification, the molded section 85 is a slab. Such slabmay, while still hot, .be placed in a further frame member 31 and cladded.
In the modification shown in FIGURES 6 through 12, the same reference characters have been utilized insofar as applicable. This modification is included to show the adaptability of the system for specialized applications. Accordingly, it will be noted that three distinctive means to vibrate the mold 52. have been provided. The first is a pulse means 86 which consists of :a piston 87 which is reciprocated within a cylinder 90 having a fluid connection with the cylinder 26. Thus when the plunger 25 is lowered by opening valve 91, the reciprocating piston 87 will communicate hydraulic pressure pulses tothe piston means 27 whereby the piston 27 is vibrated vertically simultaneously with its being lowered, which vibrations are transmitted through the plunger 25 to the backing plate 32 within the frame member 31a to prevent sticking between the mold 52 and the solidified metal which has just been poured adjacent thereto.
A second vibrating means comprises a series of mag netostrictive transducer heads 59 attached to the mold 52. Such heads transmit vibrations in the 1 to 50 kilocycle frequency range or higher and the term sonic vibration as used herein is intended to describe that acoustic energy which has a frequency above 1 kilocycle per second and may range from such frequency to many megacycles per second. The magnetostrictive transducer heads 59 have the effect of preventing stickage of the mold to the solidifying metal in the vicinity thereof during operation of the apparatus and, in addition, tend to homogenize the clad metal and cause a finer grain structure therein.
Vibration in the mold 52 may also be produced (FIGS. 11-12) by a rotating cam member 94 received within a bore 95 in the mold member 52. The cam 94 acts upon a segment 96- disposed at the top of the bore 95, whereby with each revolution the mold 52 is raised slightly, following which it lowers slightly. The cam is designed and its r.p.m. controlled so that the mold 52 and the adjacent clad never travel at the same speed whereby sticking is prevented.
In this embodiment, the cam member 94 within the bore 95 also acts to support the mold 52. The position of the mold 52 relative to the frame member 31a is determined =by the position of the motor 98 on its support stand 97 which is firmly connected to the tank 22. It will be appreciated that the shaft 100 of the motor 96 connects with the cam 94 and rotates same. By moving a motor 98 horizontally on both sides of the tank 22, by cranks and screws 99 journaled to stand 97 and threadably received by the mounts of motor 93, the mold 52 may be brought flush with the graphite frame parts 34.
The mold 52 has a graphite face 54 and is cooled by the circulation of water in jacket 53.
In order to cool the clad together with the backing plate, more rapid cooling means comprising water nozzles 101a and 1011) are disposed below the mold 52 (FIG. 7) and to either side of the hacking plate and clad metal as it is lowered .by plunger 25. Steam produced by water sprayed on the hot recently solidified metal has the effect of tending to break the vacuum within the tank which is generally a desirable condition at this point. With the breaking of such vacuum the loading door 22 may be opened and the air from the atmosphere is then swept into such door while steam is evacuated through the exhaust outlet 21. The nozzles 101a can also carry fluid and other substances to clean the surface of the backing plate 32 which is to be clad. Since such cleansing takes place in a vacuum, metal once clean tends to stay clean, a circumstance which enhances the metallurgical bond between the cladding metal and the backing plate.
It is, however, sometimes desirable to treat specially the surface of the backing plate 32 to be clad. This may be accomplished through the treating nozzle 102. Such treatment may consist of shot peening which will both clean and treat such surface or plating by the shot method such as is, for example, disclosed in the patent to N. C. Parrish, No. 2,618,572 of November 18, 1962, for the metal titanium. By such means an intermediary layer may be produced on the surface of backing plate 32 to be clad. Removal means 104 is provided at the bottom of tank 20 for the removal of spent material, debris, liquid, and the like. It will be understood by those skilled in the art that the removed material and liquid can frequently be separated for subsequent re-use.
A gas inlet 105 is provided in the vicinity of the degassing area. Such gas inlet 105 may selectively provide a jet of gas to intercept the stream of molten metal,
such gas generally being an inert gas. Where an inert gas is employed, a turbulence may be produced wherein the degassing effect is enhanced.
A bank of radiant heating cells 106 perform essentially the same function as the induction heater 65 of the first embodiment.
In this embodiment a further exhaust outlet 107 is placed in the proximity of the inlet 44 to insure the exhaust of gases which may enter with the poured metals. When the metal stops pouring, an airlock such as airlock 45 in the first embodiment or other appropriate covering means may be placed over the inlet 44 in order to maintain a pressure-tight condition within the tank 20.
In operation, the frame member 31a, together with the backing plate 32, may be first lowered through the loading door 22 onto hydraulic support means 24, following which such door is closed and atmosphere is exhausted from the tank 20. Plungers 25 lower the frame member 31a whereby the face of the backing slab 32 to be clad may be thoroughly cleaned by action of the treating nozzle 102 or the water nozzle 101a or a combination of both. Plunger 25 is then raised to the position shown in FIGURE 7, mold 52 is brought flush with frame member 31a, and, as previously described, molten metal from the ladle 42 is received in the tundish 47. A stream of argon gas 110 intersects the stream of molten metal to assist the degassing process in the area 46. The metal is then poured into the runner 51 and at the same time valve 91 is opened and pulse means 86 is started whereby the plunger 25 is lowered and at the same time vibrated through impulses imparted by pulse means 86. If desired, such vibrations may be augmented by the rotation of the cam 94 by means of the motor 98 in the mold 52 and by actuation of the transducer heads 59. The heating elements 106 are turned on in order to keep the backing plate 32 from warping or bending due to the heat generated by the poured unetal. As the plunger brings the backing slab 32 together with the clad metal past the water nozzles 101a and 101b and the pouring operation is nearing completion, such nozzles are opened in order to remove the heat from such backing plate and the recently molten metal. When the top of the slab passes the runner 51, the ladle is stopped and excess metal in the tundish 47 is spilled into the spill ladle 57. The vacuum pump is now cut off and with the continued lowering of the heated backing plate 32 and the clad past the water nozzles 101a and 101b, the tank 22 fills with steam to break the vacuum within the tank 20 to permit the opening of loading door 22. The exhaust pumps may then be again started to evacuate the steam from the tank 20 and the plunger 25 is raised by closing the valve 91 and starting the pump 1-11. Pulse means 86 is secured when the backing plate 32 together with the poured metal which is now cladded onto such plate no longer contacts mold 52.
If desired, following the cooling of the slab, the surface of the slab can be further treated by shot peening, plating by peening, or the like.
FIGURE 13 shows a melting furnace 114 connected to a modified tank 20a by means of a conduit 115. The conduit 115 is made of refractory material or other suitable substances for the conveyance of molten metal, such as steel. The outlet 116 of conduit 115 is higher than the level of the metal 117 in the melting furnace 114. Consequently, by controlling the degree of vacuum in the tank 20a--and hence the pressure differential between the two units-the rate of flow of molten metal 117 through conduit 115 to the inlet 116 may be controlled.
The modified frame means 31a is shown in FIGURE 14. In such frame member, the guide rails 3711 are incorporated in the frame member 31a and an inwardly extending flange 33a is provided in the after portion of the frame means 31a. The graphite frame parts 34a and the backing plate 32a can be readily assembled in such a frame member.
FIGURE 16 discloses a frame member 31a Which has a backing plate 32b similar to the backing plate 32a except that its surface 381) has been scored to provide an additional surface interlock between the molten metal and the surface 381).
FIGURE 17 shows a frame member 31c which in all respects is similar to frame member 31a except that a plurality of vertical division plates 39c create a plurality of spaces to receive backing plates in the form of billets for cladding, or, alternatively, by the use of dividing compound as shown in FIGURE 5, billets may be formed, per se.
It will be understood that normally the dividing plates 390 will be composed of graphite.
FIGURE 18 illustrates a further refinement wherein the slab 32 is preheated on both or either side, as desired, before and during the casting step when the piston lowers the frame member. The same reference numbers as those seen in the FIGURE 1 device are used insofar as applicable.
It will be noted that the top portion of tank 20' supporting the holding door 22 has been extended to accommodate heating elements 202 which are located between insulating screens 201 and the front and back of slab 32. The preferred heating elements are longitudinally arranged so that substantially the entire front and back surfaces of the slab can be preheated at the same time. Suitable heating elements are silicon carbide rods although alternative arrangements will occur to one skilled in the art.
Induction heater 65 can be eliminated but except for this change and the modification of the tank top, the apparatus and process described in connection with FIG- URE 1 are the same.
The heating elements are arranged so that the temperature of at least the front and back surfaces of slab 32 or either of them may quickly be brought to a temperature in the order of 2200 F. or above. Although much lower temperatures down to about 800 F. have some effect in the avoidance of premature freezing of the poured metal, it has been postulated that in the instance of pouring 18-8 stainless steel on a carbon steel backing plate, superior wetting and, accordingly, better welding occurs when the surface temperature of the slab is 2200 F. or more with the temperature of the stainless steel melt being above 2650 F. to about 3000 F. Commercially available heating elements of silicon carbide can be heated to about 3100 F. and are capable of heating the slab surfaces to the desired temperatures in a relatively short time. Other ways of raising the temperature of the slab surfaces such as induction heating within or without the tank 20 can also be employed, but if preheating is done it is preferable to carry it out completely within the tank using resistance heating elements.
After cast cladding has been completed the plunger can be moved upwardly until the clad backing plate is again in preheat position. The cladded plate can then be heated to annealing temperatures before being removed from the top of the tank.
The foregoing detailed description has been given for clearness of understanding only, and no unnecessary limitations should be understood therefrom, for further modifications will be obvious to those skilled in the art.
Having thus described our invention, what we claim as new and desire to secure by Letters Patent of the United States is:
*1. Apparatus for cast cladding which comprises a pressure chamber (20), an evacuation means (21) operatively connected to said chamber, opening means (22) in the upper part of said chamber for admitting a vertically disposed rectangular metallic slab (32), reciprocating means (24) disposed .under said opening within said chamber for moving said slab up and down in a vertical plane, horizontally disposed mold means (52) carried in said chamber positioned to be proximate and including a planar surface substantially parallel to the surface of said slab .carried by said reciprocating means, said slab being movable past said mold means while maintaining molten metal retaining relationship with said mold means, a molten metal inlet (44) in the upper portion of said chamber and a molten metal receiving and distributing means (47) within said chamber disposed to receive molten metal from said inlet and distribute same to said mold means, said mold means being limited to the region for casting metal on said slab, whereby when said molten metal is so distributed to said mold means and said slab is moved downward by said reciprocating means, a clad is cast from said molten metal on said slab as said slab moves past said mold means.
2. An apparatus in accordance with claim 1 wherein sonic vibrations means (59) are incorporated in said mold means, said sonic vibration means adapted to vibrate said mold relative to metal adjacent thereto to promote stripping of said metal from said mold.
3. An apparatus in accordance with claim 1 wherein heating means (202) is positioned in the upper part of said chamber for preheating said slab while positioned on said reciprocating means.
4. An apparatus in accordance with claim 1 wherein said reciprocating means includes a hydraulic cylinder (26) and piston (27), the fiuid in said cylinder under pressure from the weight of said slab, pump means (111) and discharge means (91) to introduce and discharge fluid from said cylinder for reciprocating said slab, and pulse means (86) interconnected with the fluid in said cylinder whereby the downward speed of said reciprocating means is varied by pressure pulsations introduced on said fluid by said pulse means within said cylinder.
5. An apparatus in accordance with claim 1 wherein a gas inlet is provided into said chamber disposed whereby gas may be directed therefrom to said molten metal received within said chamber.
6. An apparatus in accordance with claim 1 wherein a heating means (65) is included within said chamber positioned on the side of said slab opposite said mold means whereby the back of said slab receiving said molten metal may be heated to prevent warping of said slab.
7. An apparatus in accordance with claim 20 wherein cooling means (101a, 101b) are incorporated in said chamber positioned below said mold means to cool and promote solidification of said clad as it moves past said mold means.
8. An apparatus in accordance with claim 7 wherein said cooling means are positioned to direct fluid on both sides of said slab following the casting of a clad thereon.
9. An apparatus in accordance with claim 1 wherein cleansing means (102) are positioned within said chamber to direct cleansing material against said slab for removing oxides and other impurities therefrom.
10. An apparatus in accordance with claim 9 wherein said cleansing means directs a treating material at a high velocity to impinge upon said slab and a recovery means (104) operatively associated with said chamber to recover therefrom said spent treating material and debris removed from said slab.
11. An apparatus in accordance with claim 1 in combination with a melting furnace (114) containing molten metal (117), conduit means (115) connecting the lower portion of said furnace and said molten metal inlet, the latter having a height above the level of metal in said furnace whereby molten metal is received from said furnace in said chamber only when vacuum is applied in said chamber.
12. A mold for cladding a rectangular vertically disposed slab (32) on one face thereof which comprises a graphite frame (31) receiving said slab and embracing the edges thereof, said frame extending continuously forward of the face of said slab to form the ends of a space extending in front of said face, said space having a horizontally disposed rectangular cross section, a horizontal forming element (52) disposed across said frame opposite said face and in slidable molten metal retaining engagement with two parallel edges thereof, said forming element movable contiguous with said space and including a planar surface forming a partial fourth side surface of said rectangular space, and means to move relatively said forming element vertically upward along said space while maintaining said molten metal retaining engagement whereby molten metal introduced into said space between said slab and said forming element forms a clad of a uniform thickness and having the cross-sectional dimensions of said rectangular space on said slab said forming element being limited only to the essential region for casting metal on said slab.
13. Apparatus in accordance with claim 12 including a pressure chamber (2), an opening (22) in the upper part of said chamber for admitting said frame, and reciprocating means (24) disposed under said opening within said chamber for receiving said frame and comprising the means for relatively moving said forming element along said space.
References Cited UNITED STATES PATENTS Flammang et al 164-309 Brenner 164-86 Hopkins 16452 Chimelewski 164281 X Brennan 164-'156 X Bohme 16486 Schaefer 164-275 Korb 164-49 FOREIGN PATENTS I. SPENCER OVERHOLSER, Primary Examiner.
V. K. RISING, Assistant Examiner.
UNITED STATES PATENT OFFICE CERTIFICATE OF CORRECTION Patent No. 3,396,778 August 13, 1968 Niels H. Jensen et al.
It is certified that error appears in the above identified patent and that said Letters Patent are hereby corrected as shown below:
Column 1, line 60, "reasonable" should read reasonably Column 2, line 12, "emplowed" should read employed Column 3, line 49, "a" should read an Column 7, line 6, the "c" in "39c" should be in italics. Column 8, line 40, "20" should read l line 69, "ends" should read sides Column 9, line 1, "movable" should read movably Signed and sealed this 20th day of January 1970.
(SEAL) Attest:
Edward M. Fletcher, Jr.
Commissioner of Patents Attesting Officer WILLIAM E. SCHUYLER, JR.
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US3633866A (en) * 1970-01-14 1972-01-11 Shapeweld Inc Apparatus for cladding metal
US3658119A (en) * 1968-04-03 1972-04-25 Airco Inc Apparatus for processing molten metal in a vacuum
US3712367A (en) * 1971-02-11 1973-01-23 Kaiser Aluminium Chem Corp Cladding mold system
US3733157A (en) * 1970-08-03 1973-05-15 Sund Borg Machines Corp Apparatus for molding plastic sheet
US3878882A (en) * 1972-01-13 1975-04-22 Paton Boris E Method for producing shaped ingots by electroslag remelting
US3896878A (en) * 1972-01-13 1975-07-29 Boris Izrailevich Medovar Apparatus for electroslag smelting of shaped ingots
FR2703278A1 (en) * 1993-04-02 1994-10-07 Forscat International Method and device for producing a metal casing on an elongated core.
US20060102314A1 (en) * 2004-11-16 2006-05-18 Jacques Michael P Continuous casting of reactionary metals using a glass covering
US20070204970A1 (en) * 2004-11-16 2007-09-06 Rmi Titanium Company Continuous casting of reactionary metals using a glass covering
US20090008059A1 (en) * 2004-11-16 2009-01-08 Rmi Titanium Company Dba Rti Niles Method and apparatus for sealing an ingot at initial startup
US7484548B2 (en) 2004-11-16 2009-02-03 Rmi Titanium Company Continuous casting of reactionary metals using a glass covering
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US3658119A (en) * 1968-04-03 1972-04-25 Airco Inc Apparatus for processing molten metal in a vacuum
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US7484549B2 (en) 2004-11-16 2009-02-03 Rmi Titanium Company Continuous casting of reactionary metals using a glass covering
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US20090008059A1 (en) * 2004-11-16 2009-01-08 Rmi Titanium Company Dba Rti Niles Method and apparatus for sealing an ingot at initial startup
US7484548B2 (en) 2004-11-16 2009-02-03 Rmi Titanium Company Continuous casting of reactionary metals using a glass covering
US20070204970A1 (en) * 2004-11-16 2007-09-06 Rmi Titanium Company Continuous casting of reactionary metals using a glass covering
US20100282427A1 (en) * 2004-11-16 2010-11-11 Rti International Metals, Inc. Continuous casting sealing method
US7926548B2 (en) 2004-11-16 2011-04-19 Rti International Metals, Inc. Method and apparatus for sealing an ingot at initial startup
US20110146935A1 (en) * 2004-11-16 2011-06-23 Rti International Metals, Inc. Method and apparatus for sealing an ingot at initial startup
US8069903B2 (en) 2004-11-16 2011-12-06 Rti International Metals, Inc. Method and apparatus for sealing an ingot at initial startup
US8141617B2 (en) 2004-11-16 2012-03-27 Rti International Metals, Inc. Method and apparatus for sealing an ingot at initial startup
US8196641B2 (en) 2004-11-16 2012-06-12 Rti International Metals, Inc. Continuous casting sealing method
US8413710B2 (en) 2004-11-16 2013-04-09 Rti International Metals, Inc. Continuous casting sealing method

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